High-performance nylon material and preparation method thereof

By compounding nylon material components and using a twin-screw extruder to prepare high-performance nylon materials, the problem of material performance degradation in outdoor environments has been solved, achieving high strength, high modulus, long-term weather resistance, and resistance to high temperature and humidity.

CN120904677APending Publication Date: 2025-11-07NANJING JULONG SCIENCE & TECHNOLOGY CO LTD

Patent Information

Application Number
CN202510904520.3
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2025-07-01
Publication Date
2025-11-07

AI Technical Summary

Technical Problem

Existing nylon materials suffer from creep and UV aging issues when used outdoors for extended periods, leading to a decline in material performance and failing to meet the requirements for high strength, high modulus, long-term weather resistance, and resistance to high temperature and humidity.

Method used

High-performance nylon materials are prepared by rationally compounding polyamide 66, special nylon resin, glass fiber, antioxidants, lubricants, compatibilizers, wear-resistant additives, weather-resistant additives, and black masterbatch, etc., and melt blending is carried out using a twin-screw extruder to form a material with low coefficient of friction, low wear, high strength, and high modulus.

Benefits of technology

It significantly improves the material's oxidation resistance, weather resistance, and stability, extends its service life, and meets the high-performance requirements of outdoor precision bearings.

✦ Generated by Eureka AI based on patent content.

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Abstract

The invention provides a high-performance nylon material and a preparation method thereof. The high-performance nylon material comprises the following components in parts by weight: 30-65 parts of polyamide 66; 5 to 25 parts of special nylon resin; 30 to 35 parts of glass fiber; 0.2 to 0.4 part of an antioxidant; 0.4 to 0.8 part of a lubricant; 1 to 3 parts of compatilizer; 5-15 parts of a wear-resistant auxiliary agent; 0.6 to 1.0 part of a weather-proof auxiliary agent; and 0.3 to 0.7 part of black master batch. The nylon material prepared by the invention is suitable for performance requirements of outdoor precision bearings, and has excellent performances of low friction coefficient, low abrasion, high strength, high modulus, long-period weather resistance, long-period high temperature and high humidity resistance and the like.
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Description

TECHNICAL FIELD

[0001] The present application belongs to the technical field of high polymer materials, and particularly relates to a high-performance nylon material and a preparation method thereof. BACKGROUND

[0002] Nylon is a kind of polyamide thermoplastic resin, also known as PA, which is widely used in engineering plastics and synthetic fibers and other fields due to its high strength, wear resistance, impact resistance and other characteristics, especially in mechanical parts such as bearings, supports, gears, etc. Nylon is widely used due to its lightweight, corrosion resistance and other characteristics.

[0003] Outdoor bearings and supports for wind power equipment are subjected to dynamic load and extreme temperature environment for a long time, and higher requirements are put forward for the material performance. The main materials used for outdoor bearings and supports at present include glass fiber reinforced nylon, specifically polyamide 66, abbreviated as PA66, which is a semi-transparent or opaque milky white bag or yellow granular crystalline polymer, and has good mechanical properties, toughness, self-lubricating property, wear resistance, chemical resistance and other advantages.

[0004] Since the specific strength and Young's modulus of glass fiber are much greater than those of PA66, the linear expansion coefficient is about 1 / 20 of that of PA66, the water absorption rate is almost zero, and the heat resistance and chemical corrosion resistance are good. The prior art usually uses a coupling agent such as polysiloxane to prepare PA66 modified by glass fiber, which effectively improves the material rigidity, impact strength, wear resistance and high temperature resistance, and is used as a lightweight metal substitute for precision bearings and other parts.

[0005] CN110838232A discloses a new type of nylon bearing retainer, which uses PA66 and PA6 as the main polyamide resin material, polytetrafluoroethylene as the wear-resistant agent, and glass fiber as the reinforcing fiber to obtain a new type of nylon material with good tensile strength, reduced wear and heat generation, and resistance to thermal expansion and cold shrinkage. However, bearings and supports used outdoors have problems such as long-term creep and ultraviolet aging based on special application environment, and long-term outdoor use may cause continuous load deformation and brittle material defects, resulting in further shortening of the service life of the material or safety problems.

[0006] In summary, the structure of the engineering plastic bearing support is relatively complex, and in the working condition of the bearing in the outdoor environment, the injection molding material not only requires good flowability, low shrinkage and small product deformation, but also should have good mechanical properties, especially good impact strength, low wear, high temperature and humidity resistance, weather resistance and other properties, which puts forward higher performance requirements for nylon materials. SUMMARY

[0007] Therefore, the present application aims to solve the problem that the performance of the nylon material for outdoor precision bearing in the prior art does not meet the expected effect, and provides a high-performance nylon material and a preparation method thereof, which meets the performance required by the application scene of the workpiece, including low friction coefficient, low wear, high strength and high modulus, long-period weather resistance retention rate, and long-period high-temperature and high-humidity performance retention rate, etc.

[0008] To achieve the above purpose, the present application proposes the following technical solutions:

[0009] A high-performance nylon material, specifically comprising the following components by weight:

[0010] Polyamide 66: 30-65 parts;

[0011] Special nylon resin: 5-25 parts;

[0012] Glass fiber: 30-35 parts;

[0013] Antioxidant: 0.2-0.4 parts;

[0014] Lubricant: 0.4-0.8 parts;

[0015] Compatibilizer: 1-3 parts;

[0016] Wear-resistant aid: 5-15 parts;

[0017] Weathering aid: 0.6-1.0 parts;

[0018] Black masterbatch: 0.3-0.7 parts.

[0019] Preferably, a high-performance nylon material, specifically comprising the following components by weight:

[0020] Polyamide 66: 35-45 parts;

[0021] Special nylon resin: 20-25 parts;

[0022] Glass fiber: 30-35 parts;

[0023] Antioxidant: 0.3-0.4 parts;

[0024] Lubricant: 0.5-0.8 parts;

[0025] Compatibilizer: 2-3 parts;

[0026] Wear-resistant aid: 10-15 parts;

[0027] Weathering aid: 0.8-1.0 parts;

[0028] Black masterbatch: 0.5-0.7 parts.

[0029] Further preferably, a high-performance nylon material specifically includes the following components by weight:

[0030] Polyamide 66: 35.5 parts;

[0031] Special nylon resin: 20 parts;

[0032] Glass fiber: 35 parts;

[0033] Antioxidant: 0.3 parts;

[0034] Lubricant: 0.5 parts;

[0035] Compatibilizer: 2 parts;

[0036] Wear-resistant aid: 10 parts;

[0037] Weathering aid: 1 part;

[0038] Black masterbatch: 0.7 parts.

[0039] Further, the nylon resin is one or a mixture of one or more of PA6I, PA610, PA612, and PAMXD6.

[0040] Specifically, polyamide 66, abbreviated as PA66, is polyhexamethylene adipamide, which is obtained by polycondensation of adipic acid and hexamethylene diamine; PA6I, i.e. nylon 6I, is m-phenylene isophthalamide hexamethylene diamine and fiber; PA610, i.e. nylon 610, is polyhexamethylene sebacamide; PA612, i.e. nylon 612, is polyhexamethylene dodecanamide; and PAMXD6, i.e. nylon MXD6, is poly-m-xylylenediamine adipamide.

[0041] Further, the special nylon resin includes PA6I, PA610, or PA612, and a mixture of PAMXD6, wherein the weight ratio of PA6I, PA610, or PA612 to PAMXD6 is 1:(3-5).

[0042] Preferably, the nylon resin includes a mixture of PA6I, PA610, or PA612 and PAMXD6, wherein the weight ratio of PA6I, PA610, or PA612 to PAMXD6 is 1:4.

[0043] Specifically, PA6I, PA610, or PA612 and PAMXD6 are compounded in a weight ratio of 1:4, which synergistically acts with polyamide 66 to effectively reduce the water absorption of the material and ensure the strength retention rate of the material during use.

[0044] Further, the glass fiber is hydrolysis-resistant alkali-free short-cut glass fiber, with a short-cut length of 3-4.5 mm, a fiber diameter of 9-11 μm, and a special silane-type impregnant coated on the surface.

[0045] Further, the antioxidant includes one or more than one of 1098, 168, H10 and H318.

[0046] Preferably, the antioxidant includes 1098, H10 or H318, and a compound of 168.

[0047] Further preferably, the weight ratio of 1098, H10 or H318 and 168 is 2:1.

[0048] Specifically, the antioxidant 1098 is a hindered phenolic antioxidant, and the phenolic hydroxyl group in the molecular structure thereof can provide hydrogen atoms to react with active free radicals generated by the high polymer material under the action of heat, light or mechanical stress, to generate stable free radical intermediates, thereby blocking the free radical chain reaction.

[0049] The antioxidant 168 is a phosphite antioxidant, and the phosphite group thereof can react with hydroperoxide generated in the oxidation process of the high polymer material, to reduce the hydroperoxide into stable alcohol, while being oxidized into phosphate itself, thereby preventing the generation of free radicals.

[0050] The antioxidant H10 is a hindered phenolic antioxidant, and the phenolic hydroxyl group in the molecular structure thereof can provide hydrogen atoms to react with free radicals generated by the high polymer material under the action of heat, oxygen or ultraviolet light, to generate stable phenoxyl radicals, thereby terminating chain growth, in addition, the phenoxyl radicals cannot continue to participate in chain reaction due to the steric hindrance effect and conjugate stabilization of the tert-butyl group, thereby effectively blocking the oxidation process, and H10 can provide multiple active sites, and has better antioxidant effect, and due to the larger molecular weight, it has long-term aging resistance, weather resistance, long-term stability and high temperature resistance.

[0051] The antioxidant H318 is a high steric hindrance phenolic antioxidant, and the phenolic hydroxyl group in the molecular structure thereof can provide hydrogen atoms to react with free radicals generated by the high polymer material under the action of heat, oxygen or ultraviolet light, to generate stable phenoxyl radicals, thereby terminating chain growth, in addition, the generated phenoxyl radicals cannot continue to participate in chain reaction due to the protection of the large steric hindrance group (tert-butyl), but are stabilized by resonance structure to prevent further oxidation, and H318 can provide multiple active sites, and has better antioxidant efficiency, and forms high steric hindrance through the structure connected by the benzene ring center, thereby having persistent antioxidant and high temperature resistance.

[0052] In summary, the hindered phenolic antioxidant interrupts the oxidation chain reaction by capturing free radicals, preventing the breakage and crosslinking of polymer chains, thereby maintaining the molecular weight and structural integrity of the nylon. The phosphite antioxidant prevents the initiation of new free radical chain reactions by decomposing hydroperoxides. The combination of antioxidant 1098, H10 or H318 and antioxidant 168 can simultaneously exhibit both free radical scavenging and hydroperoxide decomposition effects. The free radicals are captured to prevent their participation in the oxidation cycle, and the still active hydroperoxides generated during this process are decomposed to prevent automatic oxidation. At the same time, the generation of free radicals is inhibited and delayed, significantly improving the antioxidant effect and making it more suitable for the processing needs of high-precision bearing parts.

[0053] Further, the lubricant is at least one of modified ethylene bis fatty acid amide, silicone master batch, and zinc stearate.

[0054] Further, the compatibilizer is at least one of maleic anhydride grafted PE, maleic anhydride grafted POE, and maleic anhydride grafted SEBS.

[0055] Further, the wear-resistant aid is at least one of polytetrafluoroethylene, ultra-high molecular weight polyethylene, and molybdenum disulfide.

[0056] Further, the weather-resistant aid includes one or more than one combination of benzotriazole ultraviolet stabilizer and hindered amine light stabilizer.

[0057] Preferably, the weather-resistant aid includes a combination of benzotriazole ultraviolet stabilizer and hindered amine light stabilizer.

[0058] Further preferably, the weight ratio of benzotriazole ultraviolet stabilizer to hindered amine light stabilizer is 1:1.

[0059] Specifically, the benzotriazole ultraviolet stabilizer includes anti-UV agent 234, abbreviated as UV-234, which is a high molecular weight benzotriazole light absorber that can absorb ultraviolet light. The unabsorbed ultraviolet light waveband will continue to damage the high polymer to form free radicals and continuously damage the high polymer. The hindered amine light stabilizer includes UV agent 944, abbreviated as UV-944, which is a hindered phenolic ultraviolet stabilizer that can inactivate active free radicals to meet long-term weathering requirements.

[0060] In summary, the benzotriazole ultraviolet stabilizer reduces the damage of ultraviolet to the polymer by absorbing ultraviolet radiation and converting it into heat energy; the hindered amine light stabilizer interrupts the degradation chain reaction of the polymer by capturing free radicals generated by light. The use of the above two weathering aids in combination can produce a synergistic effect through the dual protection mechanism of absorbing ultraviolet and capturing free radicals, greatly improving the use effect, while having excellent absorption efficiency in the wavelength range of 200-400 nm, expanding the ultraviolet protection range, significantly improving the weather resistance of the nylon material in outdoor environment, and prolonging its service life.

[0061] Meanwhile, the weathering aid compound used in the present application will not be affected by the antioxidant compound, ensuring the compatibility of the compound while achieving the synergistic effect of antioxidants and weathering aids. Specifically, the addition of antioxidants prevents degradation of the material during processing and slows down aging decay during use; the use of weathering aids protects the color change of the product under outdoor light and prevents performance decay, both of which have compatibility, ensuring the stability of the product during use through synergistic effect, so that the antioxidant-related properties and weather-related properties of the nylon material are significantly improved.

[0062] Further, the black masterbatch includes a carrier-free inorganic color masterbatch.

[0063] A preparation method of a high-performance nylon material, comprising the following steps:

[0064] S1, polyamide 66, special nylon resin, antioxidant, lubricant, compatibilizer, wear-resistant aid, weathering aid and black masterbatch are weighed according to the weight percentage, mixed uniformly in a mixer, and a mixture is obtained;

[0065] S2, the mixture prepared above is added to the main feeding port of the double screw extruder, glass fibers are added to the side feeding machine bin of the double screw extruder, and after melt blending, extrusion, drawing, traction and granulation, the high-performance nylon material is obtained.

[0066] Preferably, in step S1, the uniform mixing is dry mixing for 5-10 min in a low-cost mixer.

[0067] Preferably, in step S2, the double screw extruder is set to an extrusion temperature of 260-280℃ and a screw rotation speed of 300r / min.

[0068] The present application has the following advantages:

[0069] The application effectively reduces the water absorption of the nylon material through reasonable compounding, ensures the material flowability and easy processing, improves the performance retention rate in use, inhibits and delays the generation of free radicals through reasonable compounding of antioxidants, significantly improves the antioxidant effect, and greatly improves the persistent antioxidant, aging resistance, long-acting stability, high-temperature resistance and other properties of the material; the weather resistance of the nylon material in outdoor environment is significantly improved through reasonable compounding of weather resistance additives, the service life is prolonged, through the synergistic effect of the above components, a high-performance nylon material with high stability for outdoor precision bearings is obtained, and the material has low friction coefficient, low wear, high strength and modulus, long-period weather resistance and long-period high-temperature and high-humidity resistance and other excellent properties.

[0070] It should be understood that all combinations of the aforementioned concepts and additional concepts described in greater detail below can be seen as part of the subject matter of the present disclosure provided such concepts are not mutually inconsistent. DETAILED DESCRIPTION

[0071] In order to make the objectives, technical solutions and advantages of the embodiments of the present application clearer, the technical solutions of the embodiments of the present application will be described clearly and completely below with reference to the embodiments of the present application. Obviously, the described embodiments are part of the embodiments of the present application, rather than all the embodiments. Based on the described embodiments of the present application, all other embodiments obtained by those skilled in the art without any inventive effort belong to the scope of protection of the present application. Unless otherwise defined, the technical terms or scientific terms used herein should be understood as the usual meanings understood by those skilled in the art.

[0072] The terms such as "include" or "contain" and the like used in the patent application specification and claims of the present application mean that the elements or objects appearing before "include" or "contain" cover the features, integers, steps, operations, elements and / or components listed after "include" or "contain", and do not exclude the presence or addition of one or more other features, integers, steps, operations, elements, components and / or sets thereof.

[0073] The term "polymer" as used herein refers to a polymeric compound prepared by polymerizing monomers of the same or different type. The generic term "polymer" includes the terms "homopolymer", "copolymer", "terpolymer", and "interpolymer". An "interpolymer" is a polymer prepared from the polymerization of at least two different monomers. The generic term "interpolymer" includes the term "copolymer" (which generally is used to refer to polymers made from two different monomers) and the term "terpolymer" (which generally is used to refer to polymers made from three different monomers). It also includes polymers made from the polymerization of four or more monomers. "Blends" means a physical mixture of two or more polymers formed by physical or chemical means.

[0074] The sources of the main raw materials used in the following examples and comparative examples of the present application are as follows:

[0075] Polyamide 66 was purchased from Shenma Company;

[0076] PA6I was purchased from Changzhou Suotian;

[0077] PA610 was purchased from Shandong Dongchen Ruison;

[0078] PA612 was purchased from Shandong Dongchen Ruison;

[0079] PAMXD6 was purchased from Mitsubishi, Japan;

[0080] Glass fiber was purchased from Taishan Fiberglass, model T435TM;

[0081] Antioxidant 1098, Chinese name: N,N'-bis-(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionyl)hexanediamine, CAS registry number: 23128-74-7, brand: BASF;

[0082] Antioxidant 168, Chinese name: Tris[2,4-di-tert-butylphenyl] phosphite, CAS registry number: 31570-04-4, brand: BASF;

[0083] Antioxidant H10, Chinese name: Tetra[β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionic acid] pentaerythritol ester, CAS registry number: 6683-19-8, brand: Bruggemann;

[0084] Antioxidant H318, Chinese name: 1,3,5-trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxybenzyl)benzene, CAS registry number: 1709-70-2, brand: Bruggemann;

[0085] Lubricant modified ethylene bis fatty acid amide was made by Suzhou Xingtai Guoguang Chemical Auxiliary Co., Ltd., and the brand was TAF;

[0086] Compatibilizer maleic anhydride grafted POE, purchased from Dow Chemical Company, with the trade name of FUSABOND N216;

[0087] Wear-resistant aid polytetrafluoroethylene, purchased from Mule Time International Trade (Shanghai) Co., Ltd., with the trade name of TP300;

[0088] Weathering aid UV-234, purchased from BASF, with the trade name of UV234;

[0089] Weathering aid UV-944, purchased from BASF, with the trade name of UV944;

[0090] Black masterbatch, purchased from Gaozhan, with the trade name of 3300.

[0091] Examples 1-7

[0092] According to the proportions in Table 1, each component was weighed, and a high-performance nylon material prepared according to the following preparation method was obtained:

[0093] S1, polyamide 66, special nylon resin, antioxidant, lubricant, compatibilizer, wear-resistant aid, weathering aid, and black masterbatch were weighed according to the weight percentage in Table 1, and dry mixed in a low-speed mixer for 5-10 min to obtain a mixture;

[0094] S2, the mixture prepared above was added to the main feeding port of the twin-screw extruder, and the glass fiber was added to the side-feeding machine bin of the twin-screw extruder. The extrusion temperature was set to 260-280℃, and the screw rotation speed was 300r / min. After melt blending, extrusion, drawing, traction, and granulation, a high-performance nylon material was obtained.

[0095] Table 1. Proportions of each component in Examples 1-7 by weight

[0096]

[0097] Example 8

[0098] A high-performance nylon material, different from Example 7, in that the weight proportions of antioxidant 1098 and antioxidant 168 were 0.1 and 0.1.

[0099] Example 9

[0100] A high-performance nylon material, different from Example 7, in that the weight proportions of antioxidant 1098 and antioxidant 168 were 0.2 and 0.2.

[0101] Example 10

[0102] A high-performance nylon material, different from Example 7, in that antioxidant 1098 was replaced by antioxidant H10.

[0103] Example 11

[0104] A high performance nylon material, which is different from Example 7 in that antioxidant 1098 is replaced by antioxidant H318.

[0105] Example 12

[0106] A high performance nylon material, which is different from Example 7 in that the weight ratio of weathering aid UV-234 and weathering aid UV-944 is 0.6 and 0.

[0107] Comparative Example 1

[0108] A high performance nylon material, which is different from Example 1 in that the weight ratio of polyamide 66 and special nylon material is 62 and 0.

[0109] Performance detection test

[0110] In order to better verify the performance of the nylon materials obtained by the above examples and comparative examples, the nylon materials prepared by the above comparative examples and examples were subjected to performance detection according to the corresponding detection standards. The detection samples were prepared by injection molding on Haitian injection molding machine (model SA16002 / 540) at a processing temperature of 260-280°C and a mold temperature of 90°C. The detection results are shown in Tables 2 and 3.

[0111] Table 2. Performance detection results of comparative examples and examples 1-7

[0112]

[0113]

[0114] As can be seen from the results in Table 2, the special nylon prepared by compounding PA 6I, PA 610 or PA 612 and PA MXD6 and the polyamide 66 can effectively reduce the water absorption rate of the material and ensure the performance retention rate of the material during use.

[0115] From the above examples and corresponding detection results, it can be seen that the addition of PA 6I, PA 610 or PA 612 and PA MXD6 compound (comparative examples and examples 1-7) in the polyamide 66 system greatly improves the performance retention rate of the material under high temperature and high humidity conditions. The preferred weight ratio of PA 6I, PA 610 or PA 612 and PA MXD6 is 1:4.

[0116] Table 3. Performance detection results of examples 8-12

[0117]

[0118]

[0119] As shown in Table 3, the antioxidant 1098, H10 or H318 and the antioxidant 168 can be used in combination to effectively improve the antioxidant properties of the nylon material and the long-term oxidation resistance, aging resistance, high temperature resistance and other properties.

[0120] As shown in the above examples and corresponding test results, the combination ratio of the antioxidant 1098, H10 or H318 as the main antioxidant and the antioxidant 168 as the auxiliary antioxidant (Examples 6-9) can affect the antioxidant properties of the nylon material, and the preferred ratio is 2:1.

[0121] As shown in Table 3, the weathering aid UV234- and UV-944 can be used in combination to effectively improve the weathering properties and long-term stability of the nylon material.

[0122] As shown in the above examples and corresponding test results, the combination of the weathering aid UV234- and UV-944 can achieve better weathering properties than the use of one of the weathering aids alone (Examples 6-7 and Example 12), and the preferred ratio is 1:1.

[0123] In view of the test results and various factors such as cost, Examples 6-7 are a relatively superior technical solution, and thus the preferred preparation method of the present application can be obtained.

[0124] The comprehensive data shows that the technical solution achieves the expected effect, i.e., has low friction coefficient, low wear, high strength and modulus, long-term weathering and long-term high temperature and humidity resistance, and other excellent properties.

[0125] Although the present application has been disclosed with the preferred embodiments as above, it is not intended to limit the present application. Those skilled in the art can make various modifications and improvements without departing from the spirit and scope of the present application. Therefore, the protection scope of the present application shall be subject to the claims.

[0126] In addition, it should be understood that although the present application is described in terms of embodiments, each embodiment does not contain only one independent technical solution, and the description of the specification is only for clarity. Those skilled in the art should consider the specification as a whole, and the technical solutions in each embodiment can be properly combined to form other embodiments that those skilled in the art can understand. The technical details not described in detail in the present application can be realized by any existing technology in the art. In particular, all technical features not described in detail in the present application can be realized by any existing technology.

Claims

1. A high performance nylon material characterized in that, The high-performance nylon material comprises the following components by weight: Polyamide 66: 30-65 parts; Special nylon resin: 5-25 parts; Glass fiber: 30-35 parts; Antioxidant: 0.2-0.4 parts; Lubricant: 0.4-0.8 parts; Compatibilizer: 1-3 parts; Wear-resistant aid: 5-15 parts; Weather-resistant aid: 0.6-1.0 parts; Black masterbatch: 0.3-0.7 parts.

2. The high performance nylon material of claim 1, wherein, The high-performance nylon material comprises the following components by weight: Polyamide 66: 35-45 parts; Special nylon resin: 20-25 parts; Glass fiber: 30-35 parts; Antioxidant: 0.3-0.4 parts; Lubricant: 0.5-0.8 parts; Compatibilizer: 2-3 parts; Wear-resistant aid: 10-15 parts; Weather-resistant aid: 0.8-1.0 parts; Black masterbatch: 0.5-0.7 parts.

3. The high performance nylon material according to any one of claims 1-2, characterized in that, The special nylon resin is one or a mixture of more than one of PA 6I, PA 610, PA 612, and PA MXD6.

4. The high performance nylon material of claim 3, wherein, The special nylon resin comprises a mixture of PA 6I, PA 610, or PA 612 and PA MXD6, wherein the weight ratio of PA 6I, PA 610, or PA 612 to PA MXD6 is 1:

4.

5. The high performance nylon material according to any one of claims 1-2, wherein, The glass fiber is hydrolysis-resistant alkali-free short-cut glass fiber, the short-cut length is 3-4.5 mm, the fiber diameter is 9-11 μm, and the surface is coated with a special silane type impregnant.

6. The high performance nylon material according to any one of claims 1-2, wherein, The antioxidant comprises one or a mixture of more than one of 1098, 168, H10, and H318.

7. The high performance nylon material of claim 6, wherein, The antioxidant comprises a mixture of 1098, H10, or H318 and 168, and the weight ratio of 1098, H10, or H318 to 168 is 2:

1.

8. The high performance nylon material according to any one of claims 1-2, wherein, The lubricant is at least one of modified ethylene bis fatty acid amide, silicone masterbatch, and zinc stearate; the compatibilizer is at least one of maleic anhydride grafted PE, maleic anhydride grafted POE, and maleic anhydride grafted SEBS; and the wear-resistant aid is at least one of PTFE, ultra-high molecular weight polyethylene, and molybdenum disulfide.

9. The high performance nylon material according to any one of claims 1-2, wherein, The weather-resistant aid comprises one or a mixture of more than one of benzotriazole ultraviolet stabilizer and hindered amine light stabilizer.

10. A method of preparing a high performance nylon material as claimed in any one of claims 1 to 9, characterised in that, The method comprises the following steps: S1, polyamide 66, special nylon resin, antioxidant, lubricant, compatibilizer, wear-resistant aid, weather-resistant aid, and black masterbatch are weighed according to the weight percentage, mixed uniformly in a mixer, and a mixture is obtained; S2, the mixture obtained above is added to the main feeding port of a double-screw extruder, glass fiber is added to the side feeding machine bin of the double-screw extruder, and after melt blending, extrusion, drawing, traction, and granulation, the high-performance nylon material is obtained.

Citation Information

Patent Citations

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  • Glass fiber-reinforced polyamide 66 and semi-aromatic nylon composite material for vehicular structural member and preparation method

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  • High-strength wear-resistant nylon composite material and preparation method thereof

    CN111087806A

  • High-glass-fiber-content weather-resistant black nylon material

    CN113563715A

  • Nylon plastic for gun rod of high-pressure cleaning machine and preparation method of nylon plastic

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