Hair heat protection hair conditioner containing bartana oil and preparation method of hair heat protection hair conditioner

Abstract

The invention relates to the field of daily chemical products, and particularly discloses a bartana oil hair heat protection hair conditioner and a preparation method thereof, the bartana oil hair heat protection hair conditioner comprises the following components: a group A: water, cetrimonium chloride and hydroxyethyl cellulose; the group B is prepared from the following raw materials: PEG-50 shea butter, a papain oil nutrient solution, a siloxane emulsion, glyceryl stearate, PEG-20 stearate, p-hydroxyacetophenone, PEG-50 stearate, polydimethylsiloxane alcohol and PEG-100 stearate; group C: essence and phenoxyethanol; group D: panthenol, hydrolyzed keratin, vitamin complex, tridecanol polyether-12, ethylhexylglycerin, citric acid and natural carotene; the added siloxane emulsion and the bartana oil nutrient solution form a double-membrane structure, the double-membrane structure can penetrate into hair cuticle gaps to fill up damaged areas, a hydrophilic-hydrophobic composite membrane is constructed on the surface of hair, the heat conduction efficiency is reduced, the heat insulation threshold value of the hair conditioner is increased, and the prepared hair conditioner has the three-effect-in-one deep repairing and nourishing effects of heat insulation, repairing and scalp protection.

Description

TECHNICAL FIELD

[0001] The present application relates to the field of daily chemical products, in particular to a hair heat protection conditioner containing batana oil and a preparation method thereof. BACKGROUND

[0002] The hair heat protection conditioner is a hair care product specially designed to reduce the damage of high temperature to hair. High-temperature hair styling tools, such as hair dryers, straighteners or curling irons, can easily cause hair to become dry, brittle and lose luster, etc. The hair heat protection conditioner can effectively reduce hair damage by forming a heat shield, supplementing hair moisture and toughening hair, etc.

[0003] However, the current hair heat protection conditioner has limited high-temperature resistance, and is easily damaged at high temperature. The protective film formed is easily decomposed by heat and produces an odor. Many hair conditioners need to be washed after being applied. The heat insulation film has low adhesion and is easily peeled off due to friction and water dissolution, and has no protective care effect. Many hair conditioners do not have real efficacy and only have a heat insulation effect. They cannot repair the hair deeply or only have a short-term smooth appearance. The heat insulation film of most products has "insufficient toughness" and is easily cracked by the tension of the hair under high temperature. It cannot completely lock in moisture and will still be frizzy after heat styling. In order to enhance the heat insulation effect, most products add high-concentration silicon (such as polydimethylsiloxane). This type of ingredient can form a film, but has poor water solubility and is easily accumulated on the surface of the hair after long-term use. SUMMARY

[0004] The technical problem to be solved by the present application is to provide a hair heat protection conditioner containing batana oil and a preparation method thereof to solve the problems in the prior art.

[0005] To solve the above technical problems, the present application provides a hair heat protection conditioner containing batana oil, which comprises the following components by mass:

[0006] Group A: water 75-80 parts, cetrimonium chloride 0.5-1 part, hydroxyethyl cellulose 0.5-1.5 parts;

[0007] Group B: PEG-50 shea butter 0.1-2 parts, batana oil nutrient solution 3-8 parts, silicone emulsion 2-11 parts, glyceryl stearate 0.5-2 parts, PEG-20 stearate 0.3-1 part, p-hydroxyacetophenone 0.3-0.8 parts, PEG-50 stearate 0.3-1 part, dimethicone alcohol 0.1-0.5 parts, PEG-100 stearate 0.1-0.4 parts;

[0008] The silicone emulsion is obtained by mixing polydimethylsiloxane, amine-terminated polydimethylsiloxane and cyclopentasiloxane in a mass ratio of 1-4:0.5-3:0.5-4, mixing the mixture with a glycoside solution and a quaternary ammonium salt aqueous solution in a volume ratio of 11-14:1-5:1-5, and pre-stirring at 30-35 DEG C and 1000-1500 rpm for 8-10 min; forming a composite silicone system with lubricity, film-forming property and permeability, and after grafting with the glycoside solution and the quaternary ammonium salt aqueous solution, the composite silicone system has hydrophilicity and lipophilicity, strengthens hair, improves smoothness and durability, improves self-dispersing property and improves the combing property of hair;

[0009] The glycoside solution is a xylitol-based glycoside solution with a concentration of 30-40%; the glycoside solution promotes the crosslinking of linear siloxane and cyclic siloxane to form a stable protective film by introducing a linear polyhydroxy ether chain, improves the thermal stability of the silicone emulsion, and promotes the repair effect of the amine-terminated silicone;

[0010] The quaternary ammonium salt aqueous solution contains one of double-chain quaternary ammonium salt and cetyltrimethylammonium chloride, and has a concentration of 3-4%; the quaternary ammonium salt aqueous solution can reduce the spreading property of the silicone and reduce the accumulation of the silicone emulsion;

[0011] The Batana oil nutrient solution is obtained by mixing Batana oil and modified cetylstearyl alcohol in a ratio of 1-5:2-8, adding lactate, and treating 2-3 times at a pressure of 30-50 MPa and a temperature of 40-50 DEG C to form a nanoscale inclusion system with a particle size of 50-100 nm;

[0012] Batana oil is rich in antioxidant components and natural oils, can penetrate into hair fibers, repair damaged scales, has a similar molecular structure to sebum, can quickly penetrate hair, supplement nutrients and lock in moisture, make hair smooth and shiny, regulate sebum secretion, balance water and oil, reduce the problem of flatness caused by excessive oiliness, and protect the scalp barrier and reduce external irritation;

[0013] The preparation method of the modified cetyl stearyl alcohol is that: under the mixed atmosphere of nitrogen and supercritical CO2 with a volume ratio of 3:1, cetyl stearyl alcohol is added with 4-6 wt% of hydroxylated palmitic acid (pretreated with 0-0.3 wt% of tetrabutyl titanate) into a rotary high-pressure reaction kettle, dynamic mixing is carried out at 4-6 MPa and 70-80 DEG C for 10-20 min, and then molecular distillation is carried out to form a hydrogen bond network by grafting long-chain fatty acids, which has carboxyl groups and can form reversible coordination bonds with cysteine residues of hair keratin to build a "thermal protection film" on the hair surface; when high temperature is encountered, the ester bond structure can absorb heat energy through molecular conformation adjustment, while the flexible chain segment can keep the film structure integrity, reducing the water loss of the hair; the unsaturated fatty acids of butana oil can be embedded in the intermolecular gap to improve the water solubility and thermal stability and improve the hair care activity;

[0014] The addition amount of the lactate is 3-6% of the mass of the butana oil; the lactate can make the edges of the hair scales curl up through the "swelling effect" to expand the penetration channel;

[0015] Group C: essence 0.5-1.5 parts, phenoxyethanol 0.3-1 part;

[0016] Group D: panthenol 0.1-0.4 parts, hydrolyzed keratin 0.1-0.3 parts, vitamin complex 0.1-0.4 parts, tridecyl alcohol polyether-120 0.05-0.3 parts, ethylhexylglycerin 0.03-0.15 parts, citric acid 0.03-0.1 part, natural carotene 0.03-0.1 part;

[0017] The vitamin complex is composed of tocopherol, biotin and vitamin D in a mass ratio of 0.1-0.3:0.03-0.1:0.03-0.1; the molecular structure of vitamin D can form weak hydrogen bonds with biotin and vitamin D to improve the stability of the vitamins, and meanwhile, the vitamins can be compounded to realize deep repair of the hair;

[0018] The application also provides a preparation method of the butana oil hair thermal protection hair conditioner, which comprises the following steps:

[0019] Step 1: A phase is added into a main pot, heated to 85-90 DEG C, and homogenized and stirred to completely dissolve the raw materials;

[0020] Step 2: B phase is added into an oil pot, heated to 85-90 DEG C, and stirred to completely dissolve the raw materials;

[0021] Step 3: the raw materials of B phase are added into the main pot, and homogenized and stirred to fully disperse and uniformly distribute the raw materials; and the temperature is started to be reduced to 50-55 DEG C;

[0022] The homogenized stirring is carried out at 60-80 DEG C for 5-10 s;

[0023] Step 4: C-phase raw materials are added into the main pot, and stirring is performed until the raw materials are evenly dispersed;

[0024] Step 5: D-phase raw materials are added into the main pot, and stirring is performed until the raw materials are evenly dispersed, and then the temperature is continuously reduced to 40-45 DEG C. After sampling and testing, the product is discharged.

[0025] The hair heat protection hair conditioner provided by the present application has the functions of heat insulation, repair and scalp protection, and the hydrophobic carbon chain of the modified sperm whale tallow alcohol in the added batana oil nutrient solution wraps the batana oil in the cavity, the external hydroxyl (-OH) and the carboxyl (-COO-) of sodium lactate form a hydrogen bond to make the inclusion compound easily soluble in water, reduce the steric hindrance of the long-chain fatty acid of the batana oil, improve the penetration and absorption efficiency, the batana oil can adjust the viscosity of the modified sperm whale tallow alcohol, and improve the oxidation resistance and film stability, the batana oil nutrient solution can load and dissolve oil-soluble substances such as vitamins, and form a hydrogen bond with hydrolyzed keratin through the hydroxyl group, play a loading and fixing role, improve the activity of vitamin E and hydrolyzed keratin, and the antioxidant components such as vitamin E can resist the oxidative damage of free radicals to the hair, delay the aging of the hair, and maintain the strong and tough state of the hair; the added silicone emulsion and the batana oil nutrient solution form a “double film structure”, can fill the damaged area in the hair scale gap, construct a hydrophilic-hydrophobic composite film on the hair surface, further reduce the heat conduction efficiency and improve the heat insulation threshold of the hair conditioner;

[0026] The present application provides a preparation method of the hair heat protection hair conditioner of the batana oil, which can ensure the stability of the basic ingredients by phase separation and dissolution, further strengthen the core hair care ingredients such as the silicone emulsion and the batana oil nutrient solution in the B-phase by mixing the A-phase and the B-phase, improve the penetration and protection, and finally maximize the retention of active ingredients and improve the hair care performance by gradient cooling and stepwise feeding. DETAILED DESCRIPTION

[0027] The present application will be further described in detail through specific implementation examples, and it should be understood that these examples are only used to illustrate the present application and are not used to limit the protection scope of the present application. After reading the present application, those skilled in the art can make various equivalent modifications of the present application, which fall within the scope of the appended claims.

[0028] Unless otherwise specified, all raw materials and reagents of the present application are conventional market raw materials and reagents.

[0029] Example 1

[0030] A preparation method of a hair heat protection hair conditioner of batana oil

[0031] Step 1: add water 78 parts, cetrimonium chloride 0.8 parts, hydroxyethyl cellulose 1 part into the main pot, heat to 88℃, stir and homogenize to make each raw material completely dissolved;

[0032] Step 2: add PEG-50 shea butter 0.15 parts, batana oil nutrient solution 5 parts, silicone emulsion 7 parts, glyceryl stearate 1.2 parts, PEG-20 stearate 0.6 parts, p-hydroxyacetophenone 0.6 parts, PEG-50 stearate 0.6 parts, dimethicone alcohol 0.3 parts, PEG-100 stearate 0.3 parts into the oil pot, heat to 88℃, stir to make each raw material completely dissolved;

[0033] Step 3: add the raw materials in the oil pot into the main pot, homogenize for 8s at 70℃ to make each fully dispersed and uniform, start cooling to 55℃;

[0034] The silicone emulsion is a mixed solution obtained by mixing polydimethylsiloxane, amino-terminated polydimethylsiloxane and cyclopentadimethylsiloxane in a mass ratio of 3:1.8:2.5, mixing the mixed solution with a 35% concentration xylosyl glucoside solution and a 3-4% concentration cetyltrimethylammonium chloride aqueous solution in a volume ratio of 12:3:3, and pre-stirring at 30℃ and 1000rpm for 9min;

[0035] The batana oil nutrient solution is a nanoscale inclusion compound system with a particle size of 80nm formed by mixing batana oil and modified cetylstearyl alcohol at a ratio of 3:5, adding 4% of the lactate of the mass of the batana oil, and treating it 3 times at a pressure of 40MPa and a temperature of 45℃;

[0036] The preparation method of the modified cetylstearyl alcohol is as follows: in a nitrogen-super critical CO2 mixed atmosphere with a volume ratio of 3:1, 5wt% of hydroxylated palmitic acid (pretreated with 0.2wt% tetrabutyl titanate) is added to a rotary high-pressure reaction kettle, dynamic mixing is carried out at 5MPa and 75℃ for 15min, and then molecular distillation is carried out to obtain the modified cetylstearyl alcohol;

[0037] Step 4: add essence 1 part, phenoxyethanol 0.6 part into the main pot, stir until the raw materials are fully dispersed and uniform;

[0038] Step 5: add panthenol 0.3 parts, hydrolyzed keratin 0.2 parts, vitamin complex 0.2 parts, tridecyl alcohol polyether-120 0.2 parts, ethylhexylglycerin 0.08 parts, citric acid 0.06 parts, natural carrot pigment 0.06 parts into the main pot, the vitamin complex is a mixture of tocopherol, biotin and vitamin D in a mass ratio of 0.2:0.06:0.06, stir until the raw materials are fully dispersed and uniform, continue to cool to 40℃, take sample for detection, and discharge after the sample is qualified.

[0039] Example 2

[0040] A method for preparing a hair thermal protection conditioner of batana oil

[0041] Step 1: add water 75 parts, cetrimonium chloride 0.5 parts, hydroxyethyl cellulose 0.5 parts into the main pot, heat to 85°C, stir and homogenize to completely dissolve the raw materials;

[0042] Step 2: add PEG-50 shea butter 0.1 parts, batana oil nutrient solution 3 parts, silicone emulsion 2 parts, glycerol stearate 0.5 parts, PEG-20 stearate 0.3 parts, p-hydroxyacetophenone 0.3 parts, PEG-50 stearate 0.3 parts, dimethiconol 0.1 parts, PEG-100 stearate 0.1 parts into the oil pot, heat to 85°C, stir to completely dissolve the raw materials;

[0043] Step 3: add the raw materials in the oil pot into the main pot, homogenize for 5s at 60°C to fully disperse and evenly distribute the materials, and start cooling to 50°C;

[0044] The silicone emulsion is obtained by mixing polydimethylsiloxane, amino-terminated polydimethylsiloxane and cyclopentasiloxane in a mass ratio of 1:0.5:0.5, then mixing the mixture with a 30% xylosyl glucoside solution and a 3% dipentaerythritol dimethyl ammonium chloride aqueous solution in a volume ratio of 11:1:1, and pre-stirring at 30°C and 1000 rpm for 8 min;

[0045] The batana oil nutrient solution is obtained by mixing batana oil and modified cetylstearyl alcohol at a ratio of 1:2, adding 3% lactate of the mass of batana oil, and treating twice at a pressure of 30 MPa and a temperature of 40-50°C to form a nanoscale inclusion system with a particle size of 50 nm;

[0046] The preparation method of the modified cetylstearyl alcohol is as follows: in a nitrogen-super critical CO2 mixed atmosphere with a volume ratio of 3:1, 4wt% hydroxylated palmitic acid (pretreated with 0.1wt% tetrabutyl titanate) is added to a rotary high-pressure reaction kettle, and dynamic mixing is carried out at 4 MPa and 70°C for 10 min, followed by molecular distillation to obtain;

[0047] Step 4: add fragrance 0.5 parts, phenoxyethanol 0.3 parts into the main pot, stir to fully disperse and evenly distribute the materials;

[0048] Step 5: Put panthenol 0.1 part, hydrolyzed keratin 0.1 part, vitamin compound 0.1 part, tridecyl alcohol polyether-12 0.05 part, ethylhexylglycerin 0.03 part, citric acid 0.03 part, natural carrot pigment 0.03 part into the main pot, the vitamin compound is a mixture of tocopherol, biotin and vitamin D in a mass ratio of 0.1:0.03:0.03, stir until the raw materials are evenly dispersed, continue to cool to 40℃, take sample for testing, and discharge after the sample is qualified.

[0049] Example 3

[0050] A preparation method of a hair heat protection conditioner containing batana oil

[0051] Step 1: Put water 80 parts, cetrimonium chloride 1 part, hydroxyethyl cellulose 1.5 parts into the main pot, heat to 90℃, stir and homogenize to completely dissolve the raw materials;

[0052] Step 2: Put PEG-50 shea butter 2 parts, batana oil nutrient solution 8 parts, silicone emulsion 11 parts, glyceryl stearate 2 parts, PEG-20 stearate 1 part, p-hydroxyacetophenone 0.8 parts, PEG-50 stearate 1 part, dimethiconol 0.5 parts, PEG-100 stearate 0.4 parts into the oil pot, heat to 90℃, and stir to completely dissolve the raw materials;

[0053] Step 3: Add the raw materials in the oil pot into the main pot, homogenize for 10s at 80℃ to fully disperse the raw materials, and start cooling to 55℃;

[0054] The silicone emulsion is obtained by mixing polydimethylsiloxane, amino-terminated polydimethylsiloxane and cyclopentasiloxane in a mass ratio of 4:3:4, mixing the mixture with a 40% xylitol glucoside solution and a 4% aqueous solution of bisoctadecyldimethylammonium chloride in a volume ratio of 14:5:5, and pre-stirring at 35℃ and 1500rpm for 10min;

[0055] The batana oil nutrient solution is obtained by mixing batana oil and modified cetylstearyl alcohol in a ratio of 5:8, adding 6% of a lactate salt of the mass of the batana oil, and treating it 3 times at a pressure of 50MPa and a temperature of 50℃ to form a nanoscale inclusion system with a particle size of 100nm;

[0056] The preparation method of the modified cetylstearyl alcohol is as follows: in a nitrogen-super critical CO2 mixed atmosphere with a volume ratio of 3:1, 6wt% of hydroxylated palmitic acid (pretreated with 0.3wt% tetrabutyl titanate) is added to a rotary high-pressure reaction kettle, dynamic mixing is carried out at 6MPa and 80℃ for 20min, and then molecular distillation is carried out to obtain the modified cetylstearyl alcohol;

[0057] Step 4: Add essence 1.5 parts, phenoxyethanol 1 part into the main pot, and stir until the raw materials are evenly dispersed;

[0058] Step 5: Add panthenol 0.4 parts, hydrolyzed keratin 0.3 parts, vitamin complex 0.4 parts, tridecyl alcohol polyether-120 0.3 parts, ethylhexylglycerin 0.15 parts, citric acid 0.1 part, natural carrot pigment 0.1 part into the main pot, the vitamin complex is a mixture of tocopherol, biotin and vitamin D in a mass ratio of 0.3:0.1:0.1, stir until the raw materials are evenly dispersed, continue to cool to 45℃, and take sample for detection after the qualified discharge.

[0059] Example 4

[0060] A method for preparing a hair heat protection conditioner containing batana oil

[0061] Step 1: Add water 75 parts, cetrimonium chloride 1 part, hydroxyethyl cellulose 0.5 parts into the main pot, heat to 90℃, stir and homogenize to completely dissolve the raw materials;

[0062] Step 2: Add PEG-50 shea butter 0.1 part, batana oil nutrient solution 8 parts, silicone emulsion 3 parts, glyceryl stearate 0.6 parts, PEG-20 stearate 0.9 parts, p-hydroxyacetophenone 0.4 parts, PEG-50 stearate 0.6 parts, dimethiconol 0.2 parts, PEG-100 stearate 0.2 parts into the oil pot, heat to 85℃, and stir to completely dissolve the raw materials;

[0063] Step 3: Add the raw materials in the oil pot into the main pot, homogenize for 10s at 60℃ to evenly disperse the raw materials, and start cooling to 50℃;

[0064] The silicone emulsion is obtained by mixing polydimethylsiloxane, amino-terminated polydimethylsiloxane and cyclopentasiloxane in a mass ratio of 2:0.8:3, mixing the mixture with a 35% xylitol glucoside solution and a 4% cetyltrimethylammonium chloride aqueous solution in a volume ratio of 12:4:2, and pre-stirring at 30℃ and 1500rpm for 8min;

[0065] The batana oil nutrient solution is obtained by mixing batana oil and modified cetylstearyl alcohol in a ratio of 2:7, adding 4% lactate of the mass of batana oil, and treating twice at a pressure of 30MPa and a temperature of 50℃ to form a nanoscale inclusion system with a particle size of 100nm;

[0066] The preparation method of the modified cetyl stearyl alcohol is as follows: cetyl stearyl alcohol is added into a rotating high-pressure reaction kettle in a nitrogen-super critical CO2 mixed atmosphere with a volume ratio of 3:1, 4wt% of hydroxylated palmitic acid (pretreated by 0.3wt% tetrabutyl titanate) is placed in the rotating high-pressure reaction kettle, dynamic mixing is carried out at 4MPa and 80°C for 10min, and then molecular distillation is carried out to obtain;

[0067] Step 4: Add 1 part of essence and 0.4 part of phenoxyethanol into the main pot, and stir until the raw materials are evenly dispersed;

[0068] Step 5: Add 0.2 part of panthenol, 0.1 part of hydrolyzed keratin, 0.2 part of vitamin complex, 0.3 part of tridecyl alcohol polyether-120, 0.05 part of ethylhexylglycerin, 0.05 part of citric acid, and 0.03 part of natural carrot pigment into the main pot, wherein the vitamin complex is a mixture of tocopherol, biotin and vitamin D with a mass ratio of 0.3:0.03:0.1, and stir until the raw materials are evenly dispersed. Continue to cool to 40°C, and take a sample for detection. When the sample is qualified, discharge the product.

[0069] Comparative Example 1

[0070] The difference between Comparative Example 1 and Example 1 is that the cetyl stearyl alcohol in the patana oil nutrient solution of Comparative Example 1 is not modified, and the other conditions are the same.

[0071] Comparative Example 2

[0072] The difference between Comparative Example 2 and Example 1 is that no lactate is added in the patana oil nutrient solution of Comparative Example 2.

[0073] Comparative Example 3

[0074] The difference between Comparative Example 3 and Example 1 is that an equal amount of oil is used to replace patana oil in the patana oil nutrient solution of Comparative Example 3, and the other conditions are the same.

[0075] Comparative Example 4

[0076] The difference between Comparative Example 4 and Example 1 is that no glycoside solution is added in the silicone emulsion of Comparative Example 4, and the other conditions are the same.

[0077] Comparative Example 5

[0078] The difference between Comparative Example 5 and Example 1 is that no quaternary ammonium salt aqueous solution is added in the silicone emulsion of Comparative Example 5, and the other conditions are the same.

[0079] Comparative Example 6

[0080] The difference between Comparative Example 6 and Example 1 is that the preparation method of the hair conditioner of Comparative Example 6 is as follows: all the raw materials are added into the main pot, heated to 88°C, stirred and homogenized to completely dissolve the raw materials, and then cooled to obtain.

[0081] Comparative Example 7

[0082] Comparative Example 7 differs from Example 1 in that the vitamin complex of Comparative Example 7 does not add vitamin D, and the rest is unchanged.

[0083] I. The performance of the prepared hair heat protection conditioner was detected, and the detection results are shown in Table 1.

[0084] pH value: detected by a pH meter with a solid-liquid ratio of 1:10 g / mL dissolved in an aqueous solution;

[0085] Heat resistance: stored at 45±2℃ for 2 months, returned to room temperature, and observed for abnormalities;

[0086] Cold resistance: stored at -18±2℃ for 2 months, returned to room temperature, and observed for abnormalities;

[0087] Cycling test: cycling at temperatures of 45℃, room temperature, and -18℃, respectively;

[0088] Irritation, referring to the cosmetic safety standard (such as China GB / T 29665-2013 “Shampoo, Shampoo Cream”, using skin patch test;

[0089] Table 1 Hair heat protection conditioner

[0090]

[0091]

[0092] As shown in Table 1, the hair heat conditioner of the present application has stable storage performance in cold and hot environments, and no skin irritation.

[0093] II. The hair care performance of the hair heat protection conditioner prepared in the examples and comparative examples was detected, and the detection method was as follows;

[0094] Heat protection detection: take untreated hair (blank group) and hair coated with conditioner (experimental group), use a 200℃ straightener for continuous action for 3 times (10s each time); observe the integrity of the hair scales of the two groups (the degree of hair scale lifting and falling off) by scanning electron microscopy (SEM); calculate the ratio of the number of hair scales of the experimental group to the number of hair scales of the blank group, i.e. the protection rate;

[0095] Comb performance detection: use a combing force tester to test the combing peak resistance (N) of the hair bundle coated with conditioner (wet state, natural dry state); compared with the blank group (without conditioner), calculate the resistance reduction rate;

[0096] Moisturizing performance detection: the moisture content (%) of the hair after applying the hair conditioner for 10h was tested by a skin moisture tester (adapted to hair); the moisture retention rate was calculated; the above test results are shown in Table 2.

[0097] Table 2 Hair care performance detection of the hair conditioner

[0098]

[0099]

[0100] As shown in Table 2, the hair heat protection hair conditioner prepared in the application has good hair care performance, the protection performance at 200℃ is as high as 80%, can effectively insulate heat, has good dry combing performance and wet combing performance, and has good water and moisture retention performance.

Claims

1. A hair heat protection hair conditioner of Patana oil, characterized in that, The composition comprises the following components by mass fraction: Group A: water 75-80 parts, cetrimonium bromide 0.5-1 part, hydroxyethyl cellulose 0.5-1.5 parts; Group B: PEG-50 shea butter 0.1-2 parts, bata nut nutrient solution 3-8 parts, silicone emulsion 2-11 parts, glycerol stearate 0.5-2 parts, PEG-20 stearate 0.3-1 part, p-hydroxyacetophenone 0.3-0.8 part, PEG-50 stearate 0.3-1 part, dimethicone alcohol 0.1-0.5 part, PEG-100 stearate 0.1-0.4 part; The silicone emulsion is obtained by mixing polydimethylsiloxane, amino-terminated polydimethylsiloxane, and cyclopenta polydimethylsiloxane, and then reacting with a glycoside solution and an aqueous quaternary ammonium salt solution. The bata nut nutrient solution is a nanoscale inclusion compound system formed by pressure and heat treatment of bata nut, modified cetylstearyl alcohol, and lactate. Group C: essence 0.5-1.5 parts, phenoxyethanol 0.3-1 part; Group D: panthenol 0.1-0.4 part, hydrolyzed keratin 0.1-0.3 part, vitamin complex 0.1-0.4 part, tridecyl alcohol polyether-12 0.05-0.3 part, ethylhexylglycerin 0.03-0.15 part, citric acid 0.03-0.1 part, natural carotene 0.03-0.1 part.

2. A hair heat protection conditioner for batana oil according to claim 1, characterized in that, The silicone emulsion is obtained by mixing polydimethylsiloxane, amino-terminated polydimethylsiloxane, and cyclopenta polydimethylsiloxane in a mass ratio of 1-4:0.5-3:0.5-4, and then mixing the mixture with a glycoside solution and an aqueous quaternary ammonium salt solution in a volume ratio of 11-14:1-5:1-5, and pre-stirring at 30-35°C and 1000-1500 rpm for 8-10 min.

3. A hair heat protection hair conditioner according to claim 1, characterised in that, The glycoside solution is a xylitol-based glucoside solution with a concentration of 30-40%.

4. A hair heat protection hair conditioner of batana oil according to claim 1, characterized in that, The aqueous quaternary ammonium salt solution contains one of double-chain quaternary ammonium salt and cetyltrimethylammonium chloride, with a concentration of 3-4%.

5. A hair heat protection hair conditioner of batana oil as claimed in claim 1, wherein, The bata nut nutrient solution is a nanoscale inclusion compound system formed by mixing bata nut and modified cetylstearyl alcohol in a ratio of 1-5:2-8, and adding lactate under a pressure of 30-50 MPa and a temperature of 40-50°C for 2-3 times, to form a nanoscale inclusion compound system with a particle size of 50-100 nm.

6. A hair heat protectant hair conditioner of batana oil as claimed in claim 1, wherein, The preparation method of the modified cetylstearyl alcohol is as follows: in a nitrogen-super critical CO2 mixed atmosphere with a volume ratio of 3:1, cetylstearyl alcohol is added with 4-6 wt% of hydroxylated palmitic acid (pretreated with 0.1-0.3 wt% of tetrabutyl titanate catalyst) in a rotary high-pressure reaction kettle, and dynamic mixing is carried out at 4-6 MPa and 70-80°C for 10-20 min, followed by molecular distillation.

7. A hair heat protection hair conditioner of batana oil as claimed in claim 1, wherein, The addition amount of the lactate is 3-6% of the mass of the bata nut.

8. A hair heat protectant hair conditioner of batana oil as claimed in claim 1, wherein, The vitamin complex is composed of tocopherol, biotin, and vitamin D in a mass ratio of 0.1-0.3:0.03-0.1:0.03-0.

1.

9. A process for the preparation of a hair thermal protection conditioner with babassu oil, for the preparation of a hair thermal protection conditioner with babassu oil according to any one of claims 1 to 8, characterized by, The composition comprises the following steps: Step 1: add the A phase to the main pot, heat to 85-90°C, stir and homogenize to completely dissolve the raw materials; Step 2: Add B phase into the oil pot, heat to 85-90℃, and stir to dissolve all the ingredients; Step 3: Add B phase ingredients into the main pot, and homogenously stir to fully disperse all the ingredients; Start to cool down to 50-55℃; Step 4: Add C phase ingredients into the main pot, and stir to fully disperse all the ingredients; Step 5: Add D phase ingredients into the main pot, and stir to fully disperse all the ingredients, continue to cool down to 40-45℃, and discharge after sampling and testing.

10. A process for the preparation of a hair heat protection hair conditioner of batana oil as claimed in claim 9, wherein, The homogenously stirring in Step 3 is at 60-80℃ for 5-10s.

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