Preparation method of butyl acrylate

By controlling the proportion of key impurities in acrylic acid and optimizing the distillation process, combined with process adjustments to the butyl acrylate recombinant decomposer, the problem of high production cost of butyl acrylate was solved, achieving efficient impurity decomposition and recovery, and reducing raw material consumption and production costs.

CN122355824APending Publication Date: 2026-07-10WANHUA CHEM GRP CO LTD
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Patent Information

Application Number
CN202511972094.3
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2025-12-25
Publication Date
2026-07-10

AI Technical Summary

Technical Problem

The production cost of butyl acrylate in the current technology is high, mainly due to the increased raw material cost and large amount of tar emissions caused by the demand for high-purity acrylic acid, and the insufficient ability of the esterification process to decompose heavy component ester impurities.

Method used

By controlling the proportion of key impurities in acrylic acid and adding auxiliaries 2,4-dimethyldithiocarbamate and phenothiazine, the distillation and esterification process parameters are optimized to reduce the purity requirements of acrylic acid. Combined with the process adjustment of the butyl ester recombinant decomposer, the impurities are effectively decomposed and recovered.

Benefits of technology

It reduced the production cost of butyl acrylate, decreased tar emissions, improved product purity and production efficiency, and reduced the consumption of butanol.

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Abstract

The invention discloses a preparation method of butyl acrylate, the butyl acrylate is prepared by esterification reaction of raw materials acrylic acid and n-butyl alcohol, the acrylic acid comprises acryloyloxy propionic acid, maleic acid and crotonic acid, the mass ratio of the acryloyloxy propionic acid to the maleic acid is 1: 0.01-1, and the crotonic acid is 1: 0.01-1. The mass ratio of crotonic acid to acryloyloxy propionic acid is 1: (5-500). The content of key impurities in the acrylic acid is ensured to be in a specific proportion, and the crude acrylic acid is directly used as a butyl acrylate production raw material after light components are removed, so that the butyl acrylate production cost is greatly reduced, the raw material consumption and the energy consumption are reduced, and the method is a green and efficient production process.
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