Biomass-based hard carbon and preparation method and application thereof

Biomass-based hard carbon with a dense microporous structure and high sp2 hybrid carbon content was prepared by hydrothermal reaction of phenolic solvent, solid gas medium and aldehyde crosslinking agent. This solved the problems of low liquefaction efficiency and insufficient pore structure control in traditional methods and improved the performance of secondary batteries.

CN122403422APending Publication Date: 2026-07-17YONGJIANG LAB
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
YONGJIANG LAB
Filing Date
2026-05-29
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Traditional methods for preparing biomass-based hard carbon suffer from low liquefaction efficiency, insufficient precision in pore structure control, and uncontrollable reaction pressure, which affect its performance as a negative electrode material, especially in the application of sodium-ion batteries.

Method used

A hydrothermal reaction is carried out using phenolic solvents with plant-derived biomass particles, a solid-gas medium, and aldehyde crosslinking agents. The reaction pressure is controlled at 5.5 MPa to 8.5 MPa. Through pre-carbonization and high-temperature calcination, biomass-based hard carbon with a dense microporous structure, high sp2 hybrid carbon content, and high-strength carbon skeleton is formed.

Benefits of technology

It significantly improves the initial efficiency, rate performance, and cycle performance of secondary batteries, especially in applications such as sodium-ion batteries.

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Abstract

本申请涉及一种生物质基硬碳及其制备方法和应用,所述生物质基硬碳的制备方法包括以下步骤:将酚类溶剂、植物源类生物质颗粒、固态气体介质、醛类交联剂进行水热反应,反应压力为5.5MPa~8.5MPa,得到生物质树脂;其中,每克所述植物源类生物质颗粒中加入1mL~3mL的所述酚类溶剂;在惰性气氛中,将所述生物质树脂依次进行预碳化和高温煅烧,得到生物质基硬碳。本申请的制备方法可制得具有绵密微孔结构、高sp2杂化碳含量、高强度碳骨架和低灰分的生物质基硬碳,将其用作二次电池负极材料时,能够有效提升二次电池的首效、倍率性能和循环性能。
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