A method for non-destructively determining the molecular long axis orientation of an organic semiconductor material

By using a uniaxial orientation single-crystal calibration model and a polarized Raman testing system, the problem of quantitatively determining the long axis orientation of molecules in organic semiconductor materials using traditional methods has been solved. This enables non-destructive and quantitative molecular orientation analysis, which is suitable for rapid detection of organic semiconductor thin films and research on device performance.

CN122409617APending Publication Date: 2026-07-17SOUTH CHINA UNIV OF TECH
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
SOUTH CHINA UNIV OF TECH
Filing Date
2026-04-29
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Traditional methods are difficult to directly, quantitatively, and non-destructively determine the molecular long axis orientation of organic semiconductor materials, especially in non-uniform states or with small-angle orientations.

Method used

Using a uniaxially oriented single crystal as the calibration model, a polarization Raman testing system was built. Through characteristic vibration mode calibration and the dependence of deflection angle and orientation angle, a quantitative relationship between Raman signal intensity and molecular spatial angle was established. Combined with the single-molecule scattering model, the theoretical relationship was derived to achieve non-destructive and quantitative measurement of organic semiconductor thin film samples.

Benefits of technology

It enables direct, quantitative, and non-destructive characterization of the long axis orientation of organic semiconductor materials, and is suitable for rapid and quantitative analysis of organic semiconductor thin films, providing a tool for device performance research and process optimization.

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Abstract

本发明公开了一种无损测定有机半导体材料的分子长轴取向的方法,其包括以下步骤:1)特征振动模式标定;2)单晶模型标定;3)理论关系拟合与参数确定;4)薄膜样品测量。本发明利用单轴取向单晶作为标定模型建立了拉曼信号强度与分子空间角度的精确对应关系,从而能够直接、定量、无损地表征有机半导体材料的分子长轴取向以及空间分布,该方法适合在有机半导体薄膜领域进行大规模应用。
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