A catalytic cracking catalyst and a method for preparing the same

By modifying kaolin-based transcrystalline molecular sieves and controlling the crystallization process, a multi-level porous catalyst was prepared, which solved the problem of high coke production in in-situ crystallized Y-type molecular sieve catalysts and achieved high heavy oil conversion activity and low coke selectivity.

CN115812006BActive Publication Date: 2026-04-17CHINA PETROLEUM & CHEMICAL CORP +1
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Patent Information

Application Number
CN202180044957.4
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Priority Date
2020-11-25
Filing Date
2021-06-23
Publication Date
2026-04-17
Estimated Expiration
2041-06-23

AI Technical Summary

Technical Problem

Existing in-situ crystallized Y-type molecular sieve catalysts have a high coke yield during heavy oil conversion, which is difficult to reduce effectively.

Method used

Modified molecular sieves based on kaolin crystallization were used as catalyst components. By controlling the silicon-aluminum ratio and sodium content during the crystallization process and combining rare earth modification, a catalyst with a hierarchical porous structure was prepared to reduce coke selectivity.

Benefits of technology

While maintaining a high heavy oil conversion rate, it significantly reduced coke selectivity and improved catalyst activity and resistance to heavy metal contamination.

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Abstract

The present application belongs to the field of catalyst preparation, and relates to a catalytic cracking catalyst and a preparation method thereof. The catalytic cracking catalyst comprises 10-70 wt% of a cracking active component, 10-60 wt% of a binder and 10-70 wt% of clay, wherein the cracking active component comprises 5-100 wt% of a first Y-type molecular sieve and 0-95 wt% of a second molecular sieve; the first Y-type molecular sieve is a modified kaolin-based metacrystalline molecular sieve, and the sodium oxide content thereof is less than 2 wt%. The preparation method of the catalyst comprises the steps of beating, spray drying, washing, filtering and drying the cracking active component comprising the modified kaolin-based metacrystalline molecular sieve, the binder and the clay. The catalyst is used for heavy oil catalytic cracking reaction, and has good coke selectivity and high heavy oil conversion rate.
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