A micro / ultra-gravity-microinterface injection self-rotating reaction device for enhancing the catalytic hydrogenation of heavy turpentine / resin oil and its usage method

Abstract

The present invention discloses a micro / supergravity-microinterface jet-type self-rotating reaction device for enhancing the catalytic hydrogenation of heavy turpentine / resin oil. The reaction device comprises: a heat exchanger; a super / microgravity-microinterface reactor disposed within the heat exchanger; and a fluid conveyor, wherein the material inlet is connected to the fluid conveyor. Also disclosed is a method for using the micro / supergravity-microinterface jet-type self-rotating reaction device for enhancing the catalytic hydrogenation of heavy turpentine / resin oil. The present invention utilizes the self-rotating circular flow of the materials participating in the reaction within the reaction device to generate centrifugal force, thereby overcoming gravity to form a super / microgravity-microinterface field, thereby causing the heterogeneous reaction materials to form millimeter- or micrometer-sized droplets and bubbles. The collective scale of the gas-liquid and gas-liquid-liquid interfaces is efficiently controlled from the milli-centimeter level to the micrometer level, effectively promoting interphase mixing and enhancing the transfer process of the heterogeneous reaction materials.

Description

Technical Field

[0001] The present invention relates to the technical field of chemical production equipment, and in particular to a micro / supergravity-microinterface jet-type self-rotating reaction device for enhancing the catalytic hydrogenation of heavy turpentine / resin oil and a method for using the device. Background Art

[0002] Reaction units are core equipment in chemical production processes. Because chemical production processes such as redox, catalytic hydrogenation, esterification, condensation, alkylation, sulfonation, halogenation, polymerization, reaction-absorption, and reaction-extraction are primarily heterogeneous reaction-separation processes, they present challenges related to "three transmissions and one reaction" and transfer intensification. Relevant chemical process intensification methods and technologies include high-gravity technology, micro-interface technology, ultrasound technology, microwave technology, micro-chemical technology, and rotating disk reaction technology. These have promoted high-quality, green development of chemical production processes with energy conservation and emission reduction, and have resulted in the following invention applications.

[0003] CN107699276 A discloses a multi-stage high-gravity reactor heavy oil hydrogenation method, comprising the following steps: starting the high-gravity reactor motor to drive the rotating disks of each stage to rotate, and simultaneously opening the ultrasonic probe in the feed chamber; inputting hydrogen and heavy oil into the feed chamber for efficient gas-liquid two-phase mixing to form a gas-liquid mixture; spraying the gas-liquid mixture from the lower end of the feed chamber onto the rotating disk of the first-stage rotor under the action of gas pressure and gravity, utilizing the centrifugal force on the rotating disk to throw the gas-liquid mixture onto the catalyst flowing through the rotor, completing the gas-liquid-solid three-phase hydrogenation reaction process; the reaction product is transported from the liquid outlet at the bottom of the first-stage rotor to the rotating disk of the second-stage rotor and enters the second-stage rotor for reaction, and so on, until it enters the Nth-stage rotor and reacts and then exits the reactor from the liquid outlet at the bottom of the shell. CN109925993 A discloses an ultrasonic microwave coupled high gravity and lignin degradation reaction system and method. The ultrasonic microwave coupled high gravity reaction system includes: a high gravity reaction device and a circulation tank. The high gravity reaction device includes: a shell with a accommodating cavity, a high gravity unit and a microwave feeding unit; the microwave feeding unit can feed microwaves into the accommodating cavity, and the high gravity unit can shear the liquid into micro-nano scale liquid elements; the circulation tank is provided with an ultrasonic feeding unit, and the ultrasonic feeding unit can feed ultrasound into the circulation tank. CN107686742 A discloses a method for conducting a residual oil hydrogenation reaction in a supergravity reactor, comprising the following steps: selecting a supergravity reactor; starting a motor of the supergravity reactor to drive a rotating disk to rotate, and simultaneously turning on an ultrasonic probe in a feed chamber; introducing hydrogen and residual oil into the feed chamber for efficient gas-liquid two-phase mixing, so that the sparingly soluble hydrogen is dispersed into a large number of nano-micron bubbles in the residual oil, and the solubility of hydrogen in the residual oil reaches supersaturation, forming a gas-liquid mixture; spraying the gas-liquid mixture from the lower end of the feed chamber onto the rotating disk under the action of gas pressure and gravity, and utilizing the centrifugal force on the rotating disk to throw the gas-liquid mixture to the inner edge of the rotor and flow through the catalyst, thereby completing the gas-liquid-solid three-phase hydrocracking reaction process. CN110396425 A relates to the fields of petroleum refining and petrochemical technology, and more particularly to an apparatus and method for micro-interface-enhanced liquid-phase circulating hydrogenation. The apparatus comprises: a feed tank, a heating furnace, a microbubble generator, a hydrogenation unit, a hydrogenation reactor, and a separator. The discharge end of the feed tank is connected to the microbubble generator via the heating furnace, and the hydrogenation unit is connected to the microbubble generator. The discharge end of the microbubble generator is connected to the hydrogenation reactor, and the discharge end of the hydrogenation reactor is connected to the separator. The method comprises: a microbubble stream undergoes a hydrogenation reaction in the hydrogenation reactor, and the hydrogenation product is collected through a separator. The microbubble stream is primarily obtained by mixing preheated feed oil and hydrogen in the microbubble generator. CN210176791 U relates to a multi-stage liquefaction system for coal and biomass, comprising: a liquid-phase feed unit, a gas-phase feed unit, a microinterface generator, at least two reactors, and a separator.CN210176767 U relates to an enhanced system for the preparation of menthane by hydrogen peroxide, comprising a liquid phase feeding unit, a gas phase feeding unit, a micro-interface generator, a reactor and a separation tank.

[0004] The above invention applications all utilize mechanical equipment and precision instruments to generate supergravity, micro-interface, ultrasonic waves, microwaves and turntable effects to enhance the chemical transfer process, resulting in high energy consumption, equipment investment and operational difficulty. Summary of the Invention

[0005] To solve the above technical problems, the present invention provides a micro / supergravity-microinterface jet-type self-rotating reaction device for enhanced catalytic hydrogenation of heavy turpentine / resin oil. The device utilizes the centrifugal force generated by the rotational flow of the reaction materials themselves to overcome the gravitational field and form a super / microgravity field, thereby achieving the goals of convenient operation, energy saving and consumption reduction, and reduced equipment investment costs.

[0006] To achieve the above objectives, the present invention provides the following technical solutions:

[0007] A micro / supergravity-microinterface jet-type self-rotating reaction device for enhancing the catalytic hydrogenation of heavy turpentine / resin oil, the reaction device comprising:

[0008] The heat exchanger has a material inlet and a material outlet at its upper and lower ends respectively, and a heat exchange fluid inlet and a heat exchange fluid outlet at its side wall;

[0009] A super / microgravity-microinterface reactor, disposed within the heat exchanger, comprising a fluid central tube and a fluid distributor, wherein the fluid central tube is a cylindrical tube with an open upper end, the upper end of the fluid central tube being connected to the material inlet; at least one fluid distributor being disposed axially of the fluid central tube, the fluid distributor comprising at least three arc bend groups, each arc bend group comprising at least one arc bend, the arc bends being radially distributed; when the number of arc bends in each arc bend group is ≥2, the arc diameters of the arc bends increase sequentially from the inside to the outside; a nozzle being disposed at the outer end of the arc bend, the inner end of the nozzle being connected to the fluid central tube; and

[0010] A fluid conveyor, wherein the material inlet is communicated with the fluid conveyor.

[0011] Furthermore, the heat exchanger is a shell and tube heat exchanger or a jacketed heat exchanger.

[0012] Furthermore, 2 to 40 fluid distributors are arranged in the axial direction of the fluid central tube, and the interval between each fluid distributor is 50 mm to 800 mm.

[0013] Furthermore, the heat exchanger has a diameter of 100 mm to 2000 mm and a height of 500 mm to 4000 mm.

[0014] Furthermore, in each arc bend pipe group, the number of the arc bend pipes is 1 to 10, and the arc diameter of the arc bend pipe is 10 mm to 1000 mm.

[0015] Furthermore, the nozzle diameter is 1 mm to 10 mm, and the arc elbow diameter is 3 mm to 20 mm.

[0016] A method for using the micro / supergravity-microinterface jet-type self-rotating reaction device for enhancing the catalytic hydrogenation of heavy turpentine / resin oil as described above and a method for using the same include the following steps:

[0017] (1) The heat exchange fluid inlet and the heat exchange fluid outlet are connected to the device for providing cold fluid for heat exchange; the fluid conveyor is connected to each device for providing materials, and is used to convey the materials heavy turpentine / resin oil and hydrogen to the material inlet respectively, and enter the fluid center tube of the super / microgravity-micro interface reactor through the material inlet. The material flow rate of the material conveyed by the fluid conveyor is determined by the size of the β value, and the specific calculation formula is as follows:

[0018] Centrifugal acceleration is G = Rω 2 (1)

[0019] The acceleration due to gravity of the earth is g = 9.81 m / s 2 (2)

[0020] Hypergravity / microgravity factors

[0021] Where: G-centrifugal acceleration, m / s 2 ;

[0022] R-circular motion radius, that is, the arc radius of the arc bend, m;

[0023] g-Earth's gravitational acceleration, m / s 2 ;

[0024] ω-angular velocity of circular motion, i.e., the angular velocity of the material in the super / microgravity-microinterface reactor, 1 / s;

[0025] β—hyper / microgravity factor;

[0026] N—circular motion speed, r / min;

[0027] π—pi;

[0028] V—circular motion linear velocity, i.e., the flow rate of the material in the super / microgravity-microinterface reactor, m / s;

[0029] Wherein, R is a known value, and β takes a specific value so that the material is in a microgravity or supergravity state in the super / microgravity-microinterface reactor;

[0030] (2) After heavy turpentine / resin oil and hydrogen enter the fluid center tube, they are sprayed into the heat exchanger through the arc elbow and nozzle to achieve mixing and reaction.

[0031] Among them, when the centrifugal acceleration G is 1 to 50 times the earth's gravitational acceleration g, that is, β = 1 to 50, it is a microgravity field effect; when the centrifugal acceleration G is greater than 50 times the earth's gravitational acceleration g, that is, β>50, it is a supergravity field effect, and the β value is selected according to the viscosity, density, temperature and chemical reaction characteristics of the material; under the super / microgravity field, the material causes the heterogeneous reaction material to form millimeter-level or micron-level droplets and small bubbles, which effectively promotes the mixing between the heterogeneous reaction materials and enhances the transfer process.

[0032] Compared with the prior art, the present invention has the following beneficial effects:

[0033] The present invention utilizes the self-rotating circular flow of materials participating in the reaction within a reaction device to generate centrifugal force, thereby overcoming gravity to form a super / microgravity-microinterface field, thereby causing the heterogeneous reaction materials to form millimeter-scale or micron-scale droplets and small bubbles, and efficiently controlling the collective scale of the gas-liquid and gas-liquid-liquid interfaces from the milli-centimeter level to the micron level, thereby efficiently promoting interphase mixing and enhancing the transfer process of the heterogeneous reaction materials. Furthermore, the reaction device of the present invention does not require the use of special mechanical equipment to drive the reaction materials to rotate at high speed to generate centrifugal force. Due to the self-rotating circular flow of the reaction materials in the reaction device of the present invention, the super / microgravity-microinterface is generated, thereby enhancing the transfer process of the reaction system. The device has a simple structure, is easy to manufacture, convenient to install and maintain, has good sealing performance, and is simple to operate, thereby achieving high-efficiency, low-energy consumption, low-pollution, and low-investment industrial production. BRIEF DESCRIPTION OF THE DRAWINGS

[0034] Figure 1 This is a schematic diagram of a micro / supergravity-microinterface jet-type self-rotating reaction device for enhanced catalytic hydrogenation of heavy turpentine / resin oil according to the present invention; wherein material A is middle finger turpentine / resin oil, and material B is hydrogen.

[0035] Figure 2 This is a top view of the super / microgravity-micro interface reactor.

[0036] Figure 3 are heat exchangers, where (a) is a shell and tube heat exchanger and (b) is a jacketed heat exchanger.

[0037] Figure 4 This is a three-dimensional diagram of the super / microgravity-micro interface reactor.

[0038] Among them, 1-heat exchanger, 2-fluid center pipe, 3-fluid distributor, 4-fluid conveyor; 101-material inlet, 102-material outlet, 103-heat exchange fluid inlet, 104-heat exchange fluid outlet, 301-arc elbow, 302-nozzle. DETAILED DESCRIPTION

[0039] The following is a detailed description of the specific embodiments in conjunction with the accompanying drawings, but it should be understood that the scope of protection of the present invention is not limited by the specific embodiments. Unless otherwise specified, the raw materials and reagents used in the examples are all commercially available.

[0040] Unless expressly stated otherwise, throughout the specification and claims, the term "comprise" or variations such as "include" or "comprising", etc., will be understood to include the stated elements or components but not to exclude other elements or other components.

[0041] Example 1

[0042] Figure 1 The schematic diagram of the structure of a micro / supergravity-micro interface jet-type self-rotating reaction device for enhancing the catalytic hydrogenation of heavy turpentine / resin oil of the present invention is shown. The reaction device comprises:

[0043] Heat exchanger 1 has a material inlet 101 at its upper end and a material outlet 102 at its lower end. A heat exchange fluid inlet 103 and a heat exchange fluid outlet 104 are provided on the sidewall of heat exchanger 1. The reaction proceeds within heat exchanger 1, releasing heat. Cooling fluid enters and exits heat exchanger 1 to control the reaction temperature.

[0044] The super / microgravity-microinterface reactor is arranged in a heat exchanger 1. The super / microgravity-microinterface reactor includes a fluid center tube 2 and a fluid distributor 3. The fluid center tube 2 is a cylindrical tube with an upper end open. The upper end of the fluid center tube 2 is connected to the material inlet 101. At least one fluid distributor 3 is arranged axially of the fluid center tube 2. The fluid distributor 3 includes at least three arc bend groups. Each arc bend group includes at least one arc bend 301. The arc bends 301 are radially distributed. When the number of arc bends 301 in each arc bend group is ≥2, the arc of the arc bend 301 is ≥1. The diameter increases from the inside to the outside, so that when the material is ejected from the nozzle 302 of the arc-shaped curved pipe 301 of different lengths, the reaction materials in different areas can be stirred, making the reaction more complete; the outer end of the arc-shaped curved pipe 301 is provided with a nozzle 302, and the inner end of the arc-shaped curved pipe 301 is connected to the fluid center pipe 2; the various materials are mixed and reacted through the super / microgravity-micro interface reactor, that is, the various materials enter the fluid center pipe 2 to complete the primary mixing (during the mixing period, the materials also undergo a chemical reaction), and then are sprayed into the heat exchanger 1 through the fluid distributor 3 to achieve secondary mixing and reaction;

[0045] and a fluid conveyor 4, wherein the material inlet 101 is connected to the fluid conveyor 4 and is used to convey various materials into the super / microgravity-microinterface reactor.

[0046] refer to Figure 1 and Figure 3 , the heat exchanger 1 is a shell and tube heat exchanger or a jacketed heat exchanger.

[0047] refer to Figure 1 、 Figure 2 and Figure 4 , 2 to 40 fluid distributors 3 are arranged axially in the fluid center tube 2, and the interval between each fluid distributor 3 is 50 mm to 800 mm. The number of fluid distributors 3 depends on the size of the heat exchanger 1. The larger the heat exchanger 1 is, the more fluid distributors 3 there are. The more fluid distributors 3 there are, the more uniform the mixing is and the more sufficient the stirring is.

[0048] refer to Figure 1 and Figure 3 The heat exchanger 1 has a diameter of 100 mm to 2000 mm and a height of 500 mm to 4000 mm.

[0049] refer to Figure 2 In each arc bend pipe group, the number of the arc bend pipes 301 is 1 to 10, and the arc diameter of the arc bend pipe 301 is 10 mm to 1000 mm;.

[0050] Continue to refer Figure 2 The diameter of the nozzle 302 is 1 mm to 10 mm, and the diameter of the arc elbow 301 is 3 mm to 20 mm.

[0051] Example 2

[0052] The method for using the micro / supergravity-micro interface jet-type self-rotating reaction device for enhancing the catalytic hydrogenation of heavy turpentine oil / resin oil in Example 1 is as follows:

[0053] (1) The heat exchange fluid inlet 103 and the heat exchange fluid outlet 104 are connected to the device for providing cold fluid for heat exchange. The heat exchanger 1 has a diameter of 100 mm and a height of 500 mm. The heavy turpentine / resin oil and hydrogen are respectively transported to the material inlet 101 at a certain speed through the fluid conveyor 4, and enter the fluid center tube 2 through the material inlet 101. There are 3 arc bend groups in each heat exchanger 1, and each arc bend group has two arc bends 301. The arc diameter of the first arc bend is 40 mm, and the arc diameter of the second arc bend is 70 mm. The diameter of the nozzle 302 is 1 mm, and the diameter of the arc bend 301 is 3 mm. There are 3 fluid distributors 3. Among them, the material flow rate V of the material transported by the fluid conveyor 4 is determined by the size of the β value, and the material flow rate is controlled to be 1.02 m / s. The specific calculation formula is as follows:

[0054] Centrifugal acceleration is G = Rω 2 (1)

[0055] The acceleration due to gravity of the earth is g = 9.81 m / s 2 (2)

[0056] Hypergravity / microgravity factors

[0057] Where: G—centrifugal acceleration, m / s 2 ; R—circular motion radius, m; g—earth gravity acceleration, m / s 2 ;ω—angular velocity of circular motion, 1 / s;β—super / microgravity factor;N—rotational speed of circular motion, r / min;π—pi;V—linear velocity of circular motion, m / s;

[0058] Specifically, each material is in a slightly heavy state after entering the fluid center tube 2, and β≥3. At this time, G≥29.43m / s 2 Because there are two arc elbows 301, each with a different arc radius, in order to ensure that the β value meets the above requirements, the arc radius of the largest arc elbow is used to calculate V, that is, R = 0.035m, then V = 1.02m / s; because the arc radius of the arc elbows is different in the super / microgravity-microinterface reactor, the material will be stirred at different positions in the heat exchanger 1 when it is ejected, which increases the uniformity of material mixing, makes the reaction more complete, and reduces the installation of stirring equipment;

[0059] (2) Material A (i.e., heavy turpentine / resin oil) and material B (i.e., hydrogen) flowing in from the material inlet 101 are mixed once in the fluid center tube 2. Since the lower end of the fluid center tube 2 is closed, the material can only enter the arc bend tube 301 from the fluid center tube 2 and be ejected through the nozzle 302. Due to the speed imparted by the fluid conveyor 4, the ejected material generates centrifugal force, overcomes gravity to form a microgravity-microinterface field, thereby achieving the transmission process of the enhanced reaction system, and fully mixing reaction is carried out in this process. After the reaction is completed, the resulting reactants are discharged from the material outlet 102; during the reaction, cold fluid enters from the heat exchange fluid inlet 103, completes heat exchange with the reaction raw materials, and then flows out through the heat exchange fluid outlet 104.

[0060] Example 3

[0061] The method for using the micro / supergravity-micro interface jet-type self-rotating reaction device for enhancing the catalytic hydrogenation of heavy turpentine oil / resin oil in Example 1 is as follows:

[0062] (1) The heat exchange fluid inlet 103 and the heat exchange fluid outlet 104 are connected to the device for providing cold fluid for heat exchange. The heat exchanger 1 has a diameter of 2000 mm and a height of 4000 mm. The heavy turpentine / resin oil and hydrogen are respectively transported to the material inlet 101 at a certain speed through the fluid conveyor 4, and enter the fluid center pipe 2 through the material inlet 101. There are 4 arc bend groups in each heat exchanger 1, and each arc bend group has five arc bends 301. The arc diameter of the first arc bend is 20 0mm, the arc diameter of the second arc elbow is 400mm, the arc diameter of the third arc elbow is 800mm, the arc diameter of the fourth arc elbow is 1000mm, the arc diameter of the fifth arc elbow is 1500mm, the diameter of the nozzle 302 is 10mm, the diameter of the arc elbow 301 is 20mm, and there are 15 fluid distributors 3; among them, the material flow rate V conveyed by the fluid conveyor 4 is determined by the size of the β value, and the material flow rate is controlled to be 22.76m / s. The specific calculation formula is as follows:

[0063] Centrifugal acceleration is G = Rω 2 (1)

[0064] The acceleration due to gravity of the earth is g = 9.81 m / s 2 (2)

[0065] Hypergravity / microgravity factors

[0066] Where: G-centrifugal acceleration, m / s 2 ; R-circular motion radius, m; g-earth gravity acceleration, m / s 2;ω-angular velocity of circular motion, 1 / s;β-super / microgravity factor;N-rotational speed of circular motion, R / min;π-circular ratio;V-linear velocity of circular motion, m / s;

[0067] Specifically, after each material enters the fluid center tube 2, it is in an overweight state, and β≥70. At this time, G≥294.3m / s 2 Because there are five arc bends 301, each with a different arc radius, in order to ensure that the β value meets the above requirements, the arc radius of the largest arc bend is used to calculate V, that is, R = 0.75m, then V = 22.76m / s; because the arc radius of the arc bends in the super / microgravity-microinterface reactor is different, the material will be stirred at different positions in the heat exchanger 1 when it is ejected, which increases the uniformity of material mixing, makes the reaction more complete, and reduces the installation of stirring equipment;

[0068] (2) Material A (i.e., heavy turpentine / resin oil) and material B (i.e., hydrogen) flowing in from the material inlet 101 are mixed once in the fluid center tube 2. Since the lower end of the fluid center tube 2 is closed, the material can only enter the arc bend tube 301 from the fluid center tube 2 and be ejected through the nozzle 302. Due to the speed imparted by the fluid conveyor 4, the ejected material generates centrifugal force, overcomes gravity to form a supergravity-microinterface field, thereby achieving the transmission process of the enhanced reaction system, and fully mixes and reacts in this process. After the reaction is completed, the resulting reactants are discharged from the material outlet 102; during the reaction, a cold fluid enters from the heat exchange fluid inlet 103, completes heat exchange with the reaction raw materials, and then flows out through the heat exchange fluid outlet 104.

[0069] Example 4

[0070] The method for using the micro / supergravity-micro interface jet-type self-rotating reaction device for enhancing the catalytic hydrogenation of heavy turpentine oil / resin oil in Example 1 is as follows:

[0071] (1) The heat exchange fluid inlet 103 and the heat exchange fluid outlet 104 are connected to the device for providing cold fluid for heat exchange. The heat exchanger 1 has a diameter of 1000 mm and a height of 3000 mm. The materials heavy turpentine / resin oil and hydrogen are respectively transported to the material inlet 101 at a certain speed through the fluid conveyor 4, and enter the fluid center tube 2 through the material inlet 101. There are 4 arc bend groups in each heat exchanger 1, and each arc bend group has four arc bends 301. The first arc bend The arc diameter of the arc bend is 100 mm, the arc diameter of the second arc bend is 300 mm, the arc diameter of the third arc bend is 500 mm, and the arc diameter of the fourth arc bend is 800 mm. The diameter of the nozzle 302 is 7 mm, the diameter of the arc bend 301 is 20 mm, and there are 6 fluid distributors 3. The material flow rate V of the material transported by the fluid conveyor 4 is determined by the size of the β value, and the material flow rate is controlled to be 12.57 m / s. The specific calculation formula is as follows:

[0072] Centrifugal acceleration is G = Rω 2 (1)

[0073] The acceleration due to gravity of the earth is g = 9.81 m / s 2 (2)

[0074] Hypergravity / microgravity factors

[0075] Where: G-centrifugal acceleration, m / s 2 ; R-circular motion radius, m; g-earth gravity acceleration, m / s 2 ;ω-angular velocity of circular motion, 1 / s;β-super / microgravity factor;N-rotational speed of circular motion, R / min;π-circular ratio;V-linear velocity of circular motion, m / s;

[0076] Specifically, after each material enters the fluid center tube 2, it is in a super / micro-gravity state, and β≥40. At this time, G≥392.4m / s 2 Because there are four arc bends 301, each with a different arc radius, in order to ensure that the β value meets the above requirements, the arc radius of the largest arc bend is used to calculate V, that is, R = 0.4m, then V = 12.57m / s; because the arc radius of the arc bends in the super / microgravity-microinterface reactor is different, the material will be stirred at different positions in the heat exchanger 1 when it is ejected, which increases the uniformity of material mixing, makes the reaction more complete, and reduces the installation of stirring equipment;

[0077] (2) Material A (i.e., heavy turpentine / resin oil) and material B (i.e., hydrogen) flowing in from the material inlet 101 are mixed once in the fluid center tube 2. Since the lower end of the fluid center tube 2 is closed, the material can only enter the arc bend tube 301 from the fluid center tube 2 and be ejected through the nozzle 302. Due to the speed imparted by the fluid conveyor 4, the ejected material generates centrifugal force, overcomes gravity to form a super / microgravity-micro interface field, thereby achieving the transmission process of the enhanced reaction system, and fully mixing reaction is carried out in this process. After the reaction is completed, the resulting reactants are discharged from the material outlet 102; during the reaction, cold fluid enters from the heat exchange fluid inlet 103, completes heat exchange with the reaction raw materials, and then flows out through the heat exchange fluid outlet 104.

[0078] Example 5

[0079] The method for using the micro / supergravity-micro interface jet-type self-rotating reaction device for enhancing the catalytic hydrogenation of heavy turpentine oil / resin oil in Example 1 is as follows:

[0080] (1) The heat exchange fluid inlet 103 and the heat exchange fluid outlet 104 are connected to the device for providing cold fluid for heat exchange. The heat exchanger 1 has a diameter of 300 mm and a height of 1000 mm. The heavy turpentine / resin oil and hydrogen are respectively transported to the material inlet 101 at a certain speed through the fluid conveyor 4, and enter the fluid center tube 2 through the material inlet 101. There are 3 arc bend groups in each heat exchanger 1, and each arc bend group has three arc bends 301. The arc diameter of the first arc bend is 80 mm, the arc diameter of the second arc bend is 120 mm, and the arc diameter of the third arc bend is 220 mm. The diameter of the nozzle 302 is 3 mm, and the diameter of the arc bend 301 is 12 mm. There are 4 fluid distributors 3. Among them, the material flow rate V of the material transported by the fluid conveyor 4 is determined by the size of the β value, and the material flow rate is controlled to be 4.66 m / s. The specific calculation formula is as follows:

[0081] Centrifugal acceleration is G = Rω 2 (1)

[0082] The acceleration due to gravity of the earth is g = 9.81 m / s 2 (2)

[0083] Hypergravity / microgravity factors

[0084] Where: G-centrifugal acceleration, m / s 2 ; R-circular motion radius, m; g-earth gravity acceleration, m / s 2;ω-angular velocity of circular motion, 1 / s;β-super / microgravity factor;N-rotational speed of circular motion, R / min;π-circular ratio;V-linear velocity of circular motion, m / s;

[0085] Specifically, after each material enters the fluid center tube 2, it is in a super / micro-gravity state, and β≥20. At this time, G≥196.2m / s 2 Because there are three arc bends 301, each with a different arc radius, in order to ensure that the β value meets the above requirements, the arc radius of the largest arc bend is used to calculate V, that is, R = 0.11m, then V = 4.66m / s; because the arc radius of the arc bends in the super / microgravity-microinterface reactor is different, the material will be stirred at different positions in the heat exchanger 1 when it is ejected, which increases the uniformity of material mixing, makes the reaction more complete, and reduces the installation of stirring equipment;

[0086] (2) Material A (i.e., heavy turpentine / resin oil) and material B (i.e., hydrogen) flowing in from the material inlet 101 are mixed once in the fluid center tube 2. Since the lower end of the fluid center tube 2 is closed, the material can only enter the arc bend tube 301 from the fluid center tube 2 and be ejected through the nozzle 302. Due to the speed imparted by the fluid conveyor 4, the ejected material generates centrifugal force, overcomes gravity to form a super / microgravity-micro interface field, thereby achieving the transmission process of the enhanced reaction system, and fully mixing reaction is carried out in this process. After the reaction is completed, the resulting reactants are discharged from the material outlet 102; during the reaction, cold fluid enters from the heat exchange fluid inlet 103, completes heat exchange with the reaction raw materials, and then flows out through the heat exchange fluid outlet 104.

[0087] The foregoing descriptions of specific exemplary embodiments of the present invention are for purposes of illustration and description. These descriptions are not intended to limit the invention to the precise forms disclosed, and it is apparent that many variations and modifications are possible in light of the foregoing teachings. The exemplary embodiments have been selected and described for the purpose of explaining the specific principles of the invention and their practical application, thereby enabling those skilled in the art to realize and utilize a variety of exemplary embodiments of the invention and various options and modifications. The scope of the invention is intended to be defined by the claims and their equivalents.

Claims

1. A micro / supergravity-microinterface jet-type self-rotating reaction device for enhanced catalytic hydrogenation of heavy turpentine / resin oil, characterized by: The reaction device comprises: A heat exchanger having a material inlet and a material outlet at its upper and lower ends, respectively, and a heat exchange fluid inlet and a heat exchange fluid outlet at its side wall. The heat exchanger has a diameter of 100 mm to 2000 mm and a height of 500 mm to 4000 mm; A super / microgravity-microinterface reactor is disposed within the heat exchanger, the super / microgravity-microinterface reactor comprising a fluid central tube and a fluid distributor, wherein the fluid central tube is a cylindrical tube with an open upper end, the upper end of the fluid central tube being connected to the material inlet; 2 to 40 fluid distributors are disposed axially along the fluid central tube, the interval between each fluid distributor being 50 mm to 800 mm, the fluid distributor comprising at least three arc bend groups, each arc bend group comprising 1 to 10 arc bends, the arc diameter of the arc bends being 10 mm to 1000 mm, and the arc bends being radially distributed; when the number of arc bends in each arc bend group is ≥2, the arc diameter of the arc bends increases sequentially from the inside to the outside; a nozzle is disposed at the outer end of the arc bend, and the inner end is connected to the fluid central tube; the nozzle diameter is 1 mm to 10 mm, and the diameter of the arc bend is 3 mm to 20 mm; and The fluid conveyor, the material inlet is connected to the fluid conveyor, and the material flow rate of the fluid conveyor is determined by the β value. The specific calculation formula is as follows: The centrifugal acceleration is (1) The acceleration due to gravity of the Earth is (2) Hypergravity / microgravity factors (3) Where: G -Centrifugal acceleration, m / s 2 ;R-circular motion radius, m; g -Earth's gravitational acceleration, m / s 2 ; ω - angular velocity of circular motion, 1 / s; β - Hyper / microgravity factor; N -Circular motion speed, r / min; π - pi; V -Linear velocity of circular motion, m / s.

2. The micro / supergravity-microinterface jet-type self-rotating reaction device for enhanced catalytic hydrogenation of heavy turpentine / resin oil according to claim 1, characterized in that: The heat exchanger is a shell and tube heat exchanger or a jacketed heat exchanger.

3. A method for using the micro / supergravity-microinterface jet-type self-rotating reaction device for enhanced catalytic hydrogenation of heavy turpentine / resin oil as claimed in claim 1, characterized in that: The following steps are involved: (1) The heat exchange fluid inlet and the heat exchange fluid outlet are connected to the device for providing cold fluid, and the materials heavy turpentine / resin oil and hydrogen are transported to the fluid center pipe through the fluid conveyor; (2) After heavy turpentine / resin oil and hydrogen enter the fluid center tube, they are sprayed into the heat exchanger through the arc elbow and nozzle to achieve mixing and reaction.

4. The method for using the micro / supergravity-microinterface jet-type self-rotating reaction device for enhancing the catalytic hydrogenation of heavy turpentine / resin oil according to claim 3 is characterized in that: When β=1~50, it is the microgravity field effect; when β>50, it is the hypergravity field effect. The β value is selected according to the viscosity, density, temperature and chemical reaction characteristics of the material.

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