High-strength inlaid glass

By employing a high-strength glass layer and a layered solar protection device in the glazing, the problem of damage to glazing under high mechanical loads has been solved, resulting in glazing with high durability and long lifespan.

CN116529219BActive Publication Date: 2026-01-20艾索克莱玛S.P.A.
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Patent Information

Application Number
CN202180080944.2
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Priority Date
2020-10-09
Filing Date
2021-10-06
Publication Date
2026-01-20
Estimated Expiration
2041-10-06

AI Technical Summary

Technical Problem

Existing inlaid glass is prone to damage under high mechanical loads, especially in marine windows, buildings, or air transport vehicles, posing a safety hazard.

Method used

The design employs a high-strength glass layer and layered functional blocks, including an outer high-strength glass layer, an inner high-strength glass layer, and a layered solar protection device arranged between the two. The glass layers are strengthened by heat treatment or chemical treatment and then laminated in an autoclave to form a high-strength inlaid glass.

Benefits of technology

It improves the durability of the inlaid glass, prevents damage to functional blocks and solar protection devices under high mechanical loads, and extends the service life of the overall laminate.

✦ Generated by Eureka AI based on patent content.

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Abstract

The invention relates to a high-strength glazing (1; 1.1; 7; 9) and to a method for producing such a glazing, which is used in particular as a transparent ship window, but can also be used as a building glazing or as a window for ground or air traffic vehicles. The glazing (1; 1.1; 7; 9) according to the invention comprises at least an outer high-strength glass layer (3) and an inner high-strength glass layer (4) in the form of a laminate and comprises a delaminating functional block distributed and integrated between the outer high-strength glass layer and the inner high-strength glass layer (3, 4) of the laminate. The delaminating functional block, for example a delaminating solar protection device, can comprise at least one annealed glass pane (2.19; 7.22; 9.27).
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Description

TECHNICAL FIELD

[0001] The present invention relates to a high-strength glazing and a method usable for the production of such a glazing, in particular as a transparent marine window, but also as a building glazing or a window for ground or air transportation vehicles. BACKGROUND

[0002] Considering for example a marine window, high loads generated by waves or gusts or gales impacting on the marine window can lead to high mechanical loads and even very high loads of the marine window, resulting in a possible damage and even breakage of the window or glazing and thus possibly in a danger for the passengers and crew inside the ship. Similar considerations apply to high-strength glazings used in buildings or ground and air transportation vehicles. SUMMARY

[0003] It is therefore an object of the present invention to provide a high-strength glazing which exhibits a reduced likelihood of damage even under high mechanical load conditions.

[0004] This object is solved by the high-strength glazing or window as set forth in the present invention. Thus, the high-strength glazing, in particular for marine windows, comprises at least an outer high-strength glass layer and an inner high-strength glass layer in the form of a laminate and comprises a delaminating functional block arranged and integrated between the outer high-strength glass layer and the inner high-strength glass layer in the laminate.

[0005] The glazing of the present invention provides a significant advantage in that the functional block is itself protected from too strong mechanical pressure due to the arrangement of the functional block in the position between the high-strength glass layers or glass panes. Thus, the present invention enables the functional block to have a long-lasting durability without damage, such as for example a crack in the functional block, and thus also the entire laminate of the glazing.

[0006] The "high-strength glass layer" of the present invention preferably exhibits a strengthened glass with a fracture strength in the range of about 160 MPa to 400 MPa. This means that the allowable mechanical stress of the high-strength glass layer is about 40 MPa to 100 MPa for a short load period. The strengthened glass preferably corresponds to a tempered or strengthened or safety glass which has been strengthened in its strength (compared to a float glass or annealed glass) by a controlled thermal or chemical treatment.

[0007] The delaminating functional block provides additional functionality to the glazing, mainly but not limited to solar protection, for example, a switchable light transmission of the glazing, an electronic circuit layer or an antenna layer, etc.

[0008] The layered functional block preferably comprises a layered solar protection device arranged and integrated between the outer high-strength glass layer and the inner high-strength glass layer in the laminate, wherein the layered solar protection device preferably suppresses UV (ultraviolet) and / or IR (infrared) solar radiation by, but not limited to, reflection. In this embodiment of the present invention, the layered solar protection device is protected itself from excessive, not allowed mechanical stresses, as it is located between the high-strength glass layers. Thus, the present invention enables a long-lasting durability of the solar protection without damage, such as e.g. cracks in the structure of the solar protection, thus resulting in a long-lasting durability of the entire laminate of high-strength glazing.

[0009] Preferably, the glazing comprises a neutral line or layer extending inside, adjacent to or close to the layered functional block or solar protection device to avoid excessive, not allowed mechanical stresses to the functional block or solar protection layer of the present invention. By "neutral line or layer" is meant a line or neutral layer of the cross-sectional area of the glazing which exhibits a mechanical stress close to zero or at most the allowable mechanical stress, if the glazing is subjected to a mechanical load from the outside. The neutral line or layer of the glazing extends through the center or main focus of the cross-sectional area of the unloaded glazing.

[0010] The functional block or the layered solar protection device can be positioned in the glazing of the present invention such that the mechanical stress resulting from an outside bending load acting on the outer high-strength glass layer is not higher than the allowable bending tensile stress of the functional block or the layered solar protection device, thereby avoiding damage of the functional block or the layered solar protection device.

[0011] The layered functional block can comprise at least one annealed glass pane. Preferably, the annealed glass pane is positioned in the glazing such that the mechanical stress resulting from an outside bending load acting on the outer high-strength glass layer is not higher than the allowable bending tensile stress of the annealed glass pane. The annealed glass pane can extend on, along or parallel to the neutral line or neutral layer of the glazing.

[0012] The layered solar protection device preferably comprises at least one annealed glass pane and a solar protection layer provided on the annealed glass pane, wherein the annealed glass pane is positioned in the glazing such that the mechanical stress resulting from an outside bending load acting on the outer high-strength glass layer is not higher than the allowable bending tensile stress of the annealed glass pane, wherein the annealed glass pane extends on, along or parallel to the neutral line or neutral area of the glazing.

[0013] The middle portion of the cross-sectional area of the insulating glass unit near the neutral line or neutral layer of the insulating glass unit is usually in slight compression or at most under slight tension.

[0014] According to the present invention, the optimal location of the annealed glass pane with only small stresses or minimal stresses is exactly near the neutral line or neutral layer towards the side of the outer high-strength glass layer of the insulating glass unit. The present invention incorporates this functional block or solar protection element into the cross-section of the structural insulating glass unit, positioning the functional block or solar protection element adjacent to or near or next to the neutral layer of the insulating glass unit.

[0015] Annealed glass, which can also be referred to as non-strengthened glass or float glass, usually shows a breaking strength in the range of 40 MPa to 70 MPa. This means that the permissible mechanical stress of an annealed glass pane in the short loading period is in the range of 10 MPa to 18 MPa.

[0016] Preferably, the layered solar protection device comprises one or more interlayers with a high modulus of elasticity, thereby reducing the likelihood of excessive tensile stresses in the annealed glass pane.

[0017] The layered solar protection device of the present invention preferably comprises an annealed glass pane and a solar protection layer for suppressing UV (ultraviolet) and / or IR (infrared) solar radiation, wherein the solar protection layer is arranged between the outer high-strength glass layer and the annealed glass pane. The solar protection layer can comprise a thin metal layer, which can be selected from the group comprising silver, gold, copper, aluminum and combinations thereof. Preferably, the thin metal layer is made of one or more silver coatings. The layered solar protection device of the present invention can comprise a solar protection layer made by a sputtering process and incorporating a single silver coating or a multiple silver coating, wherein a three-silver coating shows almost perfect reflectivity in the IR or NIR and / or UV solar regions and almost perfect transmissivity in the visible light region.

[0018] Advantageously, using an industrial sputtering process, the silver coating as solar protection layer can be sputtered or deposited on the annealed glass pane, resulting in e.g. a double silver layer, a triple silver layer and a quadruple silver layer, which show almost perfect properties of almost complete transmission in the visible light portion of the solar wavelength spectrum of 380 nm to 780 nm and almost complete reflection in the UV portion of the solar wavelength spectrum of 300 nm to 380 nm and in the NIR portion of 780 nm to 2500 nm. In particular, a three-silver coating shows almost perfect reflectivity in the UV and / or IR or NIR solar regions and almost perfect transmissivity in the visible light region.

[0019] The high-strength glass layers of the present invention can be made of glass chemically strengthened by ion exchange, or the high-strength glass layers can be made of heat-strengthened glass. In another alternative, the high-strength glass layers can be chemically strengthened by ion exchange and the high-strength glass layers can be heat-strengthened, or one of the high-strength glass layers can be chemically strengthened by ion exchange and another one of the high-strength glass layers can be heat-strengthened. Thus, the present invention can encompass a wide range of different mechanical load cases or applications.

[0020] The layered solar protection device can comprise an annealed glass pane and comprise a solar protection layer consisting of a physical or chemical vapor deposition coating located on the annealed glass pane.

[0021] The layered solar protection device can be made by a sputtering process to produce a transparent conductive layer, a reflective layer, or an anti-reflective or absorbing layer. The layered solar protection device can be made by a chemical process to produce a transparent conductive layer, a reflective layer, or an anti-reflective or absorbing layer. The layered functional block or the layered solar protection device can comprise a sputtered or deposited top interference protection layer, a sputtered or deposited barrier layer, a sputtered or deposited silver coating or layer, a sputtered or deposited seed layer, a sputtered or deposited interference base layer, and an annealed glass pane as a substrate of the thin film system.

[0022] The inner high-strength glass layer and the outer high-strength glass layer of the present invention can be arranged in a tensile portion of the glazing or in the cross-section of the glazing when the glazing is subjected to bending loads, thereby excluding or reducing tensile stresses from the solar protection layer device.

[0023] Preferably, the inner high-strength glass layer and the outer high-strength glass layer are arranged in the glazing or in the cross-sectional area of the glazing at a position where the stresses are below the allowable value.

[0024] The present invention also relates to a method of producing a high-strength glazing, comprising the following steps:

[0025] providing at least one outer high-strength glass layer and one inner high-strength glass layer, and a layered functional block or a layered solar protection device;

[0026] arranging the layered functional block or the layered solar protection device between the outer high-strength glass layer and the inner high-strength glass layer to obtain a pre-fabricated glazing stack; and thereafter

[0027] treating the pre-fabricated glazing stack in an autoclave to laminate the pre-fabricated glazing stack, thereby obtaining a high-strength glazing. BRIEF DESCRIPTION OF DRAWINGS

[0028] Advantageous embodiments and advantages of the present invention can also be derived from the description of exemplary and preferred embodiments in conjunction with the attached drawings:

[0029] Figure 1 is a schematic cross-sectional view of a high-strength glazing comprising a layered solar protection device according to a first preferred embodiment of the present application;

[0030] Figure 2 is a schematic cross-sectional view of a high-strength glazing comprising a layered single-silver solar protection device according to a second preferred embodiment of the present application;

[0031] Figure 3 is a schematic cross-sectional view of a high-strength glazing comprising a layered double-silver solar protection device according to a third preferred embodiment of the present application; and

[0032] Figure 4 is a schematic cross-sectional view of a high-strength glazing comprising a layered triple-silver solar protection device according to a fourth preferred embodiment of the present application. DETAILED DESCRIPTION

[0033] Figure 1 A schematic cross-sectional view of a high-strength glazing 1 according to a first preferred embodiment of the present application is shown. The high-strength glazing 1 has as a functional block a layered solar protection device 2. The high-strength glazing 1 is transparent to visible light. The high-strength glazing can have dimensions of about 3000 mm x 2000 mm, but is not limited thereto.

[0034] The high-strength glazing 1 or window, which can be used as a marine window in a marine vessel, comprises an outer high-strength glass layer 3, which faces towards the outside of the vehicle or marine vessel, an inner high-strength glass layer 4, which faces towards the inside of the vehicle, marine vessel or building in the form of a laminate, and a layered solar protection device 2 arranged and integrated between the outer high-strength glass layer and the inner high-strength glass layer 3 and 4 in the laminate.

[0035] The high-strength glass layers 3 and 4 of the present application preferably exhibit a breaking strength of about 240 MPa of strengthened glass. This means that the high-strength glass layers 3 and 4 each have an allowable mechanical stress of about 60 MPa over a short load period. The high-strength glass layers 3 and 4 are made of strengthened glass corresponding to tempered or strengthened glass or safety glass.

[0036] The layered solar protection device 2 comprises an outer adhesive layer 2.1 and an inner adhesive layer 2.2 and it inhibits UV (ultraviolet) and / or IR (infrared) solar radiation. The outer adhesive layer 2.1 is adjacent to the outer high-strength glass layer 3 and the inner adhesive layer 2.2 is adjacent to the inner high-strength glass layer 4. The outer and inner adhesive layers 2.1 and 2.2 can be made of PVB (polyvinyl butyral). The layered solar protection device 2 preferably comprises, but is not limited to, an annealed non-tempered glass pane coated with a functional solar protection film coating.

[0037] The high-strength glazing 1 comprises a neutral line or layer 5 that exhibits zero mechanical stress if the glazing 1 is subjected to loads from the outside. The neutral layer 5 extends inside or close to the layered solar protection device 2, thus avoiding excessive mechanical stress on the layered solar protection device 2.

[0038] Figure 2 A further schematic partial cross-sectional view of a high-strength glazing 1.1 according to another preferred embodiment of the present application is shown. The high-strength glazing 1.1 has a layered solar protection device 2.11 as a functional block.

[0039] The high-strength glazing 1.1 comprises an outer high-strength glass layer 3.1, an inner high-strength glass layer 4.1 in the form of a laminate, and the layered solar protection device 2.11 is arranged and integrated between the outer and inner high-strength glass layers 3.1 and 4.1 in the laminate.

[0040] The layered solar protection device 2.11 comprises an outer adhesive layer 2.12, an inner adhesive layer 2.13 and an annealed glass pane 2.19. The layered solar protection device 2.11 inhibits UV (ultraviolet) and / or IR (infrared) solar radiation. The high-strength glazing 1.1 likewise comprises a neutral line or layer 5.1 extending within the layered solar protection device 2.11. The outer adhesive layer 2.12 is adjacent to the outer high-strength glass layer 3.1 and the inner adhesive layer 2.13 is adjacent to the inner high-strength glass layer 4.1.

[0041] The outer and inner adhesive layers 2.12 and 2.13 can be made of PVB (polyvinyl butyral), preferably high modulus PVB, such as Eastman's Saflex® or Kuraray-Trosifol's Extra-Strong Another suitable material for the outer and inner adhesive layers 2.12 and 2.13 is an ionomer resin, such as Kuraray-Trosifol's Ionic interlayer. Other interlayers used in glass laminates are aliphatic thermoplastic polyurethane (TPU), although its elastic modulus is generally lower than that of structural PVB or ionomer interlayers. The optimal delamination section under external bending loads is obtained when the stress is uniformly transmitted through the various layers, and this is achieved when the shear modulus of the adhesive layers 2.12 and 2.13 is higher than > about 50 MPa. The thickness of the adhesive layers 2.12 and 2.13 can be comprised between 0.3 mm and 3 mm, preferably, the thickness is about 1.52 mm.

[0042] In Figure 2 In an embodiment of the application, the solar protection is based on a thin film system arranged or deposited on an annealed glass pane 2.19 as carrier or substrate, having a thickness comprised between about 2 mm and 6 mm, preferably 4 mm.

[0043] The solar protection function is achieved by reflecting the near-infrared portion of the solar radiation wavelengths comprised between 780 nm and 2500 nm by a silver layer 2.16 as solar protection layer, having a thickness comprised between 10 nm and 20 nm, preferably 15 nm. In order to allow the transmission of the visible portion of the solar radiation with wavelengths comprised between 380 nm and 780 nm, the silver layer 2.16 is arranged between the top protection interference layer 2.14 and the interference base layer 2.18 in the thin film system.

[0044] Additionally, in order to allow the silver layer 2.16 to have the best nucleation phenomenon and to protect it from chemical reactions that can cause corrosion and degradation, the silver layer 2.16 is deposited on a seed layer 2.17 made of ZnO, for example, having a thickness less than < 15 nm. Preferably, the thickness of the seed layer 2.17 is 10 nm. Furthermore, the silver layer 2.16 is protected by a barrier layer 2.15 made of a metal or a sub-valent metal oxide, preferably NiCr or NiCrOx, and having a thickness comprised between 2 nm and 8 nm, preferably 5 nm.

[0045] The delaminated solar protection device 2 comprises, in the order shown, between the external and internal adhesive layers 2.12 and 2.13, the following layers and coatings:

[0046] - a top protection interference layer 2.14 made of Si3N4, for example, having a thickness of about 2 nm to 20 nm, preferably about 11 nm, and / or of ZnO having a thickness comprised between 30 nm and 70 nm, preferably 50 nm;

[0047] - a sputtered barrier layer 2.15 made of NiCr or NiCrOx, having a thickness of about 2 nm to 6 nm, preferably 4 nm;

[0048] - a sputtered silver coating or layer 2.16 having a thickness of between about 12 nm to 15 nm, preferably 13.5 nm;

[0049] - a seed layer 2.17, for example made of ZnO or ZnO:SnO2:Al2O3, having a thickness of about 3 nm to 10 nm, preferably 6.5 nm;

[0050] - an interference / base layer 2.18, for example made of zinc stannate ZTO or SnO2, having a thickness of between about 30 nm to 80 nm, preferably about 55 nm; and

[0051] - an annealed glass pane 2.19 adjacent to the inner adhesive layer 2.13.

[0052] The transparent annealed glass pane 2.19 corresponds to annealed non-tempered glass or float glass and preferably shows a breaking strength of about 70 MPa. This means that the annealed glass pane 2.19 has an allowable mechanical stress of about 17.5 MPa for a short load period. The annealed glass pane 2.19 is adjacent to the neutral layer 5.1 of the high-strength glazing 1.1.

[0053] The outer and inner adhesive layers 2.12 and 2.13 exhibit a higher modulus of elasticity, which leads to a value of the shear modulus of about 50 MPa to reduce the likelihood of excessive tensile stresses in the annealed glass pane 2.19 that can be higher than > about 17.5 MPa.

[0054] The sputtered silver coating 2.16 is a near-ideal solar protection layer that is almost completely transmissive in the visible part of the solar wavelength spectrum of 380 nm to 780 nm and almost completely reflective in the UV part of the solar spectrum of 300 nm to 380 nm and in the IR part of 780 nm to 2500 nm.

[0055] The high-strength glazing 1.1 can be prepared by providing an outer high-strength glass layer 3.1 and an inner high-strength glass layer 4.1 and the layered solar protection device 2.11 between the outer and inner high-strength glass layers 3.1 and 4.1 to obtain a pre-glazing stack.

[0056] The thin-film system of the layered solar protection device 2.11 can be provided and prepared step by step in the following way:

[0057] - depositing the interference / base layer 2.18 on the annealed glass pane 2.19 by sputtering or chemical vapor deposition;

[0058] - then a seed layer 2.17 or coating is deposited by sputtering or chemical vapor deposition on the interference base layer 2.18;

[0059] - at this point, a silver coating 2.16 is sputtered or deposited onto the seed layer 2.17;

[0060] - thereafter, a barrier or absorption layer 2.15 or coating is sputtered or deposited on the silver coating 2.16;

[0061] - then, an interference top layer 2.14 is deposited or sputtered on the barrier layer 2.15.

[0062] The thus obtained thin film system is arranged between an outer and an inner adhesive layer 2.12 and 2.13 of high modulus polymer to obtain a layered solar protection device 2.11 which is assembled between an outer and an inner high strength glass pane 3.1 and 4.1 to provide a pre-assembled glazing stack.

[0063] Finally, the pre-assembled glazing stack is treated in an autoclave to laminate the pre-assembled glazing stack, thereby achieving sufficient adhesion between the layers and obtaining a complete layered high strength glass 1.1.

[0064] Figure 3 A further schematic partial cross-sectional view of a high strength glazing 7 according to a third preferred embodiment of the present application is shown. The high strength glazing 7 has a layered solar protection device 7.11 as a functional block.

[0065] The high strength glazing 7 comprises an outer high strength glass layer 7.1, an inner high strength glass layer 7.2 in the form of a laminate, and the layered solar protection device 7.11 is arranged and integrated between the outer and inner high strength glass layers 7.1 and 7.2 in the laminate.

[0066] The layered solar protection device 7.11 comprises an outer adhesive layer 7.12 and an inner adhesive layer 7.13, and the layered solar protection device suppresses UV (ultraviolet) and / or IR (infrared) solar radiation. The high strength glazing 7 comprises a neutral line or layer 8 extending within the layered solar protection device 7.11. The outer adhesive layer 7.12 is adjacent to the outer high strength glass layer 7.1, and the inner adhesive layer 7.13 is adjacent to the inner high strength glass layer 7.1. The outer and inner adhesive layers 7.12 and 7.13 can be made of PVB (polyvinyl butyral), preferably high modulus PVB or ionomer resin

[0067] The layered solar protection device 7.11 comprises the following layers and coatings as a thin film system between the outer and inner adhesive layers 7.12 and 7.13 in the order shown:

[0068] a sputtered or deposited top protective interference layer 7.14, for example made of Si3N4 and / or ZnO;

[0069] a sputtered or deposited barrier layer 7.15, for example made of NiCr or NiCrOx;

[0070] a first sputtered silver coating 7.16;

[0071] a seed layer 7.17, for example made of ZnO or ZnO:SnO2:Al2O3;

[0072] an interference layer 7.23, for example made of Si3N4 and / or ZnO;

[0073] a further sputtered barrier layer 7.18, for example made of NiCr or NiCrOx;

[0074] a second sputtered silver coating 7.19;

[0075] a further seed layer 7.20, for example made of ZnO or ZnO:SnO2:Al2O3;

[0076] an interference base layer 7.21 made of ZTO or SnO2, and

[0077] an annealed glass pane 7.22, the annealed glass pane being adjacent to the inner adhesive layer 7.13.

[0078] The annealed glass pane 7.22 extends adjacent to the neutral axis 8. Figure 3 The embodiment according to the application is based on a double silver thin film coating, which enhances the filtering selectivity of high visible light transmittance versus high reflectance of near infrared and UV solar radiation.

[0079] Figure 4 A further schematic partial view of a high-strength glazing 9 according to a fourth preferred embodiment of the application is shown, which exhibits a further but optimized solar radiation filtering selectivity. The high-strength glazing 9 has a layered solar protection device 9.11 as a functional block.

[0080] The high-strength glazing 9 comprises an outer high-strength glass layer 9.1, an inner high-strength glass layer 9.2 in the form of a laminate, and the layered solar protection device 9.11 is arranged and integrated between the outer and inner high-strength glass layers 9.1 and 9.2 in the laminate.

[0081] The layered solar protection device 9.11 includes an outer adhesive layer 9.12 and an inner adhesive layer 9.13, and the layered solar protection device inhibits UV (ultraviolet) and / or IR (infrared) solar radiation. The high-strength glazing 9 also includes a neutral line or neutral layer 10 extending within the layered solar protection device 9.11. The outer adhesive layer 9.12 is adjacent to the outer high-strength glass layer 9.1, and the inner adhesive layer 9.13 is adjacent to the inner high-strength glass layer 9.2. The outer and inner adhesive layers 9.12 and 9.13 can be made of high modulus PVB (polyvinyl butyral) or made.

[0082] The layered solar protection device 9.11 includes the following layers and coatings between the outer and inner adhesive layers 9.12 and 9.13 in the order shown:

[0083] a sputtered or deposited top protective interference layer 9.14, for example made of Si3N4 and / or ZnO;

[0084] a sputtered or deposited barrier layer 9.15, for example made of NiCr or NiCrOx;

[0085] a sputtered or deposited first silver coating 9.16;

[0086] a sputtered or deposited seed layer 9.17, for example made of ZnO or ZnO:SnO2:Al2O3;

[0087] a sputtered or deposited interference layer 9.23, for example made of Si3N4 and / or ZnO;

[0088] a sputtered or deposited further barrier layer 9.18, for example made of NiCr or NiCrOx;

[0089] a sputtered or deposited second silver coating 9.19;

[0090] a sputtered or deposited further seed layer 9.20, for example made of ZnO or ZnO:SnO2:Al2O3;

[0091] a sputtered or deposited further interference layer 9.21, for example made of Si3N4 and / or ZnO;

[0092] a sputtered or deposited barrier layer 9.22, for example made of NiCr or NiCrOx;

[0093] a sputtered or deposited third silver coating 9.24;

[0094] a sputtered or deposited seed layer 9.25, for example made of ZnO or ZnO:SnO2:Al2O3;

[0095] a sputtered or deposited interference layer 9.26, for example made of ZTO or SnO2, and

[0096] an annealed glass pane 9.27, the annealed glass pane being adjacent to the inner adhesive layer 9.13. The annealed glass pane 9.27 extends adjacent to the neutral layer 10.

Claims

1. A high-strength inlaid glass (1; 1.1; 7; 9), characterized in that, The inlaid glass includes at least an outer high-strength glass layer (3) and an inner high-strength glass layer (4) in the form of a laminate, and includes a layered functional block distributed and integrated between the outer high-strength glass layer and the inner high-strength glass layer (3, 4) in the laminate; the fracture strength of the outer high-strength glass layer and the inner high-strength glass layer are both 160MPa to 400MPa, and the allowable mechanical stress during a short load period is 40MPa to 100MPa; The layered functional block includes: an outer adhesive layer on an outer high-strength glass layer; an inner adhesive layer on an inner high-strength glass layer; and at least one thin film system having the following layered sequence: a sputtered or deposited top protective interference layer; a sputtered or deposited barrier layer; a sputtered or deposited silver coating or silver layer; a sputtered or deposited seed layer; a sputtered or deposited interference base layer; and an annealed glass pane; wherein the annealed glass pane has a fracture strength of 40 MPa to 70 MPa and an allowable mechanical stress of 10 MPa to 18 MPa during a short load period; wherein at least one thin film system is disposed on the annealed glass pane.

2. The inlaid glass according to claim 1, characterized in that, The layered functional block includes a layered solar protection device (2; 2.11; 7.11; 9.11) distributed and integrated between the outer high-strength glass layer and the inner high-strength glass layer (3, 4) in the laminate, wherein the layered solar protection device (2; 2.11; 7.11; 9.11) suppresses NIR / IR (near-infrared / infrared) and / or UV (ultraviolet) solar radiation.

3. The inlaid glass according to claim 1 or claim 2, characterized in that, When the inlaid glass is subjected to external mechanical loads, the inlaid glass includes a neutral line or neutral layer extending from within, adjacent to or close to the layered functional block.

4. The inlaid glass according to claim 1, characterized in that, The annealed glass panes extend on, adjacent to, along or parallel to the neutral line or neutral layer of the inlaid glass.

5. The inlaid glass according to claim 1, characterized in that, The elastic shear modulus G of the inner and outer adhesive layers is greater than 50 MPa.

6. The inlaid glass according to claim 1, characterized in that, The inner high-strength glass layer and the outer high-strength glass layer are made of glass that has been chemically strengthened by ion exchange, or the inner high-strength glass layer and the outer high-strength glass layer are made of thermally strengthened glass, or the inner high-strength glass layer and the outer high-strength glass layer are made of mixed-strength glass that has been first thermally strengthened and then chemically strengthened by ion exchange, or one of the inner high-strength glass layers and the outer high-strength glass layer is made of glass that has been chemically strengthened by ion exchange and the other is made of thermally strengthened glass.

7. The inlaid glass according to claim 2, characterized in that, The thin film system has a coating formed on an annealed glass pane by physical vapor deposition or chemical vapor deposition, or by physical vapor deposition, chemical vapor deposition or sputtering processes, comprising a single or multiple metal coating or silver coating.

8. The inlaid glass according to claim 1, characterized in that, The thin film system comprises a sequence of layers and coatings in the following order: Sputtered or deposited top protective interference layer (2.14); A barrier layer for sputtering or deposition (2.15); Sputtered or deposited silver coating (2.16); Sputtered or deposited seed layer (2.17); Another sputtered or deposited interference layer; Another layer of sputtering or deposition barrier; Another layer of sputtered or deposited silver coating; Another seed layer sputtered or deposited; Another layer of sputtered or deposited interference layer; Another layer of sputtering or deposition barrier layer; Another layer of sputtered or deposited silver coating; Another seed layer is sputtered or deposited; as well as Interference base layer sputtered or deposited on annealed glass panes.

9. The inlaid glass according to claim 1, characterized in that, The thin film system comprises a single or multiple silver layer sequence and is directly sputtered or deposited on one of the surfaces of an annealed glass pane.

10. The inlaid glass according to claim 2, characterized in that, When the inlaid glass is subjected to external mechanical loads, the inlaid glass includes a neutral line or neutral layer inside, adjacent to or close to the extension of the layered solar protection device.

11. The inlaid glass according to claim 1, characterized in that, The inlaid glass is used for marine windows.

12. A method for preparing a high-strength stained glass (1; 1.1; 7; 9) according to any one of claims 1 to 11, the method comprising: Provides at least one external high-strength glass layer (3) and one internal high-strength glass layer (4), as well as a layered functional block; The layered functional blocks are arranged between the outer high-strength glass layer and the inner high-strength glass layer (3, 4) to obtain a prefabricated inlaid glass stack; and subsequently The prefabricated inlaid glass stack is processed in an autoclave to laminate the prefabricated inlaid glass stack, thereby obtaining the inlaid glass (1; 1.1; 7; 9); The inlaid glass comprises: at least one outer high-strength glass layer and one inner high-strength glass layer in a laminated structure, both having a fracture strength of 160 MPa to 400 MPa and an allowable mechanical stress of 40 MPa to 100 MPa during a short load period; and a layered functional block integrated between the outer and inner high-strength glass layers in the laminated structure, the layered functional block comprising an adhesive layer on the outer high-strength glass layer, an adhesive layer on the inner high-strength glass layer, at least one thin film system having the following layered sequence: a sputtered or deposited top protective interference layer; a sputtered or deposited barrier layer; a sputtered or deposited silver coating or silver layer; a sputtered or deposited seed layer; a sputtered or deposited interference base layer; and at least one annealed glass pane, the annealed glass pane having a fracture strength of 40 MPa to 70 MPa and an allowable mechanical stress of 10 MPa to 18 MPa during a short load period; wherein at least one thin film system is disposed on the annealed glass pane.

Citation Information

Patent Citations

  • Composite glass used as safety glass comprises a first thick glass made from hardened soda-lime glass and a first thin glass having a functionalized surface

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