A kind of triple curing quick-drying polyurethane modified epoxy water-permeable pavement adhesive and its preparation method and application

Abstract

The application discloses a kind of triple curing fast-drying polyurethane modified epoxy water-permeable pavement adhesives and preparation method and application thereof.The adhesive includes A, B, C three components:A component is fluorine-containing polyurethane acrylic oligomer;B component is the mixture of bisphenol A type epoxy resin and glycidyl methacrylate;C component is the mixture of polyetheramine, active diluent, photoinitiator and short carbon fiber.The triple curing fast-drying polyurethane modified epoxy water-permeable pavement adhesive has excellent mechanical properties and water and stain resistance, and the triple curing system effectively improves the drying speed, and is applied to colorful water-permeable adhesive stone pavement paving, which can effectively shorten the construction period.

Description

Technical Field

[0001] This invention belongs to the field of permeable pavement materials, specifically relating to a triple-curing, fast-drying polyurethane-modified epoxy permeable pavement adhesive, its preparation method, and its application. Background Technology

[0002] Permeable bonded stone is made by mixing and curing adhesives with natural colored stones. It is characterized by its sturdiness, beauty, natural color, and high permeability. Currently, there are two main types of adhesives for permeable bonded stone: epoxy and polyurethane. Epoxy adhesives have high strength, but their flexibility and weather resistance are slightly worse, and stones are prone to falling off after long-term use. Polyurethane adhesives have good weather resistance, but they have higher requirements for the construction environment.

[0003] Meanwhile, existing permeable adhesives for bonding stone have a slow drying speed after application, requiring at least 4-8 hours to reach surface dryness, and opening to traffic generally takes even longer, affecting the construction efficiency of some emergency road construction projects. For example, Chinese patent CN112723790A uses epoxy resin combined with organic amine curing, and through formula optimization, the surface drying time is reduced to 4 hours; Chinese patent CN112457816A uses HDI curing agent combined with a polyol system, shortening the road opening time to 4-5 hours. Summary of the Invention

[0004] In view of the above-mentioned problems in the prior art, the purpose of this invention is to provide a triple-curing fast-drying polyurethane modified epoxy permeable pavement adhesive. After being mixed and cured with stones, it has the characteristics of fast drying speed, immediate opening after construction, high strength after complete curing, and good weather resistance. It also effectively improves the water resistance and stain resistance of the adhesive layer.

[0005] This invention provides a triple-curing, fast-drying polyurethane-modified epoxy permeable pavement adhesive, comprising three components: A, B, and C.

[0006] Component A is a fluorinated polyurethane acrylic oligomer;

[0007] Component B is a mixture of bisphenol A type epoxy resin and glycidyl methacrylate;

[0008] Component C is a mixture of polyetheramine, reactive diluent, photoinitiator and short-cut carbon fibers;

[0009] The mass ratio of components A, B, and C is 20–60:4–10:5–10, for example 25:5:6, 35:7:8, 45:8:9, 55:9:7, preferably 20–40:4–8:5–8.

[0010] In this invention, the fluorinated polyurethane acrylic oligomer of component A has a structure as shown in general formula (1):

[0011] D-(PD)nF(1)

[0012] In the formula:

[0013] D represents residues derived from diisocyanate monomers;

[0014] P represents residues derived from polyether polyols;

[0015] F represents a residue derived from a fluorinated hydroxy acrylate monomer.

[0016] In component A of the present invention, in the structure shown by general formula (1), the diisocyanate monomer is selected from any one or a combination of at least two of dicyclohexylmethane diisocyanate (HMDI), isophorone diisocyanate (IPDI), and hexamethylene diisocyanate (HDI);

[0017] The polyether polyol is selected from polypropylene glycol and / or polytetrahydrofuran glycol, with a number average molecular weight of 400 to 2000.

[0018] The fluorinated hydroxy acrylic monomer is selected from hexafluorobutyl methacrylate and / or hexafluoroisopropyl methacrylate.

[0019] In this invention, the fluorinated polyurethane acrylic oligomer is prepared by reacting diisocyanate monomer, polyether polyol, and fluorinated hydroxyl acrylic monomer at 40-80°C for 3-9 hours, preferably 4-8 hours.

[0020] Preferably, the mass ratio of the diisocyanate monomer to the polyether polyol and the fluorinated hydroxyl acrylic monomer is 1:0.5 to 5:0.2 to 0.5, for example 1:0.6:0.25, 1:1:0.34, 1:1.5:0.38, 1:3:0.45, and more preferably 1:0.7 to 2:0.3 to 0.4.

[0021] Preferably, the reaction is carried out under catalytic conditions, wherein the catalyst is dibutyltin dilaurate;

[0022] More preferably, the amount of catalyst used is 10 to 50 ppm, for example 20 ppm, 30 ppm, or 40 ppm, based on the mass of the polyether polyol.

[0023] As a preferred embodiment, the preparation method of the fluorinated polyurethane acrylic oligomer is as follows: diisocyanate monomer, polyether polyol and catalyst are mixed and reacted at 50-80°C, preferably 60-80°C, for 2-6 hours, preferably 2-4 hours. Then, fluorinated hydroxyl acrylic monomer is added and the reaction is continued at 40-50°C, preferably 40-45°C, for 1-3 hours, preferably 1.5-2 hours, to obtain the fluorinated polyurethane acrylic oligomer.

[0024] In component B of the present invention, the epoxy equivalent (EEW) of the bisphenol A type epoxy resin ranges from 170 to 190, preferably from 175 to 185.

[0025] In component B of this invention, the mass ratio of the bisphenol A type epoxy resin to glycidyl methacrylate is 1:0.2 to 0.5, preferably 1:0.25 to 0.4.

[0026] In component C of this invention, the polyetheramine is selected from amino-terminated polyoxypropylene ether and / or amino-terminated polyoxyethylene ether;

[0027] Preferably, the molecular weight of the polyetheramine is in the range of 200 to 400, more preferably 200 to 250.

[0028] In component C of this invention, the active diluent is selected from any one or a combination of at least two of tripropylene glycol diacrylate (TPGDA), 1,6-hexanediol diacrylate (HDDA), dipropylene glycol diacrylate (DPGDA), trimethylolpropane triacrylate (TMPTA), and pentaerythritol triacrylate (PETA).

[0029] In component C of this invention, the photoinitiator is diphenyltitanium fluoride.

[0030] In component C of this invention, the chopped carbon fiber has a fiber length ranging from 1 to 3 cm, preferably 2 cm, and a diameter of 5 to 8 μm, preferably 5 μm; the preferred type of the chopped carbon fiber is T300.

[0031] In component C of this invention, the mass ratio of the polyetheramine, reactive diluent, photoinitiator, and chopped carbon fiber is 1:0.4-0.7:0.1-0.5:0.1-0.4, preferably 1:0.5-0.65:0.2-0.4:0.15-0.25.

[0032] This invention also provides a method for preparing the above-mentioned triple-curing, fast-drying polyurethane-modified epoxy permeable pavement adhesive, the steps of which include:

[0033] 1) Preparation of component A: For example, prepare the fluorinated polyurethane acrylic oligomer according to the above method, for later use;

[0034] 2) Preparation of component B: Mix bisphenol A epoxy resin and glycidyl methacrylate evenly and set aside.

[0035] 3) Preparation of component C: Mix polyetheramine, reactive diluent, photoinitiator, and short-cut carbon fibers evenly and set aside;

[0036] 4) When using, mix components A, B, and C evenly to obtain the triple-curing, fast-drying polyurethane modified epoxy permeable pavement adhesive.

[0037] In another aspect, the present invention also provides the application of the above-mentioned triple-curing, fast-drying polyurethane-modified epoxy permeable pavement adhesive.

[0038] As a preferred embodiment, the present invention provides a permeable adhesive stone pavement material, the raw material of which includes the triple-curing fast-drying polyurethane modified epoxy permeable pavement adhesive described in the present invention.

[0039] Preferably, the triple-curing, fast-drying polyurethane-modified epoxy permeable pavement adhesive has a mass content of 2-7%, more preferably 3-5%, based on a total mass of 100% for the permeable adhesive stone pavement material;

[0040] As a preferred embodiment, the permeable adhesive stone pavement material comprises the following raw materials by weight:

[0041] 93-98 parts of pebbles, preferably 95-97 parts;

[0042] 2-7 parts of triple-curing, fast-drying polyurethane-modified epoxy permeable pavement adhesive, preferably 3-5 parts.

[0043] The construction method of the permeable adhesive stone pavement material of the present invention includes the following steps:

[0044] First, mix the above components A, B, and C evenly to obtain a triple-curing, fast-drying polyurethane-modified epoxy permeable pavement adhesive. Then, mix it thoroughly with the stones and lay it on the road surface to be constructed. Finally, use ultraviolet light equipment to irradiate and cure the surface.

[0045] Preferably, the irradiation power of the ultraviolet light device is 6-8W, and a handheld long-wave ultraviolet lamp is preferred, with a wavelength of 325-365nm, and more preferably 325nm or 365nm lamp tubes.

[0046] The surface drying time of the permeable adhesive stone pavement material described in this invention can be reduced to less than 5 minutes, allowing passage immediately after construction.

[0047] The triple-curing, fast-drying polyurethane-modified epoxy permeable pavement adhesive of this invention innovatively employs a three-component adhesive curing system. Component A contains NCO groups and unsaturated double bonds, component B contains epoxy groups and unsaturated double bonds, and component C contains amine groups and unsaturated double bonds. After construction, the system exhibits a triple curing mechanism: free radical polymerization containing double bonds, the reaction between epoxy groups and amine groups provided by epoxy resin and glycidyl methacrylate (GMA), and the reaction between NCO groups and amine groups. Due to the presence of unsaturated double bonds, preliminary cross-linking can be rapidly achieved upon UV irradiation after construction, resulting in a surface-dry pavement layer with sufficient strength, dust-free operation, and pedestrian strength requirements, significantly improving pavement construction efficiency. Furthermore, within the adhesive layer untouched by UV light, the dual curing effect of the epoxy and polyurethane systems allows for a rapid and exothermic reaction between NCO groups and the primary amine in the polyetheramine, further accelerating the curing of the epoxy and amine and effectively shortening the required drying time of the adhesive layer. This multi-curing effect effectively enhances the adhesive layer strength and increases the drying speed. The three-component curing system can effectively link polyurethane and epoxy molecular chains through double-bond free radical polymerization, giving the cured adhesive layer superior weather resistance and toughness.

[0048] Furthermore, the adhesive of this invention introduces fluorine groups into the main chain of the fluorinated hydroxyl acrylic monomer in component A, and at the same time, the short-cut carbon fibers added in component C effectively improve the hydrophobicity of the adhesive layer surface. The short-cut carbon fibers can serve as the adhesive layer skeleton, and at the same time, they can effectively reduce the gas generated by the reaction of isocyanate groups with water in the system, thereby reducing the number of microbubbles in the adhesive layer. Experimental verification shows that this can greatly improve the strength of the adhesive layer and its long-term water resistance.

[0049] Compared with existing technologies, the triple-curing, fast-drying polyurethane-modified epoxy permeable pavement adhesive of the present invention has a fast drying speed, high strength, excellent weather resistance and long-term water resistance, which can effectively improve the construction efficiency of permeable pavement in sponge cities and has broad application prospects. Detailed Implementation

[0050] To illustrate the effects of the present invention, embodiments are provided for further detailed explanation, but the present invention is not limited to these embodiments.

[0051] The raw materials used in the examples are from the following sources:

[0052] HMDI: Purchased from Wanhua Chemical Group Co., Ltd., trade name WANNATE HMDI;

[0053] IPDI: Purchased from Wanhua Chemical Group Co., Ltd., trade name WANNATE IPDI;

[0054] PTMEG2000: Purchased from BASF (polytetrahydrofuran diol, molecular weight 2000);

[0055] PPG1000: Purchased from Lanxing Dongda, trade name DL-1000D (polypropylene glycol, molecular weight 1000);

[0056] PPG400: Purchased from Lanxing Dongda, trade name DL-400D (polypropylene glycol, molecular weight 400);

[0057] Dibutyltin dilaurate: purchased from Deyin Chemical, trade name DY-12;

[0058] Bisphenol A type epoxy resin: purchased from Nan Ya Plastics, Taiwan, China, under the trade names NPEL-127 (epoxy equivalent 176-184) and NEPL-128 (epoxy equivalent 184-190);

[0059] Polyetheramine: Purchased from Wanhua Chemical Group Co., Ltd., trade name: 8100, with a molecular weight of 230;

[0060] Photoinitiator diphenyltitanium fluoride: purchased from BASF, trade name Irgacure 784;

[0061] Short-cut carbon fiber: purchased from Toray Industries, Japan, trade name T300, length 2cm, diameter 5μm;

[0062] Unless otherwise specified, all other reagents are commercially available.

[0063] Performance testing methods in the embodiments and comparative examples of this invention:

[0064] 1. Surface drying time: After the application is completed, press the surface firmly with your finger every 5 minutes until there are no fingerprints left and no stickiness (test temperature: 20-25℃, test humidity: 50±10%).

[0065] 2. Compressive strength: 72 hours after construction, a compressive strength test shall be conducted in accordance with the GB / T 50107 standard for testing and evaluating concrete.

[0066] 3. Weather resistance: Following the Q-SUN test conditions in ASTM D904-99, after completing a 2000-hour artificial accelerated aging test, observe the stone detachment and test the compressive strength of the sample block.

[0067] 4. Water resistance: Place the sample in a 45℃ water bath, take it out every day to test the stone detachment, and record the water bath time required for the stones to start detaching.

[0068] Example 1

[0069] Preparation of component A fluorinated polyurethane acrylic prepolymer:

[0070] 10 kg IPDI, 8 kg PPG-400, and 0.16 g dibutyltin dilaurate were added to the reactor and reacted at 60 °C for 2 h. Then the temperature was lowered to 40 °C, and 3 kg hexafluorobutyl methacrylate was added to the reaction system. After reacting for 2.5 h, a fluorinated polyurethane acrylic prepolymer was obtained.

[0071] Component B: Mix 1.5 kg of glycidyl methacrylate with 3.5 kg of epoxy resin NPEL-127 until homogeneous.

[0072] Component C: Mix 3.0 kg of polyetheramine 8100, 0.5 kg of TPGDA, 1.0 kg of HDDA, 1.0 kg of photoinitiator fluorinated diphenyltitanium oxide, and 0.5 kg of 2 cm short carbon fibers until homogeneous.

[0073] When applying the adhesive, the above components A, B, and C are mixed evenly (mass ratio of 21:5:6) to obtain a triple-curing, fast-drying polyurethane-modified epoxy permeable pavement adhesive. Then, it is mixed with gravel at a mass ratio of 3:97 to prepare a permeable adhesive stone pavement material. After thorough mixing, it is laid on the road surface to be constructed. Then, a handheld ultraviolet light device is used to perform radiation curing on the surface at a wavelength of 325nm and a radiation power of 6W. Its performance is tested, and the results are shown in Table 1.

[0074] Example 2

[0075] Preparation of component A fluorinated polyurethane acrylic prepolymer:

[0076] 10 kg HMDI, 7 kg PPG-400, and 0.07 g dibutyltin dilaurate were added to the reactor and reacted at 60 °C for 2 h. Then the temperature was lowered to 45 °C, and 3 kg hexafluoroisopropyl methacrylate was added to the reactants. After reacting for 2 h, polyurethane acrylic prepolymer was obtained.

[0077] Component B: Mix 1.0 kg of glycidyl methacrylate with 3 kg of epoxy resin NPEL-127 at room temperature until homogeneous.

[0078] Component C: Mix 2.5 kg of polyetheramine 8100, 0.4 kg of TMPTA, 1.0 kg of HDDA, 0.6 kg of photoinitiator fluorinated diphenyltitanium oxide, and 0.5 kg of 2 cm short-cut carbon fiber at room temperature until homogeneous.

[0079] When applying the adhesive, the above components A, B, and C are mixed evenly (by weight 20:4:5) to obtain a triple-curing, fast-drying polyurethane-modified epoxy permeable pavement adhesive. Then, it is mixed with gravel at a mass ratio of 4:96 to prepare a permeable adhesive stone pavement material. After thorough mixing, it is laid on the pavement to be constructed. Then, a handheld ultraviolet light device is used to perform radiation curing on the surface at a wavelength of 325nm and a radiation power of 6W. Its performance is tested, and the results are shown in Table 1.

[0080] Example 3

[0081] Preparation of component A fluorinated polyurethane acrylic prepolymer:

[0082] 10 kg IPDI, 20 kg PPG-1000, and 1.0 g dibutyltin dilaurate were added to the reactor and reacted at 80 °C for 4 h. Then the temperature was lowered to 45 °C, and 2 kg hexafluorobutyl methacrylate and 2 kg hexafluoroisopropyl methacrylate were added to the reactants. After reacting for 2 h, polyurethane acrylic prepolymer was obtained.

[0083] Component B: Mix 2.0 kg of glycidyl methacrylate and 6 kg of epoxy resin NPEL-127 at room temperature until homogeneous.

[0084] Component C: Mix 3.5 kg of polyetheramine 8100, 0.8 kg of PETA, 1.0 kg of DPGDA, 1.2 kg of photoinitiator fluorinated diphenyltitanium oxide, and 0.5 kg of 2 cm short-cut carbon fiber at room temperature until homogeneous.

[0085] When applying the adhesive, the above components A, B, and C are mixed evenly (by weight 24:8:7) to obtain a triple-curing, fast-drying polyurethane-modified epoxy permeable pavement adhesive. Then, it is mixed with gravel at a mass ratio of 5:95 to prepare a permeable adhesive stone pavement material. After thorough mixing, it is laid on the pavement to be constructed. Then, a handheld ultraviolet light device is used to perform radiation curing on the surface at a wavelength of 325nm and a radiation power of 6W. Its performance is tested, and the results are shown in Table 1.

[0086] Example 4

[0087] Preparation of component A fluorinated polyurethane acrylic prepolymer:

[0088] 10 kg IPDI, 40 kg PTMEG-2000, and 1.6 g dibutyltin dilaurate were added to the reactor and reacted at 70 °C for 4 h. Then the temperature was lowered to 50 °C, and 4 kg hexafluorobutyl methacrylate was added to the reactants. After reacting for 1.5 h, polyurethane acrylic prepolymer was obtained.

[0089] Component B: Mix 2.0 kg of glycidyl methacrylate with 8 kg of epoxy resin NPEL-128 at room temperature until homogeneous.

[0090] Component C: Mix 4 kg of polyetheramine 8100, 0.5 kg of PETA, 2.0 kg of HDDA, 1.5 kg of photoinitiator fluorinated diphenyltitanium oxide, and 1 kg of 2 cm short-cut carbon fiber at room temperature until homogeneous.

[0091] When applying the adhesive, the above components A, B, and C are mixed evenly (by weight 55:10:9) to obtain a triple-curing, fast-drying polyurethane-modified epoxy permeable pavement adhesive. Then, it is mixed with gravel at a mass ratio of 5:95 to prepare a permeable adhesive stone pavement material. After thorough mixing, it is laid on the pavement to be constructed. Then, a handheld ultraviolet light device is used to perform radiation curing on the surface at a wavelength of 325nm and a radiation power of 6W. Its performance is tested, and the results are shown in Table 1.

[0092] Comparative Example 1

[0093] The adhesive was prepared by referring to the method of Example 1, except that hexafluorobutyl methacrylate was not added when preparing component A. All other operations and parameters were the same as in Example 1.

[0094] The adhesive was applied according to the method in Example 1, and its performance was tested after curing. The results are shown in Table 1.

[0095] Comparative Example 2

[0096] The adhesive was prepared by referring to the method of Example 1, except that component B was not added. All other operations and parameters were the same as in Example 1.

[0097] The adhesive was applied according to the method in Example 1, and its performance was tested after curing. The results are shown in Table 1.

[0098] Comparative Example 3

[0099] The adhesive was prepared by referring to the method of Example 1, except that glycidyl methacrylate was not added to component B. All other operations and parameters were the same as in Example 1.

[0100] The adhesive was applied according to the method in Example 1, and its performance was tested after curing. The results are shown in Table 1.

[0101] Comparative Example 4

[0102] Following the method of Example 1, except that short-cut carbon fibers were not added to component C, all other operations and parameters were the same as in Example 1, and an adhesive was prepared. The adhesive was applied according to the method of Example 1, and its performance was tested after curing. The results are shown in Table 1.

[0103] Comparative Example 5

[0104] The adhesive was prepared by referring to the method of Example 1, except that when preparing component A, hexafluorobutyl methacrylate was replaced with an equal mass of butyl methacrylate, and other conditions, operations and parameters were the same as in Example 1.

[0105] The adhesive was applied according to the method in Example 1, and its performance was tested after curing. The results are shown in Table 1.

[0106] Table 1. Performance test results of the examples and comparative examples.

[0107]

Claims

1. A triple-cured fast drying polyurethane modified epoxy water permeable pavement adhesive, characterized in that, It comprises three components A, B and C. The A component is a fluorine-containing polyurethane acrylic oligomer; The B component is a mixture of bisphenol A type epoxy resin and glycidyl methacrylate; The C component is a mixture of polyether amine, active diluent, photoinitiator and short carbon fiber; The mass ratio of A, B and C components is 20-60:4-10:5-10.

2. The triple cure fast drying polyurethane modified epoxy water permeable pavement adhesive according to claim 1, characterized in that, The mass ratio of A, B and C components is 20-40:4-8:5-8.

3. The triple cure fast drying polyurethane modified epoxy water permeable pavement adhesive according to claim 1, characterized in that, The fluorine-containing polyurethane acrylic oligomer of the A component has a structure as shown in general formula (1): D-(P-D)n-F (1) In the formula: D is a residue derived from a diisocyanate monomer; P is a residue derived from a polyether polyol; F is a residue derived from a fluorine-containing hydroxyl acrylate monomer.

4. The triple cure fast drying polyurethane modified epoxy water permeable pavement adhesive according to claim 3, characterized in that, In the structure of general formula (1) of the A component, the diisocyanate monomer is selected from any one or a combination of at least two of dicyclohexylmethane diisocyanate, isophorone diisocyanate and hexamethylene diisocyanate; The polyether polyol is selected from polypropylene oxide glycol and / or polytetrahydrofuran diol, with a number average molecular weight of 400-2000; The fluorine-containing hydroxyl acrylate monomer is selected from hexafluorobutyl methacrylate and / or hexafluoroisopropyl methacrylate.

5. The triple curable fast drying polyurethane modified epoxy water permeable pavement adhesive according to claim 1, characterized in that, The fluorine-containing polyurethane acrylic oligomer is prepared by reacting the diisocyanate monomer, the polyether polyol and the fluorine-containing hydroxyl acrylate monomer at 40-80℃ for 3-9h.

6. The triple cure fast drying polyurethane modified epoxy water permeable pavement adhesive according to claim 5, characterized in that, The reaction time is 4-8h.

7. The triple cure fast drying polyurethane modified epoxy water permeable pavement adhesive according to claim 5, characterized in that, The mass ratio of the diisocyanate monomer, the polyether polyol and the fluorine-containing hydroxyl acrylate monomer is 1:0.5-5:0.2-0.

5.

8. The triple cure fast drying polyurethane modified epoxy water permeable pavement adhesive according to claim 7, characterized in that, The mass ratio of the diisocyanate monomer, the polyether polyol and the fluorine-containing hydroxyl acrylate monomer is 1:0.7-2:0.3-0.

4.

9. The triple curable fast drying polyurethane modified epoxy water permeable pavement adhesive according to claim 5, characterized in that, The reaction is carried out in the presence of a catalyst, and the catalyst is dibutyltin dilaurate.

10. The triple cure fast drying polyurethane modified epoxy water permeable pavement adhesive according to claim 9, characterized in that, The amount of the catalyst is 10-50ppm based on the mass of the polyether polyol.

11. The triple cure fast drying polyurethane modified epoxy water permeable pavement adhesive as claimed in claim 1, wherein, In the B component, the epoxy equivalent weight EEW of the bisphenol A type epoxy resin is 170-190; and / or The mass ratio of the bisphenol A type epoxy resin to glycidyl methacrylate is 1:0.2-0.

5.

12. The triple cure fast drying polyurethane modified epoxy water permeable pavement adhesive according to claim 11, characterized in that, In the B component, the epoxy equivalent weight EEW of the bisphenol A type epoxy resin is 175-185.

13. The triple cure fast drying polyurethane modified epoxy water permeable pavement adhesive according to claim 11, wherein, The mass ratio of the bisphenol A type epoxy resin to glycidyl methacrylate is 1:0.25-0.

4.

14. The triple cure fast drying polyurethane modified epoxy water permeable pavement adhesive as claimed in claim 1, wherein, In the C component, the polyether amine is selected from amino-terminated polyoxypropylene ether and / or amino-terminated polyoxyethylene ether; and / or The active diluent is selected from any one or a combination of at least two of tripropylene glycol diacrylate, 1,6-hexanediol diacrylate, dipropylene glycol diacrylate, trimethylolpropane triacrylate and pentaerythritol triacrylate; and / or The photoinitiator is fluorinated titanocene dibenzyl; and / or The short carbon fiber has a fiber length ranging from 1 to 3 cm and a diameter of 5-8μm; and / or The mass ratio of the polyether amine, the active diluent, the photoinitiator and the short carbon fiber is 1:0.4-0.7:0.1-0.5:0.1-0.

4.

15. The triple cure fast drying polyurethane modified epoxy water permeable pavement adhesive according to claim 14, characterized in that, The molecular weight of the polyether amine ranges from 200 to 400.

16. The triple cure fast drying polyurethane modified epoxy watercure pavement adhesive according to claim 15, characterized in that, The molecular weight of the polyether amine ranges from 200 to 250.

17. The triple cure fast drying polyurethane modified epoxy watercure pavement adhesive as claimed in claim 14, wherein, The fiber length of the chopped carbon fiber is 2 cm and the diameter is 5 μm.

18. The triple cure fast drying polyurethane modified epoxy watercure pavement adhesive as claimed in claim 14, wherein, The model of the chopped carbon fiber is T300.

19. The triple cure fast drying polyurethane modified epoxy watercure pavement adhesive as claimed in claim 14, wherein, The mass ratio of the polyether amine, the active diluent, the photoinitiator and the chopped carbon fiber is 1:0.5-0.65:0.2-0.4:0.15-0.

25.

20. A process for the preparation of a triple cure fast drying polyurethane modified epoxy water permeable pavement adhesive according to any one of claims 1 to 19, characterized by, The steps include: 1) preparing component A, standby; 2) preparing component B: stirring and mixing the bisphenol A type epoxy resin and the glycidyl methacrylate uniformly, standby; 3) preparing component C: stirring and mixing the polyether amine, the active diluent, the photoinitiator and the chopped carbon fiber uniformly, standby; 4) when used, mixing components A, B and C uniformly to obtain the triple-cured quick-drying polyurethane modified epoxy water-permeable pavement adhesive.

21. A pervious cementitious paving material, characterized by, The raw materials include the triple-cured quick-drying polyurethane modified epoxy water-permeable pavement adhesive according to any one of claims 1-19 or the triple-cured quick-drying polyurethane modified epoxy water-permeable pavement adhesive prepared by the method according to claim 20.

22. The pervious cementitious paving material of claim 21, wherein, The mass content of the triple-cured quick-drying polyurethane modified epoxy water-permeable pavement adhesive is 2-7%, based on the total mass of the water-permeable adhesive stone pavement material being 100%.

23. The pervious cementitious paving material of claim 22, wherein, The mass content of the triple-cured quick-drying polyurethane modified epoxy water-permeable pavement adhesive is 3-5%, based on the total mass of the water-permeable adhesive stone pavement material being 100%.

24. The pervious cementitious paving material of claim 21, wherein, The raw material weight parts composition includes: 93-98 parts of stone; 2-7 parts of the triple-cured quick-drying polyurethane modified epoxy water-permeable pavement adhesive.

25. The pervious cementitious paving material of claim 24, wherein, The raw material weight parts composition includes: 95-97 parts of stone; 3-5 parts of the triple-cured quick-drying polyurethane modified epoxy water-permeable pavement adhesive.

26. A method of constructing a pervious cementitious paving material as defined in any one of claims 21 to 25, wherein the step of It includes: First, mixing the above components A, B and C uniformly to obtain the triple-cured quick-drying polyurethane modified epoxy water-permeable pavement adhesive, then fully mixing the adhesive with the stone, laying on the pavement to be constructed, and then irradiating and curing the surface with the ultraviolet light equipment.

27. The method of constructing a pervious cementitious paving material of claim 26, wherein, The irradiation power of the ultraviolet light equipment is 6-8 w.

28. The method of claim 26, wherein the pervious cementitious paving material is constructed by: A handheld long-wave ultraviolet lamp is used.

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