Cement clinker calcination mineralization dissolution aid and preparation method thereof

By using cement clinker to calcinate mineral melting additives, the abrasiveness of raw materials and the strength of clinker are improved, and the problem of high energy consumption in cement production is solved, and the efficiency of raw materials grinding and clinker strength is improved, with significant energy-saving and consumption-reducing effects.

CN117326812BActive Publication Date: 2025-08-22ANHUI CONCH DESIGN & RES INST OF BUILDING MATERIALS CO LTD +1
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Patent Information

Application Number
CN202311223267.2
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2023-09-21
Publication Date
2025-08-22
Estimated Expiration
2043-09-21

AI Technical Summary

Technical Problem

In the cement clinker production process, the energy consumption of raw material grinding and clinker calcining processes is high. How to reduce power and coal consumption, improve the abrasiveness of raw material and the strength of clinker.

Method used

A cement clinker calcined mineral melting aid is used, which consists of surfactant, grinding aid and mineral melting agent. By improving the dispersion and abrasionability of raw materials, the mineral eutectic point temperature is reduced, the solid phase reaction is promoted to generate high-strength calcium phosphate minerals, and the grinding efficiency and clinker strength are improved.

Benefits of technology

Effectively reduce the power consumption of raw material powder grinding, improve the grinding efficiency of the mill, reduce the liquid phase formation temperature of clinker, increase the strength of clinker, achieve energy saving and consumption reduction, improve the burnability of raw material, and reduce production costs.

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Abstract

The invention discloses a cement clinker calcining mineralization dissolving aid and a preparation method thereof. The cement clinker calcining mineralization dissolving aid is composed of the following raw materials in percentage by weight: a first surfactant: 5-10%; a second surfactant: 5-8%; a third surfactant: 1-3%; a grinding aid: 10-15%; a mineralization dissolving agent: 20%-40%; an ether emulsifier: 0.05%-3.0%; and the remainder is water. The mineralization dissolving aid can improve the dispersion degree of the raw material and improve the grindability of the raw material. At the same time, it plays a mineralization role in the clinker calcining process, reduces the eutectic temperature of the mineral, and can reduce the clinker firing temperature to a certain extent. In addition, the mineralization dissolving aid of the invention participates in a solid-phase reaction, and the generated product significantly improves the clinker strength. By using the mineralization dissolving aid of the invention, a good energy-saving and consumption-reducing effect can be achieved.
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Description

Technical Field

[0001] The invention belongs to the technical field of energy conservation, emission reduction and environmental protection in cement production, and particularly relates to a cement clinker calcination mineralization melting aid and a preparation method thereof. Background Art

[0002] Cement is a key infrastructure material in my country. Its primary raw materials are limestone, sandstone, iron ore, and shale, and coal is typically used as fuel. Based on the three-ratio principle for clinker, raw materials are blended according to specific proportions. After raw material grinding, they are then calcined in a cement kiln system to produce clinker. The "two grindings, one calcination" process for cement clinker production consumes significant amounts of energy and resources. In the context of promoting ecological progress, cement clinker production must prioritize energy conservation, consumption reduction, low carbon emissions, and environmental protection, pursuing sustainable development through green production.

[0003] In the cement clinker production process, the raw meal grinding and clinker calcining processes account for the largest proportion of energy consumption. The raw meal grinding process generally consumes 15kwh / t of raw meal, and the clinker process consumes 45-50kwh / t of clinker. After the raw meal process is converted into tons of clinker, the electricity consumption accounts for about 50% of the electricity consumption per ton of clinker; the clinker calcining process generally consumes 100-130kgce / t of coal per ton of clinker.

[0004] How to design grinding and melting aids according to the quality of raw materials, reduce the power consumption of the raw material process, promote the formation of clinker minerals, and reduce the coal consumption of the firing system is an urgent need for energy conservation and consumption reduction in the current clinker production line. Summary of the Invention

[0005] To solve the above technical problems, the present invention provides a cement clinker calcination mineralization dissolution aid and a preparation method thereof. The mineralization dissolution aid can improve the dispersion degree of the raw material and improve the grindability of the raw material. At the same time, it plays a mineralization role in the clinker calcination process, reduces the eutectic temperature of the mineral, and can reduce the clinker firing temperature to a certain extent. In addition, the mineralization dissolution aid of the present invention participates in the solid-phase reaction, and the generated product significantly improves the clinker strength. By using the mineralization dissolution aid of the present invention, it can achieve a good energy-saving and consumption-reducing effect.

[0006] The technical solution adopted by the present invention is as follows:

[0007] A cement clinker calcination mineralization dissolution aid, the cement clinker calcination mineralization dissolution aid is composed of the following raw materials in percentage by weight:

[0008] First surfactant: 5-10%;

[0009] Second surfactant: 5-8%;

[0010] Third surfactant: 1-3%;

[0011] Grinding aid: 10-15%;

[0012] Mineralizing dissolving agent: 20%-40%;

[0013] Ether emulsifier: 0.05%-3.0%;

[0014] The rest is water;

[0015] The first surfactant is a lignin derivative;

[0016] The second surfactant is a glyceride substance;

[0017] The third surfactant is an organic polymer or its sodium salt.

[0018] The first surfactant is any one or more of sodium lignin sulfonate, calcium lignin sulfonate, nitrated lignin, and halogenated lignin.

[0019] The second surfactant is any one or more of glyceryl tristearate, glyceryl monooleate, and glyceryl trilaurate.

[0020] The third surfactant is any one or more of polyacrylic acid sodium salt, polyacrylamide, and polyvinyl alcohol.

[0021] The grinding aid is any one or more of triethanolamine, triisopropanolamine, diethanol monoisopropanolamine, ethylene glycol, and diethylene glycol.

[0022] The mineralization dissolving agent is a mixture of phosphate, phosphomolybdic acid and fluorite powder.

[0023] In the mineralizing dissolving agent, the mass proportion of phosphate and phosphomolybdic acid is 70%-90%, and the mass proportion of fluorite powder is 10%-30%, wherein the optimal weight ratio of phosphate, phosphomolybdic acid and fluorite powder is 4:4:2.

[0024] The phosphate is any one or more of disodium hydrogen phosphate, potassium dihydrogen phosphate, and trisodium phosphate.

[0025] The ether emulsifier is any one or two of lauryl alcohol polyoxyethylene ether and fatty alcohol polyoxyethylene ether.

[0026] The present invention also provides a method for preparing the cement clinker calcination mineralization dissolution aid, which comprises the following steps:

[0027] 1) adding a mineralizing dissolving agent, a first surfactant, a third surfactant, and a grinding aid to half of the water in sequence, dissolving each substance and stirring uniformly to obtain a first mixed solution;

[0028] 2) Preparation of a second mixed solution: dissolving a second surfactant and an ether emulsifier in the other half of the water, and then emulsifying and mixing them uniformly using a high-speed shear emulsifier to obtain a second mixed solution;

[0029] 3) The first mixed solution and the second mixed solution are mixed, and added into a high-speed shear emulsifier for emulsification and uniform mixing to obtain the cement clinker calcination mineralization dissolution aid.

[0030] In the raw materials of the cement clinker calcination mineralization melting aid provided by the present invention, the glycerol ester substance as the second surfactant can be adsorbed on the particle surface of the raw material when the raw material is ground in the vertical mill, reducing the agglomeration between the material powders, and at the same time effectively reducing the resistance between the material and the grinding roller, reducing the fineness of the raw material, and improving the grinding efficiency of the mill; the third surfactant, such as the acrylate substance, can stabilize the vertical mill abrasive layer, thereby increasing the grinding roller pressure and improving the grinding efficiency; the added grinding aid component can improve the powder selection efficiency of the vertical mill powder classifier, further improve the grinding efficiency and reduce energy consumption; the mineralizing flux can, on the one hand, reduce the clinker calcination eutectic point and reduce the firing temperature, and on the other hand, it can react with calcium to form high-strength calcium phosphate minerals, thereby improving the clinker strength; the ether emulsifier mainly has a dispersing effect on the mineralizing flux, especially on the dispersing effect on the fluorite powder, and the prepared product is uniform, stable and non-stratified.

[0031] In addition, the various components in the cement clinker calcination mineralization dissolution aid provided by the present invention can produce a synergistic superposition effect while each playing its own individual role. For example, during the grinding process, the surfactant and the grinding aid complement each other in stabilizing the material layer, and these substances will also burn themselves during the subsequent clinker calcination process and generate calorific value, further playing a role in saving coal.

[0032] Compared with the prior art, the present invention has the following beneficial effects:

[0033] (1) The cement clinker calcination mineralization dissolution aid of the present invention can effectively improve the grindability of difficult-to-grind materials, stabilize the vertical mill abrasive layer, reduce the fineness of raw materials, improve the grinding efficiency of the mill, and reduce the power consumption of grinding.

[0034] (2) The cement clinker calcination mineralization dissolution aid of the present invention can reduce the formation temperature of the clinker liquid phase and promote the formation of minerals.

[0035] (3) The mineralizing agent in the cement clinker calcining mineralizing dissolving aid of the present invention is a mixture of phosphate, fluorite powder and phosphomolybdic acid in a certain proportion. Under the catalytic oxidation of phosphomolybdic acid, the phosphate is dehydrated to generate a large molecular structure polyphosphoric acid, and coupled with glycerol to generate phosphoglyceride with better penetration and diffusion effects, which has a better grinding aid effect. After the phosphate, phosphomolybdic acid and fluorite powder enter the firing system, they can promote the dehydration reaction of carbonate minerals in the raw material at high temperature, reduce energy consumption, and at the same time, they can react with the calcium, silicon and aluminum components in the raw material in a solid phase to generate calcium phosphate salts, while promoting the solid solution of MgO, increasing the strength of the clinker, reducing the liquid phase formation temperature, and reducing energy consumption.

[0036] (4) The cement clinker calcination mineralization dissolution aid of the present invention is a uniform and stable liquid product, and its incorporation ratio in the raw material is 0.5-1.0‰. The incorporation amount is relatively low, and it is convenient for use in production.

[0037] (5) The cement clinker calcination mineralization dissolution aid of the present invention has a wide adaptability and can increase the utilization ratio of difficult-to-grind materials. Without increasing equipment investment, the developed cement clinker calcination mineralization dissolution aid can effectively increase the fineness or output of raw materials, improve the burnability of raw materials, promote mineral formation, and significantly save coal and reduce consumption, reduce clinker production costs, and improve clinker product quality, with significant economic and social benefits. DETAILED DESCRIPTION

[0038] The present invention is described in detail below with reference to the embodiments.

[0039] Example 1

[0040] A cement clinker calcining mineralization dissolution aid is composed of the following raw materials in percentage by weight: 10% calcium lignin sulfonate, 8% glyceryl tristearate, 3% sodium polyacrylate, 10% triethanolamine, 30% mineralization dissolving agent, 2% fatty alcohol polyoxyethylene ether, and the balance being water; wherein the mineralization dissolving agent is composed of disodium hydrogen phosphate, phosphomolybdic acid, and fluorite powder in a weight ratio of 4:4:2.

[0041] The preparation method of the cement calcination mineralization dissolution aid comprises the following steps:

[0042] 1) Weigh each component by weight and divide the weighed water into 2 parts;

[0043] 2) Preparation of a first mixed solution: adding calcium lignin sulfonate, glyceryl tristearate, a mineralizing solvent, and triethanolamine to the weighed first portion of water, dissolving each substance and stirring uniformly to obtain a first mixed solution;

[0044] 3) Preparation of a second mixed solution: dissolving sodium polyacrylate and fatty alcohol polyoxyethylene ether in a second portion of water, and emulsifying and mixing them uniformly using a high-speed shear emulsifier to obtain a second mixed solution;

[0045] 4) After the first mixed solution and the second mixed solution are mixed evenly, they are added into a high-speed shear emulsifier and emulsified and mixed evenly again to obtain a cement clinker calcination mineralization dissolution aid.

[0046] Example 2

[0047] A cement clinker calcining mineralization dissolution aid is composed of the following raw materials in percentage by weight: 5% nitrated lignin, 5% trilaurin, 3% sodium polyacrylate, 10% triisopropanolamine, 40% mineralization dissolution agent, 2% fatty alcohol polyoxyethylene ether, and the balance being water; wherein the mineralization dissolution agent is composed of potassium dihydrogen phosphate, phosphomolybdic acid, and fluorite powder in a weight ratio of 4:4:2.

[0048] The preparation method of the cement clinker calcination mineralization dissolution aid comprises the following steps:

[0049] 1) Weigh each component by weight and divide the weighed water into 2 parts;

[0050] 2) Preparation of a first mixed solution: adding nitrated lignin, trilaurin, a mineralizing solvent, and triisopropanolamine to the weighed first portion of water, dissolving each substance and stirring uniformly to obtain a first mixed solution;

[0051] 3) Preparation of a second mixed solution: dissolving sodium polyacrylate and fatty alcohol polyoxyethylene ether in a second portion of water, and emulsifying and mixing them uniformly using a high-speed shear emulsifier to obtain a second mixed solution;

[0052] 4) After the first mixed solution and the second mixed solution are uniformly mixed, they are added into a high-speed shear emulsifier and emulsified and mixed again to obtain the cement clinker calcination mineralization dissolution aid of the present invention.

[0053] Example 3

[0054] A cement clinker calcining mineralization dissolution aid is composed of the following raw materials in percentage by weight: 10% nitrated lignin, 8% trilaurin, 3% sodium polyacrylate, 15% triethanolamine, 20% mineralization dissolution agent, 2% fatty alcohol polyoxyethylene ether, and the balance being water; wherein the mineralization dissolution agent is composed of trisodium phosphate, phosphomolybdic acid, and fluorite powder in a weight ratio of 4:4:2.

[0055] The preparation method of the cement clinker calcination mineralization dissolution aid comprises the following steps:

[0056] 1) Weigh each component by weight and divide the weighed water into 2 parts;

[0057] 2) Preparation of a first mixed solution: adding nitrated lignin, trilaurin, a mineralizing solvent, and triethanolamine to the weighed first portion of water, dissolving each substance and stirring uniformly to obtain a first mixed solution;

[0058] 3) Preparation of a second mixed solution: dissolving sodium polyacrylate and fatty alcohol polyoxyethylene ether 2 in a second portion of water, and emulsifying and mixing them uniformly using a high-speed shear emulsifier to obtain a second mixed solution;

[0059] 4) After the first mixed solution and the second mixed solution are uniformly mixed, they are added into a high-speed shear emulsifier and emulsified and mixed again to obtain the cement clinker calcination mineralization dissolution aid of the present invention.

[0060] Comparative Example 1

[0061] A cement clinker calcination mineralization dissolution aid, comprising the following raw materials in percentage by weight: 20% nitrated lignin, 10% trilaurin, 3% sodium polyacrylate, 25% triethanolamine, 3% fatty alcohol polyoxyethylene ether, and the balance being water;

[0062] The preparation method of the cement clinker calcination mineralization dissolution aid comprises the following steps:

[0063] 1) Weigh each component by weight and divide the weighed water into 2 parts;

[0064] 2) Preparation of a first mixed solution: adding nitrated lignin, trilaurin, and triethanolamine to the weighed first portion of water, dissolving each substance and stirring uniformly to obtain a first mixed solution;

[0065] 3) Preparation of a second mixed solution: dissolving sodium polyacrylate and fatty alcohol polyoxyethylene ether in a second portion of water, and emulsifying and mixing them uniformly using a high-speed shear emulsifier to obtain a second mixed solution;

[0066] 4) After the first mixed solution and the second mixed solution are uniformly mixed, they are added into a high-speed shear emulsifier and emulsified and mixed again to obtain the cement clinker calcination mineralization dissolution aid of the present invention.

[0067] Comparative Example 2

[0068] A cement clinker calcination mineralization dissolution aid is composed of the following raw materials in percentage by weight: 35% nitrated lignin, 10% trilaurin, 3% sodium polyacrylate, 10% triethanolamine, 1% fatty alcohol polyoxyethylene ether, and the balance being water.

[0069] The preparation method of the cement clinker calcination mineralization dissolution aid comprises the following steps:

[0070] 1) Weigh each component by weight and divide the weighed water into 2 parts;

[0071] 2) Preparation of a first mixed solution: adding nitrated lignin, trilaurin, and triethanolamine to the weighed first portion of water, dissolving each substance and stirring uniformly to obtain a first mixed solution;

[0072] 3) Preparation of a second mixed solution: dissolving sodium polyacrylate and fatty alcohol polyoxyethylene ether 2 in a second portion of water, and emulsifying and mixing them uniformly using a high-speed shear emulsifier to obtain a second mixed solution;

[0073] 4) After the first mixed solution and the second mixed solution are uniformly mixed, they are added into a high-speed shear emulsifier and emulsified and mixed again to obtain the cement clinker calcination mineralization dissolution aid of the present invention.

[0074] Comparative Example 3

[0075] A cement clinker calcining mineralization dissolution aid is composed of the following raw materials in percentage by weight: 10% calcium lignin sulfonate, 8% glyceryl tristearate, 3% sodium polyacrylate, 10% triethanolamine, 30% mineralization dissolving agent, 2% fatty alcohol polyoxyethylene ether, and the balance being water; wherein the mineralization dissolving agent is composed of disodium hydrogen phosphate and fluorite powder in a weight ratio of 8:2.

[0076] The preparation method of the cement calcination mineralization dissolution aid comprises the following steps:

[0077] 1) Weigh each component by weight and divide the weighed water into 2 parts;

[0078] 2) Preparation of a first mixed solution: adding calcium lignin sulfonate, glyceryl tristearate, a mineralizing solvent, and triethanolamine to the weighed first portion of water, dissolving each substance and stirring uniformly to obtain a first mixed solution;

[0079] 3) Preparation of a second mixed solution: dissolving sodium polyacrylate and fatty alcohol polyoxyethylene ether in a second portion of water, and emulsifying and mixing them uniformly using a high-speed shear emulsifier to obtain a second mixed solution;

[0080] 4) After the first mixed solution and the second mixed solution are mixed evenly, they are added into a high-speed shear emulsifier and emulsified and mixed evenly again to obtain a cement clinker calcination mineralization dissolution aid.

[0081] Comparative Example 4

[0082] A cement clinker calcining mineralization dissolution aid is composed of the following raw materials in percentage by weight: 10% nitrated lignin, 8% trilaurin, 10% sodium polyacrylate, 15% triisopropanolamine, 10% mineralization dissolution agent, 2% fatty alcohol polyoxyethylene ether, and the balance being water; wherein the mineralization dissolution agent is composed of potassium dihydrogen phosphate, phosphomolybdic acid, and fluorite powder in a weight ratio of 4:4:2.

[0083] The preparation method of the cement clinker calcination mineralization dissolution aid comprises the following steps:

[0084] 1) Weigh each component by weight and divide the weighed water into 2 parts;

[0085] 2) Preparation of a first mixed solution: adding nitrated lignin, trilaurin, a mineralizing solvent, and triisopropanolamine to the weighed first portion of water, dissolving each substance and stirring uniformly to obtain a first mixed solution;

[0086] 3) Preparation of a second mixed solution: dissolving sodium polyacrylate and fatty alcohol polyoxyethylene ether in a second portion of water, and emulsifying and mixing them uniformly using a high-speed shear emulsifier to obtain a second mixed solution;

[0087] 4) After the first mixed solution and the second mixed solution are uniformly mixed, they are added into a high-speed shear emulsifier and emulsified and mixed again to obtain the cement clinker calcination mineralization dissolution aid of the present invention.

[0088] Test Case

[0089] The cement clinker calcination mineralization dissolution aids prepared in the examples and comparative examples were applied to raw meal grinding and calcination as follows, and compared with a comparative example without the aid. Grindability was tested according to GB / T 26567, "Test Method for Grindability of Cement Raw Materials," clinker strength was tested according to GB / T 17671, "Test Method for Strength of Cement Mortar (ISO) Method," and raw meal burnability was tested according to GB / T 26566, "Test Method for Burnability of Cement Raw Meal."

[0090] Experimental Test 1

[0091] The cement clinker calcination mineralization dissolution aids prepared in the examples and comparative examples were subjected to grinding tests in a Φ500mm×500mm standard test mill; the additive dosage was 0.1%, the material mass was 5kg, and the grinding time was 20 minutes. The test results of the fineness of the ground raw material are shown in Table 1.

[0092] Table 1 Raw material grinding effect (80μm sieve residue)

[0093] Test items blank Example 1 Example 2 Example 3 Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Fineness (%) 12.5 8.2 7.5 8.8 8.6 9.5 9.2 9.0

[0094] It can be seen from the test data in Table 1 that after using the cement clinker calcination mineralization dissolution aid prepared in each embodiment, the fineness of the raw meal is significantly reduced compared with the blank and comparative examples of the cement clinker calcination mineralization dissolution aid test within the same grinding time, and the 80 μm sieve residue of the raw meal can be reduced by 3.0 to 5.0 percentage points, indicating that the additive of the present invention has an excellent grinding aid effect.

[0095] Experimental Test 2

[0096] The cement clinker calcination mineralization dissolution aid prepared in each embodiment and comparative example was subjected to a calcination test in a muffle furnace to prepare clinker, and the mortar strength test was carried out after grinding. The results are shown in Table 2.

[0097] Table 2 Strength effect

[0098] Test items blank Example 1 Example 2 Example 3 Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 28d strength (MPa) 56 58.0 58.5 57.8 56.5 56.2 57.6 56.7

[0099] It can be seen from the test data in Table 2 that after using the cement clinker calcination mineralization dissolution aid prepared in each embodiment, under the same test conditions, the 28-day strength of the clinker can be effectively improved, and the strength can be increased by 2.3 to 2.9 percentage points relative to the blank group, indicating that the additive of the present invention has an excellent effect of improving strength. However, after using the cement clinker calcination mineralization dissolution aid prepared in the comparative example, the strength is not much improved relative to the blank group.

[0100] Experimental Test 3

[0101] The cement clinker calcination mineralization dissolution aids prepared in each embodiment and comparative example were subjected to a 1450°C sinterability test. The results are shown in Table 3.

[0102] Table 3 Burnability

[0103] Test items blank Example 1 Example 2 Example 3 Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 f-CaO (%) 2.5 1.5 1.0 1.8 2.3 2.4 2.0 2.1

[0104] The test data in Table 3 show that, under the same test conditions, the use of the cement clinker calcination mineralization dissolution aids prepared in each example significantly improved the burnability of the raw meal at 1450°C, and f-CaO decreased by 0.7 to 1.5 percentage points, demonstrating that the additives of the present invention have an excellent effect on improving the burnability of the raw meal. However, the use of the cement clinker calcination mineralization dissolution aid prepared in the comparative example did not significantly reduce f-CaO compared to the blank control.

[0105] In summary, the cement clinker calcination mineralization dissolution aid provided by the present invention is applied to raw material grinding, which can improve the grindability of the raw material, reduce the fineness of the raw material or increase the raw material output. At the same time, during the clinker calcination process, it reduces the temperature of the clinker liquid phase, promotes the formation of solid solutions of harmful substances such as magnesium oxide, improves the burnability of the raw material, and generates phosphate minerals, thereby increasing the strength of the clinker, thereby reducing costs, saving energy and protecting the environment, and having huge economic and social benefits.

[0106] The above-mentioned detailed description of a cement clinker calcination mineralization dissolution aid and a preparation method thereof with reference to the embodiments is illustrative rather than restrictive, and several embodiments can be listed according to the limited scope. Therefore, changes and modifications without departing from the overall concept of the present invention should fall within the scope of protection of the present invention.

Claims

1. A cement clinker calcination mineralization dissolution aid, characterized in that: The cement clinker calcination mineralization dissolution aid is composed of the following raw materials in percentage by weight: First surfactant: 5-10%; Second surfactant: 5-8%; Third surfactant: 1-3%; Grinding aid: 10-15%; Mineralizing dissolving agent: 20%-40%; Ether emulsifier: 0.05%-3.0%; The rest is water; The first surfactant is a lignin derivative; The second surfactant is a glyceride substance; The third surfactant is an organic polymer or its sodium salt; The mineralizing dissolving agent is a mixture of phosphate, phosphomolybdic acid and fluorite powder; In the mineralizing dissolving agent, the mass proportion of phosphate and phosphomolybdic acid is 70%-90%, and the mass proportion of fluorite powder is 10%-30%.

2. The cement clinker calcination mineralization dissolution aid according to claim 1, characterized in that: The first surfactant is any one or more of sodium lignin sulfonate, calcium lignin sulfonate, nitrated lignin, and halogenated lignin.

3. The cement clinker calcination mineralization dissolution aid according to claim 1, characterized in that: The second surfactant is any one or more of glyceryl tristearate, glyceryl monooleate, and glyceryl trilaurate.

4. The cement clinker calcination mineralization dissolution aid according to claim 1, characterized in that: The third surfactant is any one or more of polyacrylic acid sodium salt, polyacrylamide, and polyvinyl alcohol.

5. The cement clinker calcination mineralization dissolution aid according to claim 1, characterized in that: The grinding aid is any one or more of triethanolamine, triisopropanolamine, diethanol monoisopropanolamine, ethylene glycol, and diethylene glycol.

6. The cement clinker calcination mineralization dissolution aid according to claim 1, characterized in that: The phosphate is any one or more of disodium hydrogen phosphate, potassium dihydrogen phosphate, and trisodium phosphate.

7. The cement clinker calcination mineralization dissolution aid according to claim 1, characterized in that: The ether emulsifier is any one or two of lauryl alcohol polyoxyethylene ether and fatty alcohol polyoxyethylene ether.

8. The method for preparing the cement clinker calcination mineralization dissolution aid according to any one of claims 1 to 7, characterized in that: The preparation method comprises the following steps: 1) adding a mineralizing dissolving agent, a first surfactant, a third surfactant, and a grinding aid to half of the water in sequence, dissolving each substance and stirring uniformly to obtain a first mixed solution; 2) Preparation of Component B: Dissolve the second surfactant and the ether emulsion in the other half of the water, and then emulsify and mix them uniformly using a high-speed shear emulsifier to obtain a second mixed solution; 3) The first mixed solution and the second mixed solution are mixed, and added into a high-speed shear emulsifier for emulsification and uniform mixing to obtain the cement clinker calcination mineralization dissolution aid.

Citation Information

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