Water-based rolling fluid for rolling thread machine and preparation method thereof

By using water-based thread rolling fluid, the problems of flammability, volatility, and severe wear of lubricating media in thread rolling machines are solved, achieving safety, good heat dissipation, and wear resistance, while reducing transportation and usage costs.

CN117625298BActive Publication Date: 2026-02-06JIAXING SHUNCHENG FINE CHEM CO LTD
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Patent Information

Application Number
CN202311469200.7
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2023-11-07
Publication Date
2026-02-06
Estimated Expiration
2043-11-07

AI Technical Summary

Technical Problem

When existing thread rolling machines use machine oil or diesel as a lubricating medium, they have problems such as good heat dissipation but easy volatility, flammability, poor wear resistance, and easy to cause fire hazards, as well as serious wear on the mold.

Method used

Water-based thread rolling fluid is used, which is composed of water, various amine compounds, polymers and other additives to form a water-based lubricating coolant. It has functions such as antibacterial, anti-rust, lubrication and cation settling, and can replace traditional oil-based lubricating media.

Benefits of technology

It achieves zero oil mist generation, high safety, good heat dissipation, strong wear resistance, and can be diluted two to ten times for use, reducing transportation costs and extending service life.

✦ Generated by Eureka AI based on patent content.

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Abstract

A water-based rolling liquid suitable for a thread rolling machine and a preparation method thereof, the water-based rolling liquid is composed of water, diethyleneglycol amine, triethanolamine, triethanolamine borate, 2-amino-2-methyl-1-propanol, 2-methyl-2-methylamino-1-propanol, ethylenediaminetetraacetic acid disodium, 2,4,6-tris(aminohexanoic acid)-1,3,5-triazine, 2-methyl-3(2H)-isothiazolinone, 1,2-benzisothiazolyl-3(2H)-ketone, polydichloroethyl ether tetramethyl ethylenediamine, polyoxyethylene polyoxypropylene, and polyalkylene glycol monobutyl ether, the water-based rolling liquid is a water-based lubricating coolant, can be used by diluting two to ten times, saves transportation cost, can better complete heat dissipation work due to the specific heat of water being greater than that of oil, and does not volatilize aromatic organic gas during use, does not generate oil mist, reduces safety hazards, and additionally adds various amines to increase biological stability. The application also provides a preparation method of the water-based rolling liquid.
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Description

TECHNICAL FIELD

[0001] The present application relates to the technical field of thread rolling, in particular to a water-based thread rolling liquid suitable for a thread rolling machine and a preparation method thereof. BACKGROUND

[0002] A thread rolling machine is a device for processing threads on the outer part of a cylindrical or tubular metal piece, which can be divided into double-shaft and triple-shaft types. Specifically, thread rolling is a process in which a thread rolling die roller is installed on a thread rolling machine shaft, a workpiece is placed in the gap between the die rollers, and the thread rolling machine shafts are driven to rotate while being pulled close to each other by a hydraulic method, so that the workpiece clamped between the die roller gaps is rotated due to pressure to form threads on the surface. Since a large amount of heat is generated during thread rolling, a lubricating medium must be used. The lubricating medium provides lubrication and heat dissipation functions to ensure processing accuracy and die life. As is known, lubrication can reduce wear and heat generation, so a lubricating medium must be used to achieve the above purposes. In the prior art, low-viscosity media such as machine oil and diesel oil are commonly used for thread rolling. Although machine oil and diesel oil have good heat dissipation ability due to their low viscosity, they are also volatile due to their low viscosity, making it easier to absorb heat, thereby achieving better heat dissipation of the thread die. However, as is known, the temperature is very high during processing, which makes it easy for machine oil or diesel oil to produce oil smoke during use, and because diesel oil has a flash point lower than 90℃, it is a dangerous product that can easily cause a fire hazard. Most importantly, machine oil and diesel oil have poor wear resistance, which can easily cause die wear. SUMMARY

[0003] Therefore, the present application provides a water-based thread rolling liquid suitable for a thread rolling machine and a preparation method thereof, which can solve the above problems.

[0004] A water-based thread rolling fluid for a thread rolling machine is composed of water, diethanolamine, triethanolamine, triethanolamine borate, 2-amino-2-methyl-1-propanol, 2-methyl-2-methylamino-1-propanol, disodium ethylenediaminetetraacetate, 2,4,6-tris(amino hexanoic acid)-1,3,5-triazine, 2-methyl-3(2H)-isothiazolinone, 1,2-benzisothiazolyl-3(2H)-ketone, polydichloroethyl ether tetramethyl ethylenediamine, polyoxyethylene polyoxypropylene, and polyalkylene glycol monobutyl ether, wherein the water is 45.0-60.0 parts, the diethanolamine is 1.0-3.0 parts, the triethanolamine is 10.0-15.0 parts, the triethanolamine borate is 3.0-5.0 parts, the 2-amino-2-methyl-1-propanol is 0.1-0.5 parts, the 2-methyl-2-methylamino-1-propanol is 0.03-0.05 parts, the disodium ethylenediaminetetraacetate is 1.0-2.5 parts, the 2,4,6-tris(amino hexanoic acid)-1,3,5-triazine is 4.0-6.0 parts, the 2-methyl-3(2H)-isothiazolinone is 0.01-0.03 parts, the 1,2-benzisothiazolyl-3(2H)-ketone is 0.01-0.05 parts, the polydichloroethyl ether tetramethyl ethylenediamine is 0.01-0.05 parts, the polyoxyethylene polyoxypropylene is 10.0-20.0 parts, the polyalkylene glycol monobutyl ether is 3.0-5.5 parts, the 1,2,3-benzotriazole is 0.01-0.05 parts, and the phosphate ester is 1.0-3.5 parts, all based on 100 parts.

[0005] Further, when the workpiece or the metal working machine part contains copper, the water-based thread rolling fluid is added with the 1,2,3-benzotriazole.

[0006] Further, the 1,2,3-benzotriazole is 0.01-0.05 parts, based on 100 parts of the water-based thread rolling fluid.

[0007] Further, when the workpiece or the metal working machine part contains aluminum, the water-based thread rolling fluid is added with the phosphate ester.

[0008] Further, the phosphate ester is 1.0-3.5 parts, based on 100 parts of the water-based thread rolling fluid.

[0009] A method for preparing the water-based thread rolling fluid for a thread rolling machine includes the following steps:

[0010] STEP 101: Put 45.0-60.0 parts of water, 1.0-3.0 parts of diglycolamine, 10.0-15.0 parts of triethanolamine, 3.0-5.0 parts of triethanolamine borate, 0.03-0.05 parts of 2-amino-2-methyl-1-propanol, 0.01-0.03 parts of 2-methyl-2-methylamino-1-propanol, and 1.0-2.5 parts of disodium ethylenediaminetetraacetate into a reaction kettle to mix into an aqueous solution with pH 9.0-10.0, and determine that the powder has completely dissolved into a uniform lye;

[0011] STEP 102: Put 4.0-6.0 parts of powdered 2,4,6-tris(aminohexanoyl)-1,3,5-triazine into the reaction kettle to carry out a neutralization reaction with the lye in the previous step to form a triacid rust inhibitor, and completely dissolve the 2,4,6-tris(aminohexanoyl)-1,3,5-triazine;

[0012] STEP 103: Put 0.01-0.03 parts of the 2-methyl-3(2H)-isothiazolinone and 0.01-0.05 parts of the 1,2-benzisothiazolyl-3(2H)-ketone into the reaction kettle to form a liquid with bacteriostatic function;

[0013] STEP 104: Put 0.3-0.8 parts of the polydichloroethyl ether tetramethylethylenediamine to form a function of precipitating cations;

[0014] STEP 105: Put 10.0-20.0 parts of the polyoxyethylene polyoxypropylene to make the liquid have lubricating and inverse solubility properties to obtain the water-based thread rolling liquid suitable for a thread rolling machine.

[0015] Further, after STEP 105, it further includes STEP 106: adding 0.01-0.05 parts of the 1,2,3-benzotriazole and completely dissolving it to make the liquid have the function of inhibiting the oxidation of copper ions.

[0016] Further, after STEP 105, it further includes STEP 107: adding 1.0-3.5 parts of the phosphate ester to make the liquid have the function of preventing aluminum oxidation, and finally obtaining the water-based thread rolling liquid suitable for a thread rolling machine.

[0017] Further, in STEP 102, the triacid rust inhibitor formed is a carboxylic acid amine salt with carboxylate.

[0018] Compared with the prior art, the water-based rolling liquid for the rolling machine provided by the application uses water as the base lubricating and cooling liquid, can be used after being diluted by two to ten times, saves transportation cost, can better complete heat dissipation work due to the specific heat of water being greater than that of oil, does not volatilize aromatic organic gas during use, does not generate oil mist, reduces safety hazards, and is provided with extreme pressure lubricant and physical lubrication anti-wear agent, which solves the problems of die wear and inability to process deep lines in the prior art, and is provided with multiple amines to increase biological stability. DETAILED DESCRIPTION

[0019] The specific embodiments of the application are further described below. It should be understood that the description of the embodiments of the application herein is not intended to limit the protection scope of the application.

[0020] The water-based rolling liquid for the rolling machine provided by the application is composed of water, diethylene glycol amine, triethanolamine, triethanolamine borate, 2-amino-2-methyl-1-propanol, 2-methyl-2-methylamino-1-propanol, disodium ethylenediaminetetraacetate, 2,4,6-tris(amino hexanoic acid)-1,3,5-triazine, 2-methyl-3(2H)-isothiazolinone, 1,2-benzisothiazolyl-3(2H)-ketone, polydichloroethyl ether tetramethyl ethylenediamine, polyoxyethylene polyoxypropylene, polyalkylene glycol monobutyl ether, 1,2,3-benzotriazole, and phosphate ester.

[0021] In the water-based rolling liquid, the water is 45.0-60.0 parts, the diethylene glycol amine is 1.0-3.0 parts, the triethanolamine is 10.0-15.0 parts, the triethanolamine borate is 3.0-5.0 parts, the 2-amino-2-methyl-1-propanol is 0.1-0.5 parts, the 2-methyl-2-methylamino-1-propanol is 0.03-0.05 parts, the disodium ethylenediaminetetraacetate is 1.0-2.5 parts, the 2,4,6-tris(amino hexanoic acid)-1,3,5-triazine is 4.0-6.0 parts, the 2-methyl-3(2H)-isothiazolinone is 0.01-0.03 parts, the 1,2-benzisothiazolyl-3(2H)-ketone is 0.01-0.05 parts, the polydichloroethyl ether tetramethyl ethylenediamine is 0.01-0.05 parts, the polyoxyethylene polyoxypropylene is 10.0-20.0 parts, the polyalkylene glycol monobutyl ether is 3.0-5.5 parts, the 1,2,3-benzotriazole is 0.01-0.05 parts, and the phosphate ester is 1.0-3.5 parts, all based on 100 parts. It can be understood that each component above should be the prior art, and thus the properties and preparation methods of each component above should also be the prior art, which will not be described herein.

[0022] Since the water-based thread rolling fluid is a water-based product, and water-based products can breed microorganisms, the water-based product is made into a weak base system with various amines, i.e., diethanolamine and triethanolamine, so that the water-based product can reduce microbial activity and also has other functions of stabilizing water.

[0023] In addition, since 2,4,6-tris(aminohexanoic acid)-1,3,5-triazine needs to be reacted in a weak base aqueous solution to become a compound with rust prevention function, the diethanolamine and triethanolamine are also needed to make a weak base system. After 2,4,6-tris(aminohexanoic acid)-1,3,5-triazine is reacted in the weak base aqueous solution, a compound with rust prevention function is formed, so that the rolled screw can be prevented from being oxidized, achieving the function of preventing rust.

[0024] Calcium and magnesium ions are prone to form water stains on the surface of the processed metal, resulting in poor visual finish and easily accelerating the occurrence of rust, so the formula needs to have chelation function to prevent calcium and magnesium ions from forming water stains. In addition, since water-based products are prone to cause microbial breeding problems during use due to improper operation or the entry of foreign objects, the product needs to have antibacterial function to extend the service life of the product. Therefore, by adding disodium ethylenediaminetetraacetate, the metal cations in the water-based thread rolling fluid can be chelated, and since disodium ethylenediaminetetraacetate has the property of damaging the cell membrane of bacteria, it is toxic to bacteria, so by adding disodium ethylenediaminetetraacetate, the growth of bacteria can be slowed down, thereby achieving the functions of preventing water stains and inhibiting bacteria, and further avoiding the formation of water stains on the surface of the processed metal and extending the service life of the water-based thread rolling fluid. Since water-based products are prone to cause microbial breeding problems during use due to improper operation or the entry of foreign objects, microorganisms can make the water-based thread rolling fluid acidic, so the product needs to have antibacterial function to extend the service life of the product. Because the heterocyclic active part of isothiazolinone can block the bond between DNA and protein of bacteria or algae when it contacts them, they cannot reproduce, so by adding 2-methyl-3(2H)-isothiazolinone and 1,2-benzisothiazolyl-3(2H)-ketone, respectively, to inhibit bacteria and mold, the service life of the water-based thread rolling fluid can be extended.

[0025] Since the aqueous product is prone to cause microbial breeding problems due to improper operation or foreign matter entering during use, the establishment of antibacterial function in the product can prolong the service life of the product. Therefore, when the pH is maintained at weak alkaline, the water body has good biological stability and bacteria are not easy to breed. In addition, the small residues after metal processing are easy to float on the liquid surface, and the cationic sedimentation can ensure the cleanliness of the liquid surface. The metal residues after sedimentation will accumulate at the bottom of the pool, and the liquid pump is not easy to extract metal debris, which can prevent damage to the liquid pump. In order to achieve the above purposes, by adding the polydichloroethyl ether tetramethyl ethylenediamine, the antibacterial and cationic sedimentation functions can be achieved. Polydichloroethyl ether tetramethyl ethylenediamine can affect the permeability of microbial cell wall, and microorganisms cannot exchange the required nutrients through the cell wall, so they will die, thereby reducing the breeding of microorganisms and inhibiting the generation of bacteria. The pH of 1% aqueous solution of polydichloroethyl ether tetramethyl ethylenediamine; polydichloroethyl ether tetramethyl ethylenediamine is a quaternary ammonium salt, and the general formula of quaternary ammonium salt is R4NX, X- is a negatively charged ion formed by replacing the four hydrogen atoms of the ammonium ion with hydrocarbon groups, so it can attract positively charged metal ions through X-. Since the metal processing is mostly iron, when polydichloroethyl ether tetramethyl ethylenediamine continuously absorbs iron ions for a long time, it can form large particle groups and precipitate at the bottom of the water tank, thereby achieving the function of cationic sedimentation.

[0026] The polyoxyethylene polyoxypropylene and the polyalkylene glycol monobutyl ether are main lubricants. By setting the blending ratio, the water-based thread rolling fluid has good lubricating performance and can improve the heat conduction performance of the water-based thread rolling fluid. Specifically, the polyoxyethylene polyoxypropylene is 10.0-20.0 parts. If the polyoxyethylene polyoxypropylene is less than 10 parts, the lubricating performance of the water-based thread rolling fluid will be greatly reduced. If the polyoxyethylene polyoxypropylene is more than 20 parts, the concentration of the polyoxyethylene polyoxypropylene will be too high, which may cause the equipment using the water-based thread rolling fluid to be stripped of paint, because the polyoxyethylene polyoxypropylene has a certain solubility. Of course, whether it will be stripped of paint still depends on the paint components on the equipment. The polyalkylene glycol monobutyl ether is 3.0-5.5 parts. If the polyalkylene glycol monobutyl ether is less than 3.0 parts, the lubricating performance of the water-based thread rolling fluid will be significantly reduced. If it is more than 5.5 parts, the polyalkylene glycol monobutyl ether cannot quickly dissolve into the water-based thread rolling fluid when it is dissolved in reverse, but is attached to the workpiece, which not only affects the subsequent process, but also requires cleaning, increasing the cost and possibly polluting the environment. The reverse solubility refers to the solubility being inversely proportional to the temperature. The polyalkylene glycol monobutyl ether has good reverse solubility. It can be well dissolved in water at room temperature, and will be precipitated from the water when the water temperature is increased. The polyalkylene glycol monobutyl ether is a viscous liquid at room temperature, and can increase the viscosity of water when dissolved in water. When the roller die and the workpiece generate heat during the thread rolling process, the polyalkylene glycol monobutyl ether can be dissolved in reverse in the water-based thread rolling fluid, coated on the surface of the roller die and the workpiece in the friction pair, and play a lubricating role, thereby reducing wear. When the heat of the friction pair is taken away by the water-based product, the substance is dissolved in the water-based thread rolling fluid.

[0027] Since the metal processing machine parts may contain copper, by adding the 1,2,3-benzotriazole, copper oxidation can be prevented.

[0028] Since the metal processing machine parts may contain aluminum, by adding the phosphate ester, aluminum oxidation can be prevented. At the same time, the phosphate ester can achieve the effects of smoothing the metal surface, increasing the extreme pressure lubrication at a certain temperature, such as 380-800°C. That is, the phosphorus compound can form a thin film of iron phosphate on the surface of the metal at 380-800°C, and the film has a lubricating effect, thereby reducing the probability of dry friction of the metal.

[0029] In addition, the water-based thread rolling fluid replaces the oil-based metal processing fluid, and has the characteristics of no oil smoke, no combustion, good heat dissipation, wear resistance, and high pressure resistance.

[0030] The application also provides a preparation method of the water-based thread rolling liquid suitable for a thread rolling machine, which comprises the following steps:

[0031] STEP 101: 45.0-60.0 parts of water, 1.0-3.0 parts of diglycolamine, 10.0-15.0 parts of triethanolamine, 3.0-5.0 parts of triethanolamine borate, 0.03-0.05 parts of 2-amino-2-methyl-1-propanol, 0.01-0.03 parts of 2-methyl-2-methylamino-1-propanol and 1.0-2.5 parts of disodium ethylenediaminetetraacetate are put into a reaction kettle to be mixed into an aqueous solution with a pH value of 9.0-10.0, and it is determined that the powders are completely dissolved into a uniform lye;

[0032] STEP 102: 4.0-6.0 parts of powdered 2,4,6-tris(aminohexanoyl)-1,3,5-triazine are put into the reaction kettle to be neutralized with the lye in the previous step to form a triacid rust inhibitor, and the 2,4,6-tris(aminohexanoyl)-1,3,5-triazine is completely dissolved;

[0033] STEP 103: 0.01-0.03 parts of 2-methyl-3(2H)-isothiazolinone and 0.01-0.05 parts of 1,2-benzisothiazolyl-3(2H)-ketone are put into the reaction kettle to form a liquid with bacteriostatic function;

[0034] STEP 104: 0.3-0.8 parts of polydichloroethyl ether tetramethyl ethylenediamine are put in to form a function of precipitating cations;

[0035] STEP 105: 10.0-20.0 parts of polyoxyethylene polyoxypropylene are put in to make the liquid have lubricating and inverse solubility characteristics;

[0036] STEP 106: 0.01-0.05 parts of 1,2,3-benzotriazole are added and completely dissolved to make the liquid have the function of inhibiting the oxidation of copper ions;

[0037] STEP 107: 1.0-3.5 parts of phosphate ester are added to make the liquid have the function of preventing aluminum oxidation, and finally the water-based thread rolling liquid suitable for a thread rolling machine is prepared.

[0038] In STEP 101, the pH value must be set between 9 and 10. If the pH value is less than 9, the 2,4,6-tris(aminohexanoyl)-1,3,5-triazine in STEP 102 will be dissolved very slowly, affecting the use of the product. If the pH value is greater than 10, it is easy to cause skin allergy of the operator during operation, and a high pH value may also cause damage to the sealing ring of the production equipment, which is not conducive to safe use.

[0039] In step STEP 102, the formed triacid rust preventive is a carboxylic acid amine salt with carboxylate.

[0040] In step STEP 104, the formed precipitable cation can precipitate the tiny metal residue formed after the processing of the metal floating on the liquid surface to ensure the liquid surface is clean, and the precipitated metal residue will be accumulated at the bottom of the pool, so that the metal debris can not be easily pumped by the liquid pump, thereby preventing the processing equipment from being damaged. Specific embodiments

[0042] Example 1: In the water-based rolling liquid, the water is 57.35 parts, the diglycol amine is 1.5 parts, the triethanolamine is 12 parts, the triethanolamine borate is 3.5 parts, the 2-amino-2-methyl-1-propanol is 0.2 parts, the 2-methyl-2-methylamino-1-propanol is 0.04 parts, the disodium ethylenediaminetetraacetate is 1.5 parts, the 2,4,6-tris(amino hexanoic acid)-1,3,5-triazine is 4.8 parts, the 2-methyl-3(2H)-isothiazolinone is 0.02 parts, the 1,2-benzisothiazolyl-3(2H)-ketone is 0.03 parts, the polydichloroethyl ether tetramethyl ethylenediamine is 0.03 parts, the polyoxyethylene polyoxypropylene is 14 parts, the polyalkylene glycol monobutyl ether is 3.5 parts, the 1,2,3-benzotriazole is 0.03 parts, and the phosphate is 1.5 parts, accounting for 100 parts.

[0043] Example 2: In the water-based rolling liquid, the water is 49.47 parts, the diglycol amine is 1.8 parts, the triethanolamine is 13 parts, the triethanolamine borate is 4.0 parts, the 2-amino-2-methyl-1-propanol is 0.4 parts, the 2-methyl-2-methylamino-1-propanol is 0.035 parts, the disodium ethylenediaminetetraacetate is 2 parts, the 2,4,6-tris(amino hexanoic acid)-1,3,5-triazine is 5.5 parts, the 2-methyl-3(2H)-isothiazolinone is 0.02 parts, the 1,2-benzisothiazolyl-3(2H)-ketone is 0.03 parts, the polydichloroethyl ether tetramethyl ethylenediamine is 0.03 parts, the polyoxyethylene polyoxypropylene is 16.0 parts, the polyalkylene glycol monobutyl ether is 4.5 parts, the 1,2,3-benzotriazole is 0.04 parts, and the phosphate is 2.5 parts, accounting for 100 parts.

[0044] Parameter table after testing compared with engine oil and diesel

[0045]

[0046]

[0047] In terms of dilution ratio, the water-based thread rolling fluid 1 part can be diluted up to 10 parts, which can save transportation costs.

[0048] In terms of flash point (ASTM D92), the flash point of the water-based thread rolling fluid is higher than that of No. 10 machine oil and diesel oil, which is safer.

[0049] In terms of cooling capacity (referring to ISO 9950), the water-based thread rolling fluid has better cooling capacity than No. 10 machine oil and diesel oil.

[0050] In terms of maximum non-seizure load (ASTM D2783), the water-based thread rolling fluid has better lubricating capacity.

[0051] In terms of extreme pressure value (ASTM D2783), the water-based thread rolling fluid has a higher sintering point, and the processing load is higher than that of No. 10 machine oil and diesel oil.

[0052] In terms of wear scar diameter (ASTM D2783), the wear degree of the water-based thread rolling fluid is about 12% less than that of No. 10 machine oil and diesel oil.

[0053] In terms of evaporation loss, the consumption of the water-based thread rolling fluid is about 50% of that of No. 10 machine oil and diesel oil.

[0054] Compared with the prior art, the water-based thread rolling fluid provided by the application is a water-based lubricating and cooling fluid suitable for thread rolling machines, which can be diluted by two to ten times for use, saving transportation costs. Since the specific heat of water is greater than that of oil, the water-based thread rolling fluid can better complete the heat dissipation work, and there is no aromatic organic gas volatilization and oil mist generation during use, reducing the safety hidden danger. In addition, the water-based thread rolling fluid is compounded with extreme pressure lubricant, physical lubricating anti-wear agent, which makes up for the problems of existing technology in mold wear and inability to process deep lines, and is compounded with various amines to increase biological stability.

[0055] The above is only a preferred embodiment of the application, and is not used to limit the protection scope of the application. Any modification, equivalent replacement or improvement within the spirit of the application is covered by the claim scope of the application.

Claims

1. A water-based thread rolling fluid suitable for use in a thread rolling machine, characterized in that: The water-based thread rolling liquid suitable for the thread rolling machine is composed of the following components, wherein, based on 100 parts of the water-based thread rolling liquid, water is 45.0-60.0 parts, diethyleneglycol amine is 1.0-3.0 parts, triethanolamine is 10.0-15.0 parts, triethanolamine borate is 3.0-5.0 parts, 2-amino-2-methyl-1-propanol is 0.1-0.5 parts, 2-methyl-2-methylamino-1-propanol is 0.03-0.05 parts, disodium ethylenediaminetetraacetate is 1.0-2.5 parts, 2,4,6-tris(amino hexanoic acid)-1,3,5-triazine is 4.0-6.0 parts, 2-methyl-3(2H)-isothiazolinone is 0.01-0.03 parts, 1,2-benzisothiazolyl-3(2H)-ketone is 0.01-0.05 parts, polydichloroethyl ether tetramethyl ethylenediamine is 0.01-0.05 parts, polyoxyethylene polyoxypropylene is 10.0-20.0 parts, polyalkylene glycol monobutyl ether is 3.0-5.5 parts, 1,2,3-benzotriazole is 0.01-0.05 parts, and phosphate is 1.0-3.5 parts. In the preparation of the water-based thread rolling liquid, STEP 101: water, diethyleneglycol amine, triethanolamine, triethanolamine borate, 2-amino-2-methyl-1-propanol, 2-methyl-2-methylamino-1-propanol, and disodium ethylenediaminetetraacetate are put into a reaction kettle to mix into an aqueous solution with pH 9.0-10.0, and it is determined that the powders are completely dissolved into a uniform lye; STEP 102: powdered 2,4,6-tris(amino hexanoic acid)-1,3,5-triazine is put into the reaction kettle to carry out a neutralization reaction with the lye formed in STEP 101 to form a triacid rust inhibitor, and the 2,4,6-tris(amino hexanoic acid)-1,3,5-triazine is completely dissolved; STEP 103: the 2-methyl-3(2H)-isothiazolinone and the 1,2-benzisothiazolyl-3(2H)-ketone are put into the reaction kettle to form a liquid with bacteriostatic function; STEP 104: the polydichloroethyl ether tetramethyl ethylenediamine is put in to form a function of precipitating cations; STEP 105: the polyoxyethylene polyoxypropylene is put in to make the liquid have lubricating and inverse solubility characteristics to obtain the water-based thread rolling liquid suitable for the thread rolling machine.

2. A preparation method of the water-based thread rolling liquid suitable for the thread rolling machine according to claim 1, comprising the following steps: STEP 101: water 45.0-60.0 parts, diethyleneglycol amine 1.0-3.0 parts, triethanolamine 10.0-15.0 parts, triethanolamine borate 3.0-5.0 parts, 2-amino-2-methyl-1-propanol 0.1-0.5 parts, 2-methyl-2-methylamino-1-propanol 0.03-0.05 parts, and disodium ethylenediaminetetraacetate 1.0-2.5 parts are put into a reaction kettle to mix into an aqueous solution with pH 9.0-10.0, and it is determined that the powders are completely dissolved into a uniform lye; STEP 102: 2,4,6-tris (aminohexanoic acid) -1,3,5-triazine 4.0-6.0 parts in powder form is put into the reaction kettle to carry out neutralization reaction with the alkali solution formed in STEP 101, forming a triacid rust inhibitor, and the 2,4,6-tris (aminohexanoic acid) -1,3,5-triazine is completely dissolved; STEP 103: 2-methyl-3 (2H) -isothiazolinone 0.01-0.03 parts and 1,2-benzisothiazolyl-3 (2H) -ketone 0.01-0.05 parts are put into the reaction kettle to form a liquid with bacteriostatic function; STEP 104: Polydichloroethyl ether tetramethyl ethylenediamine 0.01-0.05 parts is put in to form a function of precipitating cations; STEP 105: Polyoxyethylene polyoxypropylene 10.0-20.0 parts is put in to make the liquid have lubricating and inverse solubility characteristics to prepare a water-based thread rolling liquid suitable for a thread rolling machine.

3. The production method according to claim 2, characterized by: After STEP 105, STEP 106 is further included: 1,2,3-benzotriazole 0.01-0.05 parts is added and completely dissolved to make the liquid have the function of inhibiting the oxidation of copper ions.

4. The production method according to claim 2, characterized by: After STEP 105, STEP 107 is further included: the phosphate ester 1.0-3.5 parts is added to make the liquid have the function of preventing aluminum oxidation, and finally the water-based thread rolling liquid suitable for a thread rolling machine is prepared.

5. The production method according to claim 2, wherein: In STEP 102, the triacid rust inhibitor formed is a carboxylic acid amine salt with carboxylate.

Citation Information

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