A high-gloss mirror gloss film and its preparation process
By coating the substrate layer, radiation baking, mirror rolling and metal plating, the problem of low gloss of the mirror film caused by poor flatness of the substrate is solved, and the production of mirror films with high gloss and high yield is achieved.
Patent Information
- Application Number
- CN202410324612.X
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- Filing Date
- 2024-03-21
- Publication Date
- 2025-09-16
- Estimated Expiration
- 2044-03-21
AI Technical Summary
In the prior art, due to the poor surface flatness of the substrate, the glossiness of the produced mirror film is not high, and defects are easily generated when the color layer is coated, making it impossible to process a mirror film with higher glossiness.
The substrate flatness and coating thickness are improved through the process of unwinding, coating, radiation baking, mirror rolling, metal plating and protective coating of the substrate layer, including slot coating, multi-group infrared lamp baking, mirror roller rolling with a hardness of HRC56-HRC66, UV curing and two consecutive metal coatings, combined with the hardening layer of polyurethane acrylate resin and curtain coating silicone oil protection.
The high gloss and yield rate of the mirror film are achieved, scratches and crushing during the production process are reduced, and the aesthetics and stability of the mirror gloss film are improved.
Smart Images

Figure CN118305063B_ABST
Abstract
Description
Technical Field
[0001] The present invention relates to the technical field of decorative films, and in particular to a high-gloss mirror gloss film and a preparation process thereof. Background Art
[0002] With the development of building decoration materials, more and more research has been done on integrated wall panels. Integrated wall panels are mainly made of decorative films and base panels. The appearance of the decorative film determines the appearance of the integrated wall panels. In order to achieve the decorative effect of stainless steel mirrors, mirror films with mirror effects have been developed and prepared.
[0003] Currently, mirror film production primarily involves coating a color layer on the substrate surface and then metallizing the back of the substrate to create a reflective layer, resulting in mirror-like decorative films with varying colors. The substrate is primarily made of PET, but the untreated PET surface is not completely mirror-flat. Direct metallization will not achieve a high mirror gloss, and coating the color layer on the substrate surface will also result in imperfections in the color layer's flatness, making it impossible to produce a mirror film with a higher gloss. Therefore, improvements are needed. Summary of the Invention
[0004] The present invention addresses the defects in the prior art in that a mirror film with higher gloss cannot be produced due to poor surface flatness of the substrate when producing the mirror film, and provides a new high-gloss mirror gloss film and a preparation process thereof.
[0005] In order to solve the above technical problems, the present invention is achieved through the following technical solutions:
[0006] A process for preparing a high-gloss mirror-like gloss film comprises the following steps:
[0007] S1. Performing unwinding and coating operations on a substrate layer in sequence to obtain a mirror film semi-finished product with a coating primer layer. The substrate layer is made of PET, PMMA, PC, or ABS. During the coating operation, the coating speed is 7-20 m / min. The coating is a resin coating, which is composed of the following raw materials in parts by weight: 0-20 parts of a solvent, 0.5-2 parts of an initiator, and 60-80 parts of a polyurethane acrylate resin. The solvent is ethyl ester, butyl ester, or isopropyl butanone. The initiator is one or a mixture of the following: photoinitiator TPO, photoinitiator TPO_L, photoinitiator 184, photoinitiator 1173, or photoinitiator 907.
[0008] S2, performing radiation baking on the mirror film semi-finished product 1 to obtain a mirror film semi-finished product 2;
[0009] S3, performing mirror roller pressing and curing operations on the mirror film semi-finished product 2 to adjust the flatness of the coating base coating layer until the pressure values on the driving side and the operating side of the mirror roller are consistent, thereby obtaining a mirror film semi-finished product 3;
[0010] S4, performing a film application operation on the side of the mirror film semi-finished product 3 with the coating primer, performing a film rolling operation, and hanging and standing for 24 hours to obtain a mirror film semi-finished product 4;
[0011] S5, performing unwinding and film tearing operations on the mirror film semi-finished product 4, and performing metal coating operations twice on the side of the mirror film semi-finished product 4 with the coating primer layer, to obtain a mirror film semi-finished product 5 with a metal coating layer;
[0012] S6. Apply a protective coating to one side of the mirror film semi-finished product 5 having the metal coating layer, and apply a hardening layer to the other side of the mirror film semi-finished product 5 to obtain a high-gloss mirror gloss film with high-gloss mirror gloss.
[0013] The mirror rolling operation improves the defects and roughness of the substrate surface. The two consecutive metal plating operations make the coating thicker and denser, without pinholes, bubbles and other defects, so that the mirror gloss film has a higher gloss. The above steps protect the entire process of the mirror gloss film processing, reduce the occurrence of scratches and bruises on the mirror gloss film during the production process, and further improve the yield rate of the mirror gloss film.
[0014] Preferably, in the above-mentioned process for preparing a high-gloss mirror-finish film, a slit coating method is used when performing the coating operation in step S1.
[0015] Slit coating can be used to apply most resin coatings, for example, resin coatings without the addition of solvents can also be coated. Moreover, slit coating can accurately control the coating thickness and coating width.
[0016] Preferably, in the above-mentioned process for preparing a high-gloss mirror gloss film, in step S2, multiple groups of infrared lamps are used to radiation bake the mirror film semi-finished product, the radiation baking temperature is 50 degrees to 100 degrees, and the radiation baking time is 5 seconds to 20 seconds.
[0017] Radiation baking can not only accelerate the volatilization of the solvent, but also accelerate the self-leveling of the coating on the mirror film semi-finished product, thereby enhancing the mirror effect of the mirror film semi-finished product.
[0018] Preferably, in the above-mentioned process for preparing a high-gloss mirror gloss film, a mirror roller is used in step S3 to perform a mirror rolling operation on the mirror film semi-finished product 2, the surface of the mirror roller is made of hard chrome, and the hardness of the mirror roller is HRC56-HRC66.
[0019] The mirror roller is made of hard chrome with a hardness of HRC56-HRC66, which makes the mirror roller have super high wear resistance and super long service life; the mirror roller is used for mirror rolling operation to improve the glossiness of the mirror film semi-finished product.
[0020] Preferably, in the above-mentioned process for preparing a high-gloss mirror gloss film, in step S3, while performing the mirror rolling operation, a UV lamp is used to cure the mirror film semi-finished product 2, the curing temperature is 23 degrees to 55 degrees, and the curing time is 0.5 seconds to 1 second.
[0021] Carrying out UV curing operation at the same time as mirror rolling operation not only improves the production efficiency of mirror film, but also enables the semi-finished mirror film to be fully cured and meet the corresponding performance requirements; using UV lamp for curing operation has the advantages of environmental protection and high efficiency.
[0022] Preferably, in the above-mentioned process for preparing a high-gloss mirror-finished film, when the mirror-finished film semi-finished product 5 is subjected to a metal coating operation in step S5, the material of the metal coating is aluminum, silver or copper.
[0023] By selecting aluminum, silver or copper, mirror effects of different colors can be achieved, thereby improving the aesthetics of the mirror film.
[0024] Preferably, in the above-mentioned process for preparing a high-gloss mirror-finish film, in step S6, the protective coating is treated by flow coating with silicone oil; the hardening layer is made of polyurethane acrylate resin, and the coating speed of the hardening layer is 20 m / min-30 m / min.
[0025] The protective coating layer uses silicone oil to improve the smoothness of the metal coating surface and reduce the adhesion of dust and other substances to the metal coating surface. The hardening layer uses polyurethane acrylate resin with excellent temperature resistance, thermal stability, wear resistance and good adhesion, thereby improving the stability of the hardening layer fixed on the substrate layer and the protective effect on the substrate layer.
[0026] A high-gloss mirror-finish film is manufactured according to the above-mentioned preparation process of a high-gloss mirror-finish film, including a hardening layer, a substrate layer, a coating primer, a metal coating layer and a protective coating, wherein the hardening layer, substrate layer, coating primer, metal coating layer and protective coating are distributed from top to bottom.
[0027] The protective coating and the hardening layer improve the protection effect of the high-gloss mirror gloss film, and the coating primer improves the flatness of the substrate layer, making it easier to perform metal coating to obtain a metal coating layer with high gloss. BRIEF DESCRIPTION OF THE DRAWINGS
[0028] Figure 1It is a cross-sectional view of the high-gloss mirror gloss film of the present invention. DETAILED DESCRIPTION
[0029] The following is combined with Figure 1 The present invention is further described in detail with specific embodiments, but they are not intended to limit the present invention:
[0030] Example 1
[0031] A process for preparing a high-gloss mirror-like gloss film comprises the following steps:
[0032] S1. Performing unwinding and coating operations on a substrate layer 1 in sequence to obtain a mirror film semi-finished product 1 with a coating primer layer 2, wherein the substrate layer 1 is made of PET material, PMMA material, PC material, or ABS material;
[0033] During the coating operation, the coating speed is 7 m / min, and the coating is a resin coating, which is composed of the following raw materials in parts by weight: 0.5 parts of initiator, 60 parts of polyurethane acrylate resin, and the initiator is a photoinitiator TPO;
[0034] S2, performing radiation baking on the mirror film semi-finished product 1 to obtain a mirror film semi-finished product 2;
[0035] S3, performing mirror roller pressing and curing operations on the mirror film semi-finished product 2 to adjust the flatness of the coating base layer 2 until the pressure values on the driving side and the operating side of the mirror roller are consistent, thereby obtaining a mirror film semi-finished product 3;
[0036] S4, performing a film application operation on the side of the mirror film semi-finished product 3 with the coating primer 2, a winding operation, and hanging and standing for 24 hours to obtain a mirror film semi-finished product 4;
[0037] S5, performing unwinding and film tearing operations on the mirror film semi-finished product 4, and performing metal coating operations twice on the side of the mirror film semi-finished product 4 with the coating primer layer 2, to obtain a mirror film semi-finished product 5 with a metal coating layer 3;
[0038] S6. Apply a protective coating 4 to one side of the mirror film semi-finished product 5 having the metal coating layer 3, and apply a hardening layer 5 to the other side of the mirror film semi-finished product 5 to obtain a high-gloss mirror film with high-gloss mirror gloss.
[0039] Preferably, the coating operation in step S1 is performed by slit coating.
[0040] Preferably, in step S2, multiple groups of infrared lamps are used to perform radiation baking on the mirror film semi-finished product 1, the radiation baking temperature is 50 degrees, and the radiation baking time is 5 seconds.
[0041] Preferably, in step S3, a mirror roller is used to perform a mirror rolling operation on the mirror film semi-finished product 2, the surface of the mirror roller is made of hard chrome, and the hardness of the mirror roller is HRC56.
[0042] Preferably, in step S3, while performing the mirror rolling operation, a UV lamp is used to perform a curing operation on the mirror film semi-finished product 2, the curing temperature is 23 degrees, and the curing time is 0.5 seconds.
[0043] Preferably, when the mirror film semi-finished product 5 is subjected to metal coating in step S5, the material of the metal coating is aluminum, silver or copper.
[0044] Preferably, in step S6, the protective coating 4 is treated by flow coating with silicone oil; the hardening layer 5 is made of polyurethane acrylate resin, and the coating speed of the hardening layer 5 is 20 m / min.
[0045] A high-gloss mirror gloss film includes a hardening layer 5, a substrate layer 1, a coating primer 2, a metal coating layer 3, and a protective coating 4. The hardening layer 5, substrate layer 1, coating primer 2, metal coating layer 3, and protective coating 4 are arranged from top to bottom. The cross-sectional view of the high-gloss mirror gloss film is as follows: Figure 1 shown.
[0046] In step S5 , metal plating is performed in two positions, upper and lower. Through two consecutive metal platings, the metal plating layer 3 is thicker and denser, and the mirror effect is better.
[0047] Example 2
[0048] A process for preparing a high-gloss mirror-like gloss film comprises the following steps:
[0049] S1. Performing unwinding and coating operations on a substrate layer 1 in sequence to obtain a mirror film semi-finished product 1 with a coating primer layer 2, wherein the substrate layer 1 is made of PET material, PMMA material, PC material, or ABS material;
[0050] During the coating operation, the coating speed is 20 m / min, and the coating is a resin coating, which is composed of the following raw materials in parts by weight: 20 parts of solvent, 2 parts of initiator, and 80 parts of polyurethane acrylate resin, wherein the solvent is ethyl ester and the initiator is photoinitiator TPO_L;
[0051] S2, performing radiation baking on the mirror film semi-finished product 1 to obtain a mirror film semi-finished product 2;
[0052] S3, performing mirror roller pressing and curing operations on the mirror film semi-finished product 2 to adjust the flatness of the coating base layer 2 until the pressure values on the driving side and the operating side of the mirror roller are consistent, thereby obtaining a mirror film semi-finished product 3;
[0053] S4, performing a film application operation on the side of the mirror film semi-finished product 3 with the coating primer 2, a winding operation, and hanging and standing for 24 hours to obtain a mirror film semi-finished product 4;
[0054] S5, performing unwinding and film tearing operations on the mirror film semi-finished product 4, and performing metal coating operations twice on the side of the mirror film semi-finished product 4 with the coating primer layer 2, to obtain a mirror film semi-finished product 5 with a metal coating layer 3;
[0055] S6. Apply a protective coating 4 to one side of the mirror film semi-finished product 5 having the metal coating layer 3, and apply a hardening layer 5 to the other side of the mirror film semi-finished product 5 to obtain a high-gloss mirror film with high-gloss mirror gloss.
[0056] Preferably, in step S2, multiple groups of infrared lamps are used to perform radiation baking on the mirror film semi-finished product 1, the radiation baking temperature is 100 degrees, and the radiation baking time is 20 seconds.
[0057] Preferably, in step S3, a mirror roller is used to perform a mirror rolling operation on the mirror film semi-finished product 2, the surface of the mirror roller is made of hard chrome, and the hardness of the mirror roller is HRC66.
[0058] Preferably, in step S3, while performing the mirror rolling operation, a UV lamp is used to perform a curing operation on the mirror film semi-finished product 2, the curing temperature is 55 degrees, and the curing time is 1 second.
[0059] Preferably, in step S6, the protective coating 4 is treated by flow coating with silicone oil; the hardening layer 5 is made of polyurethane acrylate resin, and the coating speed of the hardening layer 5 is 30 m / min.
[0060] Other implementations are the same as in Example 1.
[0061] Example 3
[0062] A process for preparing a high-gloss mirror-like gloss film comprises the following steps:
[0063] S1. Performing unwinding and coating operations on a substrate layer 1 in sequence to obtain a mirror film semi-finished product 1 with a coating primer layer 2, wherein the substrate layer 1 is made of PET material, PMMA material, PC material, or ABS material;
[0064] During the coating operation, the coating speed is 13.5 m / min, and the coating is a resin coating, which is composed of the following raw materials in parts by weight: 10 parts of solvent, 1.25 parts of initiator, and 70 parts of polyurethane acrylate resin, wherein the solvent is butyl ester and the initiator is photoinitiator 184;
[0065] S2, performing radiation baking on the mirror film semi-finished product 1 to obtain a mirror film semi-finished product 2;
[0066] S3, performing mirror roller pressing and curing operations on the mirror film semi-finished product 2 to adjust the flatness of the coating base layer 2 until the pressure values on the driving side and the operating side of the mirror roller are consistent, thereby obtaining a mirror film semi-finished product 3;
[0067] S4, performing a film application operation on the side of the mirror film semi-finished product 3 with the coating primer 2, a winding operation, and hanging and standing for 24 hours to obtain a mirror film semi-finished product 4;
[0068] S5, performing unwinding and film tearing operations on the mirror film semi-finished product 4, and performing metal coating operations twice on the side of the mirror film semi-finished product 4 with the coating primer layer 2, to obtain a mirror film semi-finished product 5 with a metal coating layer 3;
[0069] S6. Apply a protective coating 4 to one side of the mirror film semi-finished product 5 having the metal coating layer 3, and apply a hardening layer 5 to the other side of the mirror film semi-finished product 5 to obtain a high-gloss mirror film with high-gloss mirror gloss.
[0070] Preferably, in step S2, multiple groups of infrared lamps are used to perform radiation baking on the mirror film semi-finished product 1, the radiation baking temperature is 75 degrees, and the radiation baking time is 12.5 seconds.
[0071] Preferably, in step S3, a mirror roller is used to perform a mirror rolling operation on the mirror film semi-finished product 2, the surface of the mirror roller is made of hard chrome, and the hardness of the mirror roller is HRC61.
[0072] Preferably, in step S3, while performing the mirror rolling operation, a UV lamp is used to perform a curing operation on the mirror film semi-finished product 2, the curing temperature is 39 degrees, and the curing time is 0.75 seconds.
[0073] Preferably, in step S6, the protective coating 4 is treated by flow coating with silicone oil; the hardening layer 5 is made of polyurethane acrylate resin, and the coating speed of the hardening layer 5 is 25 m / min.
[0074] Other implementations are the same as in Example 1.
[0075] Example 4
[0076] A process for preparing a high-gloss mirror-like gloss film comprises the following steps:
[0077] S1. Performing unwinding and coating operations on a substrate layer 1 in sequence to obtain a mirror film semi-finished product 1 with a coating primer layer 2, wherein the substrate layer 1 is made of PET material, PMMA material, PC material, or ABS material;
[0078] During the coating operation, the coating speed is 13.5 m / min, and the coating is a resin coating, which is composed of the following raw materials in parts by weight: 10 parts of solvent, 1.25 parts of initiator, and 70 parts of polyurethane acrylate resin, wherein the solvent is isopropyl alcohol butanone, and the initiator is photoinitiator 1173;
[0079] S2, performing radiation baking on the mirror film semi-finished product 1 to obtain a mirror film semi-finished product 2;
[0080] S3, performing mirror roller pressing and curing operations on the mirror film semi-finished product 2 to adjust the flatness of the coating base layer 2 until the pressure values on the driving side and the operating side of the mirror roller are consistent, thereby obtaining a mirror film semi-finished product 3;
[0081] S4, performing a film application operation on the side of the mirror film semi-finished product 3 with the coating primer 2, a winding operation, and hanging and standing for 24 hours to obtain a mirror film semi-finished product 4;
[0082] S5, performing unwinding and film tearing operations on the mirror film semi-finished product 4, and performing metal coating operations twice on the side of the mirror film semi-finished product 4 with the coating primer layer 2, to obtain a mirror film semi-finished product 5 with a metal coating layer 3;
[0083] S6. Apply a protective coating 4 to one side of the mirror film semi-finished product 5 having the metal coating layer 3, and apply a hardening layer 5 to the other side of the mirror film semi-finished product 5 to obtain a high-gloss mirror film with high-gloss mirror gloss.
[0084] Preferably, in step S2, multiple groups of infrared lamps are used to perform radiation baking on the mirror film semi-finished product 1, the radiation baking temperature is 75 degrees, and the radiation baking time is 12.5 seconds.
[0085] Preferably, in step S3, a mirror roller is used to perform a mirror rolling operation on the mirror film semi-finished product 2, the surface of the mirror roller is made of hard chrome, and the hardness of the mirror roller is HRC61.
[0086] Preferably, in step S3, while performing the mirror rolling operation, a UV lamp is used to perform a curing operation on the mirror film semi-finished product 2, the curing temperature is 39 degrees, and the curing time is 0.75 seconds.
[0087] Preferably, in step S6, the protective coating 4 is treated by flow coating with silicone oil; the hardening layer 5 is made of polyurethane acrylate resin, and the coating speed of the hardening layer 5 is 25 m / min.
[0088] Other implementations are the same as in Example 1.
[0089] Example 5
[0090] A process for preparing a high-gloss mirror-like gloss film comprises the following steps:
[0091] S1. Performing unwinding and coating operations on a substrate layer 1 in sequence to obtain a mirror film semi-finished product 1 with a coating primer layer 2, wherein the substrate layer 1 is made of PET material, PMMA material, PC material, or ABS material;
[0092] During the coating operation, the coating speed is 13.5 m / min, and the coating is a resin coating, which is composed of the following raw materials in parts by weight: 10 parts of solvent, 1.25 parts of initiator, and 70 parts of polyurethane acrylate resin, wherein the solvent is butyl ester and the initiator is photoinitiator 907;
[0093] S2, performing radiation baking on the mirror film semi-finished product 1 to obtain a mirror film semi-finished product 2;
[0094] S3, performing mirror roller pressing and curing operations on the mirror film semi-finished product 2 to adjust the flatness of the coating base layer 2 until the pressure values on the driving side and the operating side of the mirror roller are consistent, thereby obtaining a mirror film semi-finished product 3;
[0095] S4, performing a film application operation on the side of the mirror film semi-finished product 3 with the coating primer 2, a winding operation, and hanging and standing for 24 hours to obtain a mirror film semi-finished product 4;
[0096] S5, performing unwinding and film tearing operations on the mirror film semi-finished product 4, and performing metal coating operations twice on the side of the mirror film semi-finished product 4 with the coating primer layer 2, to obtain a mirror film semi-finished product 5 with a metal coating layer 3;
[0097] S6. Apply a protective coating 4 to one side of the mirror film semi-finished product 5 having the metal coating layer 3, and apply a hardening layer 5 to the other side of the mirror film semi-finished product 5 to obtain a high-gloss mirror film with high-gloss mirror gloss.
[0098] Preferably, in step S2, multiple groups of infrared lamps are used to perform radiation baking on the mirror film semi-finished product 1, the radiation baking temperature is 75 degrees, and the radiation baking time is 12.5 seconds.
[0099] Preferably, in step S3, a mirror roller is used to perform a mirror rolling operation on the mirror film semi-finished product 2, the surface of the mirror roller is made of hard chrome, and the hardness of the mirror roller is HRC61.
[0100] Preferably, in step S3, while performing the mirror rolling operation, a UV lamp is used to perform a curing operation on the mirror film semi-finished product 2, the curing temperature is 39 degrees, and the curing time is 0.75 seconds.
[0101] Preferably, in step S6, the protective coating 4 is treated by flow coating with silicone oil; the hardening layer 5 is made of polyurethane acrylate resin, and the coating speed of the hardening layer 5 is 25 m / min.
[0102] Other implementations are the same as in Example 1.
[0103] Example 6
[0104] A process for preparing a high-gloss mirror-like gloss film comprises the following steps:
[0105] S1. Performing unwinding and coating operations on a substrate layer 1 in sequence to obtain a mirror film semi-finished product 1 with a coating primer layer 2, wherein the substrate layer 1 is made of PET material, PMMA material, PC material, or ABS material;
[0106] During the coating operation, the coating speed is 13.5 m / min, and the coating is a resin coating composed of the following raw materials in parts by weight: 10 parts of a solvent, 1.25 parts of an initiator, and 70 parts of a polyurethane acrylate resin, wherein the solvent is butyl ester, and the initiator is a mixture of photoinitiator TPO, photoinitiator 184, and photoinitiator 907 in a ratio of 1:1:2 in parts by weight;
[0107] S2, performing radiation baking on the mirror film semi-finished product 1 to obtain a mirror film semi-finished product 2;
[0108] S3, performing mirror roller pressing and curing operations on the mirror film semi-finished product 2 to adjust the flatness of the coating base layer 2 until the pressure values on the driving side and the operating side of the mirror roller are consistent, thereby obtaining a mirror film semi-finished product 3;
[0109] S4, performing a film application operation on the side of the mirror film semi-finished product 3 with the coating primer 2, a winding operation, and hanging and standing for 24 hours to obtain a mirror film semi-finished product 4;
[0110] S5, performing unwinding and film tearing operations on the mirror film semi-finished product 4, and performing metal coating operations twice on the side of the mirror film semi-finished product 4 with the coating primer layer 2, to obtain a mirror film semi-finished product 5 with a metal coating layer 3;
[0111] S6. Apply a protective coating 4 to one side of the mirror film semi-finished product 5 having the metal coating layer 3, and apply a hardening layer 5 to the other side of the mirror film semi-finished product 5 to obtain a high-gloss mirror film with high-gloss mirror gloss.
[0112] Preferably, in step S2, multiple groups of infrared lamps are used to perform radiation baking on the mirror film semi-finished product 1, the radiation baking temperature is 75 degrees, and the radiation baking time is 12.5 seconds.
[0113] Preferably, in step S3, a mirror roller is used to perform a mirror rolling operation on the mirror film semi-finished product 2, the surface of the mirror roller is made of hard chrome, and the hardness of the mirror roller is HRC61.
[0114] Preferably, in step S3, while performing the mirror rolling operation, a UV lamp is used to perform a curing operation on the mirror film semi-finished product 2, the curing temperature is 39 degrees, and the curing time is 0.75 seconds.
[0115] Preferably, in step S6, the protective coating 4 is treated by flow coating with silicone oil; the hardening layer 5 is made of polyurethane acrylate resin, and the coating speed of the hardening layer 5 is 25 m / min.
[0116] Other implementations are the same as in Example 1.
[0117] In short, the above description is only a preferred embodiment of the present invention, and all equivalent changes and modifications made within the scope of the patent application of the present invention should fall within the scope of the present invention.
Claims
1. A process for preparing a high-gloss mirror-like gloss film, characterized in that: The steps include: S1. The substrate layer (1) is subjected to an unwinding operation and a coating operation in sequence to obtain a mirror film semi-finished product with a coating primer layer (2). The substrate layer (1) is made of PET material, PMMA material, PC material, or ABS material. When the coating operation is performed, the coating speed is 7 m / min to 20 m / min. The coating is a resin coating. The resin coating is composed of the following raw materials in parts by weight: 0 to 20 parts of a solvent, 0.5 to 2 parts of an initiator, and 60 to 80 parts of a polyurethane acrylate resin. The solvent is ethyl ester, butyl ester, or isopropyl butanone. The initiator is one or a mixture of the following: photoinitiator TPO, photoinitiator TPO-L, photoinitiator 184, photoinitiator 1173, and photoinitiator 907. S2, performing radiation baking on the mirror film semi-finished product 1 to obtain a mirror film semi-finished product 2; S3, performing mirror roller pressing and curing operations on the mirror film semi-finished product 2 to adjust the flatness of the coating base layer (2) until the pressure values on the driving side and the operating side of the mirror roller are consistent, thereby obtaining a mirror film semi-finished product 3; S4, performing a film-sticking operation and a roll-up operation on the side of the mirror film semi-finished product 3 with the coating primer (2), and hanging and standing for 24 hours to obtain a mirror film semi-finished product 4; S5, performing unwinding and film tearing operations on the mirror film semi-finished product 4, and performing metal coating operations twice on the side of the mirror film semi-finished product 4 with the coating primer layer (2), to obtain a mirror film semi-finished product 5 with a metal coating layer (3); S6. A protective coating (4) is applied to one side of the mirror film semi-finished product 5 having the metal coating layer (3), and a hardening layer (5) is applied to the other side of the mirror film semi-finished product 5 to obtain a high-gloss mirror film with high-gloss mirror gloss.
2. The process for preparing a high-gloss mirror-like gloss film according to claim 1, wherein: The coating operation in step S1 is performed by a slit coating method.
3. The process for preparing a high-gloss mirror-like gloss film according to claim 1, wherein: In step S2, multiple groups of infrared lamps are used to perform radiation baking on the mirror film semi-finished product 1. The temperature of the radiation baking is 50 degrees to 100 degrees, and the time of the radiation baking is 5 seconds to 20 seconds.
4. The process for preparing a high-gloss mirror-like gloss film according to claim 1, wherein: In step S3, a mirror roller is used to perform a mirror rolling operation on the mirror film semi-finished product 2. The surface of the mirror roller is made of hard chrome, and the hardness of the mirror roller is HRC56-HRC66.
5. The process for preparing a high-gloss mirror-like gloss film according to claim 1, wherein: In the step S3, while the mirror surface rolling operation is being performed, a UV lamp is used to perform a curing operation on the mirror surface film semi-finished product 2, the curing temperature is 23 degrees to 55 degrees, and the curing time is 0.5 seconds to 1 second.
6. The process for preparing a high-gloss mirror-like gloss film according to claim 1, wherein: When the mirror film semi-finished product 5 is subjected to metal coating in step S5, the material of the metal coating is aluminum, silver or copper.
7. The process for preparing a high-gloss mirror-like gloss film according to claim 1, wherein: In the step S6, the protective coating (4) is treated by spraying silicone oil; the hardening layer (5) is made of polyurethane acrylate resin, and the coating speed of the hardening layer (5) is 20 m / min-30 m / min.
8. A high-gloss mirror-like gloss film, characterized in that: A high-gloss mirror gloss film is manufactured according to the preparation process of any one of claims 1 to 7, comprising a hardening layer (5), a substrate layer (1), a coating primer (2), a metal coating layer (3) and a protective coating (4), wherein the hardening layer (5), the substrate layer (1), the coating primer (2), the metal coating layer (3) and the protective coating (4) are distributed from top to bottom.
Citation Information
Patent Citations
ABS film electroplating process for automobile electroformed label
CN105111487A
Preparation method of shading metal film layer of transparent base material of car lamp
CN117702055A