Use of (5s)-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazine-4-yl]-5-(2-chloro-4-methylbenzyl)-5, 6-dihydro-4h-1, 2, 4-oxadiazine for combating unwanted microorganisms

Abstract

The present invention relates to the use of (5s)-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazine-4-yl]-5-(2-chloro-4-methylbenzyl)-5, 6-dihydro-4h-1, 2, 4-oxadiazine according to formula (I), # imgabs 0 # for controlling unwanted microorganisms causing a variety of different plant diseases

Description

[0001] The present invention relates to the use of (5S)-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-(2-chloro-4-methylbenzyl)-5,6-dihydro-4H-1,2,4-oxadiazine of formula (I) for controlling unwanted microorganisms causing various plant diseases.

[0002]

[0003] (5S)-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-(2-chloro-4-methylbenzyl)-5,6-dihydro-4H-1,2,4-oxadiazine and methods for its preparation are known from WO 2020 / 127780.

[0004] To date, many crop protection agents have been developed for preventing or preventing microbial infection. However, there is still a need to develop new compounds that provide compounds that are effective against a broad spectrum of plant pathogenic microorganisms (e.g., fungi) and that have low toxicity, high selectivity, or can be used at low application rates while still being effective in controlling pests. It is also desirable to have new compounds to prevent the emergence of resistance.

[0005] It has now been unexpectedly found that (5S)-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-(2-chloro-4-methylbenzyl)-5,6-dihydro-4H-1,2,4-oxadiazines are very effective against a wide variety of undesirable microorganisms while exhibiting generally beneficial characteristics in terms of human and environmental safety, toxicity, low application rates and resistance.

[0006] The present invention therefore provides a method for controlling unwanted microorganisms, in particular phytopathogenic fungi and phytopathogenic viruses which cause various plant diseases, comprising applying (5S)-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-(2-chloro-4-methylbenzyl)-5,6-dihydro-4H-1,2,4-oxadiazine of formula (I) to plants or parts thereof.

[0007] In the context of the present invention, "control of unwanted microorganisms" means that the infection of the corresponding microorganisms is reduced, measured by the fungicidal effect, compared to untreated plants, preferably by 25-50% compared to untreated plants (100%), more preferably by 40-79% compared to untreated plants (100%). Even more preferably, the infection of the microorganisms is inhibited by 80-100%. Control includes curative control, i.e. the treatment of already infected plants to reduce or eliminate the infection, and protective / preventive control, i.e. the treatment of plants that have not yet been infected to prevent infection.

[0008] In the method according to the invention, plants or parts thereof are treated with a compound of formula (I).

[0009] Plant parts as understood herein are all above-ground parts and organs of a plant, such as buds, leaves and flowers, thereby listing for example leaves, stems, flowers, fruit bodies, fruits and seeds.

[0010] use

[0011] The compounds and compositions of the present invention have effective microbicidal activity and / or plant defense regulation potential. They can be used to prevent and treat unwanted microorganisms on plants, such as unwanted fungi. They are suitable for crop protection (they prevent and treat microorganisms that cause plant diseases) or protective materials (such as industrial materials, timber, stored goods), as described in more detail below. More specifically, the compounds and compositions of the present invention can be used to protect seeds, germinating seeds, emergence, plants, plant parts, fruits, harvests and / or plant growth in the soil therein from unwanted microorganisms.

[0012] The ones used in this article control or controlling Includes protective, curative and eradicative treatments for unwanted microorganisms. Unwanted microorganisms It may be a pathogenic virus or a pathogenic fungus, more specifically, a phytopathogenic virus or a phytopathogenic fungus. As described below, these phytopathogenic microorganisms are the causative agents of a wide range of plant diseases.

[0013] More specifically, the compounds and compositions of the invention can be used as fungicides. For the purposes of the present invention, the term "fungicide" refers to compounds or compositions which can be used in crop protection to control unwanted fungi, such as plasmodiophoromycates, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes and Deuteromycetes.

[0014] The compounds and compositions according to the invention can also be used as antiviral agents in crop protection. For example, the compounds and compositions of the present invention can have an effect on diseases caused by plant viruses, such as tobacco mosaic virus (TMV), tobacco rattle virus, tobacco stunt virus (TStuV), tobacco leaf curl virus (VLCV), tobacco nervilia mosaic virus (TVBMV), tobacco necrotic dwarf virus (TNDV), tobacco streak virus (TSV), potato virus X (PVX), potato viruses Y, S, M and A, potato acubamosaic virus (PAMV), potato mop-top virus (PMTV), potato leaf-roll virus (PLRV), alfalfa mosaic virus ( virus (AMV), cucumber mosaic virus (CMV), cucumber green mottle mosaic virus (CGMMV), cucumber yellows virus (Cucumber yellows virus) (Cucumber yellow mosaic virus) (Watermelon mosaic virus) (WMV), tomato spotted wilt virus (TSWV), tomato ringspot virus (TomRSV), sugarcane mosaic virus (SCMV), rice dwarf virus (rice drawf virus), rice stripe virus (rice stripe virus), rice black-streaked drawf virus (rice black-streaked drawf virus), strawberry mottle virus (SMoV), strawberry vein banding virus (SVBV), strawberry mild yellow edge virus (strawberry mild yellow edge virus) (edge virus (SMYEV), strawberry crinkle virus (SCrV), broad bean wilt virus (BBWV), and melon necrotic spot virus (MNSV).

[0015] The present invention also relates to a method for controlling unwanted microorganisms on plants, such as unwanted fungi, which comprises the step of applying a compound according to the invention or at least one composition according to the invention to the microorganisms and / or their habitat (to the plants, plant parts, seeds, fruits or to the soil in which the plants are growing).

[0016] In general, when the compounds and compositions of the invention are used in a curative or protective method for controlling phytopathogenic fungi, they are applied in an effective and phytocompatible amount to plants, plant parts, fruits, seeds or to the soil or substrate in which the plants grow. Suitable substrates for cultivating plants include inorganic-based substrates, such as mineral wool, especially asbestos, perlite, sand or gravel; organic substrates, such as peat, pine bark or sawdust; and petroleum-based substrates, such as polymer foams or plastic beads. Effective and plant-compatible amount It refers to an amount that is sufficient to control or destroy fungi present or susceptible to appear on agricultural land without causing any obvious phytotoxic symptoms in the crops. The amount can vary within a wide range, depending on the fungi to be controlled, the type of crop, the growth stage of the crop, the climatic conditions and the individual compounds or compositions of the invention used. The amount can be determined by systematic field trials and is within the capabilities of those skilled in the art.

[0017] Plants and plant parts

[0018] The compounds and compositions of the invention may be applied to any plant or plant part.

[0019] plant This means all plants and plant populations, for example desired and unwanted wild plants or crop plants (including naturally occurring crop plants). Crop plants can be plants which can be obtained by conventional breeding and optimization methods or by biotechnology and genetic engineering methods or a combination of these methods, including genetically modified plants (GMO or transgenic plants) and plant cultivars which are or are not protected by plant breeders' rights.

[0020] Plant cultivarsIt is to be understood as meaning plants which have new properties ("traits") and which have been obtained by conventional breeding, mutagenesis or recombinant DNA techniques. They may be cultivars, varieties, biotypes or genotypes.

[0021] Plant Parts It should be understood as meaning all parts and organs of the plant above and below the ground, such as buds, leaves, needles, stems, trunks, flowers, fruiting bodies, fruit bodies, fruits, seeds, roots, tubers and rhizomes. Plant parts also include harvested material and asexual and sexual propagation material, such as cuttings, tubers, rhizomes, ramets and seeds.

[0022] Plants that can be treated according to the method of the present invention include: cotton, flax, grapevines, fruits, vegetables, such as Rosaceae sp. (e.g., pome fruits, such as apples and pears, and stone fruits, such as apricots, cherries, almonds and peaches, and stoneless small fruits, such as strawberries), Ribesioidae sp., Juglandaceae sp., Betulaceae sp., Anacardiaceae sp., Fagaceae sp., Moraceae sp., Oleaceae sp., Actinidaceae sp., Lauraceae sp., Musaceae sp. (e.g., banana trees and banana plantations), Rubiaceae sp. (e.g., coffee), Theaceae sp. sp.), Sterculiceae sp., Rutaceae sp. (e.g. lemon, orange and grapefruit), Solanaceae sp. (e.g. potato and tomato), Liliaceae sp., Asteraceae sp. (e.g. lettuce), Umbelliferae sp., Cruciferae sp., Chenopodiaceae sp., Cucurbitaceae sp. (e.g. cucumber), Alliaceae sp. (e.g. leek, onion), Papilionaceae sp. (e.g. pea); major crop plants, such as Gramineae sp. sp.) (e.g. corn, turf grass, cereals (e.g. wheat, rye, rice, barley, oats, millet and triticale)), Asteraceae sp. (e.g. sunflower), Brassicaceae sp. (e.g. white cabbage, red cabbage, Brussels sprouts, cauliflower, Brussels sprouts, pakchoi, kohlrabi, radish, rapeseed, mustard, horseradish and watercress), Fabacae sp. (e.g. beans, peanuts), Papilionaceae sp. (e.g. soybeans), Chenopodiaceae sp. (e.g. sugar beet, fodder beet, Swiss chard, beetroot); useful plants and ornamental plants for gardens and forests; and genetically modified variants of each of these plants.

[0023] Preferably, plants that can be treated according to the method of the present invention include: grapevines, fruits, vegetables, such as Rosaceae sp. (e.g., pome fruits, such as apples and pears, and stone fruits, such as apricots, cherries, almonds and peaches, and stoneless small fruits, such as strawberries), Oleaceae sp., Actinidaceae sp., Musaceae sp. (e.g., banana trees and banana plantations), Rubiaceae sp. (e.g., coffee), Theaceae sp., Sterculiceae sp., Rutaceae sp. (e.g., lemons, oranges and grapefruits), Solanaceae sp. (e.g., potatoes and tomatoes), Liliaceae sp., Asteraceae sp. (e.g., lettuce), Umbelliferae sp. sp.), Cruciferae sp., Chenopodiaceae sp., Cucurbitaceae sp. (e.g., cucumber), Alliaceae sp. (e.g., leek, onion), Papilionaceae sp. (e.g., peas); major crop plants, such as Gramineae sp. (e.g., corn, lawn grass, cereals (e.g., wheat, rye, rice, barley, oats, millet and triticale)), Asteraceae sp. (e.g., sunflower), Brassicaceae sp. (e.g., white cabbage, red cabbage, broccoli, cauliflower, Brussels sprouts, pakchoi, kohlrabi, radish, rapeseed, mustard, horseradish and watercress), Fapacae sp. (e.g., beans, peanuts), Papilionaceae sp. (e.g., sp.) (eg soybean), Chenopodiaceae sp. (eg sugar beet, fodder beet, Swiss chard, beetroot), and genetically modified versions of each of these plants.

[0024] Plants and plant cultivars which can be treated by the methods disclosed above include plants and plant cultivars which are resistant to one or more biotic stresses, ie the plants have an improved defense against animal or microbial pests (e.g. against nematodes, insects, mites, phytopathogenic fungi, bacteria, viruses and / or viroids).

[0025] Plants and plant cultivars that can be treated by the above disclosed methods include those plants that are resistant to one or more abiotic stresses. Abiotic stress conditions can include, for example, drought, low temperature exposure, heat exposure, osmotic stress, waterlogging, increased soil salinity, enhanced mineral exposure, ozone exposure, high light exposure, limited nitrogen nutrient availability, limited phosphorus nutrient availability, and shade avoidance.

[0026] Plants and plant cultivars that can be processed by the above-mentioned disclosed method include those plants characterized by the yield characteristics of improvement. The yield improved in the plant can be the result of the following factors: for example, improved plant physiology, growth and development, such as water use efficiency, water holding efficiency, improved nitrogen utilization rate, enhanced carbon assimilation, improved photosynthesis, improved germination rate and accelerated maturity. Yield can also be affected by improved plant architecture (plant architecture) (under stress and non-stress conditions), and the plant architecture includes but is not limited to: early flowering, flowering control of hybrid seed production, rice seedling vigor, plant size, internode number and internode distance, root growth, seed size, fruit size, pod size, pod number or ear number, seed quantity of each pod or ear, seed quality, enhanced seed fullness, reduced seed dispersal, reduced pod cracking and lodging resistance. Other yield traits include seed composition, such as carbohydrate content and composition, for example cotton or starch, protein content, oil content and composition, nutritional value, anti-nutritional compounds reduction, improved processability and better storage stability.

[0027] Plants and plant cultivars that may be treated by the above disclosed methods include plants and plant cultivars of hybrid plants that already express the characteristic of heterosis or hybrid vigour, which generally results in higher yield, vigour, health and resistance to biotic and abiotic stresses.

[0028] Transgenic plants, seed treatments and integrated lines

[0029] The compounds according to the present invention can be advantageously used to treat transgenic plants, plant cultivars or plant parts that have received genetic material, which confer favorable and / or useful properties (traits) to these plants, plant cultivars or plant parts. Therefore, it is contemplated that the present invention is combined with one or more recombinant traits or transgenic strains or combinations thereof. For the purposes of this application, transgenic strains are produced by inserting specific recombinant DNA molecules into specific locations (sites) of plant genome chromosomes. The insertion creates a new DNA sequence known as a "strain", characterized in that the inserted recombinant DNA molecules and a certain amount of genomic DNA are adjacent to both ends of the inserted DNA / flanking both ends of the inserted DNA. This trait or transgenic strain includes, but is not limited to, resistance to pests and diseases, water use efficiency, yield performance, drought tolerance, seed quality, improved nutritional quality, hybrid seed production and herbicide tolerance, wherein the trait is measured relative to plants lacking this trait or transgenic strain. Specific examples of such advantageous and / or useful properties (traits) are better plant growth, vigor, stress tolerance, stand growth ability, lodging resistance, nutrient uptake, plant nutrition and / or yield, in particular improved growth, increased tolerance to high or low temperatures, increased tolerance to drought or to water or soil salinity levels, enhanced flowering performance, easier harvesting, accelerated maturation, higher yield, higher quality and / or higher nutritional value of the harvested product, better storage life and / or processability of the harvested product, and increased resistance to animal and microbial pests (e.g. insects, arachnids, nematodes, mites, slugs and snails).

[0030] Among the DNA sequences encoding proteins which confer tolerance properties on these animal and microbial pests, in particular insects, mention will be made in particular of the genetic material consisting of the Bt protein encoding from Bacillus thuringiensis, which is widely described in the literature and is well known to those skilled in the art. Mention will also be made of proteins extracted from bacteria, such as Photorhabdus (WO 97 / 17432 and WO 98 / 08932). In particular, BtCry or VIP proteins including Cry1A, Cry1Ab, Cry1Ac, CryIIA, CryIIIA, CryIIIB2, Cry9c, Cry2Ab, Cry3Bb and CryIF proteins or toxic fragments thereof, as well as hybrids or combinations thereof, in particular Cry1F protein or hybrids derived from Cry1F protein (such as hybrid Cry1A-CrylF protein or toxic fragments thereof), Cry1A-type proteins or toxic fragments thereof, preferably Cry1Ac protein or hybrids derived from Cry1Ac protein (such as hybrid Cry1Ab-CrylAc protein) or Cry1Ab or Bt2 protein or toxic fragments thereof, Cry2Ae, Cry2Af or Cry2Ag protein or toxic fragments thereof, Cry1A.105 protein or toxic fragments thereof, VIP3Aa19 protein, VIP3Aa20 protein, VIP3A protein produced in COT202 or COT203 cotton strains, described in Estruch et al. (1996), Proc Natl Acad Sci US A.28; 93 (11): 5389-94 or a toxic fragment thereof, a Cry protein described in WO2001 / 47952, an insecticidal protein from Xenorhabdus (such as described in WO98 / 50427), Serratia (especially from S. entomophila) or a Photorhabdus species strain, such as the Tc protein from Photorhabdus described in WO98 / 08932. In addition, the present invention also includes any variant or mutant of any of the above-mentioned proteins that differs from any of the above-named sequences (especially the sequences of their toxic fragments) in some amino acids (1-10, preferably 1-5), or any variant or mutant of the above-mentioned protein fused with a transit peptide (such as a plastid transit peptide) or another protein or peptide.

[0031] Another and particularly emphasized example of such a property is the conferring of tolerance to one or more herbicides, such as imidazolinones, sulfonylureas, glyphosate or glufosinate. Among the DNA sequences encoding proteins that confer tolerance to certain herbicides on transformed plant cells and plants, particular mention will be made of the bar or PAT genes described in WO 2009 / 152359 that confer tolerance to the glufosinate herbicide or the gene of Streptomyces coelicolor that encodes a suitable EPSPS that confer tolerance to herbicides targeting EPSPS, in particular to herbicides such as glyphosate and its salts. 5-enolpyruvylshikimate-3-phosphate-synthase ), a gene encoding a glyphosate-n-acetyltransferase, or a gene encoding a glyphosate oxidoreductase. Other suitable herbicide tolerance traits include at least one ALS (acetolactate synthase) inhibitor (e.g., WO2007 / 024782), a mutated Arabidopsis ALS / AHAS gene (e.g., U.S. Pat. No. 6,855,533), a gene encoding a 2,4-D-monooxygenase conferring tolerance to 2,4-D (2,4-dichlorophenoxyacetic acid), and a gene encoding a Dicamba monooxygenase conferring tolerance to Dicamba (3,6-dichloro-2-methoxybenzoic acid).

[0032] Yet another example of such a property is resistance to one or more phytopathogenic fungi, such as Asian Soybean Rust. Among the DNA sequences encoding proteins conferring resistance to such diseases, particular mention will be made of genetic material from glycine tomentella, such as any one of the publicly available registration series described in WO2019 / 103918: PI441001, PI483224, PI583970, PI446958, PI499939, PI505220, PI499933, PI441008, PI505256 or PI446961.

[0033] Further and particularly emphasized examples of such traits are increased resistance to bacteria and / or viruses due to, for example, systemic acquired resistance (SAR), systemin, phytoalexins, inducers and resistance genes and correspondingly expressed proteins and toxins.

[0034] Particularly useful transgenic lines among the transgenic plants or plant cultivars that can be preferentially treated according to the present invention include line 531 / PV-GHBK04 (cotton, insect control, described in WO2002 / 040677), line 1143-14A (cotton, insect control, not deposited, described in WO2006 / 128569); line 1143-51B (cotton, insect control, not deposited, described in WO2006 / 128570); line 1445 (cotton, herbicide tolerance, not deposited, described in US-A 2002-120964 or WO2002 / 034946); Line 17053 (rice, herbicide tolerant, deposited as PTA-9843, described in WO2010 / 117737); Line 17314 (rice, herbicide tolerant, deposited as PTA-9844, described in WO2010 / 117735); Line 281-24-236 (cotton, insect control-herbicide tolerant, deposited as PTA-6233, described in WO2005 / 103266 or US-A2005-216969); Line 3006-210-23 (cotton, insect control-herbicide tolerant, deposited as PTA-6233, described in US-A 2007-143876 or WO2005 / 103266); Line 3272 (maize, quality traits, deposited as PTA-9972, described in WO2006 / 098952 or US-A 2006-230473); Line 33391 (wheat, herbicide tolerance, deposited as PTA-2347, described in WO2002 / 027004), Line 40416 (maize, insect control-herbicide tolerance, deposited as ATCC PTA-11508, described in WO 11 / 075593); Line 43A47 (maize, insect control-herbicide tolerance, deposited as ATCC PTA-11509 deposited and described in WO2011 / 075595); Line 5307 (corn, insect control, deposited as ATCC PTA-9561, described in WO2010 / 077816); Line ASR-368 (bent grass, herbicide tolerant, deposited as ATCC PTA-4816, described in US-A 2006-162007 or WO2004 / 053062); Line B16 (corn, herbicide tolerant, not deposited, described in US-A 2003-126634); line BPS-CV127-9 (soybean, herbicide tolerance, deposited as NCIMB No. 41603, described in WO2010 / 080829); line BLR1 (rapeseed, restored male sterility, deposited as NCIMB No. 41193, described in WO2005 / 074671), line CE43-67B (cotton,insect control, deposited as DSMACC2724, described in US-A 2009-217423 or WO2006 / 128573); strain CE44-69D (cotton, insect control, not deposited, described in US-A 2010-0024077); strain CE44-69D (cotton, insect control, not deposited, described in WO2006 / 128571); strain CE46-02A (cotton, insect control, not deposited, described in WO2006 / 128572); strain COT102 (cotton, insect control, not deposited, described in US-A 2006-130175 or WO2004 / 039986); strain COT202 (cotton, insect control, not deposited, described in US-A 2007-067868 or WO2005 / 054479); line COT203 (cotton, insect control, not deposited, described in WO2005 / 054480); line DAS21606-3 / 1606 (soybean, herbicide tolerance, deposited as PTA-11028, described in WO2012 / 033794), line DAS40278 (corn, herbicide tolerance, deposited as ATCC PTA-10244 deposited, described in WO2011 / 022469); line DAS-44406-6 / pDAB8264.44.06.1 (soybean, herbicide tolerance, deposited as PTA-11336, described in WO2012 / 075426), line DAS-14536-7 / pDAB8291.45.36.2 (soybean, herbicide tolerance, deposited as PTA-11335, described in WO2012 / 075429), line DAS-59122-7 (corn, insect control-herbicide tolerance, deposited as ATCC PTA 11384, described in US-A 2006-070139); line DAS-59132 (corn, insect control-herbicide tolerance, not deposited, described in WO2009 / 100188); line DAS68416 (soybean, herbicide tolerance, deposited as ATCC PTA-10442, described in WO2011 / 066384 or WO2011 / 066360); line DP-098140-6 (corn, herbicide tolerance, deposited as ATCC PTA-8296, described in US-A 2009-137395 or WO 08 / 112019); line DP-305423-1 (soybean, quality traits, not deposited, described in US-A 2008-312082 or WO2008 / 054747); strain DP-32138-1 (maize, hybrid system, deposited as ATCC PTA-9158,09-0210970 or WO2009 / 103049); line DP-356043-5 (soybean, herbicide tolerant, deposited as ATCC PTA-8287, described in US-A 2010-0184079 or WO2008 / 002872); line EE-I (eggplant, insect control, not deposited, described in WO 07 / 091277); line Fil17 (maize, herbicide tolerant, deposited as ATCC 209031, described in US-A 2006-059581 or WO 98 / 044140); line FG72 (soybean, herbicide tolerant, deposited as PTA-11041, described in WO2011 / 063413), line GA21 (maize, herbicide tolerant, deposited as ATCC 209033, described in US-A2005-086719 or WO 98 / 044140); line GG25 (maize, herbicide tolerant, deposited as ATCC 209032, described in US-A 2005-188434 or WO 98 / 044140); line GHB119 (cotton, insect control-herbicide tolerant, deposited as ATCC PTA-8398, described in WO2008 / 151780); line GHB614 (cotton, herbicide tolerant, deposited as ATCC PTA-6878 deposited, recorded in US-A 2010-050282 or WO 2007 / 017186); line GJ11 (maize, herbicide tolerant, deposited as ATCC 209030, recorded in US-A 2005-188434 or WO 98 / 044140); line GM RZ13 (sugar beet, virus resistant, deposited as NCIMB-41601, recorded in WO 2010 / 076212); line H7-1 (sugar beet, herbicide tolerant, deposited as NCIMB 41158 or NCIMB 41159, recorded in US-A 2004-172669 or WO 2004 / 074492); line JOPLIN1 (wheat, disease resistant, not deposited, recorded in US-A 2008-064032); line LL27 (soybean, herbicide tolerant, deposited as NCIMB 41658, described in WO 2006 / 108674 or US-A 2008-320616); line LL55 (soybean, herbicide tolerant, deposited as NCIMB 41660, described in WO 2006 / 108675 or US-A 2008-196127); line LLcotton25 (cotton, herbicide tolerant, deposited as ATCC PTA-3343, described in WO 2003 / 013224 or US A 2003-097687); line LLRICE06 (rice,herbicide tolerance, deposited as ATCC 203353, described in US 6,468,747 or WO2000 / 026345); line LLRice62 (rice, herbicide tolerance, deposited as ATCC 203352, described in WO2000 / 026345), line LLRICE601 (rice, herbicide tolerance, deposited as ATCC PTA-2600, described in US-A2008-2289060 or WO2000 / 026356); line LY038 (maize, quality traits, deposited as ATCC PTA-5623, described in US-A 2007-028322 or WO2005 / 061720); line MIR162 (maize, insect control, deposited as PTA-8166, described in US-A 2009-300784 or WO2007 / 142840); line MIR604 (corn, insect control, not deposited, described in US-A 2008-167456 or WO2005 / 103301); line MON15985 (cotton, insect control, deposited as ATCC PTA-2516, described in US-A 2004-250317 or WO2002 / 100163); line MON810 (corn, insect control, not deposited, described in US-A 2002-102582); line MON863 (maize, insect control, deposited as ATCC PTA-2605, described in WO2004 / 011601 or US-A2006-095986); line MON87427 (maize, pollination control, deposited as ATCC PTA-7899, described in WO2011 / 062904); line MON87460 (maize, stress resistance, deposited as ATCC PTA-8910, described in WO2009 / 111263 or US-A2011-0138504); line MON87701 (soybean, insect control, deposited as ATCC PTA-8194, described in US-A 2009-130071 or WO2009 / 064652); line MON87705 (soybean, quality trait - herbicide tolerance, deposited as ATCC PTA-9241, described in US-A 2010-0080887 or WO2010 / 037016); line MON87708 (soybean, herbicide tolerance, deposited as ATCC PTA-9670, described in WO2011 / 034704); line MON87712 (soybean, yield, deposited as PTA-10296, described in WO2012 / 051199), line MON87754 (soybean, quality trait, deposited as ATCC PTA-9385, described in US-A 2010-0080887 or WO2010 / 037016); line MON87709 (soybean, herbicide tolerance, deposited as ATCC PTA-9670, described in WO2011 / 034704); line MON87710 (soybean, yield, deposited as PTA-10296, described in WO2012 / 051199), line MON87755 (soybean, quality trait, deposited as ATCC PTA-9385, described in US-A 2010-0080887 or WO2010 / 0370162008-028482 or WO2005 / 059103); line MON88913 (cotton, herbicide tolerance, deposited as ATCC PTA-4854, described in WO2004 / 072235 or US-A 2006-059590); line MON88302 (rapeseed, herbicide tolerant, deposited as PTA-10955, described in WO2011 / 153186), line MON88701 (cotton, herbicide tolerant, deposited as PTA-11754, described in WO2012 / 134808), line MON89034 (corn, insect control, deposited as ATCC PTA-7455, described in WO 07 / 140256 or US-A 2008-260932); line MON89788 (soybean, herbicide tolerant, deposited as ATCC PTA-6708, described in US-A 2006-282915 or WO2006 / 130436); line MS1 1 (canola, pollination control-herbicide tolerance, deposited as ATCC PTA-850 or PTA-2485, described in WO2001 / 031042); line MS8 (canola, pollination control-herbicide tolerance, deposited as ATCC PTA-730, described in WO2001 / 041558 or US-A 2003-188347); line NK603 (maize, herbicide tolerance, deposited as ATCC PTA-2478, described in US-A2007-292854); line PE-7 (rice, insect control, not deposited, described in WO2008 / 114282); line RF3 (canola, pollination control-herbicide tolerance, deposited as ATCC PTA-730, described in WO2001 / 041558 or US-A 2003-188347); line RT73 (rapeseed, herbicide tolerant, not deposited, described in WO2002 / 036831 or US-A2008-070260); line SYHT0H2 / SYN-000H2-5 (soybean, herbicide tolerant, deposited as PTA-11226, described in WO2012 / 082548), line T227-1 (sugar beet, herbicide tolerant, not deposited, described in WO2002 / 44407 or US-A 2009-265817); line T25 (maize, herbicide tolerant, not deposited,described in US-A 2001-029014 or WO2001 / 051654); line T304-40 (cotton, insect control-herbicide tolerance, deposited as ATCC PTA-8171, described in US-A 2010-077501 or WO2008 / 122406); line T342-142 (cotton, insect control, not deposited, described in WO2006 / 128568); line TC1507 (corn, insect control-herbicide tolerance, not deposited, described in US-A2005-039226 or WO2004 / 099447); line VIP1034 (corn, insect control-herbicide tolerance, deposited as ATCC PTA-3925 deposited and described in WO2003 / 052073), Line 32316 (maize, insect control-herbicide tolerance, deposited as PTA-11507 and described in WO2011 / 084632), Line 4114 (maize, insect control-herbicide tolerance, deposited as PTA-11506 and described in WO2011 / 084621), optionally with Line EE-GM1 / LL27 or Line EE-GM2 / LL55 (WO2011 / 063413 A2) stacked line EE-GM3 / FG72 (soybean, herbicide tolerance, ATCC Accession No. PTA-11041), line DAS-68416-4 (soybean, herbicide tolerance, ATCC Accession No. PTA-10442, WO2011 / 066360A1), line DAS-68416-4 (soybean, herbicide tolerance, ATCC Accession No. PTA-10442, WO2011 / 066384A1), line DP-040416-8 (corn, insect control, ATCC Accession No. PTA-11041). ATCC Accession No. PTA-11508, WO2011 / 075593A1), line DP-043A47-3 (corn, insect control, ATCC Accession No. PTA-11509, WO2011 / 075595A1), line DP-004114-3 (corn, insect control, ATCC Accession No. PTA-11506, WO2011 / 084621A1), line DP-032316-8 (corn, insect control, ATCC Accession No. PTA-11507, WO 2011 / 084632A1), line MON-88302-9 (rapeseed, herbicide tolerance, ATCC accession number PTA-10955, WO2011 / 153186A1), line DAS-21606-3 (soybean, herbicide tolerance, ATCC accession number PTA-11028, WO2012 / 033794A2), line MON-87712-4 (soybean, quality traits, ATCC accession number PTA-10296, WO2012 / 051199A2),Strain DAS-44406-6 (soybean, stacked herbicide tolerance, ATCC Accession No. PTA-11336, WO2012 / 075426A1), Strain DAS-14536-7 (soybean, stacked herbicide tolerance, ATCC Accession No. PTA-11335, WO2012 / 075429A1), Strain SYN-000H2-5 (soybean, herbicide tolerance, ATCC Accession No. PTA-1122 6, WO2012 / 082548A2), line DP-061061-7 (rapeseed, herbicide tolerance, no available deposit number, WO2012071039A1), line DP-073496-4 (rapeseed, herbicide tolerance, no available deposit number, US2012131692), line 8264.44.06.1 (soybean, stacked herbicide tolerance, registration number PTA-11336, WO2012075 426A2), line 8291.45.36.2 (soybean, stacked herbicide tolerance, registration number PTA-11335, WO2012075429A2), line SYHT0H2 (soybean, ATCC registration number PTA-11226, WO2012 / 082548A2), line MON88701 (cotton, ATCC registration number PTA-11754, WO2012 / 134808A1), Strain KK179-2 (alfalfa, ATCC accession number PTA-11833, WO2013 / 003558A1), strain pDAB8264.42.32.1 (soybean, stacked herbicide tolerance, ATCC accession number PTA-11993, WO2013 / 010094A1), strain MZDT09Y (corn, ATCC accession number PTA-13025, WO2013 / 012775A1). ,

[0035] In addition, the United States Department of Agriculture (USDA) Animal and Plant Health Inspection Service (APHIS) provides a list of such transgenic strains, which can be found on the Internet at their website aphis.usda.gov Found. For the purposes of this application, this list is relevant to the status on the filing date of this application.

[0036] The genes / lines which confer the desired traits may also be present in combination with one another in the transgenic plants. Examples of transgenic plants which may be mentioned are important crop plants such as cereals (wheat, rice, triticale, barley, rye, oats), corn, soybeans, potatoes, sugar beets, sugar cane, tomatoes, peas and other types of vegetables, cotton, tobacco, rapeseed and fruit plants (including apples, pears, citrus fruits and grapes), with particular emphasis on corn, soybeans, wheat, rice, potatoes, cotton, sugar cane, tobacco and rapeseed. Traits which are particularly emphasized are increased resistance of the plants to insects, arachnids, nematodes and slugs and snails, and increased resistance of the plants to one or more herbicides.

[0037] Commercially available examples of such plants, plant parts or plant seeds which may be preferentially treated according to the invention include RIB VT DOUBLE VT TRIPLE BOLLGARD ROUNDUP READY ROUNDUP 2XTEN DTM 、INTACTA RR2 VISTIVE and / or XTENDFLEX TM A commercially available product, such as plant seeds, sold or distributed under a trade name.

[0038] The compounds of formula (I) can preferably be used as fungicides.

[0039] Pathogens

[0040] Non-limiting examples of pathogens of fungal diseases that can be treated according to the present invention include:

[0041] Diseases caused by powdery mildew pathogens, such as Blumeria species, such as Blumeria graminis; Leveillula species, such as Leveillula Taurica; Podosphaera species, such as Podosphaera leucotricha or Podosphaera xanthii; Sphaerotheca species, such as Sphaerotheca fuliginea; Erysiphe species, such as Erysiphe necator, Erysiphe betae;

[0042] Diseases caused by rust pathogens, such as Gymnosporangium species, such as Gymnosporangium sabinae; Hemileia species, such as Hemileia vastatrix; Phakopsora species, such as Phakopsora pachyrhizi or Phakopsora meibomiae; Puccinia species, such as Puccinia recondita, Puccinia graminis or Puccinia striiformis; Uromyces species, such as Uromyces appendiculatus;

[0043] Leaf spot and leaf wilt diseases caused by the following pathogens: for example, Alternaria species, such as Alternaria solani or Alternaria mali or Alternaria alternata; Cercospora species, such as Cercosporabeticola; Cladiosporum species, such as Cladiosporium cucumerinum; Cochliobolus species, such as Cochliobolus sativus (conidial form: Drechslera, synonym: Helminthosporium) or Cochliobolus miyabeanus; Colletotrichum species, such as Colletotrichum lindemuthanium or Colletotrichum capsica or Colletotrichum acutatum; Corynespora species, for example Corynespora cassiicola; Cycloconium species, for example Cycloconium oleaginum; Diaporthe species, for example Diaporthecitri; Elsinoe species, for example Elsinoe fawcettii; Gloeosporium species, for example Gloeosporium laeticolor; Glomerella species, for example Glomerella cingulata); species of the genus Guignardia, such as Guignardia bidwelli; species of the genus Leptosphaeria, such as Leptosphaeria maculans; species of the genus Magnaporthe, such as Magnaporthe grisea; species of the genus Marsonina, such as Marsonina mali;Species of the genus Microdochium, such as Microdochium nivale; species of the genus Monilinia, such as Monilinia laxa; species of the genus Mycosphaerella, such as Mycosphaerella graminicola, Mycosphaerella arachidicola and Mycosphaerella fijiensis; species of the genus Phaeosphaeria, such as Phaeosphaeria nodorum; species of the genus Phyllachora, such as Phyllachora maydis; species of the genus Pyrenophora, such as Pyrenophora teres or Pyrenophora tritici; repentis; Ramularia species, for example Ramularia collo-cygni or Ramularia areola; Rhynchosporium species, for example Rhynchosporium secalis; Septoria species, for example Septoria apii or Septoria lycopersici; Setosphaeria species, for example Setosphaeria turcica; Sclerotinia species, for example Sclerotinia sclerotiorum; Stagonospora species, for example Stagonospora nodorum; Stemphylium species, for example Stemphylium cysticola; vesicarium; species of the genus Typhula, such as Typhula incarnata; species of the genus Venturia, such as Venturia inaequalis;

[0044] Root and stem diseases caused by pathogens such as Corticium species, for example Corticium graminearum; Fusarium species, for example Fusarium oxysporum; Gaeumannomyces species, for example Gaeumannomyces graminis; Marsonina species, for example Marsonina mali; Rhizoctonia species, for example Rhizoctonia solani; Sarocladium species, for example Sarocladium oryzae; Sclerotium species, for example Sclerotium oryzae; Tapesia species, for example Tapesia acuformis; species of the genus Thielaviopsis, for example Thielaviopsis basicola;

[0045] Diseases of spadix and panicles (including cobs) caused by pathogens such as Alternaria spp., for example Alternaria spp.; Aspergillus spp., for example Aspergillus flavus; Cladosporium spp., for example Cladosporium cladosporioides; Claviceps spp., for example Claviceps purpurea; Fusarium spp., for example Fusarium culmorum; Gibberella spp., for example Gibberella zeae; Monographella spp., for example Monographella nivalis; Stagonospora spp., for example Stagonosporanodorum;

[0046] Diseases caused by smut fungi, such as: species of the genus Sphacelotheca, such as Sphacelotheca reiliana; species of the genus Tilletia, such as Tilletia caries or Tilletia controversa; species of the genus Urocystis, such as Urocystis occulta; species of the genus Ustilago, such as Ustilago nuda;

[0047] Fruit rot caused by pathogens such as Aspergillus species, such as Aspergillus flavus; Botrytis species, such as Botrytis cinerea; Monilinia species, such as Monilinia laxa; Penicillium species, such as Penicillium expansum or Penicillium purpurogenum; Phomopsis species, such as Phomopsis viticola; Rhizopus species, such as Rhizopus stolonifer; Sclerotinia species, such as Sclerotinia sclerotinia; sclerotiorum); species of the genus Verticilium, for example, Verticilium alboatrum;

[0048] Seed-borne and soil-borne rot and wilt diseases, and seedling diseases caused by pathogens such as Alternaria species, for example Alternaria brassicicola; Aphanomyces species, for example Aphanomyces euteiches; Ascochyta species, for example Ascochyta lentis; Aspergillus species, for example Aspergillus flavus; Cladosporium species, for example Cladosporium herbarum; Cochliobolus species, for example Cochliobolus graminis. sativus) (conidial form: Drechslera, Bipolaris synonym: Helminthosporium); Colletotrichum species, for example Colletotrichum coccodes; Fusarium species, for example Fusarium culmorum; Gibberella species, for example Gibberella zeae; Macrophomina species, for example Macrophomina phaseolina; Microdochium species, for example Microdochium nivale; Monographella species, for example Monographella nivalis; Penicillium species, such as Penicillium expansum; Phoma species, such as Phoma lingam; Phomopsis species, such as Phomopsis sojae; Pyrenophora species, such as Pyrenophora graminea; Pyricularia species, such as Pyricularia oryzae; Rhizoctonia species, such as Rhizoctonia solani;Rhizopus species, such as Rhizopus oryzae; Sclerotium species, such as Sclerotium rolfsii; Septoria species, such as Septoria nodorum; Typhula species, such as Typhula incarnata; Verticillium species, such as Verticillium dahliae;

[0049] Cancerous diseases, galls and broom diseases caused by pathogens such as species of the genus Nectria, for example Nectria galligena;

[0050] Wilt diseases caused by pathogens such as Verticillium species, such as Verticillium longisporum; Fusarium species, such as Fusarium oxysporum;

[0051] Deformities of leaves, flowers and fruits caused by pathogens such as Exobasidium species, such as Exobasidium vexans; Taphrina species, such as Taphrina deformans;

[0052] Degenerative diseases of woody plants caused by pathogens such as species of the genus Esca, such as Phaemoniella chlamydospora, Phaeoacremonium aleophilum or Fomitiporia mediterranea; such as species of the genus Ganoderma, such as Ganoderma boninense;

[0053] Diseases of plant tubers caused by pathogens such as Rhizoctonia species, for example Rhizoctonia solani; Helminthosporium species, for example Helminthosporium solani;

[0054] Soybean diseases:

[0055] Fungal diseases of leaves, stems, pods and seeds caused by pathogens such as Alternaria leaf spot (Alternaria spec. atrans tenuissima), Anthracnose (Colletotrichum gloeosporoides dematium var.truncatum), brown spot (Septoria glycines), Cercospora leaf spot and blight (Cercospora kikuchii), Choanephora leaf blight (Choanephora infundibulifera trispora (synonym)), cordanamusae, Dactuliophora leaf spot (Dactuliophora glycines), downy mildew (Peronospora manshurica), Drechslera blight (Drechslera glycini), frogeye leaf spot (Cercospora sojina), Leptosphaerulina leaf spot (Leptosphaerulina leaf spot (Leptosphaerulina trifolii), powdery mildew (Leveillula Taurica), Phyllostica leaf spot (Phyllosticta sojaecola), pod and stem blight (Phomopsis sojae), powdery mildew (Microsphaera diffusa), Pyrenochaeta leaf spot (Pyrenochaeta glycines), Rhizoctonia aerial, web blight (Rhizoctonia solani), rust (Phakopsora pachyrhizi, Phakopsora meibomiae), scab (Sphaceloma glycines), stemphylium leaf blight (Stemphylium botryosum), North American soybean sudden death syndrome (Fusarium virguliforme), target spot (Corynespora cassiicola);

[0056] Fungal diseases of roots and stems caused by pathogens such as black root rot (Calonectria crotalariae), charcoal rot (Macrophomina phaseolina), Fusarium wilt or wilt, root rot and pod and crown rot (Fusarium oxysporum, Fusarium orthoceras, Fusarium semitectum, Fusarium equiseti), mycoleptodiscus root rot (Mycoleptodiscus terrestris), neocosmospora (Neocosmopspora vasinfecta), pod and stem wilt (Diaporthe phaseolorum), stem canker (Diaporthe phaseolorum caulivora), brown stem rot (Phialophora gregata), Rhizoctonia root rot, stem rot and damping-off (Rhizoctonia solani), Sclerotinia stem rot (Sclerotinia sclerotiorum), Sclerotinia white rot (Sclerotiniarolfsii), Thielaviopsis root rot (Thielaviopsis basicola).

[0057] Preferably, the present invention relates to the use of compounds of formula (I) for controlling diseases caused by powdery mildew pathogens, such as Blumeria species, such as Blumeria graminis of the Poaceae family; Leveillula species, such as Leveillula Taurica; Podosphaera species, such as Podosphaera leucotricha or Podosphaera xanthii; Sphaerotheca species, such as Sphaerothecafuliginea; Erysiphe species, such as Erysiphe necator and Erysiphe betae;

[0058] Leaf spot and leaf wilt diseases caused by pathogens such as Alternaria species, such as Alternaria solani or Alternaria mali or Alternaria alternata; Cercospora species, such as Cercosporabeticola; Cladiosporum species, such as Cladiosporium cucumerinum; Cochliobolus species, such as Cochliobolus sativus (conidial form: Drechslera, synonym: Helminthosporium) or Cochliobolus pachyrhizi. miyabeanus; Colletotrichum species, for example Colletotrichum lindemuthanium or Colletotrichum capsica or Colletotrichum acutatum; Corynespora species, for example Corynespora cassiicola; Cycloconium species, for example Cycloconium oleaginum; Diaporthe species, for example Diaporthecitri; Elsinoe species, for example Elsinoe fawcettii; Gloeosporium species, for example Gloeosporium oleaginum; laeticolor; Glomerella species, such as Glomerella cingulata; Guignardia species, such as Guignardia bidwelli; Leptosphaeria species, such as Leptosphaeria maculans; Magnaporthe species, such as Magnaporthe grisea; Marsonina species, such as Marsonina mali;Species of the genus Microdochium, such as Microdochium nivale; species of the genus Monilinia, such as Monilinia laxa; species of the genus Mycosphaerella, such as Mycosphaerella graminicola, Mycosphaerella arachidicola and Mycosphaerella fijiensis; species of the genus Phaeosphaeria, such as Phaeosphaeria nodorum; species of the genus Phyllachora, such as Phyllachora maydis; species of the genus Pyrenophora, such as Pyrenophora teres or Pyrenophora tritici; repentis; Ramularia species, for example Ramularia collo-cygni or Ramularia areola; Rhynchosporium species, for example Rhynchosporium secalis; Septoria species, for example Septoria apii or Septoria lycopersici; Setosphaeria species, for example Setosphaeria turcica; Sclerotinia species, for example Sclerotinia sclerotiorum; Stagonospora species, for example Stagonospora nodorum; Stemphylium species, for example Stemphylium cysticola; vesicarium; species of the genus Typhula, such as Typhula incarnata; species of the genus Venturia, such as Venturia inaequalis;

[0059] Root and stem diseases caused by pathogens such as Corticium, for example Corticium graminearum; Fusarium, for example Fusarium oxysporum; Gaeumannomyces, for example Gaeumannomyces graminis; Marsonina, for example Marsonina mali; Rhizoctonia, for example Rhizoctonia solani; Sarocladium, for example Sarocladium oryzae; Sclerotium, for example Sclerotium oryzae; Tapesia, for example Tapesia acuformis; species of the genus Thielaviopsis, for example Thielaviopsis basicola;

[0060] Diseases of spadix and panicles (including cobs) caused by pathogens such as Alternaria spp., for example Alternaria spp.; Aspergillus spp., for example Aspergillus flavus; Cladosporium spp., for example Cladosporium cladosporioides; Claviceps spp., for example Claviceps purpurea; Fusarium spp., for example Fusarium culmorum; Gibberella spp., for example Gibberella zeae; Monographella spp., for example Monographella nivalis; Stagonospora spp., for example Stagonosporanodorum;

[0061] Fruit rot caused by pathogens such as Aspergillus species, such as Aspergillus flavus; Botrytis species, such as Botrytis cinerea; Monilinia species, such as Monilinia laxa; Penicillium species, such as Penicillium expansum or Penicillium purpurogenum; Phomopsis species, such as Phomopsis viticola; Rhizopus species, such as Rhizopus stolonifer; Sclerotinia species, such as Sclerotinia sclerotinia; sclerotiorum); species of the genus Verticilium, for example, Verticilium alboatrum;

[0062] Seed-borne and soil-borne rot and wilt diseases, and seedling diseases caused by pathogens such as Alternaria species, for example Alternaria brassicicola; Aphanomyces species, for example Aphanomyces euteiches; Ascochyta species, for example Ascochyta lentis; Aspergillus species, for example Aspergillus flavus; Cladosporium species, for example Cladosporium herbarum; Cochliobolus species, for example Cochliobolus graminis. sativus) (conidial form: Drechslera, Bipolaris synonym: Helminthosporium); Colletotrichum species, for example Colletotrichum coccodes; Fusarium species, for example Fusarium culmorum; Gibberella species, for example Gibberella zeae; Macrophomina species, for example Macrophomina phaseolina; Microdochium species, for example Microdochium nivale; Monographella species, for example Monographella nivalis; Penicillium species, such as Penicillium expansum; Phoma species, such as Phoma lingam; Phomopsis species, such as Phomopsis sojae; Pyrenophora species, such as Pyrenophora graminea; Pyricularia species, such as Pyricularia oryzae; Rhizoctonia species, such as Rhizoctonia solani;Rhizopus species, such as Rhizopus oryzae; Sclerotium species, such as Sclerotium rolfsii; Septoria species, such as Septoria nodorum; Typhula species, such as Typhula incarnata; Verticillium species, such as Verticillium dahliae;

[0063] Cancerous diseases, galls and broom diseases caused by pathogens such as species of the genus Nectria, for example Nectria galligena;

[0064] Wilt diseases caused by pathogens such as Fusarium species, for example Fusarium oxysporum;

[0065] Soybean diseases:

[0066] Fungal diseases of leaves, stems, pods and seeds caused by pathogens such as Alternaria leaf spot (Alternaria spec. atrans tenuissima), Anthracnose (Colletotrichum gloeosporoides dematium var.truncatum), brown spot (Septoria glycines), Cercospora leaf spot and blight (Cercospora kikuchii), Choanephora leaf blight (Choanephora infundibulifera trispora (synonym)), Dactuliophora leaf spot (Dactuliophora glycines), downy mildew (Peronospora manshurica), Drechslera blight (Drechslera glycini), frogeye leaf spot (Cercospora sojina), Leptosphaerulina leaf spot (Leptosphaerulina trifolii), Leveillula Taurica, Phyllostica leaf spot (Phyllosticta sojaecola), pod and stem blight (Phomopsis sojae), powdery mildew (Microsphaera diffusa), Pyrenochaeta leaf spot (Pyrenochaeta glycines), Rhizoctonia aerial, webblight and scab (Rhizoctonia solani), scab (Sphaceloma glycines), stemphylium leaf blight (Stemphylium botryosum), Fusarium virguliforme), target spot (Corynespora cassiicola);.

[0067] Fungal diseases of roots and stems caused by pathogens such as black root rot (Calonectria crotalariae), charcoal rot (Macrophomina phaseolina), Fusarium wilt or wilt, root rot and pod and crown rot (Fusarium oxysporum, Fusarium orthoceras, Fusarium semitectum, Fusarium equiseti), mycoleptodiscus root rot (Mycoleptodiscus terrestris), neocosmospora (Neocosmopspora vasinfecta), pod and stem wilt (Diaporthe phaseolorum), stem canker (Diaporthe phaseolorum caulivora), brown stem rot (Phialophora gregata), Rhizoctonia root rot, stem rot and damping-off (Rhizoctonia solani), Sclerotinia stem rot (Sclerotinia sclerotiorum), Sclerotinia white rot (Sclerotiniarolfsii), Thielaviopsis root rot (Thielaviopsis basicola).

[0068] Most preferably, the present invention relates to the use of compounds of formula (I) for controlling diseases caused by powdery mildew pathogens, said pathogens being species of the genus Sphaerotheca, such as Sphaerotheca fuliginea;

[0069] Leaf spot and leaf wilt diseases caused by pathogens such as Alternaria species, such as Alternaria solani or Alternaria mali or Alternaria alternata; Cercospora species, such as Cercosporabeticola; Colletotrichum species, such as Colletotrichum lindemuthanium or Colletotrichum capsica or Colletotrichum acutatum; Diaporthe species, such as Diaporthe citri; Phaeosphaeria species, such as Phaeosphaeria glumenifolia. nodorum; species of the genus Pyrenophora, for example Pyrenophora teres or Pyrenophora tritici repentis; species of the genus Septoria, for example Septoria apii or Septoria lycopersici;

[0070] Root and stem diseases caused by pathogens such as Fusarium species, for example Fusarium oxysporum;

[0071] Diseases of spadix and panicles (including cobs) caused by pathogens such as Alternaria spp., Fusarium spp., Fusarium culmorum;

[0072] Fruit rot caused by pathogens such as Botrytis species, such as Botrytis cinerea;

[0073] Seed-borne and soil-borne rot and wilt diseases, and seedling diseases caused by pathogens such as Alternaria species, for example Alternaria brassicicola; Colletotrichum species, for example Colletotrichum coccodes; Fusarium species, for example Fusarium culmorum; Pyrenophora species, for example Pyrenophora graminea; Pyricularia species, for example Pyricularia oryzae;

[0074] Wilt diseases caused by pathogens such as Fusarium species, for example Fusarium oxysporum.

[0075] Mycotoxins

[0076] In addition, the compounds of formula (I) and compositions comprising the same can reduce the content of mycotoxins in harvested materials and foods and feeds prepared therefrom. Mycotoxins include, but are not limited to, the following: deoxynivalenol (DON), nivalenol, 15-Ac-DON, 3-Ac-DON, T2-toxin and HT2-toxin, fumonisin, zearalenon, moniliformin, fusarin, diaceotoxyscirpenol (DAS), beauvericin, enniatin, fusaroproliferin, fusarenol, ochratoxins, patulin, ergot alkaloids, alkaloids and aflatoxin, which can be produced, for example, by the following fungi: Fusarium species, such as F. acuminatum, F. asiaticum, F. avenaceum, F. crookwellense, F. culmorum, F. graminearum (Gibberella zeae), F.equiseti, F.fujikoroi, F.musarum, F.oxysporum, F.proliferatum, F.poae, F.pseudograminearum, F.sambucinum, F.scirpi, F.semitectum, F.solani, F.sporotrum ichoides), F. langsethiae, F. subglutinans, F. tricinctum, F. verticillioides, etc.; and Aspergillus species, such as A. flavus, A. parasiticus, A. nomius, A. ochraceus, A. clavatus, A. terreus, A. versicolor, A.versicolor; Penicillium species, such as P. verrucosum, P. viridicatum, P. citrinum, P. expansum, P. claviforme, P. roqueforti; Claviceps species, such as C. purpurea, C. fusiformis, C. paspali, C. africana; Stachybotrys species and others. .

[0077] Material protection

[0078] The compounds of the formula (I) and compositions comprising them can also be used in the protection of materials, in particular for protecting industrial materials from attack and destruction by phytopathogenic fungi.

[0079] Furthermore, the compounds of formula (I) and compositions comprising the same can be used as antifouling compositions alone or in combination with other active ingredients.

[0080] In this article, Industrial Materials Should be understood to mean the inanimate material prepared for industrial application.For example, the industrial material that can be protected from microbial alteration or destruction can be adhesive, glue, paper, wallpaper and wood board / cardboard, textile, carpet, leather, timber, fiber and tulle, paint and plastic products, cooling lubricant and other materials that can be infected or destroyed by microorganisms. The parts (for example cooling water loop, cooling and heating system and ventilation and air conditioning unit) of the production equipment and building that can be damaged by the proliferation of microorganisms are also included in the scope of material to be protected.Within the scope of the present invention, industrial material preferably comprises adhesive, size, paper and card, leather, timber, paint, cooling lubricant and heat transfer fluid, more preferably timber.

[0081] The compounds of formula (I) and compositions comprising the same can prevent various adverse effects, such as decay, spoilage, discoloration, fading or mold.

[0082] In the case of treating wood, the compounds of formula (I) and compositions comprising the same can also be used to combat fungal diseases susceptible to growth on the surface of or in the wood.

[0083] woodIt means all types of wood species and all types of processed products of this wood used for construction, such as solid wood, high-density wood, laminated wood and plywood. In addition, the compounds of formula (I) and compositions comprising them can be used to protect objects that come into contact with salt water or brackish water from contamination, in particular hulls, screens, nets, buildings, moorings and signaling systems.

[0084] The compound of formula (I) and the composition comprising it can also be used to protect storage. Storage should be understood to mean natural substances or processed products of plant origin or animal origin, which are of natural origin and need long-term protection. Storage of plant origin such as plants or plant parts (such as stems, leaves, tubers, seeds, fruits, grains) can be protected just after harvesting or by (pre) drying, moistening, crushing, grinding, squeezing or baking processing. Storage also includes wood, including unprocessed wood (such as building wood, electric poles and fences) or finished wood (such as furniture). Storage of animal origin is such as hides, leather, fur and hair. Compounds of formula (I) and compositions comprising it can prevent a variety of adverse effects, such as rotting, decaying, discoloring, fading or mildew.

[0085] Microorganisms capable of degrading or modifying industrial materials include, for example, bacteria, fungi, yeasts, algae and slime organisms. The compounds of formula (I) and compositions comprising them preferably act on fungi, in particular molds, wood-discoloring and wood-destroying fungi (Ascomycetes, Basidiomycetes, Deuteromycetes and Zygomycetes), as well as on slime organisms and algae.Examples include microorganisms of the genera Alternaria, such as Alternaria tenuis; Aspergillus, such as Aspergillus niger; Chaetomium, such as Chaetomium globosum; Coniophora, such as Coniophorapuetana; Lentinus, such as Lentinus tigrinus; Penicillium, such as Penicillium glaucum; Polyporus, such as Polyporus versicolor; Aureobasidium, such as Aureobasidium pullulans; Sclerophoma, such as Sclerophoma pityophila; Trichoderma, for example Trichoderma viride; Ophiostoma spp., Ceratocystis spp., Humicola spp., Petriella spp., Trichurus spp., Coriolus spp., Gloeophyllum spp., Pleurotus spp., Poria spp., Serpula spp., and Tyromyces spp., Cladosporium spp., Paecilomyces spp., Mucor spp., Escherichia spp., for example Escherichia coli. coli); Pseudomonas, such as Pseudomonas aeruginosa; Staphylococcus, such as Staphylococcus aureus, Candida spp., and Saccharomyces spp., such as Saccharomyces cerevisae.

[0086] Plant protection agents may additionally contain one or more other active ingredients, such as fungicides, bactericides, miticides, nematicides, insecticides, biological control agents or herbicides. They may also be mixed with fertilizers, growth regulators, safeners, nitrification inhibitors, chemical semiochemicals and / or other agricultural beneficial agents. This may broaden the spectrum of activity or prevent the development of resistance.

[0087] The active compounds which are known and identified here by their common names are described, for example, in the Pesticide Manual (“The Pesticide Manual” 17th Ed., British Crop Protection Council 2015) or can be found on the Internet (e.g. http: / / www.alanwood.net / pesticides ).

[0088] Examples of fungicides that can be mixed with the compounds and compositions of the present invention are:

[0089] 1) Inhibitors of ergosterol biosynthesis, for example (1.001) cyproconazole, (1.002) difenoconazole, (1.003) epoxiconazole, (1.004) fenbuconazole, (1.005) fenhexamid, (1.006) fenpropidin, (1.007) fenpropimorph, (1.008) fenpyrazamine, (1.009) fluoxytioconazole, (1.010) fluquinconazole, (1.011) flutriafol, (1.012) hexaconazole, (1.013) imazalil, (1.014) imazalil sulfate sulfate), (1.015) ipconazole, (1.016) ipfentrifluconazole, (1.017) mefentrifluconazole, (1.018) metconazole, (1.019) myclobutanil, (1.020) paclobutrazol, (1.021) penconazole, (1.022) prochloraz, (1.023) propiconazole, (1.024) prothioconazole, (1.025) pyrisoxazol ole), (1.026) spiroxamine, (1.027) tebuconazole, (1.028) tetraconazole, (1.029) triadimenol, (1.030) tridemorph, (1.031) triticonazole, (1.032) (1R, 2S, 5S)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol, (1.033) (1S, 2R, 5R)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol, (1.034)034) (2R) -2- (1-chlorocyclopropyl) -4- [(1R) -2,2-dichlorocyclopropyl] -1- (1H-1,2,4-triazol-1-yl) butan-2-ol, (1.035) (2R) -2- (1-chlorocyclopropyl) -4- [(1S) -2,2-dichlorocyclopropyl] -1- (1H-1,2,4-triazol-1-yl) butan-2-ol, (1.036) (2R) -2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1- (1H-1,2,4-triazol-1-yl) propan-2-ol, (1.037) (2S) -2- (1-chlorocyclopropyl) -4- [(1R) -2,2-dichlorocyclopropyl] -1 -(1H-1,2,4-triazol-1-yl)butan-2-ol, (1.038) (2S) -2-(1-chlorocyclopropyl)-4-[(1S)-2,2-dichlorocyclopropyl]-1-(1H-1,2,4-triazol-1-yl)butan-2-ol, (1.039) (2S) -2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol, (1.040) (R) -[3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-1,2-oxazol-4-yl](pyridin-3-yl)methanol, (1.041) (S) -[3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-1,2-oxazol-4-yl](pyridin-3-yl)methanol, phenyl)-5-(2,4-difluorophenyl)-1,2-oxazol-4-yl](pyridin-3-yl)methanol, (1.042) [3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-1,2-oxazol-4-yl](pyridin-3-yl)methanol, (1.043) 1-({(2R,4S)-2-[2-chloro-4-(4-chlorophenoxy)phenyl]-4-methyl-1,3-dioxolan-2-yl}methyl)-1H-1,2,4-triazole, (1.044) 1-({(2S,4S)-2-[2-chloro-4-(4-chlorophenoxy)phenyl]-4-methyl-1,3-dioxolan-2-yl}methyl)-1 H-1,2,4-triazole, (1.045) 1-{[3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxirane-2-yl]methyl}-1H-1,2,4-triazol-5-yl thiocyanate, (1.046) 1-{[rel(2R,3R)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxirane-2-yl]methyl}-1H-1,2,4-triazol-5-yl thiocyanate, (1.047) 1-{[rel(2R,3S)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxirane-2-yl]methyl}-1H-1,2,4-triazol-5-yl thiocyanate, (1.048)048) 2-[(2R,4R,5R)-1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylhept-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.049) 2-[(2R,4R,5S)-1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylhept-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.050) 2-[(2R,4S,5R)-1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylhept-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.051) 2 -[(2R,4S,5S)-1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylhept-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.052) 2-[(2S,4R,5R)-1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylhept-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.053) 2-[(2S,4R,5S)-1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylhept-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.054) 2-[(2S, 4S,5R)-1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylhept-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.055) 2-[(2S,4S,5S)-1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylhept-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.056) 2-[1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylhept-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.057) 2-[6-(4-bromophenoxy)-2-(trifluoromethyl)-3 -pyridinyl]-1-(1,2,4-triazol-1-yl)propan-2-ol, (1.058) 2-[6-(4-chlorophenoxy)-2-(trifluoromethyl)-3-pyridinyl]-1-(1,2,4-triazol-1-yl)propan-2-ol, (1.059) 2-{[3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxirane-2-yl]methyl}-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.060) 2-{[rel(2R,3R)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxirane-2-yl]methyl}-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.061) 2-{[rel(2R,3S)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxirane-2-yl]methyl}-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.062) 3-[2-(1-chlorocyclopropyl)-3-(3-chloro-2-fluoro-phenyl)-2-hydroxy-propyl]imidazole-4-carbonitrile, (1.063) 5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol, (1.064) 5-(allylthio)-1-{[3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxirane-2-yl]methyl}-2,4-dihydro-3H-1,2,4-triazole-3-thione 1H-1,2,4-triazole, (1.065) 5-(allylthio)-1-{[rel(2R,3R)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxirane-2-yl]methyl}-1H-1,2,4-triazole, (1.066) 5-(allylthio)-1-{[rel(2R,3S)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxirane-2-yl]methyl}-1H-1,2,4-triazole, (1.067) 3-[2-(1-chlorocyclopropyl)-3-(3-chloro-2-fluoro-phenyl)-2-hydroxy-propyl]imidazole-4-carbonitrile, (1.068) N'-(2,5-dimethyl-4-(2-methylbenzyl)phenyl)-N-ethyl-N-methylformamidine (formimidamide), (1.069) N'-(2-chloro-4-(4-cyanobenzyl)-5-methylphenyl)-N-ethyl-N-methylformamidine, (1.070) N'-(2-chloro-4-(4-methoxybenzyl)-5-methylphenyl)-N-ethyl-N-methylformamidine, (1.071) N'-(2-chloro-5-methyl-4-phenoxyphenyl)-N-ethyl-N-methyliminoformamide, (1.072) N'-(4-benzyl-2-chloro-5-methylphenyl)-N-ethyl-N-methylformamidine, (1.073 )N'-[2-chloro-4-(2-fluorophenoxy)-5-methylphenyl]-N-ethyl-N-methyliminocarboxamide, (1.074) N'-[5-bromo-6-(2,3-dihydro-1H-inden-2-yloxy)-2-methylpyridin-3-yl]-N-ethyl-N-methyliminocarboxamide, (1.075) N'-{4-[(4,5-dichloro-1,3-thiazol-2-yl)oxy]-2,5-dimethylphenyl}-N-ethyl-N-methyliminocarboxamide, (1.076) N'-{5-bromo-2-methyl-6-[(1-propoxyprop-2-yl)oxy]pyridin-3-yl}-N-ethyl-N-methyliminocarboxamide, (1.077)077) N'-{5-bromo-6-[(1R)-1-(3,5-difluorophenyl)ethoxy]-2-methylpyridin-3-yl}-N-ethyl-N-methyliminocarboxamide, (1.078) N'-{5-bromo-6-[(1S)-1-(3,5-difluorophenyl)ethoxy]-2-methylpyridin-3-yl}-N-ethyl-N-methyliminocarboxamide, (1.079) N'-{5-bromo-6-[(cis-4-isopropylcyclohexyl)oxy]-2-methylpyridin-3-yl}-N-ethyl-N-methyliminocarboxamide, (1.080) N'-{5-bromo-6-[(trans-4 -isopropylcyclohexyl)oxy]-2-methylpyridin-3-yl}-N-ethyl-N-methyliminocarboxamide, (1.081) N'-{5-bromo-6-[1-(3,5-difluorophenyl)ethoxy]-2-methylpyridin-3-yl}-N-ethyl-N-methyliminocarboxamide, (1.082) N-isopropyl-N'-[5-methoxy-2-methyl-4-(2,2,2-trifluoro-1-hydroxy-1-phenylethyl)phenyl]-N-methyliminocarboxamide, (1.083) 4-[(E)-[ethyl(methyl)amino]methyleneamino]-2,5-dimethyl-benzoic acid p-tolylmethyl ester. .

[0090] 2) Inhibitors of respiratory complex I or II, for example (2.001) benzovindiflupyr, (2.002) bixafen, (2.003) boscalid, (2.004) carboxin, (2.005) cyclobutrifluram, (2.006) flubeneteram, (2.007) fluindapyr, (2.008) fluopyram, (2.009) flutolanil, (2.010) fluxapyroxad, (2.011) furazolidone furametpyr, (2.012) inpyrfluxam, (2.013) isofetamid, (2.014) isoflucypram, (2.015) isopyrazam, (2.016) penflufen, (2.017) penthiopyrad, (2.018) pydiflumetofen, (2.019) pyrapropoyne, (2.020) pyraziflumid, (2.021) sedaxane, (2.022) thifluzamide, aka trifluzamide), (2.023) 5,8-difluoro-N-[2-(2-fluoro-4-{[4-(trifluoromethyl)pyridin-2-yl]oxy}phenyl)ethyl]quinazolin-4-amine, (2.024) 5-chloro-N-[2-[1-(4-chlorophenyl)pyrazol-3-yl]oxyethyl]-6-ethyl-pyrimidin-4-amine, (2.025) N-[2-[1-(4-chlorophenyl)pyrazol-3-yl]oxyethyl]quinazolin-4-amine, (2.026) 1,3-dimethyl-N-(1,1,3-trimethyl-2,3-dihydro- 1H-inden-4-yl)-1H-pyrazole-4-carboxamide, (2.027) 1,3-dimethyl-N-[(3R)-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1H-pyrazole-4-carboxamide, (2.028) 1,3-dimethyl-N-[(3S)-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1H-pyrazole-4-carboxamide, (2.029) 1-methyl-3-(trifluoromethyl)-N-[2'-(trifluoromethyl)biphenyl-2-yl]-1H-pyrazole-4-carboxamide, (2.030) 2-fluoro-6-(trifluoromethyl)-N-(1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl)benzamide, (2.031) 3-(difluoromethyl)-1-methyl-N-(1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl)-1H-pyrazole-4-carboxamide, (2.032) 3-(difluoromethyl)-1-methyl-N-[(3S)-1,1,3-trimethyl- 2,3-dihydro-1H-inden-4-yl]-1H-pyrazole-4-carboxamide, (2.033) 3-(difluoromethyl)-N-[(3R)-7-fluoro-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1-methyl-1H-pyrazole-4-carboxamide, (2.034) 3-(difluoromethyl)-N-[(3S)-7-fluoro-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1-methyl-1H-pyrazole-4-carboxamide 1-methyl-1H-pyrazole-4-carboxamide, (2.035) N-[(1R,4S)-9-(dichloromethylene)-1,2,3,4-tetrahydro-1,4-methanonaphthalen-5-yl]-3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxamide, (2.036) N-[(1S,4R)-9-(dichloromethylene)-1,2,3,4-tetrahydro-1,4-methanonaphthalen-5-yl]-3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxamide Tetrahydro-1,4-naphthyl-5-yl]-3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxamide, (2.037) N-[1-(2,4-dichlorophenyl)-1-methoxyprop-2-yl]-3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxamide, (2.038) N-[rac-(1S,2S)-2-(2,4-dichlorophenyl)cyclobutyl]-2-(trifluoromethyl)nicotinamide. .

[0091] 3) Inhibitors of respiratory complex III, such as (3.001) ametoctradin, (3.002) amisulbrom, (3.003) azoxystrobin, (3.004) coumethoxystrobin, (3.005) coumoxystrobin, (3.006) cyazofamid, (3.007) dimoxystrobin, (3.008) enoxastrobin, (3.009) oxathiapiprolin (famoxadone), (3.010) fenamidone, (3.011) fenpicoxamid, (3.012) pyridamole, (3.013) flufenoxystrobin, (3.014) fluoxastrobin, (3.015) kresoxim-methyl, (3.016) mandestrobin, (3.017) metaylpicoxamid, (3.018) metominostrobin bin)、(3.019) metyltetraprole、(3.020) orysastrobin、(3.021) picoxystrobin、(3.022) pyraclostrobin、(3.023) pyrametostrobin、(3.024) pyraoxystrobin、(3.025) trifloxystrobin、(3.026) (2E)-2-{2-[({[(1E)-1-(3-{[(E)-1-fluoro-2-phenylethylene 1-(4-chlorophenyl)-1H-pyrazol-3-yl]oxy}-2-(methoxyimino)-N-methylacetamide, (3.027) (2E,3Z)-5-{[1-(4-chlorophenyl)-1H-pyrazol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamide, (3.028) (2E,3Z)-5-{[1-(4-chlorophenyl)-1H-pyrazol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamide, (3.029) (2R)-2-{2-[(2,5-dimethylphenoxy)methyl]phenyl}-2-methoxy-N-methylacetamide, (3.030)030) (2S)-2-{2-[(2,5-dimethylphenoxy)methyl]phenyl}-2-methoxy-N-methylacetamide, (3.031) (Z,2E)-5-[1-(2,4-dichlorophenyl)pyrazol-3-yl]oxy-2-methoxyimino-N,3-dimethyl-pent-3-enoamide, (3.032) (Z)-2-(5-cyclohexyl-2-methyl-phenoxy)-3-methoxy-prop-2-enoic acid methyl ester, (3.033) (Z)-2-(5-cyclopentyl-2-methyl-phenoxy)-3-methoxy-prop-2-enoic acid methyl ester, (3.034) (Z)-3-methoxy-2-[2-methyl-5-(3-propylpyrazol-1-yl] )phenoxy]prop-2-enoic acid methyl ester, (3.035) (Z)-3-methoxy-2-[2-methyl-5-[3-(trifluoromethyl)pyrazol-1-yl]phenoxy]prop-2-enoic acid methyl ester, (3.036) {5-[3-(2,4-dimethylphenyl)-1H-pyrazol-1-yl]-2-methylbenzyl}carbamic acid methyl ester, (3.037) [rac-2-(4-bromo-7-fluoro-indol-1-yl)-1-methyl-propyl] (2S)-2-[(3-hydroxy-4-methoxy-pyridine-2-carbonyl)amino] propanoate, (3.038) [rac-2-(7-bromo-4-fluoro-indol-1-yl)-1-methyl-propyl] (2S)-2-[ (3.041) [(1S)-1-[1-(1-naphthyl)cyclopropyl]ethyl] (2S)-2-[(3-acetoxy-4-methoxy-pyridine-2-carbonyl)amino]propanoate, (3.039) [rac-2-(7-bromoindol-1-yl)-1-methyl-propyl] (2S)-2-[(3-hydroxy-4-methoxy-pyridine-2-carbonyl)amino]propanoate, (3.040) [rac-2-(3,5-dichloro-2-pyridinyl)-1-methyl-propyl] (2S)-2-[(3-hydroxy-4-methoxy-pyridine-2-carbonyl)amino]propanoate, .042) [(1S)-1-[1-(1-naphthyl)cyclopropyl]ethyl](2S)-2-[(3-hydroxy-4-methoxy-pyridine-2-carbonyl)amino]propanoate, (3.043) [(1S)-1-[1-(1-naphthyl)cyclopropyl]ethyl](2S)-2-[[3-(acetoxymethoxy)-4-methoxy-pyridine-2-carbonyl]amino]propanoate, (3.044) 2-methylpropanoic acid [2-[[(1S)-2-[(1RS,2SR)-2-(3,5-dichloro-2-pyridinyl)-1-methyl-propoxy]-1-methyl-2-oxo-ethyl]carbamoyl]-4-methoxy-3-pyridinyl]oxymethyl ester, (3.045)045) N-(3-ethyl-3,5,5-trimethylcyclohexyl)-3-formamido-2-hydroxybenzamide. .

[0092] 4) Inhibitors of mitosis and cell division, for example (4.001) carbendazim, (4.002) diethofencarb, (4.003) ethaboxam, (4.004) fluopicolide, (4.005) fluopimomide, (4.006) metrafenone, (4.007) pencycuron, (4.008) pyridachlometyl, (4.009) pyriofenone (chlazafe none), (4.010) thiabendazole, (4.011) thiophanate-methyl, (4.012) zoxamide, (4.013) 3-chloro-5-(4-chlorophenyl)-4-(2,6-difluorophenyl)-6-methylpyridazine, (4.014) 3-chloro-5-(6-chloropyridin-3-yl)-6-methyl-4-(2,4,6-trifluorophenyl)pyridazine, (4.015) 4-(2-bromo-4-fluorophenyl)-N-(2,6-difluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.016) 4-(2-bromo-4 -fluorophenyl)-N-(2-bromo-6-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.017) 4-(2-bromo-4-fluorophenyl)-N-(2-bromophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.018) 4-(2-bromo-4-fluorophenyl)-N-(2-chloro-6-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.019) 4-(2-bromo-4-fluorophenyl)-N-(2-chlorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.020) 4-(2-bromo-4-fluorophenyl)-N-(2-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.0 21) 4-(2-chloro-4-fluorophenyl)-N-(2,6-difluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.022) 4-(2-chloro-4-fluorophenyl)-N-(2-chloro-6-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.023) 4-(2-chloro-4-fluorophenyl)-N-(2-chlorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.024) 4-(2-chloro-4-fluorophenyl)-N-(2-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.025) 4-(4-chlorophenyl)-5-(2,6-difluorophenyl)-3,6-dimethylpyridazine, (4.026)026) N-(2-bromo-6-fluorophenyl)-4-(2-chloro-4-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.027) N-(2-bromophenyl)-4-(2-chloro-4-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.028) N-(4-chloro-2,6-difluorophenyl)-4-(2-chloro-4-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine. .

[0093] 5) Compounds capable of multi-site action, such as (5.001) Bordeaux mixture, (5.002) captafol, (5.003) captan, (5.004) chlorothalonil, (5.005) copper hydroxide, (5.006) copper naphthenate, (5.007) copper oxide, (5.008) copper oxychloride, oxychloride), (5.009) copper sulfate (2+), (5.010) dithianon, (5.011) dodine, (5.012) folpet, (5.013) mancozeb, (5.014) maneb, (5.015) metiram, (5.016) metiram zinc zinc), (5.017) oxine-copper, (5.018) propineb, (5.019) sulfur and sulfur preparations including calcium polysulfide, (5.020) thiram, (5.021) zineb, (5.022) ziram, (5.023) 6-ethyl-5,7-dioxo-6,7-dihydro-5H-pyrrolo[3',4':5,6][1,4]dithiino[2,3-c][1,2]thiazole-3-carbonitrile.

[0094] 6) Compounds that can induce host defense, such as (6.001) acibenzolar-S-methyl, (6.002) fosetyl-aluminum, (6.003) fosetyl-calcium, (6.004) fosetyl-sodium, (6.005) isotianil, (6.006) phosphoric acid and its salts, (6.007) probenazole, and (6.008) tiadinil.

[0095] 7) Inhibitors of amino acid and / or protein biosynthesis, for example (7.001) cyprodinil, (7.002) kasugamycin, (7.003) kasugamycin hydrochloride hydrate, (7.004) oxytetracycline, (7.005) pyrimethanil.

[0096] 8) Inhibitors of ATP production, for example (8.001) silthiofam.

[0097] 9) Inhibitors of cell wall synthesis, for example (9.001) benthiavalicarb, (9.002) dimethomorph, (9.003) flumorph, (9.004) iprovalicarb, (9.005) mandipropamid, (9.006) pyrimorph, (9.007) valifenalate, (9.008) (2E)-3-(4-tert-butylphenyl)-3-(2-chloropyridin-4-yl)-1-(morpholin-4-yl)prop-2-en-1-one, (9.009) (2Z)-3-(4-tert-butylphenyl)-3-(2-chloropyridin-4-yl)-1-(morpholin-4-yl)prop-2-en-1-one.

[0098] 10) Inhibitors of lipid synthesis, lipid transport or membrane synthesis, for example (10.001) fluoxapiprolin, (10.002) natamycin, (10.003) oxathiapiprolin, (10.004) propamocarb, (10.005) propamocarb hydrochloride, hydrochloride), (10.006) propamocarb-fosetylate, (10.007) tolclofos-methyl, (10.008) 1-(4-{4-[(5R)-5-(2,6-difluorophenyl)-4,5-dihydro-1,2-oxazol-3-yl]-1,3-thiazol-2-yl}piperidin-1-yl)-2-[5-methyl-3-(trifluoromethyl)-1H-pyrazol-1-yl]ethanone, (10.009) 1-(4-{4-[(5R)-5-(2,6-difluorophenyl)-4,5-dihydro-1,2-oxazol-3-yl]-1,3-thiazol-2-yl}piperidin-1-yl)-2-[5-methyl-3-(trifluoromethyl)-1H-pyrazol-1-yl]ethanone, [(5S)-5-(2,6-difluorophenyl)-4,5-dihydro-1,2-oxazol-3-yl]-1,3-thiazol-2-yl}piperidin-1-yl)-2-[5-methyl-3-(trifluoromethyl)-1H-pyrazol-1-yl]ethanone, (10.010) 2-[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]-1-[4-(4-{5-[2-(prop-2-yn-1-yloxy)phenyl]-4,5-dihydro-1,2-oxazol-3-yl}-1,3-thiazol-2-yl)piperidin-1-yl]ethanone, (10.011) 2-[3,5 1-[4-(4-{5-[2-chloro-6-(prop-2-yn-1-yloxy)phenyl]-4,5-dihydro-1,2-oxazol-3-yl}-1,3-thiazol-2-yl)piperidin-1-yl]ethanone, (10.012) 2-[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]-1-[4-(4-{5-[2-fluoro-6-(prop-2-yn-1-yloxy)phenyl]-4,5-dihydro-1,2-oxazol-3-yl}-1,3-thiazol-2-yl)piperidin-1-yl]ethanone, (1 0.013) methanesulfonic acid 2-{(5R)-3-[2-(1-{[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thiazol-4-yl]-4,5-dihydro-1,2-oxazol-5-yl}-3-chlorophenyl ester, (10.014) methanesulfonic acid 2-{(5S)-3-[2-(1-{[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thiazol-4-yl]-4,5-dihydro-1,2-oxazol-5-yl}-3-chlorophenyl ester, (10.015) methanesulfonic acid 2-{3-[2-(1-{[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thiazol-4-yl]-4,5-dihydro-1,2-oxazol-5-yl}phenyl ester, (10.016) methanesulfonic acid 3-[2-(1-{[5-methyl-3-(trifluoromethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thiazol-4-yl]-1,5-dihydro-2,4-benzodioxepin-6-yl ester, (10.017) methanesulfonic acid 9-fluoro-3-[2-(1-{[5-methyl-3-(trifluoromethyl)-1H-pyrazol- 1-{[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thiazol-4-yl]-1,5-dihydro-2,4-benzodioxepin-6-yl methanesulfonate, (10.019) 3-[2-(1-{[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thiazol-4-yl]-9-fluoro-1,5-dihydro-2,4-benzodioxepin-6-yl methanesulfonate. .

[0099] 11) Inhibitors of melanin biosynthesis, for example (11.001) tolprocarb, (11.002) tricyclazole.

[0100] 12) Inhibitors of nucleic acid synthesis, for example (12.001) benalaxyl, (12.002) benalaxyl-M (kiralaxyl), (12.003) metalaxyl, (12.004) metalaxyl-M (mefenoxam).

[0101] 13) Inhibitors of signal transduction, for example, (13.001) fludioxonil, (13.002) iprodione, (13.003) procymidone, (13.004) proquinazid, (13.005) quinoxyfen, (13.006) vinclozolin.

[0102] 14) Compounds that can act as uncouplers, for example (14.001) fluazinam and (14.002) meptyldinocap.

[0103] 15) Other compounds, such as (15.001) abscisic acid, (15.002) aminopyrifen, (15.003) benthiazole, (15.004) bethoxazin, (15.005) capsimycin, (15.006) carvone, (15.007) chinomethionat, (15.008) chloroinconazide, (15.009) cufraneb, (15.010) cyflufenamid, (15.011) cymoxanil moxanil), (15.012) cyprosulfamide, (15.013) dipymetitrone, (15.014) D-tagatose, (15.015) flufenoxadiazam, (15.016) flumetylsulforim, (15.017) flutianil, (15.018) ipflufenoquin, (15.019) methyl isothiocyanate, (15.020) mildiomycin, (15.021) nickeldimethoxybenzyl esters ldithiocarbamate), (15.022) nitrothal-isopropyl, (15.023) oxyfenthiin, (15.024) pentachlorophenol and its salts, (15.025) picarbutrazox, (15.026) quinofumelin, (15.027) tebufloquin, (15.028) tecloftalam, (15.029) tolnifanide, (15.030) 2-(6-benzylpyridin-2-yl)quinazoline, ( 15.031) 2-[6-(3-fluoro-4-methoxyphenyl)-5-methylpyridin-2-yl]quinazoline, (15.032) 2-phenylphenol and salts, (15.033) 4-amino-5-fluoropyrimidin-2-ol (tautomeric form: 4-amino-5-fluoropyrimidin-2(1H)-one), (15.034) 4-oxo-4-[(2-phenylethyl)amino]butyric acid, (15.035) 5-amino-1,3,4-thiadiazole-2-thiol, (15.036) 5-chloro-N'-phenyl-N'-(prop-2-yn-1-yl)thiophene-2-sulfonylhydrazide, (15.037) 5-fluoro-2-[(4-fluorobenzyl)oxy]pyrimidin-4-amine, (15.038) 5-fluoro-2-[(4-fluorobenzyl)oxy]pyrimidin-4-amine, (15.039) 5-fluoro-2-[(4-fluorobenzyl)oxy]pyrimidin-4-amine, (15.040) 5-fluoro-2-[(4-fluorobenzyl)oxy]pyrimidin-4-amine, (15.041) 5-fluoro-2-[(4-fluorobenzyl)oxy]pyrimidin-4-amine, (15.042) 5-fluoro-2-[(4-fluorobenzyl)oxy]pyrimidin-4-amine, (15.043) 5-fluoro-2-[(4-fluorobenzyl)oxy]pyrimidin-4-amine, (15.044) 5-fluoro-2-[(2-phenylethyl)amino]butyric acid, (15.045) 5-amino-1,3,4-thia(038) 5-fluoro-2-[(4-methylbenzyl)oxy]pyrimidin-4-amine, (15.039) but-3-yn-1-yl {6-[({[(Z)-(1-methyl-1H-tetrazol-5-yl)(phenyl)methylene]amino}oxy)methyl]pyridin-2-yl}carbamate, (15.040) (2Z)-3-amino-2-cyano-3-phenylacrylate, (15.041) methyl 2-[acetyl-[2-ethylsulfonyl-4-(trifluoromethyl)benzoyl]amino]-5-(trifluoromethoxy)benzoate, (15.042) N-acetyl-N-[2-bromo-4-(trifluoromethoxy)phenyl]-2-ethylsulfonyl-4-(trifluoromethyl)benzoyl]amino )benzamide, (15.043)phenazine-1-carboxylic acid, (15.044)3,4,5-trihydroxybenzoic acid propyl ester, (15.045)quinolin-8-ol, (15.046)quinolin-8-ol sulfate (2:1), (15.047) (2R)-2-benzyl-N-(8-fluoro-2-methyl-3-quinolinyl)-2,4-dimethyl-pentanamide, (15.048) (2S)-2-benzyl-N-(8-fluoro-2-methyl-3-quinolinyl)-2,4-dimethyl-pentanamide, (15.049)1-(4,5-dimethyl-1H-benzimidazol-1-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline, (15. 050) 1-(4,5-dimethylbenzimidazol-1-yl)-4,4,5-trifluoro-3,3-dimethyl-isoquinoline, (15.051) 1-(5-(fluoromethyl)-6-methyl-pyridin-3-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline, (15.052) 1-(5,6-dimethylpyridin-3-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline, (15.053) 1-(6-(difluoromethyl)-5-methoxy-pyridin-3-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline, (15.054) 1-(6-(difluoromethyl)-5-methyl-pyridin-3 -yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline, (15.055) 1-(6,7-dimethylpyrazolo[1,5-a]pyridin-3-yl)-4,4,5-trifluoro-3,3-dimethyl-isoquinoline, (15.056) 1-(6,7-dimethylpyrazolo[1,5-a]pyridin-3-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline, (15.057) 2-{2-fluoro-6-[(8-fluoro-2-methylquinolin-3-yl)oxy]phenyl}propan-2-ol, (15.058) 3-(4,4,5-trifluoro-3,3-dimethyl-3,4-dihydroisoquinolin-1-yl)quinoline, (15.059) 3-(4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinolin-1-yl)-8-fluoroquinoline, (15.060) 3-(4,4-difluoro-5,5-dimethyl-4,5-dihydrothieno[2,3-c]pyridin-7-yl)quinoline, (15.061) 3-(5-fluoro-3,3,4,4-tetramethyl-3,4-dihydroisoquinolin-1-yl)quinoline, (15.062) 4,4-difluoro-3,3-dimethyl-1-(4-methylbenzimidazol-1-yl)isoquinoline, (15.063) 4,4-difluoro-3,3-dimethyl-1-(6-methylpyrazolo[1,5-a]pyridin-3-yl)isoquinoline, (15.064) 5-bromo-1- (5,6-dimethylpyridin-3-yl)-3,3-dimethyl-3,4-dihydroisoquinoline, (15.065) 7,8-difluoro-N-[rac-1-benzyl-1,3-dimethyl-butyl]quinoline-3-carboxamide, (15.066) 8-fluoro-3-(5-fluoro-3,3,4,4-tetramethyl-3,4-dihydroisoquinolin-1-yl)-quinoline, (15.067) 8-fluoro-3-(5-fluoro-3,3-dimethyl-3,4-dihydroisoquinolin-1-yl)-quinoline, (15.068) 8-fluoro-N-(4,4,4-trifluoro-2-methyl-1-phenylbutan-2-yl)quinoline-3-carboxamide, (15.069) 8-fluoro-N-[(1R)-1-[(3 quinoline-3-carboxamide, (15.070) 8-fluoro-N-[(1S)-1-[(3-fluorophenyl)methyl]-1,3-dimethyl-butyl]quinoline-3-carboxamide, (15.071) 8-fluoro-N-[(2S)-4,4,4-trifluoro-2-methyl-1-phenylbutan-2-yl]quinoline-3-carboxamide, (15.072) 8-fluoro-N-[rac-1-[(3-fluorophenyl)methyl]-1,3-dimethyl-butyl]quinoline-3-carboxamide, (15.073) 9-fluoro-2,2-dimethyl-5-(quinolin-3-yl)-2,3-dihydro-1,4-benzoxazepine azepine), (15.074) N-(2,4-dimethyl-1-phenylpentan-2-yl)-8-fluoroquinoline-3-carboxamide, (15.075) N-[(1R)-1-benzyl-1,3-dimethyl-butyl]-7,8-difluoro-quinoline-3-carboxamide, (15.076) N-[(1S)-1-benzyl-1,3-dimethyl-butyl]-7,8-difluoro-quinoline-3-carboxamide, (15.077) N-[(2R)-2,4-dimethyl-1-phenylpentan-2-yl]-8-fluoroquinoline-3-carboxamide, (15.078) rac-2-benzyl-N-(8-fluoro-2-methyl-3-quinolyl)-2,4-dimethyl-pentanamide, (15.079) 1,1-diethyl-3-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]urea, (15.080) 1,3-dimethoxy-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]urea, (15.081) 1-[[3-fluoro-4-(5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl)phenyl]methyl]azepan-2-one, (15.082) 1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]piperidin-2-one, (15.083) 1-methoxy-1-methyl-3-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]urea urea, (15.084) 1-methoxy-3-methyl-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]urea, (15.085) 1-methoxy-3-methyl-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]urea, (15.086) 2-(difluoromethyl)-5-[2-[1-(2,6-difluorophenyl)cyclopropyloxy]pyrimidin-5-yl]-1,3,4-oxadiazole, (15.087) 2,2-difluoro-N-methyl-2-[4-[5-(trifluoromethyl)-1,2,4-oxadiazole- 3-yl]phenyl]acetamide, (15.088) 3,3-dimethyl-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]piperidin-2-one, (15.089) 3-ethyl-1-methoxy-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]urea, (15.090) 4,4-dimethyl-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]pyrrolidin-2-one, (15.091) 4,4-dimethyl-2-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]isoxazolidine- 3-one, (15.092) 4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl dimethylcarbamate, (15.093) 5,5-dimethyl-2-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]isoxazolidin-3-one, (15.094) 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[(1R)-1-(2,6-difluorophenyl)ethyl]pyrimidin-2-amine, (15.095) 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[(1R)-1-(2,6-difluorophenyl)propyl]pyrimidin-2-amine, (15.096) 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[(1R)-1-(2-fluorophenyl)ethyl]pyrimidin-2-amine, (15.097) 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[(1R)-1-(2-fluorophenyl)ethyl]pyrimidin-2-amine, (15.098) 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[(1R)-1-(3,5-difluorophenyl)ethyl]pyrimidin-2-amine, (15.099) 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[(1R)-1-phenylethyl]pyrimidin-2-amine, (15.1 00) 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluorophenyl)cyclopropyl]pyrimidin-2-amine, (15.101) 5-methyl-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]pyrrolidin-2-one, (15.102) 1-{4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzyl}-1H-pyrazole-4-carboxylic acid ethyl ester, (15.103) methyl {4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}carbamate, (15.104) N-(1-methylcyclopropyl)-4-[5-(trifluoromethyl)-1,2,4- oxadiazol-3-yl]benzamide, (15.105) N-(2,4-difluorophenyl)-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide, (15.106) N,2-dimethoxy-N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]propanamide, (15.107) N,N-dimethyl-1-{4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzyl}-1H-1,2,4-triazol-3-amine, (15.108) N-[(E)-methoxyiminomethyl]-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide, (15.110) N-[(E)-methoxyiminomethyl]-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide, (15.111) N-[(E)-methoxyiminomethyl]-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide, (15.112) N-[(E)-methoxyiminomethyl]-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide, (15.113) N-[(E)-methoxyiminomethyl]-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide, (15.114) N-[(E)-methoxyiminomethyl]- 109) N-[(E)-N-methoxy-C-methyl-carbonimino]-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide, (15.110) N-[(Z)-methoxyiminomethyl]-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide, (15.111) N-[(Z)-N-methoxy-C-methyl-carbonimino]-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide, (15.112) N-[[2,3-difluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]-3,3,3-trifluoro-propionamide, (15.113) N-[[2,3-difluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]-3,3,3-trifluoro-propionamide, (15.114) N-[[2,3-difluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]-3,3,3-trifluoro-propionamide, (15.115) N-[[2,3-difluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]-3,3,3-trifluoro-propionamide, (15.116) N-[[2,3-difluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]-3,3,3-trifluoro-propionamide, (15.117) N-[[2,3-difluoro-4-[5-(trifluoromethyl)113) N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]propanamide, (15.114) N-[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]cyclopropanecarboxamide, (15.115) N-{2,3-difluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzyl}butanamide, (15.11 6) N-{4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzyl}cyclopropanecarboxamide, (15.117) N-{4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}propionamide, (15.118) N-allyl-N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]acetamide, (15.119) N- Allyl-N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]propionamide, (15.120) N-ethyl-2-methyl-N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]propionamide, (15.121) N-methoxy-N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl] methyl] cyclopropanecarboxamide, (15.122) N-methyl-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide, (15.123) N-methyl-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]thiobenzamide, (15.124) N-methyl-N-phenyl-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide. .

[0104] All named mixing partners of groups (1) to (15) described above may be present in the form of free compounds or, if their functional groups are capable of salt formation, in the form of their agrochemically active salts.

[0105] The compounds and compositions of the present invention may also be combined with one or more biological control agents.

[0106] The term "biological control" as used herein is defined as the control of harmful organisms, such as phytopathogenic fungi and / or insects and / or mites and / or nematodes, by the use and application of biological control agents.

[0107] As used herein, the term "biological control agent" is defined as an organism other than a pest organism, and / or a protein or secondary metabolite produced by the organism for biological control. The definition of biological control agent includes mutants of a second organism. The term "mutant" refers to a variant of a parent strain, and methods for obtaining a mutant or variant having an insecticidal activity greater than that expressed by the parent strain. "Parent strain" is defined herein as the original strain before mutation. To obtain the mutant, the parent strain can be treated with a chemical, such as N-methyl-N'-nitro-N-nitrosoguanidine, ethylmethanesulfonamide, or irradiated by gamma rays, X-rays or ultraviolet radiation, or by other methods well known to those skilled in the art. The mechanisms of known biological control agents include the use of enteric bacteria to control root rot by competing with fungi for root surface space. Bacterial toxins (such as antibiotics) have been used to control pathogens. The toxin can be isolated and applied directly to the plant, or the bacterial genus and species that produce the toxin can be applied to produce the toxin in situ.

[0108] A "variant" is a strain having all of the identifying characteristics of a NRRL or ATCC Accession No. set forth herein and can be identified as having a genome that hybridizes under high stringency conditions for the genome of the NRRL or ATCC Accession No.

[0109] "Hybridization" refers to the reaction of one or more polynucleotides to form a complex, which is stabilized by hydrogen bonds between nucleotide residues. Hydrogen bonds can be produced by Watson-Crick base pairing, Hoogstein bonding or any other sequence-specific means. The complex can include two chains forming a double-stranded structure, three or more chains forming a multi-stranded complex, a single self-hybridizing chain or any combination of these. Hybridization reactions can be carried out under different "stringent" conditions. Typically, low-stringency hybridization reactions are carried out at about 40°C in 10X SSC or a solution of equal ionic strength / temperature. Moderately stringent hybridization reactions are typically carried out in 6X SSC at about 50°C, and high-stringency hybridization reactions are typically carried out in 1XSSC at about 60°C.

[0110] Variants of NRRL or ATCC registration numbers can also be defined as strains having a genome sequence identity greater than 85%, more preferably greater than 90% or more preferably greater than 95% with the NRRL or ATCC registration number. A polynucleotide or polynucleotide region (or polypeptide or polypeptide region) has a certain percentage (e.g., 80%, 85%, 90% or 95%) of "sequence identity" with another sequence, which means that, when compared, the base (or amino acid) percentage is the same when comparing the two sequences. This comparison and homology percentage or sequence identity can be determined using software programs known in the art, for example, those programs described in Current Protocols in Molecular Biology (FM Ausubel et al., eds., 1987).

[0111] NRRL is the abbreviation of Agricultural Research Service Culture Collection. It is an international depository institution for microbial strains established in accordance with the Budapest Treaty (a treaty on international recognition of the deposit of microorganisms for the purpose of patent procedure). Its address is National Center for Agricultural Utilization Research, Agricultural Research service, USDepartment of Agriculture, 1815 North University Street, Peroira, Illinois 61604 USA.

[0112] ATCC is the abbreviation of American Type Culture Collection. It is an international depository institution for microbial strains established in accordance with the Budapest Treaty (a treaty on international recognition of the deposit of microorganisms for the purpose of patent procedure). Its address is ATCC Patent Depository, 10801 University Blvd., Manassas, VA 10110 USA.

[0113] Examples of biological control agents that can be combined with the compounds and compositions of the present invention are:

[0114] (A) an antibacterial agent selected from the group consisting of:

[0115] (A1) Bacteria, such as (A1.01) Bacillus subtilis, in particular strain QST713 / AQ713 (available from Bayer CropScience LP, US as SERENADE OPTI or SERENADE ASO, registration number NRRLB21661, US Patent No. 6,060,051); (A1.02) Bacillus sp., in particular strain D747 (available from Kumiai Chemical Industry Co., Ltd. as DOUBLE FERM BP-8234, US Pat. No. 7,094,592); (A1.03) Bacillus pumilus, in particular strain BU F-33, NRRL50185 (available from BASF as product (EPA registration number 71840-19)); (A1.04) Bacillus subtilis var. amyloliquefaciens strain FZB24, registration number DSM10271 (available from Novozymes as or ECO (EPA registration number 70127-5)); (A1.05) Paenibacillus sp. strain with registration number NRRL B-50972 or registration number NRRL B-67129, WO 2016 / 154297; (A1.06) Bacillus subtilis strain BU1814, (available from BASF SE as PLUS, FLEX and EXTRA); (A1.07) Bacillus mojavensis strain R3B (accession number NCAIM (P) B001389) (WO2013 / 034938) from Certis USA LLC, a subsidiary of Mitsui & Co.; (A1.08) Bacillus subtilis CX-9060 from Certis USA LLC, a subsidiary of Mitsui & Co.; (A1.09) Paenibacillus polymyxa, in particular strain AC-1 (e.g., from Green Biotech Company Ltd. ); (A1.10) Pseudomonas proradix (e.g., from Sourcon Padena ); (A1.11) Pantoea agglomerans, in particular strain E325 (accession number NRRL B-21856) (available from Northwest Agri Products as BLOOMTIME BIOLOGICAL TM FDBIOPESTICIDE obtained); and

[0116] (A2) Fungi, such as (A2.01) Aureobasidium pullulans, in particular blastospores of strain DSM 14940, blastospores of strain DSM 14941 or a mixture of blastospores of strains DSM 14940 and DSM 14941 (e.g., and BLOSSOM ); (A2.02) Pseudozyma aphidis (as described by Yissum Research Development Company of the Hebrew University of Jerusalem in WO 2011 / 151819); (A2.03) Saccharomyces cerevisiae, in particular strains of CNCM No. I-3936, CNCM No. I-3937, CNCM No. I-3938 or CNCM No. I-3939 from Lesaffre et Compagnie, FR (WO 2010 / 086790);

[0117] (B) a biofungicide selected from the group consisting of:

[0118] (B1) bacteria, for example (B1.01) Bacillus subtilis, in particular strain QST713 / AQ713 (available from Bayer CropScience LP, US as SERENADE OPTI or SERENADE ASO, registration number NRRL B21661 and described in US Pat. No. 6,060,051); (B1.02) Bacillus pumilus, in particular strain QST2808 (available from Bayer CropScience LP, US as (B1.03) Bacillus pumilus, in particular strain GB34 (available from Bayer AG, DE as Yield (B1.04) Bacillus pumilus, in particular strain BU F-33, registration number NRRL50185 (available from BASF as part of the CARTISSA product (EPA registration number 71840-19)); (B1.05) Bacillus amyloliquefaciens, in particular strain D747 (available from Kumiai Chemical Industry Co., Ltd. as Double Nickel TM (B1.06) Bacillus subtilis Y1336 (available from Bion-Tech, Taiwan, China, with WP, registered as a biofungicide in Taiwan under registration numbers 4764, 5454, 5096 and 5277); (B1.07) Bacillus subtilis MBI 600 (available from BASF SE as SUBTILEX), registration number NRRL B-50595, U.S. Patent No. 5,061,495; (B1.08) Bacillus subtilis strain GB03 (available from Bayer AG, DE as (B1.09) Bacillus subtilis var. amyloliquefaciens strain FZB24, registration number DSM 10271 (available from Novozymes as or ECO (EPA Accession No. 70127-5)); (B1.10) Bacillus mycoides, isolate J, Accession No. B-30890 (available from Certis USA LLC, a subsidiary of Mitsui & Co., as BMJ or WG and LifeGard TM (B1.11) Bacillus licheniformis, in particular strain SB3086 with accession number ATCC 55406, WO 2003 / 000051 (available from Novozymes as Biofungicide and GREEN RELEAF TM (B1.12) Bacillus strain with registration number NRRL B-50972 or registration number NRRL B-67129, WO 2016 / 154297; (B1.13) Bacillus subtilis strain BU1814 (available from BASF SE as PLUS, FLEX and EXTRA); (B1.14) Bacillus subtilis CX-9060, from Certis USA LLC, a subsidiary of Mitsui & Co.; (B1.15) Bacillus amyloliquefaciens strain F727 (also known as strain MBI110) (NRRL Accession No. B-50768; WO 2014 / 028521) (from Marrone Bio Innovations ); (B1.16) Bacillus amyloliquefaciens strain FZB42, registration number DSM 23117 (available from ABiTEP, DE (B1.17) Bacillus licheniformis FMCH001 and Bacillus subtilis FMCH002 (from FMC (WG) and (WP)); (B1.18) Bacillus mojaveensis strain R3B (accession number NCAIM (P) B001389) (WO 2013 / 034938), from Certis USA LLC, a subsidiary of Mitsui & Co.; (B1.19) Paenibacillus polymyxa plantarum subsp. (WO 2016 / 020371), from BASF SE; (B1.20) Paenibacillus epiphyticus (WO 2016 / 020371), from BASF SE; (B1.21) Pseudomonas chlororaphis strain AFS009, accession number NRRL B-50897, WO 2017 / 019448 (e.g., HOWLER of AgBiome Innovations, US TM and ); (B1.22) Pseudomonas chlororaphis, in particular strain MA342 (e.g., Bioagri and Koppert and ); (B1.23) Streptomyces lydicus strain WYEC108 (also known as Streptomyces lydicus strain WYCD108US) (from Novozymes and ); (B1.24) radiobacterium strain K84 (e.g., from AgBioChem, CA ); (B1.25) radiobacterium strain K1026 (e.g., NOGALL from BASF SE TM ); (B1.26) Bacillus subtilis KTSB strain (from Donaghys ); (B1.27) Bacillus subtilis IAB / BS03 (AVIV from STK Bio-Ag Technologies TM); (B1.28) Bacillus subtilis strain Y1336 (from Bion-Tech, Taiwan, China WP, registered as a biocide in Taiwan under registration numbers 4764, 5454, 5096 and 5277); (B1.29) Bacillus amyloliquefaciens isolate B246 (e.g., AVOGREEN from University of Pretoria TM ); (B1.30) methylotrophic Bacillus strain BAC-9912 (from Chinese Academy of Sciences' Institute of Applied Ecology); (B1.31) Pseudomonas proradix (e.g., from Sourcon Padena ); (B1.32) Streptomyces glaucum strain K61 (also known as Streptomyces flavosum strain K61) (accession number DSM 7206) (from Verdera From BioWorks See Crop Protection 2006, 25, 468-475); (B1.33) Pseudomonas fluorescens strain A506 (e.g., from NuFarm A506); and

[0119] (B2) Fungi, for example: (B2.01) Coniothyrium minitans, in particular strain CON / M / 91-8 (registration number DSM-9660; e.g. ); (B2.02) Metschnikowia fructicola, in particular strain NRRL Y-30752; (B2.03) Microsphaeropsis ochracea; (B2.04) Trichoderma atroviride, in particular strain SC1 (accession number CBS122089, WO 2009 / 116106 and U.S. Pat. No. 8,431,120 (from Bi-PA)), strain 77B (T77 from Andermatt Biocontrol) or strain LU132 (e.g. Sentinel from Agrimm Technologies Limited); (B2.05) Trichoderma harzianum strain T-22, (e.g. Trianum-P from Andermatt Biocontrol or Koppert) or strain Cepa Simb-T5 (from Simbiose Agro); (B2.06) pink sticky mold (also known as Clonostachys rosea f.rosea), in particular strain 321U from Adjuvants Plus, strain ACM941 as disclosed in Xue (Efficacy of Clonostachys rosea strain ACM941 and fungicide seedtreatments for controlling the root tot complex of field pea, Can Jour Plant Sci 83(3):519-524), or strain IK726 (Jensen DF et al., Development of a biocontrol agent for plant disease control with special emphasis on thenear commercial fungal antagonist Clonostachys rosea strain 'IK726'; Australas Plant Pathol. 2007; 36:95-101); (B2.07) yellow vermicular mold (Talaromyces flavus), strain V117b; (B2.08) green wood mold (Trichoderma viride), in particular strain B35 (Pietr et al., 1993, Zesz. Nauk. A Rw Szczecinie 161: 125-137); (B2.09) Trichoderma asperellum, in particular strain SKT-1, registration number FERM P016510 (e.g. from Kumiai Chemical Industry. ), strain T34 (e.g. T34 Biocontrol from Biocontrol Technologies SL, ES) or strain ICC 012 from Isagro; (B2.10) Trichoderma atroviride, strain CNCM I-1237 (e.g. WP); (B2.11) dark green Trichoderma, strain number V08 / 002387; (B2.12) dark green Trichoderma, strain NMI number V08 / 002388; (B2.13) dark green Trichoderma, strain NMI number V08 / 002389; (B2.14) dark green Trichoderma, strain NMI number V08 / 002390; (B2.15) dark green Trichoderma, strain LC52 (e.g. Tenet provided by Agrimm Technologies Limited); (B2.16) dark green Trichoderma, strain ATCC 20476 (IMI 206040); (B2.17) dark green Trichoderma, strain T11 (IMI352941 / CECT20498; (B2.18); Trichoderma harmatum; (B2.19) Trichoderma harzianum; (B2.20) Trichoderma harzianum rifai T39 (e.g. from Makhteshim, US ); (B2.21) Trichoderma asperellum, in particular strain kd (e.g. T-Gro from Andermatt Biocontrol); (B2.22) Trichoderma harzianum, strain ITEM 908 (e.g. Trianum-P from Koppert); (B2.23) Trichoderma harzianum, strain TH35 (e.g. Root-Pro provided by Mycontrol); (B2.24) Trichoderma virens (also known as Gliocladium virens), in particular strain GL-21 (e.g. SoilGard provided by Certis, US); (B2.25) Trichoderma viride, strain TV1 (e.g. Trianum-P provided by Koppert); (B2.26) Ampelomyces quisqualis, in particular strain AQ 10 (e.g. AQ ); (B2.27) budding mold, in particular spores of strain DSM14940; (B2.28) budding mold, in particular spores of strain DSM14941; (B2.29) budding mold, in particular a mixture of spores of strains DSM14940 and DSM 14941 (e.g. provided by bio-ferm, CH ); (B2.30) Cladosporium cladosporioides, strain H39, registration number CBS122244, US2010 / 0291039 (provided by Stichting Dienst Landbouwkundig Onderzoek); (B2.31) Gliocladium catenulatum (synonym: Clonostachys rosea f. catenulate) strain J1446 (provided by Lallemand, for example) ); (B2.32) conidia of Lecanicillium lecanii (formerly Verticillium lecanii) strain KV01 (e.g. provided by Koppert / Arysta ); (B2.33) Penicillium vermiculatum; (B2.34) Pichia anomala, strain WRL-076 (NRRL Y-30842), U.S. Patent No. 7,579,183; (B2.35) Trichoderma aureum, strain SKT-1 (FERM P-16510), Japanese Patent Application (Publication) 11-253151A; (B2.36) Trichoderma aureum, strain SKT-2 (FERM P-16511), Japanese Patent Application (Publication) 11-253151A; (B2.37) Trichoderma aureum, strain SKT-3 (FERM P-17021), Japanese Patent Application (Publication) 11-253151A; (B2.38) Trichoderma gemsii gamsii) (formerly T. viride), strain ICC080 (IMI CC 392151 CABI, e.g. BioDerma provided by AGROBIOSOL DE MEXICO, SADEC.V.); (B2.39) Trichoderma harzianum, strain DB 103 (available from Dagutat Biolab 7456); (B2.40) Trichoderma polysporum, strain IMI 206039 (e.g., Binab TF WP provided by BINABBio-Innovation AB, Sweden); (B2.41) Trichoderma stromaticum, accession number Ts3550 (e.g., Tricovab provided by CEPLAC, Brazil); (B2.42) Ulocladium oudemansii strain U3, accession number NM 99 / 06216 (e.g., provided by Botry-Zen Ltd, NZ and from BioWorks, Inc. ); (B2.43) Verticillium albo-atrum (formerly V. dahliae), strain WCS850, accession number WCS850, deposited with the Central Bureau for FungiCultures (e.g. DUTCH provided by Tree Care Innovations ); (B2.44) Verticillium chlamydosporium; (B2.45) a mixture of Trichoderma asperellum strain ICC012 (also known as Trichoderma harzianum ICC012), registration number CABI CC IMI 392716 and Trichoderma gemsii (formerly Trichoderma viride) strain ICC 080, registration number IMI 392151 (e.g., BIO-TAM from Isagro USA, Inc. TM and Agrobiosol de Mexico, SAde CV (B2.46) Trichoderma aspergillus JM41R (Registration No. NRRL B-50759) (TRICHO from BASF SE ); (B2.47) Aspergillus flavus strain NRRL 21882 (product from Syngenta / ChemChina is called ); (B2.48) Chaetomium cupreum (accession number CABI 353812) (e.g., BIOKUPRUM TM ); (B2.49) Saccharomyces cerevisiae, in particular strain LASO2 (from Agro-Levures et Dérivés), strain LAS117 cell wall (from Lesaffre From BASF SE ), and strains of CNCM No. I-3936, CNCM No. I-3937, CNCM No. I-3938, and CNCM No. I-3939 from Lesaffre et Compagnie, FR (WO 2010 / 086790); (B2.50) Trichoderma virens strain G-41, formerly known as Gliocladium virens (Accession No. ATCC 20906) (e.g., from BioWorks, US PLUS WP and PLUS WP); (B2.51) Trichoderma hamatum, registration number ATCC28012; (B2.52) Ampelomyces quisqualis strain AQ10, registration number CNCM I-807 (e.g., AQ ); (B2.53) Phlebiopsis gigantea strain VRA 1992 (from Danstar Ferment C); (B2.54) Penicillium steckii (DSM 27859; WO 2015 / 067800) from BASF SE; (B2.55) Chaetomium globosum (available from Rivale (B2.56) Cryptococcus flavescens, strain 3C (NRRL Y-50378); (B2.57) Dactylaria candida; (B2.58) Dilophosphora alopecuri (available from TWIST (B2.59) Fusarium oxysporum, strain Fo47 (available from Natural Plant Protection (B2.60) yeast Pseudozyma flocculosa, strain PF-A22 UL (available from Plant Products Co., CA L); (B2.61) Trichoderma magamsii (formerly T. viride), strain ICC080 (IMI CC 392151 CABI) (available from AGROBIOSOL DEMEXICO, SADE CV (B2.62) Trichoderma apices (eg the product TrichoPlus from BASF); (B2.63) Muscodor roseus, in particular strain A3-5 (accession number NRRL30548); (B2.64) Simplicillium lanosoniveum.

[0120] (C) Biological control agents that can be combined with the compound composition of the present invention and have the effect of improving plant growth and / or plant health include:

[0121] (C1) A bacterium selected from the group consisting of: (C1.01) Bacillus pumilus, in particular strain QST2808 (NRRL registration number B-30087); (C1.02) Bacillus subtilis, in particular strain QST713 / AQ713 (NRRL registration number B-21661 and described in U.S. Pat. No. 6,060,051; available from Bayer CropScience LP, US Opti or ASO); (C1.03) Bacillus subtilis, in particular strain AQ30002 (accession number NRRL B-50421 and described in U.S. patent application Ser. No. 13 / 330,576); (C1.04) Bacillus subtilis, in particular strain AQ30004 (NRRL B-50455 and described in U.S. patent application Ser. No. 13 / 330,576); (C1.05) Sinorhizobium meliloti strain NRG-185-1 (from Bayer CropScience GOLD); (C1.06) Bacillus subtilis strain BU1814, (available from BASF SE as (obtained); (C1.07) Bacillus subtilis rm303 (from Biofilm Crop Protection ); (C1.08) Bacillus amyloliquefaciens pm414 (from Biofilm Crop Protection ); (C1.09) Bacillus mycoides BT155 (NRRL No. B-50921), (C1.10) Bacillus mycoides EE118 (NRRL No. B-50918), (C1.11) Bacillus mycoides EE141 (NRRL No. B-50916), (C1.12) Bacillus mycoides BT46-3 (NRRL No. B-50922), (C1.13) Bacillus cereus family member EE128 (NRRL No. B-50917), (C1.14) Bacillus thuringiensis (Bacillus thuringiensis) BT013A (NRRL No. B-50924) (also known as Bacillus thuringiensis 4Q7), (C1.15) Bacillus cereus family member EE349 (NRRL No. B-50928), (C1.16) Bacillus amyloliquefaciens SB3281 (ATCC #PTA-7542; WO 2017 / 205258), (C1.17) Bacillus amyloliquefaciens TJ1000 (available from Novozymes as (C1.18) Bacillus firmus, in particular strain CNMC I-1582 (e.g. from BASF SE ); (C1.19) Bacillus pumilus, in particular strain GB34 (e.g. YIELD from Bayer Crop Science, DE ); (C1.20) Bacillus amyloliquefaciens, in particular strain IN937a; (C1.21) Bacillus amyloliquefaciens, in particular strain FZB42 (e.g. from ABiTEP, DE ); (C1.22) Bacillus amyloliquefaciens BS27 (registration number NRRL B-5015); (C1.23) a mixture of Bacillus licheniformis FMCH001 and Bacillus subtilis FMCH002 (available from FMC Corporation as (WG), (WP) obtained); (C1.24) Bacillus cereus, in particular strain BP01 (ATCC 55675; e.g. from Arysta Lifescience, US ); (C1.25) Bacillus subtilis, in particular strain MBI600 (e.g. from BASF SE ); (C1.26) Bradyrhizobium japonicum (e.g., from Novozymes ); (C1.27) Mesorhizobium cicer (e.g. NODULATOR from BASF SE); (C1.28) Rhizobium leguminosarium biovar viciae (e.g. NODULATOR from BASF SE); (C1.29) Delftia acidovorans, in particular strain RAY209 (e.g. ); (C1.30) Lactobacillus sp. (e.g. from LactoPAFI ); (C1.31) Bacillus polymyxa, in particular strain AC-1 (e.g. from GreenBiotech Company Ltd. ); (C1.32) Pseudomonas proradix (e.g. from Sourcon Padena ); (C1.33) Azospirillum brasilense (e.g., from KALO, Inc. ); (C1.34) Azospirillum lipoferum (e.g. VERTEX-IF from TerraMax, Inc. TM ); (C1.35) a mixture of Azotobacter vinelandii and Clostridium pasteurianum (available from Agrinos (C1.36) Pseudomonas aeruginosa, in particular strain PN1; (C1.37) Rhizobium leguminosarum, in particular strain Z25 of biovar Vicia faba (accession number CECT 4585); (C1.38) Azorhizobium caulinodans, in particular strain ZB-SK-5; (C1.39) Azotobacter chroococcum, in particular strain H23; (C1.40) Azotobacter chroococcum, in particular strain ATCC 12837; (C1.41) Bacillus siamensis, in particular strain KCTC13613T; (C1.42) Bacillus tequila tequilensis), in particular strain NII-0943; (C1.43) Serratia marcescens, in particular strain SRM (accession number MTCC 8708); (C1.44) Thiobacillus sp. (e.g. from Cropaid Ltd UK );as well as

[0122] (C2) A fungus selected from the group consisting of: (C2.01) Purpureocillium lilacinum (formerly Paecilomyces lilacinus) strain 251 (AGAL 89 / 030550; e.g. BioAct from Bayer Crop Science Biologics GmbH); (C2.02) Penicillium bilaii, strain ATCC 22348 (e.g. BioAct from Acceleron BioAg); ), (C2.03) Demodex flavus, strain V117b; (C2.04) Trichoderma virens strain CNCM I-1237 (e.g. from Agrauxine, FR WP), (C2.05) viride, for example, strain B35 (Pietr et al., 1993, Zesz. Nauk. AR w Szczecinie 161: 125-137); (C2.06) dark green Trichoderma strain LC52 (also known as dark green Trichoderma strain LU132; for example, Sentinel from Agrimm Technologies Limited); (C2.07) dark green Trichoderma strain SC1 described in International Application No. PCT / IT2008 / 000196; (C2.08) Trichoderma aculeatus strain kd (for example, T-Gro from Andermatt Biocontrol); (C2.09) Trichoderma aculeatus strain Eco-T (Plant Health Products, ZA); (C2.10) Trichoderma harzianum strain T-22 (for example, from Andermatt Biocontrol); Biocontrol or Koppert's Trianum-P); (C2.11) Myrothecium verrucaria strain AARC-0255 (e.g. DiTera from Valent Biosciences TM ); (C2.12) Penicillium bilaiae strain ATCC ATCC20851; (C2.13) Pythium oligandrum strain M1 (ATCC 38472; for example, Polyversum from Bioprepraty, CZ); (C2.14) Trichoderma virens strain GL-21 (for example, from Certis, USA ); (C2.15) Verticillium dahliae (formerly Verticillium dahliae) strain WCS850 (CBS276.92; for example Dutch Trig from Tree Care Innovations); (C2.16) Trichoderma aureum, in particular strain number V08 / 002387, strain number NMI number V08 / 002388, strain number NMI number V08 / 002389, strain number NMI number V08 / 002390; (C2.17) Trichoderma harzianum strain ITEM 908; (C2.18) Trichoderma harzianum, strain TSTh20; (C2.19) Trichoderma harzianum strain 1295-22; (C2.20) Pythium oligandrum strain DV74; (C2.21) Rhizopogon amylopogon (for example contained in Chemical Company); (C2.22) Rhizopogon fulvigleba (e.g. contained in Myco-Sol from Helena Chemical Company); (C2.23) and Trichoderma virens strain GI-3;

[0123] (D) an insecticidally active biological control agent selected from the group consisting of:

[0124] (D1) Bacteria selected from the group consisting of: (D1.01) Bacillus thuringiensis subsp. aizawai, in particular strain ABTS-1857 (SD-1372); (D1.02) e.g. ); (D1.02) Bacillus mycoides, isolate J. (e.g., BmJ from CertisUSA LLC (a subsidiary of Mitsui & Co.)); (D1.03) Bacillus sphaericus, in particular serotype H5a5b strain 2362 (strain ABTS-1743) (e.g., from Valent BioSciences, US ); (D1.04) Bacillus thuringiensis subsp. kurstaki strain BMP 123 from Becker Microbial Products, IL; (D1.05) Bacillus thuringiensis subsp. ayuzawa, in particular serotype H-7 (e.g., from Valent BioSciences, US WG); (D1.06) Bacillus thuringiensis subsp. Kurstaki strain HD-1 (e.g., from Valent BioSciences, US ES); (D1.07) Bacillus thuringiensis subsp. Kurstaki strain BMP 123 provided by Becker Microbial Products, IL; (D1.08) Bacillus thuringiensis israelensis strain BMP 144 (e.g., provided by Becker Microbial Products IL ); (D1.09) Burkholderia spp., in particular Burkholderia rinojensis strain A396 (also known as Burkholderia rinojensis strain MBI305) (Accession No. NRRL B-50319; WO 2011 / 106491 and WO 2013 / 032693; for example MBI-206TGAI and ); (D1.10) active purple bacteria (Chromobacterium subtsugae), in particular strain PRAA4-1T (MBI-203; for example from Marrone Bio Innovations ); (D1.11) Paenibacillus popilliae (formerly Bacillus popilliae); for example, MILKY SPOREPOWDER from St.Gabriel Laboratories TM AND MILKY SPORE GRANULAR TM ); (D1.12) Bacillus thuringiensis subsp. israelensis (serotype H-14) strain AM65-52 (accession number ATCC 1276) (eg, provided by Valent BioSciences, US ); (D1.13) Bacillus thuringiensis var. kurstaki strain EVB-113-19 (e.g. from AEF Global ); (D1.14) Bacillus thuringiensis subsp. tenebrionis strain NB 176 (SD-5428; e.g. from BioFa DE FC); (D1.15) Bacillus thuringiensis var. japonensis strain Buibui; (D1.16) Bacillus thuringiensis subsp. Kurstaki strain ABTS 351; (D1.17) Bacillus thuringiensis subsp. Kurstaki strain PB 54; (D1.18) Bacillus thuringiensis subsp. Kurstaki strain SA 11; (D1.19) Bacillus thuringiensis subsp. Kurstaki strain SA 12; (D1.20) Bacillus thuringiensis subsp. Kurstaki strain EG 2348; (D1.21) Bacillus thuringiensis var. Colmeri (e.g., from Changzhou Jianghai Chemical Factory provided by TIANBAOBTC); (D1.22) Bacillus thuringiensis subsp. ayuzawa strain GC-91; (D1.23) Serratia entomophila (e.g. provided by Wrightson Seeds ); (D1.24) Serratia marcescens, in particular strain SRM (accession number MTCC 8708); and (D1.25) Wolbachia pipientis ZAP strain (e.g. ZAP from MosquitoMate );as well as

[0125] (D2) A fungus selected from the group consisting of: (D2.01) Isaria fumosorosea (formerly Paecilomyces fumosoroseus) strain apopka 97; (D2.02) Beauveria bassiana strain ATCC 74040 (e.g., from Intrachem Bio Italia) ); (D2.03) Beauveria bassiana strain GHA (Accession No. ATCC 74250; e.g., from Laverlam International Corporation ES and ); (D2.04) Zoophtora radicans; (D2.05) Metarhizium robertsii 15013-1 (deposited under NRRL Accession No. 67073), (D2.06) Metarhizium robertsii 23013-3 (deposited under NRRL Accession No. 67075), and (D2.07) Metarhizium anisopliae 3213-1 (deposited under NRRL Accession No. 67074) (WO 2017 / 066094; Pioneer Hi-Bred International); (D2.08) Beauveria bassiana strain ATP02 (Accession No. DSM 24665;

[0126] (E) a virus selected from the group consisting of Adoxophyes orana (summer fruit tortrix) granulovirus (GV), Cydia pomonella (codling moth) granulovirus (GV), Helicoverpa armigera (cotton bollworm) nuclear polyhedrosis virus (NPV), Spodoptera exigua (beet armyworm) mNPV, Spodoptera frugiperda (fall armyworm) mNPV and Spodoptera littoralis (African cotton leafworm) NPV;

[0127] (F) Bacteria and fungi which can be added to plants or plant parts or plant organs as "inoculants" and which, by virtue of their specific properties, promote plant growth and plant health. Examples are: Agrobacterium spp., Rhizobium nodosarum, Azospirillum spp., Azotobacter spp., Bradyrhizobium spp., Burkholderia spp., in particular Burkholderia cepacia (formerly known as Pseudomonas cepacia), Gigaspora spp. or Gigaspora monosporum, Glomus spp., Laccaria spp., Lactobacillus buchneri, Paraglomus spp., Pisolithus tinctorus, Pseudomonas spp. spp.), Rhizobium spp., in particular Rhizobium trifolii, Rhizopogon spp., Scleroderma spp., Suillus spp. and Streptomyces spp.; and

[0128] (G) Plant extracts and products formed by microorganisms (including proteins and secondary metabolites) that can be used as biological control agents, such as Allium sativum, Artemisia absinthium, azadirachtin, Biokeeper WP, Cassia nigricans, Celastrus angulatus, Chenopodium anthelminticum, chitin, Armour-Zen, Dryopteris filix-mas, Equisetum arvense, Fortune Aza, Fungastop, Heads Up (Chenopodium quinoa saponin extract), pyrethrum / pyrethrins, Quassia amara, Quercus, Quillaja, Regalia, "Requiem TM "Insecticides", rotenone, ryania / ryanodine, Symphytum officinale, Tanacetum vulgare, thymol, Triact 70, TriCon, Tropaeulum majus, Urtica dioica, Veratrin, Viscum album, extracts of the Brassicaceae family (especially rapeseed powder or mustard powder), and biological insecticidal / acaricidal active substances obtained from olive oil, especially those with a carbon chain length of C 16 -C 20 Unsaturated fats / carboxylic acids as active ingredients, for example, are contained in the trade name products.

[0129] The compounds and compositions of the present invention may be combined with one or more active ingredients selected from the group consisting of insecticides, acaricides and nematicides.

[0130] "Insecticide" and the term "insecticidal" refer to the ability of a substance to increase mortality or inhibit growth rate of insects. As used herein, the term "insect" includes all organisms in the class "Insecta".

[0131] "Nematicide" and "nematicidal" refer to the ability of a substance to increase mortality or inhibit the growth rate of nematodes. In general, the term "nematode" encompasses eggs, larvae, young, and mature forms of the organism.

[0132] "Acaricide" and "acaricidal" refer to the ability of a substance to increase mortality or inhibit the growth rate of ectoparasites belonging to the class Arachnida, subclass Acari.

[0133] Examples of insecticides, acaricides and nematicides which can be mixed with the compounds and compositions of the present invention, respectively, are:

[0134] (1) an acetylcholinesterase (AChE) inhibitor, preferably a carbamate selected from the group consisting of alanycarb, aldicarb, bendiocarb, benfuracarb, butocarboxim, butoxycarboxim, carbaryl, carbofuran, carbosulfan, ethiofencarb, fenobucarb, formetanate, furathiocarb, and fenoxam. rb), isoprocarb, methiocarb, methomyl, metolcarb, oxamyl, pirimicarb, propoxur, thiodicarb, thiofanox, triazamate, trimethacarb, XMC and xylylcarb, or an organophosphate selected from acephate, azamethiphos, azinphos-ethyl and thiocarb. zinphos-ethyl), azinphos-methyl, cadusafos, chlorethoxyfos, chlorfenvinphos, chlormephos, chlorpyrifos-methyl, coumaphos, cyanophos, demeton-S-methyl, diazinon, dichlorvos / DDVP, dicrotophos, dimethoate dimethoate), dimethylvinphos, disulfoton, EPN, ethion, ethoprophos, famphur, fenamiphos, fenitrothion, fenthion, fosthiazate, heptenophos, imicyafos, isofenphos, isopropyl O-(methoxyaminothiophosphoryl) salicylate, isoxathion,Malathion, mecarbam, methamidophos, methidathion, mevinphos, monocrotophos, naled, omethoate, oxydemeton-methyl, parathion-methyl, phenthoate, phorate, phosalone, phosmet, phosphamidon, phoxim, piriphos-methyl miphos-methyl), profenofos, propetamphos, prothiofos, pyraclofos, pyridaphenthion, quinalphos, sulfotep, tebupirimfos, temephos, terbufos, tetrachlorvinphos, thiometon, triazophos, triclorfon, and vamidothion.

[0135] (2) GABA-gated chloride channel blockers, preferably cyclopentadienyl organochlorines selected from chlordane and endosulfan, or phenylpyrazoles (fiproles) selected from ethiprole and fipronil.

[0136] (3) sodium channel modulators, preferably pyrethroids, selected from acrinathrin, allethrin, d-cis-trans allethrin, d-trans allethrin, bifenthrin, bioallethrin, bioallethrin S-cyclopentenyl isomer, bioresmethrin, cycloprothrin, cyfluthrin, β-cyfluthrin, cyhalothrin, λ-cyhalothrin, γ-cyhalothrin, cypermethrin, α-cypermethrin, β-cypermethrin, θ-cypermethrin, ζ-cypermethrin, cyphenothrin [(1R)-trans isomer] isomer]), deltamethrin, empenthrin [(EZ)-(1R) isomer], esfenvalerate, etofenprox, fenpropathrin, fenvalerate, flucythrinate, flumethrin, tau-fluvalinate, halfenprox, imiprothrin, kadethrin, momfluorothrin, permethrin, phenothrin [(1R)-trans] isomer]), prallethrin, pyrethrins (pyrethrum), resmethrin, silafluofen, tefluthrin, tetramethrin, tetramethrin [(EZ)-(1R)-isomer], tralomethrin and transfluthrin, or DDT or methoxychlor.

[0137] (4) nicotinic acetylcholine receptor (nAChR) competitive modulators, preferably neonicotinoids selected from acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, thiacloprid and thiamethoxam, or nicotine, or sulfoximines selected from sulfoxaflor or butenolids selected from flupyradifurone, or mesoionics selected from triflumezopyrim.

[0138] (5) Nicotinic acetylcholine receptor (nAChR) allosteric modulators (site I), preferably spinosyns, selected from spinetoram and spinosad.

[0139] (6) Glutamate-gated chloride channel (GluCl) allosteric modulators, preferably avermectins / milbemycins, selected from abamectin, emamectin benzoate, lepimectin and milbemectin.

[0140] (7) Juvenile hormone mimetics, preferably juvenile hormone analogs, selected from hydroprene, kinoprene and methoprene, or fenoxycarb, or pyriproxyfen.

[0141] (8) Other non-specific (multi-site) inhibitors, preferably alkyl halides selected from methyl bromide and other alkyl halides; or chloropicrine or sulphuryl fluoride or borax or tartar emetic or methyl isocyanate generators selected from diazomet and metam.

[0142] (9) String organ TRPV channel modulators, preferably pyridine azomethanes selected from pymetrozine and pyrifluquinazone, or pyropenes selected from afidopyropen.

[0143] (10) A mite growth inhibitor affecting CHS1 selected from clofentezine, hexythiazox, diflovidazin and etoxazole.

[0144] (11) Insect gut membrane microbial disruptors selected from Bacillus thuringiensis subspecies israelensis, Bacillus sphaericus, Bacillus thuringiensis subspecies aizawai, Bacillus thuringiensis subspecies kurstaki, Bacillus thuringiensis subspecies tenebrionis and Bt plant proteins selected from Cry1Ab, Cry1Ac, Cry1Fa, Cry1A.105, Cry2Ab, Vip3A, mCry3A, Cry3Ab, Cry3Bb and Cry34Ab1 / 35Ab1.

[0145] (12) Mitochondrial ATP synthase inhibitors, preferably ATP disruptors, selected from diafenthiuron, or organotin compounds selected from azocyclotin, cyhexatin and fenbutatinoxide, or propargite, or tetradifon.

[0146] (13) An uncoupler of oxidative phosphorylation by discontinuous proton gradient, selected from chlorfenapyr, dinitrocresol (DNOC) and sulfluramid.

[0147] (14) A nicotinic acetylcholine receptor channel blocker selected from the group consisting of bensultap, cartap hydrochloride, thiocyclam and thiosultap-sodium.

[0148] (15) Chitin biosynthesis inhibitors affecting CHS1, preferably benzoylureas, selected from bistrifluron, chlorfluazuron, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, noviflumuron, teflubenzuron and triflumuron.

[0149] (16) A type 1 chitin biosynthesis inhibitor selected from buprofezin.

[0150] (17) Molting disruptors (especially for Diptera, i.e. dipterans), selected from cyromazine.

[0151] (18) Ecdysone receptor agonists, preferably diacylhydrazines selected from chromafenozide, halofenozide, methoxyfenozide and tebufenozide.

[0152] (19) An octopamine receptor agonist selected from amitraz.

[0153] (20) A mitochondrial complex III electron transport inhibitor selected from the group consisting of hydramethylnoe, acequinocyl, fluacrypyrim and bifenazate.

[0154] (21) Mitochondrial complex I electron transport inhibitors, preferably METI acaricides, and insecticides selected from fenazaquin, fenpyroximate, pyrimidifen, pyridaben, tebufenpyrad and tolfenpyrad, or rotenone (Derris).

[0155] (22) Voltage-dependent sodium channel blockers, preferably oxadiazine selected from indoxacarb, or semicarbazones selected from metaflumizone.

[0156] (23) Acetyl CoA carboxylase inhibitors, preferably tetronic acid and tetramic acid derivatives, selected from spirodiclofen, spiromesifen, spiropidion and spirotetramat.

[0157] (24) Mitochondrial complex IV electron transport inhibitors, preferably phosphines selected from aluminum phosphide, calcium phosphide, phosphine and zinc phosphide, or cyanides selected from calcium cyanide, potassium cyanide and sodium cyanide.

[0158] (25) Mitochondrial complex II electron transport inhibitors, preferably beta-ketonitrile derivatives selected from cyenopyrafen and cyflumetofen, or carboxanilides selected from pyflubumide.

[0159] (28) ryanodine receptor modulators, preferably diamides selected from the group consisting of chlorantraniliprole, cyantraniliprole, cyclaniliprole, flubendiamide and tetraniliprole,

[0160] (29) The chord organ modulator (target site unknown) is selected from flonicamid.

[0161] (30) The allosteric modulator of the GABA-gated chloride channel, preferably the diamine is selected from broflanilide, or the isoxazole is selected from fluxametamide.

[0162] (31) Baculoviruses, preferably granuloviruses (GVs) selected from the group consisting of Cydiapomonella GV and Thaumatotibia leucotreta GV, or nuclear polyhedrosis viruses (NPVs) selected from the group consisting of Anticarsia gemmatalis MNPV, Flucypyriprole and Helicoverpa armigera NPV.

[0163] (32) Nicotinic acetylcholine receptor allosteric modulator (Site II), selected from GS-ω / κHXTX-Hv1a peptide.

[0164] (33) Other active compounds selected from the group consisting of Acynonapyr, Afoxolaner, Azadirachtin, Benclothiaz, Benzoximate, Benzpyrimoxan, Bromopropylate, Chinomethionat, Chloroprallethrin, Cryolite, Cyclobutrifluram, Cycloxaprid, Cyetpyrafen, Cyhalodiamide, Cyproflanilide (CAS 2375110-88-4), Dicloromezotiaz, Dicofol, Dimpropyridaz, Epsilon Fluthrin,metofluthrin、epsilon-Momfluthrin、Flometoquin、Fluazaindolizine、Flucypyriprole(CAS1771741-86-6)、Fluensulfone、Flufenerim、Flufenoxystrobin、Flufiprole、Fluhexafon、Fluopyram、Flupyrimin、Flura laner), Fufenozide, Flupentiofenox, Guadipyr, Heptafluthrin, Imidaclothiz, Iprodione, Isocycloseram, kappa-Bifenthrin, kappa-Tefluthrin, Lotilaner, Meperfluthrin, Nicofloxacin uprole)(CAS1771741-86-6), Oxazosulfyl, Paichongding, Pyridalyl, Pyrifluquinazon, Pyriminostrobin, Sarolaner, Spidoxamat, Spirobudiclofen, Tetramethylfluthrin, Tetrachlorantraniliprole, Tigol aner, Tioxazafen, Thiofluoximate, Tyclopyrazoflor, Iodomethane; also preparations based on Bacillus firmus (I-1582, Votivo) and azadirachtin (BioNeem), and the following compounds: 1-{2-fluoro-4-methyl-5-[(2,2,2-trifluoroethyl)sulfinyl]phenyl}-3-(trifluoromethyl)-1H-1,2,4-triazol-5-amine (known from WO 2006 / 043635) (CAS 885026-50-6), 2-chloro-N-[2-{1-[(2E)-3-(4-chlorophenyl)prop-2-en-1-yl]piperidin-4-yl}-4-(trifluoromethyl)phenyl]isonicotinamide (known from WO2006 / 003494) (CAS872999-66-1), 3-(4-chloro-2,6-dimethylphenyl)-4-hydroxy-8-methoxy-1,8-diazaspiro[4.5]dec-3-en-2-one (known from WO2010052161) (CAS1225292-17-0), 3-(4-chloro-2,6-dimethylphenyl)-8-methoxy-2-oxo-1,8-diazaspiro[4.5]dec-3-en-4-ylethyl carbonate (known from EP 2647626) (CAS-1440516-42-6), PF1364 (known from JP2010 / 018586) (CAS registration number 1204776-60-2), (3E)-3-[1-[(6-chloro-3-pyridyl)methyl]-2-pyridylidene]-1,1,1-trifluoro-propan-2-one (known from WO2013 / 144213) known from WO2010 / 051926) (CAS 1226889-14-0), 5-bromo-4-chloro-N-[4-chloro-2-methyl-6-(methylamino)-4-(1-(1-(2-(4-chloro-2-methyl-1-phenyl)-3-(pentafluoroethyl)-4-(trifluoromethyl)-1H-pyrazole-5-carboxamide (known from WO2010 / 051926) (CAS 1226889-14-0), 4-[5-(3,5-dichlorophenyl)-4,5-dihydro-5-(trifluoromethyl)-3-isoxazolyl]-2-methyl-N-(cis-1-oxo-3-thiazole)benzamide, 4-[5-(3,5-dichlorophenyl)-4,5-dihydro-5-(trifluoromethyl)-3-isoxazolyl]-2-methyl-N-(cis-1-oxo-3-thiazole)benzamide, 3,5-dichlorophenyl)-4,5-dihydro-5-(trifluoromethyl)-3-isoxazolyl]-2-methyl-N-(trans-1-oxo-3-thietanyl)benzamide and 4-[(5S)-5-(3,5-dichlorophenyl)-4,5-dihydro-5-(trifluoromethyl)-3-isoxazolyl]-2-methyl-N-(cis-1-oxo-3-thietanyl)benzamide (by WO 2013 / 050317 A1) (CAS 1332628-83-7), N-[3-chloro-1-(3-pyridyl)-1H-pyrazol-4-yl]-N-ethyl-3-[(3,3,3-trifluoropropyl)sulfinyl]propanamide, (+)-N-[3-chloro-1-(3-pyridyl)-1H-pyrazol-4-yl]-N-ethyl-3-[(3,3,3-trifluoropropyl)sulfinyl]propanamide and (-)-N-[3-chloro-1-(3-pyridyl)-1H-pyrazol-4-yl]-N-ethyl-3-[(3,3,3-trifluoropropyl)sulfinyl]propanamide (from WO 2013 / 162715 A2, WO 2013 / 162716 A2, US2014 / 0213448A1) (CAS1477923-37-7), 5-[[(2E)-3-chloro-2-propen-1-yl]amino]-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-[(trifluoromethyl)sulfinyl]-1H-pyrazole-3-carbonitrile (known from CN 101337937 A) (CAS1105672-77-2), 3-bromo-N-[4-chloro-2-methyl-6-[(methylamino)thiomethyl]phenyl]-1-(3-chloro-2-pyridyl)-1H-pyrazole-5-carboxamide, (Liudaibenjiaxuanan, known from CN103109816 A) (CAS 1232543-85-9); N-[4-chloro-2-[[(1,1-dimethylethyl)amino]carbonyl]-6-methylphenyl]-1-(3-chloro-2-pyridyl)-3-(fluoromethoxy)-1H-pyrazole-5-carboxamide (known from WO 2012 / 034403 A1) (CAS 1268277-22-0), N-[2-(5-amino-1,3,4-thiadiazol-2-yl)-4-chloro-6-methylphenyl]-3-bromo-1-(3-chloro-2-pyridyl)-1H-pyrazole-5-carboxamide (known from WO 2011 / 085575 A1) (CAS 1233882-22-8), 4-[3-[2,6-dichloro-4-[(3,3-dichloro-2-propen-1-yl)oxy]phenoxy]propoxy]-2-methoxy-6-(trifluoromethyl)-pyrimidine (known from CN 101337940 A) (CAS 1108184-52-6); (2E)-2-[2-(4-cyanophenyl)-1-[3-(trifluoromethyl)phenyl]ethylidene]-N-[4-(difluoromethoxy)phenyl]hydrazinecarboxamide and 2(Z)-2-[2-(4-cyanophenyl)-1-[3-(trifluoromethyl)phenyl]ethylidene]-N-[4-(difluoromethoxy)phenyl]hydrazinecarboxamide (known from CN 101715774A) (CAS1232543-85-9); 3-(2,2-dichlorovinyl)-2,2-dimethyl-4-(1H-benzimidazol-2-yl)phenyl-cyclopropanecarboxylate (known from CN 103524422 A) (CAS1542271-46-4); (4aS)-7-chloro-2,5-dihydro-2-[[(methoxycarbonyl)[4-[(trifluoromethyl)thio]phenyl]amino]carbonyl]-indeno[1,2-e][1,3,4]oxadiazine-4a(3H)-carboxylic acid methyl ester (known from CN 102391261A) (CAS 1370358-69-2); 6-deoxy-3-O-ethyl-2,4-diO-methyl 1-[N-[4-[1-[4-(1,1,2,2,2-pentafluoroethoxy)phenyl]-1H-1,2,4-triazol-3-yl]phenyl]carbamate]-α-L-pyranose (known from US2014 / 0275503 A1) (CAS 1181213-14-8); 8-(2-cyclopropylmethoxy-4-trifluoromethyl-phenoxy)-3-(6-trifluoromethyl-pyridazin-3-yl)-3-azabicyclo[3.2.1]octane (CAS 1253850-56-4), (8-trans)-8-(2-cyclopropylmethoxy-4-trifluoromethyl-phenoxy)-3-(6-trifluoromethyl-pyridazin-3-yl)-3-azabicyclo[3.2.1]octane (CAS 933798-27-7), (8-cis)-8-(2-cyclopropylmethoxy-4-trifluoromethyl-phenoxy)-3-(6-trifluoromethyl-pyridazin-3-yl)-3-azabicyclo[3.2.1]octane (WO2007040280A1, WO 2007040282 A1) (CAS 934001-66-8), N-[4-(aminothiomethyl)-2-methyl-6-[(methylamino)carbonyl]phenyl]-3-bromo-1-(3-chloro-2-pyridyl)-1H-pyrazole-5-carboxamide (known from CN103265527 A) (CAS1452877-50-7), 3-(4-chloro-2,6-dimethylphenyl)-8-methoxy-1-methyl-1,8-diazaspiro[4.5]decane-2,4-dione (known from WO 2014 / 187846A1) (CAS1638765-58-8), 3-(4-chloro-2,6-dimethylphenyl)-8-methoxy-1-methyl-2-oxo-1,8-diazaspiro[4.5]dec-3-en-4-yl-carbonic acid ethyl ester (known from WO 2010 / 066780A1, WO 2011151146 A1) (CAS1229023-00-0), N-[1-(2,6-difluorophenyl)-1H-pyrazol-3-yl]-2-(trifluoromethyl)benzamide (known from WO 2014 / 053450 A1) (CAS1594624-87-9), N-[2-(2,6-difluorophenyl)-2H-1,2,3-triazol-4-yl]-2-(trifluoromethyl)benzamide (known from WO 2014 / 053450 A1) (CAS1594637-65-6), N-[1-(3,5-difluoro-2-pyridyl)-1H-pyrazol-3-yl]-2-(trifluoromethyl)benzamide (known from WO2014 / 053450A1) (CAS1594626-19-3), (3R)-3-(2-chloro-5-thiazolyl)-2,3-dihydro-8-methyl-5,7-dioxo-6-phenyl-5H-thiazolo[3,2-a]pyrimidinium salt (known from WO 2018 / 177970A1) (CAS2246757-58-2), 3-(2-chloro-5-thiazolyl)-2,3-dihydro-8-methyl-5,7-dioxo-6-phenyl-5H-thiazolo[3,2-a]pyrimidinium salt (known from WO 2018 / 177970A1) (CAS 2246757-56-0), N-[3-chloro-1-(3-pyridyl)-1H-pyrazol-4-yl]-2-(methylsulfonyl)propionamide (known from WO 2019 / 236274 A1) (CAS 2396747-83-2), N-[2-bromo-4-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]-6-(trifluoromethyl)phenyl]-2-fluoro-3-[(4-fluorobenzoyl)amino]benzamide (known from WO 2019059412 A1) (CAS1207977-87-4), 3-bromo-1-(3-chloro-2-pyridyl)-N-[4,6-dichloro-3-fluoro-2-[(methylamino)carbonyl]phenyl]-1H-pyrazole-5-carboxamide (fluorochlorodiamine; known from CN110835330 A, CN106977494A) (CAS2129147-03-9).

[0165] Examples of nematicides that can be mixed with the compounds and compositions of the present invention are:

[0166] (Group N-1) acetylcholinesterase (AChE) inhibitors, preferably (N-1A) carbamates selected from aldicarb, benfuracarb, carbofuran, carbosulfan and thiodicarb; or (N-1B) organophosphates selected from cadusafos, ethoprofos, fenamiphos, fosthiazate, imicyafos, phorate and terbufos.

[0167] (Group N-2) Glutamate-gated chloride channel (GluCl) allosteric modulators, preferably avermectins selected from abamectin and emamectin benzoate.

[0168] (Group N-3) Mitochondrial complex II electron transport inhibitors, in particular inhibitors of succinate Coenzyme Q reductase, preferably pyridylmethyl-benzamide compounds selected from Fluopyram.

[0169] (Group N-4) Lipid synthesis / growth regulation modulators, in particular acetyl-CoA carboxylase inhibitors, preferably selected from tetronic acid and tetramic acid derivatives selected from the following: spirotetramat.

[0170] (Group N-UN) Compounds with unknown or undefined modes of action with various chemical substances, selected from Fluensulfone, Fluazaindolizine, Furfural, iprodione and tioxazafen.

[0171] (Group N-UNX) Compounds with unknown or undefined mode of action: putative multi-site inhibitors, preferably volatile sulfur generators selected from: carbon disulfide and dimethyl disulfide (DMDS), or carbon disulfide dissociators selected from sodium tetrathiocarbonate; or alkyl halides selected from methyl bromide and methyl iodide (iodomethane); or halogenated hydrocarbons selected from 1,2-dibromo-3-chloropropane (DBCP) and 1,3-dichloropropylene; or chloropicrin, or a methyl isothiocyanate generator selected from allyl isothiocyanate, methyl diazonium, potassium metamex and sodium metamex.

[0172] (Group N-UNB) Bacterial agents with unknown or undefined mode of action (non-Bt), preferably bacteria or bacterial derivatives, selected from Burkholderia spp., for example rinojensis strain A396; Bacillus subtilis spp., for example Bacillus firmus, Bacillus licheniformis, Bacillus subtilis var. amyloliquefaciens or Bacillus subtilis; Pasteuria spp.; for example Pasteuria penetrans or nishizawae; Pseudomonas spp., for example Pseudomonas chlororaphis or Pseudomonas fluorescens and Streptomyces spp., for example Streptomyces lydicus, dicklowii or albogriseolus.

[0173] (Group N-UNF) Fungal agents with unknown or undefined modes of action, preferably fungi or fungal derivatives are selected from the group consisting of Actinomyces spp., such as streptococcus; Arthrobotrys spp., such as oligospora; Aspergillus spp., such as Aspergillus niger, Muscodor spp., such as white muscodor; Myrobotrys spp., such as Myrobotrys; Paecilomyces fungi, such as Purple Sporangium (Purple Sporangium), Aspergillus carnosus or Paecilomyces fumosorum; Pochonia spp., such as Chlamydosporia and Trichoderma, such as Trichoderma harzianum, Trichoderma viride, Trichoderma aureum or Trichoderma viride.

[0174] (Group N-UNE) Plant or animal-derived preparations, including synthetic extracts and unrefined oils, with unknown or undefined modes of action, preferably plant or animal extracts selected from nitrogen mustard, camellia seed cake, essential oils, garlic extracts, pongamia oil, terpenes such as carvacrol and terminalia saponin extracts.

[0175] Examples of herbicides that can be mixed with the compounds and compositions of the present invention are:

[0176] Acetochlor, acifluorfen, acifluorfen-methyl, acifluorfen-sodium, aclonifen, alachlor, allidochlor, alloxydim, alloxydim-sodium, ametryn, amicarbazone, amidochlor, amidosulfuron, 4-amino-3-chloro-6-(4-chloro-2-fluoro-3-methylphenyl)-5-fluoropyridine-2-carboxylic acid, cyprodinil acid ( aminocyclopyrachlor), aminocyclopyrachlor-potassium, aminocyclopyrachlor-methyl, aminopyralid, aminopyralid-dimethylammonium, aminopyralid-tripromine, amitrole, ammoniumsulfamate, anilofos, asulam, asulam-potassium, asulam-sodium sodium), atrazine, azafenidin, azimsulfuron, beflubutamid, beflubutamid ((S)-(-)-beflubutamid, beflubutamid-M), benazolin, benazolin-ethyl, benazolin-dimethylammonium, benazolin-potassium, benfluralin, benfuresate, bensulfuron, bensulfuron-methyl, bensulide, bentazone, bentazone-sodium, benzobicyclon, benzofenap, bicyclopyrone,bifenox, bilanafos, bilanafos-sodium, bipyrazone, bispyribac, bispyribac-sodium, bixlozone, bromacil, bromacil-lithium, bromacil-sodium, bromobutide, bromofenoxim, bromoxynil, bromoxynil-butyryl ate), bromoxynil-potassium, bromoxynil-heptanoate and bromoxynil-octanoate, busoxinone, butachlor, butafenacil, butamifos, butenachlor, butralin, butroxydim, butylate, cafenstrole, cambendichlo r, carbetamide, carfentrazone, carfentrazone-ethyl, chloramben, chloramben-ammonium, chloramben-diolamine, chloramben-methyl, chloramben-methylammonium, chloramben-sodium, chlorbromuron, chlorfena c), chlorfenac-ammonium, chlorfenac-sodium, chlorfenprop, chlorfenprop-methyl, chlorflurenol, chlorflurenol-methyl, chloridazon, chlorimuron, chlorimuron-ethyl, chlorophthalim, chlorotoluron,Chlorsulfuron, chlorthal, chlorthal-dimethyl, chlorthal-monomethyl, cinidon, cinidon-ethyl, cinmethylin, exo-(+)-cinmethylin, i.e. (1R,2S,4S)-4-isopropyl-1-methyl-2-[(2-methylbenzyl)oxy]-7-oxabicyclo[2.2.1]heptane1]heptane, exo-(-)-cinmethylin, i.e. (1R,2S,4S)-4-isopropyl-1-methyl-2-[(2-methylbenzyl)oxy]-7-oxabicyclo[2.2.1]heptane1]heptane Methyl-2-[(2-methylbenzyl)oxy]-7-oxabicyclo[2.2.1]heptane, cinosulfuron, clacyfos, clethodim, clodinafop, clodinafop-ethyl, clodinafop-propargyl, clomazone, clomeprop, clopyralid, clopyralid-methyl, clopyralid-olamine , clopyralid-potassium, clopyralid-tripomine, cloransulam, cloransulam-methyl, cumyluron, cyanamide, cyanazine, cycloate, cyclopyranil, cyclopyrimorate, cyclosulfamuron, cycloxydim, cyhalofop-butyl ofop), cyhalofop-butyl, cyprazine, 2,4-D (including ammonium salts, butoxy, -butyl, choline, diethylammonium, -dimethylammonium, -diolamine, -butyl ether, -dodecylammonium, etexyl, ethyl, -2-ethylhexyl, -heptylammonium, isobutyl, isooctyl, isopropylammonium, -potassium, triisopropanolammonium, isopropyl, isopropylammonium, lithium, heptyl, methyl, potassium, tetradecylammonium, triethylammonium, triisopropanolammonium, tripropylamine and triethanolamine and their salts), 2,4-DB, 2,4-DB-butyl ester, 2,4-DB-dimethylammonium salt, 2,4-DB-isooctyl ester, 2,4-DB-potassium salt and 2,4-DB-sodium salt,daimuron (dymron), dalapon, dalapon-calcium, dalapon-magnesium, dalapon-sodium, dazomet, dazomet-sodium, n-decyl alcohol, 7-deoxy-D-sedoheptulose, desmedipham, detosyl-pyrazolate (DTP), dicamba, and its salts, such as dicamba-dipropylamine, ... Dicamba-N,N-bis(3-aminopropyl)methylamine, Dicamba-butyl, Dicamba-choline, Dicamba-diglycolamine, Dicamba-dimethylamine, Dicamba-diethanolamine ammonium salt, Dicamba-diethylammonium salt, Dicamba-isopropylammonium salt, Dicamba-methyl, Dicamba-monoethanolamine, Dicamba-olamine, Dicamba-potassium salt, Dicamba-sodium salt, Dicamba-triethanolamine, dichlobenil, 2-(2,4-dichlorobenzyl)-4,4-dimethyl-1,2-oxazolidin-3-one, 2-(2,5-dichlorobenzyl)-4,4-dimethyl-1,2-oxazolidin-3-one, 2,4-dichlorprop, 2,4-dichlorprop butyl ester (dichlorprop prop-butotyl), dichlorprop-dimethylammonium, dichlorprop-etexyl, dichlorprop-ethylammonium, 2,4-dichloropropionate, methyl 2,4-dichloropropionate, potassium 2,4-dichloropropionate, sodium 2,4-dichloropropionate, dichlorprop-P, dichloropropionate dimethylammonium, vinyl 2,4-dichloropropionate, potassium 2,4-dichloropropionate, sodium 2,4-dichloropropionate, diclofop, diclofop-butyl (dicl ofop-methyl), diclofop-P, diclofop-P-methyl, diclosulam, difenzoquat, difenzoquat-metilsulfate, diflufenican, diflufenzopyr, diflufenzopyr-sodium, dimefuron, dimepiperate, dimesulfazet, dimethachlor,dimetha-metryn, dimethenamid, dimethenamid-P, dimetrasulfuron, diinitramine, dinoterb, dinoterb-acetate, diphenamid, diquat, diquat-dibromid, diquat dichloride dichloride), dithiopyr, diuron, DNOC, DNOC-potassium, DNOC-sodium, endothal, endothal-diammonium, endothal-dipotassium, endothal-disodium, Epyrifenacil (S-3100), EPTC, esprocarb, ethalfluralin, ethametsulfuron, ethametsulfuron on-methyl), ethametsulfuron-methyl, ethiozin, ethofumesate, ethoxyfen, ethoxyfen-ethyl, ethoxysulfuron, etobenzanid, F-9600, F-5231 (i.e., N-{2-chloro-4-fluoro-5-[4-(3-fluoropropyl)-5-oxo-4,5-dihydro-1H-tetrazol-1-yl]phenyl}ethanesulfonamide), F-7967 (i.e., 3-[7-chloro-5-fluoro- 2-(trifluoromethyl)-1H-benzimidazol-4-yl]-1-methyl-6-(trifluoromethyl)pyrimidine-2,4(1H,3H)-dione), fenoxaprop, fenoxaprop-P, fenoxaprop-ethyl, fenoxaprop-P-ethyl, fenoxasulfone, fenquinotrione, fentrazamide, flamprop, flamprop-isoproyl,flamprop-methyl, flamprop-M-isopropyl, flamprop-M-methyl, flazasulfuron, florasulam, florpyrauxifen, florpyrauxifen-benzyl, fluazifop, fluazifop, fluazifop-butyl, fluazifop-methyl Fluazifop-P, fluazifop-P-butyl, flucarbazone, flucarbazone-sodium, flucetosulfuron, fluchloralin, flufenacet, flufenpyr, flufenpyr-ethyl, flumetsulam, flumiclorac, flumiclorac-p-butyl entyl), flumioxazin, fluometuron, flurenol, flurenol-butyl, flurenol-dimethylammonium and flurenol-methyl, fluoroglycofen, fluoroglycofen-ethyl, flupropanate, flupropanate-sdium, flupyrsulfuron on), flupyrsulfuron-methyl, flupyrsulfuron-methyl-sodium, fluridone, flurochloridone, fluroxypyr, fluroxypyr-butometyl, fluroxypyr-meptyl, flurtamone, fluthiacet, fluthiacet-methyl,fomesafen, fomesafen-sodium, foramsulfuron, foramsulfuron sodium salt, fosamine, fosamine-ammonium, glufosinate, glufosinate-ammonium, glufosinate-sodium, L-glufosinate-ammonium, L-glufosinate-sodium, glufosinate-P-sodium, glufosinate-P-ammonium, glyphosate, glyphosate-ammonium ammonium), glyphosate-isopropylammonium, glyphosate-diammonium, glyphosate-dimethylammonium, glyphosate-potassium, glyphosate-sodium, glyphosate-trimesium, H-9201 (i.e. O-(2,4-dimethyl-6-nitrophenyl) O-ethyl isopropylthiophosphoramidate, halauxifen, halauxifen-methyl, halosafen, halosulfuron, halosulfuron-methyl, haloxyfop, haloxyfop-P, haloxyfop-ethoxyethyl, haloxyfop-P-ethoxyethyl, Haloxyfop-methyl, haloxyfop-P-methyl, hexazinone, HNPC-A8169 (i.e., prop-2-yn-1-yl (2S)-2-{3-[(5-tert-butylpyridin-2-yl)oxy]phenoxy}propionate), HW-02 (i.e., 1-(dimethoxyphosphoryl)ethyl-(2,4-dichlorophenoxy)acetate), imazamethabenz, imazamethabenz-methyl, imazamox,Imazamox-ammonium, imazapic, imazapic-ammonium, imazapyr, imazapyr-isopropylammonium, imazaquin, imazaquin-ammonium, imazaquin methyl ester methyl), imazethapyr, imazethapyr-immonium, imazosulfuron, indanofan, indaziflam, iodosulfuron, iodosulfuron-methyl, iodosulfuron-methyl-sodium, ioxynil, ioxynil-lithium, ioxynil-octanoate, ioxynil-potassium and ioxynil-sodium, ipfencarbazone, isoproturon, isouron, isoxaben, isoxaflutole, terbuconazole ( karbutilate), KUH-043 (i.e., 3-({[5-(difluoromethyl)-1-methyl-3-(trifluoromethyl)-1H-pyrazol-4-yl]methyl}sulfonyl)-5,5-dimethyl-4,5-dihydro-1,2-oxazole), ketospiradox, ketospiradox-potassium, lactofen, lancotrione, lenacil, linuron, MCPA, MCPA-butoxyethyl ester (MCPA-but otyl), MCPA-butyl ethyl ester, MCPA-dimethyl ammonium salt, MCPA-diethanolamine, MCPA-2-ethylhexyl ester, MCPA-ethyl ethyl ester, MCPA-isobutyl ethyl ester, MCPA-isooctyl ethyl ester, MCPA-isopropyl ethyl ester, MCPA-isopropyl ammonium salt, MCPA-methyl ethyl ester, MCPA-ethanolamine, MCPA-potassium salt and MCPA-sodium salt, MCPA-triethanolamine, MCPB, MCPB-methyl ester, MCPB-ethyl ester and MCPB-sodium salt, 2-methyl-4-chloropropionic acid (mecoprop),mecoprop-butotyl, mecoprop-dimethylammonium, mecoprop-diolamine, mecoprop-etexyl, mecoprop-ethadyl, isooctyl, mecoprop-methyl, mecoprop-potassium, mecoprop-sodium, mecoprop-trolamine, mecoprop-ethyl p-P), mecoprop-butotyl, mecoprop-dimethylammonium, 2-ethylhexyl 2-methyl-4-chloropropionate (-2-ethylhexyl) and 2-methyl-4-chloropropionate potassium salt, mefenacet, mefluidide, mefluidide-diolamine, mefluidide-potassium, mesosulfuron, mesosulfuron-methyl, mesosulfuron-sodium sodium salt), mesotrione, methabenzthiazuron, metam, metamifop, metamitron, metazachlor, metazo-sulfuron, methabenzthiazuron, methiopyrsulfuron, metiozolin, methyl isothiocyanate, meto-bromuron, metobromuron, metolachlor, S-metolachlor, metosulam, metoxuron, metribuzin, metsulfuron, metsulfuron-methyl, molinat, monolinuron,Monosulfuron, monosulfuron-methyl, MT-5950 (i.e. N-[3-chloro-4-isopropylphenyl]-2-methylpentanamide), NGGC-011, napropamide, NC-310 (i.e. [5-(benzyloxy)-1-methyl-1H-pyrazol-4-yl](2,4-dichlorophenyl)methanone), NC-656 (i.e. 3-[(isopropylsulfonyl)methyl]-N-(5-methyl-1,3,4-oxadiazol-2-yl)-5-(trifluoromethyl)[1,2,4]triazolo[4,3-a]pyridine-8-carboxamide), neburon, nicosulfuron, nonanoic acid (pelargonic acid acid), norflurazon, oleic acid, orbencarb, orthosulfamuron, oryzalin, oxadiargyl, oxadiazon, oxasulfuron, oxaziclomefon, oxyfluorfen, paraquat, paraquat dichloride dichloride), pebulate, pendimethalin, penoxsulam, pentachlorphenol, pentoxazone, pethoxamid, mineral oil, phenmedipham, phenmedipham-ethyl, picloram, picloram-dimethylamine, picloram-etexyl, picloram-isooctyl ester, picloram-methyl ester, picloram-alcoholamine, picloram-potassium, picloram-triethylamine, picloram-triazine, atamid-triethanolamine, picolinafen, pinoxaden, piperophos, pretilachlor, primisulfuron, primisulfuron-methyl, prodiamine, profoxydim, prometon, prometryn, propachlor, propanil, propaquizafop, propazine,Propham, propisochlor, propoxycarbazone, propoxycarbazone-sodium, propyrisulfuron, propyzamide, prosulfocarb, prosulfuron, pyraclonil, pyraflufen, pyraflufen-ethyl, pyrasulfotole, pyrazo lynate (pyrazolate), pyrazosulfuron, pyrazosulfuron-ethyl, pyrazoxyfen, pyribambenz, pyribambenz-isopropyl, pyribambenz-propyl, pyribenzoxim, pyributicarb, pyridafol, pyridate, pyriftalid, pyriminob ac), pyriminobac-methyl, pyrimisulfan, pyrithiobac, pyrithiobac-sodium, pyroxasulfone, pyroxsulam, quinclorac, quinclorac-dimethylammonium, quinclorac-methyl, quinmerac, quinoclamine, quizalofop-p-ethyl ofop), quizalofop-ethyl, quizalofop-P, quizalofop-P-ethyl, quizalofop-P-tefuryl, QYM201, 1-{2-chloro-3-[(3-cyclopropyl-5-hydroxy-1-methyl-1H-pyrazol-4-yl)carbonyl]-6-(trifluoromethyl)phenyl}piperidin-2-one, rimsulfuron, saflufenacil, sethoxydim, siduron, simazine,Simetryn, SL-261, sulcotrion, sulfentrazone, sulfometuron, sulfometuron-methyl, sulfosulfuron, SYP-249 (i.e., 1-ethoxy-3-methyl-1-oxobut-3-en-2-yl 5-[2-chloro-4-(trifluoromethyl)phenoxy]-2-nitrobenzoate), SYP-300 (i.e., 1-[7-fluoro-3-oxo-4-(prop-2-yn-1-yl)-3,4-dihydro-2H-1,4-benzoxazin-6-yl ]-3-propyl-2-thioimidazole-4,5-dione), 2,3,6-TBA, TCA (trichloroacetic acid) and its salts, tebuthiuron, tefuryltrione, tembotrione, tepraloxydim, terbacil, terbucarb, terbumeton, terbuthylazine, terbutryn, tetflupyrolimet, thaxtomin, thenylchlor, thiophene Thiazopyr, thiencarbazone, thiencarbazone-methyl, thifensulfuron, thifensulfuron-methyl, thiobencarb, tiafenacil, tolpyralate, topramezone, tralkoxydim, triafamone, tri-allate, triasulfuron ), triaziflam, tribenuron, tribenuron-methyl, triclopyr, triclopyr butyl, triclopyr choline, triclopyr ethyl, triclopyr triethylamine, trietazine, trifloxysulfuron, trifloxysulfuron-sodium, trifludimoxazin, trifluralin, triflusulfuron,triflusulfuron-methyl, tritosulfuron, urea sulfate, vernolate, XDE-848, ZJ-0862 (i.e. 3,4-dichloro-N-{2-[(4,6-dimethoxypyrimidin-2-yl)oxy]benzyl}aniline), 3-(2-chloro-4-fluoro-5-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydropyrimidin-1(2H)-yl)phenyl)-5-methyl-4,5-dihydroisoxazole-5-carboxylic acid ethyl ester, ethyl-[(3-{2-chloro-4-fluoro-5-[3-methyl-2,6-dioxo-4-(trifluoromethyl) )-3,6-dihydropyrimidin-1(2H)-yl]phenoxy}pyridin-2-yl)oxy]acetate, 3-chloro-2-[3-(difluoromethyl)isoxazol-5-yl]phenyl-5-chloropyrimidin-2-yl ether, 2-(3,4-dimethoxyphenyl)-4-[(2-hydroxy-6-oxocyclohex-1-en-1-yl)carbonyl]-6-methylpyridazin-3(2H)-one, 2-({2-[(2-methoxyethoxy)methyl]-6-methylpyridin-3-yl}carbonyl)cyclohexane-1,3-dione, (5-hydroxy-1-methyl-1H-pyrazol-4-yl)(3,3,4-trimethyl-1,1-dioxo-2,3-dihydro-1-benzothiophen-5-yl)methanone, 1-methyl -4-[(3,3,4-trimethyl-1,1-dioxo-2,3-dihydro-1-benzothiophen-5-yl)carbonyl]-1H-pyrazol-5-ylpropane-1-sulfonate, 4-{2-chloro-3-[(3,5-dimethyl-1H-pyrazol-1-yl)methyl]-4-(methylsulfonyl)benzoyl}-1-methyl-1H-pyrazol-5-yl-1,3-dimethyl-1H-pyrazole-4-carboxylate, 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylic acid cyanomethyl ester, 2-alkyn-1-yl-4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylic acid propyl ester, 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylic acid propyl ester, -5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylic acid methyl ester, 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylic acid, benzyl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylate, ethyl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylate, methyl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylate, methyl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1-isobutyryl-1H-indol-6-yl)pyridine-2-carboxylate, methyl 6-(1-acetyl-7-fluoro-1H-indol-6-yl)-4-amino-3-chloro-5-fluoropyridine-2-carboxylate,4-Amino-3-chloro-6-[1-(2,2-dimethylpropanoyl)-7-fluoro-1H-indol-6-yl]-5-fluoropicolinate, 4-Amino-3-chloro-5-fluoro-6-[7-fluoro-1-(methoxyacetyl)-1H-indol-6-yl]pyridine-2-carboxylic acid methyl ester, 4-Amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylic acid potassium ester, 4-Amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylic acid sodium ester, 4-Amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylic acid sodium ester butyl)pyridine-2-carboxylate, 4-hydroxy-1-methyl-3-[4-(trifluoromethyl)pyridin-2-yl]imidazolidin-2-one, 3-(5-tert-butyl-1,2-oxazol-3-yl)-4-hydroxy-1-methylimidazolidin-2-one, 3-[5-chloro-4-(trifluoromethyl)pyridin-2-yl]-4-hydroxy-1-methylimidazolidin-2-one, 4-hydroxy-1-methoxy-5-methyl-3-[4-(trifluoromethyl)pyridin-2-yl]imidazolidin-2-one, 6-[(2-hydroxy-6-oxocyclohex-1-en-1-yl)carbonyl]-1,5-dimethyl-3-(2-methylbenzene 1-(2-carboxyethyl)-4-(pyrimidin-2-yl)pyridazin-1-ium salt (anion, such as chloride, acetate or trifluoroacetate), 1-(2-carboxyethyl)-4-(pyridazin-3 ... Such as chloride, acetate or trifluoroacetate), 1-(2-carboxyethyl)-4-(pyridazin-3-yl)pyridazin-1-ium salt (anion such as chloride, acetate or trifluoroacetate), 4-(pyridazin-3-yl)-1-(2-sulfonic acid ethyl)pyridazin-1-ium salt (anion such as chloride, acetate or trifluoroacetate), 1-(2-carboxyethyl)-4-(1,3-thiazol-2-yl)pyridazin-1-ium salt (anion such as chloride, acetate or trifluoroacetate), 1-(2-carboxyethyl)-4-(1,3-thiazol-2-yl)pyridazin-1-ium salt (anion such as chloride, acetate or trifluoroacetate).

[0177] Examples of plant growth regulators that can be mixed with the compounds and compositions of the present invention are:

[0178] Abscisic acid and related analogs (e.g., (2Z,4E)-5-[6-ethynyl-1-hydroxy-2,6-dimethyl-4-oxocyclohex-2-en-1-yl]-3-methylpenta-2,4-dienoic acid, (2Z,4E)-5-[6-ethynyl-1-hydroxy-2,6-dimethyl-4-oxocyclohex-2-en-1-yl]-3-methylpenta-2,4-dienoic acid methyl ester, (2Z,4E)-3-ethyl-5-(1-hydroxy-2,6,6-trimethyl-4-oxocyclohex-2-en-1-yl)penta-2,4-dienoic acid, (2E,4E)-5-(1-hydroxy-2,6,6-trimethyl-4-oxocyclohex-2-en-1-yl)penta-2,4-dienoic acid, (trimethyl-4-oxocyclohex-2-en-1-yl)-3-trifluoromethylpenta-2,4-dienoic acid, (2E,4E)-5-(1-hydroxy-2,6,6-trimethyl-4-oxocyclohex-2-en-1-yl)-3-(trifluoromethyl)penta-2,4-dienoic acid methyl ester, (2Z,4E)-5-(2-hydroxy-1,3-dimethyl-5-oxobicyclo[4.1.0]hept-3-en-2-yl)-3-methylpenta-2,4-dienoic acid), activated ester (Acibenzolar), Acibenzolar-S-methyl, S-adenosylhomocysteine ​​(S-adenosylhomocysteine) ocysteine), allantoin, 2-aminoethoxyethyleneglycine (AVG), aminoacetic acid and its related esters (e.g., (isopropylidene)-aminooxyacetic acid-2-(methoxy)-2-oxoethyl ester, (isopropylidene)-aminooxyacetic acid-2-(hexyloxy)-2-oxoethyl ester, (cyclohexylidene)-aminooxyacetic acid-2-(isopropoxy)-2-oxoethyl ester], 1-aminocyclopropan-1-ylcarboxylic acid and its derivatives, for example, as disclosed in the following documents DE3335514, EP30287, DE2906507 or US5123951) , 5-aminolevulinic acid, ancymidol, 6-benzylaminopurine, bikinin, brassinolid, brassinolid-ethyl, L-canaline, catechine and catechins (e.g., (2S,3R)-2-(3,4-dihydroxyphenyl)-3,4-dihydro-2H-chromene-3,5,7-triol), chitosan oligosaccharides (COs; COs differ from LCOs in that they lack the pendant fatty acid chains characteristic of LCOs).COs are sometimes called N-acetylchitosan oligosaccharides, which are also composed of GlcNAc residues, but their side chain modifications make them different from chitin molecules [(C8H13NO5)n, CAS No. 1398-61-4] and chitosan molecules [(C5H11NO4)n, CAS No. 9012-76-4], chitin compounds, chlormequatchloride, cloprop, cyclanilide, 3-(cycloprop-1-enyl)propionic acid, 1-[2-(4-cyano-3,5-dicyclopropylphenyl)acetamido]cyclohexanecarboxylic acid, 1-[2-(4-cyano-3-cyclopropylphenyl)acetamido]cyclohexanecarboxylic acid, Alkanecarboxylic acids, daminozide, dazomet, n-decanol, dikegulac, dikegulac-sodium, endothal, endothal-dipotassium, endothal-disodium and endothal-mono(N,N-dimethylalkylammonium), ethephon, flumetralin, flumethrin, fluorenol butyl ester, fluorenol methyl ester, flurprimidol, forchlorfenuron, gibberellic acid acid), inabenfide, indole-3-acetic acid (IAA), 4-indol-3-ylbutyric acid, isoprothiolane, probenazole, jasmonic acid, jasmonic acid or its derivatives (e.g., methyl jasmonate, ethyl jasmonate), lipo-chitooligosaccharides (LCOs, sometimes also referred to as symbiotic nodulation (Nod) signals (or Nod factors) or Myc factors) are composed of a β-l,4-linked N-acetyl D-glucosamine ("GlcNAc") residue oligosaccharide backbone and an N-linked fatty acyl chain condensed at the non-reducing end.As is understood in the art, LCOs differ in the number of GlcNAc residues in the backbone, the length and degree of saturation of the fatty acyl chains, and the substitution of reducing and non-reducing sugar residues), linoleic acid or its derivatives, linolenic acid or its derivatives, maleic hydrazide, mepiquat chloride, mepiquat pentaborate, 1-methylcyclopropene, 3-methylcyclopropene, 1-ethylcyclopropene, 1-n-propylcyclopropene, 1-cyclopropenylmethanol, methoxyvinylglycine (MVG), 3'-methylgibberellic acid, 1-(4-methylphenyl)-N-(2-oxo-1-propyl-1,2,3,4-tetrahydroquinolin-6-yl)methanesulfonamide and related substituted tetrahydroquinolin-6-yl)methanesulfonamides, (3E,3aR,8bS)-3-({[(2R)-4-methyl-5-oxo-2,5-dihydrofuran-2-yl)- ]oxy}methylene)-3,3a,4,8b-tetrahydro-2H-indeno[1,2-b]furan-2-one and related lactones described in EP2248421, 2-(1-naphthyl)acetamide, 1-naphthylacetic acid, 2-naphthyloxyacetic acid, nitrophenolate mixture, 4-oxo-4[(2-phenylethyl)amino]butyric acid, paclobutrazol, 4-phenylbutyric acid and its related salts (e.g. sodium 4-phenylbutyrate, potassium 4-phenylbutyrate) , phenylalanine, N-phenylphthalic acid, prohexadione, prohexadione calcium, putrescine, prohydrojasmone, rhizobitoxin, salicylic acid, methyl salicylate, sarcosine, sodium cycloprop-1-en-1-yl acetate, sodium cycloprop-2-en-1-yl acetate, sodium 3-(cycloprop-2-en-1-yl) propionate, sodium 3-(cycloprop-1-en-1-yl) propionate, sidefungin, spermidine, spermine, strigolactone (strigolactone), tecnazene, thidiazuron, triacontanol, trinexapac, trinexapac-ethyl, tryptophan, tsitodef, uniconazole, uniconazole-P, 2-fluoro-N-(3-methoxyphenyl)-9H-purin-6-amine.

[0179] Examples of safeners that can be mixed with the compounds and compositions of the present invention are:

[0180] S1) Heterocyclic carboxylic acid derivative compounds:

[0181] S1 a )Dichlorophenylpyrazoline-3-carboxylic acid compounds (S1 a ), preferably compounds such as 1-(2,4-dichlorophenyl)-5-(ethoxycarbonyl)-5-methyl-2-pyrazoline-3-carboxylic acid, ethyl 1-(2,4-dichlorophenyl)-5-(ethoxycarbonyl)-5-methyl-2-pyrazoline-3-carboxylate (S1-1) ("pyrazoline-mexyl") and related compounds as described in WO-A-91 / 07874;

[0182] S1 b )Dichlorophenylpyrazolecarboxylic acid derivatives (S1 b ), preferably compounds such as 1-(2,4-dichlorophenyl)-5-methylpyrazole-3-carboxylic acid ethyl ester (S1-2), 1-(2,4-dichlorophenyl)-5-isopropylpyrazole-3-carboxylic acid ethyl ester (S1-3), 1-(2,4-dichlorophenyl)-5-(1,1-dimethylethyl)pyrazole-3-carboxylic acid ethyl ester (S1-4) and related compounds as described in EP-A-333131 and EP-A-269806;

[0183] S1 c )1,5-Diphenylpyrazole-3-carboxylic acid derivatives (S1 c ), preferably compounds such as 1-(2,4-dichlorophenyl)-5-phenylpyrazole-3-carboxylic acid ethyl ester (S1-5), 1-(2-chlorophenyl)-5-phenylpyrazole-3-carboxylic acid methyl ester (S1-6) and related compounds as described in EP-A-268554;

[0184] S1 d )Triazole carboxylic acid compounds (S1 d ), preferably compounds such as fenthiocarbamide (ethyl ester), i.e. 1-(2,4-dichlorophenyl)-5-trichloromethyl-1H-1,2,4-triazole-3-carboxylic acid ethyl ester (S1-7) and related compounds as described in EP-A-174562 and EP-A-346620;

[0185] S1 e )5-benzyl- or 5-phenyl-2-isoxazoline-3-carboxylic acid compounds or 5,5-diphenyl-2-isoxazoline-3-carboxylic acid compounds (S1 e), preferably compounds such as ethyl 5-(2,4-dichlorobenzyl)-2-isoxazoline-3-carboxylate (S1-8) or ethyl 5-phenyl-2-isoxazoline-3-carboxylate (S1-9) and related compounds as described in WO-A-91 / 08202, or 5,5-diphenyl-2-isoxazolinecarboxylic acid (S1-10) or ethyl 5,5-diphenyl-2-isoxazoline-3-carboxylate (S1-11) ("ethyl isoxadifen") or n-propyl 5,5-diphenyl-2-isoxazoline-3-carboxylate (S1-12) or ethyl 5-(4-fluorophenyl)-5-phenyl-2-isoxazoline-3-carboxylate (S1-13) as described in patent application WO-A-95 / 07897.

[0186] S2) 8-Quinolineoxy derivative compounds (S2):

[0187] S2 a )8-Quinolinyloxyacetic acid compounds (S2 a ), preferably compounds such as 1-methylhexyl (5-chloro-8-quinolyloxy) acetate ("quinoline-mexyl"), (S2-1), 1,3-dimethylbutan-1-yl (5-chloro-8-quinolyloxy) acetate (S2-2), 4-allyloxybutyl (5-chloro-8-quinolyloxy) acetate (S2-3), 1-allyloxypropan-2-yl (5-chloro-8-quinolyloxy) acetate (S2-4), ethyl (5-chloro-8-quinolyloxy) acetate (S2-5). -5), methyl 5-chloro-8-quinolinyloxyacetate (S2-6), allyl (5-chloro-8-quinolinyloxy)acetate (S2-7), 2-(2-propyleneiminooxy)-1-ethyl (5-chloro-8-quinolinyloxy)acetate (S2-8), 2-oxoprop-1-yl (5-chloro-8-quinolinyloxy)acetate (S2-9) and related compounds as described in EP-A-86750, EP-A-94349, EP-A-191736 or EP-A-0 492 366, and also (5-chloro-8-quinolinyloxy)acetic acid (S2-10) and hydrates and salts thereof, for example lithium, sodium, potassium, calcium, magnesium, aluminum, iron, ammonium, quaternary ammonium, sulfonium or phosphonium salts thereof, as described in WO-A-2002 / 34048;

[0188] S2 b )(5-chloro-8-quinolinyloxy)malonic acid compounds (S2 b ), preferably compounds such as diethyl (5-chloro-8-quinolyloxy)malonate, diallyl (5-chloro-8-quinolyloxy)malonate, methylethyl (5-chloro-8-quinolyloxy)malonate and related compounds as described in EP-A-0 582 198.

[0189] S3) Active compounds of the dichloroacetamide class (S3), which are often used as pre-emergence safeners (soil-acting safeners), for example:

[0190] "Dichloroallylamine" (N,N-diallyl-2,2-dichloroacetamide) (S3-1), "R-29148" (3-dichloroacetyl-2,2,5-trimethyl-1,3-oxazolidine) from Stauffer (S3-2), "R-28725" (3-dichloroacetyl-2,2-dimethyl-1,3-oxazolidine) from Stauffer (S3-3), "oxadiazol" (4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxazine) (S3-4), from PPG Industries' "PPG-1292" (N-allyl-N-[(1,3-dioxolan-2-yl)methyl]dichloroacetamide) (S3-5), Sagro-Chem's "DKA-24" (N-allyl-N-[(allylcarbamoyl)methyl]dichloroacetamide) (S3-6), Nitrokemia or Monsanto's "AD-67" or "MON 4660" (3-dichloroacetyl-1-oxa-3-azaspiro[4.5]decane) (S3-7), TRI-Chemical RT's "TI-35" (1-dichloroacetylazepane) (S3-8), "Diclonon" (bicyclic ketone) or "BAS145138" or "LAB145138" ((RS)-1-dichloroacetyl-3,3,8a-trimethylperhydropyrrolo[1,2-a]pyrimidin-6-one) (S3-9), "oxadiazole" or "MON 13900" ((RS)-3-dichloroacetyl-5-(2-furyl)-2,2-dimethyloxazolidine) (S3-10) and its (R) isomer (S3-11).

[0191] S4) Acylsulfonamide compounds (S4):

[0192] S4 a ) N-acylsulfonamides and their salts as described in WO-A-97 / 45016,

[0193] S4 b ) 4-(Benzoylsulfamoyl)benzamide compounds and their salts as described in WO-A-99 / 16744,

[0194] S4 c) benzoylsulfamoylphenyl ureas, as described in EP-A-365484, for example 1-[4-(N-2-methoxybenzoylsulfamoyl)phenyl]-3-methylurea, 1-[4-(N-2-methoxybenzoylsulfamoyl)phenyl]-3,3-dimethylurea and 1-[4-(N-4,5-dimethylbenzoylsulfamoyl)phenyl]-3-methylurea;

[0195] S4 d )N-benzenesulfonyl terephthalamide compounds and their salts, for example, are known from CN 101838227.

[0196] S5) Active compounds from the class of hydroxyaromatic compounds and aromatic-aliphatic carboxylic acid derivatives (S5), for example ethyl 3,4,5-triacetoxybenzoate, 3,5-dimethoxy-4-hydroxybenzoic acid, 3,5-dihydroxybenzoic acid, 4-hydroxysalicylic acid, 4-fluorosalicylic acid, 2-hydroxycinnamic acid, 2,4-dichlorocinnamic acid, as described in WO-A-2004 / 084631, WO-A-2005 / 015994, WO-A-2005 / 016001.

[0197] S6) Active compounds of the 1,2-dihydroquinoxaline-2-one type (S6), for example 1-methyl-3-(2-thienyl)-1,2-dihydroquinoxaline-2-one, 1-methyl-3-(2-thienyl)-1,2-dihydroquinoxaline-2-thione, 1-(2-aminoethyl)-3-(2-thienyl)-1,2-dihydroquinoxaline-2-one hydrochloride, 1-(2-methylsulfonylaminoethyl)-3-(2-thienyl)-1,2-dihydroquinoxaline-2-one, as described in WO-A-2005 / 112630.

[0198] S7) Compounds of the diphenylmethoxyacetic acid derivative class (S7), such as methyl diphenylmethoxyacetate (CAS Reg. No. 41858-19-9) (S7-1), ethyl diphenylmethoxyacetate or diphenylmethoxyacetic acid, as described in WO-A-98 / 38856.

[0199] S8) 2-Fluoroacrylic acid derivatives as described in WO-A-98 / 27049.

[0200] S9) Active compounds of the 3-(5-tetrazolylcarbonyl)-2-quinolone type (S9), for example 1,2-dihydro-4-hydroxy-1-ethyl-3-(5-tetrazolylcarbonyl)-2-quinolone (CAS Reg. No. 219479-18-2), 1,2-dihydro-4-hydroxy-1-methyl-3-(5-tetrazolylcarbonyl)-2-quinolone (CAS Reg. No. 95855-00-8), as described in WO-A-199 / 000020.

[0201] S10) N-acylsulfonamides as described in WO-A-2007 / 023719 and WO-A-2007 / 023764.

[0202] S11) Active compounds from the class of oxyimino compounds (S11), which are known as safeners for seed dressings, for example:

[0203] "(Z)-1,3-dioxolan-2-ylmethoxyimino(phenyl)acetonitrile" (S11-1), which is known as a seed dressing safener for millet / sorghum to prevent damage from isopropylamine,

[0204] "Fluoroxime" (1-(4-chlorophenyl)-2,2,2-trifluoro-1-ethanone O-(1,3-dioxolan-2-ylmethyl) oxime) (S11-2), which is known as a seed dressing safener for millet / sorghum to prevent damage by isopropylamine,

[0205] "Metolachlor" or "CGA-43089" ((Z)-cyanomethyleneoxyimino(phenyl)acetonitrile) (S11-3), which is known as a seed dressing safener for millet / sorghum, is used to prevent damage by isopropylamine.

[0206] S12) Isothiothiobenzodihydropyran-4-one type active compounds (S12), for example [(3-oxo-1H-2-benzothiopyran-4(3H)-ylidene)methoxy]acetic acid methyl ester (CAS Reg. No. 205121-04-6) (S12-1) and related compounds as described in WO-A-1998 / 13361.

[0207] One or more compounds of group S13) (S13):

[0208] "Naphthalic anhydride" (1,8-naphthalic anhydride) (S13-1), which is known as a safener for corn seed dressings to prevent damage from thiocarbamate herbicides,

[0209] "Fenpyrimidine" (4,6-dichloro-2-phenylpyrimidine) (S13-2), which is known as a safener of pyrimethamine in rice sowing,

[0210] "Metolachlor" (benzyl 2-chloro-4-trifluoromethyl-1,3-thiazole-5-carboxylate) (S13-3), which is known as a seed dressing safener for millet / sorghum to prevent damage from alachlor and isopropyl metolachlor,

[0211] "CL 304415" (CAS Reg. No. 31541-57-8) (4-carboxy-3,4-dihydro-2H-1-benzopyran-4-acetic acid) (S13-4) from American Cyanamid, which is known as a safener for corn to prevent damage from imidazolinones,

[0212] "MG 191" (CAS Reg. No. 96420-72-3) (2-dichloromethyl-2-methyl-1,3-dioxolane) (S13-5) from Nitrokemia, which is known as a safener for corn,

[0213] "MG 838" from Nitrokemia (CAS Reg. No. 133993-74-5) (2-propenyl 1-oxa-4-azaspiro[4.5]decane-4-dithiocarboxylate) (S13-6),

[0214] "Disulfothion" (O,O-diethyl S-2-ethylthioethyl dithiophosphate) (S13-7),

[0215] "dietholate" (O,O-diethyl O-phenyl dithiophosphate) (S13-8),

[0216] "Toluol" (4-chlorophenylmethylcarbamate) (S13-9).

[0217] S14) Active compounds which, in addition to their herbicidal action on weeds, also act as safeners for crop plants such as rice, for example:

[0218] "Piperidinol" or "MY-93" (S-1-methyl 1-phenylethylpiperidin-1-thioate), which is known as a safener for rice to prevent damage by the herbicide pyralidone,

[0219] "Methiocarb" or "SK 23" (1-(1-methyl-1-phenylethyl)-3-p-tolylurea), which is known as a safener for rice to prevent damage by the herbicide pyrazosulfuron-methyl,

[0220] "benzyluron" = "JC-940" (3-(2-chlorophenylmethyl)-1-(1-methyl-1-phenylethyl)urea, see JP-A-60087254), which is known as a safener for rice and is used to prevent damage caused by some herbicides,

[0221] "Benzophenone" or "NK 049" (3,3'-dimethyl-4-methoxybenzophenone), which is known as a safener for rice, is used to prevent damage caused by some herbicides.

[0222] "CSB" (1-bromo-4-(chloromethylsulfonyl)benzene) (CAS Reg. No. 54091-06-4) from Kumiai, which is known as a safener against damage by some herbicides in rice.

[0223] S15) Pyridine-2-oxy-3-carboxamide as described in WO-A-2008 / 131861 and WO-A-2008 / 131860.

[0224] S16) are mainly used as active compounds of herbicides and also have a safener effect on crop plants, such as (2,4-dichlorophenoxy)acetic acid (2,4-D), (4-chlorophenoxy)acetic acid, (R,S)-2-(4-chloro-o-tolyloxy)propionic acid (mecoprop), 4-(2,4-dichlorophenoxy)butyric acid (2,4-DB), (4-chloro-o-tolyloxy)acetic acid (MCPA), 4-(4-chloro-o-tolyloxy)butyric acid, 4-(4-chlorophenoxy)butyric acid, 3,6-dichloro-2-methoxybenzoic acid (dicamba), and 1-(ethoxycarbonyl)ethyl 3,6-dichloro-2-methoxybenzoate (lactidichlor-ethyl).

[0225] The nitration inhibitors that can be mixed with the compounds and compositions of the present invention are selected from the group consisting of 2-(3,4-dimethyl-1H-pyrazol-1-yl)succinic acid, 2-(4,5-dimethyl-1H-pyrazol-1-yl)succinic acid, 3,4-dimethylpyrazolium oxalate, 3,4-dimethylpyrazolium citrate 3,4-dimethylpyrazolium lactate, 3,4-dimethylpyrazolium mandelate, 1,2,4-triazole, 4-chloro-3-methylpyrazole, N-((3(5)-methyl-1H-pyrazol-1-yl)methyl)acetamide, N-((3(5)-methyl-1H-pyrazol-1-yl)methyl)formamide, N-((4-chloro-3(5)-methyl-1H-pyrazol-1-yl)methyl)formamide. methyl)-formamide; dicyandiamide, reaction adduct of urea and formaldehyde, triazine-formaldehyde-dicyandiamide adduct, 2-cyano-1-((4-oxo-1,3,5-triazin-1-yl)methyl)guanidine, 1-((2-cyano-guanidino)-methyl)urea, 2-cyano-1-((2-cyano-guanidino)-methyl)-guanidine, 2-chloro-6-(trichloromethyl)-pyridine (nitropyridine or N-serve), dicyandiamide, 3,4-dimethylpyrazole phosphate, 4,5-dimethylpyrazole phosphate, 3,4-dimethylpyrazole, 4,5-dimethylpyrazole, ammonium thiosulfate, neem, neem-based products, linoleic acid, alpha-linolenic acid, methyl p-coumarate, methyl ferulate ferulate), methyl 3-(4-hydroxyphenyl)propionate, karanjin, brachialacton, p-benzoquinone sulfone, 4-amino-1,2,4-triazole hydrochloride, 1-amino-2-thiourea, 2-amino-4-chloro-6-methylpyrimidine, 2-mercaptobenzothiazole, 5-ethoxy-3-trichloromethyl-1,2,4-thiothiazole (terazol), 2-sulfonylthiazole, 3-methylpyrazole, 1,2,4-triazolethiourea, cyanamide, melamine, zeolite powder, catechol, benzoquinone, sodium tetraborate, allylthiourea, chlorate and zinc sulfate.

[0226] The compounds and compositions of the present invention may be combined with one or more agricultural benefit agents.

[0227] Examples of agricultural beneficial agents include biostimulants, plant growth regulators, plant signaling molecules, growth promoters, microbial stimulatory molecules, biomolecules, soil conditioners, nutrients, plant nutrition enhancers, and the like, such as lipochitooligosaccharides (LCO), chitosan oligosaccharides (COs), chitin compounds, flavonoids, jasmonic acid or its derivatives (such as jasmonate), cytokinins, auxins, gibberellins, abscisic acid, ethylene, brassinosteroids, salicylates, macro- and micronutrients, linoleic acid or its derivatives, linolenic acid or its derivatives, karrikins, and beneficial microorganisms (e.g., Rhizobium spp., Bradyrhizobium spp., Sinorhizobium spp., Azorhizobium caulinodans, Azotobacter spp. spp.), Gigaspora spp., Hymenoscyphous spp., Oidiodendron spp., Laccaria spp., Pisolithus spp., Rhizopogon spp., Scleroderma spp., Rhizoctonia species, Acinetobacter spp., Arthrobacter spp., Arthrobotrys spp., Aspergillus spp., Azospirillum spp., Bacillus spp., Burkholderia spp., Candida spp.), Chryseomonas spp., Enterobacter spp., Eupenicillium spp., Exiguobacterium spp., Klebsiella spp., Kluyvera spp., Microbacterium spp., Mucor spp., Paecilomyces spp., Paenibacillus spp.), Penicillium spp., Pseudomonas spp., Serratia spp., Stenotrophomonas spp., Streptomyces spp., Streptosporangium spp., Swaminathania spp., Thiobacillus spp., Torulospora spp., Vibrio spp., Xanthobacter spp., Xanthomonas spp., etc.) and combinations thereof.

[0228] According to certain embodiments, the compounds and compositions of the present invention may be used in combination with one or more biostimulants. Biostimulants may enhance metabolic or physiological processes such as respiration, photosynthesis, nucleic acid absorption, ion absorption, nutrient transport, or a combination thereof. Non-limiting examples of biostimulants that may be included or used in the compositions of the present invention may include seaweed extracts (e.g., ascophyllum nodosum; BAYFOLAN ALGAE, Aglukon gmbH, Germany), bacterial extracts (e.g., extracts of one or more nitrogen-fixing bacteria, phosphate-dissolving microorganisms and / or biopesticides), fungal extracts, humic acid (e.g., potassium humate), fulvic acid, inositol and / or glycine, protein hydrolysates and amino acids from animals, such as potassium humate), fulvic acid, inositol and / or glycine, hydrolyzed proteins and amino acids (including animal sources BAYFOLAN AMBITION & BAYFOLAN cobre, SICIT, Italy) and plant sources, inorganic compounds (e.g., silica), and any combination thereof. According to certain embodiments, the biostimulant may include one or more Azospirillum extracts (e.g., extracts of a medium comprising Azospirillum brasiliensis INTA Az-39), one or more Bradyrhizobium species extracts (e.g., extracts of a medium comprising B. elkanii SEMIA 501, B. elkanii SEMIA 587, B. elkanii SEMIA 5019, B. japonicum NRRL B-50586 (also as NRRL B-59565), B. japonicum NRRL B-50587 (also as NRRL B-59566), B. japonicum NRRL B-50588 (also as NRRL B-59567), B. japonicum NRRL B-50589 (also as NRRL B-59568), B. japonicum NRRL B-50590 (also as NRRL B-59569), B. japonicum NRRL B-50591 (also as NRRL B-59570), B. japonicum NRRL B-50592 (also as NRRL B-59571), B. japonicum NRRL B-50593 (also as NRRL B-59572), B. japonicum NRRL B-50594 (also as NRRL B-50493), B. japonicum NRRL B-50608, B. japonicum NRRL B-50609, B. japonicum NRRL B-50610, B. japonicum NRRL B-50611, B.japonicum NRRL B-50612, B.japonicum NRRL B-50726, B.japonicum NRRL B-50727, B.japonicum NRRL B-50728, B.japonicum NRRL B-50729, B.japonicum NRRL B-50730, B.japonicum SEMIA 566, B.japonicum SEMIA 5079, B.japonicum SEMIA 5080, B.japonicum USDA 6, B.japonicum USDA 110, B.japonicum USDA 122, B.japonicum USDA123, B.japonicum USDA 127, B.japonicum USDA 129 and / or B.japonicum USDA 532C), one or more Rhizobium extracts (e.g., the extracts of the medium include R. leguminosarum SO12A-2), one or more Sinorhizobium meliloti extracts (e.g., the extracts of the medium include S. fredii CCBAU114 and / or S. fredii USDA205), one or more Penicillium extracts (e.g., the extracts of the medium include P. bilaiae ATCC 18309, P. bilaiae ATCC 20851, P. bilaiae ATCC 22348, P. bilaiae NRRL 50162, P. bilaiae NRRL50169, P. bilaiae NRRL 50776, P. bilaiae NRRL 50777, P. bilaiae NRRL 50778, P. bilaiae NRRL 50777, P. bilaiae NRRL 50778, P. bilaiae NRRL 50779, P.bilaiae NRRL50780, P.bilaiae NRRL 50781, P.bilaiae NRRL 50782, P.bilaiae NRRL 50783, P.bilaiae NRRL 50784, P.bilaiae NRRL 50785, P.bilaiae NRRL 50786, P.bilaiae NRRL50787, P.bilaiae NRRL 50788, P.bilaiae RS7B-SD1, P.brevicompactum AgRF18, P.canescens ATCC 10419, P.expansum ATCC 24692, P. expansum YT02, P. fellatanum ATCC 48694, P. gaestrivorus NRRL 50170, P. glabrum DAOM 239074, P. glabrum CBS 229.28, P. janthinellum ATCC 10455, P. lanocoeruleum ATCC 48919, P. radicum ATCC 201836, P. radicum FRR 4717, P. radicum FRR 4719, P. radicum N93 / 47267 and / or P. raistrickii ATCC 10490), one or more Pseudomonas extracts (e.g., extracts of P. jessenii in a medium comprising PS06), one or more acaricidal, insecticidal and / or nematicidal extracts (e.g., extracts of the medium include Bacillus firmus I-1582, Bacillus mycoides AQ726, NRRL B-21664; Beauveria bassiana ATCC-74040, Beauveria bassiana ATCC-74250, Burkholderia sp. A396 sp. nov. rinojensis, NRRL B-50319, Chromobacterium spp. NRRL B-30655, Chromobacterium vaccinii NRRL B-50880, Flavobacterium H492, NRRL B-50584, Metarhizium anisopliae F52 (also known as Metarhizium anisopliae strain 52, Metarhizium anisopliae strain 7, Metarhizium anisopliae strain 43 and Metarhizium anisopliae BIO-1020, TAE-001; as DSM 3884, DSM 3885, ATCC 90448, SD 170 and ARSEF 7711) and / or Paecilomyces fumosorum FE991), and / or one or more fungal extracts (e.g., extracts of a medium including Parasitium graminis AQ. (Intrachem Bio GmbH & Co. KG, Germany), Aspergillus flavus (Syngenta Crop Protection, Inc., CH), Aureobasidium (bio ferm GmbH, Germany), Bacillus pumilus AQ717 (NRRL B21662), Bacillus pumilus NRRL B-30087, Bacillus AQ175 (ATCC 55608), Bacillus AQ177 (ATCC 55609), Bacillus subtilis AQ713 (NRRL B-21661), Bacillus subtilis AQ743 (NRRL B-21665), Bacillus subtilis var. amyloliquefaciens FZB24, Bacillus subtilis var. amyloliquefaciens NRRL B 50349, Bacillus subtilis var. amyloliquefaciens TJ1000 (also known as 1BE, isolate ATCC BAA-390), Bacillus thuringiensis AQ52 (NRRL B-21619), Candida oleophila I 82 (e.g., Purchased from Ecogen Inc., USA), Candida saitoana (mixed with lysozyme; BASF, USA) and (Arysta LifeScience, Ltd., Cary, NC), Gliocladium schrenkiana J1446 ( Verdera, Finland), (Prophyta, Germany), Cryphonectria parasitica (CNICM, France), Cryptococcus albidus YIELD (Anchor BioTechnologies, South Africa), Fusarium oxysporum (purchased from SIAPA, Italy) and (Natural Plant Protection, France), Drupe Saccharomyces cerevisiae (Agrogreen, Israel), Microdochium dimerum (Agrauxine, France), Muscodor albus NRRL 30547, Muscodor albus NRRL 30548, (Verdera, Finland), yeast Pseudomonas flocculans (Plant Products Co. Ltd., Canada), Pythium oligandrum DV74 ( Remeslo SSRO, Biopreparaty, Czech Rep.), Reynoutria sachlinensis (e.g., purchased from Marrone BioInnovations, USA), Streptomyces lydicus NRRLB-30145, Streptomyces lydicus M1064, Streptomyces galbus NRRL 30232, Streptomyces lydicus WYEC 108 (ATCC 55445), Streptomyces violaceus niger YCED 9 (ATCC 55660; and THATCH Idaho Research Foundation, USA), Streptomyces WYE 53 (ATCC 55750; and THATCH Idaho Research Foundation, USA), Xanthocyanobacterium V117b ( Prophyta, Germany), Trichoderma aspergillus SKT-1 ( Kumiai Chemical Industry Co., Ltd., Japan), dark green Trichoderma LC52 ( Agrimm Technologies Ltd, NZ), Trichoderma harzianum T 22 ( der Firma BioWorks Inc., USA), Trichoderma harzianum TH-35 (ROOT purchased from Mycontrol Ltd., Israel), Trichoderma harzianum T 39 ( Mycontrol Ltd., Israel; Makhteshim Ltd., Israel), Trichoderma harzianum ICC012 and Trichoderma viride TRICHOPEL (Agrimm Technologies Ltd, NZ), Trichoderma harzianum ICC012 and Trichoderma viride ICC080 ( WP, Isagro Ricerca, Italy), Trichoderma polysporum and Trichoderma harzianum ( BINAB Bio Innovation AB, Sweden), Trichoderma (CEPLAC, Brazil), Trichoderma virens GL 21 ( Certis LLC, USA), Trichoderma harzianum G1-3, ATCC 57678, Trichoderma harzianum G1-21 (Thermo Trilogy Corporation, Wasco, CA), Trichoderma harzianum G1-3 and Bacillus subtilis starch var. FZB2, Trichoderma harzianum G1-3 and Bacillus subtilis starch var. NRRL B50349, Trichoderma harzianum G1-3 and Bacillus subtilis starch var. TJ1000, Trichoderma harzianum G1-21 and Bacillus subtilis starch var. FZB24, Trichoderma harzianum G1-21 and Bacillus subtilis starch var. NRRL B 50349, Trichoderma harzianum G1-21 and Bacillus subtilis starch var. TJ1000, Trichoderma viride (Ecosense Labs. (India) Pvt. Ltd., Indien, F purchased from T. Stanes & Co. Ltd., India), Trichoderma viride TV1 (Agribiotec srl, Italy), Trichoderma viride ICC080, and / or Trichoderma oleracea HRU3 (BOTRY Botry Zen Ltd, NZ), and combinations thereof.

[0229] According to certain embodiments, the compounds and compositions of the present invention can be used in combination with one or more lipochito-oligosaccharides (LCOs), chito-oligosaccharides (COs) and / or shell-based compounds. LCOs, sometimes also referred to as symbiotic nodulation (Nod) signals (or Nod factors) or Myc factors, consist of a β-l,4-linked oligosaccharide backbone of N-acetyl-D-glucosamine ("GlcNAc") residues and an N-linked fatty acyl chain condensed at the non-reducing end. As is understood in the art, LCOs differ in the number of GlcNAc residues in the backbone, the length and degree of saturation of the fatty acyl chain, and the substitution of reducing and non-reducing sugar residues. See, e.g., Denarie et al., Ann. Rev. Biochem. 65:503 (1996); Diaz et al., Mol. Plant Microbe Interactions 13:268 (2000); Hungria et al., Soil Biol. Biochem. 29:819 (1997); Hamel et al., Planta 232:787 (2010); and Prome et al., Pure & Appl. 70(1):55 (1998).

[0230] LCO (and its derivatives) may be contained or used in various forms of purity and may be used alone or in the form of a culture of LCO-producing bacteria or fungi. For example, (available from Bayer) contains a culture of bradyzobium rhizobium that produces LCO. Methods for providing substantially pure LCO include removing microbial cells from a mixture of LCO and microorganisms, or continuing to separate and purify the LCO molecule by LCO solvent phase separation, followed by HPLC chromatography, as described in U.S. Pat. No. 5,549,718. The purification effect can be improved by repeated high performance liquid chromatography, and the purified LCO molecule can be freeze-dried for long-term storage. The compositions and methods of the present disclosure may include analogs, derivatives, hydrates, isomers, salts and / or solvates of LCO. According to the present invention, LCO can be added to the composition in any suitable amount / concentration. For example, a composition according to the present invention comprises about 1x10 -20 M to about 1x10 -1 M LCO. The amount / concentration of the LCO may be an amount effective to impart a positive trait or benefit to the plant, such as promoting growth and / or increasing yield of the plant to which the composition is applied. According to certain embodiments, the amount / concentration of the LCO may not be effective to increase the yield of the plant without the beneficial contribution of one or more other ingredients (e.g., COs and / or one or more pesticides) in the composition.

[0231] The compounds and compositions of the present invention may be used in combination with any suitable COs, and may also be used in combination with one or more LCOs. COs differ from LCOs in that they lack the pendant fatty acid chains characteristic of LCOs. COs, sometimes referred to as N-acetylchitooligosaccharides, are also composed of GlcNAc residues, but their side chain modifications distinguish them from chitin molecules [(C8-H13NO5)n, CAS No. 1398-61-4] and chitosan molecules [(C5H11NO4)n, CAS No. 9012-76-4]. See D'Haeze et al., Glycobiol. 12(6):79R (2002); Demont Caulet et al., Plant Physiol 120(1):83 (1999); Hanel et al., Planta 232:787 (2010); Muller et al., Plant Physiol 124:733 (2000); Robina et al., Tetrahedron 58:521-530 (2002); Rouge et al., Docking of Chitin Oligomers and Nod Factors on LysM-RLK Receptors in the Medicago-Rhizobium Symbiosis, in The Molecular Immunology of Complex Carbohydrates-3 (Springer Science, 2011); Van der Holst et al., Curr. Opin. Struc. Biol. 11:608 (2001); and Wan et al., Plant Physiol 124:733 (2000). Cell》21:1053(2009). COs can be obtained from any suitable source. For example, COs can be derived from LCO. For example, in one aspect, the composition according to the present invention comprises one or more COs derived from LCO, which can be obtained (isolated and / or purified) from the following strains: nitrogen-fixing rhizobium, bradyrhizobium (such as B. japonicum), bradyrhizobium wenxinzhong, rhizobium (such as pea rhizobium), Sinorhizobium (such as Sinorhizobium alfalfa) or mold (such as Glomus intraradicus). Alternatively, COs can also be synthetic. Methods for preparing recombinant COs are known in the art. For example, see Cottaz et al., Meth. Eng. 7(4):311(2005); Samain et al., Carbohydrate Res. 302:35(1997); and Samain et al., J. Biotechnol. 72:33(1999), the contents and disclosures of which are incorporated herein by reference.

[0232] COs (and its derivatives) can be included or used in various forms of purity and can be used alone or in the form of a culture of bacteria or fungi that produce COs. It should be understood that the compounds and compositions according to the present invention can be used in combination with hydrates, isomers, salts and / or solvates of COs. COs can be used in any suitable amount / concentration. For example, the composition according to the present invention can contain about 1x10 -20 M to about 1x10 -1 The amount / concentration of COs may be an amount that is effective in imparting positive traits or benefits to plants, such as enhancing the soil microbial environment, nutrient absorption, or promoting growth and / or increasing yield of plants to which the composition is applied. According to certain embodiments, the amount / concentration of COs may not be effective in promoting plant growth without the beneficial contribution of one or more other components (such as LCO and / or one or more inoculants, biomacromolecules, nutrients or pesticides) in the composition.

[0233] The compounds and compositions of the present invention can be combined with one or more suitable chitin compounds, such as chitin, chitosan and isomers, salts and sols thereof. Chitin and chitosan are the main components of fungal cell walls and the exoskeletons of insects and crustaceans, and are composed of GlcNAc residues. Chitin and chitosan can be obtained commercially or prepared from insects, crustacean shells or fungal cell walls. Methods for preparing chitin and chitosan are well known in the art. For example, see U.S. Patent Nos. 4,536,207 (prepared from crustacean shells) and 5,965,545 (preparation and hydrolysis of commercial chitosan from crab shells); and Pochanavanich et al., Lett.Appl.35:17 (2002) (prepared from fungal cell walls). Deacetylated chitin and chitosan can have a degree of deacetylation ranging from less than 35% to greater than 90% and cover a wide range of molecular weights, e.g., low molecular weight chitosan oligomers with molecular weights less than 15 kD and chitosan oligomers with molecular weights between 0.5 and 2 kD; "practical grade" chitosan with molecular weights of about 15 kD; and high molecular weight chitosan with molecular weights up to 70 kD. Chitin and chitosan compositions for seed treatment are commercially available. Commercial products include (Plant Defense Boosters, Inc.) and BEYOND TM (Agrihouse, Inc.).

[0234] The compounds and compositions of the present invention may be combined with one or more suitable flavonoids, including but not limited to anthocyanidins, flavonoids, chalcones, coumarins, flavanones, flavanols, flavans and isoflavones, and their analogs, derivatives, hydrates, isomers, polymers, salts and solvates. Flavonoids are phenolic compounds whose general structure is two aromatic rings connected by three carbon bridges. Flavonoids are compounds known in the art. For example, see Jain et al., J. Plant Biochem. 11: 1 (2002); and Shaw et al., Environ. Microbiol. 11: 1867 (2006), the contents and disclosures of which are incorporated herein by reference. There are many flavonoid compounds on the market. Flavonoid compounds can be isolated from plants or seeds, as described in U.S. Patents 5,702,752, 5,990,291 and 6,146,668. Flavonoid compounds can also be produced by genetically engineered organisms, such as yeast. See Ralston et al., Plant Physiol 137:1375 (2005).

[0235] According to some embodiments, the compounds and compositions of the present invention can be used in combination with one or more flavanones, such as butin, eriodictyol, hesperetin, hesperidin, homoeriodictyol, isosakuranetin, naringenin, naringin, pinocembrin, poncir in), sakuranetin, sakuranin and / or sterubin; in combination with one or more flavanols, such as dihydrokaempferol and / or taxifolin; in combination with one or more flavans, such as one or more flavan-3-ols (e.g., catechin (C), catechin 3-gallate (Cg), epicatechin (EC), epigallocatechin (EGC), epicatechin 3-gallate (ECg ), epigallocatechin 3-gallate (EGCg), epiafzelechin, fisetinidol, GC, GCg, guibourtinidol, mesquitol, robinetinidol, theaflavin-3-gallate, theaflavin-3'-gallate, flavin-3,3'-gallate, emodin), flavan-4-ols (e.g., apiol and / or aloesol) and / or flavonols Alkane-3,4-diols (e.g., leucocyanidin, leucodelphinidin, leucofisetinidin, leucomalvidin, luecopelargonidin, leucopeonidin, leucorobinetinidin, melacacidin and / or teracacidin) and / or dimers, trimers, oligomers and / or polymers thereof (e.g., one or more proanthocyanidins);In combination with one or more isoflavones, for example, one or more isoflavones or flavonoid derivatives (e.g., biochanin A, daidzein, formononetin, genistein and / or glycitein), isoflavans (e.g., equol, ionchocarpane and / or laxifloorane), isoflavanediols, isoflavins (e.g., glabrene, haginin D and / or 2-methoxyjudaicin), coumestrols (e.g., coumestrol, plicadin, and / or wedelolactone), pterocarpans, roetonoids, newoflavonoids (e.g., calophyllolide, coutareagenin, dalbergichromene, dalbergin, nivetin), and / or pterocarpans (e.g., bitucarpin A, bitucarpin B, erybraedin A, erybraedin B, B. Erythrabyssin-Ⅱ, erythrabyssin-1, erycristagallin, glycinol, glyceollidins, glyceollins, glycyrrhizol, maackiain, medicarpin, morisianine, orientanol, phaseolin, pisatin, striatine, trifol irhizin)), and combinations thereof. Flavonoid compounds and their derivatives may be included in the composition of the present invention in any suitable form, including but not limited to polymorphs and crystalline forms. According to the present invention, flavonoid compounds may be added to the composition in any suitable amount or concentration. The amount / concentration of flavonoids may be an effective amount that is beneficial to plants, which can be achieved indirectly through the activity of soil microorganisms or other means, such as improving plant nutrition and / or yield. According to certain embodiments, the amount / concentration of flavonoid compounds may not be effective in improving plant nutrition or yield without the beneficial contribution of one or more other components of the composition (such as LCO, COs and / or one or more pesticides). ;

[0236] The compounds and compositions of the present invention can be used in combination with one or more suitable non-flavonoid nodulation gene inducers, including but not limited to jasmonic acid ([1R-[1α,2β(Z)]]-3-oxo-2-(pentenyl)cyclopentaneacetic acid; JA), linoleic acid ((Z,Z)-9,12-octadecadienoic acid) and / or linolenic acid ((Z,Z,Z)-9,12,15-octadecatrienoic acid), and their analogs, derivatives, hydrates, isomers, polymers, salts and solvates. Jasmonic acid and its methyl jasmonate (MeJA), collectively referred to as jasmonates, are octadecyl compounds that occur naturally in certain plants (such as wheat), fungi (such as Botryodiplodia theobromae, Gibbrella fujikuroi), yeasts (such as Saccharomyces cerevisiae) and bacteria (such as Escherichia coli). Linoleic acid and linolenic acid may be produced during the biosynthesis of jasmonic acid. It is reported that jasmonic acid, linoleic acid and linolenic acid (and their derivatives) are inducers of rhizobia to express nodulation genes or produce LCO. For example, see Mabood et al., Plant Physiol. Biochem 44(11):759 (2006); Mabood et al., Agr. J. 98(2):289 (2006); Mabood et al., Field Crops Res. 95(2-3):412 (2006); and Mabood and Smith, Linoleic and linolenic acid induce the expression of nod genes in Bradyrhizobium japonicum USDA 3, Plant Biol. (2001).

[0237] Derivatives of jasmonic acid, linoleic acid and linolenic acid may include esters, amides, glycosides and salts thereof, and may also be used in combination with the compounds and compositions according to the present invention. Representative esters are compounds in which the carboxyl group of linoleic acid, linolenic acid or jasmonic acid is replaced by a -COR group, wherein R is -OR 1 Group, R 1 is: an alkyl group, such as a C1-C8 unbranched or branched alkyl group, such as a methyl group, an ethyl group or a propyl group; an alkenyl group, such as a C2-C8 unbranched or branched alkenyl group; an alkynyl group, such as a C2-C8 unbranched or branched alkynyl group; an aryl group, such as a C2-C8 unbranched or branched alkynyl group; an aryl group, such as a C2-C8 unbranched or branched alkynyl group; an aryl group, such as a C2-C8 unbranched or branched alkynyl group; or a heteroaryl group, such as a heteroaryl group, having 4 to 9 carbon atoms, wherein the heteroatom in the heteroaryl group may be N, O, P or S. A representative amide is a compound in which the carboxyl group of linoleic acid, linolenic acid or jasmonic acid is replaced by a -COR group, wherein R is NR 2 R 3 Group, where R 2 and R 3Each independently is: hydrogen; alkyl, such as C1-C8 unbranched or branched alkyl, for example, methyl, ethyl or propyl; alkenyl, such as C2-C8 unbranched or branched alkenyl; alkynyl, such as C2-C8 unbranched or branched alkynyl; aryl, for example, having 6 to 10 carbon atoms; or heteroaryl, for example, having 4 to 9 carbon atoms, wherein the heteroatom in the heteroaryl can be N, O, P or S. Esters can be prepared by known methods, such as acid-catalyzed nucleophilic addition, wherein carboxylic acid and alcohol react in the presence of a catalytic amount of a mineral acid. Amides can also be prepared by known methods, such as reacting carboxylic acid with an appropriate amine under neutral conditions in the presence of a coupling agent such as dicyclohexylcarbodiimide (DCC). Suitable salts of linoleic acid, linolenic acid and jasmonic acid include base addition salts and the like. Alkaline agents useful for preparing metabolically acceptable basic salts of these compounds include bases derived from cations such as alkali metal cations (e.g., potassium and sodium) and alkaline earth metal cations (e.g., calcium and magnesium). These salts can be readily prepared by mixing a solution of linoleic acid, linolenic acid, or jasmonic acid with a solution of a base. These salts can precipitate from solution and be collected by filtration or can be recovered by other methods, such as evaporation of the solvent.

[0238] Non-flavonoid nodulation gene inducers can be used in combination with the compounds and compositions according to the present invention and in any suitable amount / concentration. For example, the dosage / concentration of the non-flavonoid nodulation gene inducer can be an amount that can effectively impart positive traits or benefits to the plant, such as promoting the growth and / or increasing the yield of the plant to which the composition is applied. According to certain embodiments, the amount / concentration of the non-flavonoid nodulation gene inducer may not be able to effectively promote the growth of the plant without the beneficial contribution of one or more other ingredients in the composition (such as LCO, COs and / or one or more pesticides).

[0239] The compounds and compositions of the present invention may be combined with karrakins, including but not limited to 2H-furano[2,3-c]pyran-2-one, and analogs, derivatives, hydrates, isomers, polymers, salts and solvates thereof. Examples of biologically acceptable salts of karrakins include acid addition salts formed with biologically acceptable acids, examples of which include hydrochlorides, hydrobromides, sulfates or bisulfates, phosphoric acid or hydrogen phosphates, acetates, benzoates, succinates, fumarates, maleates, lactates, citrates, tartrates, gluconates; methanesulfonates, benzenesulfonates and p-toluenesulfonic acid. Other biologically acceptable metal salts may include alkali metal salts with bases, such as sodium and potassium salts. Karrakins may be used and added to the compound combinations according to the present invention in any suitable amount / concentration. For example, the dosage / concentration of karrakins may be an amount that is effective in imparting positive traits or benefits to plants, promoting growth and / or increasing yield of plants to which the composition is applied. On the one hand, the amount / concentration of Karrakins may not be effective in promoting plant growth without the beneficial contribution of one or more other ingredients in the composition (such as LCO, COs and / or one or more pesticides).

[0240] The compounds and compositions of the present invention may be used in combination with one or more anthocyanidins and / or flavonoids, such as one or more cyanidin, delphinidin, malvidin, pelargonidin, peonidin, petunidin, flavonoids (e.g., apigenin, baicalein, chrysin, 7,8-dihydroxyflavone, diosmin (d iosmin), flavoxate, 6-hydroxyflavone, luteolin, scutellarein, tangeritin and / or wogonin and / or flavonols (e.g. amurensin, astragalin, azaleatin, azalein, fisetin, furanoflavonols galangin, galangin), gossypetin, 3-hydroxyflavone, hyperoside, icariin, isoquercetin, kaempferide, kaempferitrin, kaempferol, isorhamnetin, morin, myricetin, myricitrin, natsudaidain, pachypodol, pyranoflavonols quercetin, quericitin, rhamnazin, rhamnetin, robinin, rutin, spiraeoside, troxerutin and / or zanthorhamnin, and combinations thereof.

[0241] Compound and composition of the present invention can be used in combination with gluconolactone and / or its analog, derivative, hydrate, isomer, polymer, salt and / or solvate. Gluconolactone can be added to the composition according to the present invention with any suitable amount / concentration. For example, the amount / concentration of gluconolactone can be an effective amount for transmitting or giving positive traits or benefits to plants, such as promoting the growth and / or increasing yield of the plant applying the composition. On the one hand, if there is no beneficial contribution of one or more other components (such as LCO, COs and / or one or more pesticides) in the composition, the amount / concentration of gluconolactone may not effectively improve the growth and / or yield of plants.

[0242] The compounds and compositions of the present invention can be used in combination with one or more suitable nutrients and / or fertilizers, such as organic acids (e.g., acetic acid, citric acid, lactic acid, malic acid, taurine, etc.), macrominerals (e.g., phosphorus, calcium, magnesium, potassium, sodium, iron, etc.), trace elements (e.g., boron, cobalt, chlorine, chromium, copper, fluorine, iodine, iron, manganese, molybdenum, selenium, zinc, etc.), vitamins (e.g., vitamin A, vitamin B group (i.e., vitamin B1, vitamin B2, vitamin B3, vitamin B5, vitamin B6, vitamin B7, vitamin B8, vitamin B9, vitamin B12, choline), vitamin C, vitamin D, vitamin E, vitamin K) and / or carotenoids (α-carotene, β-carotene, cryptoxanthin, lutein, lycopene, zeaxanthin, etc.), and combinations thereof. In one aspect, the compounds and compositions according to the present invention can be combined with macro- and micronutrients of plants or microorganisms, including phosphorus, boron, chlorine, copper, iron, manganese, molybdenum and / or zinc. According to certain embodiments, the compounds and compositions according to the present invention can be used in combination with one or more beneficial micronutrients. Non-limiting examples of micronutrients for the compositions described herein can include vitamins (e.g., vitamin A, vitamin B group (i.e., vitamin B5, vitamin B6, vitamin B7, vitamin B8, vitamin B9, vitamin B12, choline), vitamin C, vitamin D, vitamin E, vitamin K, carotenoids (α-carotene, β-carotene, cryptoxanthin, lutein, lycopene, zeaxanthin, etc.), macrominerals (such as phosphorus, calcium, magnesium, potassium, sodium, iron, etc.), trace minerals (such as boron, cobalt, chloride, chromium, copper, fluoride, iodine, iron, manganese, molybdenum, selenium, zinc, etc.), organic acids (such as acetic acid, citric acid, lactic acid, malic acid, taurine, etc.), and combinations thereof (BAYFOLAN secure, BAYFOLAN complete, BAYFOLAN energy, BAYFOLAN from Aglukon, Germany). power). In a particular aspect, the composition can include phosphorus, boron, chlorine, copper, iron, manganese, molybdenum and / or zinc, and combinations thereof. For compositions comprising phosphorus, it is contemplated that any suitable source of phosphorus can be used. For example, the phosphorus can be derived from a phosphate rock source, such as monoammonium phosphate, diammonium phosphate, monocalcium phosphate, superphosphate, triple superphosphate and / or ammonium polyphosphate, an organic phosphorus source, or a phosphorus source that can be solubilized by one or more microorganisms (such as Penicillium).

[0243] Composition / Formulation

[0244] The present invention further relates to compositions, in particular compositions for controlling unwanted microorganisms. The compositions can be applied to the microorganisms and / or their habitat.

[0245] Said CompositionIt comprises at least one compound of the present invention and at least one agriculturally suitable adjuvant, such as a carrier and / or a surfactant.

[0246] Carrier It is a solid or liquid, natural or synthetic, organic or inorganic substance that is generally inert. The carrier generally allows the compound to be better applied to, for example, plants, plant parts or seeds. Examples of suitable solid carriers include, but are not limited to, ammonium salts, especially ammonium sulfate, ammonium phosphate and ammonium nitrate; natural rock powders such as kaolin, clay, talc, chalk, quartz, attapulgite, montmorillonite and diatomaceous earth; silica gel and synthetic rock powders such as finely dispersed silicon dioxide, alumina and silicates. Examples of typical useful solid carriers for preparing granules include, but are not limited to, crushed and classified natural rocks such as calcite, marble, pumice, sepiolite and dolomite, synthetic particles of inorganic and organic powders, and particles of organic materials such as paper, sawdust, coconut shells, corn cobs and tobacco straw. Examples of suitable liquid carriers include, but are not limited to, water, organic solvents and combinations thereof. Examples of suitable solvents include polar and nonpolar organic chemical liquids, such as aromatic and nonaromatic hydrocarbons (e.g. cyclohexane, alkanes, alkylbenzenes, xylene, toluene, tetralin, alkylnaphthalenes, chlorinated aromatic or chlorinated aliphatic hydrocarbons such as chlorobenzene, vinyl chloride or methylene chloride), alcohols or polyols (which may optionally be substituted, etherified and / or esterified, such as ethanol, propanol, butanol, benzyl alcohol, cyclohexanol or ethylene glycol), ketones (e.g. acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone), esters (including fats and oils) and (poly)ethers, unsubstituted and substituted amines, their amides (e.g. dimethylformamide or fatty acid amides) and esters, lactams (e.g. N-alkylpyrrolidones, in particular N-methylpyrrolidone) and lactones, sulfones and sulfoxides (e.g. dimethyl sulfoxide), vegetable oils or oils of animal origin. The carrier may also be a liquefied gas extender, ie a liquid which is gaseous at standard temperature and pressure, for example an aerosol propellant such as halogenated hydrocarbons, butane, propane, nitrogen and carbon dioxide.

[0247] Preferred solid carriers are selected from clay, talc and silica.

[0248] Preferred liquid carriers are selected from water, fatty acid amides and esters thereof, aromatic and non-aromatic hydrocarbons, lactams and carbonates.

[0249] The amount of carrier is generally from 1 to 99.99%, preferably from 5 to 99.9%, more preferably from 10 to 99.5%, most preferably from 20 to 99% by weight of the composition.

[0250] The liquid carrier is generally present at 20 to 99%, such as 30 to 80%, by weight of the composition.

[0251] The solid carrier is generally present at 0 to 50%, preferably 5 to 45%, such as 10 to 30%, based on the weight of the composition.

[0252] If the composition comprises two or more carriers, the above ranges refer to the total amount of the carriers.

[0253] Said Surfactants It may be an ionic (cationic or anionic), amphoteric or nonionic surfactant, such as an ionic or nonionic emulsifier, foaming agent, dispersant, wetting agent, penetration enhancer, and any mixture of these surfactants. Examples of suitable surfactants include, but are not limited to, polyacrylates, lignin sulfonates (e.g., sodium lignin sulfonate), phenol sulfonates or naphthalene sulfonates, polycondensates of ethylene oxide and / or propylene oxide with fatty alcohols, fatty acids or fatty amines (e.g., polyoxyethylene fatty acid esters, such as castor oil ethoxylates; polyoxyethylene fatty alcohol ethers, such as alkylaryl polyglycol ethers), substituted phenols (preferably alkylphenols or arylphenols) and ethoxylates thereof (e.g., tristyrylphenol ethoxylates), salts of sulfosuccinates, taurine derivatives (preferably taurine alkyl esters), phosphate esters of polyethoxylated alcohols or phenols, fatty esters of polyols (e.g., fatty acid esters of glycerol, sorbitol or sucrose), sulfates (e.g., alkyl sulfates and alkyl ether sulfates), sulfonates (e.g., alkyl sulfonates, aryl sulfonates and alkylbenzene sulfonates), phosphate esters, protein hydrolyzates, lignin sulfate waste liquors and methylcellulose. Any salts mentioned in this paragraph preferably refer to respective alkali metal salts, alkaline earth metal salts and ammonium salts.

[0254] Preferred surfactants are selected from polyoxyethylene fatty alcohol ethers, polyoxyethylene fatty acid esters, alkylbenzene sulfonates such as calcium dodecylbenzene sulfonate, castor oil ethoxylate, sodium lignin sulfonate and arylphenol ethoxylates such as tristyrylphenol ethoxylate.

[0255] The amount of surfactant is typically from 5 to 40%, for example 10 to 20%, based on the weight of the composition.

[0256] Suitable additivesOther examples of the present invention include water repellents, desiccants, binders (adhesives, tackifiers, fixatives such as carboxymethylcellulose, natural and synthetic polymers in the form of powders, granules or latexes (e.g. gum arabic, polyvinyl alcohol and polyvinyl acetate), natural phospholipids (e.g. cephalin and lecithin) and synthetic phospholipids, polyvinylpyrrolidone and sodium tylose acetate), thickeners and secondary thickeners (e.g. cellulose ethers, acrylic acid derivatives, xanthan gum, modified clays, such as the products available under the name Bentone, and finely divided silica), stabilizers (e.g. cold stabilizers, preservatives (e.g. dichlorobenzene and benzyl alcohol semi-solids), and Formal), antioxidants, light stabilizers (especially UV stabilizers) or other agents that can improve chemical and / or physical stability), dyes or pigments (for example inorganic pigments, such as iron oxide, titanium oxide and Prussian blue; organic dyes, such as alizarin dyes, azo dyes and metal phthalocyanine dyes), defoamers (for example silicone defoamers and magnesium stearate), antifreeze agents, adhesives, gibberellins and processing aids, mineral and vegetable oils, fragrances, waxes, nutrients (including trace nutrients, such as iron salts, manganese salts, boron salts, copper salts, cobalt salts, molybdenum salts and zinc salts), protective colloids, thixotropic substances, penetrants, chelating agents and complex formers.

[0257] The selection of adjuvants is related to the intended mode of administration of the compound of the present invention and / or the physical properties of the compound. In addition, adjuvants can be selected to impart specific properties (technical, physical and / or biological properties) to the composition or the use forms prepared therefrom. The selection of adjuvants can allow the composition to be customized according to specific needs.

[0258] The composition of the present invention can be provided to the end user in the form of a ready-to-use formulation, i.e., a composition that can be applied directly to plants or seeds by suitable equipment such as spraying or dusting devices. Alternatively, the composition can be provided to the end user in the form of a concentrate that must be diluted before use, preferably with water.

[0259] The compositions of the invention can be prepared in conventional manner, for example by mixing a compound of the invention with one or more suitable auxiliaries (for example as disclosed above).

[0260] The composition comprises a fungicidal effective amount of the compound of the present invention. The term "effective amount" means an amount that is sufficient to prevent and treat harmful fungi on cultivated plants or in protected materials, and does not cause substantial damage to the treated plants. Such an amount can vary within a wide range and depends on various factors, such as the fungus species to be prevented and treated, the cultivated plants or materials to be treated, climatic conditions and the specific compounds of the present invention used. Typically, the composition according to the present invention comprises 0.01 to 99% by weight, preferably 0.05 to 98% by weight, more preferably 0.1 to 95% by weight, even more preferably 0.5 to 90% by weight, most preferably 1 to 80% by weight of the compound of the present invention. The composition may comprise two or more compounds of the present invention. In this case, the above range refers to the total amount of the compound of the present invention.

[0261] The composition of the present invention may be any conventional Composition form , such as solutions (e.g., aqueous solutions), emulsions, water-based and oil-based suspensions, powders (e.g., wettable powders, soluble powders), dusts, pastes, granules (e.g., soluble granules, granules for broadcasting), suspension concentrates, natural or synthetic products impregnated with the compounds of the invention, fertilizers, and microcapsules in polymeric substances. The compounds of the invention may be present in suspended, emulsified, or dissolved forms. Examples of particularly suitable composition forms are solutions, water-soluble concentrates (such as SL, LS), dispersible concentrates (DC), suspensions and suspension concentrates (such as SC, OD, OF, FS), emulsifiable concentrates (such as EC), emulsions (such as EW, EO, ES, ME, SE), capsules (such as CS, ZC), pastes, lozenges, wettable powders or dusts (such as WP, SP, WS, DP, DS), compressed tablets (such as BR, TB, DT), granules (such as WG, SG, GR, FG, GG, MG), insecticides (such as LN) and gel preparations (such as GW, GF) for treating plant propagation materials such as seeds. These and other composition types are defined by the Food and Agriculture Organization of the United Nations (FAO). The overview given is provided in "Catalogue of pesticide formulation types and international coding system", Technical Monograph No. 2, the 6th edition May 2008, Croplife International.

[0262] Preferably, the composition of the present invention is in the form of one of the following types: EC, SC, FS, SE, OD and WG, more preferably EC, SC, OD and WG.

[0263] Further details about the types of compositions and examples of their preparation are given below. If there are more than two compounds of the invention, the summarised amount of the compounds of the invention refers to the total amount of the compounds of the invention. This reference applies to any other components of the composition, if there are more than two such components (e.g. wetting agents, adhesives).

[0264] i) Water-soluble concentrates (SL, LS)

[0265] 10-60 wt % of at least one compound of the present invention and 5-15 wt % of a surfactant (e.g. a polyoxyethylene fatty alcohol ether) are dissolved in a corresponding amount of water and / or a water-soluble solvent (e.g. an alcohol such as propylene glycol, or a carbonate such as propylene carbonate) to give a total amount of 100 wt %. Before application, the concentrate is diluted with water.

[0266] ii) Dispersible Concentrate (DC)

[0267] 5-25 wt% of at least one compound of the present invention and 1-10 wt% of a surfactant and / or binder (eg polyvinyl pyrrolidone) are dissolved in a corresponding amount of an organic solvent (eg cyclohexanone) to give a total amount of 100 wt%. The dispersion is diluted with water.

[0268] iii) Emulsifiable Concentrate (EC)

[0269] 15-70% by weight of at least one compound of the present invention and 5-10% by weight of a surfactant (e.g. a mixture of calcium dodecylbenzenesulfonate and castor oil ethoxylate) are dissolved in a corresponding amount of a water-insoluble organic solvent (e.g. an aromatic hydrocarbon or a fatty acid amide), and if necessary, a water-soluble solvent is added to give a total amount of 100% by weight. The mixture is diluted with water to obtain an emulsion.

[0270] iv) Emulsions (EW, EO, ES)

[0271] 5-40% by weight of at least one compound of the present invention and 1-10% by weight of a surfactant (e.g., a mixture of calcium dodecylbenzenesulfonate and castor oil ethoxylate) are dissolved in 20-40% by weight of a water-insoluble organic solvent (e.g., an aromatic hydrocarbon). The mixture is added to a corresponding amount of water by an emulsifier to obtain a total amount of 100% by weight. The resulting composition is a uniform emulsion. Prior to application, the emulsion may be further diluted with water.

[0272] v) Suspension concentrates and suspension concentrates

[0273] v-1) Water-based (SC, FS)

[0274] In a suitable grinding apparatus (e.g. a stirred ball mill), 20-60% by weight of at least one compound according to the invention are pulverized with 2-10% by weight of a surfactant (e.g. sodium lignin sulfonate and polyoxyethylene fatty alcohol ether) added, 0.1-2% by weight of a thickener (e.g. xanthan gum) and water to obtain a fine active substance suspension. Water is added in a corresponding amount to give a total amount of 100% by weight. Dilution with water gives a stable suspension of the active substance. For FS-type compositions, up to 40% by weight of a binder (e.g. polyvinyl alcohol) is added.

[0275] v-2) Oil-based (OD, OF)

[0276] In a suitable grinding apparatus (e.g. a stirred ball mill), 20-60% by weight of at least one compound according to the invention is comminuted with 2-10% by weight of a surfactant (e.g. sodium lignin sulfonate and polyoxyethylene fatty alcohol ether) added, 0.1-2% by weight of a thickener (e.g. modified clay, in particular bentone or silica) and an organic carrier to obtain a fine active substance oil suspension. The organic carrier is added in a corresponding amount to give a total amount of 100% by weight. Dilution with water gives a stable dispersion of the active substance.

[0277] vi) Water dispersible granules and water soluble granules (WG, SG)

[0278] 50-80% by weight of at least one compound according to the invention is finely ground with added surfactants (e.g. sodium lignin sulfonate and polyoxyethylene fatty alcohol ether) and converted into water-dispersible or water-soluble granules by means of technical equipment (e.g. extrusion, spray tower, fluidized bed). The surfactant is used in the corresponding amount to give a total amount of 100% by weight. Dilution with water gives a stable dispersion or solution of the active substance.

[0279] vii) Water dispersible powders and water soluble powders (WP, SP, WS)

[0280] In a rotor-stator mill, 50-80% by weight of at least one compound according to the invention is finely ground with 1-8% by weight of a surfactant (e.g. sodium lignin sulfonate, polyoxyethylene fatty alcohol ether) added and a corresponding amount of a solid carrier (e.g. silica gel) to give a total amount of 100% by weight. Dilution with water gives a stable dispersion or solution of the active substance.

[0281] viii) Gel (GW, GF)

[0282] In a stirred ball mill, 5-25% by weight of at least one compound according to the invention are comminuted with added 3-10% by weight of a surfactant (e.g. sodium lignin sulfonate), 1-5% by weight of a binder (e.g. carboxymethylcellulose) and the corresponding amount of water to give a total amount of 100% by weight. This results in a fine suspension of the active substance. Dilution with water gives a stable suspension of the active substance.

[0283] ix) Microemulsion (ME)

[0284] 5-20% by weight of at least one compound of the invention is added to 5-30% by weight of an organic solvent mixture (e.g. fatty acid dimethylamide and cyclohexanone), 10-25% by weight of a surfactant mixture (e.g. polyoxyethylene fatty alcohol ether and arylphenol ethoxylate) and a corresponding amount of water to give a total amount of 100% by weight. The mixture is stirred for 1 hour to spontaneously produce a thermodynamically stable microemulsion.

[0285] x) Microcapsules (CS)

[0286] An oil phase comprising 5-50% by weight of at least one compound of the invention, 0-40% by weight of a water-insoluble organic solvent (e.g., aromatic hydrocarbons), 2-15% by weight of acrylic monomers (e.g., methyl methacrylate, methacrylic acid, and diacrylates or triacrylates) is dispersed in an aqueous solution of a protective colloid (e.g., polyvinyl alcohol). Free radical polymerization initiated by a free radical initiator leads to the formation of poly(meth)acrylate microcapsules. Alternatively, an oil phase comprising 5-50% by weight of at least one compound of the invention, 0-40% by weight of a water-insoluble organic solvent (e.g., aromatic hydrocarbons) and isocyanate monomers (e.g., diphenylmethylene-4,4'-diisocyanate) is dispersed in an aqueous solution of a protective colloid (e.g., polyvinyl alcohol). Addition of a polyamine (e.g., hexamethylenediamine) leads to the formation of polyurea microcapsules. The amount of monomers is 1-10% by weight, based on the weight of the total CS composition.

[0287] xi) Powders (DP, DS)

[0288] 1 to 10% by weight of at least one compound according to the invention are ground finely and intimately mixed with a corresponding amount of solid carrier (eg finely divided kaolin) to give a total amount of 100% by weight.

[0289] xii) Granules (GR, FG)

[0290] 0.5-30% by weight of at least one compound according to the invention are ground finely and combined with a corresponding amount of a solid carrier (eg silicate) to give a total amount of 100% by weight. Granulation is achieved by extrusion, spray drying or fluidized bed.

[0291] xiii) Ultra Low Volume Liquid (UL)

[0292] 1 to 50% by weight of at least one compound according to the invention is dissolved in a corresponding amount of an organic solvent (eg an aromatic hydrocarbon) to give a total amount of 100% by weight.

[0293] Composition types i) to xiii) may optionally comprise further auxiliaries, for example 0.1 to 1% by weight of preservatives, 0.1 to 1% by weight of antifoams, 0.1 to 1% by weight of dyes and / or pigments and 5 to 10% by weight of antifreeze agents.

[0294] The invention is illustrated by the following examples. However, the invention is not limited to the examples. Example

[0295] A-1. In vivo protection against Alternaria brassicae (radish or cabbage leaf spot) test

[0296] Solvent: 5% by volume dimethyl sulfoxide

[0297] 10% by volume acetone

[0298] Emulsifier: 1 μL per mg of active ingredient 80

[0299] The active ingredient was mixed in dimethyl sulfoxide / acetone / Dissolve in 80% of the mixture and homogenize, then dilute in water to the desired concentration.

[0300] Young plants of radish or cabbage were treated by spraying with the active ingredient prepared as described above. Control plants were treated with acetone / DMSO / 80% aqueous solution for treatment.

[0301] After 24 hours, the plants are infected by spraying the leaves with an aqueous suspension of spores of Alternaria officinalis. The infected radish or cabbage plants are incubated at 20°C and 100% relative humidity for 3 to 4 days.

[0302] The tests are evaluated 3 to 4 days after inoculation. 0% means an efficacy which corresponds to that of the control plants, while an efficacy of 100% means that no disease is observed.

[0303] In this test, compound (I) showed an efficacy of at least 70% at an active ingredient concentration of 500 ppm.

[0304] A-2. In vivo preventive test against Botrytis cinerea (gray mold) Solvent: 5% by volume dimethyl sulfoxide

[0305] 10% by volume acetone

[0306] Emulsifier: 1 μL per mg of active ingredient 80

[0307] The active ingredient was mixed in dimethyl sulfoxide / acetone / Dissolve in 80% of the mixture and homogenize, then dilute in water to the desired concentration.

[0308] Young plants of cucumber or cabbage were treated by spraying with the active ingredient prepared as described above. Control plants were treated with acetone / DMSO / 80% aqueous solution for treatment.

[0309] After 24 hours, the plants are infected by spraying the leaves with an aqueous suspension of Botrytis cinerea spores. The infected cucumber plants are incubated at 17° C. and 90% relative humidity for 4-5 days. The infected cabbage plants are incubated at 20° C. and 100% relative humidity for 4-5 days.

[0310] The tests are evaluated 4-5 days after inoculation. 0% means an efficacy which corresponds to that of the control plants, while an efficacy of 100% means that no disease is observed.

[0311] In this test, compound (I) showed an efficacy of at least 70% at an active ingredient concentration of 500 ppm.

[0312] A-3. In vivo preventive test against Pyrenophorateres (barley net blotch)

[0313] Solvent: 5% by volume dimethyl sulfoxide

[0314] 10% by volume acetone

[0315] Emulsifier: 1 μL per mg of active ingredient 80

[0316] The active ingredient was mixed in dimethyl sulfoxide / acetone / Dissolve in 80% of the mixture and homogenize, then dilute in water to the desired concentration.

[0317] Young barley plants were treated by spraying with the active ingredient prepared as described above. Control plants were treated with acetone / DMSO / 80% aqueous solution for treatment.

[0318] After 24 hours, the plants are infected by spraying the leaves with an aqueous suspension of Pyricularia terrestris spores. The infected barley plants are incubated at 20°C and 100% relative humidity for 48 hours and then at 20°C and 70-80% relative humidity for 8 days.

[0319] The test is evaluated 10 days after inoculation. 0% means an efficacy which corresponds to that of the control plants, while an efficacy of 100% means that no disease is observed.

[0320] In this test, compound (I) showed an efficacy of at least 70% at an active ingredient concentration of 500 ppm.

[0321] A-4. In vivo preventive test against Septoria tritici (wheat leaf spot)

[0322] Solvent: 5% by volume dimethyl sulfoxide

[0323] 10% by volume acetone

[0324] Emulsifier: 1 μL per mg of active ingredient 80

[0325] The active ingredient was mixed in dimethyl sulfoxide / acetone / Dissolve in 80% of the mixture and homogenize, then dilute in water to the desired concentration.

[0326] Young wheat plants were treated by spraying with the active ingredient prepared as described above. Control plants were treated with acetone / DMSO / 80% aqueous solution for treatment.

[0327] After 24 hours, the plants are infected by spraying the leaves with an aqueous suspension of Septoria tritici spores. The infected wheat plants are incubated at 17°C and 100% relative humidity for 72 hours and then at 20°C and 90% relative humidity for 14 to 16 days.

[0328] The tests are evaluated 17 to 19 days after inoculation. 0% means an efficacy which corresponds to that of the control plants, while an efficacy of 100% means that no disease is observed.

[0329] In this test, compound (I) showed an efficacy of at least 70% at an active ingredient concentration of 500 ppm.

[0330] A-5. In vivo preventive test against Sphaerotheca fuliginea (powdery mildew of melons)

[0331] Solvent: 5% by volume dimethyl sulfoxide

[0332] 10% by volume acetone

[0333] Emulsifier: 1 μL per mg of active ingredient 80

[0334] The active ingredient was mixed in dimethyl sulfoxide / acetone / Dissolve in 80% of the mixture and homogenize, then dilute in water to the desired concentration.

[0335] Young cucumber plants were treated by spraying with the active ingredient prepared as described above. Control plants were treated with acetone / DMSO / 80% aqueous solution for treatment.

[0336] After 24 hours, the plants are infected by spraying the leaves with an aqueous suspension of spores of Erysiphe lepidium. The infected cucumber plants are incubated at 20°C and 70-80% relative humidity for 8 days.

[0337] The test is evaluated 8 days after inoculation. 0% means an efficacy which corresponds to that of the control plants, while an efficacy of 100% means that no disease is observed.

[0338] In this test, compound (I) showed an efficacy of at least 70% at an active ingredient concentration of 500 ppm.

[0339] A-6. In vivo prevention of bean anthracnose (Colletotrichum lindemuthianum) (bean leaf spot) Detergent Test

[0340] Solvent: 5% by volume dimethyl sulfoxide

[0341] 10% by volume acetone

[0342] Emulsifier: 1 μL per mg of active ingredient 80

[0343] The active ingredient was mixed in dimethyl sulfoxide / acetone / Dissolve in 80% of the mixture and homogenize, then dilute in water to the desired concentration.

[0344] Young bean plants were treated by spraying with the active ingredient prepared as described above. Control plants were treated with acetone / DMSO / 80% aqueous solution for treatment.

[0345] After 24 hours, the plants were infected by spraying the leaves with an aqueous suspension of spores of Colletotrichum phaeocaulis. The infected bean plants were incubated at 20°C and 100% relative humidity for 24 hours and then at 20°C and 90% relative humidity for 6 days.

[0346] The tests are evaluated 7 days after inoculation. 0% means an efficacy which corresponds to that of the control plants, while an efficacy of 100% means that no disease is observed.

[0347] In this test, compound (I) showed an efficacy of at least 70% at an active ingredient concentration of 500 ppm.

[0348] A-7. In vitro cell test of Alternaria alternata

[0349] Solvent: DMSO

[0350] Medium: 14.6 g anhydrous D-glucose (VWR), 7.1 g Mycological Peptone (Oxoid), 1.4 g granulated yeast extract (Merck), QSP 1 liter

[0351] Inoculum: Spore suspension

[0352] The fungicide was dissolved in DMSO and the solution was used to prepare the desired concentration range. The final DMSO concentration used in the assay was ≤ 1%.

[0353] A spore suspension of A. alternata was prepared and diluted to the desired spore density.

[0354] In the liquid culture assay, the ability of fungicides to inhibit spore germination and mycelial growth was evaluated. Compounds were added to the spore-containing medium at the desired concentration. After 5 days of culture, mycelial growth was measured spectroscopically to determine the fungal toxicity of the compounds. Inhibition of fungal growth was determined by comparing the absorbance values ​​in the wells containing the fungicide with the absorbance in the control wells without the fungicide.

[0355] In this test, compound (I) showed an efficacy of at least 70% at an active ingredient concentration of 20 ppm.

[0356] A-8. In vitro cell test of Fusarium culmorum

[0357] Solvent: DMSO

[0358] Medium: 14.6 g anhydrous D-glucose (VWR), 7.1 g mycopeptone (Oxoid), 1.4 g granulated yeast extract (Merck), QSP 1 liter

[0359] Inoculum: spore suspension

[0360] The fungicide was dissolved in DMSO and the solution was used to prepare the desired concentration range. The final DMSO concentration used in the assay was ≤ 1%.

[0361] A spore suspension of Fusarium spores was prepared and diluted to the desired spore density.

[0362] In a liquid culture assay, the ability of fungicides to inhibit spore germination and mycelial growth was evaluated. Compounds were added to spore-containing medium at the desired concentration. After 4 days of incubation, mycelial growth was measured spectroscopically to determine the fungal toxicity of the compounds. Inhibition of fungal growth was determined by comparing the absorbance values ​​in the wells containing the fungicide with the absorbance in the control wells without the fungicide.

[0363] In this test, compound (I) showed an efficacy of at least 70% at an active ingredient concentration of 20 ppm.

[0364] A-9. In vitro cell test of Pyricularia oryzae

[0365] Solvent: DMSO

[0366] Medium: 14.6 g anhydrous D-glucose (VWR), 7.1 g mycopeptone (Oxoid), 1.4 g granulated yeast extract (Merck), QSP 1 liter

[0367] Inoculum: Spore suspension

[0368] The fungicide was dissolved in DMSO and the solution was used to prepare the desired concentration range. The final DMSO concentration used in the assay was ≤ 1%.

[0369] A spore suspension of P. oryzae was prepared and diluted to the desired spore density.

[0370] In the liquid culture assay, the ability of fungicides to inhibit spore germination and mycelial growth was evaluated. The compound was added to the spore-containing medium at the desired concentration. After 5 days of cultivation, mycelial growth was measured by spectrometry to determine the fungal toxicity of the compound. The inhibitory effect on fungal growth was determined by comparing the absorbance values ​​in the wells containing the fungicide with the absorbance in the control wells without the fungicide.

[0371] In this test, compound (I) showed an efficacy of at least 70% at an active ingredient concentration of 20 ppm.

[0372] A-10. In vitro cell test of Ustilagoavenae

[0373] Solvent: DMSO

[0374] Medium: 14.6 g anhydrous D-glucose (VWR), 7.1 g mycopeptone (Oxoid), 1.4 g granulated yeast extract (Merck), QSP 1 liter

[0375] Inoculum: Spore suspension

[0376] The fungicide was dissolved in DMSO and the solution was used to prepare the desired concentration range. The final DMSO concentration used in the assay was ≤ 1%.

[0377] Inoculum was prepared from pre-cultured U. avenae in liquid medium and diluted to the desired optical density (OD).

[0378] The ability of fungicides to inhibit mycelial growth was evaluated by a liquid culture test. The compound was added to a culture medium containing a spore suspension at the desired concentration. After 4 days of cultivation, mycelial growth was measured by spectroscopy to determine the fungicidal effect of the compound. The inhibitory effect on fungal growth was determined by comparing the absorbance values ​​in the wells containing the fungicide with the absorbance in the control wells without the fungicide.

[0379] In this test, compound (I) showed an efficacy of at least 70% at an active ingredient concentration of 20 ppm.

[0380] A-11. In vitro cell test of Colletotrichum lindemuthanium

[0381] Solvent: DMSO

[0382] Medium: 14.6 g anhydrous D-glucose (VWR), 7.1 g mycopeptone (Oxoid), 1.4 g granulated yeast extract (Merck), QSP 1 liter

[0383] Inoculum: Spore suspension

[0384] The fungicide was dissolved in DMSO and the solution was used to prepare the desired concentration range. The final DMSO concentration used in the assay was ≤ 1%.

[0385] A spore suspension of C. lindemuthianum was prepared and diluted to the desired spore density.

[0386] In the liquid culture assay, the ability of fungicides to inhibit spore germination and mycelial growth was evaluated. The compound was added to the spore-containing medium at the desired concentration. After 6 days of cultivation, mycelial growth was measured by spectrometry to determine the fungal toxicity of the compound. The inhibitory effect on fungal growth was determined by comparing the absorbance values ​​in the wells containing the fungicide with the absorbance in the control wells without the fungicide.

[0387] In this test, compound (I) showed an efficacy of at least 70% at an active ingredient concentration of 20 ppm.

[0388] A-12. In vitro cell test of Pyrenophorateres

[0389] Solvent: DMSO

[0390] Medium: 14.6 g anhydrous D-glucose (VWR), 7.1 g mycopeptone (Oxoid), 1.4 g granulated yeast extract (Merck), QSP 1 liter

[0391] Inoculum: Spore suspension

[0392] The fungicide was dissolved in DMSO and the solution was used to prepare the desired concentration range. The final DMSO concentration used in the assay was ≤ 1%.

[0393] A spore suspension of P. teres was prepared and diluted to the desired spore density.

[0394] In the liquid culture assay, the ability of fungicides to inhibit spore germination and mycelial growth was evaluated. The compound was added to the spore-containing medium at the desired concentration. After 6 days of cultivation, mycelial growth was measured by spectrometry to determine the fungal toxicity of the compound. The inhibitory effect on fungal growth was determined by comparing the absorbance values ​​in the wells containing the fungicide with the absorbance in the control wells without the fungicide.

[0395] In this test, compound (I) showed an efficacy of at least 70% at an active ingredient concentration of 20 ppm.

[0396] A-13. In vitro cell test on Fusarium virguliforme

[0397] Solvent: DMSO

[0398] Medium: 14.6 g anhydrous D-glucose (VWR), 7.1 g mycopeptone (Oxoid), 1.4 g granulated yeast extract (Merck), QSP 1 liter

[0399] Inoculum: Spore suspension

[0400] The fungicide was dissolved in DMSO and the solution was used to prepare the desired concentration range. The final DMSO concentration used in the assay was ≤ 1%.

[0401] A spore suspension of F. virguliforme was prepared and diluted to the desired spore density.

[0402] In the liquid culture assay, the ability of fungicides to inhibit spore germination and mycelial growth was evaluated. The compound was added to the spore-containing medium at the desired concentration. After 6 days of cultivation, mycelial growth was measured by spectrometry to determine the fungal toxicity of the compound. The inhibitory effect on fungal growth was determined by comparing the absorbance values ​​in the wells containing the fungicide with the absorbance in the control wells without the fungicide.

[0403] In this test, compound (I) showed an efficacy of at least 70% at an active ingredient concentration of 20 ppm.

[0404] A-14. In vitro cell test on Botrytis cinerea

[0405] Solvent: DMSO

[0406] Culture medium: 1g KH2PO4 (VWR), 1g K2HPO4 (VWR), 0.5g urea (VWR), 3g KNO3 (Prolabo), 10g sucrose (VWR), 0.5g MgSO4﹒7H2O (Sigma), 0.07g CaCl2﹒2H2O (Prolabo), 0.2mg MnSO4﹒H2O (Sigma), 0.6mg CuSO4﹒5H2O (Sigma), 7.9mg ZnSO4﹒7H2O (Sigma), 0.1mg H3BO3 (Merck), 0.14mg NaMoO4﹒2H2O (Sigma), 2mg thiamine (Sigma), 0.1mg biotin (VWR), 4mg FeSO4﹒7H2O (Sigma), QSP 1 liter

[0407] Inoculum: Spore suspension

[0408] The fungicide was dissolved in DMSO and the solution was used to prepare the desired concentration range. The final DMSO concentration used in the assay was ≤ 1%.

[0409] A spore suspension of Botrytis cinerea was prepared and diluted to the desired spore density.

[0410] In the liquid culture assay, the ability of fungicides to inhibit spore germination and mycelial growth was evaluated. The compound was added to the spore-containing medium at the desired concentration. After 6 days of cultivation, mycelial growth was measured by spectrometry to determine the fungal toxicity of the compound. The inhibitory effect on fungal growth was determined by comparing the absorbance values ​​in the wells containing the fungicide with the absorbance in the control wells without the fungicide.

[0411] In this test, compound (I) showed an efficacy of at least 70% at an active ingredient concentration of 20 ppm.

[0412] A-15. In vitro cell test on Septoria tritici

[0413] Solvent: DMSO

[0414] Culture medium: 1g KH2PO4 (VWR), 1g K2HPO4 (VWR), 0.5g urea (VWR), 3g KNO3 (Prolabo), 10g sucrose (VWR), 0.5g MgSO4﹒7H2O (Sigma), 0.07g CaCl2﹒2H2O (Prolabo), 0.2mg MnSO4﹒H2O (Sigma), 0.6mg CuSO4﹒5H2O (Sigma), 7.9mg ZnSO4﹒7H2O (Sigma), 0.1mg H3BO3 (Merck), 0.14mg NaMoO4﹒2H2O (Sigma), 2mg thiamine (Sigma), 0.1mg biotin (VWR), 4mg FeSO4﹒7H2O (Sigma), QSP 1 liter

[0415] Inoculum: Spore suspension

[0416] The fungicide was dissolved in DMSO and the solution was used to prepare the desired concentration range. The final DMSO concentration used in the assay was ≤ 1%.

[0417] A spore suspension of S. tritici was prepared and diluted to the desired spore density.

[0418] In the liquid culture assay, the ability of fungicides to inhibit spore germination and mycelial growth was evaluated. The compounds were added to the spore-containing medium at the desired concentration. After 7 days of cultivation, mycelial growth was measured by spectrometry to determine the fungal toxicity of the compounds. The inhibitory effect on fungal growth was determined by comparing the absorbance values ​​in the wells containing the fungicide with the absorbance in the control wells without the fungicide.

[0419] In this test, compound (I) showed an efficacy of at least 70% at an active ingredient concentration of 20 ppm.

[0420] A-16. In vivo preventive test against Fusarium graminearum (wheat)

[0421] Solvent: 24.5 parts by weight of acetone

[0422] 24.5 parts by weight of dimethyl sulfoxide

[0423] Emulsifier: 1 part by weight of polyoxyethylene sorbitan monooleate

[0424] To prepare a suitable active compound preparation, 1 part by weight of the active compound or active compound combination is mixed with the specified amounts of solvent and emulsifier and the concentrate is then diluted with water to the desired concentration.

[0425] To test for preventive activity, young plants are sprayed with the preparation of active compound or active compound combination at the stated application rate.

[0426] The next day, the plants were lightly damaged by sandblasting and then sprayed with a conidia suspension of Fusarium graminearum.

[0427] The plants were placed in a greenhouse under a transparent incubator at a temperature of about 25° C. and a relative air humidity of about 100%.

[0428] The test is evaluated 5 days after inoculation. 0% means an efficacy which corresponds to that of the control plants, while an efficacy of 100% means that no disease is observed.

[0429] In this test, compound (I) showed an efficacy of at least 70% at an active ingredient concentration of 500 ppm.

Claims

1. Use of (5S)-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-(2-chloro-4-methylbenzyl)-5,6-dihydro-4H-1,2,4-oxadiazine of formula (I) for controlling unwanted microorganisms causing plant diseases 2. The method according to claim 1, wherein the unwanted microorganisms are selected from the group consisting of phytopathogenic fungi and phytopathogenic viruses.

3. The use according to claim 1 or 2, wherein the disease is selected from the group consisting of diseases caused by powdery mildew pathogens, diseases caused by rust pathogens, leaf spot and leaf wilt diseases, root and stem diseases, spadix and panicle diseases (including corn cobs), diseases caused by smut fungi, fruit rot, seed-borne and soil-borne rot and wilt diseases, cancer diseases, galls and broom diseases, wilt diseases, deformities of leaves, flowers and fruits, degenerative diseases of woody plants, soybean diseases, such as fungal diseases of leaves, stems, pods and seeds, and fungal diseases of roots and stems.

4. Use according to any one of claims 1 to 3, wherein the disease is selected from the group consisting of diseases caused by powdery mildew pathogens, leaf spot and leaf wilt diseases, root and stem diseases, spadix and panicle diseases (including cobs), fruit rot, seed-borne and soil-borne rot and wilt diseases, cancer diseases, gall and broom diseases and wilt diseases.

5. The use according to any one of claims 1 to 4, wherein the plant is selected from cotton, flax, grapevines, fruits, vegetables, such as Rosaceae sp. (e.g. pome fruits such as apples and pears, and stone fruits such as apricots, cherries, almonds and peaches, and small stoneless fruits such as strawberries), Ribesioidae sp., Juglandaceae sp., Betulaceae sp., Anacardiaceae sp., Fagaceae sp., Moraceae sp., Oleaceae sp., Actinidaceae sp., Lauraceae sp., Musaceae sp. (e.g. banana trees and banana plantations), Rubiaceae sp. sp. (e.g. coffee), Theaceae sp., Sterculiceae sp., Rutaceae sp. (e.g. lemon, orange and grapefruit), Solanaceae sp. (e.g. potato and tomato), Liliaceae sp., Asteraceae sp. (e.g. lettuce), Umbelliferae sp., Cruciferae sp., Chenopodiaceae sp., Cucurbitaceae sp. (e.g. cucumber), Alliaceae sp. (e.g. leek, onion), Papilionaceae sp. (e.g. pea); major crop plants, such as Gramineae sp. sp.) (e.g. corn, turf grasses, cereals (e.g. wheat, rye, rice, barley, oats, millet and triticale)), Asteraceae sp.) (e.g. sunflower), Brassicaceae sp.) (e.g. white cabbage, red cabbage, Brussels sprouts, cauliflower, Brussels sprouts, pakchoi, kohlrabi, radish and rapeseed, mustard, horseradish and watercress), Fabacae sp.) (e.g. beans, peanuts), Papilionaceae sp.) (e.g. soybeans), Chenopodiaceae sp. (e.g. sugar beet, fodder beet, Swiss chard, beetroot); useful plants and ornamental plants for gardens and forests; and genetically modified variants of each of these plants.

6. The method according to claim 1 , wherein the undesirable microorganisms are selected from the group consisting of Blumeria species, such as Blumeria graminis; Leveillula species, such as Leveillula Taurica; Podosphaera species, such as Podosphaera leucotricha or Podosphaera xanthii; Sphaerotheca species, such as Sphaerothecafuliginea; Erysiphe species, such as Erysiphe necator, Erysiphe betae; species of the genus Gymnosporangium, such as Gymnosporangium sabinae; species of the genus Hemileia, such as Hemileia vastatrix; species of the genus Phakopsora, such as Phakopsora pachyrhizi or Phakopsora meibomiae; species of the genus Puccinia, such as Puccinia recondita, Puccinia graminis or Puccinia striiformis; species of the genus Uromyces, such as Uromyces appendiculatus; species of the genus Alternaria, for example Alternaria solani or Alternaria maltana; mali or Alternaria alternata; Cercospora species, such as Cercospora beticola; Cladiosporum species, such as Cladiosporium cucumerinum; Cochliobolus species, such as Cochliobolus graminearum.sativus) (conidial form: Drechslera, synonym: Helminthosporium) or Cochliobolus miyabeanus; Colletotrichum species, for example Colletotrichum lindemuthanium or Colletotrichum capsica or Colletotrichum cutatum; Corynespora species, for example Corynespora cassiicola; Cycloconium species, for example Cycloconium oleaginum; Diaporthe species, for example Diaporthe citrus citri; Elsinoe species, such as Elsinoe fawcettii; Gloeosporium species, such as Gloeosporium laeticolor; Glomerella species, such as Glomerella cingulata; Guignardia species, such as Guignardia bidwelli; Leptosphaeria species, such as Leptosphaeria maculans; Magnaporthe species, such as Magnaporthe grisea; Marsonina species, such as Marsonina mali; Microdochium species, such as Microdochium nivale; Monilinia species, such as Monilinia laxa; Mycosphaerella species, such as Mycosphaerella graminicola, Mycosphaerella arachidicola or Mycosphaerella fijiensis; Phaeosphaeria species, such as Phaeosphaeria graminicola.nodorum; Phyllachora species, for example Phyllachora maydis; Pyrenophora species, for example Pyrenophora teres or Pyrenophora tritici repentis; Ramularia species, for example Ramularia collo-cygni or Ramulariaareola; Rhynchosporium species, for example Rhynchosporium secalis; Septoria species, for example Septoria septoria, for example apii or Septorialycopersici; Setosphaeria species, such as Setosphaeriaturcica; Sclerotinia species, such as Sclerotinia sclerotiorum; Stagonospora species, such as Stagonospora nodorum; Stemphylium species, such as Stemphylium vesicarium; Typhula species, such as Typhula incarnata; Venturia species, such as Venturia sclerotiorum. inaequalis; Corticium species, such as Corticium graminearum; Fusarium species, such as Fusarium oxysporum; Gaeumannomyces species, such as Gaeumannomyces graminis; Marsonina species, such as Marsonina mali; Rhizoctonia species, such as Rhizoctonia solani; Sarocladium species, such as Sarocladium oryzae; Sclerotium species, such as Sclerotium oryzae; Tapesia species, such as Tapesiaacuformis; Thielaviopsis species, such as Thielaviopsis basicola; Alternaria species, such as Alternaria spp.; Aspergillus species, such as Aspergillus flavus; Cladosporium species, such as Cladosporium cladosporioides; Claviceps species, such as Claviceps purpurea; Fusarium species, such as Fusarium culmorum; Gibberella species, such as Gibberella zeae; Monographella species, such as Monographella cladosporioides; nivalis; species of the genus Stagonospora, for example Stagonospora nodorum; species of the genus Sphacelotheca, for example Sphacelotheca reiliana; species of the genus Tilletia, for example Tilletia caries or Tilletia conversationa; species of the genus Urocystis, for example Urocystis occulta; species of the genus Ustilago, for example Ustilago nuda; species of the genus Aspergillus, for example Aspergillus flavus. flavus; Botrytis species, such as Botrytis cinerea; Monilinia species, such as Monilinia laxa; Penicillium species, such as Penicillium expansum or Penicillium purpurogenum; Phomopsis species, such as Phomopsis viticola; Rhizopus species, such as Rhizopus stolonifer; Sclerotinia species, such as Sclerotinia sclerotinia;sclerotiorum; Verticilium species, such as Verticilium alboatrum; Alternaria species, such as Alternaria brassicicola; Aphanomyces species, such as Aphanomyces euteiches; Ascochyta species, such as Ascochytalentis; Aspergillus species, such as Aspergillus flavus; Cladosporium species, such as Cladosporium herbarum; Cochliobolus species, such as Cochliobolus graminicola. sativus) (conidial form: Drechslera, Bipolaris synonym: Helminthosporium); Colletotrichum species, for example Colletotrichum coccodes; Fusarium species, for example Fusarium culmorum; Gibberella species, for example Gibberella zeae; Macrophomina species, for example Macrophomina phaseolina; Microdochium species, for example Microdochium nivale; Monographella species, for example Monographella nivalis; Penicillium species, such as Penicillium expansum; Phoma species, such as Phoma lingam; Phomopsis species, such as Phomopsis sojae; Pyrenophora species, such as Pyrenophora graminea; Pyricularia species, such as Pyricularia oryzae; Rhizoctonia species, such as Rhizoctonia solani.solani; Rhizopus species, such as Rhizopus oryzae; Sclerotium species, such as Sclerotium rolfsii; Septoria species, such as Septoria nodorum; Typhula species, such as Typhula incarnata; Verticillium species, such as Verticillium dahliae; Nectria species, such as Nectria galligena; Verticillium species, such as Verticillium longisporum; Fusarium species, such as Fusarium fusarium; oxysporum; Exobasidium species, for example Exobasidium vexans; Taphrina species, for example Taphrina deformans; Esca species, for example Phaemoniella chlamydospora, Phaeoacremonium aleophilum or Fomitiporia mediterranea; Ganoderma species, for example Ganoderma boninense; Rhizoctonia species, for example Rhizoctonia solani; Helminthosporium species, for example Helminthosporium solani; Alternaria spec.atranstenuissima), Colletotrichum gloeosporoides dematium var.truncatum, Septoria glycines, Cercospora kikuchii, Choanephora infundibulifera trispora (synonym), Cordana musae, Dactuliophoraglycines, Peronosporamanshurica), Drechsleraglycini, Cercospora sojina, Leptosphaerulina trifolii, Leveillula Taurica, Phyllosticta sojaecola, Phomopsis sojae, Microsphaera diffusa, Pyrenochaeta glycines, Rhizoctonia solani, Phakopsora pachyrhizi, Phakopsora meibomiae, Sphaceloma glycines, Stemphylium botryosum, Fusarium virguliforme, Corynespora cassiicola), Calonectria crotalariae, Macrophomina phaseolina, Fusarium oxysporum, Fusarium orthoceras, Fusarium semitectum, Fusarium equiseti, Mycoleptodiscus terrestris, Neocosmopsporavasinfecta, Diaporthe phaseolorum, Diaporthephaseolorum var.caulivora, Phialophora gregata, Rhizoctonia solani, Sclerotinia sclerotiorum, Sclerotinia rolfsii, Thielaviopsis basicola, tobacco mosaic virus virus (TMV), tobacco rattle virus, tobacco stunt virus (TStuV), tobacco leaf curl virus (TStuV),virus (VLCV), tobacco nervilia mosaic virus (TVBMV), tobacco necrotic dwarf virus (TNDV), tobacco streak virus (TSV), potato virus X (PVX), potato viruses Y, S, M and A, potato acuba mosaic virus (PAMV), potato mop-top virus (PMTV), potato leaf roll virus (PLRV), alfalfa mosaic virus (AMV), cucumber mosaic virus (CMV), cucumber green mottle mosaic virus (CGMMV), cucumber yellows virus (CuYV), watermelon mosaic virus (WMV), tomato spotted wilt virus (Tomato spotted wilt virus) The viruses included rice dwarf virus (TSWV), tomato ringspot virus (TomRSV), sugarcane mosaic virus (SCMV), rice drawf virus, rice stripe virus, rice black-streaked drawf virus, strawberry mottle virus (SMoV), strawberry vein banding virus (SVBV), strawberry mild yellow edge virus (SMYEV), strawberry crinkle virus (SCrV), broad bean wilt virus (BBWV), and melon necrotic spot virus (MNSV).

7. The method according to claim 1 , wherein the unwanted microorganisms are selected from the group consisting of: species of the genus Sphaerotheca, such as Sphaerotheca fuliginea; species of the genus Alternaria, such as Alternaria solani, Alternaria mali or Alternaria alternata; species of the genus Cercospora, such as Cercospora beticola; species of the genus Colletotrichum, such as Colletotrichum lindemuthanium, Colletotrichum capsica or Colletotrichum oxysporum. acutatum; species of the genus Diaporthe, for example Diaporthe citri; species of the genus Phaeosphaeria, for example Phaeosphaeria nodorum; species of the genus Pyrenophora, for example Pyrenophora teres or Pyrenophora tritici repentis; species of the genus Septoria, for example Septoria apii or Septoria lycopersici; species of the genus Fusarium, for example Fusarium oxysporum; species of the genus Alternaria, for example Alternaria spp.); Fusarium species, such as Fusarium culmorum; Botrytis species, such as Botrytis cinerea; Alternaria species, such as Alternaria brassicicola; Colletotrichum species, such as Colletotrichum coccodes; Fusarium species, such as Fusarium culmorum; Pyrenophora species, such as Pyrenophora graminea; Pyricularia species, such as Pyricularia oryzae; Fusarium species, such as Fusarium oxysporum. .

8. A composition for controlling phytopathogenic fungi and / or pathogenic viruses, comprising a compound of formula (I) and at least one carrier and / or surfactant.

9. The composition according to claim 8, further comprising one or more other active substances selected from herbicides, insecticides, miticides, fungicides, safeners and / or plant growth regulators.

10. A method for controlling unwanted microbial fungi, which comprises applying a compound of formula (I) and / or a composition according to claim 8 or 9 to plants and / or parts thereof.

11. The method according to claim 6, wherein the plant and / or its part is selected from cotton, flax, grapevine, fruits, vegetables, such as Rosaceae sp. (e.g. pome fruits, such as apples and pears, and stone fruits, such as apricots, cherries, almonds and peaches, and small fruit, such as strawberries), Ribesioidae sp., Juglandaceae sp., Betulaceae sp., Anacardiaceae sp., Fagaceae sp., Moraceae sp., Oleaceae sp., Actinidaceae sp., Lauraceae sp., Musaceae sp. (e.g. banana trees and banana plantations), Rubiaceae sp. (e.g. coffee), Theaceae sp. sp.), Sterculiceae sp., Rutaceae sp. (e.g. lemon, orange and grapefruit), Solanaceae sp. (e.g. potato and tomato), Liliaceae sp., Asteraceae sp. (e.g. lettuce), Umbelliferae sp., Cruciferae sp., Chenopodiaceae sp., Cucurbitaceae sp. (e.g. cucumber), Alliaceae sp. (e.g. leek, onion), Papilionaceae sp. (e.g. pea); major crop plants, such as Gramineae sp. sp.) (e.g. corn, turf grasses, cereals (e.g. wheat, rye, rice, barley, oats, millet and triticale)), Asteraceae sp. (e.g. sunflower), Brassicaceae sp. (e.g. white cabbage, red cabbage, Brussels sprouts, cauliflower, Brussels sprouts, pakchoi, kohlrabi, radish and rapeseed, mustard, horseradish and watercress), Fabacae sp. (e.g. beans, peanuts), Papilionaceae sp. (e.g. soybeans), Chenopodiaceae sp. (e.g. sugar beet, fodder beet, Swiss chard, beetroot); useful plants and ornamental plants for gardens and forests; and genetically modified variants of each of these plants.

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