A device and method for purifying zinc powder from zinc-containing slag
By designing a zinc powder purification device for zinc smelting, the problem of zinc powder adhering to the surface of the cathode metal plate is solved by using technical means such as rotation, lifting, downpressing and high-pressure flushing, and efficient zinc powder desorption and power saving.
Patent Information
- Application Number
- CN202411738676.0
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- Filing Date
- 2024-11-29
- Publication Date
- 2025-04-11
- Estimated Expiration
- 2044-11-29
AI Technical Summary
The spongy zinc powder produced during zinc smelting or hot-dip galvanizing is easily adhered to the surface of the cathode metal plate. When rotating material is used, the zinc powder will not be de-cleaned, increasing power consumption and reducing the efficiency of desorption of the zinc powder.
A device for purifying zinc powder from zinc-containing scum is designed, including a box, a discharge pipe, a rotary frame, a desorption bucket, a cathode sleeve and a desorption mechanism. By rotating, lifting and down-pressing the cathode sleeve, combined with the use of high-pressure flushing and scraping components of the nozzle, efficient desorption of zinc powder is achieved.
The problem of zinc powder not being de-cleaned is effectively avoided, the power consumption and desorption efficiency of zinc powder are reduced, and the overall efficiency and power use efficiency of zinc powder purification device are improved.
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Figure CN119221042B_ABST
Abstract
Description
Technical Field
[0001] The invention belongs to the technical field of zinc slag purification, and in particular relates to a device and a method for purifying zinc powder from zinc-containing slag. Background Art
[0002] Zinc slag is a solid by-product produced during zinc smelting or hot-dip galvanizing processes. It is mainly composed of waste slag, slag copper, slag, etc. in zinc ore. The composition of zinc slag may vary depending on the production process and raw materials. It may contain various metal elements such as zinc, iron, lead, tin, chromium, as well as chemical substances such as zinc chloride.
[0003] Zinc powder is a dark gray powdered metallic zinc that can be used as a pigment. It has strong covering power and has good anti-rust and atmospheric corrosion resistance. It is often used to make anti-rust paints, strong reducing agents, etc.
[0004] Purification devices are key equipment used to separate impurities from a mixture to improve the purity and quality of the mixture. These devices are widely used in many industries such as chemical, pharmaceutical, and food. In the process of extracting zinc powder from zinc slag, electrolysis is often used to purify zinc to produce high-purity zinc powder.
[0005] The authorization publication number "CN116445985B" records that "a process for preparing regenerated and energy-saving zinc powder with a high recovery rate of galvanizing tank slag is provided, which belongs to the technical field of regenerated zinc powder preparation equipment, and includes: adding raw materials, electrolysis, collecting chlorine, collecting zinc powder, removing waste and replacing metal rods, two transmission gears drive multiple driven gears to rotate by meshing with multiple driven gears, and the multiple driven gears drive the multiple prisms to rotate by sliding and engaging with multiple prisms, and the multiple prisms drive the multiple support blocks to rotate, and the multiple support blocks drive the multiple cathode metal plates to rotate in the multiple condensation barrels, and the multiple cathode metal plates rotate rapidly to throw the spongy zinc powder attached to the surface to the inner surface of the multiple condensation barrels for accumulation, and the spongy zinc powder on the surface of the multiple cathode metal plates is quickly desorbed, so as to improve the electrolytic production efficiency of the regenerated zinc powder."
[0006] In the above-mentioned patent, when multiple cathode metal plates are lifted into multiple condensate barrels, the rotating motor is started, and the output end of the rotating motor drives the driving gear to rotate, and the driving gear drives the two transmission gears to rotate by meshing with the two transmission gears, and the two transmission gears drive the multiple driven gears to rotate by meshing with the multiple driven gears, and the multiple driven gears drive the multiple prisms to rotate by sliding and engaging with the multiple prisms, and the multiple prisms drive the multiple support blocks to rotate, and the multiple support blocks drive the multiple cathode metal plates to rotate in the multiple condensate barrels, and the multiple cathode metal plates rotate by fast The spongy zinc powder attached to the surface is thrown off by the high-speed rotation to the inner surfaces of multiple condensation barrels for accumulation, and the spongy zinc powder on the surfaces of multiple cathode metal plates is quickly desorbed to improve the electrolytic production efficiency of regenerated zinc powder. However, in actual use, the spongy zinc powder will adhere to the surface of the cathode metal plate. The use of the rotating material throwing method will cause the spongy zinc powder attached to the surface of the cathode metal plate to not be completely removed, resulting in increased power consumption when the cathode metal plate that has not been completely desorbed is repeatedly electrolyzed zinc and the zinc powder desorption efficiency is seriously reduced after repeated zinc powder desorption. For this reason, we propose a device and method for purifying zinc powder from zinc-containing slag. Summary of the invention
[0007] The object of the present invention is to provide a device and method for purifying zinc powder from zinc-containing slag, aiming to solve the problem that spongy zinc powder adheres to the surface of a cathode metal plate. The method of rotating the material will cause the spongy zinc powder adhered to the surface of the cathode metal plate to not be completely removed, resulting in increased power consumption when the cathode metal plate that has not been completely desorbed is repeatedly electrolyzed with zinc, and the zinc powder desorption efficiency is seriously reduced after repeated zinc powder desorption.
[0008] To achieve the above object, the present invention provides the following technical solutions:
[0009] A device for purifying zinc powder from zinc-containing slag, comprising a box;
[0010] A discharge pipe, the discharge pipe is fixedly connected to the top center of the box body, the discharge pipe is communicated with the box body, an anode rod is fixedly connected to the bottom of the inner wall of the box body through a mounting frame, and the anode rod corresponds to the discharge pipe;
[0011] A rotating frame, the rotating frame is rotatably connected to the inner wall of the box body through a first bearing, a feed pipe is rotatably connected between the inner walls of the rotating frame through a second bearing, and the feed pipe is connected to the box body;
[0012] A desorption bucket, the desorption bucket is fixedly connected to the bottom of the box;
[0013] A cathode sleeve, wherein a plurality of cathode sleeves are provided, and the plurality of cathode sleeves are arranged between the inner walls of the box body; and
[0014] The desorption mechanism is arranged between the inner walls of the box body, and the desorption mechanism is connected to the multiple cathode sleeves to move the multiple cathode sleeves.
[0015] As a preferred solution of the present invention, the desorption mechanism includes a driving component, a limiting component, a adapter component, a magnetic component, a scraping component and a filtering component. The limiting component is arranged at the top of the box body, and the limiting component is connected to the rotating frame. The driving component is arranged at the top of the limiting component, and the driving component is connected to the rotating frame. The magnetic component is arranged between the inner walls of the box body, and the magnetic component is connected to the rotating frame and multiple cathode sleeves. The adapter component is arranged between the rotating frame and the box body, and the adapter component is connected to the magnetic component. The scraping component is arranged between the inner walls of the desorption bucket, and the scraping component corresponds to a single cathode sleeve.
[0016] As a preferred solution of the present invention, the limiting assembly includes a ratchet, a pawl, a first electric push rod and a ratchet cover, the ratchet cover is sleeved on the circumferential surface of the rotating frame, and the ratchet cover is fixed to the top of the box body, the ratchet is fixedly connected to the circumferential surface of the rotating frame, and the ratchet is located between the inner walls of the ratchet cover, the pawl is rotatably connected between the inner walls of the ratchet cover, the pawl is unidirectionally meshed with the ratchet, the first electric push rod is fixedly connected to the side end of the ratchet cover, the output end of the first electric push rod extends into the ratchet cover, and the output end of the first electric push rod is rotatably connected to the pawl.
[0017] As a preferred solution of the present invention, the driving assembly includes a driven gear, a driving gear, a motor and a gear cover, the gear cover is sleeved on the circumferential surface of the rotating frame, and the gear cover is fixedly connected to the top of the ratchet cover, the driven gear is fixedly connected to the circumferential surface of the rotating frame, and the driven gear is located between the inner walls of the gear cover, the driving gear is arranged between the inner walls of the gear cover, and the driving gear is meshed with the driven gear, the motor is fixedly connected to the top of the gear cover, the output end of the motor extends into the gear cover, and the output end of the motor is meshed with the driving gear.
[0018] As a preferred solution of the present invention, the magnetic attraction component includes a buffer pad, a hollow column, an electromagnetic ring, a reset spring and a third electric push rod, the hollow column is provided with a plurality of, the plurality of hollow columns are inserted in a plurality of cathode sleeves, and the tops of the plurality of hollow columns are connected to the rotating frame, the buffer pad is provided with a plurality of, the plurality of buffer pads are sleeved on the circumferential surfaces of the plurality of hollow columns, and the plurality of buffer pads are fixedly connected to the bottom of the rotating frame, the electromagnetic ring is provided with a plurality of, the plurality of electromagnetic rings slide in the plurality of cathode sleeves, and the plurality of electromagnetic rings are fixedly connected to the The bottom of the box body is provided with multiple electromagnetic rings, and multiple electromagnetic rings are connected to multiple buffer pads through insulated wires. There are multiple return springs, and multiple return springs are arranged between the hollow column and the return spring. The tops of multiple return springs are connected to the inner walls of multiple cathode sleeves, and the bottoms of multiple return springs are connected to multiple electromagnetic rings. Two third electric push rods are provided, and the two third electric push rods are fixedly connected to the top of the box body. The output ends of the two third electric push rods extend into the box body, and the output ends of the two third electric push rods correspond to one cathode sleeve among the multiple cathode sleeves.
[0019] As a preferred solution of the present invention, the adapter assembly includes an adapter groove, a filling ring, a radiation electric coil, a sealing ring, a telescopic groove, a spring, a telescopic rod, a ball rod and an annular groove, the adapter groove is opened at the top of the rotating frame, the radiation electric coil is fixedly connected between the inner walls of the adapter groove, multiple branches of the radiation electric coil are connected to multiple buffer pads, the filling ring fills the gap between the radiation electric coil and the adapter groove, the annular groove is opened at the top of the radiation electric coil, the sealing ring is fixedly connected between the inner walls of the box, the sealing ring is located between the inner walls of the rotating frame, and the sealing ring corresponds to the adapter groove, the telescopic groove is opened at the bottom of the sealing ring, the telescopic groove corresponds to the annular groove, the telescopic rod slides between the inner walls of the telescopic groove, and the upper end of the telescopic rod extends to the top of the box, the spring is fixedly connected to the circumferential surface of the telescopic rod, and the spring is located between the inner walls of the telescopic groove, the ball rod is inserted in the telescopic rod, and the spherical bottom of the ball rod slides in the annular groove.
[0020] As a preferred solution of the present invention, the scraping assembly includes a desorption sleeve, a lifting frame, a second electric push rod, a support frame, a nozzle, a pressure pump, a rotating groove and a guide sleeve. The desorption sleeve is arranged on the circumferential surface of a single cathode sleeve. There are multiple guide sleeves, and multiple guide sleeves are fixedly connected to the inner wall of the desorption bucket. The lifting frame is inserted between the circumferential inner walls of multiple guide sleeves. The top of the lifting frame is connected to the desorption sleeve, the nozzle is fixedly connected to the bottom of the desorption bucket, the top of the nozzle extends into the desorption bucket, and the nozzle corresponds to a single cathode sleeve. The pressure pump is fixedly connected to the bottom of the desorption bucket, the pressure pump and the nozzle are connected through a pipeline, the support frame is fixedly connected to the bottom of the desorption bucket, the second electric push rod is fixedly connected to the bottom of the support frame, and the output end of the second electric push rod is connected to the lifting frame. There are two rotating grooves, two of which are opened at the top of the desorption bucket, and the two rotating grooves correspond to multiple cathode sleeves.
[0021] As a preferred solution of the present invention, a compression pump is fixedly connected to the top of the box body, and the compression pump is connected to the box body through a pipeline.
[0022] As a preferred solution of the present invention, a camera is fixedly connected to the side end of the box, two infrared locators are fixedly connected to the top of the box, the bottoms of the two infrared locators extend into the box, the two infrared locators are located on one side of two third electric push rods, and the operating terminal is fixedly connected to the top of the box.
[0023] A method for purifying zinc powder from zinc-containing slag comprises the following steps:
[0024] S1. Electrolysis:
[0025] The electronic valve on the discharge pipe is closed, and the ground zinc scum and electrolyte are added into the box through the feed pipe, and the liquid level of the electrolyte is not higher than the two rotating grooves. The motor is powered on to start, and the output end of the motor drives the driving gear to rotate. The driving gear drives the driven gear to rotate by meshing with the driven gear, and the driven gear drives the rotating frame to rotate slowly. At the same time, under the push of the first electric push rod, the pawl and the ratchet wheel limit the unidirectional rotation of the rotating frame through unidirectional engagement. The rotation of the rotating frame drives the multiple hollow columns to rotate, and the multiple hollow columns drive the multiple cathode sleeves to rotate unidirectionally in the box. The anode rod is energized into the electrolyte, and the ground zinc scum in the electrolyte adheres to the circumferential surface and bottom of the multiple cathode sleeves, so that the zinc scum in the box is electrolyzed;
[0026] S2. Efficient desorption:
[0027] A plurality of cathode sleeves are located at the bottom of a plurality of hollow columns, and the plurality of cathode sleeves rotate while electrolyzing. When a single cathode sleeve moves to the side end of the desorption bucket, the motor is powered off and stopped, and the rotation of the plurality of cathode sleeves is stopped. In the single cathode sleeve, the electromagnetic ring releases the magnetic attraction of the single cathode sleeve, and the reset spring pushes the single cathode sleeve to reset. The buffer pad buffers the lifted single cathode sleeve, and the single cathode sleeve is lifted once. Then, the motor is powered on to rotate the plurality of cathode sleeves, so that the lifted single cathode sleeve enters the desorption chamber from a rotating trough. In the bucket, when a single cathode sleeve moves to the bottom of the first infrared locator, the first infrared locator senses the obstruction of the rotating frame, and the first infrared locator triggers the power-off shutdown of the motor. At the same time, the first infrared locator triggers the output end of the third electric push rod to extend, and the output end of the first third electric push rod is inserted into a single hollow column to press down the single cathode sleeve, so that the single cathode sleeve is close to the desorption sleeve, and the single cathode sleeve is pressed down once. The electromagnetic ring in the single cathode sleeve magnetically fixes the top of the single cathode sleeve, and then the first third electric push rod The output end of the push rod is extended and retracted, and the nozzle draws the flushing liquid in the pressure pump to perform high-pressure flushing on the bottom of the single cathode sleeve, and the elemental zinc attached to the bottom of the single cathode sleeve is flushed into the desorption bucket, and then the second electric push rod is powered on to start the second electric push rod, and the output end of the second electric push rod is contracted to pull the second electric push rod, and the second electric push rod lifts the desorption sleeve, so that the desorption sleeve scrapes off the elemental zinc attached to the circumferential surface of the single cathode sleeve, and then the electromagnetic ring releases the magnetic fixation of the single cathode sleeve again, and the reset spring pushes the single cathode sleeve to be lifted for the second time, and the motor is powered on to start Push multiple cathode sleeves to rotate. When the second infrared positioner senses that the rotating frame moves to the lower side, it triggers the second and third electric push rods to be started. The second and third electric push rods are inserted into a single hollow column to press down a single cathode sleeve. In a single cathode sleeve, the electromagnetic ring and the cathode sleeve are magnetically fixed to achieve secondary downward pressure on the single cathode sleeve, making it convenient for the single cathode sleeve to be moved out of the desorption bucket from the rotating trough. By rotating multiple cathode sleeves, lifting and pressing twice, and high-pressure washing of the bottom of the nozzle and scraping of the desorption sleeve, efficient desorption of elemental zinc on the surface of multiple cathode sleeves is achieved.
[0028] S3, filter out chlorine:
[0029] During the efficient desorption process, the compression pump will extract the air in the box for filtration, and filter the waste gas generated by electrolysis in the box to avoid the overflow of waste gas and achieve the filtration of waste gas;
[0030] S4, discharge:
[0031] The desorbed zinc element falls into the desorption bucket, and during the high-pressure flushing of the nozzle, it is discharged along the desorption bucket and collected centrally, thus realizing the discharge of the zinc element.
[0032] Compared with the prior art, the present invention has the following beneficial effects:
[0033] 1. In the present scheme, during the desorption process of elemental zinc attached to the surface of a single cathode sleeve, when the cathode sleeve is pressed down and close to the desorption sleeve, the electromagnetic ring in the single cathode sleeve magnetically fixes the top of the single cathode sleeve, and then the output end of the first third electric push rod is extended and retracted, and the nozzle draws the flushing liquid in the pressure pump to perform high-pressure flushing on the bottom of the single cathode sleeve, and the elemental zinc attached to the bottom of the single cathode sleeve is flushed into the desorption bucket, and then the second electric push rod is powered on and started, and the output end of the second electric push rod is contracted to pull the second electric push rod, and the second electric push rod is lifted up by the desorption sleeve, so that the desorption sleeve scrapes off the elemental zinc attached to the circumferential surface of the single cathode sleeve, and the elemental zinc falls into the desorption bucket for removal, thereby achieving efficient desorption of elemental zinc attached to the surface of the single cathode sleeve, avoiding incomplete desorption of sponge-like zinc powder, preventing the increase of power consumption when the cathode sleeve that has not been desorbed is repeatedly electrolyzed with zinc, and preventing the serious decrease in zinc powder desorption efficiency caused by repeated zinc powder desorption.
[0034] 2. In this scheme, when a single cathode sleeve fully attached with zinc element rotates into the desorption bucket, the motor is powered off and stopped, and the rotation of multiple cathode sleeves is stopped. In the single cathode sleeve, the electromagnetic ring releases the magnetic attraction of the single cathode sleeve, the reset spring pushes the single cathode sleeve to reset, and the buffer pad buffers the lifted single cathode sleeve, so that the single cathode sleeve is lifted once, and then the motor is powered on to rotate the multiple cathode sleeves, so that the lifted single cathode sleeve enters the desorption bucket from a rotating groove. When the single cathode sleeve moves to the bottom of the first infrared locator, the first infrared locator senses the obstruction of the rotating frame, and the first infrared locator triggers the power off and shutdown of the motor. At the same time, the first infrared locator triggers the output end of the third electric push rod to extend, and the output end of the first third electric push rod is inserted into a single hollow column to press down the single cathode sleeve, so that the single cathode sleeve is close to the desorption sleeve, so that the single cathode sleeve is pressed down once, and the electromagnetic ring in the single cathode sleeve magnetically fixes the top of the single cathode sleeve. When the single cathode sleeve after desorption needs to be When the cathode sleeve moves out of the desorption bucket, the electromagnetic ring releases the magnetic fixation of the single cathode sleeve again, and the reset spring pushes the single cathode sleeve to be lifted for the second time. The motor is powered on to drive the multiple cathode sleeves to rotate. When the second infrared locator senses that the rotating frame moves to the lower side, it triggers the start of the second and third electric push rods. The second and third electric push rods are inserted into a single hollow column to press down the single cathode sleeve. In the single cathode sleeve, the electromagnetic ring and the cathode sleeve are magnetically fixed to achieve secondary downward pressure on the single cathode sleeve, which is convenient for the single cathode sleeve. The single cathode sleeve is moved out of the rotating trough into the desorption bucket, and the single cathode sleeve fully attached with zinc is conveniently rotated into the desorption bucket and the single cathode sleeve after desorption is moved out of the desorption bucket by lifting and lowering the single cathode sleeve, so that the zinc dropped from the single cathode sleeve during desorption in the box body does not fall back into the box body again, thereby avoiding repeated electrolysis and desorption, reducing the power used for electrolysis and desorption, achieving the reduction of power usage of the zinc powder purification device in the zinc-containing slag, and then improving the power saving of the zinc powder purification device in the zinc-containing slag, and avoiding power waste.
[0035] 3. In this scheme, when it is necessary to rotate multiple cathode sleeves, the motor is powered on to start, the output end of the motor drives the driving gear to rotate, the driving gear drives the driven gear to rotate by meshing with the driven gear, the rotating frame drives the multiple hollow columns to rotate, the multiple hollow columns drive the multiple cathode sleeves to rotate in the box, and the multiple cathode sleeves are rotated, so that the elemental zinc attached to the surface of the multiple cathode sleeves is generated at a time interval, and then the multiple cathode sleeves are ensured to be electrolyzed while rotating, and the elemental zinc can be electrolyzed and desorbed one by one, so that the zinc powder purification device in the zinc-containing slag can continuously electrolyze and desorb the elemental zinc, and improve the elemental zinc electrolysis and desorption efficiency of the zinc powder purification device in the zinc-containing slag, and at the same time, the rotation of the multiple cathode sleeves and the electrolyte generate a certain water flow disturbance, and the thickness of the elemental zinc attached to the multiple cathode sleeves is quantitatively controlled, which is convenient for the later desorption of elemental zinc, reduces the thrust requirement of the lifting frame, and reduces the maintenance difficulty of the zinc powder purification device in the zinc-containing slag.
[0036] 4. In this scheme, when the multiple cathode sleeves are rotated, the rotating frame synchronously drives the ratchet to rotate, and the first electric push rod pushes the pawl to engage with the ratchet in one direction. The ratchet limits the unidirectional rotation of the rotating frame by the unidirectional engagement with the pawl, thereby ensuring the unidirectional rotation of the multiple cathode sleeves, and does not cause repeated electrolysis and desorption of a single cathode sleeve, thereby avoiding unnecessary loss of production time and improving the purification efficiency of the zinc powder purification device in zinc-containing slag. BRIEF DESCRIPTION OF THE DRAWINGS
[0037] The accompanying drawings are used to provide a further understanding of the present invention and constitute a part of the specification. Together with the embodiments of the present invention, they are used to explain the present invention and do not constitute a limitation of the present invention. In the accompanying drawings:
[0038] Figure 1 A first-view stereoscopic diagram of a device for purifying zinc powder from zinc-containing slag according to the present invention;
[0039] Figure 2 A second perspective view of a device for purifying zinc powder from zinc-containing slag according to the present invention;
[0040] Figure 3 A first half cross-sectional view of a device for purifying zinc powder from zinc-containing slag according to the present invention;
[0041] Figure 4 A second half cross-sectional view of a device for purifying zinc powder from zinc-containing slag according to the present invention;
[0042] Figure 5 The invention relates to a device for purifying zinc powder from zinc-containing slag. Figure 4 A magnified image of point A;
[0043] Figure 6A third half cross-sectional view of a device for purifying zinc powder from zinc-containing slag according to the present invention;
[0044] Figure 7 A three-dimensional diagram of a scraping assembly of a device for purifying zinc powder from zinc-containing slag according to the present invention;
[0045] Figure 8 An exploded view of a scraping assembly of a device for purifying zinc powder from zinc-containing slag according to the present invention;
[0046] Fig. 9 It is a stereoscopic diagram of a driving assembly, a limiting assembly, a switching assembly and a magnetic suction assembly of a device for purifying zinc powder from zinc-containing slag of the present invention;
[0047] Fig.10 It is a cross-sectional view of a driving component, a limiting component, a switching component and a magnetic attraction component of a device for purifying zinc powder from zinc-containing slag of the present invention;
[0048] Fig.11 The present invention discloses an exploded view of a driving component and a limiting component of a device for purifying zinc powder from zinc-containing slag.
[0049] In the figure: 1, box; 2, desorption bucket; 3, rotating frame; 4, first bearing; 5, adapter groove; 6, filling ring; 7, radiation electric coil; 8, buffer pad; 9, hollow column; 10, cathode sleeve; 11, electromagnetic ring; 12, reset spring; 13, sealing ring; 14, telescopic groove; 15, spring; 16, telescopic rod; 17, ball rod; 18, annular groove; 20, second bearing; 21, driven gear; 22, driving gear; 23, motor; 24, ratchet ; 25. Ratchet; 26. First electric push rod; 27. Gear cover; 28. Ratchet cover; 30. Desorption sleeve; 31. Lifting frame; 32. Second electric push rod; 33. Support frame; 34. Nozzle; 35. Pressure pump; 36. Rotating trough; 37. Guide sleeve; 38. Feed pipe; 39. Operation terminal; 40. Compression pump; 41. Camera; 42. Mounting frame; 43. Discharge pipe; 44. Anode rod; 45. Infrared locator; 46. Third electric push rod. DETAILED DESCRIPTION
[0050] The following will be combined with the drawings in the embodiments of the present invention to clearly and completely describe the technical solutions in the embodiments of the present invention. Obviously, the described embodiments are only part of the embodiments of the present invention, not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the present invention. Example 1
[0051] Reference Figure 1 - Fig.11, a device for purifying zinc powder from zinc-containing slag, comprising:
[0052] Box 1;
[0053] A discharge pipe 43, which is fixedly connected to the top center of the box body 1, and is communicated with the box body 1. An anode rod 44 is fixedly connected to the bottom of the inner wall of the box body 1 through a mounting frame 42, and the anode rod 44 corresponds to the discharge pipe 43;
[0054] The rotating frame 3 is rotatably connected to the inner wall of the box body 1 through the first bearing 4, and a feed pipe 38 is rotatably connected between the inner walls of the rotating frame 3 through the second bearing 20, and the feed pipe 38 is connected to the box body 1;
[0055] A desorption bucket 2, which is fixedly connected to the bottom of the box body 1;
[0056] A cathode sleeve 10, wherein a plurality of cathode sleeves 10 are provided, and the plurality of cathode sleeves 10 are provided between the inner walls of the box body 1; and
[0057] The desorption mechanism is disposed between the inner walls of the box body 1 , and is connected to the plurality of cathode sleeves 10 to move the plurality of cathode sleeves 10 .
[0058] In the present invention, the box body 1 is used to accommodate multiple cathode sleeves 10, electrolyte and desorption mechanism. The bottom of the box body 1 is in a hole shape, which is conducive to the tendency of the settled metal impurities to concentrate in the discharge pipe 43. The discharge pipe 43 is used to discharge the waste electrolyte and other settled metal impurities. The mounting frame 42 is used to support and fix the anode rod 44, and the anode rod 44 is used to energize the electrolyte. The rotating frame 3 is used to support and fix multiple hollow columns 9 and the feed pipe 38, and the feed pipe 38 is used to add electrolyte and zinc scum into the box body 1. The desorption bucket 2 is used to separate the desorption space from the box body 1, and the desorption bucket 2 is used to accommodate the scraping assembly. The multiple cathode sleeves 10 are used to attach elemental zinc. The desorption mechanism is connected to the multiple cathode sleeves 10 to move the multiple cathode sleeves 10.
[0059] The desorption mechanism includes a driving component, a limiting component, a switching component, a magnetic component, a scraping component and a filtering component. The limiting component is arranged at the top of the casing 1, and the limiting component is connected to the rotating frame 3. The driving component is arranged at the top of the limiting component, and the driving component is connected to the rotating frame 3. The magnetic component is arranged between the inner walls of the casing 1, and the magnetic component is connected to the rotating frame 3 and multiple cathode sleeves 10. The switching component is arranged between the rotating frame 3 and the casing 1, and the switching component is connected to the magnetic component. The scraping component is arranged between the inner walls of the desorption bucket 2, and the scraping component corresponds to a single cathode sleeve 10.
[0060] In the present invention, the limiting assembly is used to limit the unidirectional rotation of multiple cathode sleeves 10, the driving assembly is used to provide power for the rotation of multiple cathode sleeves 10, the magnetic attraction assembly is used to lift and lower the multiple cathode sleeves 10, the adapter assembly is used to receive the return current and provide power to multiple electromagnetic rings 11 at the same time, and the scraping assembly scrapes the surface elemental zinc of a single cathode sleeve 10.
[0061] The limiting assembly includes a ratchet 24, a pawl 25, a first electric push rod 26 and a ratchet cover 28. The ratchet cover 28 is sleeved on the circumferential surface of the rotating frame 3, and the ratchet cover 28 is fixed to the top of the box body 1. The ratchet 24 is fixedly connected to the circumferential surface of the rotating frame 3, and the ratchet 24 is located between the inner walls of the ratchet cover 28. The pawl 25 is rotatably connected between the inner walls of the ratchet cover 28, and the pawl 25 is unidirectionally meshed with the ratchet 24. The first electric push rod 26 is fixedly connected to the side end of the ratchet cover 28, and the output end of the first electric push rod 26 extends into the ratchet cover 28, and the output end of the first electric push rod 26 is rotatably connected to the pawl 25.
[0062] In the present invention, the ratchet cover 28 accommodates the ratchet 24, the pawl 25 and the first electric push rod 26. The ratchet 24 is used to rotate synchronously with the rotating frame 3. The pawl 25 limits the unidirectional rotation of the ratchet 24 by unidirectional engagement with the ratchet 24, and then limits the unidirectional rotation of the rotating frame 3, so that multiple cathode sleeves 10 rotate unidirectionally. The first electric push rod 26 is used to push the pawl 25 to unidirectionally engage with the ratchet 24. When the multiple cathode sleeves 10 are rotated, the rotating frame 3 synchronously drives the ratchet 24 to rotate. The first electric push rod 26 pushes the pawl 25 to unidirectionally engage with the ratchet 24. The ratchet 24 limits the unidirectional rotation of the rotating frame 3 by unidirectional engagement with the pawl 25, and then ensures the unidirectional rotation of multiple cathode sleeves 10, does not cause repeated electrolysis and desorption of a single cathode sleeve 10, avoids unnecessary production time loss, and improves the purification efficiency of the zinc powder purification device in zinc-containing slag.
[0063] The driving assembly includes a driven gear 21, a driving gear 22, a motor 23 and a gear cover 27. The gear cover 27 is sleeved on the circumferential surface of the rotating frame 3, and the gear cover 27 is fixedly connected to the top of the ratchet cover 28. The driven gear 21 is fixedly connected to the circumferential surface of the rotating frame 3, and the driven gear 21 is located between the inner walls of the gear cover 27. The driving gear 22 is arranged between the inner walls of the gear cover 27, and the driving gear 22 is meshed with the driven gear 21. The motor 23 is fixedly connected to the top of the gear cover 27, and the output end of the motor 23 extends into the gear cover 27, and the output end of the motor 23 is meshed with the driving gear 22.
[0064] In the present invention, the gear cover 27 is used to accommodate the driven gear 21 and the driving gear 22. The driven gear 21 is used to drive the rotating frame 3 to rotate. The driving gear 22 drives the driven gear 21 to rotate by meshing with the driven gear 21. The motor 23 is used to drive the driving gear 22 to rotate. When it is necessary to rotate multiple cathode sleeves 10, the motor 23 is powered on and started. The output end of the motor 23 drives the driving gear 22 to rotate. The driving gear 22 drives the driven gear 21 to rotate by meshing with the driven gear 21. The rotating frame 3 drives the multiple hollow columns 9 to rotate. The multiple hollow columns 9 drive the multiple cathode sleeves 10 to rotate in the box body 1. The cathode sleeve 10 rotates, so that the elemental zinc attached to the surfaces of the multiple cathode sleeves 10 is generated at a time interval, thereby ensuring that the multiple cathode sleeves 10 are electrolyzed while rotating, and can electrolyze and desorb the elemental zinc one by one, so that the zinc powder purification device in the zinc-containing slag can perform continuous elemental zinc electrolysis and desorption, and improve the elemental zinc electrolysis and desorption efficiency of the zinc powder purification device in the zinc-containing slag. At the same time, the rotation of the multiple cathode sleeves 10 and the electrolyte produce a certain water flow disturbance, and the thickness of the elemental zinc attached to the multiple cathode sleeves 10 is quantitatively controlled, which facilitates the difficulty of desorption of elemental zinc in the later stage, reduces the thrust requirement of the lifting frame 31, and reduces the maintenance difficulty of the zinc powder purification device in the zinc-containing slag.
[0065] The magnetic attraction assembly includes a buffer pad 8, a hollow column 9, an electromagnetic ring 11, a reset spring 12 and a third electric push rod 46, a plurality of hollow columns 9 are provided, a plurality of hollow columns 9 are inserted in a plurality of cathode sleeves 10, and the tops of the plurality of hollow columns 9 are connected to the rotating frame 3, a plurality of buffer pads 8 are provided, a plurality of buffer pads 8 are sleeved on the circumferential surfaces of the plurality of hollow columns 9, and the plurality of buffer pads 8 are fixedly connected to the bottom of the rotating frame 3, a plurality of electromagnetic rings 11 are provided, a plurality of electromagnetic rings 11 slide in a plurality of cathode sleeves 10, a plurality of electromagnetic rings 11 are fixedly connected to the bottom of a plurality of hollow columns 9, and a plurality of electromagnetic rings 11 It is connected to multiple buffer pads 8 through insulated wires, multiple return springs 12 are provided, and the multiple return springs 12 are arranged between the hollow column 9 and the return spring 12. The tops of the multiple return springs 12 are connected to the inner walls of the multiple cathode sleeves 10, and the bottoms of the multiple return springs 12 are connected to the multiple electromagnetic rings 11. Two third electric push rods 46 are provided, and the two third electric push rods 46 are fixedly connected to the top of the box body 1. The output ends of the two third electric push rods 46 both extend into the box body 1, and the output ends of the two third electric push rods 46 correspond to one cathode sleeve 10 among the multiple cathode sleeves 10.
[0066] In the present invention, multiple hollow columns 9 are used to limit and guide the lifting and lowering of multiple cathode sleeves 10 through sliding insertion with multiple cathode sleeves 10, multiple buffer pads 8 are used to offset the impact force generated when the multiple cathode sleeves 10 are lifted, and the insulated wires built into the multiple buffer pads 8 are connected to multiple electromagnetic rings 11, and the electromagnetic rings 11 are fixed by magnetic attraction with the top of the cathode sleeve 10 to offset the thrust generated by multiple reset springs 12, and the multiple reset springs 12 are used to push the lifting and reset of multiple cathode sleeves 10, and two third electric push rods 46 are used to press down a single cathode sleeve 10 in a lifted state. When a single cathode sleeve 10 full of zinc element rotates into the desorption bucket 2, the motor 23 is powered off and stopped, and the rotation of the multiple cathode sleeves 10 stops. In the cathode sleeve 10, the electromagnetic ring 11 releases the magnetic attraction of the single cathode sleeve 10, the reset spring 12 pushes the single cathode sleeve 10 to reset, and the buffer pad 8 buffers the lifted single cathode sleeve 10, so as to lift the single cathode sleeve 10 once, and then the motor 23 is powered on to rotate the multiple cathode sleeves 10, so that the lifted single cathode sleeve 10 enters the desorption bucket 2 from a rotating groove 36. When the single cathode sleeve 10 moves to the bottom of the first infrared locator 45, the first infrared locator 45 senses the obstruction of the rotating frame 3, and the first infrared locator 45 triggers the motor 23 to power off and stop, and at the same time, the first infrared locator 45 triggers the output end of the third electric push rod 46 to extend, and the output of the first third electric push rod 46 The end is inserted into a single hollow column 9 to press down a single cathode sleeve 10, so that the single cathode sleeve 10 is close to the desorption sleeve 30, and the single cathode sleeve 10 is pressed down once. The electromagnetic ring 11 in the single cathode sleeve 10 magnetically fixes the top of the single cathode sleeve 10. When the desorbed single cathode sleeve 10 needs to be moved out of the desorption bucket 2, the electromagnetic ring 11 releases the magnetic fixation of the single cathode sleeve 10 again, and the reset spring 12 pushes the single cathode sleeve 10 to be lifted for the second time. The motor 23 is powered on to push the multiple cathode sleeves 10 to rotate. When the second infrared locator 45 senses that the rotating frame 3 moves to the lower side, it triggers the start of the second third electric push rod 46, and the second third electric push rod 46 is inserted into the single hollow column 9 to press down the single cathode Sleeve 10, in a single cathode sleeve 10, the electromagnetic ring 11 and the cathode sleeve 10 are magnetically fixed to realize secondary downward pressure on the single cathode sleeve 10, so as to facilitate the single cathode sleeve 10 to be moved out of the desorption bucket 2 from the rotating groove 36. By lifting the single cathode sleeve 10, it is convenient to rotate the single cathode sleeve 10 full of zinc into the desorption bucket 2 and to move the desorbed single cathode sleeve 10 out of the desorption bucket 2, so that the single cathode sleeve 10 does not fall back into the box 1 when the single cathode sleeve 10 is desorbed in the box 1, thereby avoiding repeated electrolysis and desorption, reducing the power used for electrolysis and desorption, and achieving the reduction of the power usage of the zinc powder purification device in the zinc-containing slag, thereby improving the power saving of the zinc powder purification device in the zinc-containing slag, and avoiding power waste.
[0067] The adapter assembly includes an adapter groove 5, a filling ring 6, a radiation electric coil 7, a sealing ring 13, a telescopic groove 14, a spring 15, a telescopic rod 16, a ball rod 17 and an annular groove 18. The adapter groove 5 is opened at the top of the rotating frame 3, the radiation electric coil 7 is fixedly connected between the inner walls of the adapter groove 5, multiple branches of the radiation electric coil 7 are connected to multiple buffer pads 8, the filling ring 6 fills the gap between the radiation electric coil 7 and the adapter groove 5, the annular groove 18 is opened at the top of the radiation electric coil 7, the sealing ring 13 is fixedly connected between the inner walls of the box body 1, and the sealing ring 1 3 is located between the inner walls of the rotating frame 3, and the sealing ring 13 corresponds to the adapter groove 5, the telescopic groove 14 is opened at the bottom of the sealing ring 13, the telescopic groove 14 corresponds to the annular groove 18, the telescopic rod 16 slides between the inner walls of the telescopic groove 14, and the upper end of the telescopic rod 16 extends to the top of the box body 1, the spring 15 is fixedly connected to the circumferential surface of the telescopic rod 16, and the spring 15 is located between the inner walls of the telescopic groove 14, the ball rod 17 is inserted in the telescopic rod 16, and the spherical bottom of the ball rod 17 slides in the annular groove 18.
[0068] In the present invention, the adapter groove 5 is used to accommodate the radiation coil 7 and the filling ring 6. The radiation coil 7 is connected to the insulated wire in the buffer pad 8 to achieve power transmission. The filling ring 6 is used to fix the radiation coil 7. The annular groove 18 is used to accommodate the bottom ball center of the ball rod 17 to slide, thereby facilitating the power transmission between the radiation coil 7 and the ball rod 17. The sealing ring 13 is used to seal the adapter groove 5. The telescopic groove 14 is opened to accommodate the spring 15 and the telescopic rod 16. The telescopic rod 16 is used to wrap and push the ball rod 17 to move. The spring 15 is used to push the ball rod 17 to fit into the annular groove 18. The ball rod 17 transmits power to the radiation coil 7 by fitting into the annular groove 18. During the rotation of the rotating frame 3, the spring 15 The telescopic rod 16 is pushed downward, and the telescopic rod 16 pushes the ball rod 17 to slide in the annular groove 18, so that the ball rod 17, the radiation electric coil 7 and the multiple buffer pads 8 are connected to each other, ensuring that a cyclic electrolysis process is formed between the anode rod 44, the electrolyte, the multiple cathode sleeves 10, the multiple buffer pads 8, the radiation electric coil 7 and the ball rod 17, and at the same time, magnetic power is provided to the multiple electromagnetic rings 11, so as to facilitate electrolysis while rotating. The ground zinc scum and the electrolyte are added into the box body 1 through the feed pipe 38. After the multiple cathode sleeves 10 rotate, the anode rod 44 is energized into the electrolyte, and the ground zinc scum in the electrolyte adheres to the circumferential surface and the bottom of the multiple cathode sleeves 10, so as to realize the electrolysis of the zinc scum in the box body 1.
[0069] The scraping assembly includes a desorption sleeve 30, a lifting frame 31, a second electric push rod 32, a support frame 33, a nozzle 34, a pressure pump 35, a rotating groove 36 and a guide sleeve 37. The desorption sleeve 30 is sleeved on the circumferential surface of a single cathode sleeve 10, and a plurality of guide sleeves 37 are provided. The plurality of guide sleeves 37 are fixedly connected to the inner wall of the desorption bucket 2. The lifting frame 31 is inserted between the circumferential inner walls of the plurality of guide sleeves 37. The top of the lifting frame 31 is connected to the desorption sleeve 30. The nozzle 34 is fixedly connected to the bottom of the desorption bucket 2. The top of the nozzle 34 The part extends into the desorption bucket 2, and the nozzle 34 corresponds to a single cathode sleeve 10, the pressure pump 35 is fixedly connected to the bottom of the desorption bucket 2, the pressure pump 35 and the nozzle 34 are connected through a pipeline, the support frame 33 is fixedly connected to the bottom of the desorption bucket 2, the second electric push rod 32 is fixedly connected to the bottom of the support frame 33, the output end of the second electric push rod 32 is connected to the lifting frame 31, and two rotating grooves 36 are provided, the two rotating grooves 36 are opened at the top of the desorption bucket 2, and the two rotating grooves 36 correspond to multiple cathode sleeves 10.
[0070] In the present invention, the desorption sleeve 30 is used to scrape off the elemental zinc attached to the circumferential surface of the cathode sleeve 10, a plurality of guide sleeves 37 are used to accommodate the insertion of the lifting frame 31, the lifting frame 31 is used to push the lifting desorption sleeve 30, the nozzle 34 is used to high-pressure wash the elemental zinc attached to the bottom of the single cathode sleeve 10, the booster pump 35 provides high-pressure cleaning liquid to the nozzle 34 through a pipeline, the support frame 33 is used to support and fix the second electric push rod 32, and the two rotating grooves 36 are used to accommodate the inlet and outlet desorption bucket 2 of the single cathode sleeve 10. In the process of desorption of elemental zinc attached to the surface of the single cathode sleeve 10, when the cathode sleeve 10 is pressed down close to the desorption sleeve 30, the electromagnetic ring 11 in the single cathode sleeve 10 magnetically fixes the top of the single cathode sleeve 10, and then the first third electric push rod 46 The output end is retracted, and the nozzle 34 draws the flushing liquid in the pressure pump 35 to perform high-pressure flushing on the bottom of the single cathode sleeve 10, and the elemental zinc attached to the bottom of the single cathode sleeve 10 is flushed into the desorption bucket 2, and then the second electric push rod 32 is powered on to start the second electric push rod 32, and the output end of the second electric push rod 32 is contracted to pull the second electric push rod 32, and the second electric push rod 32 lifts the desorption sleeve 30, so that the desorption sleeve 30 scrapes off the elemental zinc attached to the circumferential surface of the single cathode sleeve 10, so that the elemental zinc falls into the desorption bucket 2 for removal, thereby achieving efficient desorption of the elemental zinc attached to the surface of the single cathode sleeve 10, avoiding the sponge-like zinc powder from being not completely desorbed, preventing the increase in power consumption when the cathode sleeve 10 that has not been desorbed is repeatedly electrolyzed with zinc, and preventing the zinc powder desorption efficiency from being seriously reduced due to repeated zinc powder desorption.
[0071] A compression pump 40 is fixedly connected to the top of the box body 1 , and the compression pump 40 is connected to the box body 1 through a pipeline.
[0072] In the present invention, the compression pump 40 is used to filter various waste gases generated during zinc electrolysis to prevent direct discharge of harmful waste gases to pollute the air.
[0073] A camera 41 is fixedly connected to the side end of the box 1, and two infrared locators 45 are fixedly connected to the top of the box 1. The bottoms of the two infrared locators 45 extend into the box 1. The two infrared locators 45 are located on one side of the two third electric push rods 46, and the operating terminal 39 is fixedly connected to the top of the box 1.
[0074] In the present invention, the camera 41 is used to collect video information of a single cathode sleeve 10 to avoid desorption of elemental zinc, and provide data support for the operation program of the operation terminal 39. The two infrared locators 45 are used to trigger the operation terminal 39 to retract the output ends of the two infrared locators 45. The operation terminal 39 is electrically connected to the motor 23, multiple electromagnetic rings 11, the booster pump 35, the second electric push rod 32 and the electronic valve on the discharge pipe 43 to maintain the operation of the zinc powder purification device in the zinc-containing slag.
[0075] A method for purifying zinc powder from zinc-containing slag comprises the following steps:
[0076] S1. Electrolysis:
[0077] The electronic valve on the discharge pipe 43 is closed, and the ground zinc scum and electrolyte are added into the box body 1 through the feed pipe 38, and the liquid level of the electrolyte is not higher than the two rotating grooves 36. The motor 23 is powered on to start, and the output end of the motor 23 drives the driving gear 22 to rotate. The driving gear 22 drives the driven gear 21 to rotate by meshing with the driven gear 21, and the driven gear 21 drives the rotating frame 3 to rotate slowly. At the same time, under the push of the first electric push rod 26, the pawl 25 and the ratchet wheel 24 limit the unidirectional rotation of the rotating frame 3 through unidirectional engagement. The rotation of the rotating frame 3 drives the multiple hollow columns 9 to rotate, and the multiple hollow columns 9 drive the multiple cathode sleeves 10 to rotate unidirectionally in the box body 1. The anode rod 44 is energized into the electrolyte, and the ground zinc scum in the electrolyte adheres to the circumferential surface and bottom of the multiple cathode sleeves 10, so as to realize the electrolysis of the zinc scum in the box body 1;
[0078] S2. Efficient desorption:
[0079] A plurality of cathode sleeves 10 are located at the bottom of a plurality of hollow columns 9, and the plurality of cathode sleeves 10 rotate while electrolyzing. When a single cathode sleeve 10 moves to the side end of the desorption bucket 2, the motor 23 is powered off and stopped, and the rotation of the plurality of cathode sleeves 10 is stopped. In the single cathode sleeve 10, the electromagnetic ring 11 releases the magnetic attraction of the single cathode sleeve 10, and the reset spring 12 pushes the single cathode sleeve 10 to reset. The buffer pad 8 buffers the lifted single cathode sleeve 10, and the single cathode sleeve 10 is lifted once. Then, the motor 23 is powered on to start the rotation of the plurality of cathode sleeves 10, so that the lifted single cathode sleeve 10 enters the desorption bucket 2 from a rotating groove 36. In the attachment bucket 2, when the single cathode sleeve 10 moves to the bottom of the first infrared locator 45, the first infrared locator 45 senses the obstruction of the rotating frame 3, and the first infrared locator 45 triggers the power-off shutdown of the motor 23. At the same time, the first infrared locator 45 triggers the output end of the third electric push rod 46 to extend, and the output end of the first third electric push rod 46 is inserted into the single hollow column 9 to press down the single cathode sleeve 10, so that the single cathode sleeve 10 is close to the desorption sleeve 30, and the single cathode sleeve 10 is pressed down once. The electromagnetic ring 11 in the single cathode sleeve 10 magnetically fixes the top of the single cathode sleeve 10, and then the first third electric push rod 46 The output end of the push rod 46 is extended and retracted, and the nozzle 34 draws the flushing liquid in the pressure pump 35 to perform high-pressure flushing on the bottom of the single cathode sleeve 10, and the elemental zinc attached to the bottom of the single cathode sleeve 10 is flushed into the desorption bucket 2, and then the second electric push rod 32 is powered on to start the second electric push rod 32, and the output end of the second electric push rod 32 is contracted to pull the second electric push rod 32, and the second electric push rod 32 lifts the desorption sleeve 30, so that the desorption sleeve 30 scrapes off the elemental zinc attached to the circumferential surface of the single cathode sleeve 10, and then the electromagnetic ring 11 releases the magnetic fixation of the single cathode sleeve 10 again, and the reset spring 12 pushes the single cathode sleeve 10 to lift it for the second time, and the motor 2 is powered on to start. 3 pushes the multiple cathode sleeves 10 to rotate, and when the second infrared locator 45 senses that the rotating frame 3 moves to the lower side, the second third electric push rod 46 is triggered to start, and the second third electric push rod 46 is inserted into the single hollow column 9 to press down the single cathode sleeve 10, and in the single cathode sleeve 10, the electromagnetic ring 11 and the cathode sleeve 10 are magnetically fixed to achieve secondary downward pressure on the single cathode sleeve 10, so as to facilitate the single cathode sleeve 10 to move out of the desorption bucket 2 from the rotating groove 36, and through the rotation of the multiple cathode sleeves 10, the double lifting and double pressing, the high-pressure washing bottom of the nozzle 34 and the scraping of the desorption sleeve 30, the efficient desorption of the single element zinc on the surface of the multiple cathode sleeves 10 is achieved;
[0080] S3, filter out chlorine:
[0081] During the high-efficiency desorption process, the compression pump 40 extracts air from the box 1 for filtration, and filters the waste gas generated by electrolysis in the box 1 to avoid the overflow of the waste gas and achieve the filtration of the waste gas;
[0082] S4, discharge:
[0083] The desorbed zinc element falls into the desorption bucket 2, and during the high-pressure flushing process of the nozzle 34, it is discharged along the desorption bucket 2 for centralized collection, thereby realizing the discharge of the zinc element.
[0084] Finally, it should be noted that the above description is only a preferred embodiment of the present invention and is not intended to limit the present invention. Although the present invention has been described in detail with reference to the aforementioned embodiments, those skilled in the art can still modify the technical solutions described in the aforementioned embodiments or replace some of the technical features therein by equivalents. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the present invention shall be included in the protection scope of the present invention.
Claims
1. A device for purifying zinc powder from zinc-containing slag, characterized in that: include; Box (1); A discharge pipe (43), the discharge pipe (43) being fixedly connected to the top center of the box body (1), the discharge pipe (43) being in communication with the box body (1), an anode rod (44) being fixedly connected to the bottom of the inner wall of the box body (1) via a mounting frame (42), and the anode rod (44) corresponding to the discharge pipe (43); A rotating frame (3), the rotating frame (3) being rotatably connected to the inner wall of the box body (1) via a first bearing (4), a feed pipe (38) being rotatably connected between the inner walls of the rotating frame (3) via a second bearing (20), and the feed pipe (38) being connected to the box body (1); A desorption bucket (2), wherein the desorption bucket (2) is fixedly connected to the bottom of the box body (1); A cathode sleeve (10), wherein a plurality of cathode sleeves (10) are provided, and the plurality of cathode sleeves (10) are arranged between inner walls of the box body (1); and A desorption mechanism, the desorption mechanism being arranged between the inner walls of the box body (1), the desorption mechanism being connected to the plurality of cathode sleeves (10) and being used to move the plurality of cathode sleeves (10); The desorption mechanism comprises a driving component, a limiting component, a switching component, a magnetic component, a scraping component and a filtering component. The limiting component is arranged at the top of the housing (1), and the limiting component is connected to the rotating frame (3). The driving component is arranged at the top of the limiting component, and the driving component is connected to the rotating frame (3). The magnetic component is arranged between the inner walls of the housing (1), and the magnetic component is connected to the rotating frame (3) and a plurality of cathode sleeves (10). The switching component is arranged between the rotating frame (3) and the housing (1), and the switching component is connected to the magnetic component. The scraping component is arranged between the inner walls of the desorption bucket (2), and the scraping component corresponds to a single cathode sleeve (10).
2. The device for purifying zinc powder from zinc-containing slag according to claim 1, characterized in that: The limiting assembly comprises a ratchet (24), a pawl (25), a first electric push rod (26) and a ratchet cover (28); the ratchet cover (28) is sleeved on the circumferential surface of the rotating frame (3), and the ratchet cover (28) is fixed to the top of the box body (1); the ratchet (24) is fixedly connected to the circumferential surface of the rotating frame (3), and the ratchet (24) is located between the inner walls of the ratchet cover (28); the pawl (25) is rotatably connected between the inner walls of the ratchet cover (28), and the pawl (25) is unidirectionally meshed with the ratchet (24); the first electric push rod (26) is fixedly connected to the side end of the ratchet cover (28), and the output end of the first electric push rod (26) extends into the ratchet cover (28), and the output end of the first electric push rod (26) is rotatably connected to the pawl (25).
3. The device for purifying zinc powder from zinc-containing slag according to claim 2, characterized in that: The driving assembly comprises a driven gear (21), a driving gear (22), a motor (23) and a gear cover (27); the gear cover (27) is sleeved on the circumferential surface of the rotating frame (3), and the gear cover (27) is fixedly connected to the top of a ratchet cover (28); the driven gear (21) is fixedly connected to the circumferential surface of the rotating frame (3), and the driven gear (21) is located between the inner walls of the gear cover (27); the driving gear (22) is arranged between the inner walls of the gear cover (27), and the driving gear (22) meshes with the driven gear (21); the motor (23) is fixedly connected to the top of the gear cover (27), and the output end of the motor (23) extends into the gear cover (27), and the output end of the motor (23) meshes with the driving gear (22).
4. The device for purifying zinc powder from zinc-containing slag according to claim 3, characterized in that: The magnetic attraction component comprises a buffer pad (8), a hollow column (9), an electromagnetic ring (11), a reset spring (12) and a third electric push rod (46); a plurality of the hollow columns (9) are provided, and the plurality of the hollow columns (9) are inserted into a plurality of cathode sleeves (10), and the tops of the plurality of the hollow columns (9) are connected to the rotating frame (3); a plurality of the buffer pads (8) are provided, and the plurality of the buffer pads (8) are sleeved on the circumferential surfaces of the plurality of hollow columns (9), and the plurality of the buffer pads (8) are fixedly connected to the bottom of the rotating frame (3); a plurality of the electromagnetic rings (11) are provided, and the plurality of the electromagnetic rings (11) slide in the plurality of cathode sleeves (10), and the plurality of the electromagnetic rings (11) are fixedly connected to the bottom of the plurality of hollow columns (9), and the plurality of The electromagnetic ring (11) is connected to a plurality of buffer pads (8) via an insulated wire; a plurality of return springs (12) are provided; the plurality of return springs (12) are provided between the hollow column (9) and the return spring (12); the tops of the plurality of return springs (12) are connected to the inner walls of a plurality of cathode sleeves (10); the bottoms of the plurality of return springs (12) are connected to the plurality of electromagnetic rings (11); two third electric push rods (46) are provided; the two third electric push rods (46) are fixedly connected to the top of the box body (1); the output ends of the two third electric push rods (46) both extend into the box body (1); and the output ends of the two third electric push rods (46) correspond to one cathode sleeve (10) among the plurality of cathode sleeves (10).
5. The device for purifying zinc powder from zinc-containing slag according to claim 4, characterized in that: The adapter assembly comprises an adapter groove (5), a filling ring (6), a radiation coil (7), a sealing ring (13), a telescopic groove (14), a spring (15), a telescopic rod (16), a ball rod (17) and an annular groove (18); the adapter groove (5) is opened at the top of the rotating frame (3); the radiation coil (7) is fixedly connected between the inner walls of the adapter groove (5); a plurality of branches of the radiation coil (7) are connected to a plurality of buffer pads (8); the filling ring (6) fills the gap between the radiation coil (7) and the adapter groove (5); the annular groove (18) is opened at the top of the radiation coil (7); the sealing ring (13) is fixedly connected between the inner walls of the box (1); the sealing ring (13) is located between the inner walls of the rotating frame (3), and the sealing ring (13) corresponds to the adapter groove (5), the telescopic groove (14) is opened at the bottom of the sealing ring (13), the telescopic groove (14) corresponds to the annular groove (18), the telescopic rod (16) slides between the inner walls of the telescopic groove (14), and the upper end of the telescopic rod (16) extends to the top of the box body (1), the spring (15) is fixedly connected to the circumferential surface of the telescopic rod (16), and the spring (15) is located between the inner walls of the telescopic groove (14), the ball rod (17) is inserted into the telescopic rod (16), and the spherical bottom of the ball rod (17) slides in the annular groove (18).
6. The device for purifying zinc powder from zinc-containing slag according to claim 5, characterized in that: The scraping assembly comprises a desorption sleeve (30), a lifting frame (31), a second electric push rod (32), a support frame (33), a nozzle (34), a pressure pump (35), a rotating groove (36) and a guide sleeve (37); the desorption sleeve (30) is sleeved on the circumferential surface of a single cathode sleeve (10); a plurality of guide sleeves (37) are provided; the plurality of guide sleeves (37) are fixedly connected to the inner wall of the desorption bucket (2); the lifting frame (31) is inserted between the circumferential inner walls of the plurality of guide sleeves (37); the top of the lifting frame (31) is connected to the desorption sleeve (30); the nozzle (34) is fixedly connected to the bottom of the desorption bucket (2); The top of the desorption bucket (2) extends into the desorption bucket (2), and the nozzle (34) corresponds to a single cathode sleeve (10). The pressure pump (35) is fixedly connected to the bottom of the desorption bucket (2), and the pressure pump (35) and the nozzle (34) are connected through a pipeline. The support frame (33) is fixedly connected to the bottom of the desorption bucket (2). The second electric push rod (32) is fixedly connected to the bottom of the support frame (33), and the output end of the second electric push rod (32) is connected to the lifting frame (31). Two rotating grooves (36) are provided, and the two rotating grooves (36) are opened at the top of the desorption bucket (2), and the two rotating grooves (36) correspond to multiple cathode sleeves (10).
7. The device for purifying zinc powder from zinc-containing slag according to claim 6, characterized in that: A compression pump (40) is fixedly connected to the top of the box body (1), and the compression pump (40) is connected to the box body (1) via a pipeline.
8. The device for purifying zinc powder from zinc-containing slag according to claim 7, characterized in that: A camera (41) is fixedly connected to the side end of the box (1), two infrared locators (45) are fixedly connected to the top of the box (1), the bottoms of the two infrared locators (45) extend into the box (1), the two infrared locators (45) are located on one side of two third electric push rods (46), and the operation terminal (39) is fixedly connected to the top of the box (1).
9. A method for purifying zinc powder from zinc-containing slag, characterized in that: The device for purifying zinc powder from zinc-containing slag as claimed in claim 8 comprises the following steps: S1. Electrolysis: The electronic valve on the discharge pipe (43) is closed, and the ground zinc slag and electrolyte are added into the box body (1) through the feed pipe (38), and the liquid level of the electrolyte is not higher than the two rotating grooves (36). The motor (23) is powered on, and the output end of the motor (23) drives the driving gear (22) to rotate. The driving gear (22) drives the driven gear (21) to rotate by meshing with the driven gear (21). The driven gear (21) drives the rotating frame (3) to rotate slowly. At the same time, the first electric push Under the push of the rod (26), the pawl (25) and the ratchet wheel (24) restrict the rotating frame (3) from rotating in one direction through one-way engagement, the rotation of the rotating frame (3) drives the plurality of hollow columns (9) to rotate, the plurality of hollow columns (9) drive the plurality of cathode sleeves (10) to rotate in one direction in the box (1), the anode rod (44) supplies electricity to the electrolyte, the ground zinc scum in the electrolyte adheres to the circumferential surface and the bottom of the plurality of cathode sleeves (10), and the zinc scum in the box (1) is electrolyzed; S2. Efficient desorption: A plurality of cathode sleeves (10) are located at the bottom of a plurality of hollow columns (9), and the plurality of cathode sleeves (10) rotate while performing electrolysis. When a single cathode sleeve (10) moves to the side end of a desorption bucket (2), the motor (23) is powered off and stopped, and the rotation of the plurality of cathode sleeves (10) is stopped. In the single cathode sleeve (10), the electromagnetic ring (11) releases the magnetic attraction of the single cathode sleeve (10), and the reset spring (12) pushes the single cathode sleeve (10) to reset. The buffer pad (8) buffers the lifted single cathode sleeve (10), thereby lifting the single cathode sleeve (10) once. Then, the motor (23) is powered on to start the rotation of the plurality of cathode sleeves (10), so that the lifted single cathode sleeve (10) rotates from one rotation. The groove (36) enters the desorption bucket (2). When the single cathode sleeve (10) moves to the bottom of the first infrared locator (45), the first infrared locator (45) senses the obstruction of the rotating frame (3). The first infrared locator (45) triggers the motor (23) to shut down. At the same time, the first infrared locator (45) triggers the output end of the third electric push rod (46) to extend. The output end of the first third electric push rod (46) is inserted into the single hollow column (9) to press down the single cathode sleeve (10), so that the single cathode sleeve (10) is close to the desorption sleeve (30). The single cathode sleeve (10) is pressed down once. The electromagnetic ring (11) in the single cathode sleeve (10) magnetically presses the top of the single cathode sleeve (10). The first third electric push rod (46) is fixed by suction, and then the output end of the first third electric push rod (46) is extended and retracted, and the nozzle (34) extracts the flushing liquid in the pressure pump (35) to perform high-pressure flushing on the bottom of the single cathode sleeve (10), and the single zinc attached to the bottom of the single cathode sleeve (10) is flushed into the desorption bucket (2), and then the second electric push rod (32) is powered on and started, and the output end of the second electric push rod (32) is contracted to pull the second electric push rod (32), and the second electric push rod (32) lifts the desorption sleeve (30), so that the desorption sleeve (30) scrapes off the single zinc attached to the circumferential surface of the single cathode sleeve (10), and then the electromagnetic ring (11) releases the magnetic fixation of the single cathode sleeve (10) again, and the reset spring (12) pushes the single cathode sleeve (10) to move upward. 0) is lifted for the second time, and the motor (23) is powered on to drive the multiple cathode sleeves (10) to rotate. When the second infrared positioner (45) senses that the rotating frame (3) moves to the lower side, the second third electric push rod (46) is triggered to start. The second third electric push rod (46) is inserted into the single hollow column (9) to press down the single cathode sleeve (10). In the single cathode sleeve (10), the electromagnetic ring (11) and the cathode sleeve (10) are magnetically fixed to achieve the secondary downward pressure of the single cathode sleeve (10), so that the single cathode sleeve (10) can be easily moved from the rotating groove (36) to the desorption bucket (2). By rotating the multiple cathode sleeves (10), lifting and pressing twice, and high-pressure washing of the bottom of the nozzle (34) and scraping of the desorption sleeve (30),Achieving efficient desorption of elemental zinc from the surfaces of multiple cathode sleeves (10); S3, filter out exhaust gas: During the high-efficiency desorption process, the compression pump (40) extracts air from the box (1) for filtration, and filters the waste gas generated by electrolysis in the box (1), thereby preventing the waste gas from overflowing and achieving waste gas removal; S4, discharge: The desorbed zinc element falls into the desorption bucket (2), and during the high-pressure flushing process of the nozzle (34), it is discharged along the desorption bucket (2) and collected centrally, thereby achieving the discharge of the zinc element.
Citation Information
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