Ammonia reactor control system and hydrogen generation method
By designing a control system in the ammonia reactor and using sensors and control units to adjust the supply of hydrogen and ammonia, the problem of temperature drop inside the ammonia reactor is solved, and the ammonia decomposition rate and device performance are improved.
Patent Information
- Application Number
- CN202410910886.7
- Authority / Receiving Office
- CN · China
- Patent Type
- Applications(China)
- Current Assignee / Owner
- Priority Date
- 2023-07-21
- Filing Date
- 2024-07-09
- Publication Date
- 2025-01-21
AI Technical Summary
In an ammonia reactor, when the hydrogen yield is increased in a short time, the normal temperature supply of ammonia causes the internal temperature of the reactor to drop, which in turn affects the ammonia decomposition rate and device performance.
An ammonia reactor control system is designed, including a sensor unit, a control unit, a hydrogen supply unit and an ammonia supply unit. By measuring the internal temperature of the decomposer, the control unit adjusts the supply of hydrogen and ammonia based on the temperature information and the ammonia supply information to maintain the appropriate reactor temperature.
It effectively prevents the reaction speed in the reactor from decreasing and reduces the amount of residual ammonia, thus improving the process reliability and overall performance of the device.
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Figure CN119336098A_ABST
Abstract
Description
Technical Field
[0001] The present disclosure relates to an ammonia reactor control system and a hydrogen generation method. Background Art
[0002] For example, in an operation of changing the amount of ammonia decomposition according to the state of a running vehicle using a fuel cell, the ammonia supply amount is controlled differently according to the temperature of a decomposer (eg, a reactor), thereby stabilizing the ammonia decomposition rate in the reactor caused by changes in the reactor temperature.
[0003] During such load following operation, if the amount of ammonia supplied to the reactor is increased to increase hydrogen production in a short period of time, the temperature inside the reactor will drop because the temperature of the supplied ammonia is generally room temperature.
[0004] If the temperature inside the decomposer drops temporarily, the ammonia decomposition rate decreases due to deactivation of the catalyst inside the decomposer or a decrease in the overall performance of the device. As a result, the amount of residual ammonia in the device may increase. Since the residual ammonia is supplied to the adsorption tower or fuel cell, it may cause a decrease in the overall performance of the device or an unexpected failure. Summary of the invention
[0005] 1. Technical issues to be resolved
[0006] One object of the present disclosure is to provide an ammonia reactor control system with improved process reliability.
[0007] An object of the present disclosure is to provide a hydrogen generation method with improved process reliability.
[0008] The problems to be solved by the present disclosure are not limited to the above problems, and those skilled in the art can clearly understand other problems not mentioned from the following description.
[0009] (II) Technical solution
[0010] According to an embodiment of the present disclosure, an ammonia reactor control system may include: a sensor unit for measuring the internal temperature of a decomposer; a control unit for receiving temperature information collected by the sensor unit; a hydrogen supply unit for determining the amount of hydrogen supplied to the inside of the decomposer according to a first signal of the control unit; and an ammonia supply unit for determining the amount of ammonia supplied to the inside of the decomposer according to a second signal of the control unit. The control unit may be configured to: receive ammonia supply amount information from the ammonia supply unit, and determine the first signal based on the temperature information and the ammonia supply amount information.
[0011] In some embodiments, the ammonia reactor control system may further include: a storage unit storing preset heat supply information for supplying to the fuel cell through the decomposer, and the control unit may be configured to: confirm the preset heat supply information from the storage unit, and calculate the internal heat absorption information of the decomposer based on the temperature information.
[0012] In some embodiments, the control unit may be configured to temporarily reduce the output of the fuel cell by comparing the preset heat supply amount information with the decomposer internal heat absorption amount information.
[0013] In some embodiments, the ammonia reactor control system may further include: a temperature sensing unit that senses the temperature of ammonia supplied from the ammonia supply unit to the inside of the decomposer; and a preheating unit that preheats the ammonia supplied to the inside of the decomposer according to a third signal of the control unit.
[0014] In some embodiments, the control unit may be configured to receive ammonia temperature information within the ammonia supply unit from the temperature sensing unit, and determine the third signal for operating the preheating unit based on the ammonia temperature information.
[0015] In some embodiments, the control unit may be configured to: receive a hydrogen supply amount from the hydrogen supply unit, and determine the second signal based on the temperature information and the hydrogen supply amount information.
[0016] In some embodiments, the control unit may be configured to: when the decomposer temperature is within a preset first temperature range, determine the ammonia supply as a first capacity according to the second signal; when the decomposer temperature is within a preset second temperature range, determine the ammonia supply as a second capacity according to the second signal, the lower limit of the first temperature range may be greater than the upper limit of the second temperature range, and the first capacity may be less than the second capacity.
[0017] In some embodiments, the sensor unit may measure the internal temperature of a first part and a second part including the decomposer, the ammonia supply unit may be connected to the first part and the second part, and the control unit may be configured to determine the second signal based on temperature information of the first part and the second part.
[0018] In some embodiments, the control unit may be configured to determine the first signal or the second signal based on the temperature information, the ammonia supply amount information, and the hydrogen supply amount information.
[0019] According to the hydrogen generation method of an embodiment of the present disclosure, ammonia can be supplied to the inside of the decomposer. Temperature information collected by a sensor unit measuring the temperature inside the decomposer can be received. Ammonia supply information can be received from an ammonia supply unit that determines the ammonia supply amount supplied to the inside of the decomposer. Hydrogen supply information can be received from a hydrogen supply unit that determines the hydrogen supply amount supplied to the inside of the decomposer. Based on the temperature information, the ammonia supply information and the hydrogen supply information, a first signal or a second signal can be provided to the hydrogen supply unit or the ammonia supply unit.
[0020] (III) Beneficial effects
[0021] According to the above embodiment, the ammonia reactor control system can increase the ammonia supply amount and / or the unreacted hydrogen supply amount according to the temperature of the decomposer to maintain the inside of the decomposer at an appropriate temperature, thereby preventing the reaction rate in the decomposer from decreasing.
[0022] In some embodiments, the ammonia reactor control system can reduce the amount of residual ammonia by maintaining the internal temperature of the decomposer at an appropriate temperature, thereby preventing the system performance from being degraded due to residual ammonia.
[0023] The effects of the present disclosure are not limited to the above-mentioned effects, and other effects not mentioned can be clearly understood by those skilled in the art from the following description. BRIEF DESCRIPTION OF THE DRAWINGS
[0024] Figure 1 is a block diagram of an ammonia reactor control system according to an exemplary embodiment of the present disclosure.
[0025] Figure 2 is a schematic block diagram illustrating a configuration of an ammonia reactor control system according to an exemplary embodiment of the present disclosure.
[0026] Figure 3 is a schematic flowchart for explaining a control method of an ammonia reactor control system according to an exemplary embodiment of the present disclosure.
[0027] Figure 4 is a schematic flow chart for explaining ammonia preheating of an ammonia reactor control system according to an exemplary embodiment of the present disclosure.
[0028] Figure 5 is a schematic flowchart for explaining determination of an ammonia supply amount of an ammonia reactor control system according to an exemplary embodiment of the present disclosure.
[0029] Figure 6 is a schematic flowchart for explaining determination of an ammonia supply amount based on temperatures of various parts of a decomposer of an ammonia reactor control system according to an exemplary embodiment of the present disclosure. DETAILED DESCRIPTION
[0030] In the present disclosure, the same reference numerals refer to the same components. Not all elements of the embodiments are described in the present disclosure, and general contents of the technical field to which the present disclosure belongs or contents repeated between embodiments are omitted. The terms "unit, module, component, block" used in the specification can be implemented by software or hardware, and according to the embodiment, multiple "units, modules, components, blocks" can be implemented by a single component, or one "unit, module, component, block" can include multiple components.
[0031] Throughout the specification, when one part is referred to as being “connected” to another part, this includes not only a case of being directly connected but also a case of being indirectly connected including a case of being connected through a wireless communication network.
[0032] In addition, when a section is referred to as “comprising” a component, unless specifically stated otherwise, it means that other components may be further included, rather than excluding other components.
[0033] Throughout the specification, when a member is located “on” another member, this includes not only a case where one member is in contact with another member but also a case where other members exist between the two members.
[0034] Terms such as “first”, “second”, etc. are used to distinguish one component from another component, and the components are not limited by the above terms.
[0035] Unless the context clearly indicates otherwise, an expression in the singular includes an expression in the plural.
[0036] The reference numerals of the steps are used for convenience of description and do not indicate the order of the steps. Unless the context clearly indicates a specific order, the steps may be performed in an order different from the specified order.
[0037] Hereinafter, the working principle and embodiments of the present disclosure will be described with reference to the accompanying drawings.
[0038] In this specification, "device according to the present disclosure" includes all kinds of devices that can perform computing and provide results to users. For example, a device according to an embodiment of the present disclosure may include a computer, a server device, and a portable terminal, or any form thereof.
[0039] Here, the computer may include, for example, a notebook computer equipped with a web browser, a desktop computer, a laptop computer, a tablet PC, a slate PC, etc.
[0040] The server device is a server that processes information by communicating with an external device, and may include an application server, a computing server, a database server, a file server, a game server, a mail server, a proxy server, a network server, etc.
[0041] The portable terminal is, for example, a wireless communication device that ensures portability and mobility, and may include all types of handheld wireless communication devices such as PCS (Personal Communication System), GSM (Global System for Mobile communications), PDC (Personal Digital Cellular), PHS (Personal Handyphone System), PDA (Personal Digital Assistant), IMT (International Mobile Telecommunication)-2000, CDMA (Code Division Multiple Access)-2000, W-CDMA (W-Code Division Multiple Access), WiBro (Wireless Broadband Internet), terminals, smart phones, and wearable devices such as watches, rings, bracelets, anklets, necklaces, glasses, contact lenses, or head-mounted devices (HMD).
[0042] Figure 1 is a block diagram of an ammonia reactor control system according to an exemplary embodiment of the present disclosure.
[0043] Reference Figure 1 The ammonia reactor control system 10 (hereinafter referred to as the "system") includes a cracker 100, an absorption unit 200, and a fuel cell 300. Each configuration / node can send and receive data with other configurations / nodes. The configurations / nodes can be connected via a network.
[0044] The ammonia reactor control system 10 according to various embodiments of the present disclosure may receive ammonia (NH 3) and decompose it through the decomposer 100. If the internal temperature of the decomposer 100 temporarily decreases, the ammonia decomposition rate may decrease due to deactivation or performance degradation of the catalyst inside the decomposer 100. Therefore, the amount of residual ammonia in the decomposer 100 may increase relatively.
[0045] According to an exemplary embodiment, the decomposer 100 may receive ammonia and generate hydrogen (H2), nitrogen (N2) and ammonia (NH3) as decomposed products. Then, each fluid absorbed by the absorption unit 200 may be supplied to the fuel cell 300 and used for power supply of the battery.
[0046] According to an exemplary embodiment, the fuel cell 300 can resupply nitrogen and unconverted hydrogen, etc. to the decomposer 100 to completely burn the unconverted hydrogen. Therefore, the ammonia reactor control system 10 can reburn the byproducts generated by the imbalance of materials supplied to the decomposer 100 by feeding back the byproducts.
[0047] Figure 2 is a schematic block diagram illustrating a configuration of an ammonia reactor control system according to an exemplary embodiment of the present disclosure.
[0048] Reference Figure 2 , the ammonia reactor control system 10 may include a decomposer 100, a sensor unit 110, a control unit 120, a hydrogen supply unit 130, an ammonia supply unit 140, and a storage unit 150. The internal configuration included in the ammonia reactor control system 10 may include Figure 1 The absorption unit 200, the fuel cell 300, etc. are shown, but are not limited thereto.
[0049] In some embodiments, the functions of the control unit 120 may be performed by a separate processing server or a cloud server instead of the control unit 120 .
[0050] According to an exemplary embodiment, the reactor of the ammonia reactor control system 10 may refer to a device such as a cracker 100 .
[0051] The control unit 120 may receive ammonia supply amount information from the ammonia supply unit 140. The control unit 120 may receive hydrogen supply amount information from the hydrogen supply unit 130. According to an exemplary embodiment, the control unit 120 may receive ammonia supply amount and hydrogen supply amount supplied to the decomposer 100 of the ammonia reactor control system 10 from the ammonia supply unit 140 and the hydrogen supply unit 130, respectively.
[0052] The control unit 120 may receive the internal temperature information of the decomposer 100 from the sensor unit 110. The control unit 120 may receive the internal temperature of the first part and the second part of the decomposer 100. The sensor unit 110 may include a plurality of sensors, which may collect the temperature information of the first part and the second part of the decomposer 100. The first part and the second part may refer to the parts of the decomposer 100 that do not overlap with each other. In some embodiments, the first part and the second part may be a part of the part where the ammonia supply unit 140 and the decomposer 100 are connected.
[0053] According to an exemplary embodiment, the hydrogen supply unit 130 may determine the hydrogen supply amount supplied to the inside of the decomposer 100 according to the first signal of the control unit 120. The hydrogen supply amount supplied to the decomposer 100 may be adjusted according to the first signal of the control unit 120.
[0054] According to an exemplary embodiment, the ammonia supply unit 140 may determine the ammonia supply amount supplied to the inside of the decomposer 100 according to the second signal of the control unit 120. The ammonia supply amount supplied to the decomposer 100 may be adjusted according to the second signal of the control unit 120.
[0055] According to an exemplary embodiment, the storage unit 150 may store data supporting various functions of the ammonia reactor control system 10 and a program for controlling the operation of the control unit 120. The storage unit 150 may store input / output data (e.g., images, videos, etc.), and the storage unit 150 may store a plurality of application programs (or applications) running in the ammonia reactor control system 10, data for the operation of the ammonia reactor control system 10, and instructions. At least one of the application programs may be downloaded from an external server through wireless communication.
[0056] The storage unit 150 may include at least one type of storage medium selected from Network Attached Storage (NAS), flash memory type, hard disk type, SSD type (Solid State Disk type), SDD type (Silicon Disk Drive type), multimedia card micro type, card type memory (e.g., SD or XD memory, etc.), RAM (random access memory), SRAM (static random access memory), ROM (read-only memory), EEPROM (electrically erasable programmable read-only memory), PROM (programmable read-only memory), magnetic memory, magnetic disk, and optical disk. The storage unit 150 is separated from the ammonia reactor control system 10, but may also include a database connected by wire or wirelessly.
[0057] The ammonia reactor control system 10 may further include an output unit (not shown). The output unit may generate output related to vision, hearing, touch, etc., and may include a display unit.
[0058] The display unit may form an interlayer structure with the touch sensor, or may be provided in an integrated structure with the touch sensor to realize a touch screen. The touch screen may be provided as a user input unit, which provides an input interface between the ammonia reactor control system 10 and the user, and may provide an output interface between the ammonia reactor control system 10 and the user.
[0059] The display unit displays (outputs) information processed in the ammonia reactor control system 10. For example, the display unit may display execution screen information of an application program (e.g., an application) running in the ammonia reactor control system 10, or UI (User Interface) and GUI (Graphic User Interface) information according to the execution screen information.
[0060] Can be used with Figure 2The performance of the configurations shown corresponds to adding or deleting at least one configuration. In addition, those skilled in the art will readily appreciate that the relative positions of the configurations may be changed according to the performance or structure of the ammonia reactor control system 10.
[0061] on the other hand, Figure 2 Each configuration shown in the EMBODIMENTS may refer to software and / or hardware configurations such as a Field Programmable Gate Array (FPGA) and an Application Specific Integrated Circuit (ASIC).
[0062] Figure 3 is a schematic flowchart for explaining a control method of an ammonia reactor control system according to an exemplary embodiment of the present disclosure.
[0063] Reference Figure 3 , ammonia reactor control systems (e.g. Figure 1 The ammonia reactor control system 10) can be controlled by a decomposer (e.g., Figure 1 The amount of heat absorbed inside the decomposer 100 is calculated based on the internal temperature information of the decomposer 100 to temporarily reduce the output of the fuel cell.
[0064] In step S310, a control unit (eg, Figure 2 The control unit 120 of the ammonia supply unit (eg, Figure 2 The control unit 120 may receive the ammonia supply amount information through a separate flow meter or supply amount measuring device installed in the ammonia supply unit 140 .
[0065] In step S320, the control unit 120 may confirm the preset heat supply information. Considering the stability of the hydrogen reaction, the ammonia reactor control system 10 may adjust the hydrogen supply mode differently through the first signal to induce an improved warming effect. For example, the same total amount of hydrogen supply may be supplied by changing the mode.
[0066] The control unit 120 can retrieve information from a storage unit (eg, Figure 2 The control unit 120 may confirm the preset heat supply amount information based on the information provided by the sensor unit (eg, Figure 2 The temperature information received by the sensor unit 110 is used to calculate the internal heat absorption information of the decomposer 100.
[0067] In step S340, the control unit 120 can temporarily reduce the output of the fuel cell 300 by comparing the preset heat supply information with the internal heat absorption information of the decomposer 100. For example, the temporary time can be about 3 to 5 seconds, which can be changed according to experimental values. The preset heat supply information can correspond to the threshold value of the internal heat absorption of the decomposer 100.
[0068] According to an exemplary embodiment, the preset heat supply amount may be set to a heat supply amount capable of preventing the internal temperature of the decomposer 100 from being lowered due to excess ammonia or excess hydrogen inside the decomposer.
[0069] The control unit 120 may determine the first signal based on the temperature information and the ammonia supply information. The first signal of the control unit 120 may be used to control the internal temperature increase effect of the decomposer through the preset heat supply information.
[0070] According to an exemplary embodiment, when the internal heat absorption of the decomposer is lower than the preset heat supply, the control unit 120 can increase the hydrogen supply through the first signal to increase the internal temperature of the decomposer 100. Therefore, the temperature increase effect in the ammonia reactor control system 10 can be amplified.
[0071] According to an exemplary embodiment, when the temperature of the decomposer 100 decreases, the control unit 120 may increase the hydrogen supply from the fuel cell 300. Therefore, the control unit 120 may quickly increase the temperature of the decomposer 100. When determining the hydrogen supply, the control unit 120 may change the hydrogen supply mode to produce the greatest possible warming effect in consideration of the stability of the hydrogen reaction.
[0072] Figure 4 is a schematic flow chart for explaining ammonia preheating of an ammonia reactor control system according to an exemplary embodiment of the present disclosure.
[0073] In step S410, a control unit (eg, Figure 2 The control unit 120 may receive a supply to a decomposer (eg, Figure 1 The control unit 120 may receive the ammonia temperature information inside the decomposer 100. The control unit 120 may receive the ammonia temperature information through a separate temperature sensing unit 60 for sensing the temperature of ammonia supplied to the inside of the decomposer 100.
[0074] In step S420, the control unit 120 may determine a third signal based on the ammonia temperature information. The control unit 120 may preheat the ammonia before supplying the ammonia to the decomposer according to the third signal. Figure 1The ammonia reactor control system 10 of the present invention may further include a preheating unit 50, which preheats the ammonia supplied to the decomposer 100 according to the third signal. The preheating unit 50 may be located inside or outside the ammonia supply unit (e.g., the ammonia supply unit 140). The preheating unit 50 may be provided at any position capable of preheating the ammonia inside the ammonia supply unit 140.
[0075] According to an exemplary embodiment, the control unit 120 may receive ammonia temperature information in the ammonia supply unit 140 from the temperature sensing unit 60. Therefore, the control unit 120 may confirm whether the temperature of ammonia to be supplied to the decomposer 100 through the ammonia supply unit 140 is lower than the temperature of ammonia already present in the decomposer 100.
[0076] In one embodiment, when the temperature of ammonia in the ammonia supply unit 140 is lower than the temperature of ammonia in the decomposer 100 , the control unit 120 may operate the preheating unit to increase the temperature of ammonia in the ammonia supply unit 140 according to the third signal.
[0077] In one embodiment, when the temperature of ammonia to be supplied to the ammonia supply unit 140 in the decomposer 100 is low, the control unit 120 may operate the preheating unit according to the third signal to increase the temperature of ammonia in the ammonia supply unit 140 in advance.
[0078] As described above, it is possible to control the cause of the temperature drop inside the decomposer 100. For example, the temperature control can be performed using the mechanism of ammonia decomposition, which is an endothermic reaction.
[0079] According to an exemplary embodiment, the preheating unit may include a material having high thermal conductivity and large heat capacity. The preheating unit may be made of a material capable of uniformly transferring heat when preheating ammonia.
[0080] Figure 5 is a schematic flowchart for explaining determination of an ammonia supply amount of an ammonia reactor control system according to an exemplary embodiment of the present disclosure.
[0081] In step S510, a control unit (eg, Figure 2 The control unit 120 may be supplied from a hydrogen supply unit (eg, Figure 2 The control unit 120 may receive the hydrogen supply amount information through a separate flow meter or supply amount measuring device installed in the hydrogen supply unit 130.
[0082] In step S520, the control unit 120 determines the ammonia supply amount according to a preset temperature range. The control unit 120 can determine the amount of ammonia supplied to the decomposer (e.g., Figure 1 The ammonia supply amount inside the decomposer 100).
[0083] According to an exemplary embodiment, the control unit 120 may store the data from a storage unit (eg, Figure 2 The storage unit 150 of the embodiment of the present invention confirms the information of the preset temperature range. The preset temperature range may include a first temperature range and a second temperature range. For example, the first temperature range and the second temperature range may be continuous temperature ranges that do not overlap with each other. The lower limit of the first temperature range may be greater than the upper limit of the second temperature range.
[0084] In one embodiment, when the temperature of the decomposer 100 is within the preset first temperature range, the control unit 120 may determine the ammonia supply as the first capacity according to the second signal. In one embodiment, when the temperature of the decomposer 100 is within the preset second temperature range, the control unit 120 may determine the ammonia supply as the second capacity according to the second signal. The first capacity may be smaller than the second capacity. The first temperature range, the second temperature range, the first capacity, and the second capacity may be experimental values, and may be stored as preset values according to the user's experimental results.
[0085] According to some embodiments, it may be assumed that the time or cost required to increase the internal temperature of the decomposer 100 is greater than a threshold value of the cost of interrupting the ammonia supply. When approaching the threshold value, the control unit 120 may adjust the ammonia supply by reducing or blocking the ammonia supply. The control unit 120 may adjust the ammonia supply according to the second signal. Figure 5 In an embodiment, when reducing the ammonia supply, the control unit 120 may change the ammonia supply reduction mode according to the temperature range of the decomposer 100 to generate the maximum temperature increase effect as much as possible according to the internal conditions of the decomposer 100.
[0086] Figure 6 is a schematic flowchart for explaining determination of an ammonia supply amount based on temperatures of various parts of a decomposer of an ammonia reactor control system according to an exemplary embodiment of the present disclosure.
[0087] In step S610, a control unit (eg, Figure 2 The control unit 120) may receive a decomposer (eg, Figure 1 The control unit 120 may receive the internal temperature of the first part and the second part of the decomposer 100. According to an exemplary embodiment, the sensor unit (eg, Figure 2 The sensor unit 110 includes a plurality of sensors, which can collect temperature information of the first part and the second part of the decomposer 100 .
[0088] The first portion and the second portion may refer to portions of the decomposer 100 that do not overlap with each other. In some embodiments, the first portion and the second portion may be an ammonia supply unit (e.g., Figure 2 A portion of the portion where the ammonia supply unit 140) and the decomposer are connected.
[0089] The sensor unit 110 may measure the temperature of each portion inside the decomposer 100 including the first portion and the second portion of the decomposer 100. The control unit 120 may determine a second signal according to the temperature of each portion inside the decomposer 100.
[0090] According to the second signal, the ammonia reactor control system 10 may change a pattern of the total amount of ammonia supply to be supplied to the first portion and the second portion.
[0091] In one embodiment, the control unit 120 may change the supply position of ammonia. When the temperature of the first part is higher than the temperature of the second part, the control unit 120 may adjust the amount of ammonia supplied to the first part and the amount of ammonia supplied to the second part in the total amount of ammonia supply to be supplied differently according to the second signal. For example, the control unit 120 controls to induce the greatest possible warming effect in order to effectively decompose ammonia. For example, when the temperature of the first part is high, it may be controlled so that the amount of ammonia supplied to the first part is less than the amount of ammonia supplied to the second part.
[0092] In step S620, the control unit 120 may determine a second signal based on the temperature information of each portion. The control unit 120 may adjust the amount of ammonia supplied to the first portion and the second portion using the temperature information collected from each portion to produce the greatest possible warming effect.
[0093] According to an exemplary embodiment, the controller 120 may determine the first signal or the second signal based on temperature information, ammonia supply information, and hydrogen supply information. The control unit 120 may adjust the ammonia supply or the hydrogen supply based on various information collected by the ammonia reactor control system 10 to produce the greatest possible warming effect.
[0094] In one embodiment, the control unit 120 can set the total supply of ammonia or hydrogen based on the same information to produce the maximum temperature increase effect as much as possible, and change the mode of supplying ammonia or hydrogen to the decomposer 100. For example, the control unit 120 can increase or decrease the supply of ammonia and / or the supply of unreacted hydrogen according to the temperature of the decomposer 100 to maintain the inside of the decomposer 100 at an appropriate temperature. In addition, the control unit 120 can reduce the amount of residual ammonia by maintaining the internal temperature of the decomposer 100 within an appropriate range.
[0095] In some embodiments, the disclosed embodiments may be implemented in the form of a recording medium storing instructions executable by a computer. The instructions may be stored in the form of program code, and when the instructions are executed by a processor, a program module may be generated to perform the operations of the disclosed embodiments. The recording medium may be implemented in the form of a computer-readable recording medium.
[0096] Computer-readable recording media include all types of recording media that store instructions that can be read by a computer, such as ROM (Read Only Memory), RAM (Random Access Memory), magnetic tapes, magnetic disks, flash memories, optical data storage devices, etc.
[0097] Above, the disclosed embodiments are described with reference to the accompanying drawings. Those skilled in the art to which the present disclosure belongs will understand that the present disclosure can be implemented in a form different from the disclosed embodiments without changing the technical ideas or essential features of the present disclosure. The disclosed embodiments are exemplary and should not be interpreted as limiting.
Claims
1. An ammonia reactor control system, comprising: A sensor unit, measuring the internal temperature of the decomposer; a control unit, receiving temperature information collected by the sensor unit; a hydrogen supply unit, which determines the amount of hydrogen supplied to the decomposer according to the first signal of the control unit; as well as an ammonia supply unit, which determines the amount of ammonia supplied to the decomposer according to the second signal of the control unit, The control unit is configured to: receiving ammonia supply amount information from the ammonia supply unit, The first signal is determined based on the temperature information and the ammonia supply amount information.
2. The ammonia reactor control system according to claim 1, further comprising: a storage unit storing preset heat supply amount information for supplying to the fuel cell through the decomposer, The control unit is configured to: confirming the preset heat supply amount information from the storage unit, The amount of heat absorbed inside the decomposer is calculated based on the temperature information.
3. The ammonia reactor control system according to claim 2, wherein: The control unit is configured to temporarily reduce the output of the fuel cell by comparing the preset heat supply amount information with the decomposer internal heat absorption amount information.
4. The ammonia reactor control system according to claim 1, further comprising: a temperature sensing unit for sensing a temperature of ammonia supplied from the ammonia supply unit to the interior of the decomposer; as well as The preheating unit preheats the ammonia supplied to the decomposer according to the third signal of the control unit.
5. The ammonia reactor control system according to claim 4, wherein: The control unit is configured to: receiving ammonia temperature information in the ammonia supply unit from the temperature sensing unit, The third signal to operate the preheating unit is determined based on the ammonia temperature information.
6. The ammonia reactor control system according to claim 1, wherein: The control unit is configured to: receiving a hydrogen supply amount from the hydrogen supply unit, The second signal is determined based on the temperature information and the hydrogen supply amount information.
7. The ammonia reactor control system according to claim 6, wherein: The control unit is configured to: When the temperature of the decomposer is within a preset first temperature range, the ammonia supply amount is determined as a first capacity according to the second signal, When the temperature of the decomposer is within a preset second temperature range, the ammonia supply amount is determined as a second capacity according to the second signal, The lower limit of the first temperature range is greater than the upper limit of the second temperature range, The first capacity is smaller than the second capacity.
8. The ammonia reactor control system according to claim 6, wherein: The sensor unit measures the internal temperature of the first part and the second part including the decomposer, The ammonia supply unit is connected to the first part and the second part, The control unit is configured to determine the second signal based on temperature information of the first portion and the second portion.
9. The ammonia reactor control system according to claim 6, wherein: The control unit is configured to determine the first signal or the second signal based on the temperature information, the ammonia supply amount information, and the hydrogen supply amount information.
10. A method for generating hydrogen, comprising the following steps: supplying ammonia to a decomposer; receiving temperature information collected by a sensor unit measuring the internal temperature of the decomposer; receiving ammonia supply amount information from an ammonia supply unit that determines an ammonia supply amount supplied to the interior of the decomposer; receiving hydrogen supply amount information from a hydrogen supply unit that determines a hydrogen supply amount supplied to the interior of the decomposer; and Based on the temperature information, the ammonia supply amount information, and the hydrogen supply amount information, a first signal or a second signal is provided to the hydrogen supply unit or the ammonia supply unit.