Hydrate solid-state composite hydrogen storage control method and system

Abstract

The invention discloses a hydrate solid-state composite hydrogen storage control method and system, and relates to the technical field of hydrate solid-state composite hydrogen storage control. The hydrate solid-state composite hydrogen storage control method comprises the following steps: acquiring a set temperature curve and a set pressure curve corresponding to a hydrogen hydrate in an inner tank; wherein the set temperature curve and / or the set pressure curve are / is configured to be a periodic curve; determining at least one of a hydrogen filling and hydrogen hydrate generation stage, a temperature rise and pressure reduction stage, a cooling pressurization stage and a hydrogen release stage in the hydrate solid-state composite hydrogen storage control process; in at least one of the hydrogen filling and hydrogen hydrate generation stage, the heating and depressurization stage, the cooling and pressurization stage and the hydrogen release stage, rhythmic control is conducted on hydrate solid-state composite hydrogen storage control by regulating and controlling the temperature initial value of the set temperature curve and the pressure initial value of the set pressure curve. And hydrate solid-state composite hydrogen storage control can be realized.

Description

Technical Field

[0001] The present disclosure relates to the technical field of hydrate solid composite hydrogen storage control, and in particular to a hydrate solid composite hydrogen storage control method and system. Background Art

[0002] As a representative of clean energy, hydrogen energy has the advantages of high energy density and zero emissions, but efficient and safe hydrogen storage technology has always been a key challenge for the large-scale application of hydrogen energy. At present, hydrogen storage technology mainly includes three forms: gaseous hydrogen storage, liquid hydrogen storage and solid hydrogen storage. Compared with gaseous and liquid hydrogen storage, solid hydrogen storage has attracted much attention due to its safety and high hydrogen storage density.

[0003] Hydrate storage is a special solid-state hydrogen storage method that combines hydrogen with water molecules under certain temperature and pressure conditions to form solid hydrogen hydrates. This method has the following characteristics: harsh generation conditions, kinetic limitations, insufficient material optimization, and limited control accuracy.

[0004] Nowadays, highly adsorbable carbon-based materials such as metal organic frameworks (MOFs), graphene, and activated carbon are used as substrates to improve the adsorption capacity of hydrogen, and solid-state hydrogen storage is achieved through the formation of hydrogen hydrates, forming an efficient hydrogen storage system.

[0005] However, although this technology has increased the overall hydrogen storage density, it is difficult to maximize the hydrogen storage efficiency, and some hydrate molecular cages do not effectively adsorb hydrogen molecules. In addition, the existing technology for regulating temperature and pressure mostly relies on a single constant condition, which is difficult to dynamically respond to complex working conditions, resulting in excessive energy consumption and low efficiency. Summary of the invention

[0006] The present disclosure proposes a technical solution for a hydrate solid composite hydrogen storage control method and system.

[0007] According to one aspect of the present disclosure, a hydrate solid composite hydrogen storage control method is provided, comprising:

[0008] Obtaining a set temperature curve and a set pressure curve corresponding to the inner tank where the hydrogen hydrate is located; wherein the set temperature curve and / or the set pressure curve are configured as a periodic curve;

[0009] Determine at least one of the following stages in the hydrate solid composite hydrogen storage control process: hydrogen filling and hydrogen hydrate formation stage, temperature increase and pressure reduction stage, cooling and pressurization stage, and hydrogen release stage;

[0010] In at least one of the hydrogen filling and hydrogen hydrate formation stage, the temperature increase and pressure reduction stage, the cooling and pressurization stage, and the hydrogen release stage, the hydrate solid-state composite hydrogen storage control is rhythmically controlled by regulating the temperature initial value of the set temperature curve and the pressure initial value of the set pressure curve.

[0011] Preferably, the inner tank is also provided with a responsive hydrate builder; wherein the responsive hydrate builder is configured as a metal organic framework, an adsorptive activated carbon material or an adsorptive composite material.

[0012] Preferably, in the hydrogen filling and hydrogen hydrate formation stage, the method for rhythmically controlling the hydrate solid-state composite hydrogen storage control by regulating the temperature initial value of the set temperature curve and the pressure initial value of the set pressure curve includes: controlling the hydrogen flow regulating valve connected to the inner tank and the hydrogen flow to open, and controlling the hydrogen to enter the inner tank according to the set hydrogen entry rate; in the process of controlling the hydrogen to enter the inner tank according to the set hydrogen entry rate, configuring the set initial temperature corresponding to the startup stage of the hydrate solid-state composite hydrogen storage control process as the temperature initial value of the set temperature curve, raising the pressure of the inner tank to the pressure reference value, and configuring the pressure reference value as the pressure initial value of the set pressure curve; under the rhythmic control of the configured set temperature curve and the set pressure curve, the molecular vibration frequency in the hydrate lattice of the hydrogen hydrate matches the periodic changes of the temperature and pressure of the inner tank.

[0013] Preferably, during the hydrogen filling and hydrogen hydrate formation stage, in the process of matching the molecular vibration frequency in the hydrate lattice of the hydrogen hydrate with the periodic changes in the temperature and pressure of the inner tank, the responsive hydrate builder provided in the inner tank adjusts the size of its microscopic pore structure so that hydrogen molecules can quickly migrate and stably store in the hydrate lattice, thereby improving the hydrogen storage density.

[0014] Preferably, in the temperature increase and pressure reduction stage, the method for rhythmically controlling the hydrate solid composite hydrogen storage control by regulating the temperature initial value of the set temperature curve and the pressure initial value of the set pressure curve comprises:

[0015] After the hydrogen filling and hydrogen hydrate formation stage is completed, the temperature initial value of the set temperature curve in the hydrogen filling and hydrogen hydrate formation stage is increased to the first set temperature target value; the pressure initial value of the set pressure curve in the hydrogen filling and hydrogen hydrate formation stage is reduced to the first set pressure target value; under the rhythmic control of the set temperature curve corresponding to the first set temperature target value and the set pressure curve corresponding to the set pressure target value after configuration, the molecular vibration frequency in the hydrate lattice is caused to change, thereby optimizing the release and redistribution of hydrogen molecules.

[0016] Preferably, in the temperature increase and pressure reduction stage, under the rhythmic control of the set temperature curve corresponding to the first set temperature target value and the set pressure curve corresponding to the set pressure target value after configuration, the pore structure inside the responsive hydrate builder in the hydrogen filling and hydrogen hydrate formation stage is fine-tuned to allow more hydrogen to enter the pores inside the responsive hydrate builder.

[0017] Preferably, in the cooling and pressurizing stage, the method for rhythmically controlling the hydrate solid composite hydrogen storage control by regulating the temperature initial value of the set temperature curve and the pressure initial value of the set pressure curve includes: after the temperature rising and pressure reducing stage is completed, the temperature initial value of the set temperature curve in the hydrogen filling and hydrogen hydrate formation stage is reduced from the first set temperature target value to the set initial temperature corresponding to the startup stage; the pressure initial value of the set pressure curve in the hydrogen filling and hydrogen hydrate formation stage is increased from the first set pressure target value to the second set pressure target value; under the rhythmic control of the set temperature curve corresponding to the first set temperature target value and the set pressure curve corresponding to the set pressure target value after configuration, the incompletely reacted hydrogen is further converted into hydrogen hydrate.

[0018] Preferably, in the cooling and pressurizing stage, under the rhythmic control of the set temperature curve corresponding to the first set temperature target value and the set pressure curve corresponding to the set pressure target value after configuration, the stability of the hydrate lattice is enhanced, the adsorption of remaining hydrogen molecules and the further formation of hydrates are promoted, and the hydrate lattice vibration is more orderly, ensuring that the hydrogen molecules are effectively locked in the lattice structure.

[0019] Preferably, the hydrate solid composite hydrogen storage control method also includes: determining each of the temperature rising and pressure reducing stages and each of the cooling and pressurizing stages as a cyclic pressure and temperature cycle; the method for determining the corresponding number of the cyclic pressure and temperature cycles includes: after each of the temperature rising and pressure reducing stages or each of the cooling and pressurizing stages, obtaining the actual hydrogen storage capacity of the inner tank; if the actual hydrogen storage capacity reaches the set hydrogen storage capacity target and / or the preset maximum number of cycles corresponding to the set hydrogen storage capacity target, stopping the cyclic pressure and temperature cycle or stopping the temperature rising and pressure reducing stage or the cooling and pressurizing stage, and entering the static pressure and temperature stage.

[0020] Preferably, after each of the temperature rising and pressure reducing stages or each of the cooling and pressure increasing stages, the hydrogen storage capacity increment between this cycle and the previous cycle and pressure increasing stage is calculated; if the hydrogen storage capacity increment is less than a set hydrogen storage capacity increment threshold and / or the actual hydrogen storage capacity of the inner tank reaches a set hydrogen storage capacity target and / or a preset maximum number of cycles corresponding to the set hydrogen storage capacity target, the cycle and pressure increasing stage or the temperature rising and pressure reducing stage or the cooling and pressure increasing stage is stopped, and the static pressure and temperature stage is entered.

[0021] Preferably, in the hydrogen release stage, the method for rhythmically controlling the hydrate solid-state composite hydrogen storage control by regulating the temperature initial value of the set temperature curve and the pressure initial value of the set pressure curve includes: increasing the set static maintenance temperature of the static pressure and temperature stage in the hydrate solid-state composite hydrogen storage control process to a second set temperature target value corresponding to the temperature initial value of the set temperature curve; reducing the set static maintenance pressure of the static pressure and temperature stage in the hydrate solid-state composite hydrogen storage control process to a third set pressure target value corresponding to the pressure initial value of the set temperature curve; under the rhythmic control of the set temperature curve corresponding to the third set temperature target value and the set pressure curve corresponding to the third set pressure target value after configuration, the structure of the hydrate lattice is loosened, the vibration frequency of the hydrogen molecules is changed, and the hydrogen molecules in the hydrate lattice are deembedded and released into the gas phase.

[0022] Preferably, during at least one of the hydrogen filling and hydrogen hydrate formation stage, the temperature rising and pressure reducing stage, the cooling and pressurizing stage, and the hydrogen release stage, the method for rhythmically controlling the hydrate solid composite hydrogen storage control is performed by regulating the temperature initial value of the set temperature curve and the pressure initial value of the set pressure curve, and the method also includes: real-time calculation of the temperature deviation between the temperature of the inner tank and the set temperature corresponding to the set temperature curve after the temperature initial value is configured; real-time calculation of the pressure deviation between the pressure of the inner tank and the set pressure corresponding to the set pressure curve after the pressure initial value is configured; according to the set fuzzy rule set, respectively determining the temperature deviation level and the pressure deviation level corresponding to the temperature deviation; based on the temperature deviation level and the pressure deviation level, regulating the current refrigerant flow rate corresponding to the cooling conduit entering the inner tank or entering the outside of the inner tank and the hydrogen flow corresponding to the filling of the inner tank.

[0023] Preferably, the method for regulating the current refrigerant flow rate corresponding to the refrigerant flow entering the inner tank or the cooling duct entering the outer side of the inner tank and the corresponding hydrogen flow rate filled into the inner tank based on the temperature deviation level and the pressure deviation level comprises: the temperature deviation level comprises: a first temperature deviation level corresponding to the highest level, a second temperature deviation level lower than the first temperature deviation level, and a third temperature deviation level lower than the second temperature deviation level; the pressure deviation level comprises: a first pressure deviation level corresponding to the highest level, a second pressure deviation level lower than the first pressure deviation level, and a third pressure deviation level lower than the second pressure deviation level; wherein, if the temperature deviation level is the first temperature deviation level, the refrigerant flow entering the inner tank is increased. The current refrigerant flow rate corresponding to the inner tank or the cooling duct entering the outside of the inner tank is increased; if the temperature deviation level is the second temperature deviation level, the current refrigerant flow rate corresponding to the refrigerant flow entering the inner tank or the cooling duct entering the outside of the inner tank is maintained; if the temperature deviation level is the third temperature deviation level, the current refrigerant flow rate corresponding to the refrigerant flow entering the inner tank or the cooling duct entering the outside of the inner tank is reduced; wherein, if the pressure deviation level is the first pressure deviation level, the corresponding hydrogen flow rate filled into the inner tank is increased; if the pressure deviation level is the second pressure deviation level, the corresponding hydrogen flow rate filled into the inner tank is maintained; if the pressure deviation level is the third pressure deviation level, the corresponding hydrogen flow rate filled into the inner tank is reduced.

[0024] Preferably, in at least one of the hydrogen filling and hydrogen hydrate formation stage, the temperature rising and pressure reducing stage, the cooling and pressurizing stage, and the hydrogen release stage, the method for rhythmically controlling the hydrate solid composite hydrogen storage is performed by regulating the temperature initial value of the set temperature curve and the pressure initial value of the set pressure curve, and also includes: increasing or decreasing the current refrigerant flow rate corresponding to the cooling conduit entering the inner tank or entering the outside of the inner tank while maintaining the temperature corresponding to the inner tank at the set temperature corresponding to the set temperature curve.

[0025] Preferably, the method of increasing or decreasing the current refrigerant flow rate corresponding to the refrigerant flow entering the inner tank or entering the cooling conduit outside the inner tank in the process of maintaining the temperature corresponding to the inner tank at the set temperature of the set temperature curve includes: obtaining a first set temperature deviation threshold, a second set temperature deviation threshold, and a temperature deviation between the temperature corresponding to the inner tank and the set temperature of the set temperature curve; determining the corresponding first temperature hysteresis zone based on the first set temperature deviation threshold and the second set temperature deviation threshold; if the temperature deviation is outside the first temperature hysteresis zone, increasing the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank at a first set rate or reducing the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank; if the temperature deviation is within the first temperature hysteresis zone, increasing the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank at a second set rate less than the first set rate or reducing the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank or maintaining the current set rate corresponding to the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank.

[0026] Preferably, if the temperature deviation is within the first temperature hysteresis zone, the method of increasing the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outer side of the inner tank at a second set rate that is less than the first set rate, or reducing the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outer side of the inner tank, or maintaining the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outer side of the inner tank corresponding to the current set rate includes: a third set temperature deviation threshold value that is less than the first set temperature deviation threshold value and a fourth set temperature deviation threshold value that is greater than the second set temperature deviation threshold value; based on the third set temperature deviation threshold value The temperature deviation threshold and the fourth set temperature deviation threshold determine the corresponding second temperature hysteresis zone; if the temperature deviation is within the first temperature hysteresis zone, determine whether the deviation is within the second temperature hysteresis zone; if the deviation is within the second temperature hysteresis zone, maintain the current set rate corresponding to the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank; otherwise, increase the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank at a second set rate that is less than the first set rate, or decrease the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank.

[0027] Preferably, in at least one of the hydrogen filling and hydrogen hydrate formation stage, the temperature increase and pressure reduction stage, the cooling and pressurization stage, and the hydrogen release stage, the method for rhythmically controlling the hydrate solid composite hydrogen storage is performed by regulating the temperature initial value of the set temperature curve and the pressure initial value of the set pressure curve, and also includes: increasing or decreasing the hydrogen flow rate corresponding to the hydrogen flow filled into the inner tank while maintaining the pressure corresponding to the inner tank at the set pressure corresponding to the set pressure curve.

[0028] Preferably, the method of increasing or decreasing the flow rate of hydrogen corresponding to the inner tank while maintaining the pressure corresponding to the inner tank at the set pressure of the set pressure curve comprises: obtaining a first set pressure deviation threshold, a second set pressure deviation threshold, and a pressure deviation between the pressure corresponding to the inner tank and the set pressure of the set pressure curve; determining a corresponding first pressure hysteresis zone based on the first set pressure deviation threshold and the second set pressure deviation threshold; if the pressure deviation is outside the first pressure hysteresis zone, increasing the flow rate of hydrogen filled into the inner tank at a first set rate or decreasing the flow rate of hydrogen filled into the inner tank; if the pressure deviation is within the first pressure hysteresis zone, increasing the flow rate of hydrogen filled into the inner tank at a second set rate that is less than the first set rate or decreasing the flow rate of hydrogen filled into the inner tank or maintaining the flow rate of hydrogen filled into the inner tank.

[0029] Preferably, if the pressure deviation is within the first pressure hysteresis zone, the method for increasing the hydrogen flow rate filled into the inner tank connection at a second set rate that is less than the first set rate or decreasing the hydrogen flow rate filled into the inner tank connection or maintaining the hydrogen flow rate of the inner tank connection comprises: a third set pressure deviation threshold that is less than the first set pressure deviation threshold and a fourth set pressure deviation threshold that is greater than the second set pressure deviation threshold; determining the corresponding second pressure hysteresis zone based on the third set pressure deviation threshold and the fourth set pressure deviation threshold; if the pressure deviation is within the first pressure hysteresis zone, determining whether the deviation is within the second pressure hysteresis zone; if the deviation is within the second pressure hysteresis zone, maintaining the hydrogen flow rate of the inner tank connection; otherwise, increasing the hydrogen flow rate filled into the inner tank connection or decreasing the hydrogen flow rate filled into the inner tank connection at a second set rate that is less than the first set rate.

[0030] Preferably, the first set temperature deviation threshold and the second set temperature deviation threshold are configured to be 1° C. and −1° C. respectively.

[0031] Preferably, the third set temperature deviation threshold and the fourth set temperature deviation threshold are configured to be 0.5° C. and −0.5° C. respectively.

[0032] Preferably, the first set pressure deviation threshold and the second set pressure deviation threshold are configured to be 1 MPa and -1 MPa respectively.

[0033] The third set pressure deviation threshold and the fourth set pressure deviation threshold are configured to be 0.5 MPa and -0.5 MPa respectively.

[0034] Preferably, the hydrate solid composite hydrogen storage control process also includes: a startup phase; in the startup phase, obtaining the temperature corresponding to the inner tank in real time; adjusting the temperature corresponding to the inner tank to a set initial temperature, and maintaining the set initial temperature corresponding to the inner tank.

[0035] Preferably, the hydrate solid composite hydrogen storage control process also includes: a static pressure and temperature stage; in the static pressure and temperature stage, obtaining the temperature and pressure corresponding to the inner tank in real time; maintaining the temperature corresponding to the inner tank at a set static maintenance temperature or below the set static maintenance temperature; maintaining the pressure corresponding to the inner tank at a set static maintenance pressure or above the set static maintenance pressure.

[0036] Preferably, the method for maintaining the temperature corresponding to the inner tank at a set static maintenance temperature or below the set static maintenance temperature includes: obtaining a first set temperature deviation threshold, a second set temperature deviation threshold, and a temperature deviation between the temperature corresponding to the inner tank and the set static maintenance temperature; determining a corresponding first temperature hysteresis zone based on the first set temperature deviation threshold and the second set temperature deviation threshold; if the temperature deviation is outside the first temperature hysteresis zone, increasing the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank at a first set rate or reducing the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank; if the temperature deviation is within the first temperature hysteresis zone, increasing the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank at a second set rate less than the first set rate or reducing the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank or maintaining the current set rate corresponding to the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank.

[0037] Preferably, if the temperature deviation is within the first temperature hysteresis zone, the method of increasing the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outer side of the inner tank at a second set rate that is less than the first set rate, or reducing the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outer side of the inner tank, or maintaining the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outer side of the inner tank corresponding to the current set rate includes: a third set temperature deviation threshold value that is less than the first set temperature deviation threshold value and a fourth set temperature deviation threshold value that is greater than the second set temperature deviation threshold value; based on the third set temperature deviation threshold value The temperature deviation threshold and the fourth set temperature deviation threshold determine the corresponding second temperature hysteresis zone; if the temperature deviation is within the first temperature hysteresis zone, determine whether the deviation is within the second temperature hysteresis zone; if the deviation is within the second temperature hysteresis zone, maintain the current set rate corresponding to the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank; otherwise, increase the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank at a second set rate that is less than the first set rate, or decrease the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank.

[0038] Preferably, the first set temperature deviation threshold and the second set temperature deviation threshold are configured to be 1° C. and −1° C. respectively.

[0039] Preferably, the third set temperature deviation threshold and the fourth set temperature deviation threshold are configured to be 0.5° C. and −0.5° C. respectively.

[0040] Preferably, the hydrate solid composite hydrogen storage control process also includes: a startup phase; in the startup phase, the refrigerant flow regulating valve connected to the inner tank or the cooling duct entering the outside of the inner tank and the refrigerant flow is controlled to open, and the temperature corresponding to the inner tank is obtained in real time; the temperature corresponding to the inner tank is adjusted to the set initial temperature, and the set initial temperature corresponding to the inner tank is maintained.

[0041] Preferably, the hydrate solid composite hydrogen storage control process also includes: a final pressure relief and shutdown stage; in the final pressure relief and shutdown stage, the pressure in the inner tank is reduced to a set pressure relief and shutdown pressure by using a set decompression rate.

[0042] Preferably, in the final pressure relief and shutdown stage, it also includes: controlling the refrigerant flow regulating valve connected to the inner tank or the cooling duct entering the outside of the inner tank and the refrigerant flow to close, and controlling the hydrogen flow regulating valve connected to the inner tank and the hydrogen flow to close; when the pressure in the inner tank is reduced to the set pressure relief and shutdown pressure and the corresponding temperature of the inner tank returns to the ambient temperature, the status mark of the hydrate solid composite hydrogen storage control process is configured to standby.

[0043] According to one aspect of the present disclosure, a hydrate solid composite hydrogen storage control system or device is provided, comprising:

[0044] An acquisition unit, used to acquire a set temperature curve and a set pressure curve corresponding to the inner tank where the hydrogen hydrate is located; wherein the set temperature curve and / or the set pressure curve are configured as a periodic curve;

[0045] A determination unit, used to determine at least one stage of the hydrogen filling and hydrogen hydrate formation stage, the temperature increase and pressure reduction stage, the cooling and pressurization stage, and the hydrogen release stage in the hydrate solid composite hydrogen storage control process;

[0046] A control unit is used to perform rhythmic control on the hydrate solid composite hydrogen storage control using the set temperature curve and the set pressure curve in at least one of the hydrogen filling and hydrogen hydrate formation stage, the temperature increase and pressure reduction stage, the cooling and pressurization stage, and the hydrogen release stage.

[0047] According to one aspect of the present disclosure, a hydrate solid-state composite hydrogen storage control system or device is provided, comprising: a processor; a memory for storing processor executable instructions; wherein the processor is configured to call the instructions stored in the memory to execute the above-mentioned hydrate solid-state composite hydrogen storage control method.

[0048] According to one aspect of the present disclosure, a hydrate solid-state composite hydrogen storage control system or device is provided, comprising: a computer-readable storage medium having computer program instructions stored thereon, wherein the computer program instructions implement the above-mentioned hydrate solid-state composite hydrogen storage control method when executed by a processor.

[0049] According to one aspect of the present disclosure, a hydrate solid-state composite hydrogen storage control system or device is provided, comprising: a computer program product on which a computer program / instruction is configured, and when the computer program / instruction is executed by a processor, the above-mentioned hydrate solid-state composite hydrogen storage control method is implemented.

[0050] According to one aspect of the present disclosure, there is provided an electronic device, comprising: a processor; and a memory for storing instructions executable by the processor; wherein the processor is configured to: execute the above-mentioned hydrate solid-state composite hydrogen storage control method.

[0051] According to one aspect of the present disclosure, a computer-readable storage medium is provided, on which computer program instructions are stored, and when the computer program instructions are executed by a processor, the above-mentioned hydrate solid-state composite hydrogen storage control method is implemented.

[0052] According to one aspect of the present disclosure, a hydrate solid-state composite hydrogen storage control system is provided, comprising: an inner tank; a cooling duct is arranged on the outer side of the inner tank, and the inner tank is also connected to a hydrogen source; the inner tank is provided with a temperature sensor and a pressure sensor for detecting the temperature and pressure in the inner tank; wherein the inner tank is filled with a responsive hydrate builder for accommodating hydrogen hydrates; in at least one of the hydrogen filling and hydrogen hydrate generation stages, the temperature increase and pressure reduction stage, the cooling and pressurization stage, and the hydrogen release stage in the hydrate solid-state composite hydrogen storage control process, the refrigerant flow in the cooling duct and the hydrogen flow from the hydrogen source entering the inner tank are used to rhythmically control the temperature and pressure in the inner tank detected by the pressure temperature sensor and the pressure sensor by regulating the temperature initial value of the periodic set temperature curve and the pressure initial value of the periodic set pressure curve, so as to adjust the microscopic pore structure of the responsive hydrate builder and / or the vibration of the hydrate lattice of the hydrogen hydrate.

[0053] Preferably, it also includes: a heat-insulating and anti-seepage composite layer arranged on the outside of the inner tank or the cooling duct; wherein the cooling duct is configured as a coil structure; wherein the cooling duct of the coil structure is coiled on the outside of the cooling duct; wherein one end of the cooling duct is provided with a refrigerant inlet connected to a refrigerant source, and the other end of the cooling duct is provided with a refrigerant outlet.

[0054] In the embodiments of the present disclosure, a technical solution for a hydrate solid-state composite hydrogen storage control method and system is proposed to solve at least one of the technical problems of the hydrate solid-state composite hydrogen storage process, namely, harsh generation conditions, kinetic limitations, insufficient material optimization, limited control accuracy, and the existing technology for regulating temperature and pressure relying mostly on a single constant condition and having difficulty in dynamically responding to complex working conditions, resulting in excessive energy consumption and low efficiency.

[0055] It is to be understood that both the foregoing general description and the following detailed description are exemplary and explanatory only and are not restrictive of the disclosure.

[0056] Further features and aspects of the present disclosure will become apparent from the following detailed description of exemplary embodiments with reference to the attached drawings. BRIEF DESCRIPTION OF THE DRAWINGS

[0057] The drawings herein are incorporated into the specification and constitute a part of the specification. These drawings illustrate embodiments consistent with the present disclosure and are used to illustrate the technical solutions of the present disclosure together with the specification.

[0058] Figure 1 A flow chart showing a hydrate solid composite hydrogen storage control method according to an embodiment of the present disclosure;

[0059] Figure 2 A structural schematic diagram corresponding to the overall structure of the shell of the hydrogen storage bottle according to an embodiment of the present disclosure is shown;

[0060] Figure 3 A schematic structural diagram corresponding to the inner tank of the hydrogen storage bottle according to an embodiment of the present disclosure is shown;

[0061] Figure 4 A schematic structural diagram corresponding to the top of a hydrogen storage bottle according to an embodiment of the present disclosure is shown;

[0062] Figure 5 is a block diagram of an electronic device 800 according to an exemplary embodiment;

[0063] Figure 6 is a block diagram of an electronic device 1900 according to an exemplary embodiment. DETAILED DESCRIPTION

[0064] Various exemplary embodiments, features and aspects of the present disclosure will be described in detail below with reference to the accompanying drawings. The same reference numerals in the accompanying drawings represent elements with the same or similar functions. Although various aspects of the embodiments are shown in the accompanying drawings, the drawings are not necessarily drawn to scale unless otherwise specified.

[0065] The word “exemplary” is used exclusively herein to mean “serving as an example, example, or illustration.” Any embodiment described herein as “exemplary” is not necessarily to be construed as preferred or advantageous over other embodiments.

[0066] The term "and / or" herein is only a description of the association relationship of the associated objects, indicating that there may be three relationships. For example, A and / or B can represent: A exists alone, A and B exist at the same time, and B exists alone. In addition, the term "at least one" herein represents any combination of at least two of any one or more of a plurality of. For example, including at least one of A, B, and C can represent including any one or more elements selected from the set consisting of A, B, and C.

[0067] In addition, in order to better illustrate the present disclosure, numerous specific details are given in the following specific embodiments. It should be understood by those skilled in the art that the present disclosure can also be implemented without certain specific details. In some examples, methods, means, components and circuits well known to those skilled in the art are not described in detail in order to highlight the subject matter of the present disclosure.

[0068] It can be understood that the above-mentioned various method embodiments mentioned in the present disclosure can be combined with each other to form a combined embodiment without violating the principle logic. Due to space limitations, the present disclosure will not go into details.

[0069] In addition, the present disclosure also provides a hydrate solid-state composite hydrogen storage control system or device, an electronic device, a computer-readable storage medium, and a program, all of which can be used to implement any hydrate solid-state composite hydrogen storage control method provided by the present disclosure. The corresponding technical solutions and descriptions are referred to the corresponding records in the method section and will not be repeated here.

[0070] Figure 1 A flow chart showing a hydrate solid composite hydrogen storage control method according to an embodiment of the present disclosure; Figure 2 A structural schematic diagram corresponding to the overall structure of the shell of the hydrogen storage bottle according to an embodiment of the present disclosure is shown; Figure 3 A schematic structural diagram corresponding to the inner tank of the hydrogen storage bottle according to an embodiment of the present disclosure is shown; Figure 4 FIG. 2 shows a schematic diagram of the structure corresponding to the top of the hydrogen storage bottle according to an embodiment of the present disclosure. Figures 1 to 4The method for controlling solid-state composite hydrogen storage of hydrates includes: step S101: obtaining a set temperature curve and a set pressure curve corresponding to the inner tank where the hydrogen hydrate is located; wherein the set temperature curve and / or the set pressure curve are configured as a periodic curve; step S102: determining at least one of the hydrogen filling and hydrogen hydrate generation phase, the temperature rise and pressure reduction phase, the cooling and pressurization phase, and the hydrogen release phase in the process of controlling solid-state composite hydrogen storage of hydrates; step S103: in at least one of the hydrogen filling and hydrogen hydrate generation phase, the temperature rise and pressure reduction phase, the cooling and pressurization phase, and the hydrogen release phase, rhythmic control is performed on the solid-state composite hydrogen storage of hydrates by regulating the temperature initial value of the set temperature curve and the pressure initial value of the set pressure curve. This is to solve at least one of the technical problems of harsh generation conditions, kinetic limitations, insufficient material optimization, limited control accuracy, and the fact that the prior art relies on a single constant condition to control temperature and pressure, which makes it difficult to dynamically respond to complex working conditions, resulting in excessive energy consumption and low efficiency.

[0071] Step S101: obtaining a set temperature curve and a set pressure curve corresponding to an inner tank where hydrogen hydrate is located; wherein the set temperature curve and / or the set pressure curve are configured as periodic curves.

[0072] In the embodiments of the present disclosure and other possible embodiments, the set temperature curve and / or the set pressure curve are configured as periodic curves. For example, the periodic curve can be configured as a periodic curve corresponding to all trigonometric functions such as sin x, cos x, tan x, cot x, etc. For another example, the periodic curve can be configured as a periodic curve corresponding to periodic functions such as triangular waves and rectangular waves. For another example, for other possible functions f(x), for function f(x), if there is a constant T that is not 0, so that for any x in the definition domain, f(x+T)=f(x), then function f(x) is a periodic curve corresponding to a periodic function.

[0073] In the embodiments of the present disclosure and other possible embodiments, the following embodiments are described using a periodic curve corresponding to the sin x trigonometric function. For example, in a rhythmic pressure-temperature cycle, the temperature and pressure of the inner tank of the hydrogen storage bottle are adjusted according to the following function:

[0074] T(t)=T 初始 +ΔT amp ·sin(2πf T t)

[0075] P(t)=P0+ΔP amp ·sin(2πf P t)+2MPa; or, P(t)=P0+ΔP amp ·sin(2πfP t)

[0076] Among them, T 初始 is the initial temperature value of the inner tank of the hydrogen storage bottle; ΔT amp is the temperature amplitude; f T is the temperature oscillation frequency; P(t) is the current pressure in the inner tank of the hydrogen storage bottle; ΔP amp is the pressure amplitude; f P is the pressure oscillation frequency; T(t) is the current temperature of the inner tank of the hydrogen storage bottle. Among them, the rhythm parameters of the set temperature curve and the set pressure curve, such as the amplitude ΔT of the set temperature curve amp = 2℃ and set the frequency f of the temperature curve T = 0.005Hz, and set the amplitude of the pressure curve ΔP amp =2MPa, set the frequency of the pressure curve f P =0.005Hz.

[0077] In the embodiments of the present disclosure and other possible embodiments, those skilled in the art may set the amplitude ΔT of the temperature curve according to actual needs. amp and set the frequency f of the temperature curve T and set the amplitude of the pressure curve ΔP amp , set the frequency f of the pressure curve P to configure.

[0078] Step S102: determining at least one of the hydrogen charging and hydrogen hydrate formation phases, the temperature increase and pressure reduction phase, the cooling and pressurization phase, and the hydrogen release phase in the hydrate solid composite hydrogen storage control process.

[0079] In the embodiments of the present disclosure and other possible embodiments, the hydrate solid composite hydrogen storage control process includes: a start-up phase of device preparation and cooling system, a hydrogen filling and hydrogen hydrate formation phase, a temperature increase and pressure reduction phase (second cycle pressure and temperature), a cooling and pressurization phase (third cycle pressure and temperature), hydrogen storage and heat preservation (static pressure and temperature phase), a hydrogen release phase (the reverse process of the cycle pressure and temperature), and a final pressure relief and shutdown phase; wherein the temperature increase and pressure reduction phase and the cooling and pressurization phase constitute a cyclic pressure and temperature cycle (cyclic pressure and temperature cycle).

[0080] In the embodiment of the present disclosure and other possible embodiments, the inner tank 3 is further provided with a responsive hydrate builder 4; wherein the responsive hydrate builder 4 is configured as a metal organic framework, an adsorbent activated carbon material, or a composite material with adsorption. For example, the responsive hydrate builder 4 is configured as a metal organic framework (MOFs), an adsorbent activated carbon material, or other composite materials with good adsorption, and the responsive hydrate builder 4 is filled in the center of the inner tank.

[0081] Step S103: In at least one of the hydrogen filling and hydrogen hydrate formation stage, the temperature increase and pressure reduction stage, the cooling and pressurization stage, and the hydrogen release stage, rhythmic control is performed on the hydrate solid composite hydrogen storage control by regulating the temperature initial value of the set temperature curve and the pressure initial value of the set pressure curve.

[0082] In an embodiment of the present disclosure, during the hydrogen filling and hydrogen hydrate formation stage, a method for rhythmically controlling the hydrate solid composite hydrogen storage control by regulating the temperature initial value of the set temperature curve and the pressure initial value of the set pressure curve includes: controlling the hydrogen flow regulating valve connected to the inner tank and the hydrogen flow to open, and controlling the hydrogen to enter the inner tank according to the set hydrogen entry rate; in the process of controlling the hydrogen to enter the inner tank according to the set hydrogen entry rate, configuring the set initial temperature corresponding to the startup stage of the hydrate solid composite hydrogen storage control process as the temperature initial value of the set temperature curve, raising the pressure of the inner tank to a pressure reference value, and configuring the pressure reference value as the pressure initial value of the set pressure curve; under the rhythmic control of the configured set temperature curve and the set pressure curve, the molecular vibration frequency in the hydrate lattice of the hydrogen hydrate matches the periodic changes of the temperature and pressure of the inner tank.

[0083] In the embodiments of the present disclosure and other possible embodiments, during the hydrogen filling and hydrogen hydrate formation stages, in the process of matching the molecular vibration frequency in the hydrate lattice of the hydrogen hydrate with the periodic changes in the temperature and pressure of the inner tank, the responsive hydrate builder provided in the inner tank adjusts the size of its microscopic pore structure so that hydrogen molecules can quickly migrate and stably be stored in the hydrate lattice, thereby improving the hydrogen storage density.

[0084] In the embodiment of the present disclosure and other possible embodiments, after hydrogen is filled into the inner tank 3 of the hydrogen storage bottle and enters the hydrogen hydrate generation stage, the hydrogen is discharged through the air inlet 13 at a rate of 10 standard cubic meters (Nm3) per minute. 3 / min) (set hydrogen inlet rate), slowly introduces hydrogen, and enters the inner tank 3 after being filtered by the gas filter 12, and contacts with the responsive hydrate builder 4 in the inner tank 3 of the hydrogen storage bottle. Real-time adjustment is made according to the set temperature curve T(t) and the set pressure curve P(t) to ensure uniform adsorption of hydrogen and stable formation of hydrates. The adaptive dynamic fuzzy logic hybrid controller raises the pressure of the inner tank 3 to the initial pressure value P0=10MPa, and starts to execute the rhythmic control strategy, so that the temperature and pressure of the inner tank 3 of the hydrogen storage bottle change synchronously according to the set temperature curve and the set pressure curve.

[0085] In the embodiment of the present disclosure and other possible embodiments, the temperature range of the inner tank 3 of the hydrogen storage bottle is T初始 -ΔT amp To T 初始 +ΔT amp The pressure range is P0-ΔP amp To P0+ΔP amp (8MPa to 12MPa). This periodic increase and decrease in temperature and pressure promotes the rapid adsorption of hydrogen in the material and the formation of hydrogen hydrates.

[0086] In the embodiments of the present disclosure and other possible embodiments, under rhythmic control, the molecular vibration frequency in the hydrate lattice of hydrogen hydrate matches the periodic changes in temperature and pressure of the inner tank 3 outside it, thereby enhancing the diffusion and embedding efficiency of hydrogen molecules in the hydrate lattice. At the same time, under rhythmic control, the responsive hydrate builder 4 in the inner tank 3 adjusts the size of its microscopic pore structure, so that hydrogen molecules can quickly migrate and stably store in the hydrate lattice, thereby improving the overall hydrogen storage density.

[0087] In an embodiment of the present disclosure, in the temperature rising and pressure reducing stage, a method for rhythmically controlling hydrate solid composite hydrogen storage control by regulating the temperature initial value of the set temperature curve and the pressure initial value of the set pressure curve comprises: after the hydrogen filling and hydrogen hydrate formation stage is completed, the temperature initial value of the set temperature curve in the hydrogen filling and hydrogen hydrate formation stage is increased to a first set temperature target value; the pressure initial value of the set pressure curve in the hydrogen filling and hydrogen hydrate formation stage is reduced to a first set pressure target value; under the rhythmic control of the set temperature curve corresponding to the first set temperature target value and the set pressure curve corresponding to the set pressure target value after configuration, the molecular vibration frequency in the hydrate lattice is caused to change, thereby optimizing the release and redistribution of hydrogen molecules.

[0088] In the embodiments of the present disclosure and other possible embodiments, during the temperature increase and pressure reduction stage, under the rhythmic control of the set temperature curve corresponding to the first set temperature target value and the set pressure curve corresponding to the set pressure target value after configuration, the pore structure inside the responsive hydrate builder in the hydrogen filling and hydrogen hydrate formation stage is fine-tuned to allow more hydrogen to enter the pores inside the responsive hydrate builder.

[0089] In the embodiment of the present disclosure and other possible embodiments, in the temperature increase and pressure reduction stage (second cycle pressure and temperature), the adaptive dynamic fuzzy logic hybrid controller comprehensively adjusts the refrigerant flow rate according to the temperature and pressure data of the temperature sensor 9 and the pressure sensor 10 to reduce the cooling intensity, and adjusts the temperature initial value T of the inner tank 3 of the hydrogen storage bottle. 初始The temperature of the inner tank 3 of the hydrogen storage bottle is maintained within the range of T 初始 -ΔT amp To T 初始 +ΔT amp At the same time, the adaptive dynamic fuzzy logic hybrid controller adjusts the hydrogen input of the air inlet 13, and reduces the initial temperature value P0 to the first set pressure target value (for example, to 8MPa), maintaining the pressure range of the inner tank 3 of the hydrogen storage bottle within P0-ΔP amp To P0+ΔP amp This is beneficial to fine-tune the pore structure inside the responsive hydrate builder 4, allowing more hydrogen to enter and further increase the hydrogen storage density. The adaptive dynamic fuzzy logic hybrid controller sets the hysteresis zone of temperature and pressure to prevent frequent switching of control modes and improve energy efficiency.

[0090] The slow rise in temperature and the gradual decrease in pressure cause the molecular vibration frequency in the hydrate lattice to change, optimizing the release and redistribution of hydrogen molecules. Responsive hydrate builder 4 enhances the dynamic balance of hydrogen molecules by fine-tuning the pore structure, improving the overall efficiency and stability of the hydrogen storage system.

[0091] In an embodiment of the present disclosure, during the cooling and pressurizing stage, a method for rhythmically controlling hydrate solid composite hydrogen storage control by regulating the temperature initial value of the set temperature curve and the pressure initial value of the set pressure curve comprises: after the temperature rising and pressure reducing stage is completed, the temperature initial value of the set temperature curve in the hydrogen filling and hydrogen hydrate formation stage is reduced from the first set temperature target value to the set initial temperature corresponding to the startup stage; the pressure initial value of the set pressure curve in the hydrogen filling and hydrogen hydrate formation stage is reduced from the first set pressure target value to the second set pressure target value; under the rhythmic control of the set temperature curve corresponding to the first set temperature target value and the set pressure curve corresponding to the set pressure target value after configuration, the incompletely reacted hydrogen is further converted into hydrogen hydrate.

[0092] In the embodiments of the present disclosure and other possible embodiments, during the cooling and pressurizing stage, under the rhythmic control of the set temperature curve corresponding to the first set temperature target value and the set pressure curve corresponding to the set pressure target value after configuration, the stability of the hydrate lattice is enhanced, the adsorption of the remaining hydrogen molecules and the further formation of hydrates are promoted, and the hydrate lattice vibration is more orderly, ensuring that the hydrogen molecules are effectively locked in the lattice structure.

[0093] In the embodiment of the present disclosure and other possible embodiments, in the cooling and pressurizing stage (the third cycle pressure and temperature), the adaptive dynamic fuzzy logic hybrid controller increases the refrigerant flow rate by adjusting the refrigerant inlet, and adjusts the initial value T of the temperature of the inner tank 3 of the hydrogen storage bottle. 初始 The temperature of the inner tank 3 of the hydrogen storage bottle is maintained within the range of T 初始 -ΔT amp To T 初始 +ΔT amp At the same time, the hydrogen input of the air inlet 13 is adjusted again, and the pressure of the inner tank 3 of the hydrogen storage bottle is maintained within the range of P0-ΔP by increasing the pressure from the first set pressure target value to the second set pressure target value (for example, to 12MPa). amp To P0+ΔP amp In between, the incompletely reacted hydrogen is further converted into hydrogen hydrate.

[0094] In the embodiment of the present disclosure and other possible embodiments, the adaptive dynamic fuzzy logic hybrid controller sets hysteresis zones for temperature and pressure to prevent frequent switching of control modes and improve energy efficiency.

[0095] In the embodiment of the present disclosure and other possible embodiments, the above two stages of heating and depressurizing and cooling and pressurizing constitute a cycle of pressure and temperature. According to the demand, the cycle of pressure and temperature can be repeated many times to make the amount of hydrogen adsorbed tend to saturation.

[0096] In the embodiments of the present disclosure and other possible embodiments, the further reduction of temperature and the increase of pressure strengthen the stability of the hydrate lattice, promote the adsorption of the remaining hydrogen molecules and the further formation of hydrates. The hydrate lattice vibration is more orderly under high pressure and low temperature conditions, ensuring that the hydrogen molecules are effectively locked in the lattice structure, and improving the density and safety of hydrogen storage.

[0097] In an embodiment of the present disclosure, the hydrate solid-state composite hydrogen storage control method is characterized in that it also includes: determining each of the temperature rise and pressure reduction stages and each of the cooling and pressurization stages as a cyclic pressure-temperature cycle; the method for determining the corresponding number of the cyclic pressure-temperature cycles includes: after each of the temperature rise and pressure reduction stages or each of the cooling and pressurization stages, obtaining the actual hydrogen storage capacity of the inner tank; if the actual hydrogen storage capacity reaches the set hydrogen storage capacity target and / or the preset maximum number of cycles corresponding to the set hydrogen storage capacity target, stopping the cyclic pressure-temperature cycle or stopping the temperature rise and pressure reduction stage or the cooling and pressurization stage, and entering the static pressure-temperature stage.

[0098] In an embodiment of the present disclosure, after each of the temperature rising and pressure reducing phases or each of the cooling and pressure increasing phases, the hydrogen storage capacity increment between this cycle and the previous cycle and the pressure increasing phases is calculated; if the hydrogen storage capacity increment is less than a set hydrogen storage capacity increment threshold and / or the actual hydrogen storage capacity of the inner tank reaches a set hydrogen storage capacity target and / or a preset maximum number of cycles corresponding to the set hydrogen storage capacity target, the cycle and the pressure increasing phases or the temperature rising and pressure reducing phases or the cooling and pressure increasing phases are stopped, and the static pressure and temperature phase is entered.

[0099] In the embodiments of the present disclosure and other possible embodiments, for the cyclic pressure-temperature cycle, the temperature increase and pressure reduction stage and the cooling and pressure increase stage constitute a cyclic pressure-temperature cycle. According to demand, the cyclic pressure-temperature cycle can be repeated multiple times to make the amount of hydrogen adsorbed by the hydrate lattice approach a saturated state to form hydrogen hydrates.

[0100] In the embodiments of the present disclosure and other possible embodiments, multiple pressure-temperature cycles gradually improve the overall hydrogen storage capacity of the hydrogen storage system by continuously optimizing the structure of the hydrate lattice and the distribution of hydrogen molecules in the structure of the hydrate lattice. Each cycle promotes the rearrangement and optimization of the hydrate lattice, ensuring the efficient embedding and stable storage of hydrogen molecules in the structure of the hydrate lattice.

[0101] In the embodiments of the present disclosure and other possible embodiments, the basis for controlling the number of cycles is hydrogen adsorption saturation: by real-time monitoring of the pressure and temperature changes of the inner tank 3, it is determined whether the hydrogen adsorption has reached a saturated state. After multiple cycles of pressure and temperature, the amount of hydrogen adsorption tends to be stable, and the fluctuation amplitude of the pressure and temperature of the inner tank 3 is reduced, which means that the saturation state is reached and the circulation is stopped. System performance indicators: set a hydrogen storage capacity target. When the actual hydrogen storage capacity of the inner tank 3 in the system reaches more than 95% of the design capacity (that is, the set hydrogen storage capacity target), stop the pressure and temperature circulation. By regularly detecting the set hydrogen storage capacity target corresponding to the adsorption performance of the responsive hydrate builder 4, it is ensured that its pore structure has been fully utilized. Preset value of the number of cycles: according to experimental data and system design analysis, set a preset maximum number of cycles corresponding to the hydrogen storage capacity target (such as 10 times) to prevent excessive cycling from causing system fatigue or material damage. When the preset number of cycles or saturation is reached, the circulation is automatically stopped. Energy efficiency considerations: monitor the energy consumption of each cycle. When the increase in hydrogen storage between the current cycle and the previous cycle is less than the set hydrogen storage increase threshold during the cycle, stop the cycle to optimize the overall energy efficiency of the system.

[0102] In an embodiment of the present disclosure, during the hydrogen release stage, a method for rhythmically controlling the hydrate solid-state composite hydrogen storage control by regulating the temperature initial value of the set temperature curve and the pressure initial value of the set pressure curve comprises: increasing the set static maintenance temperature of the static pressure-temperature stage in the hydrate solid-state composite hydrogen storage control process to a second set temperature target value corresponding to the temperature initial value of the set temperature curve; reducing the set static maintenance pressure of the static pressure-temperature stage in the hydrate solid-state composite hydrogen storage control process to a third set pressure target value corresponding to the pressure initial value of the set temperature curve; under the rhythmic control of the set temperature curve corresponding to the third set temperature target value and the set pressure curve corresponding to the third set pressure target value after configuration, the structure of the hydrate lattice is loosened, the vibration frequency of the hydrogen molecules is changed, and the hydrogen molecules in the hydrate lattice are deintercalated and released into the gas phase.

[0103] In the embodiments of the present disclosure and other possible embodiments, in the hydrogen release stage (the reverse process of the cycle pressure and temperature), when hydrogen needs to be released, the reverse process of the cycle pressure and temperature is started, and the hydrogen hydrate is decomposed and hydrogen is released by periodically adjusting the temperature and pressure.

[0104] In the embodiment of the present disclosure and other possible embodiments, the adaptive dynamic fuzzy logic hybrid controller reduces the refrigerant flow rate so that the initial value T of the temperature of the inner tank 3 is 初始 Gradually increase the temperature to the second set temperature target value (such as 5°C), and maintain the temperature of the inner tank 3 of the hydrogen storage bottle within the range of T 初始 -ΔT amp To T 初始 +ΔT amp between, thereby reducing the stability of hydrogen hydrates.

[0105] In the embodiment of the present disclosure and other possible embodiments, while the temperature is rising, the adaptive dynamic fuzzy logic hybrid controller adjusts the air inlet 14 to reduce the temperature initial value P0 to the third set pressure target value (such as reduced to 8Mpa), maintaining the pressure range of the inner tank 3 of the hydrogen storage bottle within P0-ΔP amp To P0+ΔP amp In between, the hydrogen hydrate gradually decomposes and releases hydrogen.

[0106] In the embodiment of the present disclosure and other possible embodiments, the temperature increase and pressure reduction process is repeated according to the hydrogen demand, and hydrogen is released in stages to ensure that hydrogen hydrates are decomposed in a safe state.

[0107] In the embodiments of the present disclosure and other possible embodiments, the increase in temperature and the decrease in pressure cause the structure of the hydrate lattice to loosen, and the vibration frequency of the hydrogen molecules changes, which prompts the hydrogen molecules in the hydrate lattice to be deintercalated and released into the gas phase. The responsive hydrate builder 4 adjusts its pore structure, optimizes the deintercalation path of the hydrogen molecules, improves the efficiency and controllability of hydrogen release, and ensures the safe operation of the system.

[0108] In an embodiment of the present disclosure, in at least one of the hydrogen filling and hydrogen hydrate formation stage, the temperature increase and pressure reduction stage, the cooling and pressurization stage, and the hydrogen release stage, a rhythmic control method for hydrate solid composite hydrogen storage control is performed by regulating the temperature initial value of the set temperature curve and the pressure initial value of the set pressure curve, and also includes: real-time calculation of the temperature deviation between the temperature of the inner tank and the set temperature corresponding to the set temperature curve after the temperature initial value is configured; real-time calculation of the pressure deviation between the pressure of the inner tank and the set pressure corresponding to the set pressure curve after the pressure initial value is configured; according to a set fuzzy rule set, respectively determining the temperature deviation level and the pressure deviation level corresponding to the temperature deviation; based on the temperature deviation level and the pressure deviation level, regulating the current refrigerant flow rate corresponding to the cooling conduit entering the inner tank or entering the outside of the inner tank and the hydrogen flow corresponding to the filling of the inner tank.

[0109] In an embodiment of the present disclosure, the method for regulating the current refrigerant flow rate corresponding to the cooling duct entering the inner tank or entering the outer side of the inner tank and the corresponding hydrogen flow rate filled into the inner tank based on the temperature deviation level and the pressure deviation level includes: the temperature deviation level includes: a first temperature deviation level corresponding to the highest level, a second temperature deviation level lower than the first temperature deviation level, and a third temperature deviation level lower than the second temperature deviation level; the pressure deviation level includes: a first pressure deviation level corresponding to the highest level, a second pressure deviation level lower than the first pressure deviation level, and a third pressure deviation level lower than the second pressure deviation level; wherein, if the temperature deviation level is the first temperature deviation level, the refrigerant flow is increased. The current refrigerant flow rate corresponding to the cooling duct entering the inner tank or entering the outer side of the inner tank; if the temperature deviation level is the second temperature deviation level, the current refrigerant flow rate corresponding to the refrigerant flow entering the inner tank or entering the cooling duct outside the inner tank is maintained; if the temperature deviation level is the third temperature deviation level, the current refrigerant flow rate corresponding to the refrigerant flow entering the inner tank or entering the cooling duct outside the inner tank is reduced; wherein, if the pressure deviation level is the first pressure deviation level, the corresponding hydrogen flow rate filled into the inner tank is increased; if the pressure deviation level is the second pressure deviation level, the corresponding hydrogen flow rate filled into the inner tank is maintained; if the pressure deviation level is the third pressure deviation level, the corresponding hydrogen flow rate filled into the inner tank is reduced.

[0110] In the embodiments of the present disclosure and other possible embodiments, the adaptive dynamic fuzzy logic hybrid controller of the present invention proposes an adaptive dynamic fuzzy logic hybrid control algorithm, which innovatively introduces a circular chaotic feedback mechanism. The algorithm combines dual-mode control with a hysteresis zone, a dynamic adaptive mechanism, and a circular chaotic feedback optimized for rhythmic control to achieve precise regulation of the pressure and temperature of the inner tank, dynamically respond to hydrogen storage requirements under different working conditions, and significantly improve hydrogen storage efficiency and system stability.

[0111] In the embodiment of the present disclosure and other possible embodiments, the adaptive dynamic fuzzy logic hybrid control algorithm includes: a fuzzy logic control module, a hysteresis zone dual-mode control module, and a ring chaos feedback module.

[0112] In the embodiment of the present disclosure and other possible embodiments, for the fuzzy logic control module, the temperature deviation (e T ): indicates the current temperature T current With the target temperature T target (The temperature deviation of the set temperature curve corresponding to the set temperature).

[0113] e T =T current -Ttarget

[0114] Among them, e T is the temperature deviation; T current is the current temperature; T target Set the temperature curve corresponding to the target temperature).

[0115] In the embodiment of the present disclosure and other possible embodiments, for the fuzzy logic control module, the pressure deviation (e P ): indicates the current pressure P current With target pressure P target (The pressure deviation of the set pressure curve corresponding to the set pressure).

[0116] e P =P current -P target

[0117] Among them, e P is the pressure deviation; P current is the current pressure; P target is the target pressure (the set pressure corresponding to the set pressure curve).

[0118] In the embodiment of the present disclosure and other possible embodiments, for the fuzzy logic control module, according to the pressure deviation e T and pressure deviation e P The temperature deviation and pressure deviation are divided into different fuzzy rule sets, such as "high" (first temperature deviation level), "medium" (first temperature deviation level), and "low" (first temperature deviation level) corresponding to the temperature deviation, and "high" (first pressure deviation level), "medium" (first pressure deviation level), and "low" (first pressure deviation level) corresponding to the pressure deviation, and the control output is generated according to the set fuzzy rule set (fuzzy logic control rule set). The following is an example of a fuzzy rule set:

[0119] If e T is "high" and e P If the current refrigerant flow rate is "high", the corresponding hydrogen flow rate to the inner tank 3 is increased. T is "high" and e P If the current refrigerant flow rate is "medium", the corresponding hydrogen flow rate into the inner tank 3 is increased. P is "high" and e P If the current refrigerant flow rate is "low", the corresponding hydrogen flow rate when filling the inner tank 3 is increased. T is "medium" and e P If the current refrigerant flow rate is maintained and the corresponding hydrogen flow rate into the inner tank 3 is increased. T is "medium" and eP If the value is "Medium", the current refrigerant flow rate and the corresponding hydrogen flow rate currently charged into the inner tank 3 are maintained. T is "medium" and e P If the current refrigerant flow rate is "low", the current hydrogen flow rate corresponding to the current filling of the inner tank 3 is reduced. T is "low" and e P If the current refrigerant flow rate is "high", the current refrigerant flow rate is reduced and the corresponding flow rate into the inner tank 3 is increased. T is "low" and e P If the current refrigerant flow rate is "medium", the current refrigerant flow rate is reduced and the corresponding hydrogen flow rate currently charged into the inner tank 3 is maintained. T is "low" and e p If the value is "low", the current refrigerant flow rate is reduced and the corresponding hydrogen flow rate currently charged into the inner tank 3 is reduced. These rules ensure that the system can maintain a stable control effect under different temperature and pressure conditions.

[0120] In an embodiment of the present disclosure, in at least one of the hydrogen filling and hydrogen hydrate formation stage, the temperature rising and pressure reducing stage, the cooling and pressurizing stage, and the hydrogen release stage, a rhythmic control method for hydrate solid composite hydrogen storage is performed by regulating the temperature initial value of the set temperature curve and the pressure initial value of the set pressure curve, and also includes: increasing or decreasing the current refrigerant flow rate corresponding to the cooling conduit entering the inner tank or entering the outside of the inner tank while maintaining the temperature corresponding to the inner tank at the set temperature corresponding to the set temperature curve.

[0121] In an embodiment of the present disclosure, the method of increasing or decreasing the current refrigerant flow rate corresponding to the refrigerant flow entering the inner tank or entering the cooling conduit outside the inner tank in the process of maintaining the temperature corresponding to the inner tank at the set temperature of the set temperature curve includes: obtaining a first set temperature deviation threshold, a second set temperature deviation threshold, and a temperature deviation between the temperature corresponding to the inner tank and the set temperature of the set temperature curve; determining the corresponding first temperature hysteresis zone based on the first set temperature deviation threshold and the second set temperature deviation threshold; if the temperature deviation is outside the first temperature hysteresis zone, increasing the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank at a first set rate or reducing the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank; if the temperature deviation is within the first temperature hysteresis zone, increasing the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank at a second set rate less than the first set rate or reducing the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank or maintaining the current set rate corresponding to the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank.

[0122] In an embodiment of the present disclosure, if the temperature deviation is within the first temperature hysteresis zone, the method of increasing the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank at a second set rate that is less than the first set rate, or reducing the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank, or maintaining the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank corresponding to the current set rate includes: a third set temperature deviation threshold value that is less than the first set temperature deviation threshold value and a fourth set temperature deviation threshold value that is greater than the second set temperature deviation threshold value; based on the third set temperature deviation threshold value The set temperature deviation threshold and the fourth set temperature deviation threshold determine the corresponding second temperature hysteresis zone; if the temperature deviation is within the first temperature hysteresis zone, determine whether the deviation is within the second temperature hysteresis zone; if the deviation is within the second temperature hysteresis zone, maintain the current set rate corresponding to the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank; otherwise, increase the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank at a second set rate that is less than the first set rate, or decrease the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank.

[0123] In an embodiment of the present disclosure, in at least one of the hydrogen filling and hydrogen hydrate formation stage, the temperature increase and pressure reduction stage, the cooling and pressurization stage, and the hydrogen release stage, a rhythmic control method for hydrate solid-state composite hydrogen storage is performed by regulating the temperature initial value of the set temperature curve and the pressure initial value of the set pressure curve, and also includes: increasing or decreasing the hydrogen flow rate of the hydrogen flow corresponding to the hydrogen flow filled into the inner tank while maintaining the pressure corresponding to the inner tank at the set pressure corresponding to the set pressure curve.

[0124] In an embodiment of the present disclosure, the method for increasing or decreasing the flow rate of hydrogen corresponding to the inner tank while maintaining the pressure corresponding to the inner tank at the set pressure of the set pressure curve includes: obtaining a first set pressure deviation threshold, a second set pressure deviation threshold, and a pressure deviation between the pressure corresponding to the inner tank and the set pressure of the set pressure curve; determining a corresponding first pressure hysteresis zone based on the first set pressure deviation threshold and the second set pressure deviation threshold; if the pressure deviation is outside the first pressure hysteresis zone, increasing the flow rate of hydrogen filled into the inner tank at a first set rate or decreasing the flow rate of hydrogen filled into the inner tank; if the pressure deviation is within the first pressure hysteresis zone, increasing the flow rate of hydrogen filled into the inner tank at a second set rate that is less than the first set rate or decreasing the flow rate of hydrogen filled into the inner tank or maintaining the flow rate of hydrogen connected to the inner tank.

[0125] In an embodiment of the present disclosure, if the pressure deviation is within the first pressure hysteresis zone, the method for increasing the hydrogen flow rate filled into the inner tank connection at a second set rate that is less than the first set rate or reducing the hydrogen flow rate filled into the inner tank connection or maintaining the hydrogen flow rate of the inner tank connection includes: a third set pressure deviation threshold that is less than the first set pressure deviation threshold and a fourth set pressure deviation threshold that is greater than the second set pressure deviation threshold; determining the corresponding second pressure hysteresis zone based on the third set pressure deviation threshold and the fourth set pressure deviation threshold; if the pressure deviation is within the first pressure hysteresis zone, determining whether the deviation is within the second pressure hysteresis zone; if the deviation is within the second pressure hysteresis zone, maintaining the hydrogen flow rate of the inner tank connection; otherwise, increasing the hydrogen flow rate filled into the inner tank connection or reducing the hydrogen flow rate filled into the inner tank connection at a second set rate that is less than the first set rate.

[0126] In the embodiments of the present disclosure and other possible embodiments, those skilled in the art can configure the first set temperature deviation threshold, the second set temperature deviation threshold, the third set temperature deviation threshold, and the fourth set temperature deviation threshold according to actual needs. Similarly, those skilled in the art can configure the first set pressure deviation threshold, the second set pressure deviation threshold, the third set pressure deviation threshold, and the fourth set pressure deviation threshold according to actual needs.

[0127] For example, the first set temperature deviation threshold and the second set temperature deviation threshold are configured as 1°C and -1°C, respectively. The third set temperature deviation threshold and the fourth set temperature deviation threshold are configured as 0.5°C and -0.5°C, respectively. The first set pressure deviation threshold and the second set pressure deviation threshold are configured as 1Mpa and -1Mpa, respectively. The third set pressure deviation threshold and the fourth set pressure deviation threshold are configured as 0.5Mpa and -0.5Mpa, respectively.

[0128] In an embodiment of the present disclosure, the hydrate solid composite hydrogen storage control process also includes: a startup phase; during the startup phase, obtaining the temperature corresponding to the inner tank in real time; adjusting the temperature corresponding to the inner tank to a set initial temperature, and maintaining the set initial temperature corresponding to the inner tank.

[0129] In an embodiment of the present disclosure, the hydrate solid composite hydrogen storage control process also includes: a startup phase; in the startup phase, the refrigerant flow regulating valve connected to the inner tank or the cooling duct entering the outside of the inner tank and the refrigerant flow is controlled to open, and the temperature corresponding to the inner tank is obtained in real time; the temperature corresponding to the inner tank is adjusted to the set initial temperature, and the set initial temperature corresponding to the inner tank is maintained.

[0130] In the embodiments of the present disclosure and other possible embodiments, during the device preparation and cooling system startup phase, refrigerant is injected through the refrigerant inlet 6, and the refrigerant circulates in the cooling duct 5 to control the temperature inside the inner tank 3 in the hydrogen storage bottle. The adaptive dynamic fuzzy logic hybrid controller monitors the temperature and pressure data of the temperature sensor 9 and the pressure sensor 10 in real time, and automatically adjusts the flow rate of the refrigerant injected through the refrigerant inlet 6 to keep the inner tank 3 at the initial low temperature / initial temperature (e.g., -5°C) state. This process ensures that the environment inside the inner tank 3 of the hydrogen storage bottle is suitable for the adsorption of hydrogen and the formation of hydrogen hydrates. At the same time, the rhythm parameters of the temperature curve and the pressure curve are set, such as the amplitude ΔT of the temperature curve. amp = 2℃ and set the frequency f of the temperature curve T =0.005Hz, and set the amplitude of the pressure curve ΔP_amp=2MPa, set the frequency of the pressure curve f P =0.005Hz.

[0131] In an embodiment of the present disclosure, the hydrate solid composite hydrogen storage control process also includes: a static pressure and temperature stage; in the static pressure and temperature stage, the temperature and pressure corresponding to the inner tank are obtained in real time; the temperature corresponding to the inner tank is maintained at a set static maintenance temperature or below the set static maintenance temperature; the pressure corresponding to the inner tank is maintained at a set static maintenance pressure or above the set static maintenance pressure.

[0132] In the embodiments of the present disclosure and other possible embodiments, during hydrogen storage and heat preservation (static pressure and temperature stage), after hydrogen is completely adsorbed, the system enters the hydrogen storage and heat preservation stage, at which the inner tank 3 in the hydrogen storage bottle is kept at a low temperature (set static maintenance temperature, below -1°C) and high pressure (set static maintenance pressure, above 10Mpa) to stabilize the hydrogen hydrate structure and prevent hydrogen release. The operations in this stage are as follows:

[0133] In the embodiment of the present disclosure and other possible embodiments, the refrigerant maintains the temperature of the inner tank 3 at -5°C through the cooling duct 5, and the adaptive dynamic fuzzy logic hybrid controller fine-tunes the refrigerant flow rate in the hysteresis zone to ensure a low temperature environment.

[0134] In the embodiments of the present disclosure and other possible embodiments, under static pressure and temperature conditions, the hydrate lattice structure remains stable, and hydrogen molecules are firmly embedded in the pores of the lattice. The lattice vibration frequency matches the external environment, ensuring the dynamic balance of hydrogen molecules, preventing unnecessary hydrogen release, and improving the safety of the system and hydrogen storage efficiency.

[0135] In an embodiment of the present disclosure, the hydrate solid composite hydrogen storage control process also includes: a final pressure relief and shutdown stage; in the final pressure relief and shutdown stage, the pressure in the inner tank is reduced to a set pressure relief and shutdown pressure by using a set decompression rate.

[0136] In an embodiment of the present disclosure, during the final pressure relief and shutdown stage, it also includes: controlling the refrigerant flow regulating valve connected to the inner tank or the cooling duct entering the outside of the inner tank and the refrigerant flow to close, and controlling the hydrogen flow regulating valve connected to the inner tank and the hydrogen flow to close; when the pressure in the inner tank is reduced to the set pressure relief and shutdown pressure and the corresponding temperature of the inner tank returns to the ambient temperature, the status mark of the hydrate solid composite hydrogen storage control process is configured to standby.

[0137] In the embodiment of the present disclosure and other possible embodiments, during the final depressurization and shutdown phase, the adaptive dynamic fuzzy logic hybrid controller performs the following steps to ensure that all hydrogen is safely released.

[0138] In the embodiments of the present disclosure and other possible embodiments, the adaptive dynamic fuzzy logic hybrid controller slowly reduces the set pressure relief and shutdown pressure (3-5Mpa) of the inner tank 3, and adopts a preset set pressure reduction rate (such as 1MPa per minute) to avoid safety accidents caused by rapid pressure relief. During the decompression process, the refrigerant flow rate continues to be adjusted to maintain a suitable temperature change rate to prevent temperature fluctuations caused by excessive decomposition of hydrates. The inner tank pressure is monitored in real time by the pressure sensor 10 to ensure that the pressure gradually drops to the ambient pressure.

[0139] In the embodiments of the present disclosure and other possible embodiments, after the final pressure relief is completed, the adaptive dynamic fuzzy logic hybrid controller performs the shutdown steps as follows: the adaptive dynamic fuzzy logic hybrid controller closes the refrigerant flow regulating valve to stop the circulation of the refrigerant. Ensure that the temperature of the inner tank 3 gradually returns to the ambient temperature, and avoid structural stress caused by rapid temperature changes through the heat dissipation of the remaining refrigerant. Confirm that the pressure of the inner tank 3 has dropped to the ambient pressure to ensure that the system is in a safe state. The system automatically performs the final pressure and temperature detection to ensure that all parameters are restored to the initial state. The adaptive dynamic fuzzy logic hybrid controller marks the system state as standby and prepares for the next operation. Reset the temperature sensor 9, pressure sensor 10 data and the adaptive dynamic fuzzy logic hybrid controller parameters to ensure that the system is in a predetermined initial state when it is run next time.

[0140] During the final depressurization process, the hydrate lattice gradually returns to the state before the hydrogen filling and hydrogen hydrate formation stage, and the vibration frequency of the lattice structure returns to stability, ensuring that all hydrogen molecules have been safely released. The pore structure of the responsive hydrate builder 4 returns to its original state, preparing for the next hydrogen adsorption and storage process.

[0141] In an embodiment of the present disclosure, the method for maintaining the temperature corresponding to the inner tank at a set static maintenance temperature or below the set static maintenance temperature includes: obtaining a first set temperature deviation threshold, a second set temperature deviation threshold, and a temperature deviation between the temperature corresponding to the inner tank and the set static maintenance temperature; determining a corresponding first temperature hysteresis zone based on the first set temperature deviation threshold and the second set temperature deviation threshold; if the temperature deviation is outside the first temperature hysteresis zone, increasing the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank at a first set rate or reducing the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank; if the temperature deviation is within the first temperature hysteresis zone, increasing the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank at a second set rate less than the first set rate or reducing the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank or maintaining the current set rate corresponding to the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank.

[0142] In an embodiment of the present disclosure, if the temperature deviation is within the first temperature hysteresis zone, the method of increasing the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank at a second set rate that is less than the first set rate, or reducing the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank, or maintaining the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank corresponding to the current set rate includes: a third set temperature deviation threshold value that is less than the first set temperature deviation threshold value and a fourth set temperature deviation threshold value that is greater than the second set temperature deviation threshold value; based on the third set temperature deviation threshold value The set temperature deviation threshold and the fourth set temperature deviation threshold determine the corresponding second temperature hysteresis zone; if the temperature deviation is within the first temperature hysteresis zone, determine whether the deviation is within the second temperature hysteresis zone; if the deviation is within the second temperature hysteresis zone, maintain the current set rate corresponding to the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank; otherwise, increase the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank at a second set rate that is less than the first set rate, or decrease the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank.

[0143] In the embodiments of the present disclosure and other possible embodiments, those skilled in the art may configure the first set temperature deviation threshold, the second set temperature deviation threshold, the third set temperature deviation threshold, and the fourth set temperature deviation threshold according to actual needs. For example, the first set temperature deviation threshold and the second set temperature deviation threshold are configured to 1°C and -1°C, respectively. Among them, the third set temperature deviation threshold and the fourth set temperature deviation threshold are configured to 0.5°C and -0.5°C, respectively.

[0144] In the embodiments of the present disclosure and other possible embodiments, for the hysteresis zone dual-mode control module, a hysteresis zone design is added to the control output to avoid frequent adjustments in small fluctuations and improve system stability.

[0145] Coarse adjustment mode: When the temperature deviation is T When the temperature deviation is greater (exceeding the set first temperature hysteresis zone), the system enters the coarse adjustment mode and rapidly increases the refrigerant flow rate at the first set rate (temperature deviation e T Less than 0) or quickly reduce the refrigerant flow rate (temperature deviation e T greater than 0), to achieve fast response.

[0146] Fine adjustment mode: When the temperature deviation T When the temperature deviation is smaller (within the first temperature hysteresis zone and outside the second temperature hysteresis zone), the system enters the fine adjustment mode, fine-tunes the refrigerant flow rate, and slowly increases the refrigerant flow rate at a second set rate that is smaller than the first set rate (temperature deviation e T Less than 0) or slowly reduce the refrigerant flow rate (temperature deviation e T greater than 0) to ensure control accuracy.

[0147] The threshold value of the first temperature hysteresis zone is set as:

[0148] ΔT hysteresis1 = ±1℃;

[0149] e T =T 当前 -T 目标

[0150] Where, ΔT hysteresis1 is the first temperature hysteresis zone; ΔT 当前 is the current temperature (the temperature corresponding to the inner tank); T 目标 It is the set static maintenance temperature corresponding to the target set temperature or the set temperature of the set temperature curve corresponding to the current temperature.

[0151] ΔT hysteresis2 = ±0.5℃;

[0152] Where, ΔThysteresis2 It is the second temperature hysteresis zone.

[0153] When e T When in the second temperature hysteresis zone, the system maintains the current mode unchanged to avoid frequent switching.

[0154] Coarse adjustment mode: When the pressure deviation e P When the pressure difference is larger (exceeding the set first pressure hysteresis zone), the system enters the coarse adjustment mode and rapidly increases the hydrogen flow rate corresponding to the inner tank at the first set rate (pressure deviation e P less than 0) or quickly reduce the hydrogen flow rate corresponding to the inner tank (pressure deviation e P greater than 0), to achieve fast response.

[0155] Fine adjustment mode: When the pressure deviation e_P is small (within the first pressure hysteresis zone and outside the second pressure hysteresis zone), the system enters the fine adjustment mode, fine-tunes the refrigerant flow rate, and slowly increases the hydrogen flow rate corresponding to the inner tank at a second set rate that is smaller than the first set rate (pressure deviation e_P). P less than 0) or slowly reduce the hydrogen flow rate corresponding to the inner tank (pressure deviation e P greater than 0) to ensure control accuracy.

[0156] The threshold value of the first pressure hysteresis zone is set as:

[0157] ΔP hysteresis1 = ±0.1MPa

[0158] ΔP hysteresis =P 当前 -P 目标

[0159] ΔP hysteresis1 is the first pressure hysteresis zone; P 当前 is the current pressure (the pressure corresponding to the inner tank); P 目标 The target set pressure (the set pressure of the pressure-temperature curve corresponding to the current temperature.

[0160] ΔP hysteresis2 = ±0.5MPa

[0161] Among them, ΔP hysteresis2 It is the second pressure hysteresis zone.

[0162] When e p When in the second pressure hysteresis zone, the system maintains the current mode unchanged to avoid frequent switching.

[0163] In an embodiment of the present disclosure, in at least one of the hydrogen filling and hydrogen hydrate formation stage, the temperature rising and pressure reducing stage, the cooling and pressurizing stage, and the hydrogen release stage, the hydrate solid-state composite hydrogen storage control is rhythmically controlled by regulating the temperature initial value of the set temperature curve and the pressure initial value of the set pressure curve, and also includes: generating corresponding first rhythmic chaotic signals and second rhythmic chaotic signals based on the first periodic function corresponding to the set temperature curve and the second periodic function corresponding to the set pressure curve, respectively; constructing a set temperature rhythmic chaotic curve corresponding to the set temperature curve based on the temperature initial value and the first rhythmic chaotic signal; constructing a set pressure rhythmic chaotic curve corresponding to the set temperature curve based on the pressure initial value and the second rhythmic chaotic signal; and then, the hydrate solid-state composite hydrogen storage control is rhythmically controlled by regulating the temperature initial value of the set temperature rhythmic chaotic curve and the pressure initial value of the set pressure rhythmic chaotic curve.

[0164] In the embodiment of the present disclosure and other possible embodiments, for the ring chaotic feedback module, the signal can adapt to the periodic requirements of rhythmic control while maintaining rich dynamic change information.

[0165] The mathematical expression of the Lorentz map is:

[0166]

[0167] Among them, σ, ρ, β are system parameters; x n ,y n 、z n is the current state variable of the chaotic sequence; x n+1 ,y n+1 、z n+1 is the state variable of the chaotic sequence at the next moment.

[0168] In the embodiment of the present disclosure and other possible embodiments, for the rhythmic chaotic signal generation and integration, a series of x n ,y n 、z n , these variables constitute the chaotic sequence M i (n).

[0169] In the embodiment of the present disclosure and other possible embodiments, the rhythmic chaotic signal generation formula is:

[0170]

[0171] Where N is the number of chaotic mapping paths; k i is the weight coefficient of the i-th path; M i(n) is the chaotic signal generated by the i-th path; ω i is the rhythm frequency of the i-th path; φ i is the initial phase of the ith path.

[0172] For example, in at least one of the hydrogen charging and hydrogen hydrate formation stage, the temperature increase and pressure reduction stage, the cooling and pressure increase stage, and the hydrogen release stage, the temperature initial value T of the set temperature curve is adjusted. 初始 and the pressure initial value P0 or (P0+2) of the set pressure curve to perform rhythmic control on the hydrate solid composite hydrogen storage control, and further comprising: respectively based on the first periodic function ΔT corresponding to the set temperature curve amp ·sin(2πf T t) and the second periodic function ΔP corresponding to the set pressure curve amp ·sin(2πf P t) Generate a corresponding first rhythmic chaotic signal C 混沌1 And the second chaotic signal C 混沌2 ; Based on the temperature initial value and the first rhythmic chaotic signal, a set temperature rhythmic chaotic curve corresponding to the set temperature curve is constructed; based on the pressure initial value and the second rhythmic chaotic signal, a set pressure rhythmic chaotic curve corresponding to the set temperature curve is constructed; and then, the hydrate solid-state composite hydrogen storage control is rhythmically controlled by regulating the temperature initial value of the set temperature rhythmic chaotic curve and the pressure initial value of the set pressure rhythmic chaotic curve.

[0173] The first rhythmic chaotic signal C 混沌1 :

[0174]

[0175] Where N1 is the number of paths in the first chaotic mapping; k1 i is the first weight coefficient of the i-th path; M 1i (n) is the first chaotic signal generated by the i-th path; ω1 i is the first rhythm frequency of the i-th path; φ1 i is the first initial phase of the i-th path.

[0176] The second rhythmic chaotic signal C 混沌2 :

[0177]

[0178] Where N2 is the number of paths in the second chaotic map; k2 i is the second weight coefficient of the i-th path; M i (n) is the second chaotic signal generated by the i-th path; ω2i is the second rhythm frequency of the i-th path; φ2 i is the second initial phase of the i-th path.

[0179] The set temperature rhythmic chaotic curve configuration corresponding to the set temperature curve is constructed based on the temperature initial value and the first rhythmic chaotic signal:

[0180]

[0181] The set pressure rhythmic chaotic curve corresponding to the set temperature curve is constructed based on the initial pressure value and the second rhythmic chaotic signal as follows:

[0182]

[0183] or,

[0184]

[0185] The execution subject of the hydrate solid composite hydrogen storage control method may be a hydrate solid composite hydrogen storage control system or device, for example, the hydrate solid composite hydrogen storage control method may be executed by a terminal device or a server or other processing device, wherein the terminal device may be a user equipment (UE), a mobile device, a user terminal, a terminal, a cellular phone, a cordless phone, a personal digital assistant (PDA), a handheld device, a computing device, a vehicle-mounted device, a wearable device, etc. In some possible implementations, the hydrate solid composite hydrogen storage control method may be implemented by a processor calling a computer-readable instruction stored in a memory.

[0186] Those skilled in the art will understand that in the above-mentioned hydrate solid composite hydrogen storage control method in a specific embodiment, the writing order of each step does not mean a strict execution order and does not constitute any limitation on the implementation process. The specific execution order of each step should be determined by its function and possible internal logic.

[0187] The embodiment of the present disclosure also proposes a hydrate solid composite hydrogen storage control system, including: an acquisition unit, used to acquire a set temperature curve and a set pressure curve corresponding to the inner tank where the hydrogen hydrate is located; wherein the set temperature curve and / or the set pressure curve are configured as a periodic curve; a determination unit, used to determine at least one of the hydrogen filling and hydrogen hydrate generation stages, the temperature rise and pressure reduction stage, the cooling and pressurization stage, and the hydrogen release stage in the hydrate solid composite hydrogen storage control process; a control unit, used to perform rhythmic control of the hydrate solid composite hydrogen storage control using the set temperature curve and the set pressure curve in at least one of the hydrogen filling and hydrogen hydrate generation stages, the temperature rise and pressure reduction stage, the cooling and pressurization stage, and the hydrogen release stage. This is to solve at least one of the technical problems of harsh generation conditions, kinetic limitations, insufficient material optimization, limited control accuracy, and the fact that the existing technology for regulating temperature and pressure mostly relies on a single constant condition and is difficult to dynamically respond to complex working conditions, resulting in excessive energy consumption and low efficiency.

[0188] An embodiment of the present disclosure also proposes a hydrate solid-state composite hydrogen storage control system, comprising: a processor; a memory for storing processor executable instructions; wherein the processor is configured to call the instructions stored in the memory to execute the above-mentioned hydrate solid-state composite hydrogen storage control method.

[0189] The embodiments of the present disclosure also propose a hydrate solid-state composite hydrogen storage control system, comprising: a computer-readable storage medium having computer program instructions stored thereon, wherein the computer program instructions implement the above-mentioned hydrate solid-state composite hydrogen storage control method when executed by a processor.

[0190] The embodiments of the present disclosure also provide a hydrate solid-state composite hydrogen storage control system, including: a computer program product, on which a computer program / instruction is configured, and when the computer program / instruction is executed by a processor, the above-mentioned hydrate solid-state composite hydrogen storage control method is implemented.

[0191] The embodiment of the present disclosure also proposes a hydrate solid composite hydrogen storage control system, comprising: an inner tank 3; a cooling conduit 5 is arranged on the outer side of the inner tank 3, and the inner tank 3 is also connected to a hydrogen source; the inner tank 3 is provided with a temperature sensor 9 and a pressure sensor 10 for detecting the temperature and pressure in the inner tank 3; wherein the inner tank 3 is filled with a responsive hydrate builder 4 for accommodating hydrogen hydrates; in at least one of the hydrogen filling and hydrogen hydrate generation stages, the temperature increase and pressure reduction stage, the cooling and pressurization stage, and the hydrogen release stage in the hydrate solid composite hydrogen storage control process, the refrigerant flow in the cooling conduit 5 and the hydrogen flow from the hydrogen source entering the inner tank 3 are used to rhythmically control the temperature and pressure in the inner tank 3 detected by the pressure temperature sensor 9 and the pressure sensor 10 by adjusting the temperature initial value of the periodic set temperature curve and the pressure initial value of the periodic set pressure curve, so as to adjust the microscopic pore structure of the responsive hydrate builder and / or the vibration of the hydrate lattice of the hydrogen hydrate.

[0192] In the embodiment of the present disclosure, it also includes: a heat-insulating and anti-seepage composite layer 2 arranged on the outside of the inner tank 3 or the cooling duct 5; wherein the cooling duct 5 is configured as a coil structure; wherein the cooling duct 5 of the coil structure is coiled on the outside of the cooling duct 5; wherein one end of the cooling duct 5 is provided with a refrigerant inlet 6 connected to a refrigerant source, and the other end of the cooling duct 5 is provided with a refrigerant outlet 7.

[0193] In the embodiments of the present disclosure and other possible embodiments, it also includes: a shell 1, which uses aluminum alloy, carbon fiber composite material, titanium alloy, magnesium alloy, etc. as the external protective layer of the hydrogen storage bottle, provides good mechanical strength and pressure resistance, and resists corrosive gases in the external environment.

[0194] In the embodiment of the present disclosure and other possible embodiments, it also includes: a heat-insulating and anti-seepage composite layer 2 arranged on the inner side of the shell 1, and the shell 1 uses high-density polyethylene, polytetrafluoroethylene, aerogel coating, aluminum foil or aluminum-plated film as the outer layer, which has good heat-insulating and moisture-proof properties and is corrosion-resistant. Composite polypropylene, modified ethylene-vinyl acetate copolymer, polyimide, fluoroplastic lining layer, etc. are used as the inner layer to assist in heat insulation and anti-seepage, and can effectively prevent hydrogen diffusion.

[0195] In the embodiments of the present disclosure and other possible embodiments, it also includes: an inner tank 3 arranged in the thermal insulation and anti-seepage composite layer 2; wherein the inner tank 3 is the core storage area of ​​the hydrogen storage bottle, made of chromium-nickel alloy steel, aluminum alloy, nickel-based alloy, etc., and has corrosion resistance and pressure resistance, and the interior of the inner tank 3 is filled with a responsive hydrate builder 4.

[0196] In the embodiment of the present disclosure and other possible embodiments, the responsive hydrate constructor 4 metal organic framework (MOFs), adsorptive activated carbon material or other composite materials with good adsorption properties are filled in the center of the inner tank 3 .

[0197] In the embodiment of the present disclosure and other possible embodiments, the cooling conduit 5 is disposed in the space between the inner tank 3 and the heat-insulating and impermeable composite layer 2, and the low-temperature refrigerant circulates through the cooling conduit 5 to ensure that the low-temperature environment in the inner tank 3 is below -1 degrees Celsius. Among them, the refrigerant inlet 6 and the refrigerant outlet 7 are respectively located at the bottom and the top of the hydrogen storage bottle, which are used to circulate the low-temperature refrigerant, and a series of evenly distributed cooling conduits 5 form a ring or spiral layout around the inner tank 3 to keep the hydrogen storage bottle body at a low temperature to meet the hydrogen adsorption requirements.

[0198] In the embodiments of the present disclosure and other possible embodiments, an adaptive dynamic fuzzy logic hybrid controller is used to adjust the refrigerant flow rate and flow rate in the cooling duct 5, and dynamically optimize the temperature and pressure of the inner tank 3 by real-time monitoring of the temperature and pressure data of the temperature sensor 9 and the pressure sensor 10.

[0199] In the embodiment of the present disclosure and other possible embodiments, the temperature sensor 9 and the pressure sensor 10 are installed on the top of the hydrogen storage bottle to detect the temperature and pressure inside the inner tank 3 in real time, and feed back the temperature and pressure data to the adaptive dynamic fuzzy logic hybrid controller.

[0200] In the embodiment of the present disclosure and other possible embodiments, the sealing ring 11 is used to seal between various interfaces and components to prevent leakage of refrigerant ammonia, fluorocarbons, propane, carbon dioxide, etc. or hydrogen.

[0201] In the embodiment of the present disclosure and other possible embodiments, the hydrogen inlet 13 is located at the top of the hydrogen storage bottle, passes through the insulation and waterproof composite layer 2, the outer shell 1 and is connected to the inner tank 3, and is connected to the external hydrogen supply source through the air filter 12 to ensure that the hydrogen entering the inner tank is pure and free of impurities.

[0202] In some embodiments, the functions or modules included in the device provided in the embodiments of the present disclosure can be used to execute the hydrate solid-state composite hydrogen storage control method described in the above method embodiment. Its specific implementation can refer to the description of the above method embodiment. For the sake of brevity, it will not be repeated here.

[0203] The embodiment of the present disclosure also provides a computer-readable storage medium on which computer program instructions are stored, and when the computer program instructions are executed by a processor, the above-mentioned hydrate solid composite hydrogen storage control method is implemented. The computer-readable storage medium may be a non-volatile computer-readable storage medium.

[0204] The disclosed embodiment also provides an electronic device, comprising: a processor; a memory for storing instructions executable by the processor; wherein the processor is configured to implement the above-mentioned hydrate solid composite hydrogen storage control method. The electronic device can be provided as a terminal, a server, or other forms of equipment.

[0205] In summary, the present invention provides a hydrate solid composite hydrogen storage system, which mainly includes an outer shell, an insulation and anti-seepage composite layer, an inner tank, a responsive hydrate constructor, a cooling conduit, a refrigerant inlet and outlet, an adaptive dynamic fuzzy logic hybrid controller, a temperature, a pressure sensor and a sealing ring. The system maintains a low-temperature environment between the inner tank and the insulation layer through the refrigerant circulation, and promotes the efficient adsorption and generation of hydrogen and the responsive hydrate constructor. The adaptive dynamic fuzzy logic hybrid controller monitors the temperature of the top, the temperature and pressure data of the pressure sensor in real time, dynamically adjusts the refrigerant flow, and performs a rhythmic pressure-temperature cycle (heating and depressurization and cooling and supercharging) to improve the hydrogen storage density and system stability. An adaptive dynamic fuzzy logic hybrid control algorithm combining fuzzy logic and circular chaos feedback is used to ensure precise regulation and optimize energy efficiency. The hydrate lattice structure is optimized by circulating pressure and temperature multiple times to achieve efficient and safe hydrogen storage and release, which is suitable for high-pressure and low-temperature environments and has good energy efficiency and long-term stability.

[0206] Based on the cage-like voids in the crystal structure of hydrates, hydrogen molecules can be stably captured in them, achieving efficient hydrogen storage. The key point of this application scheme lies in the innovative hydrate solid-state hydrogen storage technology, combined with responsive hydrate builders, combined with a circular chaotic feedback mechanism adaptive dynamic fuzzy logic hybrid control system, including a double-layer design of the hydrogen storage bottle, rhythmic temperature and pressure regulation and responsive hydrate builders, and adaptive dynamic fuzzy logic hybrid control algorithms.

[0207] Compared with the prior art, the scheme of the present application designs a rhythmic temperature and pressure regulation strategy. The periodic temperature and pressure changes can cause the hydrate lattice structure to undergo dynamic adjustments, optimize the pore size and distribution, and thus enhance the adsorption capacity of hydrogen molecules. At the same time, the responsive hydrate constructor can automatically adjust its pore structure according to external conditions, and work synergistically with the rhythmic regulation strategy to further improve the storage and release efficiency of hydrogen. At the same time, an adaptive dynamic fuzzy logic hybrid controller is introduced, combined with a circular chaotic feedback mechanism, to achieve precise regulation of temperature and pressure and optimize the adsorption and release process of hydrogen. The hydrogen storage density of traditional hydrogen hydrate systems is about 4wt% to 5wt%, and the hydrogen charging and decharging rates are low, usually with a hydrogen charging rate of about 5Nm 3 / min. The hydrate solid composite hydrogen storage system of the present invention has a hydrogen storage density of up to 5.8wt%. The hydrogen charging rate is 10Nm 3 / min, hydrogen release rate 8Nm 3 / min, an increase of about 100%.

[0208] Figure 5 8 is a block diagram of an electronic device 800 according to an exemplary embodiment. For example, the electronic device 800 may be a mobile phone, a computer, a digital broadcast terminal, a messaging device, a game console, a tablet device, a medical device, a fitness device, a personal digital assistant, or the like.

[0209] Reference Figure 5 , the electronic device 800 may include one or more of the following components: a processing component 802 , a memory 804 , a power component 806 , a multimedia component 808 , an audio component 810 , an input / output (I / O) interface 812 , a sensor component 814 , and a communication component 816 .

[0210] The processing component 802 generally controls the overall operation of the electronic device 800, such as operations associated with display, phone calls, data communications, camera operations, and recording operations. The processing component 802 may include one or more processors 820 to execute instructions to complete all or part of the steps of the above-mentioned method. In addition, the processing component 802 may include one or more modules to facilitate the interaction between the processing component 802 and other components. For example, the processing component 802 may include a multimedia module to facilitate the interaction between the multimedia component 808 and the processing component 802.

[0211] The memory 804 is configured to store various types of data to support operations on the electronic device 800. Examples of such data include instructions for any application or method operating on the electronic device 800, contact data, phone book data, messages, pictures, videos, etc. The memory 804 can be implemented by any type of volatile or non-volatile storage device or a combination thereof, such as static random access memory (SRAM), electrically erasable programmable read-only memory (EEPROM), erasable programmable read-only memory (EPROM), programmable read-only memory (PROM), read-only memory (ROM), magnetic memory, flash memory, magnetic disk or optical disk.

[0212] The power supply component 806 provides power to the various components of the electronic device 800. The power supply component 806 may include a power management system, one or more power supplies, and other components associated with generating, managing, and distributing power to the electronic device 800.

[0213] The multimedia component 808 includes a screen that provides an output interface between the electronic device 800 and the user. In some embodiments, the screen may include a liquid crystal display (LCD) and a touch panel (TP). If the screen includes a touch panel, the screen may be implemented as a touch screen to receive input signals from the user. The touch panel includes one or more touch sensors to sense touch, slide, and gestures on the touch panel. The touch sensor may not only sense the boundaries of the touch or slide action, but also detect the duration and pressure associated with the touch or slide operation. In some embodiments, the multimedia component 808 includes a front camera and / or a rear camera. When the electronic device 800 is in an operating mode, such as a shooting mode or a video mode, the front camera and / or the rear camera may receive external multimedia data. Each front camera and rear camera may be a fixed optical lens system or have a focal length and optical zoom capability.

[0214] The audio component 810 is configured to output and / or input audio signals. For example, the audio component 810 includes a microphone (MIC), and when the electronic device 800 is in an operating mode, such as a call mode, a recording mode, and a voice recognition mode, the microphone is configured to receive an external audio signal. The received audio signal can be further stored in the memory 804 or sent via the communication component 816. In some embodiments, the audio component 810 also includes a speaker for outputting audio signals.

[0215] I / O interface 812 provides an interface between processing component 802 and peripheral interface modules, such as keyboards, click wheels, buttons, etc. These buttons may include but are not limited to: home button, volume button, start button, and lock button.

[0216] The sensor assembly 814 includes one or more sensors for providing various aspects of status assessment for the electronic device 800. For example, the sensor assembly 814 can detect the open / closed state of the electronic device 800, the relative positioning of the components, such as the display and keypad of the electronic device 800, and the sensor assembly 814 can also detect the position change of the electronic device 800 or a component of the electronic device 800, the presence or absence of contact between the user and the electronic device 800, the orientation or acceleration / deceleration of the electronic device 800, and the temperature change of the electronic device 800. The sensor assembly 814 may include a proximity sensor configured to detect the presence of a nearby object without any physical contact. The sensor assembly 814 may also include an optical sensor, such as a CMOS or CCD image sensor, for use in imaging applications. In some embodiments, the sensor assembly 814 may also include an acceleration sensor, a gyroscope sensor, a magnetic sensor, a pressure sensor, or a temperature sensor.

[0217] The communication component 816 is configured to facilitate wired or wireless communication between the electronic device 800 and other devices. The electronic device 800 can access a wireless network based on a communication standard, such as WiFi, 2G or 3G, or a combination thereof. In an exemplary embodiment, the communication component 816 receives a broadcast signal or broadcast-related information from an external broadcast management system via a broadcast channel. In an exemplary embodiment, the communication component 816 also includes a near field communication (NFC) module to facilitate short-range communication. For example, the NFC module can be implemented based on radio frequency identification (RFID) technology, infrared data association (IrDA) technology, ultra-wideband (UWB) technology, Bluetooth (BT) technology and other technologies.

[0218] In an exemplary embodiment, the electronic device 800 may be implemented by one or more application-specific integrated circuits (ASICs), digital signal processors (DSPs), digital signal processing devices (DSPDs), programmable logic devices (PLDs), field programmable gate arrays (FPGAs), controllers, microcontrollers, microprocessors, or other electronic components to perform the above methods.

[0219] In an exemplary embodiment, a non-volatile computer-readable storage medium is also provided, such as a memory 804 including computer program instructions, which can be executed by a processor 820 of an electronic device 800 to perform the above method.

[0220] Figure 6 1 is a block diagram of an electronic device 1900 according to an exemplary embodiment. For example, the electronic device 1900 may be provided as a server. Figure 6 , the electronic device 1900 includes a processing component 1922, which further includes one or more processors, and a memory resource represented by a memory 1932 for storing instructions executable by the processing component 1922, such as an application. The application stored in the memory 1932 may include one or more modules, each corresponding to a set of instructions. In addition, the processing component 1922 is configured to execute instructions to perform the above method.

[0221] The electronic device 1900 may also include a power supply component 1926 configured to perform power management of the electronic device 1900, a wired or wireless network interface 1950 configured to connect the electronic device 1900 to a network, and an input / output (I / O) interface 1958. The electronic device 1900 may operate based on an operating system stored in the memory 1932, such as Windows Server™, Mac OS X™, Unix™, Linux™, FreeBSD™ or the like.

[0222] In an exemplary embodiment, a non-volatile computer-readable storage medium is also provided, such as a memory 1932 including computer program instructions, which can be executed by the processing component 1922 of the electronic device 1900 to perform the above method.

[0223] The present disclosure may be a system, a method and / or a computer program product. The computer program product may include a computer-readable storage medium carrying computer-readable program instructions for causing a processor to implement various aspects of the present disclosure.

[0224] A computer-readable storage medium may be a tangible device that can hold and store instructions used by an instruction execution device. A computer-readable storage medium may be, for example, but not limited to, an electrical storage device, a magnetic storage device, an optical storage device, an electromagnetic storage device, a semiconductor storage device, or any suitable combination of the foregoing. More specific examples of computer-readable storage media (a non-exhaustive list) include: a portable computer disk, a hard disk, a random access memory (RAM), a read-only memory (ROM), an erasable programmable read-only memory (EPROM or flash memory), a static random access memory (SRAM), a portable compact disk read-only memory (CD-ROM), a digital versatile disk (DVD), a memory stick, a floppy disk, a mechanical encoding device, such as a punch card or a raised structure in a groove on which instructions are stored, and any suitable combination of the foregoing. As used herein, a computer-readable storage medium is not to be interpreted as a transient signal per se, such as a radio wave or other freely propagating electromagnetic wave, an electromagnetic wave propagating through a waveguide or other transmission medium (e.g., a light pulse through a fiber optic cable), or an electrical signal transmitted through a wire.

[0225] The computer-readable program instructions described herein can be downloaded from a computer-readable storage medium to each computing / processing device, or downloaded to an external computer or external storage device via a network, such as the Internet, a local area network, a wide area network, and / or a wireless network. The network can include copper transmission cables, optical fiber transmissions, wireless transmissions, routers, firewalls, switches, gateway computers, and / or edge servers. The network adapter card or network interface in each computing / processing device receives the computer-readable program instructions from the network and forwards the computer-readable program instructions for storage in the computer-readable storage medium in each computing / processing device.

[0226] The computer program instructions for performing the operation of the present disclosure may be assembly instructions, instruction set architecture (ISA) instructions, machine instructions, machine-related instructions, microcode, firmware instructions, state setting data, or source code or object code written in any combination of one or more programming languages, including object-oriented programming languages, such as Smalltalk, C++, etc., and conventional procedural programming languages, such as "C" language or similar programming languages. Computer-readable program instructions may be executed completely on a user's computer, partially on a user's computer, as an independent software package, partially on a user's computer, partially on a remote computer, or completely on a remote computer or server. In the case of a remote computer, the remote computer may be connected to the user's computer via any type of network, including a local area network (LAN) or a wide area network (WAN), or may be connected to an external computer (e.g., using an Internet service provider to connect via the Internet). In some embodiments, an electronic circuit, such as a programmable logic circuit, a field programmable gate array (FPGA), or a programmable logic array (PLA), may be customized by utilizing the state information of the computer-readable program instructions, and the electronic circuit may execute the computer-readable program instructions, thereby realizing various aspects of the present disclosure.

[0227] Various aspects of the present disclosure are described herein with reference to the flowcharts and / or block diagrams of the methods, devices (systems) and computer program products according to the embodiments of the present disclosure. It should be understood that each box in the flowchart and / or block diagram and the combination of each box in the flowchart and / or block diagram can be implemented by computer-readable program instructions.

[0228] These computer-readable program instructions can be provided to a processor of a general-purpose computer, a special-purpose computer, or other programmable data processing device, thereby producing a machine, so that when these instructions are executed by the processor of the computer or other programmable data processing device, a device that implements the functions / actions specified in one or more boxes in the flowchart and / or block diagram is generated. These computer-readable program instructions can also be stored in a computer-readable storage medium, and these instructions cause the computer, programmable data processing device, and / or other equipment to work in a specific manner, so that the computer-readable medium storing the instructions includes a manufactured product, which includes instructions for implementing various aspects of the functions / actions specified in one or more boxes in the flowchart and / or block diagram.

[0229] Computer-readable program instructions may also be loaded onto a computer, other programmable data processing apparatus, or other device so that a series of operating steps are performed on the computer, other programmable data processing apparatus, or other device to produce a computer-implemented process, thereby causing the instructions executed on the computer, other programmable data processing apparatus, or other device to implement the functions / actions specified in one or more boxes in the flowchart and / or block diagram.

[0230] The flow chart and block diagram in the accompanying drawings show the possible architecture, function and operation of the system, method and computer program product according to multiple embodiments of the present disclosure. In this regard, each square box in the flow chart or block diagram can represent a part of a module, program segment or instruction, and a part of the module, program segment or instruction includes one or more executable instructions for realizing the specified logical function. In some alternative implementations, the function marked in the square box can also occur in a sequence different from that marked in the accompanying drawings. For example, two continuous square boxes can actually be executed substantially in parallel, and they can sometimes be executed in reverse order, depending on the functions involved. It should also be noted that each square box in the block diagram and / or flow chart, and the combination of the square boxes in the block diagram and / or flow chart can be implemented with a dedicated hardware-based system that performs the specified function or action, or can be implemented with a combination of special hardware and computer instructions.

[0231] The embodiments of the present disclosure have been described above, and the above description is exemplary, not exhaustive, and is not limited to the disclosed embodiments. Many modifications and variations will be apparent to those of ordinary skill in the art without departing from the scope and spirit of the described embodiments. The selection of terms used herein is intended to best explain the principles of the embodiments, practical applications, or technical improvements to the technology in the market, or to enable other persons of ordinary skill in the art to understand the embodiments disclosed herein.

Claims

1. A hydrate solid composite hydrogen storage control method, characterized in that: include: Obtaining a set temperature curve and a set pressure curve corresponding to the inner tank where the hydrogen hydrate is located; wherein the set temperature curve and / or the set pressure curve are configured as a periodic curve; Determine at least one of the following stages in the hydrate solid composite hydrogen storage control process: hydrogen filling and hydrogen hydrate formation stage, temperature increase and pressure reduction stage, cooling and pressurization stage, and hydrogen release stage; In at least one of the hydrogen filling and hydrogen hydrate formation stage, the temperature increase and pressure reduction stage, the cooling and pressurization stage, and the hydrogen release stage, the hydrate solid-state composite hydrogen storage control is rhythmically controlled by regulating the temperature initial value of the set temperature curve and the pressure initial value of the set pressure curve.

2. The hydrate solid composite hydrogen storage control method according to claim 1, characterized in that: The method for rhythmically controlling the solid-state composite hydrogen storage of hydrates by regulating the temperature initial value of the set temperature curve and the pressure initial value of the set pressure curve during the hydrogen filling and hydrogen hydrate formation stage comprises: controlling the hydrogen flow regulating valve connected between the inner tank and the hydrogen flow to open, and controlling the hydrogen to enter the inner tank according to the set hydrogen entry rate; in the process of controlling the hydrogen to enter the inner tank according to the set hydrogen entry rate, configuring the set initial temperature corresponding to the start-up phase of the solid-state composite hydrogen storage control process of the hydrate to the temperature initial value of the set temperature curve, raising the pressure of the inner tank to the pressure reference value, and configuring the pressure reference value to the pressure initial value of the set pressure curve; under the rhythmic control of the configured set temperature curve and the set pressure curve, the molecular vibration frequency in the hydrate lattice of the hydrogen hydrate matches the periodic changes of the temperature and pressure of the inner tank; and / or, In the temperature increase and pressure reduction stage, a method for rhythmically controlling hydrate solid composite hydrogen storage control by regulating the temperature initial value of the set temperature curve and the pressure initial value of the set pressure curve comprises: after the hydrogen filling and hydrogen hydrate formation stage is completed, the temperature initial value of the set temperature curve in the hydrogen filling and hydrogen hydrate formation stage is increased to a first set temperature target value; the pressure initial value of the set pressure curve in the hydrogen filling and hydrogen hydrate formation stage is reduced to a first set pressure target value; under the rhythmic control of the set temperature curve corresponding to the first set temperature target value and the set pressure curve corresponding to the set pressure target value after configuration, the molecular vibration frequency in the hydrate lattice is caused to change, thereby optimizing the release and redistribution of hydrogen molecules; and / or, In the cooling and pressurizing stage, a method for rhythmically controlling hydrate solid composite hydrogen storage control by regulating the temperature initial value of the set temperature curve and the pressure initial value of the set pressure curve comprises: after the temperature increase and pressure reduction stage is completed, the temperature initial value of the set temperature curve in the hydrogen filling and hydrogen hydrate formation stage is reduced from the first set temperature target value to the set initial temperature corresponding to the startup stage; the pressure initial value of the set pressure curve in the hydrogen filling and hydrogen hydrate formation stage is increased from the first set pressure target value to the second set pressure target value; under the rhythmic control of the set temperature curve corresponding to the first set temperature target value and the set pressure curve corresponding to the set pressure target value after configuration, the incompletely reacted hydrogen is further converted into hydrogen hydrate.

3. The hydrate solid composite hydrogen storage control method according to any one of claims 1 to 2, characterized in that: Also includes: Determine each temperature increase and pressure reduction stage and each cooling and pressurization stage as a cycle of pressure and temperature; The method for determining the corresponding number of the cyclic pressure and temperature cycles comprises: obtaining the actual hydrogen storage capacity of the inner tank after each of the temperature increase and pressure reduction phases or each of the cooling and pressure increase phases; if the actual hydrogen storage capacity reaches the set hydrogen storage capacity target and / or the preset maximum number of cycles corresponding to the set hydrogen storage capacity target, stopping the cyclic pressure and temperature cycle or stopping the temperature increase and pressure reduction phase or the cooling and pressure increase phase, and entering the static pressure and temperature phase; and / or, After each of the temperature increase and pressure reduction phases or each of the cooling and pressure increase phases, the hydrogen storage capacity increment between the current cycle and the previous cycle is calculated; if the hydrogen storage capacity increment is less than the set hydrogen storage capacity increment threshold and / or the actual hydrogen storage capacity of the inner tank reaches the set hydrogen storage capacity target and / or the preset maximum number of cycles corresponding to the set hydrogen storage capacity target, the cycle and pressure temperature cycle is stopped or the temperature increase and pressure reduction phase or the cooling and pressure increase phase is stopped, and the static pressure temperature phase is entered; and / or, In the hydrogen release stage, the method for rhythmically controlling the hydrate solid composite hydrogen storage control by regulating the temperature initial value of the set temperature curve and the pressure initial value of the set pressure curve comprises: raising the set static maintenance temperature of the static pressure and temperature stage in the hydrate solid composite hydrogen storage control process to a second set temperature target value corresponding to the temperature initial value of the set temperature curve; reducing the set static maintenance pressure of the static pressure and temperature stage in the hydrate solid composite hydrogen storage control process to a third set pressure target value corresponding to the pressure initial value of the set temperature curve; under the rhythmic control of the set temperature curve corresponding to the third set temperature target value and the set pressure curve corresponding to the third set pressure target value after configuration, the structure of the hydrate lattice is loosened, the vibration frequency of the hydrogen molecules is changed, and the hydrogen molecules in the hydrate lattice are deembedded and released into the gas phase.

4. The hydrate solid composite hydrogen storage control method according to any one of claims 1 to 3, characterized in that: In at least one of the hydrogen filling and hydrogen hydrate formation stage, the temperature increase and pressure reduction stage, the cooling and pressurization stage, and the hydrogen release stage, a rhythmic control method for hydrate solid composite hydrogen storage control is performed by regulating the temperature initial value of the set temperature curve and the pressure initial value of the set pressure curve, and also includes: real-time calculation of the temperature deviation between the temperature of the inner tank and the set temperature corresponding to the set temperature curve after the temperature initial value is configured; real-time calculation of the pressure deviation between the pressure of the inner tank and the set pressure corresponding to the set pressure curve after the pressure initial value is configured; according to a set fuzzy rule set, respectively determine the temperature deviation level and the pressure deviation level corresponding to the temperature deviation; based on the temperature deviation level and the pressure deviation level, regulate the current refrigerant flow rate corresponding to the cooling conduit entering the inner tank or entering the outside of the inner tank and the hydrogen flow corresponding to the filling of the inner tank; and / or, The method for regulating the current refrigerant flow rate corresponding to the refrigerant flow entering the inner tank or the cooling duct outside the inner tank and the corresponding hydrogen flow rate filled into the inner tank based on the temperature deviation level and the pressure deviation level, comprises: the temperature deviation level comprises: a first temperature deviation level corresponding to the highest level, a second temperature deviation level lower than the first temperature deviation level, and a third temperature deviation level lower than the second temperature deviation level; the pressure deviation level comprises: a first pressure deviation level corresponding to the highest level, a second pressure deviation level lower than the first pressure deviation level, and a third pressure deviation level lower than the second pressure deviation level; wherein, if the temperature deviation level is the first temperature deviation level, the refrigerant flow entering the inner tank is increased. tank or the current refrigerant flow rate corresponding to the cooling duct entering the outer side of the inner tank; if the temperature deviation level is the second temperature deviation level, the current refrigerant flow rate corresponding to the refrigerant flow entering the inner tank or the cooling duct entering the outer side of the inner tank is maintained; if the temperature deviation level is the third temperature deviation level, the current refrigerant flow rate corresponding to the refrigerant flow entering the inner tank or the cooling duct entering the outer side of the inner tank is reduced; wherein, if the pressure deviation level is the first pressure deviation level, the corresponding hydrogen flow rate filled into the inner tank is increased; if the pressure deviation level is the second pressure deviation level, the corresponding hydrogen flow rate filled into the inner tank is maintained; if the pressure deviation level is the third pressure deviation level, the corresponding hydrogen flow rate filled into the inner tank is reduced.

5. The hydrate solid composite hydrogen storage control method according to any one of claims 1 to 4, characterized in that: In at least one of the hydrogen filling and hydrogen hydrate formation stage, the temperature increase and pressure reduction stage, the cooling and pressurization stage, and the hydrogen release stage, a rhythmic control method for hydrate solid composite hydrogen storage control is performed by regulating the temperature initial value of the set temperature curve and the pressure initial value of the set pressure curve, and further includes: increasing or decreasing the current refrigerant flow rate corresponding to the cooling conduit entering the inner tank or entering the outer side of the inner tank while maintaining the temperature corresponding to the set temperature curve; and / or, The method for increasing or decreasing the current refrigerant flow rate corresponding to the refrigerant flow entering the inner tank or the cooling conduit outside the inner tank in the process of maintaining the temperature corresponding to the inner tank at the set temperature of the set temperature curve comprises: obtaining a first set temperature deviation threshold, a second set temperature deviation threshold, and a temperature deviation between the temperature corresponding to the inner tank and the set temperature of the set temperature curve; determining the corresponding first temperature hysteresis zone based on the first set temperature deviation threshold and the second set temperature deviation threshold; if the temperature deviation is outside the first temperature hysteresis zone, increasing the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outer side of the inner tank at a first set rate or reducing the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outer side of the inner tank; if the temperature deviation is within the first temperature hysteresis zone, increasing the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outer side of the inner tank at a second set rate less than the first set rate or reducing the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outer side of the inner tank or maintaining the current set rate corresponding to the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outer side of the inner tank; and / or, The method of increasing the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outer side of the inner tank at a second set rate that is less than the first set rate, or reducing the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outer side of the inner tank, or maintaining the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outer side of the inner tank corresponding to the current set rate if the temperature deviation is within the first temperature hysteresis zone, comprises: a third set temperature deviation threshold value that is less than the first set temperature deviation threshold value and a fourth set temperature deviation threshold value that is greater than the second set temperature deviation threshold value; based on the third set temperature deviation threshold value The difference threshold and the fourth set temperature deviation threshold determine the corresponding second temperature hysteresis zone; if the temperature deviation is within the first temperature hysteresis zone, determine whether the deviation is within the second temperature hysteresis zone; if the deviation is within the second temperature hysteresis zone, maintain the current set rate corresponding to the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank; otherwise, increase the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank at a second set rate that is less than the first set rate, or decrease the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank.

6. The hydrate solid composite hydrogen storage control method according to any one of claims 1 to 5, characterized in that: In at least one of the hydrogen filling and hydrogen hydrate formation stage, the temperature increase and pressure reduction stage, the cooling and pressurization stage, and the hydrogen release stage, the method for rhythmically controlling the hydrate solid composite hydrogen storage control is performed by regulating the temperature initial value of the set temperature curve and the pressure initial value of the set pressure curve, and further includes: increasing or decreasing the hydrogen flow rate corresponding to the hydrogen flow filled into the inner tank during the process of maintaining the pressure corresponding to the set pressure curve; and / or, The method for increasing or decreasing the flow rate of hydrogen corresponding to the inner tank while maintaining the pressure corresponding to the inner tank at the set pressure of the set pressure curve comprises: obtaining a first set pressure deviation threshold, a second set pressure deviation threshold, and a pressure deviation between the pressure corresponding to the inner tank and the set pressure of the set pressure curve; determining a corresponding first pressure hysteresis zone based on the first set pressure deviation threshold and the second set pressure deviation threshold; if the pressure deviation is outside the first pressure hysteresis zone, increasing the flow rate of hydrogen connected to the inner tank at a first set rate or decreasing the flow rate of hydrogen connected to the inner tank; if the pressure deviation is within the first pressure hysteresis zone, increasing the flow rate of hydrogen connected to the inner tank at a second set rate that is less than the first set rate or decreasing the flow rate of hydrogen connected to the inner tank or maintaining the flow rate of hydrogen connected to the inner tank; and / or, The method for increasing the hydrogen flow rate filled into the inner tank connection at a second set rate that is less than the first set rate, or decreasing the hydrogen flow rate filled into the inner tank connection, or maintaining the hydrogen flow rate filled into the inner tank connection if the pressure deviation is within the first pressure hysteresis zone, comprises: a third set pressure deviation threshold that is less than the first set pressure deviation threshold and a fourth set pressure deviation threshold that is greater than the second set pressure deviation threshold; determining the corresponding second pressure hysteresis zone based on the third set pressure deviation threshold and the fourth set pressure deviation threshold; if the pressure deviation is within the first pressure hysteresis zone, determining whether the deviation is within the second pressure hysteresis zone; if the deviation is within the second pressure hysteresis zone, maintaining the hydrogen flow rate filled into the inner tank connection; otherwise, increasing the hydrogen flow rate filled into the inner tank connection or decreasing the hydrogen flow rate filled into the inner tank connection at a second set rate that is less than the first set rate.

7. The hydrate solid composite hydrogen storage control method according to any one of claims 1 to 6, characterized in that: The hydrate solid composite hydrogen storage control process also includes: a startup phase; in the startup phase, obtaining the temperature corresponding to the inner tank in real time; adjusting the temperature corresponding to the inner tank to a set initial temperature, and maintaining the set initial temperature corresponding to the inner tank; and / or, The hydrate solid composite hydrogen storage control process also includes: a static pressure and temperature stage; in the static pressure and temperature stage, obtaining the temperature and pressure corresponding to the inner tank in real time; maintaining the temperature corresponding to the inner tank at a set static maintenance temperature or below the set static maintenance temperature; maintaining the pressure corresponding to the inner tank at a set static maintenance pressure or above the set static maintenance pressure; and / or, The method for maintaining the temperature corresponding to the inner tank at a set static maintenance temperature or below the set static maintenance temperature includes: obtaining a first set temperature deviation threshold, a second set temperature deviation threshold, and a temperature deviation between the temperature corresponding to the inner tank and the set static maintenance temperature; determining a corresponding first temperature hysteresis zone based on the first set temperature deviation threshold and the second set temperature deviation threshold; if the temperature deviation is outside the first temperature hysteresis zone, increasing the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outer side of the inner tank at a first set rate or reducing the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outer side of the inner tank; if the temperature deviation is within the first temperature hysteresis zone, increasing the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outer side of the inner tank at a second set rate less than the first set rate or reducing the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outer side of the inner tank or maintaining the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outer side of the inner tank at a current set rate; and / or, The method of increasing the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outer side of the inner tank at a second set rate that is less than the first set rate, or reducing the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outer side of the inner tank, or maintaining the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outer side of the inner tank corresponding to the current set rate if the temperature deviation is within the first temperature hysteresis zone, comprises: a third set temperature deviation threshold value that is less than the first set temperature deviation threshold value and a fourth set temperature deviation threshold value that is greater than the second set temperature deviation threshold value; based on the third set temperature deviation threshold value The difference threshold and the fourth set temperature deviation threshold determine the corresponding second temperature hysteresis zone; if the temperature deviation is within the first temperature hysteresis zone, determine whether the deviation is within the second temperature hysteresis zone; if the deviation is within the second temperature hysteresis zone, maintain the current set rate corresponding to the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank; otherwise, increase the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank at a second set rate that is less than the first set rate, or decrease the refrigerant flow rate of the cooling conduit connected to the inner tank or entering the outside of the inner tank.

8. The hydrate solid composite hydrogen storage control method according to any one of claims 1 to 7, characterized in that: The hydrate solid composite hydrogen storage control process also includes: a startup phase; in the startup phase, the refrigerant flow regulating valve connected to the refrigerant flow of the inner tank or the cooling conduit entering the outer side of the inner tank is controlled to open, and the temperature corresponding to the inner tank is obtained in real time; the temperature corresponding to the inner tank is adjusted to a set initial temperature, and the set initial temperature corresponding to the inner tank is maintained; and / or, The hydrate solid composite hydrogen storage control process also includes: a final pressure relief and shutdown stage; in the final pressure relief and shutdown stage, the pressure in the inner tank is reduced to a set pressure relief and shutdown pressure by using a set decompression rate; and / or, In the final pressure relief and shutdown stage, it also includes: controlling the refrigerant flow regulating valve connected to the inner tank or the cooling conduit entering the outer side of the inner tank and the refrigerant flow to be closed, and controlling the hydrogen flow regulating valve connected to the inner tank and the hydrogen flow to be closed; when the pressure in the inner tank is reduced to the set pressure relief and shutdown pressure and the corresponding temperature of the inner tank returns to the ambient temperature, the state mark of the hydrate solid composite hydrogen storage control process is configured to standby; and / or, In at least one of the hydrogen filling and hydrogen hydrate formation stages, the temperature increase and pressure reduction stage, the cooling and pressurization stage, and the hydrogen release stage, the hydrate solid-state composite hydrogen storage control is rhythmically controlled by regulating the temperature initial value of the set temperature curve and the pressure initial value of the set pressure curve, and also includes: generating corresponding first rhythmic chaotic signals and second rhythmic chaotic signals based on the first periodic function corresponding to the set temperature curve and the second periodic function corresponding to the set pressure curve, respectively; constructing a set temperature rhythmic chaotic curve corresponding to the set temperature curve based on the temperature initial value and the first rhythmic chaotic signal; constructing a set pressure rhythmic chaotic curve corresponding to the set temperature curve based on the pressure initial value and the second rhythmic chaotic signal; and then, the hydrate solid-state composite hydrogen storage control is rhythmically controlled by regulating the temperature initial value of the set temperature rhythmic chaotic curve and the pressure initial value of the set pressure rhythmic chaotic curve.

9. A hydrate solid composite hydrogen storage control system, characterized in that: include: An acquisition unit, used to acquire a set temperature curve and a set pressure curve corresponding to the inner tank where the hydrogen hydrate is located; wherein the set temperature curve and / or the set pressure curve are configured as a periodic curve; A determination unit, used to determine at least one stage of the hydrogen filling and hydrogen hydrate formation stage, the temperature increase and pressure reduction stage, the cooling and pressurization stage, and the hydrogen release stage in the hydrate solid composite hydrogen storage control process; A control unit, used to perform rhythmic control on the hydrate solid composite hydrogen storage control using the set temperature curve and the set pressure curve in at least one of the hydrogen filling and hydrogen hydrate formation stage, the temperature increase and pressure reduction stage, the cooling and pressurization stage, and the hydrogen release stage; or, Comprising: a processor; a memory for storing processor executable instructions; wherein the processor is configured to call the instructions stored in the memory to execute the hydrate solid composite hydrogen storage control method according to any one of claims 1 to 8; or, Comprising: a computer-readable storage medium having computer program instructions stored thereon, characterized in that when the computer program instructions are executed by a processor, the hydrate solid composite hydrogen storage control method according to any one of claims 1 to 8 is implemented; or, The invention comprises: a computer program product on which a computer program / instruction is configured, and when the computer program / instruction is executed by a processor, the hydrate solid composite hydrogen storage control method according to any one of claims 1 to 8 is implemented.

10. A hydrate solid composite hydrogen storage control system, characterized in that: include: An inner tank (3); a cooling conduit (5) is arranged on the outer side of the inner tank (3); the inner tank (3) is also connected to a hydrogen source; the inner tank (3) is provided with a temperature sensor (9) and a pressure sensor (10) for detecting the temperature and pressure inside the inner tank (3); wherein the inner tank (3) is filled with a responsive hydrate building agent (4) for containing hydrogen hydrates; In at least one of the hydrogen filling and hydrogen hydrate formation stages, the temperature increase and pressure reduction stage, the cooling and pressurization stage, and the hydrogen release stage in the hydrate solid composite hydrogen storage control process, the refrigerant flow rate in the cooling conduit (5) and the hydrogen flow rate of the hydrogen source entering the inner tank (3) are used to rhythmically control the temperature and pressure in the inner tank (3) detected by the pressure temperature sensor (9) and the pressure sensor (10) by adjusting the temperature initial value of the periodic set temperature curve and the pressure initial value of the periodic set pressure curve, so as to adjust the microscopic pore structure of the responsive hydrate builder and / or the vibration of the hydrate lattice of the hydrogen hydrate; and / or, It also includes: a heat-insulating and anti-seepage composite layer (2) arranged on the outside of the inner tank (3) or the cooling duct (5); and / or, the cooling duct (5) is configured as a coil structure; wherein the cooling duct (5) of the coil structure is coiled on the outside of the cooling duct (5); and / or, one end of the cooling duct (5) is provided with a refrigerant inlet (6) connected to a refrigerant source, and the other end of the cooling duct (5) is provided with a refrigerant outlet (7).

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