Weeding composition

Abstract

The present invention relates to herbicidal compositions comprising N-(1, 3, 4-oxadiazol-2-yl) aryl carboxylic acid amides and other herbicides.

Description

Technical Field

[0001] The present invention relates to an agrochemically active herbicidal composition, a process for its preparation and its use for controlling harmful plants. Background Art

[0002] WO2015 / 059187A1 discloses a herbicidal composition comprising N-(1,3,4-oxadiazole-2-yl)arylformamide. The document also records a herbicidal composition comprising a racemic form of 2-chloro-N-(5-methyl-1,3,4-oxadiazole-2-yl)-3-(methylsulfinyl)-4-(trifluoromethyl)benzamide, such as Example No. A1-14.

[0003] However, these herbicidal compositions known from WO 2015 / 059187 A1 often have disadvantageous features with regard to their biological properties, such as herbicidal action, tolerance of crop plants, toxicological and ecotoxicological properties. Summary of the invention

[0004] The object of the present invention is to provide an alternative herbicidal active composition. This object is achieved by the herbicidal composition of the present invention comprising specific N-(1,3,4-oxadiazol-2-yl)benzamide as described below.

[0005] The present invention provides a herbicidal composition comprising

[0006] (A) a compound having an absolute configuration specified by formula (I-5) (component A) or a salt thereof,

[0007]

[0008] and

[0009] (B) one or more herbicides selected from Groups B1 to B11 (Component B):

[0010] B1: alloxydim, alloxydim-sodium, bicyclopyrone, butroxydim, clethodim, cycloxydim, ketospiradox, mesotrione, pinoxaden, profoxydim, prohexadione, prohexadione-calcium, sethoxydim, sulcotrione, tefuryltrione, tembotrione, tepraloxydim, tralkoxydim, trinexapac-ethyl,

[0011] B2: acetochlor, alachlor, amidochlor, amidosulfuron, asulam, azimsulfuron, beflubutamide, bensulfuron, bensulfuron-methyl, bromobutide, butachlor, butenachlor, butylate, carbaryl ... betamide), chlorimuron, chlorimuron-ethyl, chlorpropham, chlorsulfuron, cinosulfuron, cloransulam, cloransulam-methyl, cycloate, cyclosulfamuron, desmedipham, diclosulam, diflufenican, piperidine dimepiperate, dimethenamide, dimethenamide-P, diphenamide, EPTC, esprocarb, ethametsulfuron, ethametsulfuron-methyl, ethoxysulfuron, etobenzanid, flazasulfuron, florasulam, flucarbaz one-sodium), flucetosulfuron, flufenacet, flumetsulam, flupyrsulfuron-methyl-sodium, foramsulfuron, halosulfuron-methyl, imazosulfuron, imethachlor, iodosulfuron, iodosulfuron-methyl-sodium,ipfencarbazone, mefenacet, mefluidide, mesosulfuron, mesosulfuron-methyl, metazachlor, metazosulfuron, methasulfocarb, metiopyrsulfuron, metolachlor, metosulam, metsulfuron, metsulfuron-methyl, molinate, monosulfuron, monosulfuron-ester, napropamide, nicosulfuron, N-phenylphtalamic acid acid), orbencarb, orthosulfamuron, oxasulfuron, pebulate, penoxsulam, pethoxamid, phenmedipham, picolinafen, pretilachlor, primisulfuron-methyl, propachlor, propanil, propham, propisochlor, propoxycarbazone, propyrisulfuron on), propyzamide, prosulfocarb, prosulfuron, pyrazosulfuron, pyrazosulfuron-ethyl, pyroxsulam, rimsulfuron, propoxycarbazone-sodium, S-metolachlor, sulfometuron, sulfometuron-methyl, sulfosulfuron, thenylchlor, thiencarbazone,Thiencarbazone-methyl, thifensulfuron, thifensulfuron-methyl, thiobencarb, tri-allate, triasulfuron, tribenuron, tribenuron-methyl, trifloxysulfuron, trifloxysulfuron (sodium), triflusulfuron, triflusulfuron-methyl, tritosulfuron, vernolate, yributicarb,

[0012] B3: bromoxynil, bromoxynil-butyrate, bromoxynil-heptanoate, bromoxynil-octanoate, bromoxynil-potassium, detosyl-pyrazolate (DTP), dichlobenil, ioxynil, ioxynil-octanoate, ioxynil-potassium, ioxynil-sodium, pyraclonil,

[0013] B4: amicarbazone, amitrole, azafenidin, benzofenap, cafenstrole, carfentrazone, carfentrazone-ethyl, fenoxasulfone, fentrazamide, imazamethabenz, imazamethabenz-methyl, imazamethoxam azamox), imazamox-ammonium, imazapic, imazapic-ammonium, imazapyr, imazapyr-isopropyl-ammonium, imazaquin, imazaquin-ammonium, imazethapyr, imazethapyr-immonium, isoxathiapyr isouron, isoxaben, isoxaflutole, oxadiargyl, oxadiazon, paclobutrazol, pyraflufen, pyraflufen-ethyl, pyrasulfotole, pyrazolate, pyrazolynate, pyrazoxyfen, pyroxasulfone, sulfentrazone sulfentrazone), topramezone, uniconazole, uniconazole-P, 1-methylcyclopropene, 2,6-diisopropylnaphthalene, 6-benzylaminopurine, 6-isoamylaminopurine, allidochlor, aminocyclopyrachlor, aminocyclopyrachlor-methyl, aminocyclopyrachlor-potassium,

[0014] B5: aminopyralid, ammoniumpelargonate, ammoniumsulfamat, aviglycine, benazolin, benazolin-ethyl, benfluralin, benfuresate, bentazone, benzobicyclon, brassinolide, bromofenoxim, butralin, chlorfenac, chlorfenac-sodium, chlorfenprop, chlorflurenol, chlorflurenol-methyl, chloridazon, chlormequatchloride ), chlorphthalim, chlorthal-dimethyl, cinidon, cinidon-ethyl, cinmethylin, clofencet, clomazone, cloxyfonac, cyanamide, cyclanilide, cyclopyrimorate, dalapon, daminozide, dazomet, difenzoquatmetilsulfate, dikegulac, dikegulac-sodium, dimethipin, diinitramine, dinoterb, diquat, diquat dibromodibromide), dithiopyr, DNOC, endothal, endothal-dipotassium, endothal-disodium, endothal-mono(N), ethafluralin, ethofumesate, ethylchlozate, flamprop, flamprop-M-isopropyl, flamprop-M-methyl, fluchloralin, flufenpyr, flupyridazine Flumetralin, flumichlorac, flumiclorac-pentyl, flumioxazin, flupropanate, flurenol, flurenol-butyl, flurenol-dimethylammonium-methyl, fluridone, flurochloridone, flurtamone, fluthiacet, fluthiacet-methyl, gibberillic acid acid), halauxifen, indanofan, isoprothiolane, kinetin, maleic hydrazide, mepiquat chloride, metam, methiozolin, methylarsonic acid, methylisothiocyanate, N-acetylthiazolidine-4-carboxylic acid, n-decyl alcohol, N-dimethylalkylammonium), nitrophenolate mixture, nonanoic acid, norflurazon, n-propyl dihydrojasmonatedihydrojasmonate, oleic acid, oryzalin, oxaziclomefone, paraquat, paraquatdichloride, pendimethalin, pentachlorophenol, pentoxazone, mineral oil, prodiamine, pyridafol, pyridate, quinoclamine, sintofen, TCA, TCA-sodium, tecnazene, thiazopyr, triacontanol, triafamone, trifluralin, urea sulfate, zeatin,

[0015] B6: 1-naphtylacetic acid, 2-(1-naphthyl)acetamide, 2,3,6-TBA, 2-naphthyloxyacetic acid, 4-indol-3-ylbutyric acid, chloramben, clopyralid, dicamba, fluroxypyr, fluroxypyr-meptyl, inabenfide, indol-3-ylacetic acid, picloram, quinclorac, quinmerac, triclopyr,

[0016] B7: anilofos, bensulide, bilanafos, bilanafos-sodium, butamifos, clacyfos, ethephon, fosamine, glufosinate, glufosinate-ammonium, glufosinate-P, glufosinate salts, glufosinate-sodium, glyphosate, glyphosate-ammonium, glyphosate-diammonium diammonium), glyphosate-dimethylammonium, glyphosate-isopropyl-ammonium, glyphosate-potassium, glyphosate salts, glyphosate-sodium, glyphosate-trimesium (= sulfosate), L-glufosinate-ammonium, L-glufosinate-sodium, piperophos, tribufos,

[0017] B8: 2,4-D, 2,4-D-2-ethylhexyl ester, 2,4-DB, 2,4-D-butoxyethyl ester (2,4-D-butotyl), 2,4-D-butyl ester, 2,4-D-dimethylammonium salt, 2,4-D-diethanolamine (2,4-D-diolamin), 2,4-D-ethyl ester, 2,4-D-isobutyl ester, 2,4-D-isooctyl ester, 2,4-D-isopropylammonium salt, 2,4-D-potassium salt, 2,4-D-triisopropanol ammonium salt, 2,4-D-triethanolamine (2,4-D-trolamine), 4-CPA, acifluorfen, acifluorfen-sodium , aclonifen, bifenox, clodinafop-ethyl, clodinafop-propargyl, clomeprop, cloprop, cyhalofop, cyhalofop-butyl, dichlorprop, dichlorprop-P, diclofop, diclofop-meth yl), diclofop-P, diclofop-P-methyl, ethoxyfen-ethyl, fenoxaprop, fenoxaprop-P, fenoxaprop-P-ethyl, fluazifop, fluazifop-butyl, fluazifop-P ... luoroglycofen, fluoroglycofen-ethyl, fomesafen, fomesafen-sodium, halosafen, haloxyfop, haloxyfop-P, lactofen, MCPA, MCPA-2-ethylhexyl, MCPA-butotyl, MCPA-dimethylammonium,MCPA-isopropylammonium salt (MCPA-isopropylammonium), MCPA-potassium salt (MCPA-potassium), MCPA-sodium salt (MCPA-sodium), MCPB, MCPB-ethyl-sodium salt (MCPB-ethyl), MCPB-methyl ester (MCPB-methyl), 2-methyl-4-chloropropionic acid (mecoprop), 2-methyl-4-chloropropionic acid butoxyethyl ester (mecoprop-butotyl), 2-methyl-4-chloropropionic acid (mecoprop-P), 2-methyl-4-chloropropionic acid 2-ethylhexyl ester (mecoprop-P-2-ethylhexyl), 2-methyl-4-chloropropionic acid butoxyethyl ester (mecoprop-P-bu totyl), mecoprop-P-dimethylammonium, mecoprop-P-potassium, mecoprop-sodium, metamifop, oxyfluorfen, propaquizafop, quizalofop, quizalofop-ethyl, quizalofop-P, quizalofop-P-ethyl, quizalofop-P-tefuryl,

[0018] B9: ancymidol, bispyribac, bispyribac-sodium, bromacil, butafenacil, ethyl [(3-{2-chloro-5-[2,6-dioxo-4-(trifluoromethyl)-3,6-dihydropyrimidin-1(2H)-yl]-4-fluorophenoxy}pyridin-2-yl)oxy]acetate, flurprimidol, lenacil, pyribambenz, pyribamb enz-isopropyl), pyribambenz-propyl, pyribenzoxim, pyriftalid, pyriminobac, pyriminobac-methyl, pyrimisulfan, pyrithiobac, pyrithiobac-sodium, saflufenacil, terbacil, tifenacil,

[0019] B10: chlorbromuron, chlorotoluron, cumyluron, daimuron, diflufenzopyr, diflufenzopyr-sodium, dimefuron, diuron, fluometuron, forchlorfenuron, isoproturon, karbutilate, linuron, methabenzthiazuron, metobromuron, metoxuron, monolinuron, neburon, siduron, tebuthiuron, terbucarb, thidiazuron,

[0020] B11: ametryn, atrazine, cyanazine, cyprazine, dimethametryn, ethiozin, hexazinon, indaziflam, metamitron, metribuzin, prometon, prometryn, propazine, simazine, simetryn, terbumeton, terbuthylazine, terbutryn, triaziflam, trietazine. DETAILED DESCRIPTION

[0021] In another embodiment, these herbicidal compositions comprise (C) one or more safeners (component C) selected from benoxacor (C1), cloquintocet-mexyl (C2), cyprosulfamide (C3), dichlormid (C4), fenclorim (C5), fenchlorazole (C6), furilazole (C7), isoxadifen-ethyl (C8), mefenpyr-diethyl (C9), 4-(dichloroacetyl)-1-oxa-4-azaspiro[4.5]decane of CAS 71526-07-3 (C10), 2,2,5-trimethyl-3-(dichloroacetyl)-1,3-oxazolidine of CAS 52836-31-4 (C11).

[0022] Components B) and C) are known, for example, from "The Pesticide Manual", 15th edition, The British Crop Protection Council and the Royal Soc. of Chemistry and from the website http: / / www.alanwood.net / pesticides / .

[0023] Preferred component B are the following herbicides:

[0024] B1: flupyralid, clethodim, mesotrione, pinoxasol, sethoxydim, sulfotrione, furansulfuron, cypermethrin, pyraclostrobin, trimethylolpropane,

[0025] B2: Acetochlor, Alachlor, Amidosulfuron, Sulfuryl, Butachlor, Bisaccharide, Chlorsulfuron-methyl Ethyl, Cyprosulfuron-methyl, Betaine, Flufenacet, Dimethachlor, Dimethachlor S-P, Pentocarb, Ethoxysulfuron, Bisaccharide, Fluoxetine Sodium, Flufenacet, Flufenacet Sodium, Foramsulfuron, Iodosulfuron-methyl, Iodosulfuron Sodium, Mefenacet, Disulfuron, Mesosulfuron, Methiachlor, Isopropylamine, Sulfuramide, Mesosulfuron , fensulfuron, fensulfuron-methyl, penoxsulam, pethosulfuron, betaine, flupyralid, pretilachlor, propanil, propanil, propoxysulfone, propyzamide, bensulfuron, prosulfuron, pyrazosulfuron-methyl, methoxysulfuron, sulfamethoxazole, isopropylamine, sulfamethoxazole, dimethenamid, thiencarbazone, thifensulfuron-methyl, thifensulfuron-methyl methyl, fensulfuron, bensulfuron-methyl methyl, trifloxysulfuron (sodium salt), trifloxysulfuron,

[0026] B3: Bromobenzonitrile, heptanoyl bromoxynil, octanoyl bromoxynil, iodobenzonitrile,

[0027] B4: amitriptyline, pyraclostrobin, mesotrione, pyraclostrobin, tetrazoline, imazamox, imazethapyr, isoxathiapiprolin, oxadiazine, pyraclostrobin, sulfamethoxazole, sulfamethoxazole, pyraclostrobin ...

[0028] B5: Aminopyralid, benzylpyrazone, furamizulin, bentazone, indolepyralid, clomazone, diquat dibromide, ethoxyfurantoin, fluazifop-butyl, fluazifop-butyl, fluazifop-butyl, fluazifop-butyl, oxazithromycin, pendimethalin, pyraclostrobin, trifluralin,

[0029] B6: clopyralid, dicamba, clofopyralid, amiloride, quinclorac, triclopyralid,

[0030] B7: silanthoxyphos, glufosinate, glufosinate ammonium, glyphosate, glyphosate ammonium, glyphosate diammonium, glyphosate isopropyl ammonium, glyphosate potassium, L-glufosinate ammonium,

[0031] B8: 2,4-D, 2,4-D-dimethylammonium salt, trifluorfen sodium salt, benifloxybutyl, cypermethrin, clodinafop-butyl propargyl, cyhalofop-butyl, 2,4-dichloropropionic acid, diclofenac, diclofenac, ethyl fluazifop-butyl, butyl fluazifop-butyl, fluazifop-butyl, MCPA, 2-methyl-4-chloropropionic acid, oxyfluorfen, quizalofop-butyl,

[0032] B9: bispyribac-sodium, herbicide, ethyl [(3-{2-chloro-5-[2,6-dioxo-4-(trifluoromethyl)-3,6-dihydropyrimidin-1(2H)-yl]-4-fluorophenoxy}pyridin-2-yl)oxy]acetate, cypermethrin, cypermethrin, saflufenacil,

[0033] B10: benzylthiocarb, cypermethrin, diflupyr, diuron, and isoproturon.

[0034] B11: ametryn, atrazine, indomethacin, metamitron, metribuzin, simazine, terbuthion, terbuthion.

[0035] Particularly preferred components B are the following herbicides:

[0036] B1: flupyralid, clethodim, mesotrione, pinoxaden, sulfotrione, furansulfuron, cypermethrin,

[0037] B2: Acetochlor, Acetosulfuron-methyl, Sulfuryl, Betachlor, Fluazifop, Dimethazone, S-Dimethazone, Ethoxysulfuron-methyl, Bispyribac, Fluoxetine Sodium, Flufenacet, Foramsulfuron, Iodosulfuron Sodium, Mefenacet, Mesosulfuron, Mesosulfuron, Methiazolin, Sulfuramide, Methiosulfuron, Mesosulfuron, Naprofil, Pethodiol, Betachlor, Propylsulfuron-methyl, Benthiocarb, Methoxysulfuron, S-Isopropylamine, Sulfursulfuron-methyl, Thiencarbazone, Thifensulfuron-methyl, Thifensulfuron-methyl Methyl, Bensulfuron-methyl Methyl, Trifloxysulfuron,

[0038] B3: Bromoxynil, heptanoyl bromoxynil, octanoyl bromoxynil,

[0039] B4: Amitriptyline, tetrazopyrazone, methoxyfen-2, isoxathiapiprolin, oxadiazine, oxadiazine, pyrasulfotole, pyrasulfotole, pyrasulfotole,

[0040] B5: Aminopyralid, Furoxanthin, Ethoxyfuroxanthin, Furoxanthin, Oxamipuridine,

[0041] B6: Dicamba,

[0042] B7: Glufosinate, glufosinate ammonium salt, glyphosate, glyphosate potassium salt, L-glufosinate ammonium salt,

[0043] B8: 2,4-D, 2,4-D-dimethylammonium salt,

[0044] B9: bispyribac-sodium, herbicide, ethyl [(3-{2-chloro-5-[2,6-dioxo-4-(trifluoromethyl)-3,6-dihydropyrimidin-1(2H)-yl]-4-fluorophenoxy}pyridin-2-yl)oxy]acetate, saflufenacil,

[0045] B11: atrazine, indomethacin, fluazifop, metamitron, metribuzin, terbuthion.

[0046] Very particularly preferred components B are the following herbicides:

[0047] B1: Mesotrione, Cypersulfuron,

[0048] B2: Acetochlor, difluanid, dimethinaton, foramsulfuron-methyl, thiamethoxam-methyl,

[0049] B3: Bromoxynil,

[0050] B4: isoxathiapiprolin,

[0051] B6: Dicamba,

[0052] B7: Glufosinate, glufosinate ammonium, glyphosate, glyphosate potassium,

[0053] B8: 2,4-D,

[0054] B9: saflufenacil,

[0055] B11: atrazine, terbuthylazine.

[0056] The herbicidal compositions according to the invention may comprise or be used together with additional further components, such as, for example, other types of active crop protection ingredients and / or additives and / or formulation auxiliaries customary in crop protection.

[0057] The herbicides (A), (B) and any safeners (C) can be applied in a known manner, for example, jointly (for example in the form of a combined formulation or a tank mix), or in a short-term continuous manner at different times (in batches), for example, to plants, plant parts, plant seeds or areas where plants grow. For example, a single active ingredient or herbicide-safener composition can be applied in multiple batches (sequential application), for example, first pre-emergence application, then post-emergence application, or first early post-emergence application, then post-emergence application in the middle or late period. Preferably, the active ingredients in the corresponding composition are applied continuously in combination or immediately. It is also possible to use a single active ingredient or herbicide-safener composition for seed treatment.

[0058] In the herbicidal composition of the present invention, the application rate of component (A) is typically 0.01 to 200 g ai. / ha (grams of active ingredient per hectare), preferably 0.02 to 150 g ai / ha, more preferably 0.05 to 120 g ai / ha. In the herbicidal composition of the present invention, the application rate of component (B) is typically 0.01 to 400 g ai / ha, preferably 0.05 to 300 g ai / ha, more preferably 0.1 to 200 g ai / ha.

[0059] After application of the herbicidal composition according to the invention, a very broad spectrum of harmful plants, such as annual and perennial monocotyledonous or dicotyledonous weeds and unwanted crop plants, are controlled both before and after emergence. The herbicidal composition according to the invention is particularly suitable for crops such as cereals, corn, rice, soybeans, rapeseed, sugar beet, cotton, sugar cane, and also for perennial crops, plantations and uncultivated land. Furthermore, they are also very suitable for transgenic crops of maize, corn, sugar beet, rice, cotton and soybean (Glycine max.) (e.g. RR soybean or LL soybean) and their hybrids, Phaseolus, Pisum, Vicia and Arachis, or vegetable crops from different plant groups, such as potato, leek, cabbage, carrot, tomato, onion, and perennial and plantation crops, such as pome and stone fruit, soft fruit, grapes (wine), rubber trees (Hevea), bananas, sugar cane, coffee, tea, citrus, nut plantations, lawns, palm crops and forest crops. For the use of the herbicide-safener combinations (A)+(B) according to the invention, these crops are also preferred, with particular preference for cereals (e.g. wheat, barley, rye, oats), rice, maize, millet / sorghum, sugar beet, sugar cane, sunflower, rape and cotton. The herbicide-safener combination (A) + (B) can also be used in tolerant and non-tolerant mutant crops and tolerant and non-tolerant transgenic crops, preferably tolerant and non-tolerant mutant crops and tolerant and non-tolerant transgenic crops of the following plants: corn, rice, corn, rapeseed, cotton, sugar beet and soybean, for example those crops that are resistant to imidazolinone herbicides, atrazine, glufosinate, glyphosate, 2,4-D, dicamba and herbicides selected from the group consisting of inhibitors of hydroxyphenylpyruvate dioxygenase (for example sulcotrione, mesotrione, cypermethrin, furansulfuron, bicyclon, fluazifop and ketospiradox).

[0060] In the sense of the present invention, "herbicidal active amount" is a suitable amount of one or more herbicides that have an adverse effect on plant growth. In the sense of the present invention, "antitoxic active amount" means a suitable amount of one or more safeners that reduces the phytotoxic effects of active compounds (e.g. herbicides) in crop protection compositions on crop plants.

[0061] The safener (C) present in the herbicidal composition of the present invention can also be used for pretreatment of the seeds of crop plants (e.g., for seed dressing) according to its characteristics, or applied to the sowing furrow before sowing, or applied together with the herbicide before or after the plants emerge. Pre-emergence treatment includes the treatment of the planting area (including any water present in the planting area, such as in the case of application to rice) before sowing, and the treatment of the planting area that has been sown but not yet covered by the growing plants. It is preferably applied together with the herbicide. For this reason, a tank mix or a pre-made preparation can be used.

[0062] In a preferred embodiment, seeds (e.g., cereals, seeds or vegetative propagation organs such as tubers or sprouting parts with shoots) or seedlings are pretreated with safener (C), optionally in combination with other active agricultural chemical ingredients. For seed pretreatment, the active compound can be applied to the seeds, for example, by seed dressing, or the active compound and the seeds are added to water or other solvents and the active compound can be absorbed, for example, by adsorption or diffusion during immersion, or by swelling or pregermination. For seedling pretreatment, the seedlings can be contacted with the safener, optionally in combination with other active agricultural chemical ingredients, for example, by spraying, dipping or watering, and then transplanted and optionally post-treated with herbicides (A) and (B).

[0063] The seeds or seedlings can be treated with the safener (C) alone or together with other active agricultural chemical ingredients, such as fungicides, insecticides or plant enhancers, fertilizers or swelling and germination promoters. After the pretreatment application, the safener can then be applied again before, after or together with the herbicide (A) of formula (I-5) and the herbicide (B), or in combination with other known herbicides. Pretreatment of seeds or seedlings can improve the long-term efficacy of the safener.

[0064] The present invention therefore also provides a method for controlling unwanted plants in plant crops, characterized in that the components (A), (B) and optionally (C) of the herbicidal composition according to the invention are applied, for example jointly or individually, to plants (e.g. harmful plants, such as monocotyledonous or dicotyledonous weeds or unwanted crop plants), seeds (e.g. cereals, seeds or vegetative propagation organs, such as tubers or sprouting parts with shoots) or to areas where plants grow (e.g. planting areas). One or more safeners (C) can be applied to plants, seeds or areas where plants grow (e.g. planting areas) before, after or simultaneously with the herbicides (A) and herbicides (B) of the formula (I-5). In a preferred embodiment, the safener (C) is used for seed treatment.

[0065] Unwanted plants are understood to mean all plants that grow in locations where they are not wanted. These plants may, for example, be harmful plants (for example monocotyledonous or dicotyledonous weeds or unwanted crop plants), including, for example, those plants that are resistant to certain active herbicidal compounds (for example glyphosate, atrazine, glufosinate or imidazolinone herbicides).

[0066] Monocotyledonous weeds are, for example, from the genera Echinochloa, Setaria, Panicum, Digitaria, Phleum, Poa, Festuca, Eleusine, Brachiaria, Lolium, Bromus, Avena, Cyperus, Sorghum, Agropyron, n), Cynodon, Monochoria, Fimbristylis, Sagittaria, Eleocharis, Scirpus, Paspalum, Ischaemum, Sphenoclea, Dactyloctenium, Agrostis, Alopecurus, and Apera. Dicotyledonous weeds are, for example, from the genera Sinapis, Lepidium, Galium, Stellaria, Matricaria, Anthemis, Galinsoga, Chenopodium, Urtica, Senecio, Amaranthus, Portulaca, Xanthium, Convolvulus, Ipomoea, Polygonum, Sesbania, Ambrosia, Thistle, Cirsium, Carduus, Sonchus, Solanum, Rorippa, Rotala, Lindernia, Lamium, Veronica, Abutilon, Emex, Datura, Viola, Galeopsis, Papaver, Centaurea, Trifolium, Ranunculus, Taraxacum, Euphorbia.

[0067] The invention further provides for the use of the herbicidal compositions according to the invention for controlling unwanted vegetation, preferably in plant crops.

[0068] The herbicidal composition of the present invention can be prepared by known methods, for example, in the form of a mixed formulation of each component, optionally containing other active ingredients, additives and / or conventional formulation auxiliaries, and then diluted with water in a conventional manner and applied, or by diluting each component prepared separately or partially separately with water together and applying in the form of a bucket mixture. It is also feasible to apply (apply in batches) each component prepared separately or partially separately at different times. Each component or herbicidal composition can also be applied (sequentially), for example, first pre-emergence application, then post-emergence application, or first early post-emergence application, then mid-term or late post-emergence application. It is preferred to apply jointly or immediately apply the active ingredient in the corresponding composition continuously.

[0069] The herbicidal compositions according to the invention can also be used for controlling harmful plants in crops of genetically modified plants which are known or yet to be developed.

[0070] Typically, transgenic plants are characterized by particularly advantageous properties, such as resistance to certain pesticides, in particular certain herbicides, resistance to plant diseases or pathogens of plant diseases, such as certain insects or microorganisms such as fungi, bacteria or viruses. Other specific properties relate, for example, to the quantity, quality, storage, composition and specific ingredients of the harvested material. For example, there are known transgenic plants with increased starch content or altered starch quality, or those with different fatty acid compositions in the harvested material. Other specific properties may be tolerance or resistance to abiotic stresses, such as high temperature, low temperature, drought, salinity and ultraviolet radiation.

[0071] The herbicidal compositions according to the invention are preferably used in transgenic crops of economically important useful and ornamental plants, for example cereals such as wheat, barley, rye, oats, millet / sorghum, rice, cassava and corn, or crops such as sugar beet, cotton, soybean, rapeseed, potato, tomato, pea and other plants.

[0072] Conventional methods for producing new plants with improved properties compared to existing plants include, for example, traditional breeding methods and the generation of mutants. Alternatively, new plants with improved properties can be produced by recombinant methods (see, for example, EP-A-0221044, EP-A-0131624). For example, the following cases have been described:

[0073] - genetic modification of crop plants with the aim of modifying the starch synthesized in the plants (e.g. WO 92 / 11376, WO 92 / 14827, WO 91 / 19806),

[0074] - transgenic crop plants resistant to specific herbicides of the glufosinate group (see, for example, EP-A-0242236, EP-A-242246) or the glyphosate group (WO 92 / 00377) or the sulfonylurea group (EP-A-0257993, US-A-5013659),

[0075] - transgenic crop plants, such as cotton, which are capable of producing Bacillus thuringiensis toxins (Bt toxins) which render the plants resistant to specific pests (EP-A-0142924, EP-A-0193259),

[0076] - transgenic crop plants with altered fatty acid composition (WO 91 / 13972),

[0077] - Genetically modified crop plants with new components or secondary metabolites that confer enhanced disease resistance (e.g. new phytoalexins) (EPA 309862, EPA 0464461),

[0078] - Genetically modified plants with reduced photorespiration, which plants have higher yield and greater stress tolerance (EPA 0305398),

[0079] - transgenic crop plants producing pharmaceutically or diagnostically important proteins ("molecular pharming"),

[0080] - genetically modified crop plants characterized by higher yield or better quality,

[0081] - Transgenic crop plants which have, for example, a combination of the above-mentioned new traits ("gene stacking")

[0082] As a feature.

[0083] In principle, many molecular biology techniques are known which can be used to produce novel transgenic plants with improved properties; see, for example, I. Potrykus and G. Spangenberg (eds.) Gene Transfer to Plants, Springer Lab Manual (1995), Springer Verlag Berlin, Heidelberg, or Christou, "Trends in Plant Science" 1 (1996) 423-431.

[0084] For such genetic manipulations, nucleic acid molecules that allow mutations or sequence changes by recombinant DNA sequences can be introduced into plasmids. With the aid of standard methods, for example, base exchanges, removal of partial sequences, or addition of natural or synthetic sequences can be performed. In order to connect DNA fragments to each other, adapters or linkers can be added to the fragments; see, for example, Sambrook et al., 1989, Molecular Cloning, A Laboratory Manual, 2nd edition, Cold Spring Harbor Laboratory Press, Cold Spring Harbor, NY; or Winnacker "Gene und Klone" [Genes and Clones], VCH Weinheim, 2nd edition, 1996.

[0085] The production of plant cells with reduced activity of a gene product can be achieved, for example, by expressing at least one corresponding antisense RNA, a sense RNA for achieving co-suppression, or by expressing at least one appropriately constructed ribozyme which specifically cleaves the transcript of the above-mentioned gene product.

[0086] For this purpose, it is firstly possible to use DNA molecules that contain the entire coding sequence of the gene product (including any flanking sequences that may be present), as well as DNA molecules that contain only parts of the coding sequence, in which case these parts must be long enough to have an antisense effect in the cell. It is also possible to use DNA sequences that have a high degree of homology to the coding sequence of the gene product, but are not completely identical to them.

[0087] When expressing nucleic acid molecules in plants, the synthesized protein can be located in any desired compartment of the plant cell. However, in order to achieve localization in a specific compartment, for example, the coding region can be connected to a DNA sequence that ensures localization in a specific compartment. These sequences are known to those skilled in the art (see, for example, Braun et al., EMBO J. 11 (1992), 3219-3227; Wolter et al., Proc. Natl. Acad. Sci. USA 85 (1988), 846-850; Sonnewald et al., Plant J. 1 (1991), 95-106). The nucleic acid molecules can also be expressed in the organelles of plant cells.

[0088] The transgenic plant cells can be regenerated by known techniques to obtain complete plants. In principle, the transgenic plants can be plants of any desired plant species, ie not only monocotyledons but also dicotyledons.

[0089] In this way, transgenic plants can be obtained whose properties are altered by overexpression, suppression or inhibition of homologous (=natural) genes or gene sequences, or by expression of heterologous (=foreign) genes or gene sequences.

[0090] The composition of the present invention can preferably be used in transgenic crops that are resistant to growth regulators such as dicamba, or to herbicides that inhibit essential plant enzymes such as acetolactate synthase (ALS), EPSP synthase, glutamine synthetase (GS) or hydroxyphenylpyruvate dioxygenase (HPPD), or to herbicides selected from sulfonylureas, glyphosate, glufosinate or benzoylisoxazoles and similar active ingredients.

[0091] When the compositions of the present invention are used in transgenic crops, not only the effects on harmful plants observed in other crops are produced, but also often effects specific to the application in a particular transgenic crop are produced, such as an altered or particularly broadened spectrum of weeds that can be controlled, an altered application rate that can be used for application, preferably good compatibility with herbicides to which the transgenic crop is resistant, and an influence on the growth and yield of the transgenic crop plants.

[0092] The present invention therefore also provides the use of the compositions according to the invention for controlling harmful plants in transgenic crop plants.

[0093] The compositions according to the invention are preferably used in transgenic crops of economically important useful and ornamental plants, such as cereals (e.g. wheat, barley, rye, oats), millet / sorghum, rice, cassava and corn, or crops of sugar beet, cotton, soybean, rapeseed, potato, tomato, pea and other plants.

[0094] The present invention therefore also provides for the use of the compositions according to the invention for controlling harmful plants in transgenic crop plants or in crop plants that have been made tolerant by selective breeding.

[0095] The herbicides (A), (B) and any safeners (C) can be converted together or separately into conventional formulations, such as solutions, emulsions, suspensions, powders, foams, pastes, granules, aerosols, natural and synthetic substances impregnated with the active ingredient, microcapsules in polymers, for example, for application by spraying, watering, sprinkling and seed dressing. The formulations may contain conventional adjuvants and additives.

[0096] These formulations are prepared in a known manner, for example by mixing the active compounds with extenders, ie liquid solvents, pressurized liquefied gases and / or solid carriers, optionally with the use of surfactants, ie emulsifiers and / or dispersants, and / or foam formers.

[0097] When the extender used is water, it is also possible to use, for example, organic solvents as auxiliary solvents. Useful liquid solvents are primarily: aromatic hydrocarbons, such as xylene, toluene or alkylnaphthalene; chlorinated aromatic hydrocarbons or chlorinated aliphatic hydrocarbons, such as chlorobenzene, vinyl chloride or methylene chloride; aliphatic hydrocarbons, such as cyclohexane or paraffins, such as mineral oil fractions, mineral oils and vegetable oils; alcohols, such as butanol or ethylene glycol and their ethers and esters; ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone; strongly polar solvents, such as dimethylformamide or dimethyl sulfoxide; and water.

[0098] Useful solid carriers include, for example, ammonium salts and ground natural minerals, such as kaolin, clay, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth, and ground synthetic minerals, such as finely divided silica, alumina and silicates; useful solid carriers for granules include, for example, crushed and classified natural rocks, such as calcite, marble, pumice, sepiolite, dolomite and synthetic particles of inorganic and organic powders, and particles of organic materials, such as sawdust, coconut shells, corn cobs and tobacco stalks; useful emulsifiers and / or foaming agents include, for example, nonionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers (such as alkylaryl polyethylene glycol ethers), alkyl sulfonates, alkyl sulfates, aryl sulfonates and protein hydrolysates; useful dispersants include, for example, lignin sulfite waste liquor and methylcellulose.

[0099] In the preparation, viscosity enhancers such as carboxymethylcellulose, natural and synthetic polymers in the form of powders, granules or latexes such as gum arabic, polyvinyl alcohol and polyvinyl acetate, and natural phospholipids (such as cephalin and lecithin) and synthetic phospholipids can be used. Other additives can be mineral oils and vegetable oils.

[0100] Colorants may be used, for example inorganic pigments such as iron oxide, titanium oxide and Prussian blue, and organic colorants such as alizarin colorants, azo colorants and metal phthalocyanine colorants, and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.

[0101] The formulations generally comprise from 0.1% to 95% by weight of active compound, preferably from 0.5% to 90% by weight.

[0102] The herbicides (A), (B) and any safeners (C) - as such or in their formulations - can also be used in the form of a mixture with other active agrochemical ingredients for controlling unwanted vegetation, for example for controlling weeds or for controlling unwanted crop plants, for example as ready-made formulations or tank mixes.

[0103] A mixture with other known active ingredients, such as fungicides, insecticides, acaricides, nematicides, bird antifeedants, plant nutrients and soil conditioners, and likewise with additives and formulation auxiliaries customary in crop protection, is also possible.

[0104] The herbicides (A), (B) and any safeners (C) can be used in their own form, in the form of their formulations or in the use forms prepared by further dilution thereof, such as ready-to-use solutions, suspensions, emulsions, powders, pastes and granules. Application is typically achieved, for example, by watering, spraying, atomizing, broadcasting.

[0105] The active compound can be applied to plants, plant parts, seeds or planting areas (farmland), preferably to seeds or green plants and plant parts, and optionally additionally to farmland. One possible use is to apply the active ingredients together in the form of a tank mix, wherein the best formulated concentrates of the individual active ingredients are mixed with water in a bucket and the resulting spray liquor is then applied.

[0106] The combined formulation of the herbicide (A), (B) and optionally (C) according to the invention has the advantage that the application is more convenient because the dosage of each component can already be set to an optimal ratio. In addition, the adjuvants in the formulation can be optimized with respect to each other.

[0107] For application, the commercially available formulations are diluted, if appropriate, in a customary manner, for example with water in the case of wettable powders, emulsifiable concentrates, dispersants and water-dispersible granules. Formulations in the form of powders, granules for soil application or granules for broadcasting and sprayable solutions are usually not diluted further with other inert substances before application.

[0108] Biological Examples:

[0109] The abbreviations used for harmful plants have the following meanings:

[0110] AMATA=Amaranthus tamariscinus

[0111] CENCY=Centaurea cyanus

[0112] CHRVI=Chloris virgata

[0113] CYPIR = Cyperus iria

[0114] EPHHL = Euphorbia heterophylla

[0115] ERIBO=Erigeron bonariensis

[0116] POAAN = Poa annua

[0117] SETFA = Setaria faberi

[0118] SOLNI = Solanum nigrum

[0119] SONOL=Sonchus oleraceus

[0120] VLPMY=Vulpia myuros

[0121] XANST=Xanthium strumarium

[0122] BRSNW Brassica napus (winter rapeseed)

[0123] GLXMA Soybean (Glycine max) (Soybean)

[0124] ORYZA Rice (Oryza sativa)

[0125] TRZAS wheat (Triticum aestiva) (bread wheat)

[0126] ZEAMXCorn (Zea mays) (Corn)

[0127] Post-emergence herbicidal effect on harmful plants

[0128] Seeds of monocotyledonous and dicotyledonous weeds and crop plants are spread in sandy loam in wood fiber pots, covered with soil and cultivated in a greenhouse under good growth conditions. The test plants are treated at the one-leaf stage 2 to 3 weeks after sowing. The compounds of the invention, formulated in the form of wettable powders (WP) or emulsifiable concentrates (EC), are then sprayed onto the green parts of the plants in the form of aqueous suspensions or emulsions with the addition of 0.2% wetting agent and at a water application rate equivalent to 600 to 800 l / ha. After the test plants have been placed in the greenhouse under optimal growth conditions for about 3 weeks, the effect of the preparations compared with the untreated control group is visually evaluated (herbicidal effect in percentage (%): 100% activity = plant has died, 0% activity = similar control plants). Many compounds of the invention have very good effects on a variety of important harmful plants. The following table shows the post-emergence herbicidal effect of the compounds of the invention by way of example, the herbicidal activity being expressed in percentage.

[0129] Comparative experiment

[0130] In a comparative experiment, the herbicidal efficacy of the composition according to the invention was compared with the herbicidal efficacy of the corresponding composition known from WO 2015 / 059187 A1 under the specified conditions by the post-emergence method. The example numbers given in the table are associated with the compounds disclosed in the corresponding document.

[0131] E means the expected synergistic effect value according to Colby's formula.

[0132] ΔSYN refers to the difference between the actual synergistic effect value and the expected synergistic effect value.

[0133] A1-14 refers to the compound of the following formula (racemic) known from WO 2015 / 059187 A1:

[0134]

[0135] I-5 refers to a chiral (S-configuration) compound of the following formula:

[0136]

[0137] The data of the comparative experiment show that the composition of the present invention exhibits a higher synergistic effect compared with the similar composition known from WO 2015 / 059187 A1.

[0138]

[0139]

[0140]

[0141]

[0142]

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Claims

1. A herbicidal composition comprising (A) a compound having an absolute configuration specified by formula (I-5) (component A) or a salt thereof, and (B) one or more herbicides selected from Groups B1 to B11 (Component B): B1: fenpyroxil, fenpyroxil sodium, fluazifop, butyclotrim, clethodim, cyclathione, ketospiradox, mesotrione, pinoxaden, cyproconazole, prohexadione, prohexadione calcium salt, sethoxydim, sulfotrione, furansulfuron, cyproconazole, pyraclostrobin, trimethylolpropane, trinexapac-ethyl, B2: acetochlor, alachlor, acetochlor, sulfamethoxam, sulfamethoxam, tetrazosulfuron, flubutyric acid, bensulfuron, benzylsulfuron, bromobutyric acid, butachlor, butachlor, butachlor, butachlor, carbaryl, bisacodyl, chlorimuron, chlorimuron ethyl, chlorpropamide, chlorsulfuron, ethersulfuron, chlorsulfuron, chlorsulfuron acid, chlorsulfuron, cyclosulfuron, cyprosulfuron, betaine, bisacodyl, pyrifos, piperidine, dimethoate, and spirit Dimethazone, bisbenzamide, EPTC, pentocarb, ethametsulfuron-methyl, methyl ethametsulfuron-methyl, ethoxysulfuron-methyl, ethoxybenzamide, fluazifop-butyl, bispyribac, fluazifop-butyl, fluazifop-butyl, fluazifop-butyl sodium, flutosulfuron-methyl, flufenacet, flufenacet, flutosulfuron-butyl sodium, foramsulfuron-methyl, chlorpyrifossulfuron-methyl, pyrasulfuron-methyl, dimethoate, iodosulfuron-methyl, iodosulfuron-methyl sodium, triazolam, mefenacet, flusulfuron, disulfuron, methyl disulfuron, pyrasulfuron Amine, pyrazosulfuron-methyl, sulfamethoxam, sulfamethoxam, sulfamethoxam, isopropylamine, sulfamethoxam, sulfamethoxam, sulfamethoxam, chloranil, monosulfuron, monosulfuron, nicosulfuron, N-phenyl-o-aminobenzoic acid, pyraclostrobin, pyrimethoxam, epoxysulfuron, kecaomen, penoxsulam, pethodiola, betaine, flupyralid, pretilachlor, primisulfuron, pyraclostrobin, propamid, fenamicarb, isopropylamine, propasulfuron, propazine, propasulfuron, propazine, Fensulfuron-methyl, pyrazosulfuron-methyl, pyrazosulfuron-methyl ethyl, methoxysulfone, sulfamethoxazole, propensulfuron-methyl sodium salt, s-isopropylamine, sulfamethoxazole acid, sulfamethoxazole-methyl, sulfamethoxazole-methyl, dimethenamid, thiencarbazone, thifensulfuron-methyl, thifensulfuron-methyl methyl, thifensulfuron-methyl, thifensulfuron-methyl methyl, fensulfuron, wild wheat chlorpyrifos, ether bensulfuron-methyl, bensulfuron-methyl, bensulfuron-methyl methyl, trifloxysulfuron, trifloxysulfuron (sodium salt), flufenac, flufenac methyl, trifloxysulfuron, fensulfuron-methyl, trifloxysulfuron, fensulfuron-methyl, barnyard grass dan, B3: bromoxynil, butyryl bromoxynil, heptanoyl bromoxynil, octanoyl bromoxynil, bromoxynil potassium salt, detoluenesulfonyl-pyrazol (DTP), dichlobenil, ioxazolidinone, octanoyl ioxazolidinone, ioxazolidinone potassium salt, ioxazolidinone sodium salt, bispyribac, B4: amitriptyline, cypermethrin, oxazolidinone, pyraclostrobin, mesotrione, pyraclostrobin, pyraclostrobin, benzylpyrazone, tetrazoline, imazapic acid, imazapic acid methyl, methoxyimazapic acid, methoxyimazapic acid ammonium salt, imazapic acid, imazapic acid ammonium salt, imazapic acid, imazapic acid isopropyl ammonium salt, imazaquinoline acid, imazaquinoline acid ammonium salt, imazaquinoline acid, imazaquinoline acid iminium salt, isoxadiazole, isoxadiazole, isoxadiazole, propargyl oxadiazole, oxadiazole, paclobutrazol, pyraflufen, pyraflufen-butyl, pyrazol, pyrazol, pyrazol, benzylpyrachlor, sulfonepyraclostrobin, sulfonepyraclostrobin, sulfentrazone, benzylpyraclostrobin, ethyleneimine, ethyleneimine, 1 -methylcyclopropene, 2,6-diisopropylnaphthalene, 6-benzylaminopurine, 6-isopentylaminopurine, diacylaminopurine, cyproconazole, cyproconazole methyl ester, cyproconazole potassium salt, B5: chloranil, ammonium nonanoate, ammonium sulfamate, aviglycine, benzylchlor, benzylchlor ethyl ester, ethyl butyralid, furazolidone, bentazon, bicyclic sulfone, brassinolide, bromophenol oxime, butyralid, fumarate, fumarate sodium salt, avena sativa ester, chloranil, chloranil, chloranil, chloranil, chlormequat, chloranil imide, dimethyl chloranil, indole, indole ethyl, cyproconazole, pyridazine acid, isoxamethoxazole, fruit acid, aminocyanide, cyclopropanecarboxylic acid, Cyclopyridazine, dalapon, butyric acid hydrazide, dazomethane, fenthion methyl sulfate, flufenpyr, flufenoxate sodium, flufenoxate sodium, thiamethoxam, ammonia fluorine, telofenol, diquat, diquat dibromide, fluthiopyr, DNOC, endoxan, dipotassium endoxan, disodium endoxan, endoxan mono(N, ethylbutylfluorine, ethoxyfuran, indole, wheat grass fluorine, high-efficiency wheat grass fluorine isopropyl ester, high-efficiency wheat grass fluorine methyl ester, chlorethylfluorine, flufenpyr, flupyridazine, flumetrazone, flumichlorac, flufenoxate, propargyl flufenoxate, tetrafluoropropionic acid, flufenoxate, butyl ester of fluorenol, dimethyl ammonium methyl ester of fluorenol, flupyridazine, fluchloridone, flufenoxate, flufenoxate, flufenoxate, flufenoxate Acid methyl ester, gibberellic acid, fluclopyralid, indole, rice blast, kinetin, maleic hydrazide, mepiquat, metamidine, methiothiocarb, methyl arsenic acid, methyl isothiocyanate, N-acetylthiazolidine-4-carboxylic acid, n-decyl alcohol, N-dimethylalkylammonium), nitrophenol salt mixture, nonanoic acid, fluazifop, dihydrojasmonate n-propyl ester, oleic acid, amosulfuron, oxazithromycin, paraquat, dichloroparaquat, dimethoate, pendimethalin, pentachlorophenol, cyclopentadione, mineral oil, amosulfuron, daclofenac, daclofenac, quinone, cypermethrin, TCA, TCA-sodium, tetrachloronitrobenzene, thiazolinic acid, triacontanol, fluazifop, trifluralin, urea sulfate, zeatin, B6: 1-naphthylacetic acid, 2-(1-naphthyl)acetamide, 2,3,6-TBA, 2-naphthylacetic acid, 4-indol-3-ylbutyric acid, chlorpyrifos, clopyralid, dicamba, clofopyralid, clofopyralid isooctyl ester, anti-inversion amine, indol-3-ylacetic acid, amiloride, quinclorac, clomequinol, triclopyrazone, B7: cypermethrin, dimethoate, bialaphos, bialaphos sodium, glufosinate, chloramidophos, ethephon, cypermethrin, glufosinate ammonium, glufosinate ammonium, glufosinate ammonium, glufosinate salt, glufosinate sodium, glyphosate, glyphosate ammonium, glyphosate diammonium, glyphosate dimethylamine, glyphosate isopropylamine, glyphosate potassium, glyphosate salt, glyphosate sodium, glyphosate trimethylsulfonium salt (= glufosinate), L-glufosinate ammonium, L-glufosinate sodium, piperophosphate, defoliant, B8: 2,4-D, 2,4-D-2-ethylhexyl ester, 2,4-DB, 2,4-D-butoxyethyl ester, 2,4-D-butyl ester, 2,4-D-dimethylammonium salt, 2,4-D-diethanolamine, 2,4-D-ethyl ester, 2,4-D-isobutyl ester, 2,4-D-isooctyl ester, 2,4-D-isopropylammonium salt, 2,4-D-potassium salt, 2,4-D-triisopropanol ammonium salt, 2,4-D-triethanolamine, 4-CPA, trifluorfen, trifluorfen Acyfluthrin sodium salt, benifloxybutyl, cypermethrin, clodinafop-ethyl, clodinafop-propyl propargyl, chloranil, fruit acid, cyhalofop-butyl, cyhalofop-butyl, 2,4-dichlorprop, 2,4-dichlorprop, 2-[4-(2,4-dichlorophenoxy)phenoxy]propionic acid, dichlorvos-butyl, 2-[4-(2,4-dichlorophenoxy)phenoxy]propionic acid, dichlorvos-butyl, dichlorvos-butyl, chloranil ethyl, oxadiazine, oxadiazine, ethyl oxadiazine, fluazifop-butyl, fluazifop-butyl Butyl fluoride, fluazifop-butyl, fluazifop-butyl butyl, fluoroglycofen, fluazifop-butyl, fluazifop-butyl, fluazifop-butyl sodium salt, flunitramide, fluazifop-butyl, fluazifop-butyl, lactofen, MCPA, MCPA-2-ethylhexyl ester, MCPA-butoxyethyl ester, MCPA-dimethylammonium salt, MCPA-isopropylammonium salt, MCPA-potassium salt, MCPA-sodium salt, MCPB, MCPB-ethyl-sodium salt, M CPB-methyl ester, 2-methyl-4-chloropropionic acid, 2-methyl-4-chloropropionic acid butoxyethyl ester, 2-methyl-4-chloropropionic acid, 2-ethylhexyl ester, 2-methyl-4-chloropropionic acid butoxyethyl ester, dimethylammonium 2-methyl-4-chloropropionate, potassium 2-methyl-4-chloropropionate, sodium 2-methyl-4-chloropropionate, oxadiazine, oxyfluorfen, oxadiazine, quizalofop-p-ethyl, quizalofop-p-ethyl, quizalofop-p-ethyl, quizalofop-p-ethyl, B9: cyprodinil, bispyribac-butyl, bispyribac-butyl sodium salt, herbicide, fluazifop-butyl, [(3-{2-chloro-5-[2,6-dioxo-4-(trifluoromethyl)-3,6-dihydropyrimidin-1(2H)-yl]-4-fluorophenoxy}pyridin-2-yl)oxy]ethyl acetate, furafil, cypermethrin, pyribambenz, isopropylpyrimidine, propylpyrimidine, pyrimidine oxime, pyrimidine oxime, pyriminobac, pyrimidine oxime, pyrimidine oxime, pyrimidine oxime, pyrimidine oxime, pyrimidine oxime, pyrimidine oxime, pyrimidine oxime, pyrimidine oxime, pyrimidine oxime, pyrimidine oxime, tifenacil, B10: Chlorbromocarb, Chlorotoluron, Benthiocarb, Diflupyrron, Diflupyrron Sodium, Oxazocarb, Diuron, Fluorouron, Chloroforamide, Isoproturon, Terbuconazole, Linuron, Methylbenzyl, Bromothiocarb, Methoxythiocarb, Chlorthiocarb, Cyclothiocarb, Cyclothiocarb, Tebuthiocarb, Tebuthiocarb, Thidiazuron, B11: atrazine, cyanazine, cyprodinil, isopentyl, ethidium, hexazinone, indoxazine fluazifop, metamitron, metribuzin, promethazine, promethazine, simazine, simethoate, terbutaline, terbutylazine, terbutaline, triazinon, and thiazine.

2. The herbicidal composition according to claim 1, comprising one or more herbicides selected from Groups B1 to B11 (component B): B1: flupyralid, clethodim, mesotrione, pinoxasol, sethoxydim, sulfotrione, furansulfuron, cypermethrin, pyraclostrobin, trimethylolpropane, B2: Acetochlor, Alachlor, Amidosulfuron, Sulfuryl, Butachlor, Bisaccharide, Chlorsulfuron-methyl, Cyprosulfuron-methyl, Betaine, Flufenacet, Dimethachlor, Dimethachlor S-P, Pentocarb, Ethoxysulfuron, Bisaccharide, Fluoxetine Sodium, Flufenacet, Flufenacet Sodium, Foramsulfuron, Iodosulfuron-methyl, Iodosulfuron Sodium, Mefenacet, Disulfuron, Mesosulfuron-methyl, Methiachlor, Isopropylamine, Sulfonamide, Methiachlor, Graminicide, pyraclostrobin, nicosulfuron, pyrimidinesulfuron, penoxsulam, pethosulfuron, betaine, flupyralid, pretilachlor, propanil, propanil, propansulfuron, propyzamide, bensulfuron, prosulfuron, pyrazosulfuron ethyl, methoxysulfuron, sulfamethoxazole, isopropylamine, sulfamethoxazole, dimethenamid, thiencarbazone, thiamethoxam, thifensulfuron methyl, gram, bensulfuron methyl, trifloxysulfuron (sodium salt), trifloxysulfuron, B3: Bromobenzonitrile, heptanoyl bromoxynil, octanoyl bromoxynil, iodobenzonitrile, B4: amitriptyline, pyraclostrobin, mesotrione, pyraclostrobin, tetrazoline, imazamox, imazethapyr, isoxathiapiprolin, oxadiazine, pyraclostrobin, sulfamethoxazole, sulfamethoxazole, pyraclostrobin ... B5: Aminopyralid, benzylpyrazone, furamizulin, bentazone, indolepyralid, clomazone, diquat dibromide, ethoxyfurantoin, fluazifop-butyl, fluazifop-butyl, fluazifop-butyl, fluazifop-butyl, oxazithromycin, pendimethalin, pyraclostrobin, trifluralin, B6: clopyralid, dicamba, clofopyralid, amiloride, quinclorac, triclopyralid, B7: silanthoxyphos, glufosinate, glufosinate ammonium, glyphosate, glyphosate ammonium, glyphosate diammonium, glyphosate isopropyl ammonium, glyphosate potassium, L-glufosinate ammonium, B8: 2,4-D, 2,4-D-dimethylammonium salt, trifluorfen sodium salt, benifloxybutyl, cypermethrin, clodinafop-butyl propargyl, cyhalofop-butyl, 2,4-dichloropropionic acid, diclofenac, diclofenac, ethyl fluazifop-butyl, butyl fluazifop-butyl, fluazifop-butyl, MCPA, 2-methyl-4-chloropropionic acid, oxyfluorfen, quizalofop-butyl, B9: bispyribac-sodium, herbicide, ethyl [(3-{2-chloro-5-[2,6-dioxo-4-(trifluoromethyl)-3,6-dihydropyrimidin-1(2H)-yl]-4-fluorophenoxy}pyridin-2-yl)oxy]acetate, cypermethrin, cypermethrin, saflufenacil, B10: benzyluron, cypermethrin, diflupyrone, diuron, isoproturon, B11: ametryn, atrazine, indomethacin, metamitron, metribuzin, simazine, terbuthion, terbuthion.

3. The herbicidal composition according to claim 1 or 2, comprising one or more herbicides selected from Groups B1 to B11 (component B): B1: flupyralid, clethodim, mesotrione, pinoxaden, sulfotrione, furansulfuron, cypermethrin, B2: Acetochlor, Acetosulfuron-methyl, Sulfuryl, Betachlor, Fluazifop, Dimethazone, S-Dimethazone, Ethoxysulfuron-methyl, Bispyribac, Fluoxetine Sodium, Flufenacet, Foramsulfuron, Iodosulfuron Sodium, Mefenacet, Mesosulfuron, Mesosulfuron, Methiazolin, Sulfuramide, Methiosulfuron, Mesosulfuron, Naprofil, Pethodiol, Betachlor, Propylsulfuron-methyl, Benthiocarb, Methoxysulfuron, S-Isopropylamine, Sulfursulfuron-methyl, Thiencarbazone, Thifensulfuron-methyl, Thifensulfuron-methyl Methyl, Bensulfuron-methyl Methyl, Trifloxysulfuron, B3: Bromoxynil, heptanoyl bromoxynil, octanoyl bromoxynil, B4: Amitriptyline, tetrazopyrazone, methoxyfen-2, isoxathiapiprolin, oxadiazine, oxadiazine, pyrasulfotole, pyrasulfotole, pyrasulfotole, B5: Aminopyralid, Furoxanthin, Ethoxyfuroxanthin, Furoxanthin, Oxamipuridine, B6: Dicamba, B7: Glufosinate, glufosinate ammonium salt, glyphosate, glyphosate potassium salt, L-glufosinate ammonium salt, B8: 2,4-D, 2,4-D-dimethylammonium salt, B9: bispyribac-sodium, herbicide, ethyl [(3-{2-chloro-5-[2,6-dioxo-4-(trifluoromethyl)-3,6-dihydropyrimidin-1(2H)-yl]-4-fluorophenoxy}pyridin-2-yl)oxy]acetate, saflufenacil, B11: atrazine, indomethacin, fluazifop, metamitron, metribuzin, terbuthion.

4. The herbicidal composition according to any one of claims 1 to 3, comprising one or more herbicides selected from Groups B1 to B11 (component B): B1: Mesotrione, Cypersulfuron, B2: Acetochlor, difluanid, dimethinaton, foramsulfuron-methyl, thiamethoxam-methyl, B3: Bromoxynil, B4: isoxathiapiprolin, B6: Dicamba, B7: Glufosinate, glufosinate ammonium, glyphosate, glyphosate potassium, B8: 2,4-D, B9: saflufenacil, B11: atrazine, terbuthylazine.

5. The herbicidal composition according to any one of claims 1 to 4, further comprising one or more safeners as component C, the safeners being selected from fenthiocarb, cloquintocet-mexyl, cyprosulfamide, dichloropropene, fenthiocarb, fenthiocarb, fenthiopyrad, fenthiocarb, isoxadiazole, pyraclostrobin, 4-(dichloroacetyl)-1-oxa-4-azaspiro[4.5]decane, and 2,2,5-trimethyl-3-(dichloroacetyl)-1,3-oxazolidine.

6. A method for controlling harmful plants in crops, characterized in that: A herbicidally active amount of the herbicidal composition according to one or more of claims 1 to 5 is applied to the harmful plants, plants, plant seeds or the area where the plants grow.

7. The method according to claim 6, characterized in that The plant is selected from the group consisting of sugarcane, corn, wheat, rye, barley, oats, rice, sorghum, cotton and soybean.

8. The method according to claim 6 or 7, characterized in that: The plants are transgenic plants.

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