Flame retardant textile fabric

By combining pure cotton, polyester cotton, high-performance flame retardant fibers, antibacterial fibers and other materials into textile fabrics, the bacterial reproduction, odor generation and fabric aging problems caused by the lack of antibacterial materials in existing flame retardant textile fabrics are solved, and efficient flame retardant and antibacterial effects are achieved, extending the service life of the fabric.

CN119777049APending Publication Date: 2025-04-08QINGDAO CHAOCHEN TEXTILE CO LTD
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Patent Information

Application Number
CN202510075430.8
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2025-01-17
Publication Date
2025-04-08

AI Technical Summary

Technical Problem

The existing flame-retardant textile fabrics have not been added to antibacterial materials, resulting in bacterial reproduction, odor generation, fiber decomposition and fabric aging, reducing wear comfort and service life.

Method used

Design a textile fabric containing pure cotton, polyester cotton, high-performance flame retardant fibers, antibacterial fibers, antibacterial agents, polytetrafluoroethylene fibers, titanium dioxide fine powder, antimony trioxide fine powder, crystalline water compounds and flame retardant additives. Through the mutual cooperation of these materials, the flame retardant performance and antibacterial effect of the fabric are improved.

Benefits of technology

It significantly improves the flame retardant performance and antibacterial effect of the fabric, reduces the combustion speed, prevents the spread of flames, extends the service life of the fabric, and reduces the infection and odor generation caused by microbial growth.

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Abstract

The invention relates to the technical field of flame-retardant textile fabrics, in particular to flame-retardant textile fabrics, which comprise the following components by mass percentage: 70%-85% of pure cotton, 15%-30% of polyester-cotton, 30%-50% of high-performance flame-retardant fiber, 10%-30% of antibacterial fiber, 0.1%-2% of antibacterial agent, 5%-15% of polytetrafluoroethylene fiber, 0.5%-1% of titanium dioxide micropowder, 0.5%-1% of antimony trioxide micropowder, 2%-5% of crystal water-containing compound, and 3%-1% of flame-retardant additive. The invention can significantly improve the flame-retardant performance of the fabric, reduce the burning speed, effectively prevent the spread of flames, reduce the danger of fire, reduce the infection caused by the breeding of microorganisms, absorb ultraviolet rays, protect the skin from sunburn and sun aging, improve the strength and wear resistance of the fabric, make the fabric more wear-resistant, friction-resistant, not easy to be damaged, and improve the service life of the fabric.
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Description

Technical Field

[0001] The invention relates to the technical field of flame-retardant textile fabrics, in particular to flame-retardant textile fabrics. Background Art

[0002] With the progress of society and the rapid development of science and technology, people have put forward higher and more diversified requirements on the performance of textile fabrics. Traditional textile fabrics have gradually exposed many shortcomings when facing some special scenarios and needs. In recent years, the public's safety awareness has been significantly improved, and flame retardant performance has become a key consideration for textile fabrics. In the fields of building interiors, vehicle interiors and various protective clothing, the demand for flame retardant textile fabrics has increased sharply. Therefore, work clothes with reliable flame retardant performance are needed to reduce the risk of fire at work.

[0003] Most of the existing textile fabrics are made of special fibers, which generally feel hard, greatly reducing the comfort of wearing. At the same time, most flame-retardant textile fabrics do not contain antibacterial materials. During use, bacteria will multiply in large numbers, causing the fabric to produce an unpleasant odor, affecting the wearing experience and the hygiene of the use environment. At the same time, it will decompose and destroy the fibers of the fabric, causing the strength of the fabric to decrease and the fibers to become brittle, thereby accelerating the aging of the fabric and shortening the service life of the fabric.

[0004] Therefore, in order to address the problem that the above-mentioned textile fabrics do not have antibacterial materials added, which affects the wearing experience and the sanitary conditions of the use environment, and at the same time causes decomposition and damage to the fibers of the fabrics, accelerates the aging of the fabrics, and shortens the service life of the fabrics, a flame-retardant textile fabric can be designed. Summary of the invention

[0005] In order to overcome the problem that antibacterial materials are not added to textile fabrics, which affects the wearing experience and the hygiene of the use environment, and at the same time causes decomposition and damage to the fibers of the fabric, accelerates the aging of the fabric, and shortens the service life of the fabric.

[0006] The technical solution of the present invention is: a flame-retardant textile fabric, which comprises the following components by mass percentage: 70% to 85% of pure cotton, 15% to 30% of polyester-cotton, 30% to 50% of high-performance flame-retardant fiber, 10% to 30% of antibacterial fiber, 0.1% to 2% of antibacterial agent, 5% to 15% of polytetrafluoroethylene fiber, 0.5% to 1% of titanium dioxide powder, 0.5% to 1% of antimony trioxide powder, 2% to 5% of crystalline water-containing compound, and 3% to 1% of flame-retardant additive.

[0007] Preferably, the high-performance flame-retardant fiber includes 10% to 30% aramid fiber, 5% to 20% kevlar fiber, 5% to 15% phenolic fiber, and 5% to 15% melamine fiber.

[0008] Preferably, the antibacterial fibers include natural fibers and synthetic fibers. The natural fibers include bamboo fibers, chitin fibers, hemp fibers and kapok fibers. The synthetic fibers include antibacterial polyester fibers, antibacterial cotton fibers and antibacterial acrylic fibers.

[0009] Preferably, the antibacterial agent includes organic antibacterial agent, inorganic antibacterial agent and natural antibacterial agent, the organic antibacterial agent includes nano silver antibacterial agent, copper ion antibacterial agent, zinc ion antibacterial agent and photocatalytic antibacterial agent, and the natural antibacterial agent includes chitosan and plant extracts.

[0010] Preferably, the inorganic antibacterial agents include quaternary ammonium salt antibacterial agents, biguanide antibacterial agents and phenolic antibacterial agents. Quaternary ammonium salt antibacterial agents include single-chain quaternary ammonium salts and double-chain quaternary ammonium salts. Biguanide antibacterial agents include chlorhexidine and polyhexamethylene biguanide hydrochloride. Phenolic antibacterial agents include triclosan and parabens.

[0011] Preferably, the flame retardant additives include phosphorus-based flame retardants, inorganic flame retardants and other flame retardant additives, and the phosphorus-based flame retardants include triphenyl phosphate and tricresyl phosphate.

[0012] Preferably, the inorganic flame retardant includes aluminum hydroxide, magnesium hydroxide and expanded graphite, and other flame retardant additives include antimony trioxide and zinc borate.

[0013] The flame retardant textile fabric is prepared in the following steps:

[0014] Step 1: Yarn preparation: Aramid fiber and polyester fiber are uniformly mixed by mechanical stirring, titanium dioxide micropowder and antimony trioxide micropowder are added and stirred evenly during the mixing process to form a uniform cotton roll, and the cotton roll is placed in a carding machine to card the fiber into a single fiber state, so that the fiber is initially straightened and parallel;

[0015] Step 2: Combine multiple raw slivers together, pass through the roller drafting system to further straighten, parallelize and mix the fibers evenly, feed the raw slivers into the roving frame, and use the roller drafting device to thin the slivers to a certain degree, then use the spindle wing to twist the slivers to obtain a certain twist, feed the roving from the rear roller of the spinning frame, and pass through the roller drafting system to further thin it to the required linear density to form spun yarn;

[0016] Step 3: Fabric manufacturing: Wind the yarns parallely around the warp beam, size the warp yarns with starch, PVA and other sizing agents, dry them after sizing, and use a loom to interweave the warp and weft yarns;

[0017] Step 4: Mix the prepared hydrated compounds, immerse the woven fine sand in the prepared hydrated compounds solution, apply a certain pressure through the roller to allow the fabric to evenly absorb an appropriate amount of solution, and place the impregnated fabric in a dryer for drying.

[0018] Preferably, the rolling ratio is 70% to 80%, the drying temperature is 120 to 150° C., and the drying time is 20 to 60 minutes.

[0019] The beneficial effects of the present invention are as follows: pure cotton is a natural fiber, biodegradable, has good moisture absorption and air permeability, can absorb sweat discharged from the human body and quickly dissipate it, keep the skin dry, and make the wearer feel comfortable; polyester cotton has good moisture absorption and softness, so that the fabric can maintain its shape and be comfortable to wear; high-performance flame-retardant fiber can still maintain good stability in a high temperature environment, is not easy to melt or deform, can effectively prevent the spread of flames, and reduce the burning speed; antibacterial agents and antibacterial fibers have a lasting antibacterial effect, can effectively inhibit the growth and reproduction of a variety of bacteria, fungi and other microorganisms, reduce odors and stains caused by bacterial growth, and increase the service life of the fabric; compounds containing crystalline water reduce the temperature of the fabric and slow down the burning speed of the fabric. At the same time, the water vapor generated during decomposition can dilute the oxygen concentration in the air to form a The combination of titanium dioxide micropowder and antimony trioxide micropowder can produce free radicals, destroy the cell wall and cell membrane of bacteria, achieve the effect of antibacterial disinfection, and effectively absorb ultraviolet rays to prevent ultraviolet rays from damaging human skin, protect fabric fibers from degradation by ultraviolet rays, and inhibit the generation of smoke to reduce the harm of smoke to the human body; through the mutual cooperation of the above materials, the flame retardant performance of the fabric can be significantly improved, the burning speed can be reduced, the spread of flames can be effectively prevented, the danger of fire can be reduced, and the infection caused by the breeding of microorganisms can be reduced, ultraviolet rays can be absorbed, the skin can be protected from sunburn and aging, the strength and wear resistance of the fabric can be improved, the fabric can be more durable, friction-resistant, not easy to break, and the service life of the fabric can be increased. DETAILED DESCRIPTION

[0020] The present invention will be further described below in conjunction with the embodiments.

[0021] Example 1

[0022] The present invention provides an embodiment: a flame-retardant textile fabric, comprising the following components, by mass percentage: 70% pure cotton, 30% polyester-cotton, 30% high-performance flame-retardant fiber, 10% antibacterial fiber, 0.1% antibacterial agent, 5% polytetrafluoroethylene fiber, 0.5% titanium dioxide powder, 0.5% antimony trioxide powder, 2% crystal water-containing compound, and 3% flame-retardant additive;

[0023] High-performance flame-retardant fibers include aramid fiber 10%, kavla fiber 5%, phenolic fiber 5%, and melamine fiber 5%; antibacterial fibers include natural fibers and synthetic fibers, natural fibers include bamboo fiber, chitin fiber, hemp fiber, and kapok fiber, and synthetic fibers include antibacterial polyester fiber, antibacterial cotton fiber, and antibacterial acrylic fiber; antibacterial agents include organic antibacterial agents, inorganic antibacterial agents, and natural antibacterial agents, organic antibacterial agents include nano-silver antibacterial agents, copper ion antibacterial agents, zinc ion antibacterial agents, and photocatalytic antibacterial agents, and natural antibacterial agents include chitosan and plant extracts substances; inorganic antibacterial agents include quaternary ammonium salt antibacterial agents, biguanide antibacterial agents and phenolic antibacterial agents. Quaternary ammonium salt antibacterial agents include single-chain quaternary ammonium salts and double-chain quaternary ammonium salts. Biguanide antibacterial agents include chlorhexidine and polyhexamethylene biguanide hydrochloride. Phenolic antibacterial agents include triclosan and parabens; flame retardant additives include phosphorus-based flame retardants, inorganic flame retardants and other flame retardant additives. Phosphorus-based flame retardants include triphenyl phosphate and tricresyl phosphate; inorganic flame retardants include aluminum hydroxide, magnesium hydroxide and expanded graphite. Other flame retardant additives include antimony trioxide and zinc borate.

[0024] The flame retardant textile fabric is prepared in the following steps:

[0025] Yarn preparation: 10% aramid fiber and 5% phenolic fiber are mixed evenly by mechanical stirring. During the mixing process, 0.5% titanium dioxide powder and 0.5% antimony trioxide powder are added and stirred evenly to make uniform cotton rolls. The cotton rolls are placed in a carding machine to comb the fibers into a single fiber state, so that the fibers are initially straightened and parallel; multiple raw strips are combined together and passed through a roller drafting system to further straighten, parallelize and mix the fibers evenly. The cooked strips are sent to a roving frame, and the strips are stretched to a certain degree by a roller drafting device. Then, the spindle wings are twisted to give the whiskers a certain twist. The roving is sent from the spinning frame to the spinning frame. The yarn is fed into the rear roller and further stretched to the required linear density through the roller drafting system to form fine yarn; fabric manufacturing: the yarn is wound in parallel on the warp beam, and the warp yarn is sized with starch, PVA and other slurries. After sizing, it is dried and the warp and weft yarns are interwoven using a loom; the prepared 2% crystalline water compound is mixed and prepared, and the spun fine yarn is immersed in the prepared crystalline water compound solution, and a certain pressure is applied by the roller to control the rolling rate to 70%, so that the fabric can evenly absorb an appropriate amount of solution, and the impregnated fabric is placed in a dryer and dried at a temperature of 120°C for 60 minutes.

[0026] Example 2

[0027] The present invention provides an embodiment: a flame-retardant textile fabric, comprising the following components, by mass percentage: 85% pure cotton, 15% polyester-cotton, 50% high-performance flame-retardant fiber, 30% antibacterial fiber, 2% antibacterial agent, 15% polytetrafluoroethylene fiber, 1% titanium dioxide micropowder, 1% antimony trioxide micropowder, 25% crystal water-containing compound, and 1% flame-retardant additive;

[0028] Preferably, the high-performance flame-retardant fiber includes 30% aramid fiber, 20% kavla fiber, 15% phenolic fiber and 15% melamine fiber; the antibacterial fiber includes natural fiber and synthetic fiber, the natural fiber includes bamboo fiber, chitin fiber, hemp fiber and kapok fiber, the synthetic fiber includes antibacterial polyester fiber, antibacterial cotton fiber and antibacterial acrylic fiber; the antibacterial agent includes organic antibacterial agent, inorganic antibacterial agent and natural antibacterial agent, the organic antibacterial agent includes nano silver antibacterial agent, copper ion antibacterial agent, zinc ion antibacterial agent and photocatalytic antibacterial agent, the natural antibacterial agent includes chitosan and Plant extracts; inorganic antimicrobial agents include quaternary ammonium salt antimicrobial agents, biguanide antimicrobial agents and phenolic antimicrobial agents. Quaternary ammonium salt antimicrobial agents include single-chain quaternary ammonium salts and double-chain quaternary ammonium salts. Biguanide antimicrobial agents include chlorhexidine and polyhexamethylene biguanide hydrochloride. Phenolic antimicrobial agents include triclosan and parabens; flame retardant additives include phosphorus-based flame retardants, inorganic flame retardants and other flame retardant additives. Phosphorus-based flame retardants include triphenyl phosphate and tricresyl phosphate; inorganic flame retardants include aluminum hydroxide, magnesium hydroxide and expanded graphite. Other flame retardant additives include antimony trioxide and zinc borate.

[0029] The flame retardant textile fabric is prepared in the following steps:

[0030] Yarn preparation: 30% aramid fiber and 15% phenolic fiber are mixed evenly by mechanical stirring. During the mixing process, 1% titanium dioxide powder and 1% antimony trioxide powder are added and stirred evenly to form uniform cotton rolls. The cotton rolls are placed in a carding machine to comb the fibers into a single fiber state, so that the fibers are initially straightened and parallel; multiple raw strips are combined together, and the fibers are further straightened, paralleled and mixed evenly through a roller drafting system. The cooked strips are sent to a roving frame, and the strips are stretched to a certain degree through a roller drafting device. Then, the spindle wing is twisted to give the whiskers a certain twist. The roving is pulled out from the back roller of the spinning frame. The yarn is fed into the cloth and further stretched to the required linear density by the roller drafting system to form fine yarn; fabric manufacturing: the yarn is wound in parallel on the warp beam, and the warp yarn is sized with starch, PVA and other slurries. After sizing, it is dried and the warp and weft yarns are interwoven on a loom; the prepared 2% crystalline water compound is mixed and prepared, and the spun fine yarn is immersed in the prepared crystalline water compound solution, and a certain pressure is applied by the roller to control the rolling rate to 80%, so that the fabric can evenly absorb an appropriate amount of solution, and the impregnated fabric is placed in a dryer and dried at a temperature of 150°C for 20 minutes.

[0031] The flame-retardant textile fabrics of Examples 1 and 2 can significantly improve the flame-retardant properties of the fabrics, reduce the burning speed, effectively prevent the spread of flames, reduce the danger of fire, and at the same time reduce health problems such as infection and allergies caused by microbial growth. It can also absorb ultraviolet rays and protect the skin from sunburn, sun aging, etc.

[0032] The above is a detailed description of the embodiments of the present invention, but the present invention is not limited to the above embodiments, and various changes can be made within the knowledge scope of those skilled in the art without departing from the purpose of the present invention.

Claims

1. A flame retardant textile fabric, characterized in that: Calculated by mass percentage, it includes the following components: 70% to 85% pure cotton, 15% to 30% polyester-cotton, 30% to 50% high-performance flame-retardant fiber, 10% to 30% antibacterial fiber, 0.1% to 2% antibacterial agent, 5% to 15% polytetrafluoroethylene fiber, 0.5% to 1% titanium dioxide powder, 0.5% to 1% antimony trioxide powder, 2% to 5% crystalline water-containing compounds, and 3% to 1% flame retardant additives.

2. The flame retardant textile fabric according to claim 1, characterized in that: The high-performance flame-retardant fibers include aramid fibers 10% to 30%, kavla fibers 5% to 20%, phenolic fibers 5% to 15%, and melamine fibers 5% to 15%.

3. The flame retardant textile fabric according to claim 1, characterized in that: Antibacterial fibers include natural fibers and synthetic fibers. Natural fibers include bamboo fibers, chitin fibers, hemp fibers and kapok fibers. Synthetic fibers include antibacterial polyester fibers, antibacterial cotton fibers and antibacterial acrylic fibers.

4. The flame retardant textile fabric according to claim 1, characterized in that: Antimicrobial agents include organic antimicrobial agents, inorganic antimicrobial agents and natural antimicrobial agents. Organic antimicrobial agents include nanosilver antimicrobial agents, copper ion antimicrobial agents, zinc ion antimicrobial agents and photocatalytic antimicrobial agents. Natural antimicrobial agents include chitosan and plant extracts.

5. The flame retardant textile fabric according to claim 4, characterized in that: Inorganic antimicrobial agents include quaternary ammonium salt antimicrobial agents, biguanide antimicrobial agents and phenolic antimicrobial agents. Quaternary ammonium salt antimicrobial agents include single-chain quaternary ammonium salts and double-chain quaternary ammonium salts. Biguanide antimicrobial agents include chlorhexidine and polyhexamethylene biguanide hydrochloride. Phenolic antimicrobial agents include triclosan and parabens.

6. The flame retardant textile fabric according to claim 1, characterized in that: The flame retardant additives include phosphorus-based flame retardants, inorganic flame retardants and other flame retardant additives. The phosphorus-based flame retardants include triphenyl phosphate and tricresyl phosphate.

7. The flame retardant textile fabric according to claim 6, characterized in that: Inorganic flame retardants include aluminum hydroxide, magnesium hydroxide and expanded graphite, and other flame retardant additives include antimony trioxide and zinc borate.

8. The flame retardant textile fabric according to claim 1, characterized in that: The preparation steps are as follows: Step 1: Yarn preparation: Aramid fiber and polyester fiber are uniformly mixed by mechanical stirring, titanium dioxide micropowder and antimony trioxide micropowder are added and stirred evenly during the mixing process to form a uniform cotton roll, and the cotton roll is placed in a carding machine to card the fiber into a single fiber state, so that the fiber is initially straightened and parallel; Step 2: Combine multiple raw slivers together, pass through the roller drafting system to further straighten, parallelize and mix the fibers evenly, feed the raw slivers into the roving frame, and use the roller drafting device to thin the slivers to a certain degree, then use the spindle wing to twist the slivers to obtain a certain twist, feed the roving from the rear roller of the spinning frame, and pass through the roller drafting system to further thin it to the required linear density to form spun yarn; Step 3: Fabric manufacturing: Wind the yarns parallely around the warp beam, size the warp yarns with starch and PVA slurry, dry them after sizing, and interweave the warp and weft yarns using a loom; Step 4: Mix the prepared hydrated compounds, immerse the woven fine sand in the prepared hydrated compounds solution, apply a certain pressure through the roller to allow the fabric to evenly absorb an appropriate amount of solution, and place the impregnated fabric in a dryer for drying.

9. The flame retardant textile fabric according to claim 8, characterized in that: The rolling rate is 70% to 80%, the drying temperature is 120 to 150°C, and the drying time is 20 to 60 minutes.