Electro-catalytic hydrogenation reduction device for vat dye

Abstract

The invention discloses an electrocatalytic hydrogenation reduction device for vat dye, and relates to the technical field of electrocatalysis, the electrocatalytic hydrogenation reduction device comprises a cathode tank block and an anode tank block, the opposite surfaces of the cathode tank block and the anode tank block are jointly provided with an electrolysis assembly, the electrolysis assembly comprises a first sealing strip, an ion exchange membrane, an anode material, a cathode material and a second sealing strip, and a plurality of fixing screws are jointly connected between the electrolysis assembly and the cathode cell block and between the electrolysis assembly and the anode cell block in a threaded mode, fixing nuts are connected to the rear sides of the rod walls of the fixing screws in a threaded mode, and a ventilation assembly is arranged on the top face of the cathode cell block. The device solves the problems of low production efficiency, high energy consumption, need of pure chemical hydrogenation and the like in the aspect of electro-catalytic hydrogenation reduction production of the existing vat dye, and has the advantages of high catalytic oxidation speed, low energy consumption, only consumption of electric energy, no addition of any chemical agent, no secondary pollution, safe and simple operation, high automation degree of system operation and no manual operation burden.

Description

Technical Field

[0001] The invention relates to the technical field of electrocatalysis, and in particular to an electrocatalytic hydrogenation reduction device for reducing dyes. Background Art

[0002] Higher requirements are put forward for textile enterprises to adapt to the development of ecological environment and implement corporate social responsibility. Vat dyes are mostly used for dyeing blended fabrics with the same color because of their complete color spectrum, bright colors, excellent light fastness, chlorine fastness and excellent stability. However, due to the structural characteristics of vat dyes themselves, they are insoluble in water, so they cannot be directly used to dye cotton cloth. During use, they must be reduced to the leuco form of the corresponding dye before they can be dyed under alkaline conditions. In most industrial processes, dyes are often chemically reduced with sodium dithionite (suicide powder). In the process of using sodium dithionite reduction, a large amount of sodium dithionite, sulfite, sulfate and toxic sulfide will be produced, which seriously pollutes the environment. Therefore, people have studied catalytic hydrogenation, biological reduction, and new reducing agents to replace sodium dithionite reduction. At present, these three methods cannot meet the needs of industrial production due to harsh reaction conditions, high cost and low reduction efficiency. Therefore, an electrocatalytic hydrogenation reduction device for reducing dyes is needed to meet the needs of industrial production. Summary of the invention

[0003] In order to achieve the above-mentioned purpose, the present invention specifically adopts the following technical solutions: An electrocatalytic hydrogenation reduction device for reducing dyes, comprising a cathode cell block and an anode cell block, wherein the cathode cell block and the anode cell block are provided with an electrolytic assembly on opposite sides thereof, wherein the electrolytic assembly comprises a first sealing strip, an ion exchange membrane, an anode material, a cathode material, and a second sealing strip, wherein the electrolytic assembly and the cathode cell block and the anode cell block are threadedly connected with a plurality of fixing screws, and the rear sides of the rod walls of the plurality of fixing screws are threadedly connected with fixing nuts; A ventilation assembly is provided on the top surface of the cathode tank block, and a liquid storage and replenishment assembly is provided on the left side of the anode tank block; The ventilation assembly comprises a cathode air inlet pipe and a cathode gas output pipe fixedly connected to the top surface of the cathode tank block, and the top surface of the anode tank block is fixedly connected to an anode air inlet pipe and an anode gas output pipe.

[0004] Further, the liquid storage and replenishment assembly includes an anode solution adding shell fixedly connected to the left side of the anode tank block, an oxidation product output pipe is fixedly connected to the lower side of the right side of the anode solution adding shell, the left end of the oxidation product output pipe is fixedly connected to the right side of the anode tank block, the left side of the anode solution adding shell is fixedly connected to the anode solution input pipe, the right side of the anode solution input pipe is fixedly connected to the left side of the anode tank block, a first power pump is provided on the right side of the wall of the oxidation product output pipe, a liquid push shell is fixedly connected to the upper side of the wall of the anode solution input pipe, and a liquid push assembly is provided inside the liquid push shell; A reduction product output pipe is fixedly connected to the lower right side of the cathode cell block, a second power pump is provided on the lower side of the wall of the reduction product output pipe, a cathode solution input pipe is fixedly connected to the upper left side of the cathode cell block, a cathode solution addition shell is fixedly connected to the right side of the cathode solution input pipe, a liquid adding cone is fixedly connected to the top surface of the cathode solution addition shell and the top surface of the anode solution addition shell, and a cathode liquid water pump is provided on the lower side of the wall of the cathode solution input pipe.

[0005] Further, the liquid pushing assembly includes three circular cavities opened on the inner wall of the liquid pushing shell, a suction cavity is opened on the lower side of the inner wall of the liquid pushing shell located at the lower side of the middle circular cavity, a derivation pipe is fixedly connected to the right side of the inner wall of the middle circular cavity, the lower end of the derivation pipe penetrates the interior of the liquid pushing shell and the top surface of the anode tank block and extends to the interior of the anode tank block, the inner wall of the derivation pipe and the inner wall of the suction cavity are both provided with a check valve, a suction port is opened on the right side of the upper side of the inner wall of the suction cavity, piston blocks are arranged on the right sides of the inner walls of the three circular cavities, and a pushing assembly is arranged on the left sides of the front and rear two piston blocks; The pushing assembly includes a moving cross bar fixedly connected to the left side of the piston block, the left ends of the two moving cross bars respectively penetrate the left side of the corresponding circular cavity inner wall and extend to the left side of the liquid pushing shell, the rod walls of the two moving cross bars are commonly fixedly connected with a pull plate, and the front and rear sides of the middle circular cavity inner wall are located on one side of the pull plate and a moving opening is opened, the surface of the pull plate is in contact with the inner wall of the moving opening, a pull rod is fixedly connected to the center of the right side of the pull plate, and the right end of the pull rod is fixedly connected to the middle piston block, the rod walls of the two moving cross bars are located on the left side of the pull plate and are sleeved with springs, a pressure relief port is opened on the left side of the upper side of the front and rear circular cavity inner walls, and an N-type connecting port is opened on the right side of the front and rear circular cavity inner walls.

[0006] Furthermore, a special-shaped heating cavity is provided on the lower side of the inner wall of the cathode trough block and the anode trough block, three groups of heating components are provided on the upper side of the inner wall of the two special-shaped heating cavities, and a group of starting switches is provided on the opposite side of the left side of the cathode trough block and the anode trough block.

[0007] Furthermore, each of the plurality of heating components is composed of five electric heating tubes, and the front and rear ends of the plurality of electric heating tubes are respectively fixedly connected to the front and rear sides of the inner wall of the special-shaped heating cavity.

[0008] Furthermore, valve bodies are provided on the lower sides of the tube walls of the cathode air inlet pipe, the cathode gas output pipe, the anode air inlet pipe and the anode gas output pipe.

[0009] Furthermore, the front ends of the plurality of fixing nuts are in contact with the rear end of the cathode slot block, the cathode air inlet pipe and the cathode gas output pipe are respectively fixed on the left and right sides of the top surface of the cathode slot block, the anode air inlet pipe and the anode gas output pipe are respectively fixed on the left and right sides of the top surface of the anode slot block, the bottom surface of the anode solution addition shell is fixedly connected to the top surface of the cathode slot block, the left end of the anode gas output pipe is fixedly connected to the left side of the liquid push shell, and the bottom surface of the liquid push shell is fixedly connected to the top surface of the anode slot block.

[0010] Furthermore, the five layers of the first sealing strip, the ion exchange membrane, the anode material, the cathode material and the second sealing strip are combined into a plate structure, the front of the first sealing strip is in contact with the back of the anode slot block, the back of the second sealing strip is in contact with the front of the cathode slot block, the two front surfaces of the ion exchange membrane are in contact with the opposite sides of the anode material and the cathode material respectively, the back of the first sealing strip is in contact with the front of the anode material, and the front of the second sealing strip is in contact with the back of the cathode material.

[0011] Furthermore, the first sealing strip and the second sealing strip are both frame structures made of rubber material, the material of the anode material is silicon, the material of the cathode material is copper, and each group of the start switches has three settings.

[0012] Furthermore, the wall of the oxidation product output pipe is located on the left side of the first power pump and is fixedly connected to two supporting orifice plates, the top surfaces of the two supporting orifice plates are fixedly connected to the bottom surface of the anode tank block, and the bottom surface of the special-shaped heating chamber is provided with an aluminum silicate wool plate.

[0013] Technical effects and advantages of the present invention: The present invention can electrolyze the substances in the cathode cell block and the anode cell block through the electrolysis component, and the gas generated in the treatment process can be discharged through the anode gas output pipe and the cathode gas output pipe in the ventilation component to ensure the collection and utilization effect of the reaction gas, and the substances electrolyzed in the cathode cell block and the anode cell block are discharged through the oxidation product output pipe and the reduction product output pipe to ensure the overall use effect. Through the above structure, it is guaranteed that the device can solve the problems of low production efficiency, high energy consumption, and the need for pure chemical hydrogenation in the existing electrocatalytic hydrogenation reduction production of reducing dyes. The device has a fast catalytic oxidation speed, low energy consumption, and only consumes electrical energy. No chemical agents are added, there is no secondary pollution, and the operation is safe and simple. The system operation has a high degree of automation and there is no human operation burden.

[0014] The present invention utilizes the oxygen driven structure generated near the anode electrode in the anode cell block to introduce the alkaline substance solution in the anode solution addition shell into the anode cell block. By reintroducing the alkaline substance solution, the hydroxide concentration in the anode cell block is guaranteed, thereby ensuring the liquid recycling in the device processing process and reducing the cost of the processing process.

[0015] The present invention utilizes a start switch to control the heating of the electric heating tube, which can make the reaction in the cathode slot block and the anode slot block more complete, increase the electrolyte amount of the overall device, and thus ensure the quality of the dye processed by the device. BRIEF DESCRIPTION OF THE DRAWINGS

[0016] Figure 1 It is a schematic diagram of the overall front three-dimensional structure of the present invention.

[0017] Figure 2 For the present invention Figure 1 Schematic diagram of the enlarged structure of part A in the middle.

[0018] Figure 3 It is a schematic diagram of the overall rear three-dimensional structure of the present invention.

[0019] Figure 4 For the present invention Figure 3 Schematic diagram of the enlarged structure of part B in the middle.

[0020] Figure 5 It is a schematic diagram of the cross-sectional three-dimensional structure of the liquid push shell of the present invention.

[0021] Figure 6 It is a schematic diagram of the vertical section three-dimensional structure of the liquid push shell of the present invention.

[0022] Figure 7 It is a schematic diagram of the overall cross-sectional three-dimensional structure of the present invention.

[0023] Figure 8 For the present invention Figure 7 Schematic diagram of the enlarged structure of part C in the middle.

[0024] Fig. 9 It is a schematic diagram of the cross-sectional three-dimensional structure of the cathode cell block of the present invention.

[0025] Fig.10 It is a schematic diagram of the three-dimensional structure of the electrolytic component of the present invention.

[0026] In the figure: 1, cathode tank block; 2, anode tank block; 3, first sealing strip; 4, ion exchange membrane; 5, anode material; 6, cathode material; 7, second sealing strip; 8, fixing screw; 9, pressure relief port; 10, cathode air inlet pipe; 11, cathode gas output pipe; 12, anode air inlet pipe; 13, anode gas output pipe; 14, anode solution adding shell; 15, oxidation product output pipe; 16, anode solution input pipe; 17, first power pump; 18, liquid push shell; 19, reduction product output pipe; 20, The second power pump; 21. cathode solution input pipe; 22. cathode solution adding shell; 23. liquid adding cone; 24. cathode liquid water pump; 25. special-shaped heating chamber; 26. start switch; 27. electric heating tube; 28. valve body; 29. ​​supporting orifice plate; 30. aluminum silicate wool plate; 31. round cavity; 32. suction cavity; 33. outlet pipe; 34. check valve; 35. suction port; 36. piston block; 37. moving cross bar; 38. pull plate; 39. moving port; 40. pull rod; 41. spring; 42. N-type connecting port. DETAILED DESCRIPTION

[0027] To make the purpose, technical solution and advantages of the embodiments of the present invention more clear, the technical solution in the embodiments of the present invention will be clearly and completely described below in conjunction with the accompanying drawings in the embodiments of the present invention.

[0028] like Figure 1-10 As shown, an electrocatalytic hydrogenation reduction device for reducing dyes comprises a cathode cell block 1 and an anode cell block 2, wherein an electrolytic assembly is provided on opposite sides of the cathode cell block 1 and the anode cell block 2, wherein the electrolytic assembly comprises a first sealing strip 3, an ion exchange membrane 4, an anode material 5, a cathode material 6, and a second sealing strip 7, wherein a plurality of fixing screws 8 are threadedly connected between the electrolytic assembly and the cathode cell block 1 and the anode cell block 2, and fixing nuts are threadedly connected to the rear sides of the rod walls of the plurality of fixing screws 8; A ventilation assembly is provided on the top surface of the cathode tank block 1, and a liquid storage and replenishment assembly is provided on the left side of the anode tank block 2; The ventilation assembly includes a cathode air inlet pipe 10 and a cathode gas outlet pipe 11 fixedly connected to the top surface of the cathode cell block 1, and an anode air inlet pipe 12 and an anode gas outlet pipe 13 fixedly connected to the top surface of the anode cell block 2; The liquid storage and replenishment assembly includes an anode solution adding shell 14 fixedly connected to the left side of the anode tank block 2, an oxidation product output pipe 15 is fixedly connected to the lower side of the right side of the anode solution adding shell 14, the left end of the oxidation product output pipe 15 is fixedly connected to the right side of the anode tank block 2, an anode solution input pipe 16 is fixedly connected to the left side of the anode solution adding shell 14, the right side of the anode solution input pipe 16 is fixedly connected to the left side of the anode tank block 2, a first power pump 17 is provided on the right side of the wall of the oxidation product output pipe 15, a liquid push shell 18 is fixedly connected to the upper side of the wall of the anode solution input pipe 16, the connection position of the anode solution input pipe 16 and the liquid push shell 18 is on one side of the suction cavity 32, which can ensure the inflow effect of the liquid in the anode solution adding shell 14, and a liquid push assembly is provided inside the liquid push shell 18; A reduction product output pipe 19 is fixedly connected to the lower side of the right side of the cathode tank block 1, and a second power pump 20 is provided on the lower side of the wall of the reduction product output pipe 19. A cathode solution input pipe 21 is fixedly connected to the upper side of the left side of the cathode tank block 1, and a cathode solution adding shell 22 is fixedly connected to the right side of the cathode solution input pipe 21. The top surface of the cathode solution adding shell 22 and the top surface of the anode solution adding shell 14 are both fixedly connected with a liquid adding cone 23. A cathode liquid water pump 24 is provided on the lower side of the wall of the cathode solution input pipe 21. Through the above structure, it is ensured that the device solves the problems of low production efficiency, high energy consumption, and the need for pure chemical hydrogenation in the existing electrocatalytic hydrogenation reduction production of reducing dyes. The device has a fast catalytic oxidation speed, low energy consumption, and only consumes electrical energy. No chemical agent is added, there is no secondary pollution, and the operation is safe and simple. The system operation has a high degree of automation and no human operation burden. The liquid push assembly includes three circular cavities 31 opened on the inner wall of the liquid push shell 18, a suction cavity 32 is opened on the lower side of the inner wall of the liquid push shell 18 and located at the lower side of the middle circular cavity 31, a derivation pipe 33 is fixedly connected to the right side of the inner wall of the middle circular cavity 31, the lower end of the derivation pipe 33 penetrates the interior of the liquid push shell 18 and the top surface of the anode tank block 2 and extends to the interior of the anode tank block 2, the inner wall of the derivation pipe 33 and the inner wall of the suction cavity 32 are both provided with a check valve 34, a suction port 35 is opened on the right side of the upper side of the inner wall of the suction cavity 32, piston blocks 36 are all provided on the right side of the inner walls of the three circular cavities 31, and a push assembly is provided on the left side of the front and rear two piston blocks 36; The pushing assembly includes a moving cross bar 37 fixedly connected to the left side of the piston block 36. The left ends of the two moving cross bars 37 respectively penetrate the left side of the inner wall of the corresponding circular cavity 31 and extend to the left side of the liquid pushing shell 18. The rod walls of the two moving cross bars 37 are commonly fixedly connected with a pull plate 38. The front and rear sides of the inner wall of the middle circular cavity 31 are located on one side of the pull plate 38 and a moving opening 39 is opened. The surface of the pull plate 38 contacts the inner wall of the moving opening 39. A pull rod 40 is fixedly connected to the center of the right side of the pull plate 38. The right end of the pull rod 40 is fixedly connected to the middle piston block 36. The two moving cross bars The rod wall of 37 is located on the left side of the pull plate 38 and is sleeved with a spring 41. A pressure relief port 9 is provided on the left side of the upper inner wall of the front and rear circular cavities 31. The pressure relief port 9 can be connected to other collection equipment to ensure the recycling effect of the reaction gas. An N-type connecting port 42 is provided on the right side of the inner wall of the front and rear circular cavities 31. The gas reacted in the anode cell block 2 is transported to the liquid push shell 18 through the anode gas output pipe 13. The structure can ensure the continuous output of the liquid in the anode solution addition shell 14, ensure the concentration of the substance in the anode cell block 2, and ensure the quality of the processing process.

[0029] like Figure 1-7 As shown, in some embodiments, an electrocatalytic hydrogenation reduction device for reducing dyes includes a cathode cell block 1 and an anode cell block 2, and an electrolytic assembly is provided on opposite sides of the cathode cell block 1 and the anode cell block 2. The electrolytic assembly includes a first sealing strip 3, an ion exchange membrane 4, an anode material 5, a cathode material 6, and a second sealing strip 7. A plurality of fixing screws 8 are threadedly connected between the electrolytic assembly and the cathode cell block 1 and the anode cell block 2, and the rear sides of the rod walls of the plurality of fixing screws 8 are threadedly connected with fixing nuts; A ventilation assembly is provided on the top surface of the cathode tank block 1, and a liquid storage and replenishment assembly is provided on the left side of the anode tank block 2; The ventilation assembly includes a cathode air inlet pipe 10 and a cathode gas outlet pipe 11 fixedly connected to the top surface of the cathode cell block 1, and an anode air inlet pipe 12 and an anode gas outlet pipe 13 fixedly connected to the top surface of the anode cell block 2; A special-shaped heating cavity 25 is provided on the lower side of the inner wall of the cathode tank block 1 and the anode tank block 2, and three groups of heating components are provided on the upper side of the inner wall of the two special-shaped heating cavities 25. A group of starting switches 26 are provided on the opposite side of the left side of the cathode tank block 1 and the anode tank block 2. The multiple heating components are composed of five electric heating tubes 27, and the front and rear ends of the multiple electric heating tubes 27 are respectively fixedly connected to the front and rear sides of the inner wall of the special-shaped heating cavity 25, and valve bodies 28 are provided on the lower sides of the tube walls of the cathode air inlet pipe 10, the cathode gas output pipe 11, the anode air inlet pipe 12 and the anode gas output pipe 13.

[0030] like Figure 3-8As shown, in some embodiments, an electrocatalytic hydrogenation reduction device for reducing dyes includes a cathode cell block 1 and an anode cell block 2, and an electrolytic assembly is provided on opposite sides of the cathode cell block 1 and the anode cell block 2. The electrolytic assembly includes a first sealing strip 3, an ion exchange membrane 4, an anode material 5, a cathode material 6, and a second sealing strip 7. A plurality of fixing screws 8 are threadedly connected between the electrolytic assembly and the cathode cell block 1 and the anode cell block 2, and the rear sides of the rod walls of the plurality of fixing screws 8 are threadedly connected with fixing nuts; A ventilation assembly is provided on the top surface of the cathode tank block 1, and a liquid storage and replenishment assembly is provided on the left side of the anode tank block 2; The ventilation assembly includes a cathode air inlet pipe 10 and a cathode gas outlet pipe 11 fixedly connected to the top surface of the cathode cell block 1, and an anode air inlet pipe 12 and an anode gas outlet pipe 13 fixedly connected to the top surface of the anode cell block 2; The fronts of the plurality of fixing nuts are in contact with the rear of the cathode cell block 1, the cathode air inlet pipe 10 and the cathode gas output pipe 11 are fixed on the left and right sides of the top surface of the cathode cell block 1, respectively, the anode air inlet pipe 12 and the anode gas output pipe 13 are fixed on the left and right sides of the top surface of the anode cell block 2, respectively, the bottom surface of the anode solution addition shell 14 is fixedly connected to the top surface of the cathode cell block 1, the left end of the anode gas output pipe 13 is fixedly connected to the left side of the liquid push shell 18, the connection position of the anode gas output pipe 13 and the liquid push shell 18 is at the position of the N-type connection port 42, which can ensure the effect of gas delivery to the front and rear two circular cavities 31, the bottom surface of the liquid push shell 18 is fixedly connected to the top surface of the anode cell block 2, the first sealing strip 3, the ion exchange membrane 4, the anode material 5, the cathode material 6, and the second sealing strip 7 are integrated into a plate structure, the front of the first sealing strip 3 is in contact with the back of the anode cell block 2, and the back of the second sealing strip 7 It is in contact with the front of the cathode cell block 1, the two front surfaces of the ion exchange membrane 4 are in contact with the opposite sides of the anode material 5 and the cathode material 6 respectively, the back of the first sealing strip 3 is in contact with the front of the anode material 5, and the front of the second sealing strip 7 is in contact with the back of the cathode material 6. The first sealing strip 3 and the second sealing strip 7 are both frame structures made of rubber material, the material of the anode material 5 is silicon, and the material of the cathode material 6 is copper. Each group of starting switches 26 is set to three. The wall of the oxidation product output pipe 15 is located on the left side of the first power pump 17 and is fixedly connected to two supporting orifice plates 29. The supporting orifice plates 29 ensure the stability of the oxidation product output pipe 15 during use. The top surfaces of the two supporting orifice plates 29 are fixedly connected to the bottom surface of the anode cell block 2. The bottom surface of the special-shaped heating chamber 25 is provided with an aluminum silicate wool plate 30. The aluminum silicate wool plate 30 can ensure the bottom of the device and avoid the problem of heat generation caused by the special-shaped heating chamber 25 directly heating the bottom of the device.

[0031] Working principle of the present invention: when the device is used, it is necessary to connect the power supply, and the positive and negative poles of the power supply are connected to the fixed screw 8. The fixed screw 8 can ensure the fixing effect of the cathode tank block 1, the anode tank block 2 and the electrolytic assembly, and two of them can be selected as positive and negative electrodes. The fixed screw 8 uses the power line to connect the positive and negative poles of the power supply respectively. When in use, ensure that the anode electrode material is only in close contact with the anode screw and does not contact with the other screws. Similarly, ensure that the cathode electrode material is in close contact with the cathode screw and does not contact with the other screws. Each screw can be connected to the power supply and the electrode material, and can be flexibly selected according to needs, which increases the flexibility of the device during use; The lower end of the reduction product output pipe 19 will be connected to the reduction product collector to ensure the collection and utilization effect of the reduction product. The anode gas output pipe 13 in the device can transport the gas reacted in the anode tank block 2. The gas is introduced into the N-type connecting port 42 in the liquid push shell 18 through the anode gas output pipe 13, so that the gas will push the piston blocks 36 in the front and rear circular cavities 31 to move. Driven by the front and rear piston blocks 36, the pull plate 38 can drive the piston block 36 on the pull rod 40 to move in the same direction. In this way, under the movement of the middle piston block 36, the vacuum effect of the middle circular cavity 31 can be guaranteed, and then the middle circular cavity 31 will extract the liquid in the anode solution adding shell 14 through the suction port 35 and the suction cavity 32 and the anode solution input pipe 16. When the front and rear piston blocks 36 move to the pressure relief port 9 position, the gas will flow out. In this way, the front and rear two piston blocks 36 are The pressure in the circular cavity 31 will decrease, and under the elastic force of the spring 41, the front and rear piston blocks 36 are pushed to move in the opposite direction of the original moving direction, thereby ensuring that the middle piston block 36 pushes the liquid in the middle circular cavity 31 into the anode tank block 2 through the outlet pipe 33, thereby ensuring the replenishment of the substance in the anode tank block 2 and the concentration of the substance. The check valve 34 in the suction cavity 32 can ensure that the liquid flows into the circular cavity 31 through the anode solution input pipe 16, and will not allow the liquid in the circular cavity 31 to flow back to the anode solution input pipe 16, while the check valve 34 in the outlet pipe 33 can only ensure that the liquid in the circular cavity 31 flows into the anode tank block 2 and is blocked in the reverse direction. In this way, under the elastic force of the spring 41 and the gas delivery conditions of the anode gas output pipe 13, the left and right reciprocating motion of the central piston block 36 is guaranteed, which ensures the replenishment of the liquid in the anode tank block 2 and improves the reaction effect. The oxidation product output pipe 15 in the anode tank block 2 of the device is transported to the anode solution adding shell 14 under the transportation of the first power pump 17, so as to ensure the recycling effect of the solution in the anode solution adding shell 14. The liquid in the cathode tank block 1 is transported by the cathode liquid water pump 24 to the cathode solution adding shell 22. When the yin and yang tank block structure is used, the electric heating tube 27 can increase the internal temperature, thereby increasing the reaction rate of electrolysis and ensuring the full reaction. Each group of three settings of the starting switch 26, when one starting switch 26 is started, the two electric heating tubes 27 in the heating component will be started, and then another starting switch 26 will be started. When the start switch 26 is turned on, four electric heating tubes 27 in the heating component will be started. When three start switches 26 are turned on at the same time, the electric heating tubes 27 in each group of heating components will all be started. When one start switch 26 is started, the temperature in the special-shaped heating chamber 25 is 300-400 degrees Celsius. When two start switches 26 are started, the temperature in the special-shaped heating chamber 25 is 600-750 degrees Celsius. When all three start switches 26 are started, the temperature in the special-shaped heating chamber 25 is 800-1100 degrees Celsius. The device can set a temperature sensor on the surface of the yin and yang groove block structure, which can better ensure the use effect of the device.

[0032] The present invention highlights the innovative structure and does not elaborate on the existing mature technologies and structures.

[0033] The above description of the disclosed embodiments enables one skilled in the art to implement or use the present invention. Various modifications to these embodiments will be apparent to one skilled in the art, and the general principles defined herein may be implemented in other embodiments without departing from the spirit or scope of the present invention. Therefore, the present invention will not be limited to the embodiments shown herein, but rather to the widest scope consistent with the principles and novel features disclosed herein.

Claims

1. An electrocatalytic hydrogenation reduction device for reducing dyes, comprising a cathode cell block (1) and an anode cell block (2), characterized in that: An electrolytic assembly is provided on opposite sides of the cathode cell block (1) and the anode cell block (2), the electrolytic assembly comprising a first sealing strip (3), an ion exchange membrane (4), an anode material (5), a cathode material (6), and a second sealing strip (7); a plurality of fixing screws (8) are threadedly connected between the electrolytic assembly and the cathode cell block (1) and the anode cell block (2); and fixing nuts are threadedly connected to the rear sides of the rod walls of the plurality of fixing screws (8); A ventilation component is provided on the top surface of the cathode cell block (1), and a liquid storage and replenishment component is provided on the left side of the anode cell block (2); The ventilation assembly comprises a cathode air inlet pipe (10) and a cathode gas outlet pipe (11) fixedly connected to the top surface of the cathode cell block (1), and an anode air inlet pipe (12) and an anode gas outlet pipe (13) fixedly connected to the top surface of the anode cell block (2).

2. The electrocatalytic hydrogenation reduction device for reducing dyes according to claim 1, characterized in that: The liquid storage and replenishment assembly comprises an anode solution adding shell (14) fixedly connected to the left side of the anode tank block (2); an oxidation product output pipe (15) is fixedly connected to the lower side of the right side of the anode solution adding shell (14); the left end of the oxidation product output pipe (15) is fixedly connected to the right side of the anode tank block (2); an anode solution input pipe (16) is fixedly connected to the left side of the anode solution adding shell (14); the right side of the anode solution input pipe (16) is fixedly connected to the left side of the anode tank block (2); a first power pump (17) is provided on the right side of the wall of the oxidation product output pipe (15); a liquid propulsion shell (18) is fixedly connected to the upper side of the wall of the anode solution input pipe (16); and a liquid propulsion assembly is provided inside the liquid propulsion shell (18); A reduction product output pipe (19) is fixedly connected to the lower right side of the cathode tank block (1), and a second power pump (20) is provided on the lower side of the tube wall of the reduction product output pipe (19). A cathode solution input pipe (21) is fixedly connected to the upper left side of the cathode tank block (1), and a cathode solution addition shell (22) is fixedly connected to the right side of the cathode solution input pipe (21). A liquid addition cone (23) is fixedly connected to the top surface of the cathode solution addition shell (22) and the top surface of the anode solution addition shell (14), and a cathode solution water pump (24) is provided on the lower side of the tube wall of the cathode solution input pipe (21).

3. The electrocatalytic hydrogenation reduction device for reducing dyes according to claim 2, characterized in that: The liquid pushing assembly comprises three circular cavities (31) formed on the inner wall of the liquid pushing shell (18); a suction cavity (32) is formed on the lower side of the inner wall of the liquid pushing shell (18) and located below the middle circular cavity (31); a discharge pipe (33) is fixedly connected to the right side of the inner wall of the middle circular cavity (31); the lower end of the discharge pipe (33) penetrates the interior of the liquid pushing shell (18) and the top surface of the anode cell block (2) and extends to the interior of the anode cell block (2); a check valve (34) is formed on the inner wall of the discharge pipe (33) and the inner wall of the suction cavity (32); a suction port (35) is formed on the right side of the upper side of the inner wall of the suction cavity (32); piston blocks (36) are formed on the right sides of the inner walls of the three circular cavities (31); and a pushing assembly is formed on the left sides of the front and rear two piston blocks (36); The pushing assembly comprises a moving cross bar (37) fixedly connected to the left side of the piston block (36), the left ends of the two moving cross bars (37) respectively penetrate the left side of the inner wall of the corresponding circular cavity (31) and extend to the left side of the liquid pushing shell (18), the rod walls of the two moving cross bars (37) are commonly fixedly connected with a pull plate (38), and the front and rear sides of the inner wall of the middle circular cavity (31) are both provided with a moving opening (39) on one side of the pull plate (38), and the surface of the pull plate (38) is in contact with the moving cross bar (37). The inner wall of the opening (39) is in contact with the inner wall of the opening (39), a pull rod (40) is fixedly connected to the center of the right side of the pull plate (38), the right end of the pull rod (40) is fixedly connected to the middle piston block (36), the rod wall of the two movable cross bars (37) located on the left side of the pull plate (38) are both sleeved with springs (41), the left side of the upper side of the inner wall of the front and rear two circular cavities (31) are provided with a pressure relief port (9), and the right side of the inner wall of the front and rear two circular cavities (31) are jointly provided with an N-type connecting port (42).

4. The electrocatalytic hydrogenation reduction device for reducing dyes according to claim 2, characterized in that: A special-shaped heating cavity (25) is provided on the lower side of the inner wall of the cathode cell block (1) and the anode cell block (2), three groups of heating components are provided on the upper side of the inner wall of the two special-shaped heating cavities (25), and a group of starting switches (26) are provided on the opposite sides of the left sides of the cathode cell block (1) and the anode cell block (2).

5. The electrocatalytic hydrogenation reduction device for reducing dyes according to claim 4, characterized in that: The plurality of heating components are each composed of five electric heating tubes (27), and the front and rear ends of the plurality of electric heating tubes (27) are respectively fixedly connected to the front and rear sides of the inner wall of the special-shaped heating cavity (25).

6. The electrocatalytic hydrogenation reduction device for reducing dyes according to claim 1, characterized in that: A valve body (28) is provided on the lower side of the tube wall of the cathode air inlet pipe (10), the cathode gas output pipe (11), the anode air inlet pipe (12) and the anode gas output pipe (13).

7. The electrocatalytic hydrogenation reduction device for reducing dyes according to claim 2, characterized in that: The front ends of the plurality of fixing nuts are in contact with the rear end of the cathode cell block (1); the cathode air inlet pipe (10) and the cathode gas output pipe (11) are respectively fixed to the left and right sides of the top surface of the cathode cell block (1); the anode air inlet pipe (12) and the anode gas output pipe (13) are respectively fixed to the left and right sides of the top surface of the anode cell block (2); the bottom surface of the anode solution addition shell (14) is fixedly connected to the top surface of the cathode cell block (1); the left end of the anode gas output pipe (13) is fixedly connected to the left side of the liquid push shell (18); and the bottom surface of the liquid push shell (18) is fixedly connected to the top surface of the anode cell block (2).

8. The electrocatalytic hydrogenation reduction device for reducing dyes according to claim 1, characterized in that: The first sealing strip (3), the ion exchange membrane (4), the anode material (5), the cathode material (6) and the second sealing strip (7) are combined into a plate structure. The front of the first sealing strip (3) contacts the back of the anode cell block (2), the back of the second sealing strip (7) contacts the front of the cathode cell block (1), the front two surfaces of the ion exchange membrane (4) contact the opposite sides of the anode material (5) and the cathode material (6), the back of the first sealing strip (3) contacts the front of the anode material (5), and the front of the second sealing strip (7) contacts the back of the cathode material (6).

9. The electrocatalytic hydrogenation reduction device for reducing dyes according to claim 4, characterized in that: The first sealing strip (3) and the second sealing strip (7) are both frame structures made of rubber material, the material of the anode material (5) is silicon, the material of the cathode material (6) is copper, and each group of the start switches (26) has three settings.

10. The electrocatalytic hydrogenation reduction device for reducing dyes according to claim 4, characterized in that: The wall of the oxidation product output pipe (15) is located on the left side of the first power pump (17) and is fixedly connected to two supporting orifice plates (29), the top surfaces of the two supporting orifice plates (29) are fixedly connected to the bottom surface of the anode tank block (2), and the bottom surface of the special-shaped heating chamber (25) is provided with an aluminum silicate wool plate (30).

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