Gradient electrolysis-dynamic extraction combined small molecular group water preparation method and device
Through the combination of gradient electrolysis-dynamic extraction, the problem that existing drinking water treatment technology cannot effectively enrich trace elements is solved, and efficient enrichment and deep purification are achieved, with simple process, low cost and low energy consumption.
Patent Information
- Application Number
- CN202510472584.0
- Authority / Receiving Office
- CN · China
- Patent Type
- Applications(China)
- Current Assignee / Owner
- Filing Date
- 2025-04-16
- Publication Date
- 2025-05-30
AI Technical Summary
The existing drinking water treatment technology has problems such as complex processes, high energy consumption, and inability to effectively retain or enrich trace elements in the water, making it difficult to meet the human body's demand for high-quality drinking water.
The gradient electrolysis-dynamic extraction combination method is adopted to achieve efficient enrichment of trace elements and deep purification of water quality through electrolytic crystallization and dynamic extraction technology.
It realizes efficient enrichment of trace elements and deep purification of water quality. It has simple process, low cost and low energy consumption, and is suitable for large-scale popularization.
Smart Images
Figure CN120058187A_ABST
Abstract
Description
Technical Field
[0001] The present invention relates to the technical field of drinking water, and particularly to a method and device for preparing small-molecule cluster water by combining gradient electrolysis and dynamic extraction, specifically a method for preparing trace-element-enriched small-molecule cluster water by combining gradient electrolysis crystallization and dynamic extraction and a multi-stage purification device. Background Art
[0002] Water is the basis of life. High-quality drinking water can not only provide energy for the human body, but also maintain the normal physiological functions of the human body by dissolving and transporting minerals, trace elements, etc. However, with the acceleration of the industrialization process and the aggravation of environmental pollution, the contents of minerals and trace elements in natural water sources have gradually decreased, and traditional drinking water treatment technologies are also difficult to meet people's needs for high-quality drinking water.
[0003] Currently, the drinking water treatment technologies on the market are mainly divided into two categories: one is the integrated magnetization and purification technology, and the other is the traditional electrolysis method. The integrated magnetization and purification technology removes impurities in water through adsorption and filtration while retaining trace elements in water. However, this technology has obvious limitations. First, the process of adding trace elements is uneven, which easily leads to precipitation and affects the stability and taste of water quality. Second, this technology cannot effectively remove bacteria and microorganisms in water, and it is difficult to ensure the hygienic safety of drinking water. In addition, the improvement effect of the magnetization technology on water quality is limited, and it cannot significantly improve the activity and bioavailability of water.
[0004] The traditional electrolysis method decomposes water into alkaline ion water and acidic ion water through electrolysis. Although the alkaline ion water improves the water quality to a certain extent, its stability is poor, trace elements are easily lost, resulting in insufficient mineral content in water. At the same time, the traditional electrolysis method has high energy consumption, complex equipment, and high price, making it difficult to popularize. In addition, acidic ion water cannot be directly drunk and requires additional treatment, which further increases the complexity and cost of the process.
[0005] In addition to the above two main technologies, there are also some other drinking water treatment methods on the market, such as reverse osmosis, ultrafiltration, etc. Although these technologies can effectively remove impurities and bacteria in water, they also remove minerals and trace elements in water, resulting in overly "pure" water quality and unable to meet the human body's intake requirements for minerals and trace elements. Long-term drinking of this kind of water may have an adverse impact on human health.
[0006] Judging from the current market situation, the existing drinking water treatment devices generally have the following problems: First, the process is complex and requires multi-stage treatment, resulting in large equipment volume and high cost; second, the energy consumption is high and the operating cost is expensive; third, it is unable to effectively retain or enrich trace elements in water and cannot meet the human body's demand for minerals and trace elements; fourth, the equipment maintenance is complex and the user experience is poor. These problems have restricted the popularization and promotion of high-quality drinking water. Summary of the Invention
[0007] The purpose of the present invention is to provide a method and device for preparing small-molecule cluster water by combining gradient electrolysis and dynamic extraction, specifically a method for preparing trace element-enriched small-molecule cluster water based on the combination of gradient electrolysis crystallization and dynamic extraction and a multi-stage purification device. Through innovative electrolysis crystallization technology and dynamic extraction process, the method realizes the efficient enrichment of trace elements and the deep purification of water quality, and at the same time has the advantages of simple process, low cost, low energy consumption, etc., providing a new solution for improving the quality of drinking water.
[0008] To achieve the above object, the present invention provides the following technical solutions:
[0009] A method for preparing small-molecule cluster water by combining gradient electrolysis and dynamic extraction, comprising:
[0010] It includes a refining process, a reaction process, a static purification process, a desalting process, and an extraction process. The specific process flow of each process is as follows:
[0011] The refining process includes salting and refining raw materials such as rose salt and sea salt: mixing the raw salt and water to dissolve the raw salt to obtain a first brine solution; adjusting the first brine solution to make a second brine solution with a concentration of 15%.
[0012] In the reaction process, the second brine solution is electrolytically extracted, and spiral first crystals appear on the surface of the container.
[0013] In the static purification process, the solution after the reaction process is allowed to stand and solid-liquid separation is carried out to obtain the first crystals and the brine mother liquor, and the first crystals and the brine mother liquor are stored separately.
[0014] In the desalting process, the first crystals are added to mineral water for dilution, and after stirring, standing, and filtering, second crystals are obtained.
[0015] In the extraction process, the second crystals are added to an appropriate amount of mineral water and stirred clockwise for dynamic extraction to obtain small-molecule cluster water rich in trace elements: Specifically, the raw salt can be rose salt, mineral salt, sea salt, lake salt, or well salt because the raw salt is rich in minerals and trace elements.
[0016] Further, the second brine solution is subjected to a three-stage treatment system of electrolytic extraction (zinc-nanocarbon electrode) + crystal purification + dynamic extraction. The electrolytic reaction of the second brine solution needs to be carried out under the conditions of a light intensity of more than 30,000 lux and an ambient temperature of 10 - 30 degrees, and the reaction time lasts for 7 days. During the electrolytic reaction, if the second brine solution is uneven, precipitation will occur, and the precipitated substances will float in the solution, easily causing the reaction to stop. Therefore, during the electrolytic reaction, there is also a step of stirring the second brine solution, and the clockwise stirring frequency is 1 time per day.
[0017] Further, in the static purification process, the static time is 12 hours.
[0018] Further, the first crystal is stored in a plastic container in the dark, specifically a black or blue plastic container.
[0019] Further, the brine mother liquor is subjected to precipitation filtration treatment, and the upper brine mother liquor separated from the precipitation is put into the refining process for preparation, and the second brine solution can be obtained.
[0020] Further, before the extraction process and after the desalting process, there is also a step of detecting the pH value of the second crystal. The second crystal with a pH value between 7.5 - 9.5 is put into the extraction process, and the second crystal with a pH value not between 7.5 - 9.5 is put back into the desalting process. Preferably, the optimal pH value is between 8 - 9.
[0021] Further, in the stirring operation in the extraction process, the stirring frequency is 1 - 2 times per day, and the duration is 15 - 20 days.
[0022] On this basis, the present invention also provides a multi-stage purification device for a method of preparing small-molecule cluster water by combining gradient electrolysis and dynamic extraction, including a salt dissolving tank, a reaction device, a storage tank, a desalting tank, and an extraction tank. The functions of each component are as follows:
[0023] The salt dissolving tank includes a salt dissolving barrel and a refining reactor. The salt dissolving barrel is used for dissolving raw salt; the refining reactor is used for preparing the second brine solution;
[0024] The reaction device includes a reaction tank and a power controller. The reaction tank is provided with a positive electrode and a negative electrode. The power controller steps down 220v alternating current to 1.2v low-voltage electricity. The output terminals of the power controller are respectively connected to the positive and negative electrodes. The second brine solution undergoes electrolytic extraction and static purification treatment in the reaction tank;
[0025] The storage tank stores the brine mother liquor obtained from the static purification process;
[0026] The desalting tank is used for desalting the first crystal;
[0027] An extraction tank is used for dynamically extracting the second crystal.
[0028] Furthermore, the positive electrode of the reaction device is a zinc rod, and the negative electrode is a nano-carbon rod.
[0029] Furthermore, the material of the reaction tank is plastic or glass. The shape of the reaction tank includes vertical and horizontal types, and the horizontally-shaped reaction tank is the most preferred.
[0030] Due to the application of the above technical solutions, the present invention has the following advantages compared with the prior art:
[0031] 1. Simple process: By using gradient electrolytic crystallization and dynamic extraction technologies, the preparation process is simplified, and the equipment complexity is reduced.
[0032] 2. Low cost: By adopting a closed-loop circulation system, the raw material utilization rate exceeds 92%, significantly reducing the production cost.
[0033] 3. High-efficiency enrichment: Through electrolytic crystallization and dynamic extraction, not only can impurities and bacteria in water be effectively removed, but the small-molecule cluster water rich in trace elements made therefrom is also rich in minerals and trace elements, effectively enriching the minerals and trace elements in water and improving the water quality.
[0034] 4. Energy-saving and environmental protection: By adopting low-voltage electrolysis and natural light, the energy consumption is low, which conforms to the concept of green environmental protection. BRIEF DESCRIPTION OF THE DRAWINGS
[0035] Figure 1 It is a flow schematic diagram of the method for preparing small-molecule cluster water by combining gradient electrolysis and dynamic extraction in the present invention;
[0036] Figure 2 It is a framework diagram of the preparation device of the method for preparing small-molecule cluster water by combining gradient electrolysis and dynamic extraction in the present invention. DETAILED DESCRIPTION OF THE EMBODIMENTS
[0037] The technical solutions of the present invention will be described clearly and completely below. Obviously, the described embodiments are some, but not all, of the embodiments of the present invention. All other embodiments obtained by those of ordinary skill in the art based on the embodiments of the present invention without creative efforts shall fall within the protection scope of the present invention.
[0038] In the description of the present invention, it should be noted that the terms "first" and "second" are only used for descriptive purposes and cannot be understood as indicating or implying relative importance. In addition, the technical features involved in different embodiments of the present invention described below can be combined with each other as long as they do not conflict with each other.
[0039] The present invention relates to a method for preparing small-molecule cluster water rich in trace elements, and the preparation method at least includes the following processes:
[0040] Refining process, including salting out and refining the raw salt: mixing the raw salt and water to dissolve the raw salt to obtain a first brine solution; adjusting the first brine solution to prepare a second brine solution with a concentration of 15%; wherein, the raw salt can be rose salt, mineral salt, sea salt, lake salt, or well salt.
[0041] Reaction process, electrolytically extracting the second brine solution, and spiral first crystals appear on the surface of the container; wherein, the conditions for the electrolytic reaction of the second brine solution are: the light intensity is above 30000 lux, the ambient temperature is 10 - 30 degrees, and the reaction time is 7 days.
[0042] In addition, the reaction process also includes a stirring operation. Specifically, during the electrolytic reaction, the second brine solution is stirred every day, and the stirring frequency is 1 time / day.
[0043] Static purification process, allowing the solution after the reaction process to stand and performing solid-liquid separation to obtain the first crystals and brine mother liquor, and storing the first crystals and brine mother liquor separately; wherein, the standing time is 12 hours.
[0044] Among them, the separated first crystals need to be stored in a plastic container away from light. Preferably, the first crystals are stored in a black or blue plastic container.
[0045] Among them, after the brine mother liquor is subjected to precipitation and filtration treatment, the upper-layer brine mother liquor obtained is put into the refining process for adjustment to obtain a second brine solution.
[0046] Desalting process, adding the first crystals to mineral water for dilution, and obtaining second crystals through stirring, standing, and filtration; further, after the desalting process is completed, the pH value of the second crystals needs to be detected, and the second crystals with a pH value between 7.5 - 9.5 are put into the next process, and the second crystals with a pH value not between 7.5 - 9.5 are put back into the desalting process.
[0047] Preferably, the pH value of the second crystals is between 8 - 9.
[0048] Extraction process, adding the second crystals to mineral water and stirring clockwise to dynamically extract small-molecule cluster water rich in trace elements: wherein, the stirring frequency is 1 - 2 times / day, and the duration is 15 - 20 days.
[0049] In this embodiment, a multi-stage purification device for a method for preparing trace element-enriched small-molecule cluster water based on the combination of gradient electrolytic crystallization and dynamic extraction is provided, including the following components:
[0050] The brine dissolving tank, which includes a brine dissolving barrel and a refining reactor. The brine dissolving barrel is used for the brine dissolving treatment of raw salt, and the refining reactor is used for preparing the second brine solution.
[0051] The reaction device is used for electrolytic extraction and static purification treatment of the second brine solution, which includes a reaction tank and a power controller. The reaction tank is provided with a positive electrode and a negative electrode. The function of the power controller is to step down 220V alternating current to 1.2V low-voltage electricity.
[0052] Among them, the output terminals of the power controller are respectively connected to the positive and negative electrodes.
[0053] Preferably, the positive electrode is a zinc rod and the negative electrode is a nano-carbon rod.
[0054] Among them, the material of the reaction tank is plastic or glass, and the shape of the reaction tank has a vertical type and a horizontal type.
[0055] Preferably, the shape of the reaction tank is horizontal.
[0056] The liquid storage tank is used for storing the brine mother liquor.
[0057] The desalting tank is used for desalting treatment of the first crystal.
[0058] The extraction tank is used for dynamic extraction treatment of the second crystal.
[0059] The preparation method and device of the small molecule cluster water rich in trace elements in the above embodiments are simple in process and low in cost. They can not only effectively remove impurities and bacteria in water, but also the weakly alkaline small molecule cluster water prepared by the method and device is rich in dozens of trace elements and minerals, including potassium ion 3.48mg / L, magnesium ion 5mg / L, iron ion <4.5×10-3mg / L, zinc ion 0.700mg / L, copper ion <9×10-3mg / L, manganese ion <5×10-4mg / L, nickel ion <6×10-3mg / L, molybdenum ion <8×10-3mg / L, silver ion <0.013mg / L, germanium ion <2.0×10-4mg / L, selenium ion <4×10-4mg / L, strontium ion 6.3×10-2mg / L, lithium ion 1.61×10-3mg / L, thallium ion 0.04mg / L, vanadium ion <5×10-3mg / L, etc.
[0060] The above embodiments are only for explaining the technical concept and characteristics of the present invention. The purpose is to enable those skilled in the art to understand the content of the present invention and implement it accordingly, and it cannot be used to limit the protection scope of the present invention. All equivalent changes or modifications made according to the spirit and essence of the present invention should be covered within the protection scope of the present invention.
Claims
1. A method for preparing small molecular cluster water by combining gradient electrolysis and dynamic extraction, comprising a refining process, a reaction process, a static purification process, a desalting process, and an extraction process, characterized in that: The refining process includes salting and refining the raw materials such as rose salt and sea salt: mixing the raw salt with water, dissolving the raw salt, and obtaining a first salt water solution; The first saline solution is prepared to prepare a second saline solution with a concentration of 15%; A reaction step, electrolyzing the second salt water solution, and first spiral crystals appear on the surface of the container; a standing purification step, wherein the solution after the reaction step is allowed to stand and undergo solid-liquid separation to obtain the first crystals and a brine mother liquor, and the first crystals and the brine mother liquor are stored separately; Desalting step, adding the first crystals into mineral water for dilution, stirring, standing and filtering to obtain second crystals; In the extraction process, a proper amount of mineral water is added to the second crystals, and the mixture is stirred clockwise to dynamically extract small molecular cluster water rich in trace elements.
2. The method for preparing small molecular cluster water by gradient electrolysis-dynamic extraction according to claim 1, characterized in that: The second brine solution is subjected to a three-stage treatment system of electrolytic extraction + crystal purification + dynamic extraction, under conditions of light intensity of more than 30,000 lux and ambient temperature of 10 to 30 degrees. The light energy absorbed from sunlight is converted into magnetic energy through the device. The reaction time lasts for 7 days, and the second brine solution needs to be stirred during the reaction, with a stirring frequency of once a day.
3. The method for preparing small molecular cluster water by gradient electrolysis-dynamic extraction according to claim 1, characterized in that: In the static purification step, the static time is 12 hours.
4. The method for preparing small molecular cluster water by gradient electrolysis-dynamic extraction according to claim 1, characterized in that: The first crystals were stored in a blue plastic container in the dark.
5. The method for preparing small molecular cluster water by gradient electrolysis-dynamic extraction according to claim 1, characterized in that: The brine mother liquor is subjected to a precipitation and filtration treatment, and the upper brine mother liquor separated by precipitation is put into the refining step for blending to obtain a second brine solution.
6. The method for preparing small molecular cluster water by gradient electrolysis-dynamic extraction according to claim 1, characterized in that: After the desalting process and before the extraction process, the method further includes a step of detecting the pH value of the second crystals. The second crystals with a pH value between 7.5 and 9.5 are put into the extraction process, and the second crystals with a pH value not between 7.5 and 9.5 are put into the desalting process again.
7. The method for preparing small molecular cluster water by gradient electrolysis-dynamic extraction according to claim 1, characterized in that: The stirring operation in the extraction process is performed in a clockwise direction at a frequency of 1-2 times per day, 60 circles each time, and the duration is 15-20 days.
8. A preparation device for preparing small molecular cluster water based on the method for preparing small molecular cluster water by combining gradient electrolysis and dynamic extraction according to any one of claims 1 to 7, comprising a salting tank, a reaction device, a liquid storage tank, a desalting tank, and an extraction tank, characterized in that: The salt treatment pool includes a salt treatment tank and a refining reactor, wherein the salt treatment tank is used for salt treatment of raw salt, and the refining reactor is used for preparing the second brine solution; The reaction device includes a reaction tank and a power controller. The reaction tank is provided with a positive electrode and a negative electrode. The electrode material adopts an asymmetric design of zinc rods and nano-carbon rods. The ratio of the diameter of the zinc rod to the diameter of the nano-carbon rod is 1:1.2-1.
5. The power controller reduces the voltage of 220 volts of alternating current into 1.2 volts of low-voltage electricity. The voltage stabilization characteristic of the power controller, that is, the fluctuation rate is less than 1%. The output end of the power controller is connected to the positive and negative electrodes respectively. The second salt solution is electrolyzed in the reaction tank and is placed for purification. A liquid storage tank, in which the brine mother liquid obtained in the static purification step is stored: Desalination tank, used for desalination of the first crystal: An extraction tank is used for extracting the second crystal.
9. The preparation device of the method for preparing small molecular cluster water by combining gradient electrolysis and dynamic extraction according to claim 8, characterized in that: The positive electrode of the reaction device is a zinc rod, and the negative electrode is a nano carbon rod.
10. The preparation device of the method for preparing small molecular cluster water by combining gradient electrolysis and dynamic extraction according to claim 8, characterized in that: The reaction tank is made of plastic or glass, and has vertical and horizontal shapes.