Composition for removing age odor, application of composition and washing product

Abstract

The invention provides a composition for removing aging odor, application of the composition and a washing product, the composition for removing aging odor comprises a first component and a second component, and the mass ratio of the first component to the second component is 3: 1-12: 1; the first component is one or more of compounds containing primary amino, and the second component comprises one or more of sulfite, pyrosulfite and hydrosulfite. A primary amine group in the first component compound can be subjected to a Schiff base reaction with an aldehyde group, so that the main source substance 2-nonenal of the aged odor can be effectively eliminated; the sulfite, the pyrosulfite and / or the hydrosulfite in the second component can be subjected to redox reaction with the aldehyde group, so that the 2-nonenal can be effectively removed; the first component and the second component are used together, so that synergistic interaction can be realized, and an excellent 2-nonenal removal effect is achieved.

Description

Technical Field

[0001] The present application relates to the technical field of daily chemical products, and particularly to a composition for removing aging odor, its application, and a washing product. Background Art

[0002] Currently, issues related to the elderly have increasingly received extensive attention from all sectors of society. Among them, the phenomenon of aging odor (also known as "old people's smell") has gradually emerged and become one of the problems that cannot be ignored. Compared with other age groups, the elderly have relatively more leisure time, so social interaction occupies an important position in the lives of the elderly. However, aging odor, as a relatively common and easily detectable odor among the middle-aged and elderly groups, has brought many obstacles to their social lives. Aging odor not only causes psychological burdens on the elderly in interpersonal communication, reduces their quality of life, but also may lead to negative self-perception of their own images by the elderly, believing that they have lost their previous charm and value, thereby triggering negative emotions and affecting physical and mental health.

[0003] In the related art, under traditional washing conditions, it is difficult for detergents to thoroughly clean the odors attached to the clothes of the elderly.

[0004] The liquid detergent encapsulated in a water-soluble film is an innovative laundry product. It encapsulates a certain volume of detergent with a water-soluble film. It not only looks like beads, is small, delicate, fashionable and beautiful, but also is extremely convenient to use. There is no need to measure laboriously. One can wash a bucket of clothes. It is an ideal choice for modern people who pursue a convenient and fashionable life. However, there is a problem of the interaction between the water-soluble film and the content in the liquid detergent encapsulated in a water-soluble film, which leads to a reduction in the stability of this type of liquid detergent.

[0005] Therefore, how to provide a liquid detergent encapsulated in a water-soluble film that can effectively remove fabric odors and has excellent stability is an urgent problem to be solved at present. Summary of the Invention

[0006] Based on this, the present application provides a composition for removing aging odor, its application, and a washing product to effectively remove fabric odors and at the same time improve the stability of the liquid washing product encapsulated in a water-soluble film.

[0007] The first aspect of the present application provides a composition for removing aging odor, including a first component and a second component, and the mass ratio of the first component to the second component is 3:1 to 12:1; the first component has the structure shown in the following general formula (I):

[0008]

[0009] Among them, R1 is selected from one of C6-C12 alkyls;

[0010] The second component includes one or more of sulfite, metabisulfite and bisulfite.

[0011] In some embodiments, the first component compound is selected from one or more of n-hexyldipropylenetriamine, n-heptyldipropylenetriamine, isoheptyldipropylenetriamine, neoheptyldipropylenetriamine, n-octyldipropylenetriamine, isooctyldipropylenetriamine, sec-octyldipropylenetriamine, tert-octyldipropylenetriamine, n-nonyldipropylenetriamine, n-decyldipropylenetriamine, n-undecyldipropylenetriamine and n-dodecyldipropylenetriamine; and / or

[0012] The second component includes one or more of sodium sulfite, sodium bisulfite and sodium metabisulfite.

[0013] The second aspect of the present application provides an application of the composition for removing aged odor of the first aspect of the present application in the preparation of a washing product for removing aged odor.

[0014] The third aspect of the present application provides a washing product for removing aged odor. The washing product includes a water-soluble film and a washing liquid encapsulated in the water-soluble film. The washing liquid includes a first component and a second component, and the mass ratio of the first component to the second component is 3:1 to 12:1; the first component has the structure shown in the following general formula (I):

[0015]

[0016] wherein, R1 is selected from one of C6-C12 alkyls;

[0017] The second component includes one or more of sulfite, metabisulfite and bisulfite;

[0018] The mass proportion of the first component in the washing liquid is 3%-6%, and the mass proportion of the second component in the washing liquid is 0.5%-1%.

[0019] In some embodiments, the first component is selected from one or more of n-hexyldipropylenetriamine, n-heptyldipropylenetriamine, isoheptyldipropylenetriamine, neoheptyldipropylenetriamine, n-octyldipropylenetriamine, isooctyldipropylenetriamine, sec-octyldipropylenetriamine, tert-octyldipropylenetriamine, n-nonyldipropylenetriamine, n-decyldipropylenetriamine, n-undecyldipropylenetriamine and n-dodecyldipropylenetriamine; and / or

[0020] The second component includes one or more of sodium sulfite, sodium bisulfite and sodium metabisulfite.

[0021] In some embodiments, the washing liquid further comprises an anionic surfactant, a nonionic surfactant, an auxiliary agent, a solvent, and optionally an amphoteric surfactant and an optional cationic surfactant.

[0022] In some embodiments, the mass percentage of the anionic surfactant in the washing liquid is 20%-50%; and / or

[0023] The anionic surfactant includes one or more of alkylbenzene sulfonates having C6-C24 alkyl groups, alkyl sulfates having C8-C18 alkyl groups, ethoxylated fatty alcohol sulfates having C8-C18 alkyl groups, α-olefin sulfonates, fatty acid salts having C8-C18 alkyl groups, ethoxylated fatty alcohol ether carboxylates, sulfosuccinates, and alkyl disulfonates and their derivatives;

[0024] Optionally, the anionic surfactant includes one or more of dodecylbenzene sulfonate, sodium lauryl polyether sulfate, dodecyl sulfate, oleate, laurate, alkyl diphenyl ether disulfonate, and disodium fatty alcohol polyoxyethylene ether sulfosuccinate monoester.

[0025] In some embodiments, the mass percentage of the nonionic surfactant in the washing liquid is 20%-25%; and / or

[0026] The nonionic surfactant includes one or more of fatty alcohol alkoxylates having C6-C24 alkyl groups, alkyl polyglycosides having C6-C24 alkyl groups, fatty acid ester alkoxylates having C8-C18 alkyl groups, fatty acid alkyl alcohol amides having C6-C24 alkyl groups, fatty acid methyl ester ethoxylates having C6-C24 alkyl groups, and polyether surfactants.

[0027] In some embodiments, the mass percentage of the amphoteric surfactant in the washing liquid is 0%-15%, optionally 0.01%-15%; and / or

[0028] The amphoteric surfactant includes one or more of betaine-type surfactants, imidazoline-type surfactants, amino acid-type surfactants, and amine oxide-type surfactants;

[0029] Optionally, the betaine-type surfactant includes one or more of alkyl betaine, fatty amide betaine, fatty amide propyl betaine, and fatty amide propyl hydroxypropyl sulfobetaine;

[0030] Optionally, the imidazoline-type surfactant includes one or more of alkyl acetate-type imidazoline, fatty acid-type imidazoline, and sulfonic acid-type imidazoline;

[0031] Optionally, the amino acid-type surfactant includes one or more of amino propionate derivatives and glycine derivatives;

[0032] Optionally, the amine oxide surfactant includes one or more of alkyl dimethyl amine oxide and fatty amide propyl dimethyl amine oxide.

[0033] In some embodiments, the mass percentage of the cationic surfactant in the washing liquid is 0% - 15%, optionally 0.01% - 15%; and / or

[0034] The cationic surfactant includes one or more of quaternary ammonium salt surfactants, heterocyclic surfactants, and polymer-type cationic surfactants;

[0035] Optionally, the cationic surfactant includes one or more of single long straight-chain quaternary ammonium salts, double long straight-chain quaternary ammonium salts, benzyl quaternary ammonium salts, hydroxyalkyl quaternary ammonium salts, fatty amide propyl hydroxyalkyl quaternary ammonium salts, and multi-quaternary ammonium salts obtained by copolymerization of vinyl pyrrolidone with unsaturated amides or unsaturated quaternary ammonium salts.

[0036] In some embodiments, the mass percentage of the auxiliary agent in the washing liquid is 0.1% - 20%; and / or

[0037] The auxiliary agent includes a mixture of one or more of acid-base regulators, enzyme preparations, preservatives, polymers, inorganic salts, viscosity regulators, antibacterial and antifungal agents, colorants, fragrances, and water softeners;

[0038] Optionally, the acid-base regulator includes one or more of citric acid, succinic acid, boric acid, monoethanolamine, diethanolamine, triethanolamine, N-alkyl diethanolamine, tetraalkyl ammonium hydroxide, and ethylenediamine and its coupling products; further optionally, the tetraalkyl ammonium hydroxide includes one or more of tetramethyl ammonium hydroxide, tetraethyl ammonium hydroxide, and tetrabutyl ammonium hydroxide; further optionally, the ethylenediamine coupling products include one or more of diethylenetriamine, triethylenetetramine, and tetraethylenepentamine;

[0039] Optionally, the enzyme preparation includes one or more of protease, amylase, lipase, cellulase, mannanase, and pectinase;

[0040] Optionally, the antibacterial and antifungal agent includes one or more of hypochlorous acid and its salts, parachlorometaxylenol, parachlorometacresol, chloroxylenol, triclosan, trichlocarban, o-phenylphenol, dodecyl dimethyl benzyl ammonium chloride, dodecyl trimethyl ammonium chloride, tetradecyl dimethyl benzyl ammonium chloride, tetradecyl trimethyl ammonium chloride, hexadecyl trimethyl ammonium chloride, octadecyl trimethyl ammonium chloride, ditetradecyl dimethyl ammonium chloride, polyhexamethylene biguanide hydrochloride, 1-hexadecylpyridinium chloride, zinc pyrithione, and pyrithione ethanolamine salt;

[0041] Optionally, the polymer includes one or more of salts of homopolymers of acrylic acid, salts of copolymers of acrylic acid, cellulose derivatives, homopolymers of vinyl pyrrolidone, copolymers of vinyl pyrrolidone, and polyethyleneimine derivatives.

[0042] In some embodiments, the mass percentage of the solvent in the washing liquid is 20%-40%; and / or

[0043] The solvent includes a mixture of water and an organic substance, and the organic substance includes one or more of polyhydric alcohols and polyhydric alcohol ethers; optionally, the organic substance includes one or more of propylene glycol, glycerol, ethylene glycol, sorbitol, and polyethylene glycol.

[0044] In some embodiments, the material of the water-soluble film includes one or more of homopolymers of polyvinyl alcohol and copolymers of polyvinyl alcohol;

[0045] Optionally, the homopolymer of polyvinyl alcohol is a hydrolysis product of a homopolymer of vinyl acetate, and the degree of hydrolysis is 86%-99%;

[0046] Optionally, the copolymer of polyvinyl alcohol is a hydrolysis product of a copolymer of vinyl acetate and a second monomer, and the degree of hydrolysis is 86%-99%;

[0047] Further optionally, the second monomer includes one or more of acrylic acid, acrylic esters, methacrylic acid, and methacrylic esters.

[0048] In some embodiments, the pH value of the washing liquid in the washing product is 5.5-7.5.

[0049] In the composition for removing aging odor provided above, the primary amine group in the first component can undergo a Schiff base reaction with the aldehyde group, thereby effectively eliminating 2-nonenal, the main source substance of aging odor; the sulfite, metabisulfite, and / or bisulfite in the second component can undergo a redox reaction with the aldehyde group, thereby effectively removing 2-nonenal; by using the first component and the second component together, synergistic effects can be achieved, and an excellent 2-nonenal removal effect can be obtained.

[0050] The washing product for removing aging odor provided above has at least the following beneficial effects:

[0051] (1) Under traditional washing conditions, it has a good effect of removing aging odor from the clothes of the elderly.

[0052] (2) The outer film and liquid content of the washing product for removing aged odor have good stability after undergoing the aging treatment, without producing adverse effects such as color change, taste change, precipitation, delamination, leakage of the content, decline in dissolution performance, and decline in the performance of removing aged odor, that is, it has good content stability, film stability, dissolution stability, and the effect of removing aged odor.

[0053] (3) The washing product for removing aged odor is mild and non-irritating to the skin. BRIEF DESCRIPTION OF THE DRAWINGS

[0054] In order to more clearly illustrate the technical solutions in the embodiments of the present application and more fully understand the present application and its beneficial effects, the following will briefly introduce the drawings required for the description of the embodiments. Obviously, the following drawings are only some embodiments of the present application, and those skilled in the art can obtain other drawings based on these drawings without creative efforts.

[0055] Figure 1 It is the chromatogram of the removal rate of 2-nonenal by dodecyl dipropylenetriamine.

[0056] Figure 2 It is the chromatogram of the removal rate of 2-nonenal by sodium bisulfite.

[0057] Figure 3 It is the chromatogram of the removal rate of 2-nonenal by 2-amino-4-methylvaleric acid.

[0058] Figure 4 It is the appearance picture of Example 1 before aging treatment.

[0059] Figure 5 It is the appearance picture of Example 1 after aging treatment.

[0060] Figure 6 It is the appearance picture of Comparative Example 3 before aging treatment.

[0061] Figure 7 It is the appearance picture of Comparative Example 3 after aging treatment.

[0062] Figure 8 It is the appearance picture of Comparative Example 10 before aging treatment.

[0063] Figure 9 It is the appearance picture of Comparative Example 10 after aging treatment.

[0064] Figure 10 It is the appearance picture of Comparative Example 7 before aging treatment.

[0065] Figure 11 It is the appearance picture of Comparative Example 7 after aging treatment. SPECIFIC EMBODIMENTS

[0066] For the convenience of understanding the present invention, the present application will be described more comprehensively below with reference to related embodiments. The following gives preferred embodiments of the present application. However, the present application can be implemented in many different forms and is not limited to the embodiments described herein. On the contrary, these embodiments are provided to make the understanding of the disclosure of the present application more thorough and comprehensive.

[0067] Unless otherwise defined, all technical and scientific terms used herein have the same meaning as commonly understood by those of ordinary skill in the technical field to which this application belongs. The terms used in the specification of this application are only for the purpose of describing specific embodiments and are not intended to limit this application.

[0068] The term "and / or", "or / and", "and / or" as used herein includes any one of two or more related listed items, and also includes any and all combinations of the related listed items. The said any and all combinations include any two related listed items, any more related listed items, or the combination of all related listed items. It should be noted that when at least two conjunctions selected from "and / or", "or / and", "and / or" are used to connect at least three items, it should be understood that in this application, this technical solution undoubtedly includes the technical solution connected by "logical AND", and also undoubtedly includes the technical solution connected by "logical OR".

[0069] In this application, among the technical features described in an open-ended manner, it includes a closed technical solution composed of the listed features, and also includes an open technical solution containing the listed features.

[0070] In this application, when it comes to numerical ranges, unless otherwise specified, the above numerical ranges are considered continuous and include the minimum and maximum values of the range, as well as each value between such minimum and maximum values. Further, when the range refers to integers, it includes each integer between the minimum and maximum values of the range. In addition, when multiple ranges are provided to describe features or characteristics, these ranges can be combined. In other words, unless otherwise specified, all ranges disclosed herein should be understood to include any and all sub-ranges subsumed therein.

[0071] Only some numerical ranges are specifically disclosed herein. However, any lower limit can be combined with any upper limit to form a range not explicitly recited; and any lower limit can be combined with other lower limits to form a range not explicitly recited, and similarly any upper limit can be combined with any other upper limit to form a range not explicitly recited. In addition, each individually disclosed point or single numerical value itself can be used as a lower limit or an upper limit to be combined with any other point or single numerical value or with other lower limits or upper limits to form a range not explicitly recited.

[0072] In this application, unless otherwise specified, all percentages, fractions, and ratios are calculated based on the total mass of the compositions of the present invention. Unless otherwise indicated, the mass fractions of the listed components refer to the content of the active substances, that is, the listed components do not include diluents, by-products, or other components that may be contained in the raw materials obtained by purchase. The term "mass fraction" is represented by the symbol "%".

[0073] The temperature parameters in this application, unless otherwise specifically defined, allow both constant temperature treatment and treatment within a certain temperature range. The constant temperature treatment allows the temperature to fluctuate within the accuracy range controlled by the instrument. Fluctuations within ranges such as ±5℃, ±4℃, ±3℃, ±2℃, ±1℃ are allowed.

[0074] Unless otherwise specified, all preparations and tests in this article occur in a room temperature environment. Room temperature generally refers to 4℃~30℃, preferably 25±5℃.

[0075] The dimensions and numerical values disclosed in this application should not be understood as strict limitations of the precise values. Unless otherwise specified, each such dimension is intended to represent the value and the functionally equivalent range around that value. For example, a dimension disclosed as "45℃" is intended to represent "about 45℃".

[0076] In this article, the "suitable combination method", "suitable method", "any suitable method", etc. The "suitable" described herein is subject to being able to implement the technical solution of this application, solve the technical problems of this application, and achieve the expected technical effects of this application.

[0077] In this application, "further", "even further", "especially", etc. are used for descriptive purposes, indicating differences in content, but should not be understood as limitations on the protection scope of this application.

[0078] In this application, "optionally", "optional", "option", mean that it can be either present or absent, that is, it refers to any one of the two alternative schemes of "present" or "absent". If "optional" appears multiple times in a technical solution, unless otherwise specifically stated and there are no contradictions or mutual restrictions, each "optional" is independent of each other.

[0079] In the description of the application, the meaning of "a variety of" is at least two, such as two, three, etc., unless otherwise specifically defined.

[0080] Unless otherwise indicated, all preparations and tests in this article occur in an environment of 25℃.

[0081] In this text, the terms "include", "comprise", "contain", "have", or other variants are intended to cover non-closed inclusion, and no distinction is made between these terms. The term "comprise" also includes the terms "consist of" and "substantially consist of", which means that other steps and components that do not affect the final result can be added according to the actual situation. The compositions and methods / processes of the present invention contain, consist of, and substantially consist of the essential elements and limitations described herein, as well as any additional or optional components, ingredients, steps, or limitations described herein.

[0082] If there is no special instruction, all embodiments and optional embodiments of this application can be combined with each other to form a new technical solution. If there is no special instruction, all technical features and optional technical features of this application can be combined with each other to form a new technical solution.

[0083] If there is no special instruction, all steps of this application can be carried out sequentially or randomly, and preferably sequentially.

[0084] In this application, no distinction is made between "performance" and "efficiency". No distinction is made between "stability" and "stable performance". No distinction is made between "aging", "accelerated aging", "aging treatment", and "accelerated aging treatment". No distinction is made between "2-nonenal" and "nonenal".

[0085] The term "fabric odor" involved in this application refers to the odor of aging. In the present invention, no distinction is made between "odor of aging", "old person smell", and "fabric odor".

[0086] The term "odor of aging" involved in this application refers to the general term for the odor produced by the oxidative decomposition of unsaturated fatty acids secreted by the human body or by the decomposition of skin resident bacteria. 2-Nonenal is one of the main components of this odor. In this application, 2-nonenal is used as a representative substance of the odor of aging, and the ability to remove 2-nonenal is used as a quantitative characterization of the ability to remove the odor of aging.

[0087] It should be noted that the "washing product" of this application is obtained by encapsulating the washing liquid with a water-soluble film. The volume of the encapsulated washing liquid is 5 mL to 35 mL. The term "outer membrane" in this application refers to the side of the water-soluble film that is exposed to the air in the detergent composition encapsulated by the water-soluble film. The term "inner membrane" refers to the side of the water-soluble film that is in direct contact with the liquid detergent composition in the detergent composition encapsulated by the water-soluble film.

[0088] The "washing liquid" of this application covers the following forms, in which the solid components are present in liquid compositions such as dispersions, gels, slurries, etc. The washing product also includes capsule-type detergents prepared using the washing liquid of this application.

[0089] The term "washing liquid" refers to any fabric detergent composition that includes a liquid capable of wetting and treating fabrics, and the ways of wetting and treating fabrics include pre-coating with the undiluted composition, hand-washing after dilution with tap water, machine-washing with a washing machine, etc. A large number of literature studies have shown that aging odor is closely related to unsaturated aldehydes such as octenal and nonenal. The main mechanism of its generation is as follows: The content of 9-hexadecenoic acid (palmitoleic acid) in the sebum secretions of middle-aged and elderly people shows an upward trend with age. This unsaturated fatty acid will undergo oxidative decomposition through lipid peroxides or decomposition reactions under the action of skin resident bacteria, and finally generate 2-nonenal with an unpleasant odor.

[0090] To effectively address the problem of aging odor, a variety of solutions have emerged in the current related technologies. For example, using a fragrance composition to mask the body odor of the elderly. However, this method only superficially masks the odor and fails to touch the root of the problem, and cannot fundamentally eliminate the "aging odor". Or using butylene glycol, oolong tea extract and sweet tea extract as aging odor deodorants. Although it has a certain deodorizing effect, the required concentration for the effect is quite high. For example, the concentration of 1,3-butylene glycol solution is as high as 50%, which may be restricted in practical applications. Or using arginine aspartate to remove 2-nonenal and then inhibit the odor of the elderly. However, the action time of this method is relatively long, up to 20 hours, and it is difficult to meet people's needs for convenient and efficient problem-solving. Moreover, most of the above methods are applied as skin external components in the cosmetics field, and a relatively high concentration or a long action time is required to achieve a better removal effect.

[0091] Under normal washing conditions, it is difficult for detergents to completely remove the odor attached to the clothes of the elderly, which undoubtedly brings new challenges to solving the problem of aging odor.

[0092] The water-soluble film-encapsulated liquid detergent composition is an innovative laundry product. It encapsulates a certain volume of detergent with a water-soluble film. It not only looks like beads, small, delicate, fashionable and beautiful, but also is extremely convenient to use. There is no need to measure laboriously. One can wash a bucket of clothes. It is an ideal choice for modern people who pursue a convenient and fashionable life. However, it also has problems with the interaction between the water-soluble film and the content, such as possible color change affecting the aesthetic degree; or soft collapse phenomenon, where the product loses its proper shape and integrity before use; in severe cases, it may even cause the content to precipitate, which not only affects the cleaning effect of the product, but also may cause pollution to other items during storage, bringing inconvenience and trouble to users.

[0093] How to provide a water-soluble film-encapsulated liquid detergent that can effectively remove fabric odors and has excellent stability is an urgent problem to be solved at present. Based on the above problems, this application will include a first component with a compound of a specific structure and a second component containing at least one of sulfite, pyrosulfite, and bisulfite, which are used together as a composition for removing aging odor, and can synergistically enhance the effect to effectively remove the aging odor of the clothes of the elderly.

[0094] One or more embodiments of this application provide a composition for removing aging odor, including a first component and a second component, and the mass ratio of the first component to the second component is 3:1 to 12:1; the first component has the structure shown in the following general formula (I):

[0095]

[0096] Among them, R1 is selected from one of C6-C12 alkyl groups;

[0097] The second component includes one or more of sulfite, pyrosulfite, and bisulfite.

[0098] It should be noted that in this application, "the first component", "the second component", etc. are only for descriptive purposes, and cannot be understood as indicating or implying relative importance or quantity, nor can it be understood as implicitly indicating the importance or quantity of the indicated technical features. Moreover, "the first", "the second", etc. only serve the purpose of non-exhaustive enumeration and description, and it should be understood that they do not constitute a closed limitation on the quantity.

[0099] As an example, the mass ratio of the first component to the second component of 3:1 to 12:1 can be, but is not limited to, 3:1, 4:1, 5:1, 6:1, 7:1, 8:1, 9:1, 10:1, 11:1, 12:1 or the range between any two of the above mass ratios, etc. When the mass ratio of the first component to the second component is within the above range, the water-soluble film-encapsulated liquid detergent composition not only has a good effect of removing the aging odor of the clothes of the elderly, but also has good stability at the same time, that is, after the detergent composition undergoes aging treatment, its content color change value, film integrity, film appearance change degree, content integrity, odor stability, and dissolution stability are also good.

[0100] It can be understood that in the composition for removing aging odor provided by this application, the primary amine group in the first component can react with the aldehyde group to form a Schiff base reaction, so as to effectively eliminate 2-nonenal, the main source substance of aging odor; the sulfite, pyrosulfite, and / or bisulfite in the second component can react with the aldehyde group in an oxidation-reduction reaction, so as to effectively remove 2-nonenal; by using the first component and the second component together, the effect can be synergistically enhanced to achieve an excellent 2-nonenal removal effect.

[0101] In some alternative embodiments, the first component is selected from one or more of n-hexyldipropylenetriamine, n-heptyldipropylenetriamine, isoheptyldipropylenetriamine, neoheptyldipropylenetriamine, n-octyldipropylenetriamine, iso-octyldipropylenetriamine, sec-octyldipropylenetriamine, tert-octyldipropylenetriamine, n-nonyldipropylenetriamine, n-decyldipropylenetriamine, n-undecyldipropylenetriamine, and n-dodecyldipropylenetriamine.

[0102] In some exemplary embodiments, the second component includes one or more of sodium sulfite, sodium bisulfite, and sodium metabisulfite.

[0103] One or more embodiments of the present application provide an application of the above-mentioned composition for removing aged odor in the preparation of a washing product for removing aged odor.

[0104] One or more embodiments of the present application provide a washing product for removing aged odor, the washing product includes a water-soluble film and a washing liquid encapsulated in the water-soluble film, the washing liquid includes a first component and a second component, and the mass ratio of the first component to the second component is 3:1 to 12:1; the first component has a structure shown in the following general formula (I):

[0105]

[0106] Wherein, R1 is selected from one of C6-C12 alkyls;

[0107] The second component includes one or more of sulfites, metabisulfites, and bisulfites;

[0108] The mass proportion of the first component in the washing liquid is 3%-6%, and the mass proportion of the second component in the washing liquid is 0.5%-1%.

[0109] As an example, the mass proportion of the first component in the washing liquid can be, but is not limited to, 3%, 3.2%, 3.4%, 3.6%, 3.8%, 4%, 4.2%, 4.4%, 4.6%, 4.8%, 5%, 5.2%, 5.4%, 5.6%, 5.8%, 6% or the range between any two of the above mass proportions, etc. When the mass proportion of the first component in the washing liquid is within the above range, it has a good effect of removing the aged odor of old people's clothes, and at the same time does not affect the color stability of the liquid detergent composition encapsulated by the water-soluble film.

[0110] The mass percentage of the second component in the washing liquid can be, but is not limited to, 0.5%, 0.55%, 0.6%, 0.65%, 0.7%, 0.75%, 0.8%, 0.85%, 0.9%, 1%, or the range between any two of the above mass percentages, etc. When the mass percentage of the second component in the washing liquid is within the above range, it not only has the effect of synergistically removing the aging odor of the elderly's clothes, but also helps to improve the color stability of the liquid detergent composition encapsulated by the water-soluble film, and at the same time does not cause wrinkling of the appearance of the water-soluble film.

[0111] It can be understood that the washing product provided above for removing aging odor has at least the following beneficial effects:

[0112] (1) Under traditional washing conditions, it has a good effect of removing the aging odor of the elderly's clothes.

[0113] (2) The outer film and liquid content of the washing product for removing aging odor have good stability after undergoing aging treatment, and do not produce bad effects such as color change, taste change, precipitation, stratification, leakage of the content, decline in dissolution performance, and decline in the performance of removing aging odor, that is, it has good content stability, film stability, dissolution stability, and the effect of removing aging odor.

[0114] (3) The washing product for removing aging odor is mild and non-irritating to the skin.

[0115] In some embodiments, the first component is selected from one or more of n-hexyldipropylenetriamine, n-heptyldipropylenetriamine, isoheptyldipropylenetriamine, neoheptyldipropylenetriamine, n-octyldipropylenetriamine, iso-octyldipropylenetriamine, sec-octyldipropylenetriamine, tert-octyldipropylenetriamine, n-nonyldipropylenetriamine, n-decyldipropylenetriamine, n-undecyldipropylenetriamine, and n-dodecyldipropylenetriamine.

[0116] In some alternative embodiments, the second component includes one or more of sodium sulfite, sodium bisulfite, and sodium metabisulfite.

[0117] In some embodiments, the washing liquid further includes an anionic surfactant, a nonionic surfactant, an auxiliary agent, a solvent, and optionally an amphoteric surfactant and an optional cationic surfactant.

[0118] It should be noted that the "optional amphoteric surfactant" means that the washing liquid may or may not contain an amphoteric surfactant. The "optional cationic surfactant" means that the washing liquid may or may not contain a cationic surfactant.

[0119] In some embodiments, the mass percentage of the anionic surfactant in the washing liquid is 20%-50%; for example, it can be, but is not limited to, 20%, 22%, 24%, 26%, 28%, 30%, 32%, 34%, 36%, 38%, 40%, 42%, 44%, 46%, 48%, 50% or the range between any two of the above mass percentages, etc.

[0120] In some embodiments, the anionic surfactant includes one or more of alkylbenzene sulfonates having C6-C24 alkyl chains, alkyl sulfates having C8-C18 alkyl chains, ethoxylated fatty alcohol sulfates having C8-C18 alkyl chains, α-olefin sulfonates, fatty acid salts having C8-C18 alkyl chains, ethoxylated fatty alcohol ether carboxylates, sulfosuccinates, and alkyl disulfonates and their derivatives.

[0121] As a non-limiting example, the alkyl chain segment in the alkylbenzene sulfonate having C6-C24 alkyl chains is selected from straight-chain alkyls and branched-chain alkyls; it can be a saturated alkyl or an alkyl containing one or more unsaturated double bonds, and its content is not less than 15% based on alkylbenzene sulfonic acid.

[0122] The alkylbenzene sulfonate satisfies the structure shown by the following general formula:

[0123]

[0124] Among them, R is an alkyl having 6 to 24 carbon atoms, and M + is the cationic part. A suitable example is dodecylbenzene sulfonate.

[0125] The ethoxylated fatty alcohol sulfate is a derivative of ethoxylated fatty alcohol and has the structure shown by the following general formula:

[0126]

[0127] R b is an alkyl having 6 to 24 carbon atoms; x is 0.5 to 15; among them, M + is the cationic part. R1 can be a straight-chain alkyl or a branched-chain alkyl; it can be a saturated alkyl or an alkyl containing one or more unsaturated double bonds. Preferably, R b is a straight-chain alkyl having 8 to 18 carbon atoms. x represents the average degree of ethoxylation, which is 0.5 to 15, preferably 0.5 to 10, and more preferably 0.5 to 3.

[0128] The alkyl chain segment in the alkyl sulfate can be straight-chain or branched-chain, and can be a saturated alkyl or an alkyl containing one or more unsaturated double bonds. Preferably, it is an alkyl sulfate having 6 to 24 carbon atoms in the alkyl, and further preferably an alkyl sulfate having 8 to 18 carbon atoms. A suitable example is ethoxylated lauryl alcohol sulfate (the average degree of ethoxylation is 2 to 3).

[0129] The α-olefin sulfonate has a structure represented by the following general formula:

[0130]

[0131] a is from 0 to 2, and R c is an alkyl group having 6 to 24 carbon atoms, and preferably R c is an alkyl group having 8 to 18 carbon atoms.

[0132] The alkyl chain segment in the fatty acid salt of C8-C18 can be straight-chain or branched-chain, and can be a saturated alkyl group or an alkyl group containing one or more unsaturated double bonds. The fatty acid salt can be of a single composition or a mixture of multiple fatty acids.

[0133] The ethoxylated fatty alcohol ether carboxylate preferably contains 8 to 18 carbon atoms, and the average degree of ethoxylation is preferably 2 to 10.

[0134] In some alternative embodiments, the anionic surfactant includes one or more of dodecylbenzenesulfonate, sodium lauryl polyether sulfate, dodecyl sulfate, oleate, laurate, alkyl diphenyl ether disulfonate, and disodium fatty alcohol polyoxyethylene ether sulfosuccinate monoester.

[0135] The fatty alcohol in the disodium fatty alcohol polyoxyethylene ether sulfosuccinate monoester preferably has 8 to 18 carbon atoms, and the average degree of ethoxylation is preferably 2.0.

[0136] As a non-limiting example, the cationic part contained in the anionic surfactant can be selected from one or more of sodium ions, potassium ions, ammonium ions formed by ammonium and organic amines, etc. The organic amine in the ammonium ion formed by organic amine can be selected from one or more of monoethanolamine, diethanolamine, triethanolamine, N-alkyl diethanolamine, ethylenediamine and its by-products, etc. Ethylenediamine and its by-products include one or more of diethylenetriamine, triethylenetetramine, tetraethylenepentamine, etc.

[0137] In some embodiments, the mass ratio of the non-ionic surfactant in the washing liquid is 20%-25%; for example, it can be but not limited to 20%, 21%, 22%, 23%, 24%, 25% or the range between any two of the above mass ratios, etc.

[0138] In some embodiments, the non-ionic surfactant includes one or more of C6-C24 fatty alcohol alkoxylates, C6-C24 alkyl polyglycosides, C8-C18 fatty acid ester alkoxylates, C6-C24 fatty acid alkyl alcohol amides, C6-C24 fatty acid methyl ester ethoxylates, and polyether surfactants.

[0139] The fatty alcohol alkoxylates have the following general formula:

[0140]

[0141] n is from 6 to 24; x is from 5 to 30, and y is from 0 to 10. The fatty alcohol alkoxylates are the products of ring-opening polymerization of fatty alcohols and alkylene oxides under the action of a basic catalyst, and are basically mixtures. The fatty alcohols include straight-chain alcohols or branched isomeric alcohols. The alkoxy groups include ethoxy groups and propoxy groups. The fatty alcohols are preferably fatty alcohols having 8 to 18 carbon atoms, and the preferred alcohols include, but are not limited to, one or a mixture of octanol, decanol, 2-ethylhexanol, 3-propylheptanol, lauryl alcohol, isotridecanol, tridecanol, tetradecanol, hexadecanol, palm oil alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, linoleyl alcohol, and linolenyl alcohol. The average degree of ethoxylation x is preferably from 2 to 12.

[0142] As a non-limiting example, the fatty alcohol alkoxylates can be selected from the NEODOL series of straight-chain fatty alcohol ethoxylates products of SHELL, the ECOSURF EH series of ethoxylated and propoxylated 2-ethylhexanol products of DOW, the Lutensol XL series of ethoxylated and propoxylated 3-propylheptanol products of BASF, and the Lutensol XP series of ethoxylated 3-propylheptanol products of BASF.

[0143] The alkyl polyglycosides have the structure shown by the following general formula:

[0144]

[0145] n is from 6 to 24, and p is from 1.1 to 3. Preferably, n is from 8 to 16. As a non-limiting example, the alkyl polyglycosides can be selected from the Glucopon series of alkyl polyglycosides products of BASF.

[0146] In the fatty acid alkylolamide, the carbon number of the fatty acid chain segment is from 6 to 24, which can be a straight-chain fatty acid, a branched-chain fatty acid, a saturated fatty acid, or an unsaturated fatty acid; the number of alkylol groups is from 0 to 2. Preferably, the fatty acid is a monoethanolamide, diethanolamide, or isopropanolamide having 8 to 18 carbon atoms. As a non-limiting example, the fatty acid alkylolamide can be coconut oil acid diethanolamide.

[0147] The fatty acid methyl ester ethoxylates have the structure shown by the following general formula:

[0148]

[0149] n is from 6 to 24; x is from 2 to 20. Preferably, n is from 8 to 18 and x is from 0.5 to 30. Preferably, x is from 4 to 10. As a non-limiting example, fatty acid methyl ester ethoxylate can adopt the MEE product of LION Corporation.

[0150] Polyether surfactants are nonionic surfactants containing ethylene oxide and / or propylene oxide repeating units. As a non-limiting example, polyether surfactants can adopt the Pluronic series products of BASF Corporation.

[0151] In some embodiments, the mass proportion of zwitterionic surfactants in the washing liquid is 0%-15%; for example, it can be but not limited to 0.01%, 0.1%, 0.5%, 1%, 2%, 3%, 4%, 5%, 6%, 7%, 8%, 9%, 10%, 11%, 12%, 13%, 14%, 15% or the range between any two of the above mass proportions, etc.

[0152] It should be noted that when the mass proportion of zwitterionic surfactants in the washing liquid is 0%, it means that the washing liquid does not contain zwitterionic surfactants.

[0153] In an alternative embodiment, the mass proportion of zwitterionic surfactants in the washing liquid is 0.01%-15%.

[0154] It should be noted that in this application, there is no distinction between amphoteric surfactants, amphoteric surfactants and zwitterionic surfactants.

[0155] In some embodiments, zwitterionic surfactants include one or more of betaine surfactants, imidazoline surfactants, amino acid surfactants and amine oxide surfactants.

[0156] As a possible embodiment, betaine surfactants include one or more of alkyl betaines, fatty acid amide betaines, fatty acid amide propyl betaines and fatty acid amide propyl hydroxypropyl sulfobetaines.

[0157] In some alternative embodiments, imidazoline surfactants include one or more of alkyl acetate imidazolines, fatty acid imidazolines and sulfonic acid imidazolines.

[0158] In some of these embodiments, amino acid surfactants include one or more of aminopropionic acid derivatives and glycine derivatives.

[0159] As a possible embodiment, amine oxide surfactants include one or more of alkyl dimethyl amine oxides and fatty acid amide propyl dimethyl amine oxides

[0160] As a non-limiting example, the zwitterionic surfactant may be one or more of lauryldimethylamine oxide, coconut oil amide propylamine oxide, and coconut oil amide propyl betaine.

[0161] In some embodiments, the mass percentage of the cationic surfactant in the washing liquid is 0%-15%; for example, it may be, but is not limited to, 0.01%, 0.1%, 0.5%, 1%, 2%, 3%, 4%, 5%, 6%, 7%, 8%, 9%, 10%, 11%, 12%, 13%, 14%, 15%, or the range between any two of the above mass percentages, etc.

[0162] It should be noted that when the mass percentage of the cationic surfactant in the washing liquid is 0%, it means that the washing liquid does not contain a cationic surfactant.

[0163] In some alternative embodiments, the mass percentage of the cationic surfactant in the washing liquid is 0.01%-15%.

[0164] In some embodiments, the cationic surfactant includes one or more of quaternary ammonium salt surfactants, heterocyclic surfactants, and polymeric cationic surfactants.

[0165] As a possible embodiment, the cationic surfactant includes one or more of single long straight-chain quaternary ammonium salts, double long straight-chain quaternary ammonium salts, benzyl quaternary ammonium salts, hydroxyalkyl quaternary ammonium salts, fatty amide propyl hydroxyalkyl quaternary ammonium salts, and multi-quaternary ammonium salts obtained by copolymerization of vinyl pyrrolidone with unsaturated amides or unsaturated quaternary ammonium salts.

[0166] In some embodiments, the mass percentage of the auxiliary agent in the washing liquid is 0.1%-20%.

[0167] As a possible embodiment, the auxiliary agent includes a mixture of one or more of acid-base regulators, enzyme preparations, preservatives, polymers, inorganic salts, viscosity regulators, antibacterial and antifungal agents, colorants, fragrances, and water softeners.

[0168] In some alternative embodiments, the acid-base regulator includes an acidity regulator and an alkalinity regulator. The acidity regulator includes one or more of organic acids, inorganic acids, and strong acid-weak base salts. Optionally, the acidity regulator includes one or more of citric acid, succinic acid, and boric acid. The alkalinity regulator includes organic amines. Optionally, the organic amines include one or more of monoethanolamine, diethanolamine, triethanolamine, N-alkyl diethanolamine, tetraalkyl ammonium hydroxide, and ethylenediamine and its coupling products. Further optionally, the tetraalkyl ammonium hydroxide includes one or more of tetramethyl ammonium hydroxide, tetraethyl ammonium hydroxide, and tetrabutyl ammonium hydroxide; further optionally, the ethylenediamine coupling products include one or more of diethylenetriamine, triethylenetetramine, and tetraethylenepentamine.

[0169] In some embodiments, the enzyme preparation includes one or more of protease, amylase, lipase, cellulase, mannanase, and pectinase.

[0170] As a possible embodiment, the mass percentage of the enzyme preparation in the washing liquid is 0.01-5%, optionally 0.1%-2%.

[0171] In some embodiments, the antibacterial and antifungal agent includes one or more of hypochlorous acid and its salts, parachlorometaxylenol, parachlorocresol, chloroxylenol, triclosan, triclocarban, o-phenylphenol, dodecyldimethylbenzylammonium chloride, dodecyltrimethylammonium chloride, tetradecyldimethylbenzylammonium chloride, tetradecyltrimethylammonium chloride, cetyltrimethylammonium chloride, octadecyltrimethylammonium chloride, ditetradecyldimethylammonium chloride, polyhexamethyleneguanidine hydrochloride, 1-hexadecylpyridinium chloride, zinc pyrithione, and pyrithione ethanolamine salt.

[0172] As a possible embodiment, the polymer includes one or more of salts of homopolymers of acrylic acid, salts of copolymers of acrylic acid, cellulose derivatives, homopolymers of vinylpyrrolidone, copolymers of vinylpyrrolidone, and polyethyleneimine derivatives.

[0173] In some alternative embodiments, the cellulose derivative includes at least one of carboxymethyl cellulose, ethyl hydroxyethyl cellulose, and methyl cellulose. The polyethyleneimine derivative includes one or more of ethoxylated polyethyleneimine, polyethylene terephthalate glycol ester and its derivatives, and polyethylene glycol and its derivatives.

[0174] It should be noted that by adding the polymer, the dissociation of dirt from the substrate surface can be effectively promoted, the redeposition of dirt can be avoided, and the appearance of the detergent composition can be improved.

[0175] In some embodiments, the mass percentage of the solvent in the washing liquid is 20%-40%; for example, it can be, but is not limited to, 20%, 22%, 24%, 26%, 28%, 30%, 32%, 34%, 36%, 38%, 40%, or the range between any two of the above mass percentages, etc.

[0176] In some alternative embodiments, the solvent includes a mixture of water and an organic substance, and the organic substance includes one or more of polyhydric alcohols and polyhydric alcohol ethers. Optionally, the organic substance includes one or more of propylene glycol, glycerol, ethylene glycol, sorbitol, and polyethylene glycol.

[0177] It should be noted that "water" and "deionized water" are not distinguished in this application.

[0178] As a non-limiting example, the washing liquid may further contain one or more of a co-solvent, a solubilizer, a structuring agent, a foam promoter, a foam inhibitor, a fabric softener, a bleaching system, and an anti-wrinkle agent.

[0179] In some embodiments, the material of the water-soluble film includes one or more of a polyvinyl alcohol homopolymer and a polyvinyl alcohol copolymer.

[0180] It should be noted that the water-soluble film of the present application is a water-soluble polymer prepared from monomers and then obtained through a film-forming device. The terms water-soluble film and water-soluble thin film in the present application are not distinguished. The thickness of the water-soluble film is 65 to 90 microns.

[0181] In some alternative embodiments, the polyvinyl alcohol homopolymer is a hydrolysis product of a homopolymer of vinyl acetate, and the degree of hydrolysis is 86%-99%; for example, it can be, but is not limited to, 86%, 88%, 90%, 92%, 94%, 96%, 98%, 99% or the range between any two of the above degrees of hydrolysis, etc.

[0182] It should be noted that the test method for the degree of hydrolysis is described in detail in "GB / T12010.2-2010 Plastics - Polyvinyl Alcohol Materials (PVAL) - Part 2: Determination of Properties". In this standard, the degree of hydrolysis is called the degree of alcoholysis, and the two have the same meaning.

[0183] In some alternative embodiments, the polyvinyl alcohol copolymer is a hydrolysis product of a copolymer of vinyl acetate and a second monomer, and the degree of hydrolysis is 86%-99%; for example, it can be, but is not limited to, 86%, 88%, 90%, 92%, 94%, 96%, 98%, 99% or the range between any two of the above degrees of hydrolysis, etc.

[0184] As a possible embodiment, the second monomer includes one or more of acrylic acid, acrylic esters, methacrylic acid, and methacrylic esters.

[0185] In some embodiments, the pH value of the washing liquid in the washing product is 5.5-7.5; for example, it can be, but is not limited to, 5.5, 5.7, 6, 6.3, 6.5, 6.8, 7, 7.3, 7.5 or the range between any two of the above pH values, etc.

[0186] It should be noted that the washing product of the present application can be prepared by various methods well-known to those skilled in the art to make the components constituting the washing liquid uniformly mixed. The preparation of the composition can be carried out by conventional means, and specific formulation parameters should be selected according to the physical and chemical properties and stability of the components, such as the formulation temperature, stirring time, and the rate of temperature rise and fall.

[0187] The method of using the water-soluble film-encapsulated washing product involved in this application is well-known to those skilled in the art. A relatively conventional method of use is to bring the washing product into contact with the item to be washed in its undiluted form or diluted in water, and then perform washing through scrubbing, mechanical stirring, or other means, and finally perform rinsing to remove it from the surface of the item. The item to be washed is a fabric.

[0188] The following specifically describes the technical solution of the present invention in combination with specific embodiments. It should be understood that these embodiments are only used to illustrate the present invention and not to limit the scope of the present invention. For the experimental methods without specific conditions indicated in the following embodiments, priority is given to the guidance given in the present invention, and it can also be carried out according to the experimental manuals or conventional conditions in the art, or according to the conditions recommended by the manufacturer, or referring to the experimental methods known in the art.

[0189] In the following specific embodiments, regarding the measurement parameters of the raw material components, if there is no special indication, there may be slight deviations within the weighing accuracy range. Regarding the temperature and time parameters, acceptable deviations caused by instrument test accuracy or operation accuracy are allowed.

[0190] In the following embodiments, the following compounds are used:

[0191] Hexyldipropylenetriamine, belonging to the category of aging odor removers (the first component, nitrogen-containing compound), meets the requirements of the technical solution of this application.

[0192] Dodecyldipropylenetriamine, belonging to the category of aging odor removers (the first component, nitrogen-containing compound), meets the requirements of the technical solution of this application.

[0193] Sodium sulfite, belonging to the category of aging odor removers (the second component, sulfur-containing compound), meets the requirements of the technical solution of this application.

[0194] Sodium bisulfite, belonging to the category of aging odor removers (the second component, sulfur-containing compound), meets the requirements of the technical solution of this application.

[0195] Sodium metabisulfite, belonging to the category of aging odor removers (the second component, sulfur-containing compound), meets the requirements of the technical solution of this application.

[0196] 4-Amino-1-butanol, belonging to the category of aging odor removers (the first component, nitrogen-containing compound), does not meet the requirements of the technical solution of this application.

[0197] 2,2'-Dihydroxydiethylamine, belonging to the category of aging odor removers (the first component, nitrogen-containing compound), does not meet the requirements of the technical solution of this application.

[0198] 2,6-Diaminohexanoic acid, belonging to the category of aging odor removers (the first component, nitrogen-containing compounds), does not meet the requirements of the technical solution of this application.

[0199] 2-Amino-4-methylpentanoic acid, belonging to the category of aging odor removers (the first component, nitrogen-containing compounds), does not meet the requirements of the technical solution of this application.

[0200] Pentyl dipropylenetriamine, belonging to the category of aging odor removers (the first component, nitrogen-containing compounds), does not meet the requirements of the technical solution of this application.

[0201] Tetradecyl dipropylenetriamine, belonging to the category of aging odor removers (the first component, nitrogen-containing compounds), does not meet the requirements of the technical solution of this application.

[0202] Hexylamine, belonging to the category of aging odor removers (the first component, nitrogen-containing compounds), does not meet the requirements of the technical solution of this application.

[0203] Sodium dithionite, belonging to the category of aging odor removers (the second component, sulfur-containing compounds), does not meet the requirements of the technical solution of this application.

[0204] Sodium thiosulfate, belonging to the category of aging odor removers (the second component, sulfur-containing compounds), does not meet the requirements of the technical solution of this application.

[0205] Dodecylbenzenesulfonic acid, abbreviated as LAH, belongs to the precursor of linear alkylbenzene sulfonates in anionic surfactants. During the preparation of the composition, LAH undergoes an acid-base neutralization reaction with organic amines to transform into dodecylbenzenesulfonate. The product dodecylbenzenesulfonate belongs to alkylbenzene sulfonates in anionic surfactants.

[0206] Ethoxylated lauryl alcohol sulfate (degree of ethoxylation 2 to 3, carbon chain number of fatty alcohol 12 to 14), abbreviated as AES, belongs to ethoxylated fatty alcohol sulfates in anionic surfactants.

[0207] Sodium laurate, belonging to the category of anionic surfactants.

[0208] Sodium myristate, belonging to the category of anionic surfactants.

[0209] Sodium oleate, belonging to the category of anionic surfactants.

[0210] Fatty alcohol polyoxyethylene ether (9), where the carbon chain number of the fatty alcohol is 12 to 14, abbreviated as AEO9, belongs to fatty alcohol polyoxyethylene ethers in non-ionic surfactants.

[0211] 3-Propylheptanol ethoxylated propoxylated product, abbreviated as Lutensol XL, belongs to fatty alcohol polyoxyethylene ethers in non-ionic surfactants.

[0212] Monoethanolamine, belonging to the category of organic amines in acid-base regulators.

[0213] Sodium citrate, the said category being chelating agent.

[0214] Glycerol, belonging to the category of organic solvents.

[0215] Propylene glycol, belonging to the category of organic solvents.

[0216] Deionized water, belonging to the category of solvents.

[0217] It should be noted that the raw materials used in the above examples and comparative examples can all be purchased from the market.

[0218] I. Preparation of a washing product for removing aging odor

[0219] 1. The formulation compositions of Examples 1 - 5 are shown in Table 1, and the formulation settings of Examples 6 - 8 and Comparative Examples 1 - 16 are shown in Table 2.

[0220] Table 1

[0221]

[0222] In the mixture of sodium dodecyl sulfate, sodium myristate and sodium oleate in Table 1, the mass ratio of sodium dodecyl sulfate, sodium myristate and sodium oleate is 1:1:1.

[0223] Table 2

[0224]

[0225] 2. Preparation method

[0226] Step 1. Preparation of the washing solution: Add the organic solvent and the fatty acid sodium anionic surfactant into a pot, and at the same time install a stirring paddle. After stirring evenly, add dodecylbenzenesulfonic acid in 3 to 5 portions, and at the same time cool it to below 50°C in a cold deionized water water bath; then add AES, AEO9, Lutensol XL and the chelating agent pre-dissolved with deionized water in advance; add the acid-base regulator while stirring to adjust the pH value to 5.5 - 6.5. Then add the first combination and the second component, and finally make up to 100% with deionized water and continue to stir for 2 hours to obtain the washing solution.

[0227] Step 2. Preparation of the washing product: Heat the water-soluble film on a heating roller at a temperature of 40°C to 50°C, suck the above water-soluble film into a mold of appropriate shape by vacuum. When the film fits with the mold, fill 10 g of the washing solution prepared in Step 1 into the mold, coat a small amount of water on the surface of another layer of water-soluble film, then cover it with the previous mold, and apply pressure in the edge area of the mold to form a seal to obtain the washing product.

[0228] II. Performance Test

[0229] 1. Test the 2-nonenal removal rate of the first component and the second component used in the above-mentioned examples and comparative examples. The test method is as follows:

[0230] Dissolve the 2-nonenal standard product in a 50% ethanol aqueous solution (by volume) at a concentration of 200 ppm (mg / kg), and dissolve the aging odor remover in a 50% ethanol aqueous solution (by volume) at a concentration of 2%. Mix the 200 ppm 2-nonenal solution and the 2% aging odor remover solution in a mass ratio of 1:1 to prepare a sample solution. Mix the 200 ppm 2-nonenal solution and the 50% ethanol aqueous solution (by volume) in a mass ratio of 1:1 to prepare a reference solution. After shaking the obtained sample solution and reference solution, let them stand for 30 min, and then use liquid chromatography to measure the chromatographic peak area of 2-nonenal in the solution. The chromatographic conditions are as follows: the mobile phase is methanol: water = 70:30; the injection volume is 5 μL; the flow rate is 1.0 mL / min; the column temperature is 35 °C; the detector wavelength is 226 nm; the chromatographic column is Agilent SB-C18 (4.6×250 mm, 5 μm).

[0231] The 2-nonenal removal rate ΔA is calculated according to the following formula:

[0232]

[0233] S0 represents the chromatographic peak area of 2-nonenal in the reference solution, without unit; S m represents the chromatographic peak area of 2-nonenal in the sample solution, without unit. The test results are shown in Table 3. The chromatogram of the 2-nonenal removal rate of dodecyl dipropyltriamine is shown in the appendix Figure 1 as follows. The chromatogram of the 2-nonenal removal rate of sodium bisulfite is shown in the appendix Figure 2 as follows. The chromatogram of the 2-nonenal removal rate of 2-amino-4-methylpentanoic acid is shown in the appendix Figure 3 as follows.

[0234] Table 3

[0235] Component Removal rate of 2-nonenal % Hexyl dipropylenetriamine 100 Dodecyl dipropylenetriamine 100 Sodium sulfite 100 Sodium bisulfite 100 Sodium metabisulfite 100 4-Amino-1-butanol 46.32 2,2'-Dihydroxydiethylamine 41.55 2,6-Diaminohexanoic acid 100 2-Amino-4-methylpentanoic acid 19.28 Pentyl dipropylenetriamine 100 Tetradecyl dipropylenetriamine 100 Hexylamine 100 Sodium dithionite 100 Sodium thiosulfate 100

[0236] As can be seen from the results in Table 3, the 2-nonenal removal rates of hexyl dipropyltriamine, dodecyl dipropyltriamine, sodium sulfite, sodium bisulfite, and sodium metabisulfite used in the examples of the present application are all greater than 50%.

[0237] The removal rates of 2-nonenal by 4-amino-1-butanol, 2,2'-dihydroxydiethylamine, and 2-amino-4-methylvaleric acid used in each comparative ratio are all less than 50%. The removal rates of 2-nonenal by 2,6-diaminohexanoic acid, pentyl dipropyltriamine, tetradecyl dipropyltriamine, hexylamine, sodium dithionite, and sodium thiosulfate used in each comparative ratio are all 100%

[0238] 2. Evaluation of the effect of removing aged odor

[0239] The washing products prepared in the above-mentioned examples and comparative ratios were evaluated for their effect of removing aged odor. The evaluation method is as follows:

[0240] a. Mix 2-nonenal and JB-03 sebum sewage (China Light Daily Chemical Inspection and Certification Co., Ltd., meeting the requirements of GB / T 13174) evenly at a ratio of 1:1000. Drop the mixed solution onto a circular cloth sample with a diameter of 8 cm, and the mass ratio of the liquid to the cloth sample is 0.02:0.65 (g:g). The cloth sample is all-cotton pique cloth (gram weight is 170 g / m 2 ). Obtain the aged odor-contaminated cloth for the next step.

[0241] b. The washing performance test of the washing product on the aged odor-contaminated cloth was carried out with reference to "Determination of the detergency and cyclic washing performance of detergents for fabric use (GB / T 13174-2021)". Prepare washing water with a hardness of 250 ppm according to "Determination of the detergency and cyclic washing performance of detergents for fabric use (GB / T 13174-2021)", where the molar ratio of calcium and magnesium ions is 3:2. Prepare a 0.06% washing solution of the washing product with 250 ppm washing water, and complete 1 wash with the RHLQ vertical decontamination machine of the China National Research Institute of Daily Chemical Industry. The washing time is 20 min, the washing temperature is 30 °C, and the stirring speed is 120 revolutions per minute. Immediately take out all the cloth samples and the washing solution after the washing is over for the next step.

[0242] It should be noted that in the evaluation method of the effect of removing aged odor of the washing product, the washing product washes the cloth sample (aged odor-contaminated cloth) under conventional washing conditions. The so-called conventional washing conditions refer to that the concentration of the water-soluble film-encapsulated liquid detergent composition in the washing system is 0.06%, and the washing time is 20 minutes.

[0243] c. Evaluation of the effect of removing aged odor: An expert panel was used to evaluate the removal effect of 2-nonenal on the washed aged odor-contaminated cloth and the washing solution. The expert panel is composed of 7 people with sensitive olfaction who have received professional training. Score the effect of removing aged odor according to the criteria in Table 4, and take the average value of the scoring results to evaluate the level of the effect of removing aged odor according to the criteria in Table 5. The higher the score, the worse the removal effect. The evaluation results of the effect of removing aged odor of each example and comparative ratio are shown in Table 6.

[0244] Table 4

[0245] Evaluation of the effect of removing aged odor Score There is no change in the aged odor before and after washing, very strong 5 The aged odor is slightly weakened after washing, but can be clearly perceived 4 The aged odor is significantly weakened after washing, but can still be perceived 3 The aged odor cannot be clearly perceived after washing, but the fragrance of the detergent solution has changed significantly 2 The aged odor cannot be clearly perceived after washing, but the odor of the detergent solution has changed slightly 1 There is no aged odor after washing, and the odor of the detergent solution has no obvious change 0

[0246] Table 5

[0247] Score of the effect of removing aged odor after washing Evaluation grade ≤2 Good 2 to 3 General ≥3 Poor

[0248] Table 6

[0249] Group Score of the effect of removing aged odor Evaluation grade Example 1 0.4 Good Example 2 0.2 Good Example 3 0 Good Example 4 O Good Example 5 0.9 Good Example 6 0.5 Good Example 7 0.6 Good Example 8 0.5 Good Comparative example 1 5 Poor Comparative example 2 0.3 Good Comparative example 3 1.7 Good Comparative example 4 2.2 General Comparative example 5 1.8 Good Comparative example 6 0.3 Good Comparative example 7 0 Good Comparative example 8 3.0 Poor Comparative example 9 3.4 Poor Comparative example 10 0.9 Good Comparative example 11 4.3 Poor Comparative example 12 0.7 Good Comparative example 13 0.8 Good Comparative example 14 0.6 Good Comparative example 15 0 Good Comparative example 16 0 Good

[0250] As can be seen from the results in Table 6, the evaluation grades of the aged odor removal effect of the washing products in Examples 1-8 are all good, indicating that the washing products provided by this application all have excellent aged odor removal effects.

[0251] In Comparative Example 1, the first component and the second component were not added during the preparation of the washing product, and it did not have the ability to remove 2-nonenal, and the evaluation grade of the aged odor removal effect was poor.

[0252] In Comparative Example 4, the content of the first component was 2.5% during the preparation of the washing product. Due to the too low dosage of the first component, the evaluation grade of the aged odor removal effect was average.

[0253] In Comparative Example 8, Comparative Example 9, and Comparative Example 11, 4-amino-1-butanol, 2,2'-dihydroxydiethylamine, and 2-amino-4-methylpentanoic acid with a 2-nonenal removal rate of less than 50% were used as the first component respectively. Even when the addition amount reached 6%, the evaluation grade of their aged odor removal effect was still poor.

[0254] 2. Test on the color change value of the content for the content stability performance

[0255] It should be noted that the "content" mentioned in the context refers to the washing liquid encapsulated by the water-soluble film of the washing product. The aging treatment refers to storing the liquid detergent composition encapsulated by the water-soluble film in an environment of 45°C and 75±5% relative humidity for four weeks.

[0256] No distinction is made between the terms aging treatment, aging experiment, high-temperature accelerated aging treatment, and high-temperature acceleration. The aging treatment in other parts of the following text is the same as this step.

[0257] The degree of color change of the content is quantitatively characterized by the following method. Use a color difference meter to measure the D b value (yellow-blue value) of the washing product before and after the aging treatment, and calculate the color change value (Y) of the content (that is, the washing liquid encapsulated by the water-soluble film) according to the following formula. Evaluate the color change value grade of the content of the washing product after the aging treatment according to Table 7 below.

[0258] Y = D b 2 - Db 1

[0259] Among them, Y: the value of the color change of the content; D b 1: D value (yellow - blue value) of the liquid detergent composition encapsulated in the water - soluble film before the aging treatment b value; D b 2: D value (yellow - blue value) of the liquid detergent composition encapsulated in the water - soluble film after the aging treatment b value.

[0260] Table 7

[0261]

[0262] The test results of the color change value of the content after the aging treatment of Examples 1 - 8 and Comparative Examples 2 - 3, Comparative Examples 5 - 7, Comparative Example 110, and Comparative Examples 12 - 16 are shown in Table 8. The appearance pictures of Example 1 before and after the aging treatment are respectively shown in Attachment Figure 4 and Attachment Figure 5 as shown. The appearance pictures of Comparative Example 3 before and after the aging treatment are respectively shown in Attachment Figure 6 and Attachment Figure 7 as shown.

[0263] Table 8

[0264] Group Color change value of the content after aging treatment Color change value grade Example 1 4.2 Good Example 2 3.6 Good Example 3 1.4 Good Example 4 2.2 Good Example 5 3.2 Good Example 6 4.5 Good Example 7 2.7 Good Example 8 2.6 Good Comparative example 2 1.2 Good Comparative example 3 13.2 Poor Comparative example 5 8.5 General Comparative example 6 7.5 General Comparative example 7 0.8 Good Comparative example 10 5.5 Good Comparative example 12 7.9 General Comparative example 13 5.6 Good Comparative example 14 6.5 General Comparative example 15 3.9 Good Comparative example 16 3.6 Good

[0265] As can be seen from the results in Table 8, after the aging treatment of the washing products in Examples 1 - 8, the color change values are all less than 6, and the color change value level is good, indicating that the content color stability of the washing products provided by this application is excellent.

[0266] In Comparative Example 3, the second component was not added when preparing the washing product, and the color change value of the washing product after the aging treatment was greater than 10, and the evaluation level was poor.

[0267] In Comparative Example 5, the content of the second component was 0.4% when preparing the washing product, and in Comparative Example 6, the content of the first component was 6.5% when preparing the washing product. The color change values of the washing products in Comparative Examples 5 - 6 after the aging treatment were both greater than 6, and the evaluation level was average. The ratio ranges of the first component and the second component in Comparative Examples 5 and 6 do not meet the requirements of the technical solution of this application and cannot achieve good results. It can be seen that too high an addition amount of the first component or too low an addition amount of the second component in the washing product will have a negative impact on the content color stability of the washing product.

[0268] In Comparative Examples 12 and 14, pentyl dipropyltriamine and hexylamine were respectively used as the first component when preparing the washing product, and the color change values of the washing products after the aging treatment were also both greater than 6, and the evaluation level was average.

[0269] 3. Content Integrity Test for the Stability of the Contents

[0270] As shown in Table 9, the integrity of the contents of the washing products after aging treatment was evaluated by visual inspection.

[0271] The steps of the aging treatment are as described above.

[0272] Table 9

[0273]

[0274] The test results of the integrity of the contents after aging treatment for Examples 1-8, Comparative Example 2, Comparative Example 7, Comparative Example 10, Comparative Example 13, Comparative Example 15, and Comparative Example 16 are shown in Table 10. The appearance pictures of Comparative Example 10 before and after aging treatment are shown in Figure 8 and Figure 9 respectively.

[0275] Table 10

[0276]

[0277] As can be seen from the results in Table 10, the evaluation grades of the integrity of the contents of Examples 1-8 are all good, indicating that the washing products provided by this application have excellent integrity of the contents.

[0278] In Comparative Example 10, 2,6-diaminohexanoic acid was used as the first component. Due to solubility problems, fine precipitates appeared in the contents of the washing product after aging treatment, and the evaluation grade of the integrity of the contents was average.

[0279] 4. Odor Stability Test for the Stability of the Contents

[0280] The odor of the contents of the washing products before and after aging treatment was tested.

[0281] The steps of the high-temperature aging treatment are as described above.

[0282] The test steps are as follows: Cut open the outer membrane of the washing product, squeeze out the contents into a culture dish with a diameter of 9 cm, and use an expert panel to evaluate the difference in odor before and after aging treatment. The expert panel consists of 5 people and scores the odor stability according to Tables 11 and 12 below.

[0283] Table 11

[0284] Grade Fragrance Strength Newly added abnormal odor No obvious change Consistent with the sample before aging Consistent with the sample before aging None No change Basically consistent with the sample before aging Consistent with the sample before aging None Consistent with the sample before aging Basically consistent with the sample before aging None There is a change Different from the sample before aging Do not need to detect Do not need to detect

[0285] Table 12

[0286]

[0287] The test results of odor stability after the aging treatment of Examples 1-8, Comparative Example 2, Comparative Example 7, Comparative Example 13, Comparative Example 15, and Comparative Example 16 are shown in Table 13.

[0288] Table 13

[0289]

[0290] As can be seen from the results in Table 13, after 4 weeks of aging treatment, the odor of the washing product content in Examples 1-8 did not change significantly, and the evaluation grade of temperature stability was good; indicating that the washing product provided by the present application has excellent odor stability of the content.

[0291] In Comparative Example 15 and Comparative Example 16, sodium dithionite and sodium thiosulfate were used as the second component respectively, and the odor of the content before and after aging treatment changed significantly, indicating that the odor stability of the washing product content prepared with sodium dithionite and sodium thiosulfate as the second component could not meet the requirements.

[0292] 5. Membrane Integrity Test of Membrane Stability Performance

[0293] It should be noted that the liquid detergent composition encapsulated by the water-soluble film has good membrane stability performance, specifically referring to that after undergoing aging treatment, its membrane integrity, degree of change in membrane appearance, and tactile performance evaluation grade are all good. The relevant test and evaluation methods are as follows.

[0294] The steps of the aging treatment are as described above.

[0295] Evaluate the membrane integrity after the aging treatment according to Table 14.

[0296] Table 14

[0297]

[0298] The evaluation results of membrane integrity after the aging treatment of Examples 1-8, Comparative Example 2, Comparative Example 7, and Comparative Example 13 are shown in Table 15. The appearance pictures of Comparative Example 7 before and after aging treatment are respectively as shown in Figure 10 and 11 shown.

[0299] Table 15

[0300]

[0301] As can be seen from the results in Table 15, after 4 weeks of aging treatment, the evaluation grades of membrane integrity in Examples 1-8 were all good; indicating that the washing product provided by the present application has excellent membrane integrity.

[0302] In Comparative Example 7, the content of the second component in the preparation of the washing product was 1.5%. The water-soluble film of the washing product wrinkled after the aging treatment, and the evaluation grade of the film integrity was average; indicating that too high content of the second component in the washing product would affect the film integrity.

[0303] 6. Test on the degree of change in film appearance of film stability performance

[0304] Evaluate the degree of change in film appearance after the aging treatment as shown in Table 16. The steps of the aging treatment are as described above.

[0305] Table 16

[0306]

[0307] The test results of the degree of change in film appearance after the aging treatment of Examples 1-8, Comparative Example 2 and Comparative Example 13 are shown in Table 17.

[0308] Table 17

[0309]

[0310] As can be seen from the results in Table 17, after 4 weeks of aging treatment in Examples 1-8, the evaluation grades of the degree of change in film appearance of the washing products are all good; indicating that the washing products provided by the present application have excellent film appearance stability.

[0311] 7. Test on the tactile performance of the film of film stability performance

[0312] According to Table 18, touch the outer film surface of the washing product after the aging treatment by hand to evaluate the tactile performance. 5 testers were used for each sample, and each person detected 2 times in parallel. The evaluation results were distinguished as "non-sticky" and "sticky". The steps of the aging treatment are as described above.

[0313] Table 18

[0314]

[0315] The test results of the tactile performance of the film after the aging treatment of Examples 1-15, Comparative Example 2 and Comparative Example 13 are shown in Table 19.

[0316] Table 19

[0317] Group Number of "sticky" sample parallels / total number of sample parallels Tactile performance grade Example 1 0 / 10 Good Example 2 0 / 10 Good Example 3 0 / 10 Good Example 4 1 / 10 Good Example 5 0 / 10 Good Example 6 0 / 10 Good Example 7 0 / 10 Good Example 8 0 / 10 Good Comparative example 2 0 / 10 Good Comparative example 13 4 / 10 General

[0318] As can be seen from the results in Table 19, the outer film surface of the washing products in Examples 1-8 is non-sticky after the aging treatment, and the evaluation grade of the tactile performance is good; indicating that the film tactile performance of the washing products provided by the present application is excellent.

[0319] In Comparative Example 13, tetradecyl dipropylenetriamine was used as the first component. After the aging treatment of the washing product, the outer film surface was sticky, and the tactile performance grade was evaluated as average.

[0320] 8. Dissolution Stability Test

[0321] The dissolution stability performance of the washing product refers to the good retention of the dissolution performance grade of the washing product after aging treatment. The test steps are as follows: Place 1 washing product into a beaker, stir and dissolve it in the beaker for 10 minutes, and then stop stirring. Immediately filter all the solutions and residues in the beaker through a 60-mesh sieve, and evaluate the dissolution performance according to the residue on the sieve within 5 minutes. Each sample is tested in parallel 5 times, and the dissolution stability performance is rated according to Tables 20 and 21. The steps of the aging treatment are as described above.

[0322] Table 20

[0323]

[0324] Table 21

[0325]

[0326] The dissolution stability test results of Examples 1-8 and Comparative Example 2 after aging treatment are shown in Table 22.

[0327] Table 22

[0328] Group Number of completely dissolved sample parallels / total number of sample parallels Dissolution stability performance grade Example 1 5 / 5 Good Example 2 5 / 5 Good Example 3 5 / 5 Good Example 4 5 / 5 Good Example 5 5 / 5 Good Example 6 5 / 5 Good Example 7 5 / 5 Good Example 8 5 / 5 Good Comparative example 2 5 / 5 Good

[0329] As can be seen from the results in Table 22, after 4 weeks of aging treatment, the dissolution stability performance evaluation grades of Examples 1-8 are good; indicating that the washing products provided by the present application have excellent dissolution stability.

[0330] 9. Evaluation of the Effect of Removing Aging Odor after Aging Treatment

[0331] The effect of removing aging odor of the washing product after aging treatment was evaluated according to the aging odor evaluation method described in "2. Evaluation of the Effect of Removing Aging Odor". The evaluation results of the effect of removing aging odor of Examples 1-8 and Comparative Example 2 after aging treatment are shown in Table 23. The steps of the aging treatment are as described above.

[0332] Table 23

[0333] Group Score of the effect of removing aged odor after aging treatment Evaluation grade Example 1 0.5 Good Example 2 0.7 Good Example 3 1.4 Good Example 4 0.6 Good Example 5 1.1 Good Example 6 0.9 Good Example 7 0.8 Good Example 8 0.7 Good Comparative example 2 2.4 General

[0334] As can be seen from the results in Table 23, after 4 weeks of aging treatment, the evaluation grade of the odor removal effect of Examples 1-8 remains unchanged and is still good; indicating that the washing products provided by the present application still have excellent aging odor removal effect after aging treatment.

[0335] In Comparative Example 2, the first component was not added when preparing the washing product, and only the second component, the sulfur-containing compound, was added. Possibly because the sulfur-containing compound has a certain reducibility and undergoes partial decomposition after the aging treatment, resulting in a decrease in the overall effect of removing aged odor.

[0336] 10. Skin irritation test

[0337] In this application, zein experiments were used to evaluate the skin irritation of the washing product. Zein has a similar protein structure to that in human skin and hair. After interacting with the washing product, its spatial conformation changes, thereby changing the water solubility of zein, and its water solubility will increase. The content of zein dissolved in the aqueous solution is proportional to the skin irritation it causes.

[0338] The test steps are as follows: (1) Prepare an aqueous solution of the 5% sample to be tested. (2) Add zein to the test solution under stirring at room temperature, and stir with a magnetic stirrer for about 4 h. (3) Centrifuge the above solution at 4000 rpm for 15 min and take the supernatant. (4) Use a kit (Pierce TM BCA Protein Assay Kit) from Thermo Fisher Scientific, USA to test the protein concentration C of the sample. According to the nitrogen content in the protein being 16%, calculate the ZEIN value (mgN / 100 mL).

[0339] ZEIN = C × 16

[0340] The higher the protein concentration C, the higher the ZEIN value, indicating that the sample has stronger irritation. The irritation of the detergent samples was evaluated according to Table 24 below.

[0341] Table 24

[0342] ZEIN value Skin irritation grade <200 Mild and non-irritating 200～400 Moderate irritation ＞400 Strong irritation

[0343] The skin irritation test results of Examples 1-15 and Comparative Example 1 are shown in Table 25.

[0344] Table 25

[0345] Group ZEIN value Evaluation grade of skin irritation Example 1 124.34 Mild and non-irritating Example 2 127.38 Mild and non-irritating Example 3 138.67 Mild and non-irritating Example 4 165.87 Mild and non-irritating Example 5 109.58 Mild and non-irritating Example 6 145.87 Mild and non-irritating Example 7 171.39 Mild and non-irritating Example 8 173.54 Mild and non-irritating Comparative Example 1 148.68 Mild and non-irritating

[0346] From the results in Table 25, it can be seen that the skin irritation levels of Examples 1-8 are "mild and non-irritating", indicating that the washing product provided in this application is non-irritating to the skin.

[0347] In Comparative Example 1, neither the first component nor the second component was added when preparing the washing product, and the skin irritation level of Comparative Example 1 was also "mild and non-irritating". This further shows that the first component and the second component added to the washing product in this application do not increase the skin irritation of the washing product and can give consumers a mild and comfortable use experience.

[0348] From the evaluation grades of the aged odor removal effect, the stability of the content, the stability of the film, the dissolution stability, and the irritation evaluation results before and after the aging treatment in the above Examples 1-8, it can be seen that the washing product of the present application not only has a good effect of removing the aged odor of the clothes of the elderly, but also has good stability. That is, after the washing product undergoes the aging treatment, the color change value of the content, the film integrity, the degree of film appearance change, the content integrity, the odor stability, and the dissolution stability are all good. Moreover, the evaluation grade of the aged odor removal effect after the aging treatment remains unchanged, no new odor is generated, and at the same time, it is mild and non-irritating to the skin.

[0349] The technical features of the above-described embodiments can be combined arbitrarily. For the sake of brevity of description, not all possible combinations of the technical features in the above embodiments are described. However, as long as there is no contradiction in the combination of these technical features, it should be considered as the scope recorded in this specification.

[0350] The above-described embodiments only represent several implementation manners of the present invention, and their descriptions are relatively specific and detailed, but they should not be construed as limiting the scope of the invention patent. It should be noted that for those of ordinary skill in the art, without departing from the concept of the present invention, several modifications and improvements can be made, and these all belong to the protection scope of the present invention. Therefore, the protection scope of the present invention patent shall be subject to the appended claims.

Claims

1. A composition for removing aging odor, characterized in that: The invention comprises a first component and a second component, wherein the mass ratio of the first component to the second component is 3:1 to 12:1; and the first component has a structure shown in the following general formula (I): Wherein, R1 is selected from one of C6-C12 alkyl groups; The second component includes one or more of sulfites, pyrosulfites and bisulfites.

2. The composition according to claim 1, characterized in that The first component is selected from one or more of n-hexyldipropylenetriamine, n-heptyldipropylenetriamine, isoheptyldipropylenetriamine, neoheptyldipropylenetriamine, n-octyldipropylenetriamine, isooctyldipropylenetriamine, sec-octyldipropylenetriamine, tert-octyldipropylenetriamine, n-nonyldipropylenetriamine, n-decyldipropylenetriamine, n-undecyldipropylenetriamine and n-dodecyldipropylenetriamine; and / or The second component includes one or more of sodium sulfite, sodium bisulfite and sodium metabisulfite.

3. Use of the composition for removing age odor as claimed in claim 1 or 2 in the preparation of a detergent product for removing age odor.

4. A cleaning product for removing age odor, characterized in that: The washing product comprises a water-soluble film and a washing liquid encapsulated in the water-soluble film, wherein the washing liquid comprises a first component and a second component, wherein the mass ratio of the first component to the second component is 3:1 to 12:1; and the first component has a structure represented by the following general formula (I): Wherein, R1 is selected from one of C6-C12 alkyl groups; The second component includes one or more of sulfites, pyrosulfites, and bisulfites; The mass proportion of the first component in the washing liquid is 3%-6%, and the mass proportion of the second component in the washing liquid is 0.5%-1%.

5. The cleaning product according to claim 4, characterized in that The first component compound is selected from one or more of n-hexyldipropylenetriamine, n-heptyldipropylenetriamine, isoheptyldipropylenetriamine, neoheptyldipropylenetriamine, n-octyldipropylenetriamine, isooctyldipropylenetriamine, sec-octyldipropylenetriamine, tert-octyldipropylenetriamine, n-nonyldipropylenetriamine, n-decyldipropylenetriamine, n-undecyldipropylenetriamine and n-dodecyldipropylenetriamine; and / or The second component includes one or more of sodium sulfite, sodium bisulfite and sodium metabisulfite.

6. The cleaning product according to any one of claims 4 to 5, characterized in that The washing liquid also includes anionic surfactants, nonionic surfactants, adjuvants, solvents, and optionally zwitterionic surfactants and optionally cationic surfactants.

7. The cleaning product according to claim 6, characterized in that The mass proportion of the anionic surfactant in the washing liquid is 20%-50%; and / or The anionic surfactant includes one or more of C6-C24 alkylbenzene sulfonates, C8-C18 alkyl sulfates, C8-C18 ethoxylated fatty alcohol sulfates, α-olefin sulfonates, C8-C18 fatty acid salts, ethoxylated fatty alcohol ether carboxylates, sulfosuccinates and alkyl disulfonates and their derivatives; Optionally, the anionic surfactant includes one or more of dodecylbenzene sulfonate, sodium laureth sulfate, dodecyl sulfate, oleate, laurate, alkyl diphenyl oxide disulfonate and disodium fatty alcohol polyoxyethylene ether sulfosuccinate monoester.

8. The cleaning product according to claim 6, characterized in that The mass percentage of the nonionic surfactant in the washing liquid is 20%-25%; and / or The nonionic surfactant includes one or more of C6-C24 fatty alcohol alkoxylates, C6-C24 alkyl polysaccharides, C8-C18 fatty acid ester alkoxylates, C6-C24 fatty acid alkyl alcohol amides, C6-C24 fatty acid methyl ester ethoxylates and polyether surfactants.

9. The cleaning product according to claim 6, characterized in that The mass percentage of the zwitterionic surfactant in the washing liquid is 0%-15%, and can be 0.01%-15%; and / or The zwitterionic surfactant includes one or more of a betaine-type surfactant, an imidazoline-type surfactant, an amino acid-type surfactant, and an amine oxide-type surfactant; Optionally, the betaine-type surfactant includes one or more of alkyl betaine, fatty amide betaine, fatty amide propyl betaine and fatty amide propyl hydroxypropyl sulfonated betaine; Optionally, the imidazoline type surfactant includes one or more of sodium alkyl acetate type imidazoline, fatty acid type imidazoline and sulfonic acid type imidazoline; Optionally, the amino acid surfactant includes one or more of aminopropionic acid derivatives and glycine derivatives; Optionally, the amine oxide surfactant includes one or more of alkyl dimethyl amine oxide and fatty amide propyl dimethyl amine oxide.

10. The cleaning product according to claim 6, characterized in that The mass percentage of the cationic surfactant in the washing liquid is 0%-15%, and can be 0.01%-15%; and / or The cationic surfactant includes one or more of quaternary ammonium salt surfactants, heterocyclic surfactants and polymeric cationic surfactants; Optionally, the cationic surfactant includes one or more of a monolong linear quaternary ammonium salt, a dilong linear quaternary ammonium salt, a benzyl quaternary ammonium salt, a hydroxyalkyl quaternary ammonium salt, a fatty amide propyl hydroxyalkyl quaternary ammonium salt, and a polyquaternary ammonium salt obtained by copolymerizing vinyl pyrrolidone with an unsaturated amide or an unsaturated quaternary ammonium salt.

11. The cleaning product according to claim 6, characterized in that The mass proportion of the auxiliary agent in the washing liquid is 0.1%-20%; and / or The auxiliary agent includes a mixture of one or more of an acid-base regulator, an enzyme preparation, a preservative, a polymer, an inorganic salt, a viscosity regulator, an antibacterial agent, a colorant, a flavor and a water softener; Optionally, the acid-base regulator includes one or more of citric acid, succinic acid, boric acid, monoethanolamine, diethanolamine, triethanolamine, N-alkyldiethanolamine, tetraalkylammonium hydroxide and ethylenediamine and their co-products; further optionally, the tetraalkylammonium hydroxide includes one or more of tetramethylammonium hydroxide, tetraethylammonium hydroxide and tetrabutylammonium hydroxide; further optionally, the ethylenediamine co-product includes one or more of diethylenetriamine, triethylenetetramine and tetraethylenepentamine; Optionally, the enzyme preparation comprises one or more of protease, amylase, lipase, cellulase, mannanase and pectinase; Optionally, the antibacterial agent includes one or more of hypochlorous acid and its salts, p-chlororesorcinol, p-chlororesorcinol, hydroxydichlorodiphenyl ether, hydroxytrichlorodiphenyl ether, triclocarban, o-phenylphenol, dodecyldimethylbenzylammonium chloride, dodecyltrimethylammonium chloride, tetradecyldimethylbenzylammonium chloride, tetradecyltrimethylammonium chloride, hexadecyltrimethylammonium chloride, octadecyltrimethylammonium chloride, didecyldimethylammonium chloride, polyhexamethylene biguanide hydrochloride, 1-hexadecylpyridinium chloride, pyrithione zinc and pyridone ethanolamine salt; Optionally, the polymer includes one or more of a salt of a homopolymer of acrylic acid, a salt of a copolymer of acrylic acid, a cellulose derivative, a homopolymer of vinyl pyrrolidone, a copolymer of vinyl pyrrolidone, and a polyethylene imine derivative.

12. The cleaning product according to claim 6, characterized in that The mass proportion of the solvent in the washing liquid is 20%-40%; and / or The solvent comprises a mixture of water and an organic substance, wherein the organic substance comprises one or more of polyols and polyol ethers; optionally, the organic substance comprises one or more of propylene glycol, glycerol, ethylene glycol, sorbitol and polyethylene glycol.

13. The cleaning product according to any one of claims 4 to 5 and 7 to 12, characterized in that The material of the water-soluble film includes one or more of polyvinyl alcohol homopolymer and polyvinyl alcohol copolymer; Optionally, the polyvinyl alcohol homopolymer is a hydrolysis product of a homopolymer of vinyl acetate, and the degree of hydrolysis is 86%-99%; Optionally, the polyvinyl alcohol copolymer is a hydrolysis product of a copolymer of vinyl acetate and a second monomer, and the degree of hydrolysis is 86%-99%; Further optionally, the second monomer includes one or more of acrylic acid, acrylic acid esters, methacrylic acid and methacrylic acid esters.

Images