Color fixing and hair care composition with hair nourishing and hair care functions and preparation method of color fixing and hair care composition
By combining specific peptides and polysaccharides with plant extracts such as brown algae extract, mulberry extract and Polygonum multiflorum extract, a color-fixing hair care composition with good color-fixing and hair-fabricating effects was prepared, which solved the problems of unstable properties and serious side effects of existing color-fixing and hair-fabricating products, and achieved better hair color-fixing and hair-fabricating effects.
Patent Information
- Application Number
- CN202510383232.8
- Authority / Receiving Office
- CN · China
- Patent Type
- Applications(China)
- Current Assignee / Owner
- Filing Date
- 2025-03-28
- Publication Date
- 2025-06-24
AI Technical Summary
The existing color-fixing hair care products have problems such as unstable properties, poor color-fixing effect, irritation of the scalp, serious side effects, and short storage time, which is difficult to effectively solve the problems of difficult and unstable hair fixing after perming and dyeing.
A hair-fixing composition with brown algae extract, mulberry fruit extract and Polygonum multiflorum leaching extract combined with palmitoyl tripept-1, acetyl tetrapeptide-3, trehalose and fucoidan is prepared by enzymatic decomposition and multi-stage heating and extraction steps to improve the content and purity of the ingredients to prepare products with good color-fixing and hair-fabricating effects.
It achieves good hair color fixation effect, improves hair quality, and has no adverse reactions. It has a long shelf life and stable use effect, which is better than commercially available color fixation products.
Smart Images
Figure BDA0005335174360000071
Abstract
Description
Technical Field
[0001] The present invention relates to the field of hair care daily chemical products, and particularly to a color-fixing hair care composition with hair nourishing and hair care effects and a preparation method thereof. Background Art
[0002] After hair is permed, dyed, bleached and dyed, the damaged hair has problems such as the keratin structure being damaged, the strength or toughness decreasing, resulting in difficult color fixation. Unstable color fixation will affect the beauty of hair quality. Therefore, the color-fixing hair care composition after hair perming and dyeing is popular among consumers. The commercially available color-fixing hair care compositions have the following problems. First, the product properties are unstable and the color-fixing effect is poor. The commercially available hair color-fixing products are uneven, expensive and have poor effects. Second, although the addition of a large amount of chemical reagents increases the color-fixing effect, it stimulates the scalp, resulting in side effects such as allergies and hair loss. The long-term use of surfactants extracted from petrochemical materials is irritating to the skin and mucous membranes, and has the disadvantages of short storage time and easy deterioration, affecting its safety and active ingredients. Third, short-chain polypeptide small molecules are widely used in moisturizing and emollient products. This research finds that their combination with brown algae extracts, mulberry fruit extracts, polygonum multiflorum extracts, etc. has color-fixing and hair nourishing and hair care effects. Therefore, in order to solve the above problems, the present application provides a color-fixing hair care composition with hair nourishing and hair care effects and a preparation method thereof. Summary of the Invention
[0003] In view of this, the present invention develops a color-fixing hair care composition with hair nourishing and hair care effects and a preparation method thereof.
[0004] The technical solution of the present invention is realized as follows:
[0005] A color-fixing hair care composition with hair nourishing and hair care effects, comprising the following raw materials in parts by weight: 20-40 parts of brown algae extract, 15-20 parts of mulberry fruit extract, 10-15 parts of polygonum multiflorum extract, 5-10 parts of palmitoyl tripeptide-1, 5-10 parts of acetyl tetrapeptide-3, 3-6 parts of trehalose, and 2-4 parts of fucoidan.
[0006] Further, the types of brown algae in the brown algae extract include sargassum and giant kelp.
[0007] The preparation method of the brown algae extract includes the following steps:
[0008] S1. Remove impurities from fresh brown algae, dry and crush them to obtain brown algae powder;
[0009] S2. Enzymatically hydrolyze the brown algae powder to obtain enzymatically hydrolyzed brown algae;
[0010] S3. Add the enzymatically hydrolyzed brown algae to an ethanol aqueous solution and carry out extraction by heating in 3 stages to obtain an extract;
[0011] S4. Stir the leaching solution, homogenize it, rapidly cool it, and perform solid-liquid separation to obtain the supernatant.
[0012] S5. Concentrate the supernatant under reduced pressure, purify it, and dry it to obtain the finished product.
[0013] Further, in step S1, the drying temperature is 50 - 60°C, and the moisture content of the brown algae after drying is < 10%; for the pulverization, the pulverization particle size is < 0.8 mm.
[0014] Further, in step S2, for the enzymatic hydrolysis, add Bacillus subtilis, β-mannanase, and cellulase with a mass ratio of 1 - 3:2 - 4:1; the enzymatic hydrolysis temperature is 35 - 40°C, the time is 12 - 18 h, and the pH value is 4.5 - 7.5.
[0015] Further, in step S3, for the three-stage temperature-rising leaching, in the first stage, the leaching temperature is 100 - 150°C, the leaching time is 15 - 20 min to obtain the polysaccharide leaching solution; in the second stage, the leaching temperature is raised to 190 - 210°C, the leaching time is 25 - 30 min to obtain the polyphenol and small molecule peptide leaching solution; in the third stage, cool down to < 60°C to end the leaching; the volume-mass concentration of the ethanol aqueous solution is 10 - 25%.
[0016] Further, in step S4, the stirring speed is 150 - 200 rpm, for the solid-liquid separation, the centrifugation speed is 6000 - 8000 rpm, the centrifugation time is 10 - 20 min, and the residue is dried and used as fertilizer.
[0017] Further, in step S5, for the concentration, in the first stage, the polysaccharide leaching solution is separated and concentrated by an ultrafiltration membrane with a molecular weight cut-off of 30 - 100 kDa; in the second stage, the polyphenol and small molecule peptide leaching solution is adsorbed by macroporous resin, and the macroporous resin is AB-8 resin or XAD-16 resin.
[0018] A color-fixing hair care composition with hair nourishing and hair care effects, characterized by comprising the following production steps:
[0019] S1. Mix the brown algae extract, mulberry fruit extract, and fleece-flower root extract, stir evenly to obtain mixture I; mix palmitoyl tripeptide-1, acetyl tetrapeptide-3, trehalose, and fucoidan, stir evenly to obtain mixture II.
[0020] S2. Dissolve mixture II in mixture I, heat at 65 - 85°C, cool, and seal in vacuum and light-proof manner to obtain the color-fixing hair care composition.
[0021] Compared with the prior art, the beneficial effects of the present invention are:
[0022] The present invention combines the extracts of brown algae, mulberries, and fleeceflower roots, which has a basic hair color fixation effect. After being combined with palmitoyl tripeptide-1, acetyl tetrapeptide-3, trehalose, and fucoidan, the effect of color fixation and hair care is enhanced. The preparation of the brown algae extract in the present invention includes enzymatically hydrolyzing brown algae powder, heating and extracting, separating, and concentrating in three stages, which improves the content and purity of polyphenols and small molecular peptides in the components and enhances the hair color fixation effect. The color fixation hair care composition prepared by the formula and method of the present invention has a good color fixation effect after hair dyeing, can improve hair quality, has a hair nourishing and care effect, has no adverse reactions, and has application value. Detailed implementation manners
[0023] To better understand the technical content of the present invention, specific examples are provided below to further illustrate the present invention. Unless otherwise specified, the experimental methods used in the examples of the present invention are all conventional methods.
[0024] Unless otherwise specified, the materials, reagents, etc. used in the examples of the present invention can all be obtained from commercial channels. Bacillus subtilis was purchased from Shandong Xinzhuoyuan Biotechnology Co., Ltd., with an effective substance content of 99.9%, a product number of 20230115, and a product content of 100 - 1000 billion / G; β-mannanase was purchased from Huanxu Biotechnology Co., Ltd., with an effective ingredient content of 99% and an enzyme activity (u / g) ≥ 4000; cellulase was purchased from Shandong Gushuo Biotechnology Co., Ltd., food grade, with an effective ingredient of 99% and an enzyme activity (u / g) ≥ 3800.
[0025] Preparation Example 1
[0026] The preparation method of the brown algae extract includes the following steps:
[0027] Step (1): Wash fresh Sargassum and Macrocystis to remove sediment and salt, remove impurities and then dry them. The drying temperature is 50°C, and the water content of the brown algae after drying is 6%. After drying, crush them, and the crushing particle size is < 0.8 mm to obtain brown algae powder;
[0028] Step (2): Add Bacillus subtilis, β-mannanase, and cellulase with a mass ratio of 1:2:1 to the brown algae powder for enzymatic hydrolysis. The enzymatic hydrolysis temperature is 35°C, the time is 12 h, and the pH value is 5.0 to obtain enzymatically hydrolyzed brown algae;
[0029] Step (3): Add the enzymatically hydrolyzed brown algae to an ethanol aqueous solution with a volume mass concentration of 10%, and heat and extract in three stages. In the first stage, the extraction temperature is 100°C, the extraction time is 15 min, to obtain a polysaccharide extract; in the second stage, the extraction temperature is raised to 190°C, the extraction time is 25 min, to obtain a polyphenol and small molecular peptide extract; in the third stage, cool down to 40°C to end the extraction and obtain an extract;
[0030] Step (IV): Stir the leaching solution respectively at a stirring speed of 150 rpm, homogenize, rapidly cool, perform solid-liquid separation at a centrifugation speed of 6000 rpm for 10 min, dry the residue for use as fertilizer, and collect the supernatant;
[0031] Step (V): Concentrate the supernatant under reduced pressure. In the first stage, the polysaccharide leaching solution is separated and concentrated by a 30 kDa ultrafiltration membrane. In the second stage, the polyphenol and small molecule peptide leaching solution is adsorbed by macroporous resin, where the macroporous resin is AB-8 resin.
[0032] Preparation Example 2
[0033] The preparation method of the brown algae extract includes the following steps:
[0034] Step (I): Wash fresh Sargassum and Macrocystis to remove sediment and salt, remove impurities and then dry at a drying temperature of 60 °C. After drying, the water content of the brown algae is 5%, and after drying, it is pulverized with a pulverization particle size of < 0.8 mm to obtain brown algae powder;
[0035] Step (II): Add Bacillus subtilis, β-mannanase and cellulase with a mass ratio of 3:4:1 to the brown algae powder for enzymatic hydrolysis at an enzymatic hydrolysis temperature of 40 °C for 18 h and a pH value of 5.5 to obtain enzymatically hydrolyzed brown algae;
[0036] Step (III): Add the enzymatically hydrolyzed brown algae to an ethanol aqueous solution with a volume-mass concentration of 10-25%. In the first stage, the extraction temperature is 150 °C and the extraction time is 20 min to obtain a polysaccharide leaching solution; in the second stage, the extraction temperature is raised to 210 °C and the extraction time is 30 min to obtain a polyphenol and small molecule peptide leaching solution; in the third stage, cool down to 55 °C to end the extraction and obtain the leaching solution;
[0037] Step (IV): Stir the leaching solution respectively at a stirring speed of 200 rpm, homogenize, rapidly cool, perform solid-liquid separation at a centrifugation speed of 8000 rpm for 20 min, dry the residue for use as fertilizer, and collect the supernatant;
[0038] Step (V): Concentrate the supernatant under reduced pressure. In the first stage, the polysaccharide leaching solution is separated and concentrated by a 100 kDa ultrafiltration membrane. In the second stage, the polyphenol and small molecule peptide leaching solution is adsorbed by macroporous resin, where the macroporous resin is XAD-16 resin.
[0039] Preparation Example 3
[0040] The preparation method of the brown algae extract includes the following steps:
[0041] Step (I): Wash fresh Sargassum and Macrocystis to remove sediment and salt, remove impurities and then dry at a drying temperature of 55 °C. After drying, the water content of the brown algae is 6%, and after drying, it is pulverized with a pulverization particle size < 0.8 mm to obtain brown algae powder;
[0042] Step (ii): Add Bacillus subtilis, β-mannanase, and cellulase with a mass ratio of 2:3:1 to the brown algae powder for enzymatic hydrolysis. The enzymatic hydrolysis temperature is 38°C, the time is 16 h, and the pH value is 5.0 to obtain enzymatically hydrolyzed brown algae.
[0043] Step (iii): Add the enzymatically hydrolyzed brown algae to an ethanol aqueous solution with a volume-mass concentration of 20%. In the first stage, the extraction temperature is 120°C and the extraction time is 20 min to obtain a polysaccharide extract. In the second stage, the extraction temperature is increased to 200°C and the extraction time is 30 min to obtain a polyphenol and small molecule peptide extract. In the third stage, the temperature is lowered to 40°C to end the extraction and obtain an extract.
[0044] Step (iv): Stir the extract respectively at a stirring speed of 180 rpm, homogenize, rapidly cool, perform solid-liquid separation at a centrifugation speed of 7000 rpm for 15 min, dry the residue for use as fertilizer, and collect the supernatant.
[0045] Step (v): Concentrate the supernatant under reduced pressure. In the first stage, the polysaccharide extract is separated and concentrated using an 80 kDa ultrafiltration membrane. In the second stage, the polyphenol and small molecule peptide extract is adsorbed using macroporous resin, where the macroporous resin is AB-8 resin.
[0046] Example 1
[0047] A color-fixing hair care composition with hair nourishing and protecting effects includes the following preparation steps: Mix the brown algae extract, mulberry fruit extract, and polygonum multiflorum extract prepared in Preparation Example 1, stir evenly to obtain Mixture 1; Mix palmitoyl tripeptide-1, acetyl tetrapeptide-3, trehalose, and fucoidan, stir evenly to obtain Mixture II; Dissolve Mixture II in Mixture 1, heat at 65°C, cool, and seal in vacuum and away from light to obtain the color-fixing hair care composition.
[0048] Example 2
[0049] A color-fixing hair care composition with hair nourishing and protecting effects includes the following preparation steps: Mix the brown algae extract, mulberry fruit extract, and polygonum multiflorum extract prepared in Preparation Example 2, stir evenly to obtain Mixture 1; Mix palmitoyl tripeptide-1, acetyl tetrapeptide-3, trehalose, and fucoidan, stir evenly to obtain Mixture II; Dissolve Mixture II in Mixture 1, heat at 85°C, cool, and seal in vacuum and away from light to obtain the color-fixing hair care composition.
[0050] Example 3
[0051] A color-fixing hair care composition with hair nourishing and hair care effects comprises the following preparation steps: Mix the brown algae extract, mulberry fruit extract, and polygonum multiflorum extract prepared in Preparation Example 3, and stir evenly to obtain Mixture 1; Mix palmitoyl tripeptide-1, acetyl tetrapeptide-3, trehalose, and fucoidan, and stir evenly to obtain Mixture II; Dissolve Mixture II in Mixture 1, heat at 80°C, cool, and seal in a vacuum in the dark to obtain the color-fixing hair care composition.
[0052] Comparative Example 1
[0053] The main difference between Comparative Example 1 and Example 3 is that the brown algae extract is not added in the preparation steps, and other raw materials and preparation methods remain unchanged.
[0054] Comparative Example 2
[0055] The main difference between Comparative Example 2 and Example 3 is that palmitoyl tripeptide-1 and acetyl tetrapeptide-3 are not added in the preparation steps, and other raw materials and preparation methods remain unchanged.
[0056] Comparative Example 3
[0057] The main difference between Comparative Example 3 and Example 3 is that the enzymatic hydrolysis and the three-stage temperature-raising extraction steps are removed in the preparation steps of the brown algae extract, and other raw materials and preparation methods remain unchanged.
[0058] Control
[0059] The control uses a commercially available external color-fixing hair care capsule, purchased from Henan Baihuikang Biotechnology Co., Ltd., with a product barcode of 9874847551315. The test usage amount is the same as that in Examples 1-3.
[0060] Test:
[0061] Sample preparation: Subjects are people aged 30-35 with hair length greater than 20 cm. Random grouping design: Experimental group: After unified hair dyeing, use the compositions in Examples 1-3 for hair care for 7 days. Comparative group: After unified hair dyeing, use the compositions in Comparative Examples 1-3 for hair care for 7 days. Control group: After unified hair dyeing, use the commercially available control composition for hair care for 7 days.
[0062] Unified hair dyeing: Use the same hair dye, concentration, time, and temperature to dye all hair strands of the subjects black, ensuring that the initial color after hair dyeing is black. Color-fixing treatment: Use the color-fixing products of Examples 1-3, Comparative Examples 1-3, and the control of the present invention according to the grouping. The color-fixing residence time of all products is the same, 45 minutes, and the temperature is 25°C. Within 7 days, use a unified commercially available regular shampoo to wash hair at a fixed water temperature (37±2°C), wash hair once every 2 days, and wash hair 3 times in total.
[0063] Detection indicators: The Lab* value was measured using a spectrophotometer colorimeter, and ΔE (the color difference between the color after 7 days of the test and the just-dyed color) was calculated. The larger ΔE is, the more serious the fading is. The color of the hair was measured using a color difference meter, and the brightness of the hair was detected using an intelligent scalp detector. L represents the brightness, ranging from 0 to 100. 0 indicates the darkest color, and 100 indicates the highest brightness. The specific statistical results are shown in Table 1.
[0064] Table 1 Hair Index Parameter Table
[0065]
[0066] Summary of test results: The combined use of brown algae extract, mulberry fruit extract and polygonum multiflorum extract in the present invention has a basic hair color fixation effect. After being combined with palmitoyl tripeptide-1, acetyl tetrapeptide-3, trehalose and fucoidan, the effect of color fixation and hair care is improved. The tests of Examples 1-3 prove that the color fixation composition of the present invention is more conducive to improving the hair brightness and maintaining the hair color after dyeing. Changing the main components of the raw materials in Comparative Example 1 and changing the preparation method of the main components in Comparative Example 3 both reduce the color fixation effect of the present invention, resulting in hair fading and dullness. After removing palmitoyl tripeptide-1 and acetyl tetrapeptide-3 from the raw materials in Comparative Example 2, the color fixation effect is reduced. The color fixation hair care composition prepared by using the formula and method of the present invention has a good color fixation effect after hair dyeing, can improve the hair quality, has no adverse reactions, and is superior to commercially available color fixation products.
[0067] The above are only the preferred embodiments of the present invention and are not intended to limit the present invention. Any modifications, equivalent replacements, improvements, etc. made within the spirit and principle of the present invention shall be included in the protection scope of the present invention.
Claims
1. A color fixing hair care composition having the functions of nourishing and protecting hair, characterized in that: The invention comprises the following raw materials in parts by weight: 20-40 parts of brown algae extract, 15-20 parts of mulberry extract, 10-15 parts of Polygonum multiflorum extract, 5-10 parts of palmitoyl tripeptide-1, 5-10 parts of acetyl tetrapeptide-3, 3-6 parts of trehalose and 2-4 parts of fucoidan.
2. A color-fixing hair care composition having the functions of nourishing and protecting hair according to claim 1, characterized in that: The brown algae species in the brown algae extract include Sargassum and giant kelp.
3. A color-fixing hair care composition having the functions of nourishing and protecting hair according to claim 1, characterized in that: The method for preparing the brown algae extract comprises the following steps: S1. Remove impurities from fresh brown algae, dry them, and crush them to obtain brown algae powder; S2, enzymatically hydrolyzing the brown algae powder to obtain enzymatically hydrolyzed brown algae; S3, adding the enzymatically hydrolyzed brown algae to the ethanol aqueous solution and performing heating extraction in three stages to obtain an extract; S4, stirring, homogenizing, quenching, and solid-liquid separation of the extract to obtain a supernatant; S5. The supernatant is concentrated under reduced pressure, purified, and dried to obtain a finished product.
4. A color-fixing hair care composition having the functions of nourishing and protecting hair according to claim 3, characterized in that: Step S1, the drying temperature is 50-60°C, and the water content of the brown algae after drying is less than 10%; the crushing has a crushing particle size of less than 0.8mm.
5. The color-fixing hair care composition having the functions of nourishing and protecting hair according to claim 3, characterized in that: Step S2, the enzymolysis, adding Bacillus subtilis, β-mannanase and cellulase in a mass ratio of 1-3:2-4:1; the enzymolysis temperature is 35-40°C, the time is 12-18h, and the pH value is 4.5-7.
5.
6. The color-fixing hair care composition having the functions of nourishing and protecting hair according to claim 3, characterized in that: Step S3, the three stages of temperature-raising extraction, in the first stage, the extraction temperature is 100-150°C, the extraction time is 15-20min, and a polysaccharide extract is obtained; in the second stage, the extraction temperature is raised to 190-210°C, the extraction time is 25-30min, and a polyphenol and small molecule peptide extract is obtained; in the third stage, the temperature is lowered to <60°C, and the extraction is completed; the volume mass concentration of the ethanol aqueous solution is 10%-25%.
7. The color-fixing hair care composition having the functions of nourishing and protecting hair according to claim 3, characterized in that: In step S4, the stirring speed is 150-200 rpm, the solid-liquid separation is performed at a centrifugal speed of 6000-8000 rpm, the centrifugal time is 10-20 min, and the residue is dried and used as fertilizer.
8. The color-fixing hair care composition having the functions of nourishing and protecting hair according to claim 3, characterized in that: Step S5, the concentration, the first stage polysaccharide extract is separated and concentrated by using a 30-100 kDa ultrafiltration membrane; the second stage polyphenol and small molecule peptide extract is adsorbed by a macroporous resin, and the macroporous resin is AB-8 resin or XAD-16 resin.
9. The color-fixing hair care composition having the functions of nourishing and protecting hair according to claim 1, characterized in that: The production steps include: S1, mixing brown algae extract, mulberry extract and Polygonum multiflorum extract, stirring evenly to obtain mixture 1; mixing palmitoyl tripeptide-1, acetyl tetrapeptide-3, trehalose and fucoidan, stirring evenly to obtain mixture II; S2. Dissolve mixture II in mixture 1, heat to 65-85°C, cool, and seal in a vacuum and light-proof manner to obtain a color-fixing hair care composition.
10. The color fixing hair care composition prepared according to claim 9, characterized in that The composition is diluted with purified water in a volume ratio of 1-3:20-25 before use, and the single usage amount is 5-15 mL.