Game suite based on shape memory polymer

Abstract

A shape memory polymer-based game kit includes a plurality of elastomeric copolymer materials and an operating manual of one or more user instructions specifying one or more game rules. Each elastic copolymer material can be deformed from its original shape into one or more three-dimensional structures through external force, and can be changed back to its original shape through temperature stimulation.

Description

Technical Field

[0001] The present invention relates to technical fields such as elastic materials, thermodynamics, general game kit design and manufacturing processes. Background Art

[0002] In the past few years, the children's toy manufacturing industry has paid increasing attention to safety. This high attention is due to the need to ensure that these products do not pose any risk to children's health during use. Traditional children's toys are usually made of materials such as plastics and rubbers. However, in certain cases, these materials may be doped with plasticizers or other toxic substances, thus bringing potential safety hazards. The use of innovative materials such as shape memory polymers (SMP) has become indispensable for such requirements, thus laying the foundation for non-toxic, safe and attractive children's toys.

[0003] SMP is produced by deforming a material with a first "permanent" configuration and a second "temporary" configuration. When subjected to external stimuli such as heat energy, solvents, electric current, light, magnetic fields, pH value changes and thermal stimuli, the material will return to its initial form. That is to say, the material can "remember" its original shape and return to the original shape after being subjected to external stimuli.

[0004] Such shape memory filaments and fibers can be manufactured by melt spinning, wet spinning and dry spinning methods. In such smart fibers, the shape memory function can be retained, that is, the deformation can be remembered through a reversible phase and the original shape can be restored when triggered by external stimuli. Since the 1960s, bicomponent filaments and fibers have been developed as a new type of chemical fiber and have been widely exploited. Through this technology, for two different polymers with appropriate viscosities, their compositions can be co-extruded from two separate extruders through a spinneret into a single filament. The cross-section of the filament can be of different styles, including coaxial sleeve / core, eccentric core-sheath sleeve / core, side-by-side, wedge sheath, island / seafoam pattern, depending on the application requirements.

[0005] However, all the long fibers and filaments in the above patent applications are limited to two components, and it is difficult for them to freely convert between linear or curly / helical shapes. Based on the disadvantages of existing shape memory polymers, there is a need to provide a non-toxic shape memory material that can adjust its curly shape under different conditions to provide a safer and healthier gaming experience for children. Summary of the Invention

[0006] Accordingly, a first aspect of the present invention provides a game kit based on shape memory polymers. The game kit includes a plurality of elastic copolymer materials and an operation manual. The operation manual includes one or more user instructions for specifying one or more game rules. The instruction manual can be in electronic or paper form. Each elastic copolymer material can be manipulated by an external force from its original shape to form one or more three-dimensional structures and can be reversed back to its original shape by stimulation. The three-dimensional structures include one or more of curls, spirals, loops, waves, and coils.

[0007] In one embodiment, the stimulation is thermal energy radiatively transferred by a medium such as air, water, or other fluid having a temperature equal to or higher than the shape recovery temperature.

[0008] In one embodiment, the plurality of elastic copolymer materials include multi-component shape memory wires, fibers, tubes, or tapes.

[0009] In one embodiment, the plurality of elastic copolymer materials include at least two shape memory polymer (SMP-N) components, each of the at least two SMP-N components accounting for at least 1% of the total weight, and N being a positive integer starting from 1.

[0010] In yet another embodiment, the SMP-N component has a shape recovery temperature (T r ) between about -50°C and 100°C, and the recovery temperatures of two or more different components can be represented as T rN and T rN+1 .

[0011] When T rN and T rN+1 are above room temperature and where T rN+1 is greater than T rN , in response to the plurality of elastic copolymer materials being stretched to about 30% to about 300% of their original length, the plurality of elastic copolymer materials are configured to exhibit a first shape change from the original shape to a thin straight shape; when heated to a temperature above T rN and below T rN+ 1, they are configured to exhibit a second shape change, substantially into a spiral shape; when heated to a temperature above T rN+1 , they exhibit a third shape change, substantially returning to the original shape.

[0012] When T rN is below room temperature and T rN+1 is above room temperature, in response to the plurality of elastic copolymer materials being stretched to about 30% to about 300% of their original length and released, the plurality of elastic copolymer materials are changed from the original straight shape to a spiral shape; when heated to a temperature above T rN+1 , the material returns to the original straight shape.

[0013] In one embodiment, one or more three-dimensional structures of the plurality of elastomeric copolymer materials are changed by adjusting the elongation length or the stretching time of the plurality of elastomeric copolymer materials.

[0014] In one embodiment, one or more of curls, helices, loops, waves, and coils have a coil diameter of 0.5 to 10 millimeters and a number of turns per centimeter of 5 to 30.

[0015] In one embodiment, the elongation length ranges from 0.5 - 50 centimeters.

[0016] In one embodiment, the stretching time ranges from 0.1 - 60 seconds.

[0017] In another embodiment, the kit further includes one or more challenge cards, where each challenge card includes at least a task that prompts a user to manipulate the plurality of elastomeric copolymer materials into a specified structure.

[0018] In another embodiment, the kit further includes a container for holding a thermal fluid and a thermometer for regulating the temperature of the thermal fluid, which helps protect the user and allows the user to adjust the temperature of the thermal fluid.

[0019] In another embodiment, the kit further includes one or more building blocks having various shapes, where each of the building blocks is configured to be attachable to the building module via a connector; where each elastomeric copolymer material is connected to the connector for connection to one of the building blocks. One or more substrates may also be included, and each of the one or more elastomeric copolymer materials is connected to a connector for connection to one of the substrates.

[0020] In one embodiment, one or more user instructions are printed on a card, paper, or provided as a link to an interactive online game video guide, or a downloadable game video guide, or a combination thereof. For example, one or more user instructions may be delivered via a QR code.

[0021] In one aspect, the present invention provides a shape memory polymer art tool kit that includes a plurality of elastomeric copolymer filaments and one or more art tools. Specifically, the game kit based on shape memory polymers is used for decoration, artworks, clothing, household items, or product surface design, as well as other creative projects.

[0022] In one embodiment, at least one of the elastomeric copolymer filaments has a different color from another elastomeric copolymer filament.

[0023] In one embodiment, one or more art tools include one or more brushes, rollers, dies, presses, blades, cutters, printers, or tubes.

[0024] The present invention has the following advantages: (1) Users can explore infinite design options by adjusting the elongation length or stretching time of the elastic copolymer material, achieving a dynamic and customizable experience. (2) The shape recovery of the elastic copolymer material is triggered at a safe and optimized temperature (about 38 °C), ensuring that the interaction with the material is user-friendly and safe. (3) The elastic copolymer material exhibits excellent elasticity and can withstand elongation of more than 300%, providing a wide range of shape transformation and creative possibilities. (4) The reversible helical-to-linear shape memory effect can be repeated more than 500 cycles, demonstrating the robustness and durability of the material. (5) The game kit complies with strict toy material safety standards, including ROHS, REACH, EN71, EU2015 / 2030 (SCCPs), CPSIA, etc., ensuring that the product meets regulatory requirements and can be used safely. BRIEF DESCRIPTION OF THE DRAWINGS

[0025] Embodiments of the present invention are described in more detail below with reference to the drawings, in which:

[0026] Figure 1 A schematic diagram showing a shape memory polymer-based game kit of the present invention.

[0027] Figure 2 Different embodiments of the present invention are shown in cross-sectional views according to different configurations of the shape memory polymer (SMP) to produce different three-dimensional structures.

[0028] Figure 3 An elastic copolymer filament showing a controllable helical-linear shape memory effect.

[0029] Figure 4 A process showing the multi-shape change function of a multi-component shape memory filament is shown.

[0030] Figures 5A - 5G Task cards in the game kit of the present invention and their corresponding task contents are shown respectively.

[0031] Figures 6A - 6B The actual application of the shape memory polymer filament according to the present invention in a toy is shown. DETAILED DESCRIPTION OF THE EMBODIMENTS

[0032] The present invention will be described in detail by the following embodiments with reference to the drawings. It should be understood that the specific embodiments provided are for illustrative purposes only and should not be construed in a limiting manner. Those skilled in the art will understand that the invention described herein is subject to changes and modifications other than those specifically described.

[0033] The present invention includes all such variations and modifications. The present invention also includes all the steps and features mentioned or indicated in the specification, whether individually or collectively, and any combination of two or more of all such steps or features. Other aspects and advantages of the present invention will be apparent to those skilled in the art from a review of the following description.

[0034] Reference Figure 1 , the game kit 10 is designed to provide an interactive and dynamic experience for users of all ages. At its core, the kit employs an elastomeric copolymer material 101, each of which can be selectively assembled with a connector 210 and exhibits variability from a linear shape to a structural shape (such as a helical shape) upon external force operation (such as stretching). The uniqueness of the present invention lies in the adoption of advanced shape memory materials, enabling the elastomeric copolymer materials to seamlessly return to their original linear shape when stimulated (such as by thermal energy within a specific temperature range, for example, 38 - 40 °C), thereby further enhancing the possibility of interactive play.

[0035] Accompanying the elastomeric copolymer material 101 are components such as a container 102 designed to hold water, which is one of the media for carrying and dissipating thermal energy stimulation. To ensure precise control, a thermometer 103 is also included, allowing users to fine - tune the water temperature for optimal shape operation of the elastomeric copolymer material. The kit 10 is also equipped with an instruction manual 104, which can be in electronic and / or physical form, to guide users through the various functions of the kit 10 and the shape operation of the elastomeric copolymer material 101.

[0036] After being manipulated into a structural shape, exposing the elastomeric copolymer material 101 to a thermal energy stimulation at a temperature equal to or higher than the shape memory recovery temperature will cause the three - dimensional structure formed by the elastomeric copolymer material 101 to substantially return to its original shape. The medium carrying the thermal energy stimulation can be air, water, gel, or any other fluid capable of enveloping the three - dimensional structure. In various embodiments, users can immerse the shaped elastomeric copolymer material 101 in a container of water at approximately 40 °C, or use a hair dryer, either of which will cause the elastomeric copolymer material 10 to return to its original linear shape.

[0037] To add additional stimulation, the game kit 10 also includes one or more challenge cards 105. Each challenge card 105 presents specific task information, encouraging users to explore the full potential of the shape memory material in an interesting and engaging way.

[0038] In one embodiment, the plurality of elastomeric copolymer materials 101 includes at least two shape memory polymer (SMP-N) components, each of the at least two SMP-N components being at least 1% by total weight, and N being a positive integer starting from 1. For example, N can be 1, 2, 3, 4, 5, etc. The SMP-N components have a shape recovery temperature (T r ) between approximately -50 °C and 100 °C, and the recovery temperatures of two or more different components can be represented as T rN and T rN+ 1.

[0039] In one embodiment, the cross-section of at least two SMP-N components has a side-by-side, eccentric core-sheath, circumferential, or layer-by-layer structure.

[0040] In one embodiment, the plurality of elastomeric copolymer materials includes multi-component shape memory wires, fibers, tubes, or tapes. Each of the at least two shape memory polymer components can be a polyester-based polyurethane shape memory material, a polyether-based polyurethane shape memory material, and other suitable shape memory polymer materials. Preferably, the polyester-based polyurethane shape memory material is a polycaprolactone-based shape memory material.

[0041] In one embodiment, the desired SMP includes but is not limited to Diaplex 2520, 3520, 4520. However, the materials of the SMP are not limited to thermosensitive shape memory polymers, but include other polymers sensitive to other stimuli, such as moisture / water-sensitive shape memory polymers, light-sensitive shape memory polymers, and radiation-sensitive shape memory polymers.

[0042] In one embodiment, the diameter of the wire or fiber is in the range of approximately 0.1 to 2 millimeters.

[0043] In one embodiment, the thickness of the tube or tape is in the range of approximately 0.5 to 1 millimeter.

[0044] In one embodiment, when T rN and T rN+1 are above room temperature and where T rN+1 is greater than T rN , in response to the plurality of elastomeric copolymer materials being elongated to about 30% to about 300% of the original length, the plurality of elastomeric copolymer materials are configured to exhibit a first shape change from the original shape to a thin straight shape. When heated to a temperature above T rN and below T rN+ 1, it is configured to exhibit a second shape change, substantially in a helical shape. When heated to a temperature above T rN+1 , it exhibits a third shape change, substantially returning to the original shape.

[0045] When TrN below room temperature and T rN+1 above room temperature, in response to the plurality of elastomeric copolymer materials being stretched to about 30% to about 300% of their original length and released, the plurality of elastomeric copolymer materials change from an original straight shape to a helical shape; when heated to a temperature of T rN+1 or above, the material returns to its original straight shape.

[0046] In one embodiment, when the at least two SMP-N components are SMP-1 and SMP-2, the SMP-1 and the SMP-2 are co-extruded together at a weight ratio of 1-10:10-1. The T r (T r1 ) of SMP-1 is lower than the T r (T r2 ) of SMP-2, and T r is the melting point or glass transition temperature of SMP-1 and SMP-2. The T r1 of SMP-1 is about -30 °C, and the T r2 of SMP-2 is about 35 °C.

[0047] In one embodiment, the helical shape has a coil diameter of 0.5 to 10 mm and includes 5 to 30 turns per centimeter.

[0048] In another aspect, the present invention also provides a method for preparing the elastomeric copolymer material, the method comprising co-extruding a plurality of components together to form an elastomeric copolymer material. The plurality of components comprise at least two shape memory polymer (SMP-N) components, and each of the at least two SMP-N components is at least 1% of the total weight, and the weight ratio between the at least two SMP-N components is 1:10. N is a positive integer starting from 1, including SMP-1, SMP-2, SMP-3, SMP-4, etc. In the present invention, the number of SMP components is not less than two, and in particular, at least two SMP-N components can potentially be used in the elastomeric copolymer material.

[0049] Turning in detail to the drawings, Figure 2 schematically shows a cross-section of an elastomeric copolymer material composed of at least three shape memory polymers (SMP). These SMPs are co-extruded through a spinneret, a T-die, a side-by-side nozzle or a slot die coater. From left to right, there are listed side-by-side in a thread, eccentric core-sheath in a fiber, circumferential within a tube, and layer-by-layer within a strip. The diameter of the multi-component wire or fiber is in the range of about 0.1 to 2 mm, and the thickness of the multi-component tube or strip is in the range of about 0.5 to 1 mm. The elastomeric copolymer material has the function of various shape changes after being stretched. The amount of shape change after stretching depends on the amount of SMP components in the elastomeric copolymer material.

[0050] In one embodiment, the SMP has a glass transition temperature (T r ) and / or a melting temperature (T g ) that serves as the shape recovery temperature (T m ) of the SMP. The T r of all SMP-N components is approximately between -50 and 100 °C.

[0051] The elastomeric copolymer material can be stretched and at least partially fixed in an elongated shape to change from the original shape to the first shape. After stretching under normal conditions, subsequent stimulation of the first shape changes the first shape to a second helical shape. Finally, when the elastomeric copolymer material in the second shape is triggered by stimulation, it causes the shape to change from the second shape to a third linear shape, equivalent to the original shape. This phenomenon is caused by the deformation of the entire structure including the elastomer and crystal compartments during the stretching process. However, when the force is released, only the elastomer part rebounds, causing the material to form curls (see Figure 3 ). When heated, the deformed crystal compartment melts, releasing stress and causing the material to return to its original shape.

[0052] Reference Figure 4 , in one embodiment, when two thermosensitive SMP components SMP-1 and SMP-2 are used in a multi-component filament, they exhibit stimuli that regulate multi-shape changes after stretching. Both SMP-1 and SMP-2 can provide pseudoplasticity at temperatures below the T r of the SMP. For example, T r1 is below room temperature and T r2 is above room temperature. The longer the filament is repeatedly pulled and released at room temperature, the denser the resulting helical structure is in terms of the number of turns. After stretching and releasing at room temperature, the pseudoplasticity on the SMP-2 side tends to maintain elongation, resulting in an instantaneously formed curly shape. If heated above T r2 , the pseudoplasticity of SMP-2 will be removed and the original linear shape will be restored. Heating can be achieved by immersing the filament in water at 40 °C or using a hair dryer with a lower hot air setting.

[0053] In the case of different stimulation modes, the first stimulation of the SMP-1 component can cause a first shape change, and the second stimulation of the SMP-2 component can cause a second shape change. The stimulation can be selected from temperature, humidity / water, light, pH, and radiation. T r1 is above room temperature and below T r2 . Stretching the filament to an elongation of 30 - 30% at room temperature can produce a thin straight shape, and subsequent heating to T r1 can produce a curly / helical shape. If continuously heated above T r2 , the shape can be restored from the curly / helical shape to the original straight shape.

[0054] The following examples illustrate the present invention and are not intended to limit the present invention.

[0055] Example

[0056] Example 1 - Preparation of an elastic copolymer material

[0057] Two SMP-N components can potentially be used in the elastomeric copolymer material. Both the SMP-1 and SMP-2 components account for at least 1% of the total weight and are co-extruded in a weight ratio of 1:1 using an eccentric nozzle. In this example, SMP-1 uses thermoplastic polyurethane elastomer and SMP-2 uses shape memory polyurethane. T r1 is -30 °C, and T r2 is 35 °C. Before processing, all the pellets must be dried at 104 °C for 2 - 4 hours. The barrel temperature of the extruder is 180 - 195 °C (zone 1), 185 - 200 °C (zone 2), 190 - 205 °C (zone 3), and 190 - 200 °C (die zone). The screw speed is 180 - 200 revolutions per minute. Next, without any stretching process, the extruded filaments from the nozzle are cooled in cold water at 15 °C.

[0058] Stretching the elastomeric copolymer material to an elongation of 30 - 300% at room temperature can produce a curly / helical shape, and subsequently heating to 40 °C can produce a straight shape.

[0059] Example 2 - Application of a shape - memory polymer - based game set

[0060] In the kit, there are at least 8 task cards, and each task card lists a specific structure of the elastomeric copolymer filaments that the user needs to create ( Figures 5A - 5G ). In this example, the process of generating the shapes specified by the various task cards in the provided invention kit is outlined.

[0061] In Challenge 1, the goal is to generate a helical structure with a helix diameter of 2 mm. By extending the duration of stretching the shape memory wire, the degree of deformation of the shape memory wire becomes more obvious. Therefore, a longer stretch results in a more complete deformation, thus forming a helical shape with a smaller helix diameter.

[0062] In Challenge 2, the aim is to produce a helical structure with a diameter of 10 mm. As mentioned before, the user can reduce the crystal deformation by shortening the duration of stretching the shape memory wire, which in turn leads to a helical structure with a larger diameter.

[0063] In Challenge 3, the goal is to produce a helical structure on the same filament with diameters of both 2 mm and 10 mm simultaneously. The method includes stretching the filament with different tightness and duration. The shorter the duration of stretching, the larger the helix diameter, and conversely, the longer the extended duration, the smaller the helix diameter.

[0064] In Challenge 4, the goal is to generate multiple spiral structures with lengths less than 4 cm. Following the instructions of Challenge 1, repeatedly transform multiple filaments into a coiled shape and use connectors to gather all the filaments together.

[0065] In Challenge 5, the goal is to generate multiple spiral structures with lengths of 7 - 11 cm. This is achieved by stretching and elongating only one-third of the filaments to form spiral structures with a diameter of 2 mm at the ends of the filaments.

[0066] In Challenge 6, the goal is to create a line segment with the same bending direction and exceeding 15 mm. The user needs to twist the filament during the stretching process. The bending direction can be clockwise or counterclockwise and can be adjusted manually.

[0067] In Challenge 7, there are no restrictions on the number and shape of the filaments, allowing users to make creative and unrestricted designs.

[0068] Example 3 - Other applications of a shape - memory polymer - based set

[0069] Turning Figure 6A , the kit of the present invention extends its versatility by potentially combining one or more building blocks (e.g., Lego bricks). The elastic copolymer materials provided in the kit can be skillfully assembled onto Lego bricks, resulting in visually novel and innovative designs. For example, these elastic copolymer materials are applied in Lego creations and can serve as integral components of various designs, such as imitating animal hair / tails, the hands and feet of dolls, fountains, jellyfish tentacles, decorative bouquets, leaves, etc. The flexibility of the elastic copolymer materials allows users to unleash their creativity and bring a unique touch to their Lego structures.

[0070] It can also be applied to other toys, including the hair of dolls (see Figure 6B ), skipping ropes, spring toys, and parts of toy cars, etc.

[0071] In addition to toys, the kit can be further applied to other designs, such as decorations, artworks, clothing, household items, or product surface designs, or other creative projects.

[0072] Examples of decorations include wreaths, hanging ornaments, table centerpieces, customized party decorations, etc.

[0073] Examples of artworks include mixed-media artworks, innovative 3D canvas artworks showing dynamic textures, wall-mounted artworks, contemporary art installations, etc.

[0074] Examples of clothing include fashion accessories such as bracelets and necklaces, decorative patches or embellishments, belts, shoelaces, etc.

[0075] Examples of household articles include coasters, curtain tapes, the insulating outer layer of electric wires, telephone wires, straps or lanyards for mobile phones, straps for backpacks, etc.

[0076] Definitions

[0077] Throughout the specification, unless otherwise specified, the term "comprise" or variations such as "comprises" or "comprising" will be understood to include a stated integer or group of integers but not to exclude the inclusion of any other integer or group of integers. It should also be noted that in the present disclosure, particularly in the claims or during, terms such as "comprises", "comprised", or "comprising" have the meaning given to them in US patent law. For example, they allow for elements not recited, but exclude elements found in the prior art or elements that affect the basic or novel features of the invention.

[0078] Furthermore, throughout the specification and claims, unless otherwise required, the term "include" or variations such as "includes" or "including" will be understood to include a stated integer or group of integers but not to exclude the inclusion of any other integer or group of integers.

[0079] The terms "an embodiment", "embodiment", "exemplary embodiment", etc. mentioned in the specification mean that the described embodiment may include specific features, structures or characteristics, but each embodiment may not necessarily include specific ones, and these features do not necessarily refer to the same embodiment. Additionally, when a specific feature, structure or characteristic is described in connection with an embodiment, it is considered within the knowledge of those skilled in the art that these features, structures or characteristics can be combined with other embodiments, whether explicitly described or not.

[0080] The term "linear" or "straight" used herein to describe the state of the multi-component shape memory wire, fiber, tube or tape of the present invention refers to the tight or substantially linear state of the shaped multi-component shape memory wire, fiber, tube, or tape of the present invention, which can be visually observed and determined qualitatively and / or quantitatively.

[0081] The term "fiber" used herein refers to a three-dimensional structure having an elongated form. In some contexts, the term "fiber" may also refer to a slender filamentous object or article.

[0082] The term "shape memory polymer" or "shape memory polymer component" as used herein (or sometimes they are used interchangeably) refers to a unique class of polymers or materials that have the ability to fix a temporary shape and then return to a previous state due to an external stimulus (e.g., heat, radiation, solvent, electric current, light, magnetic field, or a change in pH).

[0083] The term "elastomer" or "elastomer component" as used herein (or sometimes they are used interchangeably) refers to a material that exhibits the properties of elasticity, a low Young's modulus (i.e., the ratio of tensile stress to tensile strain), and is capable of deforming when a stress is applied and returning to its original shape (i.e., length, volume, shape, etc.) when the stress is removed. Examples of elastomers useful in the present invention include, but are not limited to, polyesters or polyether-based polyurethanes.

[0084] Other definitions of alternative terms used herein can be found in the detailed description of the present invention and converted throughout the text. Unless otherwise defined, all other technical terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which the present invention pertains.

[0085] Based on the teachings of the present disclosure, those skilled in the art can implement alternative embodiments without departing from the spirit or scope of the present invention. The scope of the present invention is defined by the following claims, which include all embodiments and various modifications made in conjunction with the above specification and drawings.

Claims

1. A game set based on shape memory polymers, characterized in that, The game kit includes: A variety of elastic copolymer materials, each of which can generate one or more three-dimensional structures from its original shape through external force operation and return to the original shape through temperature stimulation; An operation manual, which includes one or more user instructions for specifying one or more game rules; Wherein the one or more three-dimensional structures include one or more of curls, spirals, small loops, waves and coils; and Wherein the temperature stimulation is thermal energy having a temperature equal to or higher than the shape recovery temperature, and the thermal energy is carried and radiated through a medium selected from one or more of air, water and other fluids.

2. The shape memory polymer-based game kit according to claim 1, wherein the variety of elastic copolymer materials include multi-component shape memory wires, fibers, tubes or tapes.

3. The shape memory polymer-based game kit according to claim 1, wherein the variety of elastic copolymer materials are made of at least two shape memory polymer (SMP-N) components, each of the at least two SMP-N components accounts for at least 1% of the total weight, and N is a positive integer starting from 1.

4. The shape memory polymer-based game kit according to claim 3, wherein the SMP-N component has a shape recovery temperature (T r ) between about -50 °C and 100 °C, and the recovery temperatures of two or more different components can be represented as T rN and T rN+1 .

5. The shape memory polymer-based game kit according to claim 4, when T rN and T rN+1 are above room temperature and wherein T rN+1 is greater than T rN , in response to the plurality of elastomeric copolymer materials elongating to about 30% to about 300% of their original length, the plurality of elastomeric copolymer materials are designed to exhibit a first shape change from an original shape to an elongated, thin, straight shape; when heated to a temperature above T rN and below T rN+ 1, they exhibit a second shape change, substantially a helical shape; when heated to a temperature above T rN+1 , they exhibit a third shape change, substantially returning to the original shape.

6. The shape memory polymer-based game kit according to claim 4, when T rN is below room temperature and T rN+1 is above room temperature, in response to the plurality of elastomeric copolymer materials being stretched to about 30% to about 300% of their original length and released, the plurality of elastomeric copolymer materials change from an original straight shape to a helical shape; when heated to a temperature of T rN+1 or above, the material returns to the original straight shape.

7. The shape memory polymer-based game kit according to claim 1, wherein the one or more three-dimensional structures of the variety of elastic copolymer materials are changed by adjusting the elongation length or stretching time of the variety of elastic copolymer materials.

8. The shape memory polymer-based game kit according to claim 1, wherein one or more of the curls, spirals, small loops, waves and coils have a coil diameter of 0.5 to 10 mm and 5 to 30 turns per centimeter.

9. The shape memory polymer-based game kit according to claim 7, wherein the elongation length ranges from 0.5 to 50 cm.

10. The shape memory polymer-based game kit according to claim 7, wherein the stretching time ranges from 0.1 to 60 seconds.

11. The shape memory polymer-based game kit according to claim 1, further comprising one or more challenge cards, each of which at least includes a task of prompting the user to deform the variety of elastic copolymer materials into a specified structure by external force.

12. The shape memory polymer-based game kit according to claim 1, further comprising a container for containing a hot fluid.

13. The shape memory polymer-based game kit according to claim 12, further comprising a thermometer for adjusting the temperature of the hot fluid, which helps to protect the user and allows the user to adjust the temperature of the hot fluid.

14. The shape memory polymer-based game kit according to claim 1, further comprising one or more building blocks having various shapes, each of which is configured to be attachable to another building block via a connector; wherein Each elastic copolymer material is connected to a connector for connecting one of the building blocks.

15. The shape memory polymer-based game kit according to claim 1 further includes one or more substrates, wherein each of the elastomeric copolymer materials is connected to a connector of one of the substrates.

16. The shape memory polymer-based game kit according to claim 1, wherein the one or more user instructions are printed on cards, paper, or provided as a link to an interactive online game video guide, or a downloadable game video guide, or a combination thereof.

17. A shape memory polymer art tool kit, characterized in that, The art tool kit includes: A plurality of elastomeric copolymer filaments; wherein each of the elastomeric copolymer filaments is capable of being deformed from its original shape into one or more three-dimensional structures by an external force and returning to the original shape by temperature stimulation; wherein at least one of the elastomeric copolymer filaments has a different color from another elastomeric copolymer filament; One or more art tools.

18. The shape memory polymer art tool kit according to claim 17, wherein the one or more art tools include one or more brushes, rollers, molds, presses, blades, cutters, printers, or tubes.

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