Anti-sunlight reflecting cloth and preparation method thereof

By using a combination of recycled PP masterbatch, anti-reflective masterbatch, and anti-UV masterbatch, the shortcomings of anti-reflective fabric in terms of reflectivity, UV resistance, and weather resistance have been solved, resulting in a low-carbon and environmentally friendly high-performance reflective fabric suitable for long-term outdoor use and large-scale production.

CN120519967BActive Publication Date: 2026-03-03GUANGDONG YINONG NEW MATERIALS TECH CO LTD
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Patent Information

Application Number
CN202510909231.2
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2025-07-02
Publication Date
2026-03-03
Estimated Expiration
2045-07-02

AI Technical Summary

Technical Problem

Existing anti-reflective fabrics are inadequate in terms of reflectivity, UV resistance, and long-term weather resistance, failing to meet practical application requirements. Furthermore, PP materials have high petroleum consumption and carbon emissions, and recycled PP materials exhibit decreased mechanical properties, making it difficult to meet long-term use requirements.

Method used

Using recycled PP masterbatch as the base material, combined with anti-reflective masterbatch, anti-UV masterbatch and hydrostatic masterbatch, a specific ratio of these components enhances reflectivity, UV resistance and weather resistance, reduces material water absorption, and forms a synergistic system that adapts to different qualities of recycled PP materials, ensuring product quality stability.

Benefits of technology

This low-carbon and environmentally friendly anti-reflective fabric boasts excellent UV protection, high reflectivity, weather resistance, low water absorption, and mechanical properties. It is suitable for long-term outdoor use, ensuring a long service life and practicality, and is suitable for large-scale industrial production.

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Abstract

The application relates to the field of high polymer materials, in particular to a sun-proof light-reflecting cloth and a preparation method thereof. The sun-proof light-reflecting cloth is prepared from the following raw materials in percentage by weight: 85-95% of PP recycled master batch, 3-8% of sun-proof color master batch, 1-4% of anti-UV master batch and 1-3% of hydrostatic pressure master batch; the sun-proof color master batch is composed of colorant, electroplated silver resin, terpene resin and rosin derivative; the anti-UV master batch is composed of multiple kinds of organic silicon cross-linked polyethylene, bismaleimide, boron-modified phenolic resin and anti-UV agent; and the hydrostatic pressure master batch is cashew nut shell oil modified resin. The sun-proof light-reflecting cloth has excellent anti-UV property, high reflectivity, weather resistance and mechanical property and the like through the optimized compounding of the PP recycled master batch, the anti-UV master batch, the sun-proof color master batch and the hydrostatic pressure master batch, is suitable for long-term outdoor use, has good adaptability to different quality PP recycled materials and ensures product quality stability.
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Description

Technical Field

[0001] This application relates to the field of polymer materials, and more specifically, to a sun-reflective fabric and its preparation method. Background Technology

[0002] Reflective sunshade fabric, as a key material, plays an irreplaceable role in numerous fields such as agricultural shading, building insulation, and outdoor protection. It primarily protects crops from excessive sunlight and UV damage by reflecting sunlight and reducing ultraviolet radiation, while also reducing heat accumulation inside buildings, creating a comfortable indoor environment. With societal progress and rising demands for quality of life, the application of reflective sunshade fabric is becoming increasingly widespread, and its market demand continues to grow. It not only affects the stability and yield of agricultural production but also plays a vital role in building energy conservation and the safety of outdoor personnel, providing strong protection for people's production and daily life.

[0003] For a long time, most sunscreen reflective fabrics on the market were made of polypropylene (PP). PP's lightweight nature makes it easy to transport and install; its resistance to chemical corrosion allows it to maintain stable performance in various complex environments, making it the mainstream choice for manufacturing sunscreen reflective fabrics. To align with the trend of green and low-carbon development and reduce reliance on virgin PP, the market has begun to promote the use of recycled PP materials in the production of sunscreen reflective fabrics. Furthermore, the industry typically uses fillers (such as calcium carbonate and talc) and compatibilizers to blend and modify recycled PP materials to improve their mechanical properties and weather resistance, aiming to enhance the material's practicality while ensuring environmental protection.

[0004] Existing technologies have significant shortcomings. PP materials rely on petroleum resources for synthesis, and large-scale production leads to increased petroleum consumption and high carbon emissions, which contradicts the current green and low-carbon development philosophy. While recycled PP materials offer some environmental advantages, they suffer from significant problems such as decreased mechanical properties, brittleness, and short service life, making them unsuitable for long-term practical applications. Even with blending modification using fillers and compatibilizers, mechanical strength can only be improved to a certain extent, failing to achieve a balance in material properties, reflectivity, and resistance to solar aging. This results in poor performance of the anti-sunlight reflective fabric in terms of reflectivity, UV resistance, and long-term weather resistance, failing to achieve the desired performance. Summary of the Invention

[0005] The purpose of this application is to overcome the above-mentioned technical problems and provide a sun-proof reflective fabric and its preparation method.

[0006] In a first aspect, this application provides a sun-reflective fabric composed of the following raw materials by weight percentage: 85-95% recycled PP masterbatch; 3-8% sun-reflective color masterbatch; 1-4% UV-resistant masterbatch; and 1-3% hydrostatic masterbatch. The sun-reflective color masterbatch is composed of pigments, electroplating silver resin, terpene resin, and rosin derivatives. The UV-resistant masterbatch is composed of multiple components including organosilicon cross-linked polyethylene, bismaleimide, boron-modified phenolic resin, and UV-resistant agents, and contains at least one UV-resistant agent. The hydrostatic masterbatch is cashew nut shell oil modified resin.

[0007] By adopting the above technical solutions, the use of PP recycled masterbatch reduces petroleum resource consumption and carbon emissions, thus achieving environmental benefits. In the anti-reflective color masterbatch, electroplated silver resin enhances the light reflection performance and sunlight blocking effect of the reflective fabric; terpene resin and rosin derivatives improve the masterbatch's dispersibility and adhesion, synergistically enhancing UV protection and reflectivity, and improving the processing stability and mechanical strength of the PP recycled masterbatch. In the anti-UV masterbatch, organosilicon cross-linked polyethylene improves the material's weather resistance and flexibility; bismaleimide enhances thermal stability and anti-aging properties; boron-modified phenolic resin improves flame retardancy and mechanical strength and assists in UV protection; the anti-UV agent directly absorbs or scatters ultraviolet rays to prevent material degradation, improving the anti-UV ability, physical properties, and durability of the anti-reflective fabric. The hydrostatic masterbatch reduces the material's water absorption rate, preventing performance degradation caused by moisture penetration, and synergistically improves the overall performance of the anti-reflective fabric with other masterbatches, ensuring a longer service life and practicality. The formulation system is adaptable to different qualities of recycled PP, ensuring product quality stability and suitability for large-scale industrial production.

[0008] Preferably, the anti-reflective color masterbatch is composed of colorant, electroplating silver resin, terpene resin, and rosin derivative in a weight ratio of 1:(1-3):(1-2):(0.5-1).

[0009] By adopting the above technical solution and limiting the weight ratio of each component in the anti-reflective color masterbatch, the synergistic effect of each component can be further precisely exerted, the enhancement effect of electroplating silver resin on reflective light performance can be improved, the effect of terpene resin and rosin derivative on the dispersibility and adhesion of the masterbatch and the synergistic enhancement of UV protection and reflective performance with electroplating silver resin can be enhanced, and the processing stability and mechanical strength of PP recycled masterbatch can be better improved.

[0010] Preferably, the rosin derivative is rosin-modified pentaerythritol ester and / or rosin-modified phenolic resin.

[0011] By adopting the above technical solution, using rosin-modified pentaerythritol ester and / or rosin-modified phenolic resin as rosin derivatives, combined with PP recycled masterbatch, a specific proportion of anti-reflective color masterbatch, anti-UV masterbatch, and hydrostatic pressure masterbatch, it can work synergistically with other raw materials to improve the UV protection capability, reflectivity, weather resistance, and mechanical properties of the anti-reflective fabric, ensuring a longer service life and practicality. At the same time, it makes the formulation system adaptable to PP recycled materials of different qualities, ensuring stable product quality and suitability for large-scale industrial production.

[0012] Preferably, the rosin derivative is composed of rosin-modified pentaerythritol ester and rosin-modified phenolic resin.

[0013] By adopting the above technical solutions, the use of recycled PP masterbatch can reduce dependence on virgin PP, thereby reducing petroleum resource consumption and carbon emissions. The electroplated silver resin in the anti-reflective masterbatch enhances the light reflection performance of the reflective fabric, while terpene resin and rosin derivatives (composed of rosin-modified pentaerythritol ester and rosin-modified phenolic resin) improve the dispersibility and adhesion of the masterbatch, synergistically enhancing UV protection and reflectivity with the electroplated silver resin, while also improving the processing stability and mechanical strength of the recycled PP masterbatch. The anti-UV masterbatch enhances the UV resistance and physical properties of the anti-reflective fabric. Performance and durability; hydrostatic masterbatch has excellent hydrophobic properties, which can reduce the water absorption rate of the material and synergistically improve the overall performance of the anti-sun reflective fabric with other masterbatches; the optimized compounding of PP recycled masterbatch with other masterbatches forms a synergistic effect system, which enables the anti-sun reflective fabric to have excellent UV protection, high reflectivity, weather resistance, low water absorption and mechanical properties, making it suitable for long-term outdoor use, ensuring a long service life and practicality, and the formulation system has good adaptability to PP recycled materials of different qualities, ensuring the quality stability of the final product, and is suitable for large-scale industrial production.

[0014] Preferably, the UV-resistant masterbatch is composed of organosilicon cross-linked polyethylene, bismaleimide, boron-modified phenolic resin, and UV-resistant agent.

[0015] By adopting the above technical solution, with the combination of PP recycled masterbatch, anti-reflective color masterbatch, and hydrostatic masterbatch, organosilicon cross-linked polyethylene improves the material's weather resistance and flexibility, reduces UV-induced embrittlement, bismaleimide enhances thermal stability and anti-aging properties, and extends service life, boron-modified phenolic resin improves flame retardancy and mechanical strength, and assists in UV protection, and UV-resistant agents directly absorb or scatter ultraviolet rays and prevent material degradation, significantly improving the UV resistance of the anti-reflective fabric, enhancing its physical properties and durability. This results in anti-reflective fabric with excellent UV protection, high reflectivity, weather resistance, low water absorption, and mechanical properties, suitable for long-term outdoor use, ensuring a long service life and practicality. Furthermore, the formulation system has good adaptability to PP recycled materials of different qualities, ensuring the quality stability of the final product, and is suitable for large-scale industrial production.

[0016] Preferably, the PP recycled masterbatch is composed of polypropylene, recycled PP material, filler, and processing aids.

[0017] Preferably, the polypropylene is β-crystalline polypropylene.

[0018] By adopting the above technical solutions, recycled PP materials have advantages such as low carbon emissions and environmental friendliness. β-crystalline polypropylene and fillers are uniformly mixed under the action of processing aids, giving the recycled PP masterbatch excellent comprehensive performance. Combined with the optimized compounding of anti-UV masterbatch, anti-reflective masterbatch, and hydrostatic masterbatch, a synergistic system is formed, enabling the anti-reflective fabric to possess excellent UV protection, high reflectivity, weather resistance, low water absorption, and mechanical properties, making it suitable for long-term outdoor use and ensuring a long service life and practicality. The formulation system has good adaptability to recycled PP materials of different qualities, effectively compensating for the impact of performance fluctuations in recycled materials, ensuring the quality stability of the final product, and making it suitable for large-scale industrial production.

[0019] Preferably, the relative molecular weight of the β-crystalline polypropylene is 100,000 to 200,000.

[0020] By adopting the above technical solution, PP recycled masterbatch is prepared using β-crystalline polypropylene with a relative molecular weight of 100,000-200,000. Combined with UV-resistant masterbatch, anti-reflective masterbatch, and hydrostatic masterbatch, a synergistic system is formed through optimized compounding. This system enables the anti-reflective fabric to possess excellent UV protection, high reflectivity, weather resistance, low water absorption, and mechanical properties, making it suitable for long-term outdoor use and ensuring a long service life and practicality. The formulation system has good adaptability to PP recycled materials of different qualities, can compensate for the impact of performance fluctuations in recycled materials, ensure the quality stability of the final product, and is suitable for large-scale industrial production.

[0021] Preferably, the processing aid is a combination of multiple components of hydrogenated vegetable oil, stearic acid, epoxidized soybean oil, and PE wax.

[0022] By adopting the above technical solutions, including PP recycled masterbatch, anti-reflective masterbatch, anti-UV masterbatch, and hydrostatic masterbatch, the use of virgin PP is reduced, thus lowering petroleum consumption and carbon emissions. Anti-reflective masterbatch enhances the light reflection and UV protection performance of reflective fabric, improving processing stability and mechanical strength. Anti-UV masterbatch improves UV resistance, physical properties, and durability. Hydrostatic masterbatch reduces water absorption and improves overall performance. The recycled PP material in the PP recycled masterbatch is environmentally friendly, and combined with other masterbatches to form a synergistic system, giving the reflective fabric multiple excellent properties. The formula is adaptable to different qualities of recycled PP material, ensuring stable product quality. The use of hydrogenated vegetable oil, stearic acid, epoxidized soybean oil, and PE wax as processing aids lowers processing temperature and promotes uniform mixing of raw materials.

[0023] Secondly, a method for preparing a sun-reflective fabric includes the following steps: weighing PP recycled masterbatch, sun-reflective color masterbatch, UV-resistant masterbatch, hydrostatic masterbatch, and processing aids according to weight percentages, mixing them evenly, and then melt-extruding to obtain a blended modified material; then melt-spinning, traction web laying, hot rolling molding, and winding and slitting the blended modified material to finally obtain the sun-reflective fabric.

[0024] By adopting the above technical solutions, it is possible to produce sun-reflective fabric with excellent UV protection, high reflectivity, weather resistance, low water absorption, and mechanical properties, which is suitable for long-term outdoor use and ensures a long service life and practicality. The formula system has good adaptability to PP recycled materials of different qualities, can make up for the impact of performance fluctuations of recycled materials, ensure the stability of the final product quality, and is suitable for large-scale industrial production.

[0025] In summary, this application includes at least one of the following beneficial technical effects:

[0026] 1. Using recycled PP masterbatch as the base material significantly reduces the use of virgin PP, lowers petroleum resource consumption and carbon emissions, and meets the requirements of green, low-carbon and sustainable development.

[0027] 2. In the anti-reflective color masterbatch, the electroplated silver resin enhances the reflective properties of the reflective fabric, while the terpene resin and rosin derivatives improve the dispersibility and adhesion of the masterbatch. Together with the electroplated silver resin, they enhance the UV protection and reflective properties, and improve the processing stability and mechanical strength of the PP recycled masterbatch.

[0028] 3. The synergistic effect of the components of the anti-UV masterbatch enhances the UV resistance, physical properties, and durability of the anti-reflective fabric;

[0029] 4. Hydrostatic masterbatch has excellent hydrophobic properties, reducing the water absorption rate of materials, and works synergistically with anti-UV masterbatch and anti-reflective color masterbatch to improve the overall performance of anti-reflective fabric;

[0030] 5. Through optimized blending of PP recycled masterbatch with anti-UV masterbatch, anti-reflective masterbatch, and hydrostatic masterbatch, the anti-reflective fabric possesses excellent UV protection, high reflectivity, weather resistance, low water absorption, and mechanical properties. It is suitable for long-term outdoor use and has good adaptability to PP recycled materials of different qualities, ensuring product quality stability and making it suitable for large-scale industrial production. Detailed Implementation

[0031] The present application will be further described in detail below with reference to the embodiments.

[0032] Partial ingredient descriptions:

[0033] PP recycled materials: Material A, with a purity (referring to the PP content) of 95%, has a measured tensile strength of 19.7 MPa; Material B, with a purity of 70%, has a measured tensile strength of 17.9 MPa. The above data were all measured using ASTM D638, with experimental conditions of 50 mm / min and a sample thickness of 2 mm.

[0034] Pigment: Iron oxide blue powder (1000 mesh);

[0035] Electroplating silver resin Greenlink (Jining) Chemical Technology Co., Ltd. AA-8316;

[0036] Terpene Resin Greenlink (Jining) Chemical Technology Co., Ltd., Product Name: Terpene Resin T-110, Granule Code: BT08;

[0037] Rosin-modified pentaerythritol ester, brand name: Sinan 146#

[0038] Rosin-modified phenolic resin, brand and model: Sinan 2112#;

[0039] Hydrogenated vegetable oil CAS No. 68334-28-1;

[0040] Epoxidized soybean oil CAS No. 8013-07-8;

[0041] PE wax CAS number 9016-5-9

[0042] Organosilicon cross-linked polyethylene, Henan Anerxin Polymer Materials Co., Ltd., according to JB / T10437-2004, the typical values ​​of tensile strength are 20MPa and elongation at break are 460%.

[0043] Boron-modified phenolic resin, model ALL, manufactured by Greenlink (Jining) Chemical Technology Co., Ltd.

[0044] Cashew nut shell oil modified resin, Jinan Shengquan Group Co., Ltd., model RT2201;

[0045] Example

[0046] Example 1

[0047] A method for preparing a sun-reflective fabric includes the following steps:

[0048] PP recycled masterbatch: β-crystalline polypropylene, recycled PP, filler, and processing aids are weighed and mixed evenly in a weight ratio of 1:6.65:2:0.35, and then melt-extruded and granulated in an extruder to obtain PP recycled masterbatch. The extruder temperature is set sequentially to 180℃, 190℃, 195℃, 200℃, 210℃, 225℃, 220℃, and 210℃. The recycled PP is material A, the filler is 800-mesh silica, and the processing aids are hydrogenated vegetable oil, epoxidized soybean oil, and PE wax in a weight ratio of 1:0.5:0.5. The relative molecular weight of β-crystalline polypropylene is 100,000-200,000, and in this embodiment, it is preferably 180,000.

[0049] Anti-reflective color masterbatch: The colorant, electroplating silver resin, terpene resin and rosin derivative are weighed in a weight ratio of 1:1:1:0.5, mixed evenly, and then put into an extruder for melt extrusion, water cooling and granulation to obtain anti-reflective color masterbatch. The extruder temperature is set to 150℃, 160℃, 165℃, 170℃, 180℃, 175℃, 170℃ and 160℃ in sequence. The rosin derivative is rosin-modified pentaerythritol ester.

[0050] UV-resistant masterbatch: Weigh out silicone cross-linked polyethylene, boron-modified phenolic resin and UV-resistant agent in a weight ratio of 1:1:1, mix them evenly, and then put them into an extruder for melt extrusion, water cooling, and granulation to obtain anti-reflective color masterbatch. The UV-resistant agent is UV-234. The extruder temperature is set to 160℃, 170℃, 185℃, 190℃, 200℃, 195℃, 190℃ and 185℃ in sequence.

[0051] The hydrostatic masterbatch is a cashew nut shell oil modified resin.

[0052] Anti-reflective fabric: By weight percentage, weigh 85% recycled PP masterbatch, 8% anti-reflective color masterbatch, 4% anti-UV masterbatch, and 3% hydrostatic masterbatch, mix them evenly in a mixer, transfer them to an extruder for melt extrusion, water cooling, and granulation to obtain a blended modified material. The blended modified material is then subjected to melt spinning (spinning temperature 278℃, spinning speed 300m / min, L / D 20, spinneret orifice diameter 0.2mm), traction web laying (air-jet traction web laying), hot rolling forming (hot rolling treatment, hot rolling mill upper temperature 130℃, hot rolling mill lower temperature 120℃), and winding and slitting to obtain the anti-reflective fabric. The extruder temperatures are sequentially set to 185℃, 190℃, 200℃, 205℃, 210℃, 220℃, 210℃, and 200℃. The reflective fabric has a g / m² content of 115g. 2 .

[0053] Example 2-3

[0054] The difference between Examples 2-3 and Example 1 is that the amount of raw materials used is different, as shown in Table 1.

[0055] Table 1. Raw material usage (by weight percentage) for Examples 1-3

[0056] raw material Example 1 Example 2 Example 3 PP recycled masterbatch 85 90.10 95 Anti-reverse color masterbatch 8 5.40 3 UV-resistant masterbatch 4 2.70 1 hydrostatic masterbatch 3 1.80 1

[0057] Example 4

[0058] The difference between Example 4 and Example 2 is that the anti-reflective color masterbatch is composed of colorant, electroplating silver resin, terpene resin, and rosin derivative in a ratio of 1:2:2:0.8.

[0059] Example 5

[0060] The difference between Example 5 and Example 2 is that the anti-reflective color masterbatch is composed of colorant, electroplating silver resin, terpene resin, and rosin derivative in a ratio of 1:3:2:1.

[0061] Example 6

[0062] The difference between Example 6 and Example 5 is that the rosin derivative is a rosin-modified phenolic resin.

[0063] Example 7

[0064] The difference between Example 7 and Example 5 is that the rosin derivative is composed of rosin-modified pentaerythritol ester and rosin-modified phenolic resin in a weight ratio of 1:1.

[0065] Example 8

[0066] The difference between Example 8 and Example 7 is that the UV-resistant masterbatch is composed of organosilicon cross-linked polyethylene, bismaleimide, and UV agent in a weight ratio of 1:1:3.

[0067] Example 9

[0068] The difference between Example 9 and Example 7 is that the UV-resistant masterbatch is composed of organosilicon cross-linked polyethylene, bismaleimide, boron-modified phenolic resin, and UV agent in a weight ratio of 2:1:2:5.

[0069] Example 10

[0070] The difference between Example 10 and Example 7 is that the recycled PP material is material B.

[0071] Paired proportions

[0072] Comparative Example 1

[0073] The difference between Comparative Example 1 and Example 2 is that the hydrostatic masterbatch was replaced with an equal amount of recycled PP masterbatch.

[0074] Comparative Example 2

[0075] The difference between Comparative Example 2 and Example 2 is that the UV-resistant masterbatch was replaced with an equal amount of recycled PP masterbatch.

[0076] Comparative Example 3

[0077] The difference between Comparative Example 3 and Example 2 is that the electroplating silver resin was replaced with an equal amount of terpene resin.

[0078] Comparative Example 4

[0079] The difference between Comparative Example 4 and Example 2 is that the anti-reflective color masterbatch is composed of colorant and electroplating silver resin.

[0080] Comparative Example 5

[0081] The difference between Comparative Example 5 and Example 2 is that the UV-resistant masterbatch is a UV-resistant agent.

[0082] Performance testing

[0083] Detection methods / test methods

[0084] The reflective fabrics obtained in Examples 1-10 and Comparative Examples 1-5 were subjected to the following performance tests;

[0085] 1) Reflective properties

[0086] The reflectivity was tested using a Jinanrui C84-Ⅲ reflectivity meter with an incident angle of 45° and an observation angle of 0.2°; the visible light band was 500nm.

[0087] 2) Mechanical properties

[0088] Referring to GB / T3923.1-2013 "Textiles - Tensile Properties of Fabrics - Part 1: Determination of Breaking Strength and Elongation at Break (Strip Method)", a fabric tensile testing machine was used to obtain the tensile strength and elongation at break in the longitudinal and transverse directions.

[0089] 3) Aging performance

[0090] The reflective fabric was placed in an aging test as follows:

[0091] Ultraviolet irradiation for 4 hours (lamp UVA-340nm, power 0.63W / (m²)) 2 The sample was subjected to 4 hours of humidification (temperature 85℃, ambient humidity 85%) at a temperature of 60℃ and 85% at 85℃, with each cycle continuing until the test was completed; each cycle lasted 8 hours, for a total of 50 cycles. The sample was cut and tested according to the method in 1), and the residual MD tensile strength (%) was calculated by multiplying the ratio of the aging result to the initial result by 100%.

[0092] All the above experiments were performed three times, and the average value was taken, as shown in Table 2.

[0093] Table 2 Examples 1-10 and Comparative Examples 1-5

[0094]

[0095] Combining Example 2 and Comparative Examples 1-5 with Table 2, it can be seen that the tensile strength, elongation at break, and residual tensile strength (%) of Comparative Examples 1-5 are all lower than those of Example 1, and the reflectivity is also lower than that of Example 1. This indicates that the present application uses recycled PP masterbatch, which also possesses basic low-carbon and environmentally friendly characteristics. Combined with the synergistic effect of anti-reflective color masterbatch, anti-UV masterbatch, and hydrostatic pressure masterbatch, the material properties, sunlight resistance, and reflectivity of the anti-reflective fabric are further improved. Furthermore, the anti-reflective color masterbatch is composed of colorant, electroplated silver resin, terpene resin, and rosin derivative; the anti-UV masterbatch is composed of multiple components including organosilicon cross-linked polyethylene, bismaleimide, boron-modified phenolic resin, and anti-UV agents, with at least one being an anti-UV agent; the hydrostatic pressure masterbatch is cashew nut shell oil modified resin. The interaction of these components further improves the overall performance of the anti-reflective fabric.

[0096] Combining Examples 5 and 7 with Table 2, it can be seen that the tensile strength, elongation at break, and residual tensile strength (%) of Example 5 are all lower than those of Example 7, and the reflectivity is also lower than that of Example 7. This indicates that the rosin derivative used in this application, which is composed of rosin-modified pentaerythritol ester and rosin-modified phenolic resin, plays a synergistic role and further improves the overall performance.

[0097] Combining Examples 7 and 9 with Table 2, it can be seen that the tensile strength, elongation at break, and residual tensile strength (%) of Example 7 are all lower than those of Example 9, and the reflectivity is also lower. This indicates that the use of the anti-UV masterbatch, composed of silicone cross-linked polyethylene, bismaleimide, boron-modified phenolic resin, and UV agent in a weight ratio of 2:1:2:5, has a synergistic effect, further improving the overall performance of the reflective fabric.

[0098] Combining Examples 7 and 10 with Table 2, it can be seen that the tensile strength, elongation at break, and residual tensile strength (%) of Example 7 are all lower than those of Example 10, and the reflectivity is also lower than that of Example 10. This indicates that the PP recycled material with different impurity contents obtained through the technical solution of this application is better and has more uniform quality.

[0099] This specific embodiment is merely an explanation of this application and is not intended to limit it. After reading this specification, those skilled in the art can make modifications to this embodiment without contributing any inventive step, but such modifications are protected by patent law as long as they fall within the scope of the claims of this application.

Claims

1. A type of anti-reflective fabric, characterized in that, Composed of the following raw materials by weight percentage: PP recycled masterbatch 85-95% Anti-reflective color masterbatch 3-8% UV-resistant masterbatch 1-4% hydrostatic masterbatch 1-3%; The anti-reflective masterbatch is composed of pigment, electroplating silver resin, terpene resin, and rosin derivative; the anti-UV masterbatch is composed of multiple components including organosilicon cross-linked polyethylene, bismaleimide, boron-modified phenolic resin, and anti-UV agent, and at least one of them is an anti-UV agent; the hydrostatic masterbatch is cashew nut shell oil modified resin; the anti-UV masterbatch is composed of organosilicon cross-linked polyethylene, bismaleimide, boron-modified phenolic resin, and anti-UV agent; the rosin derivative is rosin-modified pentaerythritol ester and / or rosin-modified phenolic resin.

2. The anti-reflective fabric according to claim 1, characterized in that: The anti-reflective color masterbatch is composed of colorant, electroplating silver resin, terpene resin and rosin derivative in a weight ratio of 1:(1-3):(1-2):(0.5-1).

3. The anti-reflective fabric according to claim 1, characterized in that: The rosin derivative is composed of rosin-modified pentaerythritol ester and rosin-modified phenolic resin.

4. The anti-reflective fabric according to claim 1, characterized in that: The PP recycled masterbatch is composed of polypropylene, recycled PP material, fillers, and processing aids.

5. The anti-reflective fabric according to claim 4, characterized in that: The polypropylene is β-crystalline polypropylene.

6. The anti-reflective fabric according to claim 5, characterized in that: The relative molecular weight of the β-crystalline polypropylene is 100,000 to 200,000.

7. The anti-reflective fabric according to claim 4, characterized in that: The processing aid is a combination of various hydrogenated vegetable oils, stearic acid, epoxidized soybean oil, and PE wax.

8. A method for preparing the anti-reflective fabric according to any one of claims 1-7, characterized in that, Includes the following steps: According to the weight percentage, weigh out PP recycled masterbatch, anti-reflective masterbatch, anti-UV masterbatch, hydrostatic masterbatch, and processing aids, mix them evenly, melt extrude to obtain a blended modified material, and then melt spin-spin, draw and lay web, hot roll forming, and rewind and slit the blended modified material to obtain anti-reflective fabric.

Citation Information

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