Thermal-process evaporative crystallization treatment system and method for desulfurization wastewater

By designing a thermal evaporation and crystallization treatment system for desulfurization wastewater and utilizing a sodium carbonate-sodium hydroxide dual alkali softening and multi-effect flash concentration unit, the problem of large steam and water consumption in desulfurization wastewater treatment was solved, the risk of scaling of heat exchange tubes was reduced, and production efficiency was improved.

CN120589840AActive Publication Date: 2025-09-05HUANENG GANSU ENERGY DEVELOPMENT CO LTD 803 BRANCH
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Patent Information

Application Number
CN202511099854.4
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2025-08-07
Publication Date
2025-09-05
Estimated Expiration
2045-08-07

AI Technical Summary

Technical Problem

In the existing desulfurization wastewater treatment process, the treatment steps are independent, resulting in large amounts of steam and water, and easily causing scaling of heat exchange tubes, thereby reducing production efficiency.

Method used

A thermal evaporation and crystallization treatment system for desulfurization wastewater is designed. It uses a sodium carbonate-sodium hydroxide dual-alkali softening device for pretreatment, combined with a multi-effect flash concentration unit and a mechanical steam compression crystallization unit to achieve the recycling of steam and water and reduce the risk of scaling of heat exchange tubes.

Benefits of technology

It reduces the use of steam and water, reduces heat consumption, improves heat exchange efficiency, reduces maintenance frequency, and improves production efficiency.

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Abstract

The system comprises a pretreatment unit, a multi-effect flash evaporation and concentration unit, a mechanical vapor compression and crystallization unit, a thermal evaporation and crystallization unit, a thermal evaporation and crystallization unit, a thermal evaporation and crystallization unit, a thermal evaporation and crystallization unit and a thermal evaporation and crystallization unit, and is characterized in that the multiple-effect flash evaporation and concentration unit is used for producing a concentrated solution from desulfurization wastewater; the mechanical vapor compression crystallization unit is composed of an evaporator, a vapor compressor, a crystallizer and a crystal mush treatment module, and the vapor compressor pressurizes and heats secondary vapor and then conveys the secondary vapor back to the evaporator for secondary utilization; wherein the final steam of the negative pressure flash evaporation module is input into the mechanical steam compression crystallization unit to serve as initial steam, and the condensate water of the negative pressure flash evaporation module is input into the mechanical steam compression crystallization unit to serve as production water. When the system is used, the steam condensate water and the secondary steam of the multi-effect flash evaporation concentration unit are recycled, and the two treatment processes are communicated, so that the steam consumption and the water consumption are reduced, the heat consumption is reduced, and the system is simpler.
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Citation Information

Patent Citations

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