Wall yellowing agent and production method thereof

Abstract

The invention provides a wall yellowing agent and a production method thereof, and relates to the field of wall yellowing agents. The yellowing eliminating agent composition is prepared from the following raw materials: an alkaline neutralizer, a redox agent, a penetrant, a dispersing agent, a water-based solution, tea tree essential oil, organosiloxane, an ethylene glycol compound and sodium percarbonate microcapsules. The sodium percarbonate microcapsules are added in the raw material preparation process, so that the starting time of oxidation reaction can be delayed to 15 minutes, excessive oxidation caused by high-temperature accelerated reaction is avoided, the use efficiency in a high-temperature environment can be effectively improved, and the use is prevented from being influenced; the method has the beneficial effects that preparation and use of raw materials in different environments can be realized, corresponding different yellowing-eliminating agents are selected according to different conditions, the use effect of the yellowing-eliminating agent can be fully exerted, the use defects of a traditional yellowing-eliminating agent are reduced, and the limitation problem is reduced.

Description

Technical Field

[0001] The invention relates to the technical field of wall surface anti-yellowing and anti-yellowing agents, in particular to a wall surface anti-yellowing and anti-yellowing agent and a production method thereof. Background Art

[0002] The wall anti-yellowing agent is a highly efficient and environmentally friendly wall repair material, specifically developed to address issues such as wall yellowing, mildew, and oxidative discoloration. This product utilizes core ingredients such as alkaline neutralizers, redox agents, and organosiloxanes to effectively decompose residual yellowing substances in the wall, adjust the pH value, and form a hydrophobic protective layer on the surface to prevent water vapor penetration and secondary yellowing. The addition of tea tree essential oil provides natural antibacterial and mildew-proof properties, making it suitable for a variety of substrates such as latex paint and putty layers. This anti-yellowing agent boasts strong permeability, long-lasting action, and convenient construction, making it suitable for a variety of scenarios, including homes, offices, and businesses. The water-based, environmentally friendly formula does not affect the aesthetics of the wall after drying. It is suitable for use in humid, high-alkali environments prone to yellowing, helping to restore the whiteness of walls to their new, pristine whiteness and extending the life of decorative elements.

[0003] The wall anti-yellowing and yellowing-eliminating agents in the prior art can eliminate the yellowing of the wall during use, effectively solving the problem of difficult-to-clean anti-yellowing. However, a suitable environment is required during use to effectively use the anti-yellowing agents. For example, in an environment with a relative humidity greater than 85%, the active ingredients of the water-based anti-yellowing agents will hydrolyze and become ineffective prematurely, and the reaction rate will drop by 50% below 5°C. Above 35°C, excessive oxidation may occur, leading to fading of the wall. Therefore, different weather changes in winter in northern my country and summer in southern China will result in different usage effects, so traditional anti-yellowing agents cannot be used efficiently. At the same time, traditional anti-yellowing agents also have a pungent odor during use, which requires operators to take multiple layers of protection during use to solve the pungent odor problem. Summary of the Invention

[0004] (1) Technical problems solved In response to the shortcomings of the existing technology, the present invention provides a wall anti-yellowing and yellowing-eliminating agent and a production method thereof, which solves the problem that traditional yellowing-eliminating agents cannot exert their efficient use effects; at the same time, traditional yellowing-eliminating agents also have a pungent odor when used, resulting in operators needing multiple layers of protection during use to solve the problem of the pungent odor.

[0005] (2) Technical solution To achieve the above objectives, the present invention is implemented through the following technical scheme: a wall anti-yellowing and anti-yellowing agent, the anti-yellowing agent composition comprises the following raw materials: an alkaline neutralizer, an oxidizing-reducing agent, a penetrant, a dispersant, a water-based solution, tea tree essential oil, an organosiloxane, an ethylene glycol compound and sodium percarbonate microcapsules.

[0006] Preferably, the anti-yellowing agent composition comprises the following raw materials in parts by weight: 12 parts of alkaline neutralizer, 8 parts of redox agent, 1 part of penetrant, 1.5 parts of dispersant, 60 parts of water-based solution, 0.3 parts of tea tree essential oil, 5 parts of organosiloxane and 3 parts of ethylene glycol compound.

[0007] Preferably, the anti-yellowing agent composition comprises the following raw materials in parts by weight: 12 parts of alkaline neutralizer, 8 parts of redox agent, 1 part of penetrant, 1.5 parts of dispersant, 60 parts of water-based solution, 0.1 part of tea tree essential oil, 3 parts of organosiloxane and 2 parts of ethylene glycol compound.

[0008] Preferably, the anti-yellowing agent composition comprises the following raw materials in parts by weight: 12 parts of alkaline neutralizer, 8 parts of redox agent, 1 part of penetrant, 1.5 parts of dispersant, 60 parts of water-based solution, 0.2 parts of tea tree essential oil, 4 parts of organosiloxane and 2.5 parts of ethylene glycol compound.

[0009] Preferably, the anti-yellowing agent composition comprises the following raw materials in parts by weight: 12 parts of alkaline neutralizer, 8 parts of redox agent, 1 part of penetrant, 1.5 parts of dispersant, 60 parts of water-based solution, 0.3 parts of tea tree essential oil, 5 parts of organosiloxane and 3 parts of sodium percarbonate microcapsules.

[0010] A method for producing a wall anti-yellowing and anti-yellowing agent comprises the following specific steps: Step 1: Premixing the water-based solution: Heat deionized water to 1% HCl, add the alkaline neutralizer and stir until completely dissolved, and adjust the pH of the system to between 7-8. Step 2: Oxidation system construction: Slowly add the redox agent and maintain a stirring rate of 300 rpm to prevent local high concentrations from triggering side reactions; Step 3: Introduction of ethylene glycol compounds: Ethylene glycol, penetrant, dispersant, organosiloxane, and tea tree essential oil are pre-emulsified and added to the system. Ultrasonic treatment at 20kHz / 5min is performed to improve dispersion uniformity. Step 4: Rheological properties control: Adjust the viscosity to 2000-3000 mPa·s by adding 0.2%-0.5% polyurethane thickener; Step 5: Post-processing: The prepared raw materials will be cooled naturally at a constant temperature, screened through a 500-mesh vibrating screen, and stored by filling and sealing.

[0011] Preferably, the deionized water in step 1 is heated to 35-40°C.

[0012] Preferably, in step 5, the mixture is cooled to 25° C. by natural constant temperature cooling.

[0013] (3) Beneficial effects The present invention provides a wall anti-yellowing agent and a production method thereof. It has the following beneficial effects: 1. The present invention adds tea tree essential oil. During the preparation process, the tea tree essential oil is added to the system after pre-emulsification of organosiloxane and tea tree essential oil to achieve sustained release, and is evenly dispersed to cover chemical odors, thereby improving comfort during use, preventing pungent and unpleasant odors, and affecting the yellowing of the wall surface.

[0014] 2. The present invention adds organic siloxane during the raw material preparation process to form a hydrophobic film, thereby reducing the water vapor permeability and allowing the yellowing agent to maintain stability for 72 hours in an environment with a humidity of 90%. This can effectively improve the use efficiency in a relatively humid environment and prevent the use from being affected.

[0015] 3. The present invention adds ethylene glycol compounds as freezing inhibitors during the raw material preparation process, which can enable the anti-yellowing agent to maintain effective molecular activity in a 0°C environment, avoid incomplete oxidation reaction residues caused by low temperature, and effectively solve the problem of improving usage efficiency in a low-temperature environment and preventing usage from being affected.

[0016] 4. The present invention adds sodium percarbonate microcapsules. By adding sodium percarbonate microcapsules during the raw material preparation process, the start time of the oxidation reaction can be delayed to 15 minutes, thereby avoiding excessive oxidation caused by high temperature accelerated reaction, and effectively improving the use efficiency in a high temperature environment and preventing the use from being affected. This beneficial effect can be combined with beneficial effect 3 to achieve the preparation and use of raw materials in different environments. Different oxidizing agents can be selected according to different situations, which can give full play to the use effect of the oxidizing agent, reduce the defects of the traditional oxidizing agent, and reduce the limitations. DETAILED DESCRIPTION

[0017] The following is a clear and complete description of the technical solutions in the embodiments of the present invention. Obviously, the embodiments described are only some embodiments of the present invention, not all embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without making any creative efforts are within the scope of protection of the present invention.

[0018] Example 1:

[0019] The embodiment of the present invention provides a wall anti-yellowing agent, wherein the anti-yellowing agent composition comprises the following raw materials: an alkaline neutralizer, an oxidizing-reducing agent, a penetrant, a dispersant, a water-based solution, tea tree essential oil, an organosiloxane, an ethylene glycol compound, and sodium percarbonate microcapsules.

[0020] The anti-yellowing agent composition comprises the following raw materials in parts by weight: 12 parts of an alkaline neutralizer, 8 parts of an oxidation-reduction agent, 1 part of a penetrant, 1.5 parts of a dispersant, 60 parts of a water-based solution, 0.3 parts of tea tree essential oil, 5 parts of an organosiloxane, and 3 parts of an ethylene glycol compound.

[0021] A method for producing a wall anti-yellowing and anti-yellowing agent comprises the following specific steps: Step 1: Premixing the water-based solution: Heat deionized water to 40°C, add the alkaline neutralizer and stir until completely dissolved. Adjust the system pH to 8. Step 2: Oxidation system construction: Slowly add the redox agent and maintain a stirring rate of 300 rpm to prevent local high concentrations from triggering side reactions; Step 3: Introduction of ethylene glycol compounds: Ethylene glycol, penetrant, dispersant, organosiloxane, and tea tree essential oil are pre-emulsified and added to the system. Ultrasonic treatment at 20kHz / 5min is performed to improve dispersion uniformity. Step 4: Rheological properties control: Adjust the viscosity to 2000 mPa·s by adding 0.2% polyurethane thickener; Step 5: Post-processing: The prepared raw materials will be naturally cooled to 25°C, screened through a 500-mesh vibrating screen, and stored by filling and sealing.

[0022] Example 2:

[0023] The difference between this embodiment and the first embodiment is that: a wall anti-yellowing agent is provided, and the anti-yellowing agent composition comprises the following raw materials: an alkaline neutralizer, an oxidizing-reducing agent, a penetrant, a dispersant, a water-based solution, tea tree essential oil, an organosiloxane, an ethylene glycol compound, and sodium percarbonate microcapsules. The anti-yellowing agent composition comprises the following raw materials in parts by weight: 12 parts of an alkaline neutralizer, 8 parts of an oxidizing-reducing agent, 1 part of a penetrant, 1.5 parts of a dispersant, 60 parts of a water-based solution, 0.1 part of a tea tree essential oil, 3 parts of an organosiloxane, and 2 parts of an ethylene glycol compound.

[0024] A method for producing a wall anti-yellowing and anti-yellowing agent comprises the following specific steps: Step 1: Premixing the water-based solution: Heat deionized water to 40°C, add the alkaline neutralizer and stir until completely dissolved. Adjust the system pH to 7. Step 2: Oxidation system construction: Slowly add the redox agent and maintain a stirring rate of 300 rpm to prevent local high concentrations from triggering side reactions; Step 3: Introduction of ethylene glycol compounds: Ethylene glycol, penetrant, dispersant, organosiloxane, and tea tree essential oil are pre-emulsified and added to the system. Ultrasonic treatment at 20kHz / 5min is performed to improve dispersion uniformity. Step 4: Rheological properties control: Adjust the viscosity to 3000 mPa·s by adding 0.5% polyurethane thickener; Step 5: Post-processing: The prepared raw materials will be naturally cooled to 25°C, screened through a 500-mesh vibrating screen, and stored by filling and sealing.

[0025] Example 3:

[0026] The difference between this embodiment and the first embodiment is that: a wall anti-yellowing agent, the anti-yellowing agent composition comprises the following raw materials: an alkaline neutralizer, an oxidizing-reducing agent, a penetrant, a dispersant, a water-based solution, tea tree essential oil, an organosiloxane, an ethylene glycol compound and sodium percarbonate microcapsules, and the anti-yellowing agent composition comprises the following raw materials in parts by weight: 12 parts of an alkaline neutralizer, 8 parts of an oxidizing-reducing agent, 1 part of a penetrant, 1.5 parts of a dispersant, 60 parts of a water-based solution, 0.2 parts of a tea tree essential oil, 4 parts of an organosiloxane and 2.5 parts of an ethylene glycol compound.

[0027] A method for producing a wall anti-yellowing and anti-yellowing agent comprises the following specific steps: Step 1: Premixing the water-based solution: Heat deionized water to 35°C, add the alkaline neutralizer and stir until completely dissolved. Adjust the system pH to 8. Step 2: Oxidation system construction: Slowly add the redox agent and maintain a stirring rate of 300 rpm to prevent local high concentrations from triggering side reactions; Step 3: Introduction of ethylene glycol compounds: Ethylene glycol, penetrant, dispersant, organosiloxane, and tea tree essential oil are pre-emulsified and added to the system. Ultrasonic treatment at 20kHz / 5min is performed to improve dispersion uniformity. Step 4: Rheological properties control: Adjust the viscosity to 2000 mPa·s by adding 0.2% polyurethane thickener; Step 5: Post-processing: The prepared raw materials will be naturally cooled to 25°C, screened through a 500-mesh vibrating screen, and stored by filling and sealing.

[0028] Example 4:

[0029] The difference between this embodiment and the first embodiment is that: a wall anti-yellowing agent, the anti-yellowing agent composition comprises the following raw materials: an alkaline neutralizer, an oxidizing-reducing agent, a penetrant, a dispersant, a water-based solution, tea tree essential oil, an organosiloxane, an ethylene glycol compound and sodium percarbonate microcapsules, and the anti-yellowing agent composition comprises the following raw materials in parts by weight: 12 parts of the alkaline neutralizer, 8 parts of the oxidizing-reducing agent, 1 part of the penetrant, 1.5 parts of the dispersant, 60 parts of the water-based solution, 0.3 parts of the tea tree essential oil, 5 parts of the organosiloxane and 3 parts of the sodium percarbonate microcapsules.

[0030] A method for producing a wall anti-yellowing and anti-yellowing agent comprises the following specific steps: Step 1: Premixing the water-based solution: Heat deionized water to 35°C, add the alkaline neutralizer and stir until completely dissolved. Adjust the system pH to 7. Step 2: Oxidation system construction: Slowly add the redox agent and maintain a stirring rate of 300 rpm to prevent local high concentrations from triggering side reactions; Step 3: Introduction of Sodium Percarbonate Microcapsules: Pre-emulsify the sodium percarbonate microcapsules, penetrant, dispersant, organosiloxane, and tea tree essential oil and add them to the system. Ultrasonic treatment at 20kHz / 5min is then performed to improve dispersion uniformity. Step 4: Rheological properties control: Adjust the viscosity to 3000 mPa·s by adding 0.5% polyurethane thickener; Step 5: Post-processing: The prepared raw materials will be naturally cooled to 25°C, screened through a 500-mesh vibrating screen, and stored by filling and sealing.

[0031] Comparative Example: This embodiment of the present invention provides a wall anti-yellowing agent, comprising the following raw materials: an alkaline neutralizer, a redox agent, a penetrant, a dispersant, a water-based solution, tea tree essential oil, an organosiloxane, an ethylene glycol compound, and sodium percarbonate microcapsules. The anti-yellowing agent composition comprises the following raw materials, in parts by weight: 12 parts alkaline neutralizer, 8 parts redox agent, 1 part penetrant, 1.5 parts dispersant, 60 parts water-based solution, 0.3 parts tea tree essential oil, 5 parts organosiloxane, and 3 parts ethylene glycol compound.

[0032] The wall anti-yellowing and yellowing-eliminating agents prepared in Example 1, Example 2, Example 3, Example 4 and the comparative example were used respectively, and the conditions during use were recorded. The results are shown in Table 1:

[0033] It can be seen from Table 1 that the addition of different tea tree essential oils, organosiloxanes, ethylene glycol compounds and sodium percarbonate microcapsule raw materials in Example 1, Example 2, Example 3 and Example 4 has a better effect on the preparation of the wall anti-yellowing and yellowing agent.

[0034] While embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that various changes, modifications, substitutions, and variations may be made to these embodiments without departing from the principles and spirit of the invention, and that the scope of the invention is defined by the appended claims and their equivalents.

Claims

1. A wall anti-yellowing and anti-yellowing agent, characterized by: The anti-yellowing agent composition comprises the following raw materials: 12 parts of an alkaline neutralizer, 8 parts of an oxidation-reduction agent, 1 part of a penetrant, 1.5 parts of a dispersant, 60 parts of a water-based solution, 0.3-0.1 parts of tea tree essential oil, 5-3 parts of an organosiloxane, 3-2 parts of an ethylene glycol compound and 3 parts of sodium percarbonate microcapsules.

2. The wall anti-yellowing and yellowing agent according to claim 1, characterized in that: The anti-yellowing agent composition comprises the following raw materials in parts by weight: 12 parts of an alkaline neutralizer, 8 parts of an oxidation-reduction agent, 1 part of a penetrant, 1.5 parts of a dispersant, 60 parts of a water-based solution, 0.3 parts of tea tree essential oil, 5 parts of an organosiloxane, and 3 parts of an ethylene glycol compound.

3. The wall anti-yellowing and yellowing agent according to claim 1, characterized in that: The anti-yellowing agent composition comprises the following raw materials in parts by weight: 12 parts of an alkaline neutralizer, 8 parts of an oxidation-reduction agent, 1 part of a penetrant, 1.5 parts of a dispersant, 60 parts of a water-based solution, 0.1 parts of tea tree essential oil, 3 parts of an organosiloxane, and 2 parts of an ethylene glycol compound.

4. The wall anti-yellowing and anti-yellowing agent according to claim 1, characterized in that: The anti-yellowing agent composition comprises the following raw materials in parts by weight: 12 parts of an alkaline neutralizer, 8 parts of an oxidation-reduction agent, 1 part of a penetrant, 1.5 parts of a dispersant, 60 parts of a water-based solution, 0.2 parts of tea tree essential oil, 4 parts of an organosiloxane, and 2.5 parts of an ethylene glycol compound.

5. The wall anti-yellowing and yellowing agent according to claim 1, characterized in that: The anti-yellowing agent composition comprises the following raw materials in parts by weight: 12 parts of an alkaline neutralizer, 8 parts of an oxidation-reduction agent, 1 part of a penetrant, 1.5 parts of a dispersant, 60 parts of a water-based solution, 0.3 parts of tea tree essential oil, 5 parts of an organosiloxane, and 3 parts of sodium percarbonate microcapsules.

6. A method for producing a wall anti-yellowing and anti-yellowing agent, based on the wall anti-yellowing and anti-yellowing agent according to any one of claims 1 to 5, characterized in that: The specific steps include: Step 1: Premixing the water-based solution: Heat deionized water to 1% HCl, add the alkaline neutralizer and stir until completely dissolved, and adjust the pH of the system to between 7-8. Step 2: Oxidation system construction: Slowly add the redox agent and maintain a stirring rate of 300 rpm to prevent local high concentrations from triggering side reactions; Step 3: Introduction of ethylene glycol compounds: Ethylene glycol, penetrant, dispersant, organosiloxane, and tea tree essential oil are pre-emulsified and added to the system. Ultrasonic treatment at 20kHz / 5min is performed to improve dispersion uniformity. Step 4: Rheological properties control: Adjust the viscosity to 2000-3000 mPa·s by adding 0.2%-0.5% polyurethane thickener; Step 5: Post-processing: The prepared raw materials will be cooled naturally at a constant temperature, screened through a 500-mesh vibrating screen, and stored by filling and sealing.

7. The method for producing a wall anti-yellowing and yellowing eliminating agent according to claim 1, wherein: The deionized water in step 1 is heated to 35-40°C.

8. The method for producing a wall anti-yellowing and yellowing eliminating agent according to claim 1, wherein: In the step 5, the mixture is cooled to 25° C. by natural constant temperature cooling.

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