Energy-saving window film, preparation method and application

Abstract

The invention belongs to the technical field of window films, and discloses an energy-saving window film, a preparation method and application. According to the energy-saving window film, solvent-free EB glue is adopted, EB covering film curing is adopted, VOC emission is avoided, the national green and environment-friendly requirements are met, and compared with traditional oven thermosetting, energy consumption is reduced, and production efficiency can be improved. The EB heat insulation coating is adopted, supercritical carbon dioxide fluid spraying equipment is used for spraying, the use amount of a solvent can be reduced, VOC emission is reduced, energy consumption is reduced, EB is used for curing, a photoinitiator does not need to be added, and the influence of photoinitiator micromolecule residues and residual free radicals on the heat insulation function is reduced; the same quality as 3M, longham, Weiguo and other foreign brands can be achieved, and even superior to the 3M, longham and Weiguo. Moreover, the EB heat insulation coating and the EB glue are cured at the same time at a time and are initiated at home and abroad, and the production line speed can be increased to 80 m / min to 100 m / min and is increased by more than two times compared with the speed of 30 m / min of a traditional thermosetting process.

Description

Technical Field

[0001] The present invention relates to the technical field of window films, in particular to an energy-saving window film, a preparation method and applications. Background Art

[0002] At present, the curing process of the hardened coating of window film is UV curing. UV curing requires a photoinitiator to absorb ultraviolet light and release free radicals to initiate curing. Excellent weather resistance requires the addition of more ultraviolet absorbers and ultraviolet stabilizers. If too much ultraviolet absorber and ultraviolet stabilizer is added, the hardened coating will not be completely cured during UV curing and will not meet the hardness requirements. If it is changed to a thermosetting process, the production efficiency will be very low due to the long thermosetting time, and the hardness of the hardened coating will be low. These problems cannot be solved by the thermosetting process. There is an urgent need for a production process to replace UV and thermosetting to achieve both high production efficiency and meet the hardness and weather resistance requirements.

[0003] Automotive window film has evolved from its first generation to its fifth generation, becoming an essential component of every car. While the domestic market is rife with domestic automotive window film brands, they often operate at a low price point with a short lifespan, resulting in little customer acceptance. Foreign companies like 3M, LLumar, and V-KOOL dominate the market, leaving virtually no domestic automotive window film manufacturers comparable to established brands like 3M, LLumar, and V-KOOL.

[0004] The process used for the surface hardening coating of automobile window films is also UV curing. UV curing requires the addition of photoinitiators, which results in small molecules remaining in the surface hardening coating, thereby affecting the heat insulation effect of the surface hardening coating. There is an urgent need for a production process to replace UV to avoid small molecule residues. Summary of the Invention

[0005] The object of the present invention is to provide a method for preparing an energy-saving window film, which can provide excellent weather resistance, 100% blocking of infrared bands, 100% blocking of ultraviolet bands, and long-term high-efficiency blocking of ultraviolet and infrared rays.

[0006] In the first aspect, the present invention provides an energy-saving window film material, including a substrate, a backing glue and a release film, and a top coating layer. The backing glue is coated on the lower surface of the substrate, the release film is covered on the backing glue surface, and the top coating layer is coated on the upper surface of the substrate. The top coating layer and the backing glue are both cured by EB, the backing glue is slit coated, and the top coating layer is sprayed using supercritical spraying equipment.

[0007] In some embodiments, the back glue is coated on the lower surface of the substrate, the release film is covered on the back glue surface, and the top coating is coated on the upper surface of the substrate. The back glue uses EB glue, and the top coating uses EB thermal insulation coating. The EB glue and EB thermal insulation coating are both cured and formed using EB in one step.

[0008] In certain embodiments, the substrate is PET In some embodiments, the release film is a fluorine release film or a silicone release film.

[0009] In certain embodiments, the EB glue comprises, by weight: 10-70 parts of acrylate monomer, 10-50 parts of acrylate resin, 0.1-10 parts of ultraviolet light absorber, 0.1-10 parts of light stabilizer, and 0.1-10 parts of antioxidant.

[0010] In certain embodiments, the acrylate monomer is o-phenylphenoxyethyl acrylate, phenoxyethyl acrylate, ethoxyethoxyethyl acrylate, lauryl alcohol acrylate, stearyl alcohol acrylate, benzyl acrylate, ethoxylated o-phenylphenoxy acrylate, ethoxylated nonylphenol acrylate, propoxylated nonylphenol acrylate, ethoxylated propoxylated nonylphenol acrylate, cyclotrimethylolpropane formal acrylate, ethoxylated phenoxy acrylate, propoxylated phenoxy acrylate, isobornyl acrylate, cyclohexyl propionate, (2-ethyl-2-methyl-1,3-dioxolan-4-yl) acrylate, cyclohexyl-2-(1,3-dioxolan-4-yl) acrylate, 1-adamantyl methacrylate, γ-butyrolactone acrylate, γ-butyrolactone methacrylate, 4-tert-butylcyclohexyl acrylate, m-phenoxybenzyl methacrylate, dicyclopentenyl acrylate, dicyclopentenyl ethoxylated acrylate, 3,3,5-trimethylcyclohexyl acrylate, tetrahydrofurfuryl acrylate, dicyclopentenyl ethoxylated methacrylate, 2-phenoxyethyl methacrylate, tetrahydrofurfuryl methacrylate, isobornyl methacrylate, cyclohexyl methacrylate, benzyl methacrylate; the acrylate resin is any one of epoxy acrylate, polyurethane acrylate, polyester acrylate, pure acrylate, organic-inorganic hybrid resin, or a combination of two or more thereof; the ultraviolet light absorber is BASF Tinuvin The light stabilizer is any one of BASF's Tinuvin 622, Tinuvin 770, Tinuvin 326, and Tinuvin 234; and the antioxidant is any one of BASF's Irganox 1010, Irganox 1076, Irganox 1098, and Irganox B215.

[0011] In certain embodiments, the EB thermal insulation coating comprises, by weight: 10-50 parts of acrylate resin, 10-30 parts of heat insulation auxiliary agent, 10-40 parts of solvent, 0.1-10 parts of antioxidant, and 0.01-0.1 parts of leveling agent.

[0012] In some embodiments, the acrylate resin is any one of epoxy acrylate, polyurethane acrylate, polyester acrylate, pure acrylate, and organic-inorganic hybrid resin, or a combination of two or more thereof; the thermal insulation additive is any one of indium tin oxide dispersion, antimony tin oxide dispersion, and tungsten oxide dispersion; the solvent is one of ethyl acetate, butyl acetate, propylene glycol methyl ether, and isopropyl alcohol, or a combination of two or more thereof; the leveling agent is any one of BYK333, BYK353, BYK356, BYK359, and BYK361N; and the antioxidant is any one of BASF's Irganox1010, Irganox1076, Irganox1098, and Irganox B215.

[0013] Secondly, the present invention also provides a method for preparing an energy-saving window film, wherein the method is carried out in two steps: S1: Apply EB glue to the lower surface of the substrate and cover with release film; S2: Apply EB thermal insulation coating to the surface of the substrate, evaporate the solvent in an oven, use EB to cure, and cure the thermal insulation coating and EB glue into shape at one time.

[0014] In certain embodiments, the EB glue is applied to the lower surface of the substrate with a coating thickness of 10-50 microns; The EB thermal insulation coating is sprayed onto the upper surface of the substrate using a supercritical carbon dioxide fluid spraying device, with a coating thickness of 10-50 microns, an EB voltage of 100kv-250kv, and a dosage of 10-100kgy.

[0015] Finally, the present invention also provides an application of the energy-saving window film, which is applied to automobile windows and building windows.

[0016] The advantages and beneficial effects of the present invention are: The energy-saving window film of the present invention adopts solvent-free EB glue, uses EB coating and curing, has no VOC emissions, meets the national green environmental protection requirements, and compared with traditional oven thermal curing, reduces energy consumption and improves production efficiency.

[0017] Using EB thermal insulation coating and spraying it with supercritical carbon dioxide fluid spraying equipment can reduce solvent usage, reduce VOC emissions, and reduce energy consumption. Using EB curing, there is no need to add photoinitiators, which reduces the impact of small molecule residues and residual free radicals of photoinitiators on thermal insulation function, achieving the same quality as foreign brands such as 3M, LLumar, and V-KOOL, or even better than them.

[0018] Moreover, EB thermal insulation coating and EB glue are cured simultaneously at one time, which is a domestic and international first. The production line speed can be increased to 80m / min-100m / min, more than twice the speed of 30m / min of the traditional thermosetting process. DETAILED DESCRIPTION

[0019] The technical solutions provided by the present invention are described in detail below with reference to the examples, but they should not be construed as limiting the scope of protection of the present invention. Unless otherwise specified, the materials and reagents used in the following examples can be obtained from commercial sources.

[0020] The names of the compounds used in the following examples (the following compounds are all commercially available raw materials): BR-3042: Aromatic polyurethane acrylate from BOMAR; BR-344: Aliphatic polyurethane acrylate from BOMAR; BR-3641AA: Aliphatic polyurethane acrylate from BOMAR; BR-3641AJ: Aliphatic polyurethane acrylate from BOMAR; BR-374: Aliphatic polyurethane acrylate from BOMAR; BR-3741AJ: Aliphatic polyurethane acrylate from BOMAR; BR-3747AE: Aliphatic polyurethane acrylate from BOMAR; BR-543: Aromatic polyurethane acrylate from BOMAR; TBCHA: 4-tert-butylcyclohexyl acrylate; TMCHA: 3,3,5-trimethylcyclohexyl acrylate; CTFA: Cyclotrimethylolpropane formal acrylate; BASF's UV absorbers Tinuvin 477 and Tinuvin 1600; BASF's light stabilizer Tinuvin 770; BASF's antioxidants Irganox 1010 and Irganox 1076; BDT-1006: BOMAR's thioether hyperbranched acrylate; ES-6768: Shanghai Beiyue Polymer Materials Co., Ltd.; 6170: Changxing Materials Industry Co., Ltd.; MP5163: Guangdong Haohui New Materials Co., Ltd.; GU9315Z: Guojing Chemical Co., Ltd.; 6150-100: Changxing Materials Industry Co., Ltd. HDDA: 1,6-hexanediol diacrylate; PM: propylene glycol methyl ether; BASF's UV absorbers Tinuvin 477 and Tinuvin 1600; BASF's light stabilizer Tinuvin 770; BASF's antioxidants Irganox 1010 and Irganox 1076; leveling agent BYK 333; infrared blocking additive indium tin oxide paste - Shanghai Huzheng G-P35-EA Example 1 A basic energy-saving window film comprises a substrate, an adhesive backing, a release film, and a topcoat. The adhesive backing is applied to the lower surface of the substrate, the release film is applied to the adhesive backing, and the topcoat is applied to the upper surface of the substrate. The substrate can be any roll material. In this embodiment, the substrate is PET, the adhesive backing is EB glue, and the topcoat is EB thermal insulation coating. The preparation method comprises the following steps: S1: First, prepare EB glue, including the following steps: In a heating kettle, add 10 kg of BR-3042, 87 kg of TBCHA, 0.5 kg of Tinuvin 477, 0.5 kg of Tinuvin 1600, 0.5 kg of Tinuvin 770 and 0.5 kg of Irganox 1010, set the temperature to 60 degrees and stir for 1 hour to obtain EB glue, which is then slit-coated onto the lower surface of the PET substrate with a coating thickness of 10 microns. At the same time, cover with a fluorine release film at a line speed of 80 m / min.

[0021] S2: Preparation of EB thermal insulation coating: In a heating kettle, 30 kg of BDT-1006, 30 kg of HDDA, 10 kg of PM, 29.5 kg of G-P35-EA, 0.1 kg of Tinuvin 477, 0.1 kg of Tinuvin 1600, 0.1 kg of Tinuvin 770, 0.1 kg of Irganox 1010 and 0.1 kg of BYK 333 were added, the temperature was set to 60 degrees and stirred for 1 hour to obtain EB thermal insulation coating, and the EB thermal insulation coating was sprayed onto the upper surface of the substrate using supercritical carbon dioxide fluid equipment with a coating thickness of 10 microns, a line speed of 80 m / min, an oven temperature of 120°C, an EB voltage of 200 kV, and a dosage of 80 kgy. The EB glue and EB thermal insulation coating were cured at one time to obtain an energy-saving and thermal insulation window film.

[0022] Example 2: A basic energy-saving window film comprises a substrate, an adhesive backing, a release film, and a topcoat. The adhesive backing is applied to the lower surface of the substrate, the release film is applied to the adhesive backing, and the topcoat is applied to the upper surface of the substrate. The substrate can be any roll material. In this embodiment, the substrate is PET, the adhesive backing is EB glue, and the topcoat is EB thermal insulation coating. The preparation method comprises the following steps: S1: First, prepare EB glue, including the following steps: In a heating kettle, add 10 kg of BR-344, 87 kg of TBCHA, 0.5 kg of Tinuvin 477, 0.5 kg of Tinuvin 1600, 0.5 kg of Tinuvin 770 and 0.5 kg of Irganox 1010. Set the temperature to 60 degrees and stir for 1 hour to obtain EB glue. The EB glue is slit-coated on the lower surface of the PET substrate with a coating thickness of 10 microns. At the same time, it is covered with a fluorine release film at a line speed of 80 m / min.

[0023] S2: Preparation of EB thermal insulation coating: In a heating kettle, 30 kg of BDT-1006, 30 kg of HDDA, 10 kg of PM, 29.5 kg of G-P35-EA, 0.1 kg of Tinuvin 477, 0.1 kg of Tinuvin 1600, 0.1 kg of Tinuvin 770, 0.1 kg of Irganox 1010 and 0.1 kg of BYK 333 were added, the temperature was set to 60 degrees and stirred for 1 hour to obtain EB thermal insulation coating, and the EB thermal insulation coating was sprayed onto the upper surface of the substrate using supercritical carbon dioxide fluid equipment with a coating thickness of 10 microns, a line speed of 80 m / min, an oven temperature of 120°C, an EB voltage of 200 kV, and a dosage of 80 kgy. The EB glue and EB thermal insulation coating were cured at one time to obtain an energy-saving and thermal insulation window film.

[0024] Example 3: A basic energy-saving window film comprises a substrate, an adhesive backing, a release film, and a topcoat. The adhesive backing is applied to the lower surface of the substrate, the release film is applied to the adhesive backing, and the topcoat is applied to the upper surface of the substrate. The substrate can be any roll material. In this embodiment, the substrate is PET, the adhesive backing is EB glue, and the topcoat is EB thermal insulation coating. The preparation method comprises the following steps: S1: First, prepare EB glue, including the following steps: In a heating kettle, add 10 kg of BR-3641AA, 87 kg of TBCHA, 0.5 kg of Tinuvin 477, 0.5 kg of Tinuvin 1600, 0.5 kg of Tinuvin 770 and 0.5 kg of Irganox 1010. Set the temperature to 60 degrees and stir for 1 hour to obtain EB glue. The EB glue is slit-coated on the lower surface of the PET substrate with a coating thickness of 10 microns. At the same time, cover it with a fluorine release film at a line speed of 80 m / min.

[0025] S2: Preparation of EB thermal insulation coating: In a heating kettle, 30 kg of BDT-1006, 30 kg of HDDA, 10 kg of PM, 29.5 kg of G-P35-EA, 0.1 kg of Tinuvin 477, 0.1 kg of Tinuvin 1600, 0.1 kg of Tinuvin 770, 0.1 kg of Irganox 1010 and 0.1 kg of BYK 333 were added, the temperature was set to 60 degrees and stirred for 1 hour to obtain EB thermal insulation coating, and the EB thermal insulation coating was sprayed onto the upper surface of the substrate using supercritical carbon dioxide fluid equipment with a coating thickness of 10 microns, a line speed of 80 m / min, an oven temperature of 120°C, an EB voltage of 200 kV, and a dosage of 80 kgy. The EB glue and EB thermal insulation coating were cured at one time to obtain an energy-saving and thermal insulation window film.

[0026] Example 4: A basic energy-saving window film comprises a substrate, an adhesive backing, a release film, and a topcoat. The adhesive backing is applied to the lower surface of the substrate, the release film is applied to the adhesive backing, and the topcoat is applied to the upper surface of the substrate. The substrate can be any roll material. In this embodiment, the substrate is PET, the adhesive backing is EB glue, and the topcoat is EB thermal insulation coating. The preparation method comprises the following steps: S1: First, prepare EB glue, including the following steps: In a heating kettle, add 10 kg of BR-3641AJ, 87 kg of TBCHA, 0.5 kg of Tinuvin 477, 0.5 kg of Tinuvin 1600, 0.5 kg of Tinuvin 770 and 0.5 kg of Irganox 1010. Set the temperature to 60 degrees and stir for 1 hour to obtain EB glue. The EB glue is slit-coated on the lower surface of the PET substrate with a coating thickness of 10 microns. At the same time, it is covered with a fluorine release film at a line speed of 80 m / min.

[0027] S2: Preparation of EB thermal insulation coating: In a heating kettle, 30 kg of BDT-1006, 30 kg of HDDA, 10 kg of PM, 29.5 kg of G-P35-EA, 0.1 kg of Tinuvin 477, 0.1 kg of Tinuvin 1600, 0.1 kg of Tinuvin 770, 0.1 kg of Irganox 1010 and 0.1 kg of BYK 333 were added, the temperature was set to 60 degrees and stirred for 1 hour to obtain EB thermal insulation coating, and the EB thermal insulation coating was sprayed onto the upper surface of the substrate using supercritical carbon dioxide fluid equipment with a coating thickness of 10 microns, a line speed of 80 m / min, an oven temperature of 120°C, an EB voltage of 200 kV, and a dosage of 80 kgy. The EB glue and EB thermal insulation coating were cured at one time to obtain an energy-saving and thermal insulation window film.

[0028] Example 5: A basic energy-saving window film comprises a substrate, an adhesive backing, a release film, and a topcoat. The adhesive backing is applied to the lower surface of the substrate, the release film is applied to the adhesive backing, and the topcoat is applied to the upper surface of the substrate. The substrate can be any roll material. In this embodiment, the substrate is PET, the adhesive backing is EB glue, and the topcoat is EB thermal insulation coating. The preparation method comprises the following steps: S1: First, prepare EB glue, including the following steps: In a heating kettle, add 10 kg of BR-374, 87 kg of TBCHA, 0.5 kg of Tinuvin 477, 0.5 kg of Tinuvin 1600, 0.5 kg of Tinuvin 770 and 0.5 kg of Irganox 1010. Set the temperature to 60 degrees and stir for 1 hour to obtain EB glue. The EB glue is slit-coated on the lower surface of the PET substrate with a coating thickness of 10 microns. At the same time, cover it with a fluorine release film at a line speed of 80 m / min.

[0029] S2: Preparation of EB thermal insulation coating: In a heating kettle, 30 kg of BDT-1006, 30 kg of HDDA, 10 kg of PM, 29.5 kg of G-P35-EA, 0.1 kg of Tinuvin 477, 0.1 kg of Tinuvin 1600, 0.1 kg of Tinuvin 770, 0.1 kg of Irganox 1010 and 0.1 kg of BYK 333 were added, the temperature was set to 60 degrees and stirred for 1 hour to obtain EB thermal insulation coating, and the EB thermal insulation coating was sprayed onto the upper surface of the substrate using supercritical carbon dioxide fluid equipment with a coating thickness of 10 microns, a line speed of 80 m / min, an oven temperature of 120°C, an EB voltage of 200 kV, and a dosage of 80 kgy. The EB glue and EB thermal insulation coating were cured at one time to obtain an energy-saving and thermal insulation window film.

[0030] Example 6: A basic energy-saving window film comprises a substrate, an adhesive backing, a release film, and a topcoat. The adhesive backing is applied to the lower surface of the substrate, the release film is applied to the adhesive backing, and the topcoat is applied to the upper surface of the substrate. The substrate can be any roll material. In this embodiment, the substrate is PET, the adhesive backing is EB glue, and the topcoat is EB thermal insulation coating. The preparation method comprises the following steps: S1: First, prepare EB glue, including the following steps: In a heating kettle, add 10 kg of BR-3741AJ, 87 kg of TBCHA, 0.5 kg of Tinuvin 477, 0.5 kg of Tinuvin 1600, 0.5 kg of Tinuvin 770 and 0.5 kg of Irganox 1010. Set the temperature to 60 degrees and stir for 1 hour to obtain EB glue. The EB glue is slit-coated on the lower surface of the PET substrate with a coating thickness of 10 microns. At the same time, cover it with a fluorine release film at a line speed of 80 m / min.

[0031] S2: Preparation of EB thermal insulation coating: In a heating kettle, 30 kg of BDT-1006, 30 kg of HDDA, 10 kg of PM, 29.5 kg of G-P35-EA, 0.1 kg of Tinuvin 477, 0.1 kg of Tinuvin 1600, 0.1 kg of Tinuvin 770, 0.1 kg of Irganox 1010 and 0.1 kg of BYK 333 were added, the temperature was set to 60 degrees and stirred for 1 hour to obtain EB thermal insulation coating, and the EB thermal insulation coating was sprayed onto the upper surface of the substrate using supercritical carbon dioxide fluid equipment with a coating thickness of 10 microns, a line speed of 80 m / min, an oven temperature of 120°C, an EB voltage of 200 kV, and a dosage of 80 kgy. The EB glue and EB thermal insulation coating were cured at one time to obtain an energy-saving and thermal insulation window film.

[0032] Example 7: A basic energy-saving window film comprises a substrate, an adhesive backing, a release film, and a topcoat. The adhesive backing is applied to the lower surface of the substrate, the release film is applied to the adhesive backing, and the topcoat is applied to the upper surface of the substrate. The substrate can be any roll material. In this embodiment, the substrate is PET, the adhesive backing is EB glue, and the topcoat is EB thermal insulation coating. The preparation method comprises the following steps: S1: First, prepare EB glue, including the following steps: In a heating kettle, add 10 kg of BR-3747AE, 87 kg of TBCHA, 0.5 kg of Tinuvin 477, 0.5 kg of Tinuvin 1600, 0.5 kg of Tinuvin 770 and 0.5 kg of Irganox 1010. Set the temperature to 60 degrees and stir for 1 hour to obtain EB glue. The EB glue is slit-coated on the lower surface of the PET substrate with a coating thickness of 10 microns. At the same time, cover it with a fluorine release film at a line speed of 80 m / min.

[0033] S2: Preparation of EB thermal insulation coating: In a heating kettle, 30 kg of BDT-1006, 30 kg of HDDA, 10 kg of PM, 29.5 kg of G-P35-EA, 0.1 kg of Tinuvin 477, 0.1 kg of Tinuvin 1600, 0.1 kg of Tinuvin 770, 0.1 kg of Irganox 1010 and 0.1 kg of BYK 333 were added, the temperature was set to 60 degrees and stirred for 1 hour to obtain EB thermal insulation coating, and the EB thermal insulation coating was sprayed onto the upper surface of the substrate using supercritical carbon dioxide fluid equipment with a coating thickness of 10 microns, a line speed of 80 m / min, an oven temperature of 120°C, an EB voltage of 200 kV, and a dosage of 80 kgy. The EB glue and EB thermal insulation coating were cured at one time to obtain an energy-saving and thermal insulation window film.

[0034] Example 8: A basic energy-saving window film comprises a substrate, an adhesive backing, a release film, and a topcoat. The adhesive backing is applied to the lower surface of the substrate, the release film is applied to the adhesive backing, and the topcoat is applied to the upper surface of the substrate. The substrate can be any roll material. In this embodiment, the substrate is PET, the adhesive backing is EB glue, and the topcoat is EB thermal insulation coating. The preparation method comprises the following steps: S1: First, prepare EB glue, including the following steps: In a heating kettle, add 10 kg of BR-543, 87 kg of TBCHA, 0.5 kg of Tinuvin 477, 0.5 kg of Tinuvin 1600, 0.5 kg of Tinuvin 770 and 0.5 kg of Irganox 1010. Set the temperature to 60 degrees and stir for 1 hour to obtain EB glue. The EB glue is slit-coated on the lower surface of the PET substrate with a coating thickness of 10 microns. At the same time, it is covered with a fluorine release film at a line speed of 80 m / min.

[0035] S2: Preparation of EB thermal insulation coating: In a heating kettle, 30 kg of BDT-1006, 30 kg of HDDA, 10 kg of PM, 29.5 kg of G-P35-EA, 0.1 kg of Tinuvin 477, 0.1 kg of Tinuvin 1600, 0.1 kg of Tinuvin 770, 0.1 kg of Irganox 1010 and 0.1 kg of BYK 333 were added, the temperature was set to 60 degrees and stirred for 1 hour to obtain EB thermal insulation coating, and the EB thermal insulation coating was sprayed onto the upper surface of the substrate using supercritical carbon dioxide fluid equipment with a coating thickness of 10 microns, a line speed of 80 m / min, an oven temperature of 120°C, an EB voltage of 200 kV, and a dosage of 80 kgy. The EB glue and EB thermal insulation coating were cured at one time to obtain an energy-saving and thermal insulation window film.

[0036] Example 9 A basic energy-saving window film comprises a substrate, an adhesive backing, a release film, and a topcoat. The adhesive backing is applied to the lower surface of the substrate, the release film is applied to the adhesive backing, and the topcoat is applied to the upper surface of the substrate. The substrate can be any roll material. In this embodiment, the substrate is PET, the adhesive backing is EB glue, and the topcoat is EB thermal insulation coating. The preparation method comprises the following steps: S1: First, prepare EB glue, including the following steps: In a heating kettle, add 10 kg of BR-3042, 87 kg of TMCHA, 0.5 kg of Tinuvin 477, 0.5 kg of Tinuvin 1600, 0.5 kg of Tinuvin 770 and 0.5 kg of Irganox 1010. Set the temperature to 60 degrees and stir for 1 hour to obtain EB glue. The EB glue is slit-coated on the lower surface of the PET substrate with a coating thickness of 10 microns. At the same time, cover it with a fluorine release film at a line speed of 80 m / min.

[0037] S2: Preparation of EB thermal insulation coating: In a heating kettle, 30 kg of BDT-1006, 30 kg of HDDA, 10 kg of PM, 29.5 kg of G-P35-EA, 0.1 kg of Tinuvin 477, 0.1 kg of Tinuvin 1600, 0.1 kg of Tinuvin 770, 0.1 kg of Irganox 1010 and 0.1 kg of BYK 333 were added, the temperature was set to 60 degrees and stirred for 1 hour to obtain EB thermal insulation coating, and the EB thermal insulation coating was sprayed onto the upper surface of the substrate using supercritical carbon dioxide fluid equipment with a coating thickness of 10 microns, a line speed of 80 m / min, an oven temperature of 120°C, an EB voltage of 200 kV, and a dosage of 80 kgy. The EB glue and EB thermal insulation coating were cured at one time to obtain an energy-saving and thermal insulation window film.

[0038] Example 10: A basic energy-saving window film comprises a substrate, an adhesive backing, a release film, and a topcoat. The adhesive backing is applied to the lower surface of the substrate, the release film is applied to the adhesive backing, and the topcoat is applied to the upper surface of the substrate. The substrate can be any roll material. In this embodiment, the substrate is PET, the adhesive backing is EB glue, and the topcoat is EB thermal insulation coating. The preparation method comprises the following steps: S1: First, prepare EB glue, including the following steps: In a heating kettle, add 10 kg of BR-344, 87 kg of TMCHA, 0.5 kg of Tinuvin 477, 0.5 kg of Tinuvin 1600, 0.5 kg of Tinuvin 770 and 0.5 kg of Irganox 1010. Set the temperature to 60 degrees and stir for 1 hour to obtain EB glue. The EB glue is slit-coated on the lower surface of the PET substrate with a coating thickness of 10 microns. At the same time, it is covered with a fluorine release film at a line speed of 80 m / min.

[0039] S2: Preparation of EB thermal insulation coating: In a heating kettle, 30 kg of BDT-1006, 30 kg of HDDA, 10 kg of PM, 29.5 kg of G-P35-EA, 0.1 kg of Tinuvin 477, 0.1 kg of Tinuvin 1600, 0.1 kg of Tinuvin 770, 0.1 kg of Irganox 1010 and 0.1 kg of BYK 333 were added, the temperature was set to 60 degrees and stirred for 1 hour to obtain EB thermal insulation coating, and the EB thermal insulation coating was sprayed onto the upper surface of the substrate using supercritical carbon dioxide fluid equipment with a coating thickness of 10 microns, a line speed of 80 m / min, an oven temperature of 120°C, an EB voltage of 200 kV, and a dosage of 80 kgy. The EB glue and EB thermal insulation coating were cured at one time to obtain an energy-saving and thermal insulation window film.

[0040] Example 11: A basic energy-saving window film comprises a substrate, an adhesive backing, a release film, and a topcoat. The adhesive backing is applied to the lower surface of the substrate, the release film is applied to the adhesive backing, and the topcoat is applied to the upper surface of the substrate. The substrate can be any roll material. In this embodiment, the substrate is PET, the adhesive backing is EB glue, and the topcoat is EB thermal insulation coating. The preparation method comprises the following steps: S1: First, prepare EB glue, including the following steps: In a heating kettle, add 10 kg of BR-3641AA, 87 kg of TMCHA, 0.5 kg of Tinuvin 477, 0.5 kg of Tinuvin 1600, 0.5 kg of Tinuvin 770 and 0.5 kg of Irganox 1010. Set the temperature to 60 degrees and stir for 1 hour to obtain EB glue. The EB glue is slit-coated on the lower surface of the PET substrate with a coating thickness of 10 microns. At the same time, it is covered with a fluorine release film at a line speed of 80 m / min.

[0041] S2: Preparation of EB thermal insulation coating: In a heating kettle, 30 kg of BDT-1006, 30 kg of HDDA, 10 kg of PM, 29.5 kg of G-P35-EA, 0.1 kg of Tinuvin 477, 0.1 kg of Tinuvin 1600, 0.1 kg of Tinuvin 770, 0.1 kg of Irganox 1010 and 0.1 kg of BYK 333 were added, the temperature was set to 60 degrees and stirred for 1 hour to obtain EB thermal insulation coating, and the EB thermal insulation coating was sprayed onto the upper surface of the substrate using supercritical carbon dioxide fluid equipment with a coating thickness of 10 microns, a line speed of 80 m / min, an oven temperature of 120°C, an EB voltage of 200 kV, and a dosage of 80 kgy. The EB glue and EB thermal insulation coating were cured at one time to obtain an energy-saving and thermal insulation window film.

[0042] Example 12: A basic energy-saving window film comprises a substrate, an adhesive backing, a release film, and a topcoat. The adhesive backing is applied to the lower surface of the substrate, the release film is applied to the adhesive backing, and the topcoat is applied to the upper surface of the substrate. The substrate can be any roll material. In this embodiment, the substrate is PET, the adhesive backing is EB glue, and the topcoat is EB thermal insulation coating. The preparation method comprises the following steps: S1: First, prepare EB glue, including the following steps: In a heating kettle, add 10 kg of BR-3641AJ, 87 kg of TMCHA, 0.5 kg of Tinuvin 477, 0.5 kg of Tinuvin 1600, 0.5 kg of Tinuvin 770 and 0.5 kg of Irganox 1010. Set the temperature to 60 degrees and stir for 1 hour to obtain EB glue. The EB glue is slit-coated on the lower surface of the PET substrate with a coating thickness of 10 microns. At the same time, cover it with a fluorine release film at a line speed of 80 m / min.

[0043] S2: Preparation of EB thermal insulation coating: In a heating kettle, 30 kg of BDT-1006, 30 kg of HDDA, 10 kg of PM, 29.5 kg of G-P35-EA, 0.1 kg of Tinuvin 477, 0.1 kg of Tinuvin 1600, 0.1 kg of Tinuvin 770, 0.1 kg of Irganox 1010 and 0.1 kg of BYK 333 were added, the temperature was set to 60 degrees and stirred for 1 hour to obtain EB thermal insulation coating, and the EB thermal insulation coating was sprayed onto the upper surface of the substrate using supercritical carbon dioxide fluid equipment with a coating thickness of 10 microns, a line speed of 80 m / min, an oven temperature of 120°C, an EB voltage of 200 kV, and a dosage of 80 kgy. The EB glue and EB thermal insulation coating were cured at one time to obtain an energy-saving and thermal insulation window film.

[0044] Example 13: A basic energy-saving window film comprises a substrate, an adhesive backing, a release film, and a topcoat. The adhesive backing is applied to the lower surface of the substrate, the release film is applied to the adhesive backing, and the topcoat is applied to the upper surface of the substrate. The substrate can be any roll material. In this embodiment, the substrate is PET, the adhesive backing is EB glue, and the topcoat is EB thermal insulation coating. The preparation method comprises the following steps: S1: First, prepare EB glue, including the following steps: In a heating kettle, add 10 kg of BR-374, 87 kg of TMCHA, 0.5 kg of Tinuvin 477, 0.5 kg of Tinuvin 1600, 0.5 kg of Tinuvin 770 and 0.5 kg of Irganox 1010. Set the temperature to 60 degrees and stir for 1 hour to obtain EB glue. The EB glue is slit-coated on the lower surface of the PET substrate with a coating thickness of 25 microns. At the same time, it is covered with a fluorine release film at a line speed of 80 m / min.

[0045] S2: Preparation of EB thermal insulation coating: In a heating kettle, 30 kg of BDT-1006, 30 kg of HDDA, 10 kg of PM, 29.5 kg of G-P35-EA, 0.1 kg of Tinuvin 477, 0.1 kg of Tinuvin 1600, 0.1 kg of Tinuvin 770, 0.1 kg of Irganox 1010 and 0.1 kg of BYK 333 were added, the temperature was set to 60 degrees and stirred for 1 hour to obtain EB thermal insulation coating, and the EB thermal insulation coating was sprayed onto the upper surface of the substrate using supercritical carbon dioxide fluid equipment with a coating thickness of 10 microns, a line speed of 80 m / min, an oven temperature of 120°C, an EB voltage of 200 kV, and a dosage of 80 kgy. The EB glue and EB thermal insulation coating were cured at one time to obtain an energy-saving and thermal insulation window film.

[0046] Example 14: A basic energy-saving window film comprises a substrate, an adhesive backing, a release film, and a topcoat. The adhesive backing is applied to the lower surface of the substrate, the release film is applied to the adhesive backing, and the topcoat is applied to the upper surface of the substrate. The substrate can be any roll material. In this embodiment, the substrate is PET, the adhesive backing is EB glue, and the topcoat is EB thermal insulation coating. The preparation method comprises the following steps: S1: First, prepare EB glue, including the following steps: In a heating kettle, add 10 kg of BR-3741AJ, 87 kg of TMCHA, 0.5 kg of Tinuvin 477, 0.5 kg of Tinuvin 1600, 0.5 kg of Tinuvin 770 and 0.5 kg of Irganox 1010. Set the temperature to 60 degrees and stir for 1 hour to obtain EB glue. The EB glue is slit-coated on the lower surface of the PET substrate with a coating thickness of 10 microns. At the same time, cover it with a fluorine release film at a line speed of 80 m / min.

[0047] S2: Preparation of EB thermal insulation coating: In a heating kettle, 30 kg of BDT-1006, 30 kg of HDDA, 10 kg of PM, 29.5 kg of G-P35-EA, 0.1 kg of Tinuvin 477, 0.1 kg of Tinuvin 1600, 0.1 kg of Tinuvin 770, 0.1 kg of Irganox 1010 and 0.1 kg of BYK 333 were added, the temperature was set to 60 degrees and stirred for 1 hour to obtain EB thermal insulation coating, and the EB thermal insulation coating was sprayed onto the upper surface of the substrate using supercritical carbon dioxide fluid equipment with a coating thickness of 10 microns, a line speed of 80 m / min, an oven temperature of 120°C, an EB voltage of 200 kV, and a dosage of 80 kgy. The EB glue and EB thermal insulation coating were cured at one time to obtain an energy-saving and thermal insulation window film.

[0048] Example 15: A basic energy-saving window film comprises a substrate, an adhesive backing, a release film, and a topcoat. The adhesive backing is applied to the lower surface of the substrate, the release film is applied to the adhesive backing, and the topcoat is applied to the upper surface of the substrate. The substrate can be any roll material. In this embodiment, the substrate is PET, the adhesive backing is EB glue, and the topcoat is EB thermal insulation coating. The preparation method comprises the following steps: S1: First, prepare EB glue, including the following steps: In a heating kettle, add 10 kg of BR-3747AE, 87 kg of TMCHA, 0.5 kg of Tinuvin 477, 0.5 kg of Tinuvin 1600, 0.5 kg of Tinuvin 770 and 0.5 kg of Irganox 1010. Set the temperature to 60 degrees and stir for 1 hour to obtain EB glue. The EB glue is slit-coated on the lower surface of the PET substrate with a coating thickness of 10 microns. At the same time, cover it with a fluorine release film at a line speed of 80 m / min.

[0049] S2: Preparation of EB thermal insulation coating: In a heating kettle, 30 kg of BDT-1006, 30 kg of HDDA, 10 kg of PM, 29.5 kg of G-P35-EA, 0.1 kg of Tinuvin 477, 0.1 kg of Tinuvin 1600, 0.1 kg of Tinuvin 770, 0.1 kg of Irganox 1010 and 0.1 kg of BYK 333 were added, the temperature was set to 60 degrees and stirred for 1 hour to obtain EB thermal insulation coating, and the EB thermal insulation coating was sprayed onto the upper surface of the substrate using supercritical carbon dioxide fluid equipment with a coating thickness of 10 microns, a line speed of 80 m / min, an oven temperature of 120°C, an EB voltage of 200 kV, and a dosage of 80 kgy. The EB glue and EB thermal insulation coating were cured at one time to obtain an energy-saving and thermal insulation window film.

[0050] Example 16: A basic energy-saving window film comprises a substrate, an adhesive backing, a release film, and a topcoat. The adhesive backing is applied to the lower surface of the substrate, the release film is applied to the adhesive backing, and the topcoat is applied to the upper surface of the substrate. The substrate can be any roll material. In this embodiment, the substrate is PET, the adhesive backing is EB glue, and the topcoat is EB thermal insulation coating. The preparation method comprises the following steps: S1: First, prepare EB glue, including the following steps: In a heating kettle, add 10 kg of BR-543, 87 kg of TMCHA, 0.5 kg of Tinuvin 477, 0.5 kg of Tinuvin 1600, 0.5 kg of Tinuvin 770 and 0.5 kg of Irganox 1010. Set the temperature to 60 degrees and stir for 1 hour to obtain EB glue. The EB glue is slit-coated on the lower surface of the PET substrate with a coating thickness of 10 microns. At the same time, cover it with a fluorine release film at a line speed of 80 m / min.

[0051] S2: Preparation of EB thermal insulation coating: In a heating kettle, 30 kg of BDT-1006, 30 kg of HDDA, 10 kg of PM, 29.5 kg of G-P35-EA, 0.1 kg of Tinuvin 477, 0.1 kg of Tinuvin 1600, 0.1 kg of Tinuvin 770, 0.1 kg of Irganox 1010 and 0.1 kg of BYK 333 were added, the temperature was set to 60 degrees and stirred for 1 hour to obtain EB thermal insulation coating, and the EB thermal insulation coating was sprayed onto the upper surface of the substrate using supercritical carbon dioxide fluid equipment with a coating thickness of 10 microns, a line speed of 80 m / min, an oven temperature of 120°C, an EB voltage of 200 kV, and a dosage of 80 kgy. The EB glue and EB thermal insulation coating were cured at one time to obtain an energy-saving and thermal insulation window film.

[0052] Example 17 A basic energy-saving window film comprises a substrate, an adhesive backing, a release film, and a topcoat. The adhesive backing is applied to the lower surface of the substrate, the release film is applied to the adhesive backing, and the topcoat is applied to the upper surface of the substrate. The substrate can be any roll material. In this embodiment, the substrate is PET, the adhesive backing is EB glue, and the topcoat is EB thermal insulation coating. The preparation method comprises the following steps: S1: First, prepare EB glue, including the following steps: In a heating kettle, add 10 kg of BR-3042, 87 kg of CTFA, 0.5 kg of Tinuvin 477, 0.5 kg of Tinuvin 1600, 0.5 kg of Tinuvin 770, and 0.5 kg of Irganox 1010. Set the temperature to 60 degrees and stir for 1 hour to obtain EB glue. The EB glue is then slit-coated onto the lower surface of the PET substrate with a coating thickness of 10 μm. At the same time, a fluorine release film is applied at a line speed of 80 m / min.

[0053] S2: Preparation of EB thermal insulation coating: In a heating kettle, 30 kg of BDT-1006, 30 kg of HDDA, 10 kg of PM, 29.5 kg of G-P35-EA, 0.1 kg of Tinuvin 477, 0.1 kg of Tinuvin 1600, 0.1 kg of Tinuvin 770, 0.1 kg of Irganox 1010 and 0.1 kg of BYK 333 were added, the temperature was set to 60 degrees and stirred for 1 hour to obtain EB thermal insulation coating, and the EB thermal insulation coating was sprayed onto the upper surface of the substrate using supercritical carbon dioxide fluid equipment with a coating thickness of 10 microns, a line speed of 80 m / min, an oven temperature of 120°C, an EB voltage of 200 kV, and a dosage of 80 kgy. The EB glue and EB thermal insulation coating were cured at one time to obtain an energy-saving and thermal insulation window film.

[0054] Example 18: A basic energy-saving window film comprises a substrate, an adhesive backing, a release film, and a topcoat. The adhesive backing is applied to the lower surface of the substrate, the release film is applied to the adhesive backing, and the topcoat is applied to the upper surface of the substrate. The substrate can be any roll material. In this embodiment, the substrate is PET, the adhesive backing is EB glue, and the topcoat is EB thermal insulation coating. The preparation method comprises the following steps: S1: First, prepare EB glue, including the following steps: In a heating kettle, add 10 kg of BR-344, 87 kg of CTFA, 0.5 kg of Tinuvin 477, 0.5 kg of Tinuvin 1600, 0.5 kg of Tinuvin 770, and 0.5 kg of Irganox 1010. Set the temperature to 60 degrees and stir for 1 hour to obtain EB glue. The EB glue is then slit-coated onto the lower surface of the PET substrate with a coating thickness of 10 μm. At the same time, a fluorine release film is applied at a line speed of 80 m / min.

[0055] S2: Preparation of EB thermal insulation coating: In a heating kettle, 30 kg of BDT-1006, 30 kg of HDDA, 10 kg of PM, 29.5 kg of G-P35-EA, 0.1 kg of Tinuvin 477, 0.1 kg of Tinuvin 1600, 0.1 kg of Tinuvin 770, 0.1 kg of Irganox 1010 and 0.1 kg of BYK 333 were added, the temperature was set to 60 degrees and stirred for 1 hour to obtain EB thermal insulation coating, and the EB thermal insulation coating was sprayed onto the upper surface of the substrate using supercritical carbon dioxide fluid equipment with a coating thickness of 10 microns, a line speed of 80 m / min, an oven temperature of 120°C, an EB voltage of 200 kV, and a dosage of 80 kgy. The EB glue and EB thermal insulation coating were cured at one time to obtain an energy-saving and thermal insulation window film.

[0056] Example 19: A basic energy-saving window film comprises a substrate, an adhesive backing, a release film, and a topcoat. The adhesive backing is applied to the lower surface of the substrate, the release film is applied to the adhesive backing, and the topcoat is applied to the upper surface of the substrate. The substrate can be any roll material. In this embodiment, the substrate is PET, the adhesive backing is EB glue, and the topcoat is EB thermal insulation coating. The preparation method comprises the following steps: S1: First, prepare EB glue, including the following steps: In a heating kettle, add 10 kg of BR-3641AA, 87 kg of CTFA, 0.5 kg of Tinuvin 477, 0.5 kg of Tinuvin 1600, 0.5 kg of Tinuvin 770 and 0.5 kg of Irganox 1010. Set the temperature to 60 degrees and stir for 1 hour to obtain EB glue. The EB glue is then slit-coated onto the lower surface of the PET substrate with a coating thickness of 10 μm. At the same time, a fluorine release film is applied at a line speed of 80 m / min.

[0057] S2: Preparation of EB thermal insulation coating: In a heating kettle, 30 kg of BDT-1006, 30 kg of HDDA, 10 kg of PM, 29.5 kg of G-P35-EA, 0.1 kg of Tinuvin 477, 0.1 kg of Tinuvin 1600, 0.1 kg of Tinuvin 770, 0.1 kg of Irganox 1010 and 0.1 kg of BYK 333 were added, the temperature was set to 60 degrees and stirred for 1 hour to obtain EB thermal insulation coating, and the EB thermal insulation coating was sprayed onto the upper surface of the substrate using supercritical carbon dioxide fluid equipment with a coating thickness of 10 microns, a line speed of 80 m / min, an oven temperature of 120°C, an EB voltage of 200 kV, and a dosage of 80 kgy. The EB glue and EB thermal insulation coating were cured at one time to obtain an energy-saving and thermal insulation window film.

[0058] Example 20: A basic energy-saving window film comprises a substrate, an adhesive backing, a release film, and a topcoat. The adhesive backing is applied to the lower surface of the substrate, the release film is applied to the adhesive backing, and the topcoat is applied to the upper surface of the substrate. The substrate can be any roll material. In this embodiment, the substrate is PET, the adhesive backing is EB glue, and the topcoat is EB thermal insulation coating. The preparation method comprises the following steps: S1: First, prepare EB glue, including the following steps: In a heating kettle, add 10 kg of BR-3641AJ, 87 kg of CTFA, 0.5 kg of Tinuvin 477, 0.5 kg of Tinuvin 1600, 0.5 kg of Tinuvin 770 and 0.5 kg of Irganox 1010. Set the temperature to 60 degrees and stir for 1 hour to obtain EB glue. The EB glue is slit-coated onto the lower surface of the PET substrate with a coating thickness of 10 microns. At the same time, cover with a fluorine release film at a line speed of 80 m / min.

[0059] S2: Preparation of EB thermal insulation coating: In a heating kettle, 30 kg of BDT-1006, 30 kg of HDDA, 10 kg of PM, 29.5 kg of G-P35-EA, 0.1 kg of Tinuvin 477, 0.1 kg of Tinuvin 1600, 0.1 kg of Tinuvin 770, 0.1 kg of Irganox 1010 and 0.1 kg of BYK 333 were added, the temperature was set to 60 degrees and stirred for 1 hour to obtain EB thermal insulation coating, and the EB thermal insulation coating was sprayed onto the upper surface of the substrate using supercritical carbon dioxide fluid equipment with a coating thickness of 10 microns, a line speed of 80 m / min, an oven temperature of 120°C, an EB voltage of 200 kV, and a dosage of 80 kgy. The EB glue and EB thermal insulation coating were cured at one time to obtain an energy-saving and thermal insulation window film.

[0060] Example 21: A basic energy-saving window film comprises a substrate, an adhesive backing, a release film, and a topcoat. The adhesive backing is applied to the lower surface of the substrate, the release film is applied to the adhesive backing, and the topcoat is applied to the upper surface of the substrate. The substrate can be any roll material. In this embodiment, the substrate is PET, the adhesive backing is EB glue, and the topcoat is EB thermal insulation coating. The preparation method comprises the following steps: S1: First, prepare EB glue, including the following steps: In a heating kettle, add 10 kg of BR-374, 87 kg of CTFA, 0.5 kg of Tinuvin 477, 0.5 kg of Tinuvin 1600, 0.5 kg of Tinuvin 770 and 0.5 kg of Irganox 1010. Set the temperature to 60 degrees and stir for 1 hour to obtain EB glue. The EB glue is then slit-coated onto the lower surface of the PET substrate with a coating thickness of 10 μm. At the same time, a fluorine release film is applied at a line speed of 80 m / min.

[0061] S2: Preparation of EB thermal insulation coating: In a heating kettle, 30 kg of BDT-1006, 30 kg of HDDA, 10 kg of PM, 29.5 kg of G-P35-EA, 0.1 kg of Tinuvin 477, 0.1 kg of Tinuvin 1600, 0.1 kg of Tinuvin 770, 0.1 kg of Irganox 1010 and 0.1 kg of BYK 333 were added, the temperature was set to 60 degrees and stirred for 1 hour to obtain EB thermal insulation coating, and the EB thermal insulation coating was sprayed onto the upper surface of the substrate using supercritical carbon dioxide fluid equipment with a coating thickness of 10 microns, a line speed of 80 m / min, an oven temperature of 120°C, an EB voltage of 200 kV, and a dosage of 80 kgy. The EB glue and EB thermal insulation coating were cured at one time to obtain an energy-saving and thermal insulation window film.

[0062] Example 22: A basic energy-saving window film comprises a substrate, an adhesive backing, a release film, and a topcoat. The adhesive backing is applied to the lower surface of the substrate, the release film is applied to the adhesive backing, and the topcoat is applied to the upper surface of the substrate. The substrate can be any roll material. In this embodiment, the substrate is PET, the adhesive backing is EB glue, and the topcoat is EB thermal insulation coating. The preparation method comprises the following steps: S1: First, prepare EB glue, including the following steps: In a heating kettle, add 10 kg of BR-3741AJ, 87 kg of CTFA, 0.5 kg of Tinuvin 477, 0.5 kg of Tinuvin 1600, 0.5 kg of Tinuvin 770 and 0.5 kg of Irganox 1010. Set the temperature to 60 degrees and stir for 1 hour to obtain EB glue. The EB glue is slit-coated onto the lower surface of the PET substrate with a coating thickness of 10 microns. At the same time, cover with a fluorine release film at a line speed of 80 m / min.

[0063] S2: Preparation of EB thermal insulation coating: In a heating kettle, 30 kg of BDT-1006, 30 kg of HDDA, 10 kg of PM, 29.5 kg of G-P35-EA, 0.1 kg of Tinuvin 477, 0.1 kg of Tinuvin 1600, 0.1 kg of Tinuvin 770, 0.1 kg of Irganox 1010 and 0.1 kg of BYK 333 were added, the temperature was set to 60 degrees and stirred for 1 hour to obtain EB thermal insulation coating, and the EB thermal insulation coating was sprayed onto the upper surface of the substrate using supercritical carbon dioxide fluid equipment with a coating thickness of 10 microns, a line speed of 80 m / min, an oven temperature of 120°C, an EB voltage of 200 kV, and a dosage of 80 kgy. The EB glue and EB thermal insulation coating were cured at one time to obtain an energy-saving and thermal insulation window film.

[0064] Example 23: A basic energy-saving window film comprises a substrate, an adhesive backing, a release film, and a topcoat. The adhesive backing is applied to the lower surface of the substrate, the release film is applied to the adhesive backing, and the topcoat is applied to the upper surface of the substrate. The substrate can be any roll material. In this embodiment, the substrate is PET, the adhesive backing is EB glue, and the topcoat is EB thermal insulation coating. The preparation method comprises the following steps: S1: First, prepare EB glue, including the following steps: In a heating kettle, add 10 kg of BR-3747AE, 87 kg of CTFA, 0.5 kg of Tinuvin 477, 0.5 kg of Tinuvin 1600, 0.5 kg of Tinuvin 770, and 0.5 kg of Irganox 1010. Set the temperature to 60 degrees and stir for 1 hour to obtain EB glue. The EB glue is then slit-coated onto the lower surface of the PET substrate with a coating thickness of 10 μm. At the same time, a fluorine release film is applied at a line speed of 80 m / min.

[0065] S2: Preparation of EB thermal insulation coating: In a heating kettle, 30 kg of BDT-1006, 30 kg of HDDA, 10 kg of PM, 29.5 kg of G-P35-EA, 0.1 kg of Tinuvin 477, 0.1 kg of Tinuvin 1600, 0.1 kg of Tinuvin 770, 0.1 kg of Irganox 1010 and 0.1 kg of BYK 333 were added, the temperature was set to 60 degrees and stirred for 1 hour to obtain EB thermal insulation coating, and the EB thermal insulation coating was sprayed onto the upper surface of the substrate using supercritical carbon dioxide fluid equipment with a coating thickness of 10 microns, a line speed of 80 m / min, an oven temperature of 120°C, an EB voltage of 200 kV, and a dosage of 80 kgy. The EB glue and EB thermal insulation coating were cured at one time to obtain an energy-saving and thermal insulation window film.

[0066] Example 24: A basic energy-saving window film comprises a substrate, an adhesive backing, a release film, and a topcoat. The adhesive backing is applied to the lower surface of the substrate, the release film is applied to the adhesive backing, and the topcoat is applied to the upper surface of the substrate. The substrate can be any roll material. In this embodiment, the substrate is PET, the adhesive backing is EB glue, and the topcoat is EB thermal insulation coating. The preparation method comprises the following steps: S1: First, prepare EB glue, including the following steps: In a heating kettle, add 10 kg of BR-543, 87 kg of CTFA, 0.5 kg of Tinuvin 477, 0.5 kg of Tinuvin 1600, 0.5 kg of Tinuvin 770 and 0.5 kg of Irganox 1010. Set the temperature to 60 degrees and stir for 1 hour to obtain EB glue. The EB glue is then slit-coated onto the lower surface of the PET substrate with a coating thickness of 10 μm. At the same time, a fluorine release film is applied at a line speed of 80 m / min.

[0067] S2: Preparation of EB thermal insulation coating: In a heating kettle, 30 kg of BDT-1006, 30 kg of HDDA, 10 kg of PM, 29.5 kg of G-P35-EA, 0.1 kg of Tinuvin 477, 0.1 kg of Tinuvin 1600, 0.1 kg of Tinuvin 770, 0.1 kg of Irganox 1010 and 0.1 kg of BYK 333 were added, the temperature was set to 60 degrees and stirred for 1 hour to obtain EB thermal insulation coating, and the EB thermal insulation coating was sprayed onto the upper surface of the substrate using supercritical carbon dioxide fluid equipment with a coating thickness of 10 microns, a line speed of 80 m / min, an oven temperature of 120°C, an EB voltage of 200 kV, and a dosage of 80 kgy. The EB glue and EB thermal insulation coating were cured at one time to obtain an energy-saving and thermal insulation window film.

[0068] Table 1 Performance test of energy-saving window films prepared in Examples 1-24:

[0069] From the results in Table 1, it can be concluded that in the EB glues with TBCHA, TMCHA and CTFA, TBCHA and CTFA will have residual glue, only TMCHA will not have residual glue, which means that TMCHA has better high temperature resistance and hydrolysis resistance; the EB glue containing CTFA has the worst 180-degree peel strength, which means that CTFA cannot provide better peel strength; TBCHA, TMCHA and CTFA have little effect on haze, mainly because the main resin has a greater impact. The results show that the EB glue containing BR-3641AJ and BR-3741AJ has better transmittance and lower haze; the EB glue containing BR-3042 has the worst yellowing resistance, which means that the aromatic polyurethane acrylate BR-3042 cannot provide better yellowing resistance; in summary, in Example 12, the EB glue using TMCHA and BR-3641AJ has the most suitable performance in weather resistance, transmittance, haze and yellowing resistance.

[0070] Example 25 A basic energy-saving window film comprises a substrate, an adhesive backing, a release film, and a topcoat. The adhesive backing is applied to the lower surface of the substrate, the release film is applied to the adhesive backing, and the topcoat is applied to the upper surface of the substrate. The substrate can be any roll material. In this embodiment, the substrate is PET, the adhesive backing is EB glue, and the topcoat is EB thermal insulation coating. The preparation method comprises the following steps: S1: First, prepare EB glue and use a slit coating to coat the lower surface of the PET substrate, and then cover it with a fluorine release film. The preparation method is the same as that in Example 20.

[0071] S2: Preparation of EB thermal insulation coating: In a heating kettle, 30 kg of 6150-100, 30 kg of HDDA, 10 kg of PM, 29.5 kg of G-P35-EA, 0.1 kg of Tinuvin 477, 0.1 kg of Tinuvin 1600, 0.1 kg of Tinuvin 770, 0.1 kg of Irganox 1010 and 0.1 kg of BYK 333 were added, the temperature was set to 60 degrees and stirred for 1 hour to obtain EB thermal insulation coating, and the EB thermal insulation coating was sprayed onto the upper surface of the substrate using a supercritical carbon dioxide fluid equipment with a coating thickness of 10 microns, a line speed of 80 m / min, an oven temperature of 120°C, an EB voltage of 200 kV, and a dosage of 80 kgy. The EB glue and EB thermal insulation coating were cured at one time to obtain an energy-saving and thermal insulation window film.

[0072] Example 26 A basic energy-saving window film comprises a substrate, an adhesive backing, a release film, and a topcoat. The adhesive backing is applied to the lower surface of the substrate, the release film is applied to the adhesive backing, and the topcoat is applied to the upper surface of the substrate. The substrate can be any roll material. In this embodiment, the substrate is PET, the adhesive backing is EB glue, and the topcoat is EB thermal insulation coating. The preparation method comprises the following steps: S1: First, prepare EB glue and use a slit coating to coat the lower surface of the PET substrate, and then cover it with a fluorine release film. The preparation method is the same as that in Example 20.

[0073] S2: Preparation of EB thermal insulation coating: In a heating kettle, 30 kg of ES-6768, 30 kg of HDDA, 10 kg of PM, 29.5 kg of G-P35-EA, 0.1 kg of Tinuvin 477, 0.1 kg of Tinuvin 1600, 0.1 kg of Tinuvin 770, 0.1 kg of Irganox 1010 and 0.1 kg of BYK 333 were added, the temperature was set to 60 degrees and stirred for 1 hour to obtain EB thermal insulation coating, and the EB thermal insulation coating was sprayed onto the upper surface of the substrate using a supercritical carbon dioxide fluid equipment with a coating thickness of 10 microns, a line speed of 80 m / min, an oven temperature of 120°C, an EB voltage of 200 kV, and a dosage of 80 kgy. The EB glue and EB thermal insulation coating were cured at one time to obtain an energy-saving and thermal insulation window film.

[0074] Example 27: A basic energy-saving window film comprises a substrate, an adhesive backing, a release film, and a topcoat. The adhesive backing is applied to the lower surface of the substrate, the release film is applied to the adhesive backing, and the topcoat is applied to the upper surface of the substrate. The substrate can be any roll material. In this embodiment, the substrate is PET, the adhesive backing is EB glue, and the topcoat is EB thermal insulation coating. The preparation method comprises the following steps: S1: First, prepare EB glue and use a slit coating to coat the lower surface of the PET substrate, and then cover it with a fluorine release film. The preparation method is the same as that in Example 20.

[0075] S2: Preparation of EB thermal insulation coating: In a heating kettle, 30 kg of 6170, 30 kg of HDDA, 10 kg of PM, 29.5 kg of G-P35-EA, 0.1 kg of Tinuvin 477, 0.1 kg of Tinuvin 1600, 0.1 kg of Tinuvin 770, 0.1 kg of Irganox 1010 and 0.1 kg of BYK 333 were added, the temperature was set to 60 degrees and stirred for 1 hour to obtain EB thermal insulation coating, and the EB thermal insulation coating was sprayed onto the upper surface of the substrate using a supercritical carbon dioxide fluid equipment with a coating thickness of 10 microns, a line speed of 80 m / min, an oven temperature of 120°C, an EB voltage of 200 kV, and a dosage of 80 kgy. The EB glue and EB thermal insulation coating were cured at one time to obtain an energy-saving and thermal insulation window film.

[0076] Example 28 A basic energy-saving window film comprises a substrate, an adhesive backing, a release film, and a topcoat. The adhesive backing is applied to the lower surface of the substrate, the release film is applied to the adhesive backing, and the topcoat is applied to the upper surface of the substrate. The substrate can be any roll material. In this embodiment, the substrate is PET, the adhesive backing is EB glue, and the topcoat is EB thermal insulation coating. The preparation method comprises the following steps: S1: First, prepare EB glue and use a slit coating to coat the lower surface of the PET substrate, and then cover it with a fluorine release film. The preparation method is the same as that in Example 20.

[0077] S2: Preparation of EB thermal insulation coating: In a heating kettle, 30 kg of MP5163, 30 kg of HDDA, 10 kg of PM, 29.5 kg of G-P35-EA, 0.1 kg of Tinuvin 477, 0.1 kg of Tinuvin 1600, 0.1 kg of Tinuvin 770, 0.1 kg of Irganox 1010 and 0.1 kg of BYK333 were added, the temperature was set to 60 degrees and stirred for 1 hour to obtain EB thermal insulation coating, and the EB thermal insulation coating was sprayed onto the upper surface of the substrate using supercritical carbon dioxide fluid equipment with a coating thickness of 10 microns, a line speed of 80 m / min, an oven temperature of 120°C, an EB voltage of 200 kV, and a dosage of 80 kgy. The EB glue and EB thermal insulation coating were cured at one time to obtain an energy-saving and thermal insulation window film.

[0078] Example 29 A basic energy-saving window film comprises a substrate, an adhesive backing, a release film, and a topcoat. The adhesive backing is applied to the lower surface of the substrate, the release film is applied to the adhesive backing, and the topcoat is applied to the upper surface of the substrate. The substrate can be any roll material. In this embodiment, the substrate is PET, the adhesive backing is EB glue, and the topcoat is EB thermal insulation coating. The preparation method comprises the following steps: S1: First, prepare EB glue and use a slit coating to coat the lower surface of the PET substrate, and then cover it with a fluorine release film. The preparation method is the same as that in Example 20.

[0079] S2: Preparation of EB thermal insulation coating: In a heating kettle, 30 kg of GU9315Z, 30 kg of HDDA, 10 kg of PM, 29.5 kg of G-P35-EA, 0.1 kg of Tinuvin 477, 0.1 kg of Tinuvin 1600, 0.1 kg of Tinuvin 770, 0.1 kg of Irganox 1010 and 0.1 kg of BYK333 were added, the temperature was set to 60 degrees and stirred for 1 hour to obtain EB thermal insulation coating, and the EB thermal insulation coating was sprayed onto the upper surface of the substrate using supercritical carbon dioxide fluid equipment with a coating thickness of 10 microns, a line speed of 80 m / min, an oven temperature of 120°C, an EB voltage of 200 kV, and a dosage of 80 kgy. The EB glue and EB thermal insulation coating were cured at one time to obtain an energy-saving and thermal insulation window film.

[0080] Table 2 Energy-saving window film performance test

[0081] It can be concluded from Table 2 that the higher the functional group, the higher the pencil hardness. The functional groups of GU9315Z used in Example 29 are 12-15, and the others are all 6. The results of the double 85 performance test show that the higher the functional group, the higher the cross-linking density, and the less the infrared blocking rate decreases. There is little difference in yellowing resistance. In summary, in Example 29, the energy-saving window film prepared using EB glue configured with TMCHA and BR-3641AJ and EB thermal insulation coating configured with GU9315Z has the best performance.

[0082] The above is a preferred embodiment of the present invention. It should be pointed out that for ordinary technicians in this technical field, several improvements and modifications can be made without departing from the principles of the present invention. These improvements and modifications should also be regarded as within the scope of protection of the present invention.

Claims

1. An energy-saving window film, characterized in that: The energy-saving window film includes a substrate, a backing glue, a release film, and a topcoat. The backing glue is coated on the lower surface of the substrate, the release film is covered on the backing glue surface, and the topcoat is coated on the upper surface of the substrate. The backing glue adopts EB glue, and the topcoat adopts EB thermal insulation coating. The EB glue and EB thermal insulation coating are both cured and formed using EB in one step.

2. The energy-saving window film according to claim 1, characterized in that: The substrate is a single-layer PET or a multi-layer PET.

3. The energy-saving window film according to claim 1, characterized in that: The release film is a fluorine release film or a silicon release film.

4. The energy-saving window film according to any one of claims 1 to 3, characterized in that: The EB glue includes by weight: 10-70 parts of acrylate monomer, 10-50 parts of acrylate resin, 0.1-10 parts of ultraviolet light absorber, 0.1-10 parts of light stabilizer, and 0.1-10 parts of antioxidant.

5. The energy-saving window film according to claim 4, characterized in that: The acrylate monomers are o-phenylphenoxyethyl acrylate, phenoxyethyl acrylate, ethoxyethoxyethyl acrylate, lauryl alcohol acrylate, stearyl alcohol acrylate, benzyl acrylate, ethoxylated o-phenylphenoxy acrylate, ethoxylated nonylphenol acrylate, propoxylated nonylphenol acrylate, ethoxylated propoxylated nonylphenol acrylate, cyclotrimethylolpropane formal acrylate, ethoxylated phenoxy acrylate, propoxylated phenoxy acrylate, isobornyl acrylate, cyclohexyl propionate, (2-ethyl-2-methyl-1,3-dioxolan-4-yl) acrylate, cyclohexyl-2-(1,3-dioxolan-4-yl) acrylate, 1-adamantyl methacrylate, acrylate, γ-butyrolactone acrylate, γ-butyrolactone methacrylate, 4-tert-butylcyclohexyl acrylate, m-phenoxybenzyl acrylate, dicyclopentenyl acrylate, dicyclopentenyl ethoxylated acrylate, 3,3,5-trimethylcyclohexyl acrylate, tetrahydrofurfuryl acrylate, dicyclopentenyl ethoxylated methacrylate, 2-phenoxyethyl methacrylate, tetrahydrofurfuryl methacrylate, isobornyl methacrylate, cyclohexyl methacrylate, benzyl methacrylate; the acrylate resin is any one of epoxy acrylate, polyurethane acrylate, polyester acrylate, pure acrylate, and organic-inorganic hybrid resin, or a combination of two or more thereof; The ultraviolet light absorber is any one of BASF Tinuvin 405, Tinuvin 292, Tinuvin 1130, Tinuvin 477, and Tinuvin 1600, or a combination of two or more thereof; The light stabilizer is any one of BASF Tinuvin 622, Tinuvin 770, Tinuvin 326, and Tinuvin 234, or a combination of two or more thereof; The antioxidant is any one of BASF Irganox 1010, Irganox 1076, Irganox 1098, and Irganox B215, or a combination of two or more thereof.

6. The energy-saving window film according to any one of claims 1 to 3, characterized in that: The EB thermal insulation coating comprises, by weight: 10-50 parts of acrylate resin, 10-30 parts of heat insulation auxiliary agent, 10-40 parts of solvent, 0.1-10 parts of antioxidant, and 0.01-0.1 parts of leveling agent.

7. The energy-saving window film according to claim 6, characterized in that: The acrylate resin is any one of epoxy acrylate, polyurethane acrylate, polyester acrylate, pure acrylate, and organic-inorganic hybrid resin, or a combination of two or more thereof; the thermal insulation additive is any one of indium tin oxide dispersion, antimony tin oxide dispersion, and tungsten oxide dispersion; the solvent is one of ethyl acetate, butyl acetate, propylene glycol methyl ether, and isopropyl alcohol, or a combination of two or more thereof; The leveling agent is any one of BYK333, BYK353, BYK356, BYK359, and BYK361N; the antioxidant is any one of BASF's Irganox1010, Irganox1076, Irganox1098, and Irganox B215, or a combination of two or more thereof.

8. A method for preparing an energy-saving window film, characterized in that The following steps are involved: S1: Apply EB glue to the lower surface of the substrate and cover with release film; S2: Apply EB thermal insulation coating to the surface of the substrate, evaporate the solvent in an oven, use EB to cure, and cure the thermal insulation coating and EB glue into shape at one time.

9. The method for preparing an energy-saving window film according to claim 8, wherein: The EB glue is applied to the lower surface of the substrate with a coating thickness of 10-50 microns; The EB thermal insulation coating is sprayed onto the upper surface of the substrate using a supercritical carbon dioxide fluid spraying device, with a coating thickness of 10-50 microns, an oven temperature of 80-150°C, an EB voltage of 100kv-250kv, and a dosage of 10-100kgy.

10. An application of the energy-saving window film according to any one of claims 1 to 7, characterized in that: The application is to apply film to automobile windows and architectural windows.

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