Preparation method and use method of long-acting slow-release bird repellent special for electric power

By compounding kappa and iota carrageenan with caseinate to form a sustained-release gel carrier, the effective ingredients of the bird repellent are loaded, which solves the problem of poor sustained-release effect of existing bird repellents and achieves long-lasting bird repellent effect and environmental protection.

CN120731944AInactive Publication Date: 2025-10-03HUZHOU ELECTRIC POWER SUPPLY CO OF STATE GRID ZHEJIANG ELECTRIC POWER CO LTD
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Patent Information

Application Number
CN202311191378.X
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2023-09-15
Publication Date
2025-10-03
Estimated Expiration
Not applicable · inactive patent

AI Technical Summary

Technical Problem

Existing bird repellents have poor sustained-release effects, short efficacy periods, and are easily affected by weather, resulting in unstable bird repellent effects and safety and environmental issues.

Method used

Kappa and iota carrageenan are compounded with caseinate to form a sustained-release gel carrier, which is loaded with effective ingredients such as Houttuynia cordata essential oil, cinnamaldehyde, and methyl anthranilate. Polyvinylidene fluoride resin is combined to improve the weather resistance and waterproofness of the carrier, and the physical binding effect is enhanced by adding it in batches.

Benefits of technology

It achieves long-term sustained release, significantly prolongs the efficacy of the drug, can resist external environmental damage, has low toxicity to birds and humans, has good adaptability, and reduces environmental complaints.

✦ Generated by Eureka AI based on patent content.

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Abstract

The invention relates to the technical field of bird repelling agents, and discloses a preparation method and a use method of a long-acting slow-release bird repelling agent special for electric power, and the preparation method comprises the following steps: (1) dissolving kappa-type carrageenan and iota-type carrageenan in water to obtain a first solution; dissolving herba houttuyniae essential oil, cinnamyl aldehyde and methyl anthranilate in ethanol to obtain a second solution; dissolving potassium caseinate and calcium caseinate in water to obtain a third solution; (2) adding polyvinylidene fluoride resin, musk-T, peppermint oil, an antioxidant and an antifreeze agent into N-methyl pyrrolidone to obtain a fourth solution; (3) adding the second solution into the first solution, stirring, adding the third solution, and heating for reaction to obtain a colloid mixed solution; and (4) cooling the colloid mixed solution, adding the fourth solution, and stirring to obtain a colloid agent, namely the long-acting slow-release bird repellent. The bird repellent disclosed by the invention can play a role initially, and meanwhile, the long-term slow-release effect is better, and the effective time is longer.
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Description

Technical Field

[0001] The present invention relates to the technical field of bird repellents, and in particular to a preparation method and a use method of a long-acting sustained-release bird repellent specially used for electric power. Background Art

[0002] With social development and the promotion of policies to maintain ecological balance, birds are proliferating and expanding their range. This gradual increase in bird populations, however, has led to increased bird activity, which poses a constant threat to power grid security. These hazards include: Birds nest in conductive materials like damp branches, vines, and wire, which can easily cause short circuits; bird droppings can contaminate porcelain bottles, causing line tripping; and birds can infiltrate gaps between electrical equipment like transformers, circuit breakers, and disconnectors, causing transient power outages. These threats pose a serious threat to the safe operation of the power grid, resulting in significant economic losses for both the power sector and people's livelihoods.

[0003] Currently, the main technical measures implemented on high-voltage substation equipment include: 1) installing bird droppings baffles; 2) installing bird-proof covers, bird spikes, or bird nets; 3) installing bird-proof windmills and voice-activated bird repellents; and 4) installing induction electric shock panels. While these bird-proofing measures on high-voltage substation equipment can achieve some success, they also present numerous challenges: 1) Birds easily adapt, rendering them ineffective; 2) bird-proof spikes or electric shock panels are unsafe, creating dangers for maintenance personnel who might accidentally touch them; 3) sound and light bird-repellent devices like bird-proof windmills have a limited range, and the noise or flashes they emit can pollute the surrounding environment, leading to environmental complaints; 4) ultrasonic and electric shock panels lose their functionality after a power outage, making their operation impossible to observe and measure; and 5) other bird-repellent measures are cost-prohibitive and susceptible to climate change.

[0004] In recent years, low-toxic bird repellent products have gradually emerged. For example, Chinese invention patent publication number CN 101361495 B discloses a bird repellent composition, a colloidal mixture, a suspension concentrate, and a preparation method thereof. The bird repellent fragrance is selected from one or both of anthranilate (1% to 50%), houttuynia cordata essential oil (0.1% to 5%), or musk T (10% to 21%); the antioxidant is selected from one or both of 2,6-di-tert-butyl-p-cresol and sodium ascorbate (0.02% to 0.5%), and the remainder is a sustained-release carrier. However, these products suffer from poor sustained-release effects and a short duration of efficacy. Furthermore, in rainy or windy weather, the bird repellent ingredients are easily lost, significantly reducing their effectiveness or even rendering them ineffective. Summary of the Invention

[0005] In order to solve the above technical problems, the present invention provides a preparation method and use method of a long-acting sustained-release bird repellent specially for power generation, and develops a new environmentally friendly long-acting bird repellent to drive away birds from nesting and frequent activities to ensure the safe and normal operation of power equipment, which is of great significance to the safe operation of the power grid.

[0006] The purpose of the present invention is achieved through the following technical solutions: In a first aspect, the present invention provides a method for preparing a long-acting sustained-release bird repellent for power generation, comprising the following steps: (1) dissolving kappa carrageenan and iota carrageenan in water to obtain a first solution; dissolving houttuynia cordata essential oil, cinnamaldehyde, and methyl anthranilate in ethanol to obtain a second solution; and dissolving potassium caseinate and calcium caseinate in water to obtain a third solution; (2) adding polyvinylidene fluoride resin, musk-T, peppermint oil, antioxidant and antifreeze agent to N-methylpyrrolidone to obtain a fourth solution; (3) adding the second solution to the first solution, stirring, adding the third solution, heating and reacting, and obtaining a colloidal mixture; (4) After the colloid mixture is cooled, the fourth solution is added and stirred to obtain a colloid agent, i.e., a long-acting sustained-release bird repellent.

[0007] The present invention adopts the low toxicity compounding of several active ingredients of Herba Houttuyniae essential oil, cinnamaldehyde, methyl anthranilate, musk-T and peppermint oil, and the compounding effect is good and can obviously enhance the effect, does not have direct lethality to birds, and is also relatively low in toxicity to humans and other mammals. However, the volatility of conventional active ingredients is strong, and the drug effect period is short, which is unfavorable for the long-term use of bird repellent. Thus, the present invention obtains a slow-release gel carrier by adding carrageenan and caseinate, and the active ingredient load is combined on the slow-release gel carrier, not only can provide a larger load capacity, slow down the release rate, and can resist the infringement of external environment (such as rain, strong wind), and the drug effect performance time is significantly extended.

[0008] Specifically, carrageenan itself has good viscosity. κ-type carrageenan forms a harder gel in the presence of potassium ions, which is used to improve the weather resistance of the bird repellent. κ-type carrageenan also forms a good bond with protein, which can improve the binding stability between carrageenan and caseinate. Io-type carrageenan forms a soft, elastic gel in the presence of calcium ions. By regulating the raw material ratio, a carrier with suitable viscosity and elasticity is obtained, which can form a good bond with the active ingredients and have a good sustained-release effect. The subsequent addition of polyvinylidene fluoride resin can improve the carrier's high temperature resistance and water resistance. In addition, adding the active ingredients in batches is conducive to achieving better dispersibility. First, Houttuynia cordata essential oil, cinnamaldehyde, and methyl anthranilate, which have multiple components, high volatility, and good compatibility with each other, are added to the preparation process of the sustained-release gel carrier. They form a physical bond with the carrier, which can absorb more active ingredients. The remaining components are then added and mixed, allowing the bird repellent to work from the beginning while also having better long-term sustained-release effect and weather resistance, and lasting longer.

[0009] Preferably, in step (1), the mass ratio of kappa carrageenan, iota carrageenan and water in the first solution is 2-3:5-7:100.

[0010] Preferably, in step (1), the mass ratio of Houttuynia cordata essential oil, cinnamaldehyde, methyl anthranilate and ethanol in the second solution is 5-10:10-15:25-30:30.

[0011] Preferably, in step (1), the mass ratio of potassium caseinate, calcium caseinate and water in the third solution is 0.5-1:2-3:100.

[0012] Preferably, in step (3), the mass ratio of the first solution, the second solution and the third solution is 5:0.8 to 1:10.

[0013] Preferably, in step (3), the heating reaction is carried out by heating to reflux for 30 to 40 minutes.

[0014] Preferably, in step (4), the mass ratio of the colloid mixture to the fourth solution is 100:1-2; and the cooling temperature is 55-65°C.

[0015] Preferably, in step (2), the mass ratio of polyvinylidene fluoride resin, musk-T, peppermint oil, antioxidant, antifreeze agent and N-methylpyrrolidone in the fourth solution is 10:3-5:10-15:0.1-0.5:2-3:20.

[0016] Preferably, in step (2), the antioxidant is ethyl hydroxybenzoate; and the antifreeze agent is ethylene glycol or glycerol.

[0017] In a second aspect, the present invention also provides a method for using a long-acting slow-release bird repellent in the power field, comprising the following steps: applying the bird repellent to power transmission facilities, hanging the bird repellent, or placing the bird repellent on the ground along the power transmission line.

[0018] Compared with the prior art, the present invention has the following beneficial effects: (1) The compounding effect is good and the efficacy is significantly enhanced through the low-toxic compounding of active ingredients. It has no direct lethality to birds and has low toxicity to humans and other mammals. (2) By adding carrageenan and caseinate to form a sustained-release gel carrier, the active ingredient is loaded and bound to the sustained-release gel carrier, which not only provides a larger load and slows down the release rate, but also can resist the damage of the external environment (such as rain and strong wind), and the duration of drug efficacy is significantly prolonged; (3) The active ingredients are added in batches to improve the physical bonding effect between them and the carrier, which can absorb more effective components. The subsequent addition of polyvinylidene fluoride resin can also improve the weather resistance of the carrier, so that the bird repellent can take effect at the beginning and has a better long-term sustained release effect and a longer effective time. DETAILED DESCRIPTION

[0019] The technical solution of the present invention is described below with specific embodiments, but the protection scope of the present invention is not limited thereto: A method for preparing a long-acting slow-release bird repellent specifically for power generation comprises the following steps: (1) Dissolving kappa carrageenan and iota carrageenan in water, wherein the mass ratio of kappa carrageenan, iota carrageenan and water is 2-3:5-7:100, to obtain a first solution; dissolving houttuynia cordata essential oil, cinnamaldehyde and methyl anthranilate in ethanol, wherein the mass ratio of houttuynia cordata essential oil, cinnamaldehyde, methyl anthranilate and ethanol is 5-10:10-15:25-30:30, to obtain a second solution; dissolving potassium caseinate and calcium caseinate in water, wherein the mass ratio of potassium caseinate, calcium caseinate and water is 0.5-1:2-3:100, to obtain a third solution; (2) adding polyvinylidene fluoride resin, musk-T, peppermint oil, antioxidant (ethyl hydroxybenzoate) and antifreeze (ethylene glycol or glycerol) to N-methylpyrrolidone, wherein the mass ratio of polyvinylidene fluoride resin, musk-T, peppermint oil, antioxidant, antifreeze and N-methylpyrrolidone is 10:3-5:10-15:0.1-0.5:2-3:20, to obtain a fourth solution; (3) adding the second solution to the first solution, stirring, and then adding the third solution so that the mass ratio of the first solution, the second solution, and the third solution is 5:0.8 to 1:10, and then heating to reflux for 30 to 40 minutes to obtain a colloidal mixed solution; (4) After the colloid mixture is cooled to 55-65° C., the fourth solution is added and stirred, and the mass ratio of the colloid mixture to the fourth solution is 100:1-2; thereby obtaining a colloid agent, i.e., a long-acting sustained-release bird repellent.

[0020] Example 1 A method for preparing a long-acting sustained-release bird repellent specifically for power generation comprises the following steps: (1) Dissolving kappa carrageenan (molecular weight of 20,000) and iota carrageenan (molecular weight of 40,000) in water, wherein the mass ratio of kappa carrageenan, iota carrageenan and water is 3:6:100, to obtain a first solution; dissolving houttuynia cordata essential oil, cinnamaldehyde and methyl anthranilate in ethanol, wherein the mass ratio of houttuynia cordata essential oil, cinnamaldehyde, methyl anthranilate and ethanol is 10:12:30:30, to obtain a second solution; dissolving potassium caseinate and calcium caseinate in water, wherein the mass ratio of potassium caseinate, calcium caseinate and water is 0.5:2:100, to obtain a third solution; (2) adding polyvinylidene fluoride resin, musk-T, peppermint oil, antioxidant (ethyl hydroxybenzoate) and antifreeze (propylene glycol) to N-methylpyrrolidone, wherein the mass ratio of polyvinylidene fluoride resin, musk-T, peppermint oil, antioxidant, antifreeze and N-methylpyrrolidone is 10:5:15:0.3:2:20 to obtain a fourth solution; (3) adding the second solution to the first solution, stirring, and then adding the third solution so that the mass ratio of the first solution, the second solution, and the third solution is 5:0.8:10, and then heating to reflux for 35 minutes to obtain a colloidal mixture; (4) After the colloid mixture is cooled to 55° C., the fourth solution is added and stirred, and the mass ratio of the colloid mixture to the fourth solution is 100:1.2. After drying and post-treatment, a colloid agent, i.e., a long-acting sustained-release bird repellent, is obtained.

[0021] Example 2 A method for preparing a long-acting sustained-release bird repellent specifically for power generation comprises the following steps: (1) Dissolving kappa carrageenan (molecular weight of 20,000) and iota carrageenan (molecular weight of 40,000) in water, wherein the mass ratio of kappa carrageenan, iota carrageenan and water is 2.5:7:100, to obtain a first solution; dissolving houttuynia cordata essential oil, cinnamaldehyde and methyl anthranilate in ethanol, wherein the mass ratio of houttuynia cordata essential oil, cinnamaldehyde, methyl anthranilate and ethanol is 10:15:30:30, to obtain a second solution; dissolving potassium caseinate and calcium caseinate in water, wherein the mass ratio of potassium caseinate, calcium caseinate and water is 0.5:2.6:100, to obtain a third solution; (2) adding polyvinylidene fluoride resin, musk-T, peppermint oil, antioxidant (ethyl hydroxybenzoate) and antifreeze (propylene glycol) to N-methylpyrrolidone, wherein the mass ratio of polyvinylidene fluoride resin, musk-T, peppermint oil, antioxidant, antifreeze and N-methylpyrrolidone is 10:4:15:0.4:2.3:20 to obtain a fourth solution; (3) adding the second solution to the first solution, stirring, and then adding the third solution so that the mass ratio of the first solution, the second solution, and the third solution is 5:1:10, and then heating to reflux for 40 minutes to obtain a colloidal mixture; (4) After the colloid mixture is cooled to 60° C., the fourth solution is added and stirred, and the mass ratio of the colloid mixture to the fourth solution is 100:1.7. After drying and post-treatment, a colloid agent, i.e., a long-acting sustained-release bird repellent, is obtained.

[0022] Example 3 A method for preparing a long-acting slow-release bird repellent specifically for power generation comprises the following steps: (1) Dissolving kappa carrageenan (molecular weight of 20,000) and iota carrageenan (molecular weight of 40,000) in water, wherein the mass ratio of kappa carrageenan, iota carrageenan and water is 2:5:100, to obtain a first solution; dissolving houttuynia cordata essential oil, cinnamaldehyde and methyl anthranilate in ethanol, wherein the mass ratio of houttuynia cordata essential oil, cinnamaldehyde, methyl anthranilate and ethanol is 8:15:25:30, to obtain a second solution; dissolving potassium caseinate and calcium caseinate in water, wherein the mass ratio of potassium caseinate, calcium caseinate and water is 0.8:3:100, to obtain a third solution; (2) adding polyvinylidene fluoride resin, musk-T, peppermint oil, antioxidant (ethyl hydroxybenzoate) and antifreeze (propylene glycol) to N-methylpyrrolidone, wherein the mass ratio of polyvinylidene fluoride resin, musk-T, peppermint oil, antioxidant, antifreeze and N-methylpyrrolidone is 10:5:10:0.3:3:20 to obtain a fourth solution; (3) adding the second solution to the first solution, stirring, and then adding the third solution so that the mass ratio of the first solution, the second solution, and the third solution is 5:0.8:10, and then heating to reflux for 40 minutes to obtain a colloidal mixed solution; (4) After the colloid mixture is cooled to 65° C., the fourth solution is added and stirred, and the mass ratio of the colloid mixture to the fourth solution is 100:2. After drying and post-treatment, a colloid agent, i.e., a long-acting sustained-release bird repellent, is obtained.

[0023] Comparative Example 1 The difference from Example 1 is that only iota carrageenan is added.

[0024] The preparation method of the bird repellent comprises the following steps: (1) Dissolving iota carrageenan (molecular weight of 40,000) in water at a mass ratio of iota carrageenan to water of 6:100 to obtain a first solution; dissolving houttuynia cordata essential oil, cinnamaldehyde, and methyl anthranilate in ethanol at a mass ratio of houttuynia cordata essential oil, cinnamaldehyde, methyl anthranilate, and ethanol of 10:12:30:30 to obtain a second solution; dissolving potassium caseinate and calcium caseinate in water at a mass ratio of potassium caseinate, calcium caseinate, and water of 0.5:2:100 to obtain a third solution; (2) adding polyvinylidene fluoride resin, musk-T, peppermint oil, antioxidant (ethyl hydroxybenzoate) and antifreeze (propylene glycol) to N-methylpyrrolidone, wherein the mass ratio of polyvinylidene fluoride resin, musk-T, peppermint oil, antioxidant, antifreeze and N-methylpyrrolidone is 10:5:15:0.3:2:20 to obtain a fourth solution; (3) adding the second solution to the first solution, stirring, and then adding the third solution so that the mass ratio of the first solution, the second solution, and the third solution is 5:0.8:10, and then heating to reflux for 35 minutes to obtain a colloidal mixture; (4) After the colloid mixture is cooled to 55° C., the fourth solution is added and stirred. The mass ratio of the colloid mixture to the fourth solution is 100:1.2. After drying, a colloid agent, i.e., a bird repellent, is obtained.

[0025] Comparative Example 2 The difference from Example 1 is that only calcium caseinate is added.

[0026] The preparation method of the bird repellent comprises the following steps: (1) Dissolving kappa carrageenan (molecular weight of 20,000) and iota carrageenan (molecular weight of 40,000) in water, wherein the mass ratio of kappa carrageenan, iota carrageenan and water is 3:6:100, to obtain a first solution; dissolving houttuynia cordata essential oil, cinnamaldehyde and methyl anthranilate in ethanol, wherein the mass ratio of houttuynia cordata essential oil, cinnamaldehyde, methyl anthranilate and ethanol is 10:12:30:30, to obtain a second solution; dissolving calcium caseinate in water, wherein the mass ratio of calcium caseinate to water is 2:100, to obtain a third solution; (2) adding polyvinylidene fluoride resin, musk-T, peppermint oil, antioxidant (ethyl hydroxybenzoate) and antifreeze (propylene glycol) to N-methylpyrrolidone, wherein the mass ratio of polyvinylidene fluoride resin, musk-T, peppermint oil, antioxidant, antifreeze and N-methylpyrrolidone is 10:5:15:0.3:2:20 to obtain a fourth solution; (3) adding the second solution to the first solution, stirring, and then adding the third solution so that the mass ratio of the first solution, the second solution, and the third solution is 5:0.8:10, and then heating to reflux for 35 minutes to obtain a colloidal mixture; (4) After the colloid mixture is cooled to 55° C., the fourth solution is added and stirred. The mass ratio of the colloid mixture to the fourth solution is 100:1.2. After drying, a colloid agent, i.e., a bird repellent, is obtained.

[0027] Comparative Example 3 The difference from Example 1 is that only potassium citrate and calcium chloride are added.

[0028] The preparation method of the bird repellent comprises the following steps: (1) Dissolving kappa carrageenan (molecular weight of 20,000) and iota carrageenan (molecular weight of 40,000) in water, wherein the mass ratio of kappa carrageenan, iota carrageenan and water is 3:6:100, to obtain a first solution; dissolving houttuynia cordata essential oil, cinnamaldehyde and methyl anthranilate in ethanol, wherein the mass ratio of houttuynia cordata essential oil, cinnamaldehyde, methyl anthranilate and ethanol is 10:12:30:30, to obtain a second solution; dissolving potassium citrate and calcium chloride in water, wherein the mass ratio of potassium citrate, calcium chloride and water is 0.5:2:100, to obtain a third solution; (2) adding polyvinylidene fluoride resin, musk-T, peppermint oil, antioxidant (ethyl hydroxybenzoate) and antifreeze (propylene glycol) to N-methylpyrrolidone, wherein the mass ratio of polyvinylidene fluoride resin, musk-T, peppermint oil, antioxidant, antifreeze and N-methylpyrrolidone is 10:5:15:0.3:2:20 to obtain a fourth solution; (3) adding the second solution to the first solution, stirring, and then adding the third solution so that the mass ratio of the first solution, the second solution, and the third solution is 5:0.8:10, and then heating to reflux for 35 minutes to obtain a colloidal mixture; (4) After the colloid mixture is cooled to 55° C., the fourth solution is added and stirred. The mass ratio of the colloid mixture to the fourth solution is 100:1.2. After drying, a colloid agent, i.e., a bird repellent, is obtained.

[0029] Comparative Example 4 The difference from Example 1 is that the proportion of raw materials added is different.

[0030] The preparation method of the bird repellent comprises the following steps: (1) Dissolving kappa carrageenan (molecular weight of 20,000) and iota carrageenan (molecular weight of 40,000) in water, wherein the mass ratio of kappa carrageenan, iota carrageenan and water is 6:3:100, to obtain a first solution; dissolving houttuynia cordata essential oil, cinnamaldehyde and methyl anthranilate in ethanol, wherein the mass ratio of houttuynia cordata essential oil, cinnamaldehyde, methyl anthranilate and ethanol is 10:12:30:30, to obtain a second solution; dissolving potassium caseinate and calcium caseinate in water, wherein the mass ratio of potassium caseinate, calcium caseinate and water is 2:0.5:100, to obtain a third solution; (2) adding polyvinylidene fluoride resin, musk-T, peppermint oil, antioxidant (ethyl hydroxybenzoate) and antifreeze (propylene glycol) to N-methylpyrrolidone, wherein the mass ratio of polyvinylidene fluoride resin, musk-T, peppermint oil, antioxidant, antifreeze and N-methylpyrrolidone is 10:5:15:0.3:2:20 to obtain a fourth solution; (3) adding the second solution to the first solution, stirring, and then adding the third solution so that the mass ratio of the first solution, the second solution, and the third solution is 5:0.8:10, and then heating to reflux for 35 minutes to obtain a colloidal mixture; (4) After the colloid mixture is cooled to 55° C., the fourth solution is added and stirred. The mass ratio of the colloid mixture to the fourth solution is 100:1.2. After drying, a colloid agent, i.e., a bird repellent, is obtained.

[0031] Bird repellent test: The bird repellents obtained in the examples and comparative examples were used for bird repellent operations on 10KV power lines. Each test area was 1 kilometer, and the number of power towers in each test area was 16. A 200g piece of bird repellent was placed in a matching plastic box within 0.5 meters below the area where birds are likely to cause damage or nest. The box was magnetically attached to the iron frame of the power tower where birds inhabited, with adjacent bird repellents placed 4 to 5 meters apart.

[0032] Bird landings were counted based on landings on the track and its surroundings, with no requirement for the duration of their stay. Bird landings in the corresponding area for 30 consecutive days (June 1st to June 30th) before the installation of the repellent were used as a control. Statistics were collected for each test area over a 30-day period, for a total of three consecutive periods (July 1st to September 28th). Note: Bird populations within the test area remained stable from June to September.

[0033] Table 1 As shown in Table 1, the present invention is compounded by the low toxicity of active ingredient, and compounding effect is good and can obviously enhance efficacy, there is no direct lethality to birds, and the toxicity to humans and other mammals is also relatively low, and, by adding a slow-release gel carrier, the active ingredient load is combined on the slow-release gel carrier, not only can a larger load capacity be provided, the release rate is slowed down, and the infringement of the external environment (such as rain, strong wind) can be resisted, and the drug effect is significantly extended. Comparative Examples 1-2 show that only a kind of carrageenan is added or only a kind of carrageenan is made to form a gel, and the viscosity of the carrier and the active ingredient load effect are all deteriorated, and the strength of the carrier also deteriorates, and the long-term sustained-release effect is not obvious. Comparative Example 3 shows that the addition of casein helps to promote the formation of gel, and helps the stable combination between the carrier and the active ingredient, and the long-term sustained-release effect is better. Comparative Example 4 shows that the present invention can obtain a carrier with suitable viscosity and elasticity by controlling the raw material ratio, can form a good combination with the active ingredient and possess a good sustained-release effect.

[0034] The above are only preferred embodiments of the present invention and are not intended to limit the patent scope of the present invention. Any equivalent structure or equivalent process transformation made using the description of the present invention, or directly or indirectly applied in other related technical fields, are also included in the patent protection scope of the present invention.

Claims

1. A method for preparing a long-acting sustained-release bird repellent for power generation, characterized in that: The steps include: (1) Dissolving kappa carrageenan and iota carrageenan in water to obtain a first solution; dissolving houttuynia cordata essential oil, cinnamaldehyde, and methyl anthranilate in ethanol to obtain a second solution; and dissolving potassium caseinate and calcium caseinate in water to obtain a third solution; (2) adding polyvinylidene fluoride resin, musk-T, peppermint oil, antioxidant and antifreeze agent to N-methylpyrrolidone to obtain a fourth solution; (3) adding the second solution to the first solution, stirring, and then adding the third solution, heating and reacting to obtain a colloidal mixture; (4) After the colloid mixture is cooled, the fourth solution is added and stirred to obtain a colloid agent, i.e., a long-acting sustained-release bird repellent.

2. The method for preparing the long-acting sustained-release bird repellent for power generation as claimed in claim 1, characterized in that: In step (1), the mass ratio of kappa carrageenan, iota carrageenan and water in the first solution is 2-3:5-7:

100.

3. The method for preparing the long-acting sustained-release bird repellent for power use according to claim 1 or 2, wherein: In step (1), the mass ratio of Houttuynia cordata essential oil, cinnamaldehyde, methyl anthranilate and ethanol in the second solution is 5-10:10-15:25-30:

30.

4. The method for preparing the long-acting sustained-release bird repellent for power use according to claim 1 or 2, wherein: In step (1), the mass ratio of potassium caseinate, calcium caseinate and water in the third solution is 0.5-1:2-3:

100.

5. The method for preparing the long-acting sustained-release bird repellent for power generation as claimed in claim 1, characterized in that: In step (3), the mass ratio of the first solution, the second solution and the third solution is 5:0.8~1:

10.

6. The method for preparing the long-acting sustained-release bird repellent for power generation according to claim 1 or 5, characterized in that: In step (3), the heating reaction is to raise the temperature to reflux reaction for 30 to 40 minutes.

7. The method for preparing the long-acting sustained-release bird repellent for power generation according to claim 1 or 5, characterized in that: In step (4), the mass ratio of the colloid mixture to the fourth solution is 100:1-2; and the cooling temperature is 55-65°C.

8. The method for preparing the long-acting sustained-release bird repellent for power generation as claimed in claim 1, characterized in that: In step (2), the mass ratio of polyvinylidene fluoride resin, musk-T, peppermint oil, antioxidant, antifreeze agent and N-methylpyrrolidone in the fourth solution is 10:3~5:10~15:0.1~0.5:2~3:

20.

9. The method for preparing the long-acting sustained-release bird repellent for power generation according to claim 1 or 8, characterized in that: In step (2), the antioxidant is ethyl hydroxybenzoate; and the antifreeze agent is ethylene glycol or glycerol.

10. A method for using the long-acting sustained-release bird repellent prepared by the preparation method according to any one of claims 1 to 9, characterized in that: The method comprises the following steps: applying the device to the power transmission facilities, hanging the device, or placing the device on the ground along the power transmission line.

Citation Information

Patent Citations

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