Preparation method of nickel-based high-temperature alloy based on synergistic strengthening of sawtooth grain boundary and irregular precipitated phase

Abstract

The invention relates to the technical field of nickel-based superalloy forming machining and heat treatment, in particular to a nickel-based superalloy preparation method based on synergistic strengthening of sawtooth grain boundaries and irregular precipitated phases. The preparation method comprises the following steps: carrying out solution treatment, rolling, complete recrystallization annealing and aging treatment on a gamma 'precipitation hardening type nickel-based superalloy blank to obtain the nickel-based superalloy based on synergistic strengthening of the sawtooth grain boundary and the irregular precipitated phase, and the complete recrystallization annealing specifically comprises the following steps: keeping the temperature of the rolled alloy blank at 1050 DEG C for 1-4 hours, and then cooling to 775 DEG C at the cooling speed of 3 DEG C / min. According to the method, the non-uniform precipitation kinetics of the gamma'phase can be controlled, a continuous zigzag structure grain boundary and an irregular butterfly-shaped gamma 'precipitated phase are successfully formed, and the high-temperature ductility of the alloy is improved. The preparation process is simple, convenient, low in cost and suitable for large-scale production.

Description

TECHNICAL FIELD

[0001] The present application relates to the technical field of forming processing and heat treatment of nickel-based superalloys, and particularly relates to a preparation method of a nickel-based superalloy based on synergistic strengthening of serrated grain boundaries and irregular precipitated phases. BACKGROUND

[0002] Superalloys have been widely used in various fields such as aerospace, shipbuilding, petroleum, chemical industry and power due to their excellent high-temperature strength, outstanding oxidation resistance and reliable usability. As early as the 1940s, researchers developed nickel-based superalloys to meet the performance requirements of high-pressure turbine blades in extreme service environments. Nickel-based superalloys have higher service temperature than iron-based alloys due to the high content of Ni element (more than 50%), less harmful phase precipitation, high-temperature thermal corrosion resistance, and better performance than cobalt-based superalloys in turbine blade manufacturing, which can be applied to higher stress and temperature conditions, so it has become the preferred material for hot components of aircraft engines. However, these alloys face a serious problem of intermediate temperature brittleness (ITB), which is characterized by a sharp decrease in the material's plastic deformation ability at 600-900℃, leading to brittle fracture of components at intermediate temperatures. Considering that superalloys usually serve at 600-900℃, intermediate temperature brittleness can adversely affect the reliability of their applications. Therefore, it is particularly important to effectively avoid the problem of intermediate temperature brittleness. SUMMARY

[0003] The purpose of the present application is to provide a preparation method of a nickel-based superalloy based on synergistic strengthening of serrated grain boundaries and irregular precipitated phases, to solve the problem of brittle failure of existing alloys due to flat grain boundaries at 600-900℃.

[0004] To achieve the above-mentioned purpose, the present application provides the following solutions:

[0005] One of the technical solutions of the present application is a preparation method of a nickel-based superalloy based on synergistic strengthening of serrated grain boundaries and irregular precipitated phases, comprising the following steps:

[0006] The gamma prime precipitated hardening type nickel-based superalloy blank is subjected to solid solution treatment, rolling, complete recrystallization annealing and aging treatment to obtain the nickel-based superalloy based on synergistic strengthening of serrated grain boundaries and irregular precipitated phases.

[0007] The complete recrystallization annealing is specifically as follows: the alloy blank after rolling is kept at 1030-1100℃ for 1-4h, and then cooled to 775℃ at a cooling rate of 3℃ / min.

[0008] The second technical solution of the present application is a nickel-based superalloy based on synergistic strengthening of serrated grain boundaries and irregular precipitated phases prepared according to the above preparation method.

[0009] The application discloses a method for preparing a nickel-based high-temperature alloy based on sawtooth grain boundaries and irregular precipitated phase synergistic strengthening.

[0010] The application discloses a turbine disc, and raw materials of the turbine disc comprise the nickel-based high-temperature alloy based on sawtooth grain boundaries and irregular precipitated phase synergistic strengthening.

[0011] The application discloses the following technical effects:

[0012] The application controls the cooling speed after complete recrystallization treatment, adopts a slow cooling process of 3 ℃ / min (decreases at a cooling rate of 3 ℃ / min from 1050 ℃ to 775 ℃), controls the heterogeneous precipitation kinetics of γ' phase, successfully forms continuous sawtooth structure grain boundaries (sawtooth amplitude: 0.85 μm, wavelength between continuous waves: 2.41 μm) and irregular butterfly-shaped γ' precipitated phase, and significantly improves the medium-temperature brittleness resistance of the alloy. Specifically, the sawtooth grain boundaries (SGBs) can significantly increase the crack nucleation and expansion resistance between cracks, and effectively inhibit the grain boundary sliding under high-temperature conditions. In turn, the high-temperature ductility of the alloy can be improved.

[0013] The preparation process of the application is simple, low in cost and suitable for large-scale production. BRIEF DESCRIPTION OF DRAWINGS

[0014] In order to more clearly illustrate the technical solutions of the embodiments of the present application or the prior art, the drawings needed in the embodiments will be briefly introduced below. Obviously, the drawings in the following description are only some embodiments of the present application, and other drawings can also be obtained by those skilled in the art without creative labor.

[0015] Figure 1 It is a backscattered electron image (BSE) of the GH4698 alloy treated by the method of example 1.

[0016] Figure 2 It is a precipitated phase SEM image of the GH4698 alloy treated by the method of example 1.

[0017] Figure 3 It is a transmission electron microscope image of the GH4698 alloy treated by the method of example 1. (a) is a microstructure feature of the sawtooth grain boundary, (b) and (c) are bright field images near the sawtooth grain boundary and corresponding EDS component analysis, respectively, (d) and (e) are bright field images of the γ' precipitated phase and corresponding high-resolution transmission electron microscope images, respectively, (f) and (j) are Fourier transform images of the γ' precipitated phase and the matrix in the high-resolution transmission electron microscope images, respectively.

[0018] Figure 4 Backscattered electron image (BSE) of GH4698 alloy after treatment of Comparative Example 1.

[0019] Figure 5 Scanning electron micrograph of GH4698 alloy after treatment of Comparative Example 1.

[0020] Figure 6 Engineering stress strain curves corresponding to tensile test of GH4698 alloy after treatment of Example 1 in the temperature range of 600-900°C.

[0021] Figure 7 Engineering stress strain curves corresponding to tensile test of GH4698 alloy after treatment of Comparative Example 1 in the temperature range of 600-900°C.

[0022] Figure 8 Metallographic structure of GH4698 alloy after treatment of Comparative Example 2. DETAILED DESCRIPTION

[0023] Various illustrative embodiments of the present application are described in detail below. This detailed description is not intended to be a limitation on the application, but rather an exemplification of the present application. It is thus contemplated that there can be other embodiments of the application that fall within the scope of the present application.

[0024] It is to be understood that the terminology used herein is for the purpose of describing particular embodiments of the application only and is not intended to be limiting of the present application. Additionally, unless otherwise specified, all numerical ranges are to be understood as encompassing every integer, fraction, and sub-range within the range. In other words, each numerical range should be considered as having been reported individually as well as collectively. Additionally, any range of numerical values, either stated or implied, include every value between the ranges' limits, regardless of whether those values are specifically enumerated. The upper and lower limits of these smaller ranges can independently be included or excluded in the range.

[0025] Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this application belongs. Although any methods and materials similar or equivalent to those described herein can be used in the practice or testing of the present application, the preferred methods and materials are described. It is to be understood that the present application is not limited to particular methods or materials, unless otherwise specified.

[0026] Many modifications and variations of this application can be made in the light of the above teachings without departing from the spirit and scope thereof, and it is to be understood that all such modifications and variations fall within the scope of the application. Additional embodiments of the application will readily occur to those skilled in the art. The disclosures of the specification and drawings are to be considered as illustrative only of the principles of the application and are to be considered not as narrowing the present application in any way.

[0027] As used herein, the terms "comprise", "comprising", "include", "including", "have", "having" and the like are open-ended and do not exclude additional, unrecited elements or method steps.

[0028] "room temperature" as described in the present invention, unless otherwise specified, is 20-30℃.

[0029] Serrated grain boundaries (SGBs) are a special structure in the microstructure of high-temperature alloys, usually characterized by wavy undulations, can significantly affect the high-temperature mechanical properties of the material, and can be obtained by controlling the cooling rate. Compared with flat grain boundaries, serrated grain boundaries can significantly enhance the resistance of intergranular crack nucleation and propagation, and effectively inhibit the grain boundary sliding at high temperature, thus showing great potential in relieving the intermediate temperature embrittlement. The present invention builds a serrated grain boundary structure in a nickel-based high-temperature alloy by regulating the cooling rate after recrystallization, aiming to solve the problem of intermediate temperature embrittlement in high-temperature alloys.

[0030] In view of the intermediate temperature embrittlement phenomenon commonly existing in existing nickel-based high-temperature alloys, the present invention controls the cooling rate after complete recrystallization treatment, adopts a slow cooling process of 3℃ / min (1050℃ slow cooling to 775℃), controls the non-uniform precipitation kinetics of γ' phase, successfully forms continuous serrated structure grain boundaries (serrated amplitude: 0.85μm, wavelength between continuous waves: 2.41μm) and irregular butterfly-shaped γ' precipitates, and significantly improves the intermediate temperature embrittlement resistance of the alloy. The method of the present invention is suitable for high-temperature components such as turbine discs and fasteners of aircraft engines.

[0031] The first aspect of the present invention provides a preparation method of a nickel-based high-temperature alloy based on the synergistic strengthening of serrated grain boundaries and irregular precipitates, comprising the following steps:

[0032] The γ' precipitated hardening type nickel-based high-temperature alloy blank is subjected to solid solution treatment, rolling, complete recrystallization annealing and aging treatment to obtain the nickel-based high-temperature alloy based on the synergistic strengthening of serrated grain boundaries and irregular precipitates.

[0033] The complete recrystallization annealing is specifically: the alloy blank after rolling is kept at 1030℃-1100℃ for 1-4h, and then cooled to 775℃ at a cooling rate of 3℃ / min.

[0034] In a preferred embodiment of the present invention, the γ' precipitated hardening type nickel-based high-temperature alloy blank is GH4698 alloy blank.

[0035] In a preferred embodiment of the present invention, the temperature of the solid solution treatment is 1100℃, and the time is 4-8h.

[0036] In a preferred embodiment of the present invention, after the solid solution treatment, the step of water cooling to room temperature is further included.

[0037] In a preferred embodiment of the present invention, the temperature of the rolling is room temperature, and a total of 7 passes of rolling are performed, with a deformation amount of 10% of the initial thickness for each pass.

[0038] In a preferred embodiment of the present invention, the aging treatment specifically involves holding the temperature at 775℃ (γ′ precipitation peak temperature) for 5–16 h (more preferably 5–7 h).

[0039] The solution treatment of this invention allows for the complete re-dissolution of precipitates in the alloy billet, eliminating compositional segregation and internal stress within the billet, which is beneficial for subsequent rolling processes. Room temperature (20–30°C) rolling causes significant grain deformation and introduces numerous crystal defects, including dislocations, stacking faults, and LC lock-in. This is followed by a complete crystallization annealing treatment, cooled to 775°C at a rate of 3°C / min. Finally, an aging treatment is performed to ensure the complete precipitation of γ′.

[0040] This invention employs a method that controls the cooling rate, and the serrated grain boundaries and irregular butterfly-shaped precipitates are formed during the slow cooling process.

[0041] Only at the slow cooling rate (3°C / min) specified in this invention can the grain boundaries be guaranteed to have a serrated morphology. When the cooling rate is too fast, for example, air cooling after complete recrystallization can only produce straight grain boundaries.

[0042] In a preferred embodiment of the present invention, the aging process is further further included by air cooling to room temperature after the aging process is completed.

[0043] A second aspect of the present invention provides a nickel-based superalloy based on the synergistic strengthening of serrated grain boundaries and irregular precipitates, prepared according to the above-described preparation method.

[0044] The nickel-based superalloy based on the synergistic strengthening of serrated grain boundaries and irregular precipitates has serrated grain boundaries and irregular γ′ precipitates; the alloy microstructure consists of uniformly distributed fine equiaxed grains with an average grain size of 15.0 μm, and the grain boundaries exhibit a serrated morphology (serration amplitude: 0.85 μm, wavelength between continuous waves: 2.41 μm); the irregular γ′ precipitates exhibit an irregular butterfly morphology with an average feret diameter of 389.4 ± 133.1 nm.

[0045] The third aspect of this invention provides the application of the above-mentioned nickel-based superalloys based on the synergistic strengthening of serrated grain boundaries and irregular precipitates in the fields of aerospace, shipbuilding, petroleum, chemical or power.

[0046] The present invention provides a nickel-based superalloy that is synergistically strengthened by serrated grain boundaries and irregular precipitates, which is suitable for high service temperature environments; the temperature range of the high service temperature environment is 600-900℃, more preferably 750-850℃.

[0047] A fourth aspect of the present invention provides a turbine disk, the raw material of which includes the above-mentioned nickel-based high-temperature alloy based on the synergistic strengthening of serrated grain boundaries and irregular precipitates.

[0048] Unless otherwise specified, the technical solutions described in this invention are all conventional solutions in the field, and the reagents or raw materials used are all purchased from commercial channels or are publicly available unless otherwise specified.

[0049] The GH4698 alloy billet used in the embodiments and comparative examples of this invention is a GH4698 alloy plate (initial thickness of 6mm), cut from GH4698 alloy hot-rolled bar provided by Guizhou Aerospace Precision Manufacturing Co., Ltd. Its chemical composition is Cr 15.52wt%, Mo 2.91wt%, Ti 2.66wt%, Nb 1.87wt%, Al 1.84wt%, Fe 0.20wt%, Si 0.05wt%, C 0.06wt%, with the balance being Ni and unavoidable impurities.

[0050] The technical solutions provided by the present invention will be described in detail below with reference to the embodiments, but they should not be construed as limiting the scope of protection of the present invention.

[0051] Example 1

[0052] A method for preparing nickel-based superalloys based on the synergistic strengthening of serrated grain boundaries and irregular precipitates, comprising the following steps:

[0053] (1) Solution treatment: The GH4698 alloy billet was placed in a muffle furnace heated to 1100℃ and held for 8 hours, and then cooled to room temperature by water.

[0054] (2) Room temperature rolling: The GH4698 alloy treated in step (1) is rolled for a total of 7 passes at room temperature, with each pass having a deformation amount of 10% of the initial thickness, until the total deformation amount is 70% of the initial thickness, and the final plate thickness is reduced to 1.8 mm.

[0055] (3) Full recrystallization annealing: The GH4698 alloy rolled in step (2) is placed in a muffle furnace heated to 1050℃ and held for 1 hour, and then cooled to 775℃ at a cooling rate of 3℃ / min.

[0056] (4) Aging treatment: After cooling to 775℃ in step (3), continue to hold at 775℃ for 16h, and then air cool to room temperature to obtain a nickel-based superalloy with serrated grain boundaries and irregular butterfly precipitates based on the synergistic strengthening of serrated grain boundaries and irregular precipitates (abbreviated as SC3℃ / min).

[0057] Figure 1 Backscattered electron image (BSE) of GH4698 alloy after processing in Example 1. Figure 1It can be seen that the SC3℃ / min sample exhibits uniformly distributed fine equiaxed grains with an average grain size of 15.0μm. After slow cooling treatment, the alloy grain boundaries were distorted and exhibited a sawtooth shape. The statistical results of the grain boundary amplitude and the wavelength between the continuous peaks were 0.85μm and 2.41μm, respectively.

[0058] Figure 2 This is a SEM image of the precipitated phases in the GH4698 alloy after treatment in Example 1. Figure 2 It can be seen that the γ' precipitate of the alloy changes after slow cooling treatment, exhibiting an irregular butterfly-shaped morphology with an average feret diameter of 389.4±133.1 nm.

[0059] Figure 3 The images are transmission electron microscope (TEM) images of the GH4698 alloy after treatment in Example 1. Among them, (a) shows the microstructure characteristics of the serrated grain boundaries, (b) and (c) are bright-field images near the serrated grain boundaries and their corresponding EDS composition analyses, respectively, (d) and (e) are bright-field images of the γ′ precipitates and their corresponding high-resolution TEM images, respectively; (f) and (j) are Fourier transform diagrams of the γ′ precipitates and the matrix in the high-resolution TEM images, respectively.

[0060] Depend on Figure 3 As can be seen from (a), (b), and (c), there is a direct correlation between the precipitation behavior of the γ′ precipitate at the grain boundaries and the formation of serrated grain boundaries. For example... Figure 3 As shown in (b) and (c), a significant one-to-one or one-to-many correspondence can be observed between the serrated grain boundaries and the precipitated phase: each serrated protrusion or depression distributed along the grain boundary is clearly adjacent to one or more γ′ precipitate phase particles that preferentially precipitate on the grain interface, confirming that the precipitated phase is γ′-Ni3(Al / Ti). Figure 3 (d)(e)(f) confirmed that the irregular butterfly-shaped γ' precipitate phase is coherent with the GH4698 alloy matrix and is also an FCC phase.

[0061] Comparative Example 1 (without rolling process)

[0062] A method for preparing a nickel-based superalloy, comprising the following steps:

[0063] (1) Solution treatment: The GH4698 alloy billet was placed in a muffle furnace heated to 1110℃ and held for 8 hours, and then air-cooled to room temperature;

[0064] (2) First aging: The GH4698 alloy treated in step (1) is placed in a muffle furnace heated to 1000℃ and held for 4 hours, and then air-cooled to room temperature;

[0065] (3) Secondary aging: The GH4698 alloy treated in step (2) is placed in a muffle furnace heated to 775°C and held for 16 hours, and then air-cooled to room temperature; (The processing technology of this comparative example is carried out according to the traditional standard heat treatment, and the product obtained is referred to as SHT).

[0066] Figure 4 This is a backscattered electron image (BSE) of the GH4698 alloy after processing in Comparative Example 1. (Source: [Insert Source Here]) Figure 4 It can be seen that after treatment with Comparative Example 1, the grains of GH4698 alloy consist of coarse equiaxed grains with relatively straight grain boundaries and an average grain size of 197.3 μm. At the same time, a large number of annealed twins were also observed.

[0067] Figure 5 This is a scanning electron microscope (SEM) image of the GH4698 alloy after treatment in Comparative Example 1. Figure 5 It can be seen that after treatment with Comparative Example 1, the spherical γ′ precipitates are uniformly distributed in the γ matrix. The γ′ precipitates exist in two sizes, large and small, with diameters ranging from 100 to 300 nm and 20 to 50 nm, respectively, and average sizes of 214.5 nm and 41.5 nm, respectively.

[0068] Comparative Example 2

[0069] The only difference from Example 1 is that in step (3), "cooling to 775°C at a cooling rate of 3°C / min" is changed to "air cooling to 775°C".

[0070] Figure 8 The image shows the metallographic structure of the GH4698 alloy after treatment in Comparative Example 2. Figure 8 It can be seen that after complete recrystallization, rapid cooling (air cooling) results in a microstructure with straight grain boundaries and no obvious serrated features.

[0071] Stress-strain testing:

[0072] The products of Example 1 and Comparative Examples 1-2 were subjected to high-temperature tensile tests at 600–900°C. The high-temperature tensile tests were performed using an XforceK universal testing machine with a uniaxial tensile rate set to 1 mm / min. The specimens were held at the target temperature for 10 min before the tensile test. The parallel section dimensions of the tensile specimens were 26.5 × 1.5 × 1.8 mm. 3 The test results are as follows: Figures 6-7 As shown in Table 1.

[0073] Figure 6 The tensile test results of the GH4698 alloy treated in Example 1 are the engineering stress-strain curves corresponding to the tensile test in the temperature range of 600-900℃.

[0074] Figure 7The tensile test results of GH4698 alloy after Comparative Example 1 are shown as engineering stress-strain curves in the temperature range of 600-900℃.

[0075] Table 1

[0076]

[0077]

[0078] Note: "-" in the table indicates that no test was performed.

[0079] Table 1 shows the tensile strength (UTS), elongation at break (EL), and strength-ductility product of the samples treated in Example 1 and Comparative Examples 1-2. Figures 6-7 As shown in Table 1, the GH4698 alloy treated in Comparative Example 1 exhibits significant embrittlement at intermediate temperatures of 600-900℃, which poses a serious threat to the reliability of manufacturing and application. In contrast, the SC3℃ / min sample treated in Example 1 did not exhibit intermediate-temperature brittle fracture (ITB) at any temperature, a fact clearly demonstrated in the engineering stress-strain curves.

[0080] The elongation at break (EL) of the GH4698 alloy treated in Comparative Example 2 was 21.0% at room temperature, but only 2.4% at 750°C. Strength-ductility product is a comprehensive indicator reflecting the strength and toughness of metallic materials. As shown in Table 1, the strength-ductility product of the GH4698 alloy treated in Example 2 at room temperature and 750°C was 27762 and 2032.8 MPa·%, respectively, far lower than that of Example 1. This indicates that although the GH4698 alloy treated in Comparative Example 2 has high strength, its toughness is poor. For critical components such as aero-engine turbine disks, high strength can withstand enormous centrifugal stress, but good ductility allows the material to redistribute stress and blunt crack tips through localized plastic deformation when stress concentration or micro-defects occur, thus avoiding catastrophic low-stress brittle fracture. Conversely, too low ductility leads to brittle fracture characteristics, extreme sensitivity to micro-defects, and rapid, unpredictable crack propagation once initiation, making catastrophic low-stress fracture highly likely under normal operating conditions. Such sudden failure not only causes components to lose their damage tolerance and fatigue life, but also jeopardizes the safety of the entire system. One of the core objectives of modern advanced high-temperature alloy design, such as powder metallurgy high-temperature alloys and dual-performance heat-treated turbine disk technology, is to maintain high strength while striving to avoid a decrease in ductility and toughness. Therefore, sufficient ductility is a necessary condition for ensuring structural reliability, and its value far exceeds the limited benefits of simply pursuing strength indicators.

[0081] The embodiments described above are merely preferred embodiments of the present invention and are not intended to limit the scope of the present invention. Various modifications and improvements made by those skilled in the art to the technical solutions of the present invention without departing from the spirit of the present invention should fall within the protection scope defined by the claims of the present invention.

Claims

1. A method for preparing nickel-based superalloys based on synergistic strengthening by serrated grain boundaries and irregular precipitates, characterized in that, Includes the following steps: The nickel-based superalloy based on synergistic strengthening by serrated grain boundaries and irregular precipitates was obtained by solution treatment, rolling, full recrystallization annealing and aging treatment of γ′ precipitation hardening nickel-based superalloy billet. The complete recrystallization annealing specifically involves holding the rolled alloy billet at 1030℃~1100℃ for 1~4h, and then cooling it to 775℃ at a cooling rate of 3℃ / min.

2. The method for preparing nickel-based superalloys based on the synergistic strengthening of serrated grain boundaries and irregular precipitates according to claim 1, characterized in that, The γ′ precipitation-hardening nickel-based superalloy billet is a GH4698 alloy billet.

3. The method for preparing nickel-based superalloys based on the synergistic strengthening of serrated grain boundaries and irregular precipitates according to claim 1, characterized in that, The solution treatment is performed at a temperature of 1100℃ for 4–8 hours.

4. The method for preparing nickel-based superalloys based on the synergistic strengthening of serrated grain boundaries and irregular precipitates according to claim 1, characterized in that, The solution treatment process also includes a step of cooling to room temperature with water.

5. The method for preparing nickel-based superalloys based on the synergistic strengthening of serrated grain boundaries and irregular precipitates according to claim 1, characterized in that, The rolling temperature is room temperature, and the rolling is carried out in 7 passes, with the deformation amount in each pass being 10% of the initial thickness.

6. The method for preparing nickel-based superalloys based on the synergistic strengthening of serrated grain boundaries and irregular precipitates according to claim 1, characterized in that, The aging process specifically involves maintaining the temperature at 775℃ for 5–16 hours.

7. The method for preparing nickel-based superalloys based on the synergistic strengthening of serrated grain boundaries and irregular precipitates according to claim 1, characterized in that, The aging process also includes a step of air cooling to room temperature after the aging process is completed.

8. A nickel-based superalloy based on the synergistic strengthening of serrated grain boundaries and irregular precipitates, prepared by the preparation method according to any one of claims 1 to 7.

9. The application of the nickel-based superalloy based on the synergistic strengthening of serrated grain boundaries and irregular precipitates as described in claim 8 in the fields of aerospace, shipbuilding, petroleum, chemical or power.

10. A turbine disk, characterized in that, The raw materials include the nickel-based superalloy based on the synergistic strengthening of serrated grain boundaries and irregular precipitates as described in claim 8.

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