Equipment for degrading biomass hybrid nano functional material by peroxidation catalytic free radicals
By using a single set of equipment to prepare nanomaterials through the degradation of biomass by peroxidation catalytic free radicals, the limitations of traditional materials in application have been solved, enabling the application of biomass in organic water-soluble fertilizers, feed, food, and biopharmaceuticals, while being environmentally friendly and efficient.
Patent Information
- Authority / Receiving Office
- CN · China
- Patent Type
- Applications(China)
- Current Assignee / Owner
- SHANGHAI MINGDI ENERGY SAVING TECHNOLOGY CO LTD
- Filing Date
- 2025-12-29
- Publication Date
- 2026-04-17
AI Technical Summary
Existing technologies lack equipment for biomass hybrid functional materials, and traditional hybrid functional materials are mainly used in catalysts, sensors, batteries and solar cells, without involving the application of biomass in organic water-soluble fertilizers, feed, food and biopharmaceutical fields.
Biomass is degraded by peroxidation catalytic free radicals. The biomass hybrid nanomaterials are prepared using equipment such as a biomass aqueous solution storage tank, a peroxidation catalytic degradation machine, a catalyst tank, a high-speed circulating shear nanomachine, a laser particle nano-online controller, a biosynthetic hybrid reactor, an inorganic nano tank, a high-speed circulating impactor, and an AI intelligent controller. These materials are used to produce nano-organic water-soluble fertilizers, nano-feeds, nano-foods and health products, and nano-biopharmaceuticals.
It achieves efficient degradation of biomass, producing nanomaterials suitable for multiple fields, and the entire process produces no odorous greenhouse gases or wastewater emissions, meeting the standards and requirements of relevant fields.
Smart Images
Figure CN121869835A_ABST
Abstract
Description
Technical Field
[0001] This invention belongs to the field of biosynthetic organic-inorganic hybrid functional materials, and particularly relates to a device for degrading biomass hybrid nanomaterials using peroxidation catalytic free radicals. Background Technology
[0002] The meaning of "functional hybrid materials" can be found in the reference "Functional Hybrid Materials [Spain] Pedro Cománz Romano, [France] Clément Sanchez, eds., translated by Zhang Xuejun and Chi Weidong, Chemical Industry Press, 2006.3".
[0003] Currently, hybrid reaction organic materials both domestically and internationally are made from artificially synthesized high-molecular organic compounds such as organosilanes.
[0004] Inorganic intercalation materials, which are not made from natural biomass (organic waste and non-organic waste), are all artificially synthesized, though some contain natural components.
[0005] Traditional hybrid functional materials are mainly used in catalysts, sensors, batteries, and solar cell adsorbents. There are no hybrid functional materials for biomass; they are used in organic water-soluble fertilizers, feed, food, and biopharmaceuticals. Summary of the Invention
[0006] The purpose of this invention is to address the aforementioned problems in the preparation of hybrid nanofunctional materials by providing an apparatus for degrading biomass hybrid nanofunctional materials using peroxidation catalytic free radicals. This apparatus is used to degrade biomass through a hybrid reaction to produce biosynthetic nanofunctional materials, which can be used to produce nano-organic water-soluble fertilizers, nano-feeds, nano-foods and health products, nano-biopharmaceuticals, and many other fields.
[0007] The principle of this invention is that biomass consists of organic polymers connected by oxygen atoms. Through the catalytic degradation reaction of hydrogen free radicals HO2· and oxygen free radicals OH·, a molecule of water and a molecule of oxygen O2 are generated respectively, which breaks the organic polymers apart. Finally, nano-sized small molecules are formed, which are then transformed into hybrid nano-functional materials through the hybridization reaction of nano-inorganic materials.
[0008] To achieve the above-mentioned objectives, the technical solution adopted by this invention is as follows: An apparatus for degrading biomass hybrid nanomaterials using peroxide catalytic free radicals includes: a biomass aqueous solution storage tank, a peroxide catalytic degradation machine, a catalyst tank, a high-speed circulating shear nanomachine, a laser particle nanomachine online controller, a biosynthetic hybrid reactor, an inorganic nanochannel, a high-speed circulating impactor, an AI intelligent controller, and a biosynthetic hybrid nanomaterial storage tank. The biomass outlet of the biomass aqueous solution storage tank is connected to the biomass inlet of the peroxide catalytic degradation machine via a pipe valve. The catalyst outlet of the catalyst tank is connected to the catalyst inlet of the peroxide catalytic degradation machine via a pipe valve. The outlet of the peroxide catalytic degradation machine is connected to the biomass inlet of the biomass hydrochemical reactor. The feed end of the high-speed circulating shear nanomachine is connected to the feed end of the high-speed circulating impact machine via a pipe valve. The discharge end of the high-speed circulating shear nanomachine is connected to the feed end of the high-speed circulating impact machine via a pipe valve. The discharge end of the high-speed circulating impact machine is connected to the feed end of the biosynthetic hybrid reactor via a pipe valve. The discharge end of the biosynthetic hybrid reactor is connected to the feed end of the biosynthetic synthetic nanomaterial storage tank via a pipe valve. The AI intelligent controller is connected to the peroxide catalytic degradation machine, the high-speed circulating shear nanomachine, the high-speed circulating impact machine, and the biosynthetic hybrid reactor. The laser particle nanotechnology online controller is connected to the high-speed circulating shear nanomachine.
[0009] In a preferred embodiment of the present invention, the peroxidation catalytic degradation machine is composed of an oxygen enrichment machine, a peroxide machine, and a catalytic degradation machine, wherein the oxygen enrichment machine and the peroxide machine are connected to the catalytic degradation machine.
[0010] In a preferred embodiment of the present invention, the catalyst in the catalyst tank is a mixture of ferrous hydroxyoxide, manganese hydroxyoxide, and titanium hydroxyoxide, and the mass ratio of ferrous hydroxyoxide, manganese hydroxyoxide, and titanium hydroxyoxide is 1-1.5:1-1.8:0.8-0.2.
[0011] In a preferred embodiment of the present invention, the amount of catalyst added is 2wt%-6wt% of the biomass material.
[0012] In a preferred embodiment of the present invention, the peroxidation active free radicals added by the peroxidation catalytic degradation machine to the biomass aqueous solution storage tank are hydrogen free radicals HO2· and oxygen free radicals OH·, and the total volume added is 5%-20% of the total volume of the biomass aqueous solution in the biomass aqueous solution storage tank.
[0013] In a preferred embodiment of the present invention, the high-speed cyclic shearing nanomachine has a rotation speed of 3000 rpm to 6000 rpm, and the cyclic shearing time is controlled by an online laser particle nanomachine controller.
[0014] In a preferred embodiment of the present invention, the speed of the high-speed cyclic impact machine is controlled at 10,000 rpm to 7,000 rpm, and the Newton force is controlled at 0.3 N to 0.8 N.
[0015] In a preferred embodiment of the present invention, the biosynthetic hybrid reactor is used for inorganic nanomaterials in hybrid reactions, wherein the inorganic nanomaterials in hybrid reactions include a variety of nano-aqueous solutions leached from natural volcanic ash, a variety of nano-aqueous solutions leached from natural maifanite, and one of the following: nano-scale macro-elements, medium-scale elements, and micro-elements used in fertilizers.
[0016] In a preferred embodiment of the present invention, the amount of inorganic nanomaterials used in the biosynthetic hybrid reactor for the hybrid reaction is controlled according to the national standard GB / T 17419-2018 for nano water-soluble fertilizers, including limiting elements.
[0017] In a preferred embodiment of the present invention, the amount of nano-trace elements and phosphorus and calcium elements added to the feed is controlled according to the corresponding national standards for each livestock and poultry breed. In a preferred embodiment of the present invention, the limiting elements are controlled in accordance with the feed hygiene standard GB / T13078-2017.
[0018] In a preferred embodiment of the present invention, the food and health food products can be made in accordance with the corresponding national food safety standards and the General Hygiene Standard for Food GB14880-2025.
[0019] In a preferred embodiment of the present invention, the limited elements are used in biopharmaceuticals, and the limited elements are controlled in accordance with the provisions of the 2025 edition of the pharmacopoeia.
[0020] This invention produces biosynthetic hybrid nanomaterials from biomass (including organic and non-organic waste) through peroxidation catalytic degradation and high-speed shearing nanomachines, a biosynthetic hybrid reactor, a high-speed circulating impactor, an inorganic nano tank, and a biosynthetic nanomaterial storage tank. These materials have applications in fertilizers, feed, food, and biopharmaceuticals. The entire production process produces no odorous greenhouse gases or wastewater emissions. Attached Figure Description
[0021] Figure 1 This is a schematic diagram of the device for degrading biomass hybrid nanomaterials using peroxidation catalytic free radicals according to the present invention.
[0022] The attached diagram shows: 1. Biomass aqueous solution storage tank; 2. Peroxidation catalytic degradation machine; 2-1. Catalyst tank; 3. High-speed circulating shearing nanomachine; 3-1. Laser particle nano-online controller; 4. Biosynthetic hybrid reactor; 4-1. Inorganic nano tank; 4-2. High-speed circulating impact machine; 5. AI intelligent controller; 6. Biohybrid synthesis nanofunctional material storage tank. Detailed Implementation
[0023] To make the objectives, preferred technical solutions, and advantages such as innovation and practicality of the present invention clearer, the present invention will be further described in detail below with reference to the accompanying drawings and embodiments. It should be understood that the specific embodiments described herein are only used to explain the present invention and are not intended to limit the present invention.
[0024] The specific implementation of the present invention will be described in detail below with reference to specific embodiments.
[0025] like Figure 1 As shown, this is a complete set of equipment for producing hybrid nanomaterials by degrading biomass using peroxidation catalytic free radicals according to an embodiment of the present invention. It includes a biomass aqueous solution storage tank 1, a peroxidation catalytic degradation machine 2, a catalyst tank 2-1, a high-speed circulating shear nanomachine 3, a laser particle nanomachine online controller 3-1, a biosynthetic hybrid reactor 4, an inorganic nano tank 4-1, a high-speed circulating impact machine 4-2, an AI intelligent controller 5, and a biosynthetic nanomaterials storage tank 6.
[0026] The discharge end of biomass aqueous solution storage tank 1 is connected to the first inlet of 2 via a pipe valve. The discharge port of 2-1 is connected to the second inlet of 2 via a pipe valve. The discharge port of 2 is connected to the inlet of 3 via a pipe valve. 3-1 is connected to the sensor interface of 3 via a sensor. The discharge port of 3 is connected to the first inlet of 4 via a pipe valve. The discharge port of 4-1 is connected to the second inlet of 4 via a pipe valve. The discharge port of 4-2 is connected to the third inlet of 4 via a pipe valve. The discharge port of 4 is connected to the inlet of 6 via a pipe valve pump. 5 is connected to 2, 3, 4, and 4-2 via an electrical wire.
[0027] The preferred embodiment shown as 2 consists of an oxygen generator and a catalytic degradation machine connected in series. The catalysts are ferrous hydroxyl oxide, manganese hydroxyl oxide, and titanium hydroxyl oxide, with a ratio of 1:1:0.5. The amount added is 3% of the biomass weight. The active free radicals for peroxidation are hydrogen free radical HO2· and oxygen free radical OH·, and the total volume added is 10% of the biomass solution volume.
[0028] Preferably, the rotation speed of the 3 is 6000 rpm, and the Newtonian force is controlled at 0.4 N.
[0029] The preferred inorganic nanomaterials used in the hybridization reaction of 4 include various nano-aqueous solutions leached from natural volcanic ash, various nano-aqueous solutions leached from natural maifanite, and nano-scale macro-, meso-, and micro-elements for fertilizers. Also included are micro-elements and dicalcium phosphate for feed.
[0030] Organic waste in biomass used for organic water-soluble fertilizers includes crop straw, human and animal manure, kitchen waste, green waste, and organic waste generated from the production of products using animal and plant residues as raw materials. The mixed inorganic part consists of macro, medium, and micro elements, and the proportions and amounts are controlled in accordance with the GB / T17419-2018 standard.
[0031] Non-organic wastes in biomass used as raw materials for livestock and poultry feed include fishmeal containing crude protein, soybean meal, starch containing carbohydrates, inorganic hybrid materials containing trace elements, and dicalcium phosphate. The proportion and limit elements are controlled in accordance with GB13078-2017 feed hygiene standards and feed standards for various breeds such as pigs, chickens, cattle, and sheep.
[0032] The organic component used in commercial food and health food is various meats, eggs, and milk rich in protein from biomass, while the inorganic component is the proportion and limit of natural maifan stone nano-extract, controlled in accordance with the national food safety standard General Hygiene Specifications for Food Production GB4881-2025.
[0033] The organic biomass formulations of traditional Chinese medicines used in biopharmaceuticals, as well as the inorganic natural maifanite nano-extract formulations and limited elements, shall be controlled in accordance with the provisions of the 2025 edition of the Pharmacopoeia.
Claims
1. An apparatus for degrading biomass hybrid nano-functional materials by catalytic free radicals using peroxide, characterized in that, include: The system comprises a biomass aqueous solution storage tank, a peroxide catalytic degradation machine, a catalyst tank, a high-speed circulating shear nanomachine, a laser particle nanomachine online controller, a biosynthetic hybrid reactor, an inorganic nanocage, a high-speed circulating impactor, an AI intelligent controller, and a biosynthetic nanomaterials storage tank. The biomass outlet of the biomass aqueous solution storage tank is connected to the biomass inlet of the peroxide catalytic degradation machine via a pipe valve. The catalyst outlet of the catalyst tank is connected to the catalyst inlet of the peroxide catalytic degradation machine via a pipe valve. The outlet of the peroxide catalytic degradation machine is connected to the inlet of the high-speed circulating shear nanomachine via a pipe valve. The high-speed circulating shearing nanomachine is connected to the high-speed circulating impactor via a pipe valve. The discharge end of the high-speed circulating impactor is connected to the feed end of the biosynthetic hybrid reactor via a pipe valve. The discharge end of the biosynthetic hybrid reactor is connected to the feed end of the biosynthetic synthetic nanomaterial storage tank via a pipe valve. The AI intelligent controller is connected to the peroxide catalytic degradation machine, the high-speed circulating shearing nanomachine, the high-speed circulating impactor, and the biosynthetic hybrid reactor. The laser particle nanotechnology online controller is connected to the high-speed circulating shearing nanomachine.
2. The apparatus for degrading biomass hybrid nanofunctional material by catalytic free radicals of peroxide according to claim 1, characterized in that, The peroxidation catalytic degradation machine consists of an oxygen enrichment machine, an oxygen peroxide machine, and a catalytic degradation machine, wherein the oxygen enrichment machine and the oxygen peroxide machine are connected to the catalytic degradation machine.
3. The apparatus for degrading biomass hybrid nanofunctional material by catalytic free radicals of peroxide according to claim 2, characterized in that, The catalyst in the catalyst tank is a mixture of ferrous hydroxyoxide, manganese hydroxyoxide, and titanium hydroxyoxide, with a mass ratio of 1-1.5:1-1.8:0.8-0.
2.
4. The apparatus for degrading biomass hybrid nanofunctional material by catalytic free radicals of peroxide according to claim 3, characterized in that, The amount of catalyst added is 2wt%-6wt% of the biomass material.
5. The apparatus for degrading biomass hybrid nanomaterials using peroxidation catalytic free radicals according to claim 4, characterized in that, The peroxidation active free radicals added to the biomass aqueous solution storage tank by the peroxidation catalytic degradation machine are hydrogen free radicals HO2· and oxygen free radicals OH·, and the total volume added is 5%-20% of the total volume of the biomass aqueous solution in the biomass aqueous solution storage tank.
6. The apparatus for degrading biomass hybrid nanomaterials using peroxidation catalytic free radicals according to claim 5, characterized in that, The high-speed cyclic shearing nanomachine has a rotation speed of 3000 rpm to 6000 rpm, and the cyclic shearing time is controlled by an online laser particle nanomachine controller.
7. The apparatus for degrading biomass hybrid nanomaterials using peroxidation catalytic free radicals according to claim 6, characterized in that, The speed of the high-speed cyclic impact machine is controlled between 10,000 rpm and 7,000 rpm, and the Newton force is controlled between 0.3 N and 0.8 N.
8. The apparatus for degrading biomass hybrid nanomaterials using peroxidation catalytic free radicals according to claim 7, characterized in that, The aforementioned biosynthetic hybrid reactor is used for the inorganic nanomaterials of the hybrid reaction. The inorganic nanomaterials of the hybrid reaction include a variety of nano-aqueous solutions leached from natural volcanic ash, a variety of nano-aqueous solutions leached from natural maifanite, and one of the following nano-scale macro-elements, medium-scale elements, and micro-elements used in fertilizers.
9. The apparatus for degrading biomass hybrid nanomaterials using peroxidation catalytic free radicals according to claim 8, characterized in that, The amount of inorganic nanomaterials used in the biosynthetic hybrid reactor for the hybrid reaction, including limiting elements, is controlled according to the national standard GB / T 17419-2018 for nano water-soluble fertilizers.
10. The apparatus for degrading biomass hybrid nanomaterials using peroxidation catalytic free radicals according to claim 9, characterized in that, The amount of nano-trace elements, phosphorus and calcium elements added to feed shall be controlled according to the corresponding national standards for each livestock and poultry breed.
11. The apparatus for degrading biomass hybrid nanomaterials using peroxidation catalytic free radicals according to claim 10, characterized in that, Limit elements are controlled in accordance with the feed hygiene standard GB / T13078-2017.
12. The apparatus for degrading biomass hybrid nanomaterials using peroxidation catalytic free radicals according to claim 11, characterized in that, For use in food and health food products, the relevant national food safety standards and general food hygiene standards GB14880—2025 shall apply.
13. The apparatus for degrading biomass hybrid nanomaterials using peroxidation catalytic free radicals according to claim 12, characterized in that, The restricted elements are used in biopharmaceuticals and are controlled in accordance with the new 2025 edition of the pharmacopoeia.