A lithium manganese iron phosphate material and a preparation method thereof

By employing a multi-stage complexation co-precipitation process and carbon source sintering technology, the problem of uniform distribution of manganese iron elements in lithium iron phosphate materials was solved, resulting in high-voltage, high-capacity, and excellent rate performance lithium manganese iron phosphate materials, which significantly improves the energy density and cycle stability of batteries.

CN122403401APending Publication Date: 2026-07-17湖南泓原新能源科技有限公司

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
湖南泓原新能源科技有限公司
Filing Date
2026-05-07
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

The uniform distribution of manganese and iron elements in existing lithium iron phosphate materials is difficult, leading to micro-phase separation and the formation of nanoscale iron-rich and manganese-rich phase regions. This results in reduced energy efficiency and structural failure, making it difficult to meet the requirements for high energy density and long cycle life.

Method used

A multi-stage complexation coprecipitation process is adopted, which utilizes the stepwise complexation effect of different complexing agents at different temperatures and pH to achieve molecular-level uniform mixing of manganese and iron ions in the liquid phase. The manganese and iron ions are then fixed in the crystal lattice by carbon source and sintering process to suppress phase separation.

Benefits of technology

Atomic-level uniformity of manganese and iron elements was achieved, and the material exhibited a single voltage plateau during charge and discharge, which improved voltage efficiency and energy density and extended cycle life.

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Abstract

本申请涉及锂电池领域,公开了一种磷酸锰铁锂材料及其制备方法。该方法包括以下步骤:将锂源、锰源、铁源和磷源溶于去离子水中,形成预混液;向预混液中加入第一络合剂,进行第一次络合反应;反应结束后加入第二络合剂,进行第二次络合反应;加入沉淀剂,进行共沉淀反应,得到前驱体悬浊液;将前驱体悬浊液陈化、过滤、洗涤、干燥,得到前驱体粉末;将前驱体粉末与碳源机械混合,得到混合料,将混合料烧结,粉碎,得到磷酸锰铁锂材料。本申请的方法通过两次络合反应显著提升了材料的均匀性和电化学稳定性。所得磷酸锰铁锂材料具有高比容量、优异的循环性能和热稳定性,适用于锂离子电池正极材料,能有效提升电池的能量密度和安全性。
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