A fiber reinforced polymer derived ceramic-based wave-absorbing composite material and a preparation method thereof

By depositing an interface layer on the surface of the fiber preform and using an impregnation and pyrolysis process to protect the matrix, the problem of fiber-ceramic matrix composite at high temperatures was solved, and a high-performance fiber-reinforced ceramic matrix composite material was prepared. This composite material has excellent dielectric properties and electromagnetic wave absorption capabilities and is suitable for high-temperature environments.

CN122403992APending Publication Date: 2026-07-17ZHEJIANG SCI-TECH UNIV
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
ZHEJIANG SCI-TECH UNIV
Filing Date
2026-04-23
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies struggle to effectively combine high-melting-point, high-strength fibers with ceramic matrices under high-temperature conditions. Traditional preparation methods are energy-intensive and prone to fiber damage, failing to meet the material stability and electromagnetic wave absorption requirements under high temperature and pressure.

Method used

An interface layer and a protective matrix were deposited on the surface of the fiber preform using the impregnation pyrolysis (PIP) process. A SiC or Si3N4 interface layer was deposited on the fiber surface using low-pressure chemical vapor deposition technology. Combined with polycarbosilane and polysilazane solutions, a fiber-reinforced ceramic matrix composite material with excellent dielectric properties was prepared.

Benefits of technology

A high-temperature stable fiber-reinforced ceramic matrix composite material was prepared under low pressure, which improved dielectric properties and electromagnetic wave absorption capacity, reduced energy consumption, and enhanced the toughness and fracture resistance of the material, making it suitable for industrial applications.

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Abstract

本发明公开了一种纤维增强聚合物衍生陶瓷基吸波复合材料及其制备方法,属于陶瓷基复合材料和磁波材料技术领域。制备包括:首先在纤维预制体表面沉积界面,然后沉积一定厚度的SiC和 / 或Si3N4基体对界面进行保护得到纤维预制体,将其置于经惰性有机溶剂稀释的聚碳硅烷溶液、聚硅氮烷溶液或聚碳硅烷‑聚硅氮烷混合溶液中,进行真空超声浸渍并设定时长;浸渍完毕后,将该纤维预制体转移至烘箱内完成首次固化交联;随后放入高温炉中实施裂解处理,制得纤维增强型聚合物衍生陶瓷基复合材料;最终对所得复合材料开展高温热处理工艺。本发明通过上述方法,使得陶瓷基复合材料在保证力学性能的同时大幅提升其吸波性能。
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