High-toughness nanocomposite ceramic and preparation method and application thereof

By processing polyimide fiber felt and modified waste ceramic powder, and by applying modifiers and modified alumina whiskers, high-toughness nanocomposite ceramics were prepared, which solved the shortcomings of existing ceramics in terms of refractoriness, flexural strength, fracture toughness, wear resistance, water resistance and corrosion resistance, and achieved a comprehensive improvement in material properties.

CN122404007APending Publication Date: 2026-07-17CHAOZHOU HUAZHONG CERAMIC IND CO LTD
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
CHAOZHOU HUAZHONG CERAMIC IND CO LTD
Filing Date
2026-05-12
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing high-toughness nanocomposite ceramics have shortcomings in terms of fire resistance, flexural strength, fracture toughness, wear resistance, water resistance, dimensional stability and corrosion resistance, especially in terms of interfacial bonding strength, matrix density and high-temperature stability, which need to be improved.

Method used

High-toughness nanocomposite ceramics were prepared by subjecting polyimide fiber felt to oxygen low-temperature plasma treatment and silane coupling agent KH550 vapor-phase grafting treatment, combined with impregnation and curing of a composite slurry containing modified waste ceramic powder and nano zinc oxide powder, followed by hot pressing curing and multiple aqueous Soxhlet extraction purification treatments. The modified waste ceramic powder was further modified by citric acid ultrasonic etching and silane coupling agent KH570 surface modification. Nano silica was prepared using a sol-gel method for surface modification, and modified alumina whiskers were treated with hydrogen peroxide hydroxylation to form strong mechanical interlocking interfaces and chemical bonds, thereby improving material properties.

Benefits of technology

It significantly improves the material's fire resistance, flexural strength, fracture toughness, wear resistance, water resistance, and corrosion resistance. By improving interfacial bonding, matrix density, and high-temperature stability, it fully realizes the toughening effect of fibers.

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Abstract

本发明公开了一种高韧性纳米复合陶瓷及其制备方法与应用,涉及陶瓷技术领域。本发明包括以下步骤:先对聚酰亚胺纤维毡进行氧气低温等离子体处理,之后进行硅烷偶联剂KH550气相接枝处理,然后用复合浆料进行5‑7次浸渍固化处理,最后装入模具进行热压固化成型处理,冷却后经后处理,得到高韧性纳米复合陶瓷。其中,复合浆料由改性废瓷粉、纳米氧化锌粉末、乙酸锌、磷酸二氢钠、硼酸、针状硅灰石粉、纳米二氧化硅粉体、无水乙醇、碱性纳米硅溶胶、改性剂、改性氧化铝晶须等原料制得。本发明中改性废瓷粉改性剂、改性氧化铝晶须等原料的引入有效提高了耐火性、抗弯强度、断裂韧性、耐磨性、耐水性、尺寸稳定性和耐腐蚀性。
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