An anti-fouling porcelain insulator and a preparation method and application thereof

By forming a film layer on the surface of porcelain insulators with organic fluorine-silicon segments embedded in an inorganic silicon-oxygen network, combined with a step-by-step film-forming process using functional glaze slurry and surface locking liquid, the problem of easy aging and peeling off of porcelain insulator surfaces is solved. This achieves improved high hydrophobicity, strong adhesion, and long-term stability, significantly enhancing pollution flashover voltage and insulation performance.

CN122404032APending Publication Date: 2026-07-17JIANGXI YILONG ELECTRIC CO LTD
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
JIANGXI YILONG ELECTRIC CO LTD
Filing Date
2026-04-22
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

The organic coating on the surface of existing porcelain insulators is prone to aging and peeling off. The inorganic-organic hybrid functional layer is difficult to achieve high hydrophobicity, high resistivity, strong adhesion and long-term environmental stability, and cannot meet the requirements of long-term maintenance-free power equipment.

Method used

A fluorinated organosilicon copolymer polysilsesquioxane precursor and a tetraethoxysilane-boric acid system are polycondensed under stepwise acid/base catalysis to form organofluorine-silicon segments uniformly embedded in an inorganic silicon-oxygen network. Combined with a step-by-step film-forming process of two-stage spraying of functional glaze slurry and surface locking liquid, a dense, chemically anchored film layer is formed by step-by-step temperature rise and curing.

Benefits of technology

It achieves improved hydrophobicity, mechanical strength and insulation, significantly suppresses the increase in leakage current after the contaminant layer becomes damp, improves flashover voltage, and significantly enhances film stability and adhesion, meeting the requirements for long-term environmental stability.

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Abstract

本发明涉及瓷绝缘子技术领域,具体涉及一种防污瓷绝缘子及其制备方法和应用。该绝缘子由瓷绝缘子基体、基础釉层和功能釉层构成。核心在于,功能釉层由特定配比的四乙氧基硅烷、硼酸、甲基三甲氧基硅烷、(3,3,3‑三氟丙基)三甲氧基硅烷和3‑氨基丙基三乙氧基硅烷经溶胶‑凝胶工艺制备而成,并采用两次喷涂功能釉浆液和喷涂表面锁定液及阶梯升温固化的特定工艺。该结构形成了以化学键结合的致密无机‑有机杂化网络,表面富含低表面能含氟基团,从而赋予绝缘子持久的高疏水性、高表面电阻和优异的防污闪性能,并具有出色的耐老化特性,适用于污秽环境下的电力传输。
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