Preparation method of dry granular rock plate with antibacterial and acid and alkali resistance

By forming a dense inorganic oxide barrier and an organic-inorganic hybrid composite layer on the surface of dry granulated rock slabs, the problems of insufficient antibacterial properties and acid and alkali resistance of dry granulated rock slabs are solved, achieving high-efficiency antibacterial durability and chemical stability.

CN122404034APending Publication Date: 2026-07-17SHANDONG HUAMANTIAN CULTURAL & CREATIVE IND CO LTD
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2026-05-07
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing dry-grained rock slabs have shortcomings in terms of antibacterial properties and acid and alkali resistance, especially in surface structures with obvious undulations and abundant micropores, making it difficult to simultaneously achieve antibacterial durability, acid and alkali resistance stability, and improved surface granular texture.

Method used

After ball milling core-shell structured antibacterial composite powder with dry ceramic particles, titanium zirconium silica sol is sprayed on and sintered. Subsequently, flexible polishing and silicon-modified boron-containing polyester coating are applied to form a dense inorganic oxide barrier and an organic-inorganic hybrid composite protective layer.

Benefits of technology

It effectively seals micropores, blocks acid and alkali penetration, enhances Mohs hardness and antibacterial durability, and ensures chemical stability and mechanical resistance in extreme environments.

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Abstract

本发明公开有一种抗菌、耐酸碱的干粒岩板的制备方法,属于岩板制备技术领域,用于解决在现有技术中的干粒岩板的抗菌性能和耐酸碱性能有待进一步提高的技术问题,具体包括以下步骤:将核壳结构抗菌复合粉和陶瓷干粒加入球磨机,干式球磨15‑30min,得到抗菌功能干粒,本发明是利用乙酰丙酮螯合改性钛、锆醇盐以调控其水解活性,随后将其与正硅酸乙酯在酸性条件下共水解缩聚,构建含Ti‑O‑Zr‑Si键合的三元无机杂化前驱体,制得钛锆硅溶胶,将其用于岩板干粒层表面并经高温烧结,得到干粒岩板,显著增强岩板的耐腐蚀性能及抗菌性能。
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