Ionic liquid non-covalent functionalized carbon nanofiller, preparation method and application thereof

By performing ionic liquid non-covalent functionalization on graphene nanosheets and carbon nanotubes, their dispersibility and interfacial compatibility in mixed explosives are improved, solving the problem of high interfacial thermal resistance in mixed explosives and achieving a synergistic improvement in thermal conductivity and mechanical properties.

CN122404085APending Publication Date: 2026-07-17INST OF CHEM MATERIAL CHINA ACADEMY OF ENG PHYSICS
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
INST OF CHEM MATERIAL CHINA ACADEMY OF ENG PHYSICS
Filing Date
2026-06-15
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies struggle to effectively improve the thermal conductivity and mechanical properties of mixed explosives under low filler load conditions. Furthermore, the poor interfacial compatibility between carbon nanofillers and explosive crystals and polymer binders results in high interfacial thermal resistance, leading to insufficient thermal conductivity enhancement efficiency.

Method used

Ionic liquids were used to non-covalently functionalize graphene nanosheets and carbon nanotubes. Through non-covalent interactions such as π-π stacking, cation-π interaction, and hydrogen bonding, the dispersibility and interfacial compatibility of carbon nanofillers in mixed explosives were improved, and the interfacial interactions were enhanced.

Benefits of technology

Without damaging the intrinsic thermally conductive structure of carbon nanofillers, the interfacial thermal resistance is significantly reduced, the thermal conductivity utilization efficiency is improved, and the tensile fracture strength and fracture strain of the mixed explosive are enhanced, thereby strengthening its ability to resist thermal stress damage.

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Abstract

本发明为一种离子液体非共价功能化碳纳米填料及其制备方法和应用。所述离子液体非共价功能化碳纳米填料包括碳纳米填料以及非共价吸附于所述碳纳米填料表面的离子液体,所述碳纳米填料包括石墨烯纳米片和 / 或碳纳米管。其制备方法包括:将离子液体分散或溶解于去离子水中,加入碳纳米填料,经超声分散和搅拌处理后,使离子液体非共价吸附在碳纳米填料表面,再经离心、洗涤和干燥,得到离子液体非共价功能化碳纳米填料。将所述功能化碳纳米填料与高聚物粘结剂溶液混合后,通过水悬浮造粒法引入混合炸药中,经干燥和压制成型,获得力学性能与导热性能协同提升的混合炸药。
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