Efficient biological carbon sequestration treatment device for regulating and controlling ion transmembrane transport through tail gas driven power generation

Abstract

The utility model discloses an efficient biological carbon sequestration treatment device for regulating and controlling ion transmembrane transport through tail gas driven power generation. The efficient biological carbon sequestration treatment device comprises a shell and a master controller, a cathode and an anode are arranged on the two opposite sides in the shell respectively, the interior of the shell is divided into a cathode chamber, an algae liquid chamber and an anode chamber through a cathode membrane and a bipolar membrane, feeding ports for feeding are formed in the tops of the cathode chamber, the algae liquid chamber and the anode chamber respectively, a cathode exhaust port is formed in the top of the cathode chamber, and an anode exhaust port is formed in the top of the anode chamber; a stirring paddle driven by a driving motor is assembled at the bottom of the algae liquid chamber; a gas transmission port communicated with the cathode chamber is formed in the bottom of the cathode chamber and is connected with a gas transmission pipe; an N pole and an S pole which are oppositely provided with magnets are arranged outside the gas conveying pipe, a coil is arranged in the gas conveying pipe and corresponds to the N pole and the S pole inside and outside, and a propeller for driving the coil to rotate is arranged at one end of the coil; the other end of the coil is connected with a commutator which is connected with a master controller through a first wire and a second wire.

Description

TECHNICAL FIELD

[0001] The utility model relates to the field of environmental protection and energy utilization technology, especially to tail gas drive power generation control ion transmembrane transport's efficient biological carbon fixation treatment device. BACKGROUND

[0002] With the rapid development of global economy, the massive emission of industrial tail gas has become one of the important factors leading to climate change and energy crisis. According to the International Energy Agency (IEA) 2020 report, global carbon dioxide (CO2) emissions continue to rise, posing a serious threat to the environment and ecosystem. Therefore, reducing CO2 emissions and improving energy efficiency have become important issues facing the world.

[0003] Microalgae, as a biological resource with high CO2 utilization capacity, have been widely concerned and regarded as one of the important ways to solve the above problems due to their rapid growth, easy cultivation and high ecological and economic benefits. Microalgae can convert CO2 into organic matter through photosynthesis, while producing oxygen, which is of great significance to alleviate the greenhouse effect and improve energy efficiency. However, industrial carbon-containing tail gas not only has large flux, but also has high CO2 concentration, which directly used for microalgae cultivation not only causes CO2 secondary escape, but also often leads to limited growth or even death of microalgae.

[0004] Currently, some technologies have attempted to convert CO2 in industrial tail gas to provide a suitable growth environment for microalgae. For example, by converting CO2 in solution into carbonate, electric repulsion, and screening through ion membrane, a suitable culture environment for microalgae growth is formed. This kind of technology reduces the dissipation of high concentration CO2 escape to some extent, but still has some problems.

[0005] Specifically, most existing technologies are still in the laboratory stage, lacking mature devices to effectively combine tail gas conversion with microalgae symbiotic devices. These technologies often have low efficiency, high cost, and complex equipment when dealing with large-scale industrial tail gas. For example, in [Reference 1: A novel system integrating electrolysis and ionic membranes (EIMs) enables artificial carbon concentration and alleviation of metal cation stress in microalgae cultivation, author: Hou Yuyong, journal name: Green Chemistry, publication year: 2023, volume: 25. Issue number: 18, page number: 7273-82], although a CO2 conversion device based on electronic repulsion for transmembrane screening is disclosed, the device has not yet been practically connected with large-scale industrial tail gas treatment.

[0006] At the same time, in [Reference 2: Combination of bicarbonate and low temperature stress induces the biosynthesis of both arachidonic and docosahexaenoic acids in alkaliphilic microalgae Dunaliella salina HTBS, author: Guo Zhile, journal name: Frontiers in Marine Science, publication year: 2022, volume: 9], the exploration of microalgae culture environment parameters is disclosed, but it does not involve the problem of how to effectively combine tail gas conversion with microalgae culture. Practical new type content

[0007] The utility model aims at solving the problem of high concentration CO2 conversion and consumption in industrial tail gas, overcoming the deficiencies of existing technologies in efficiency, cost and equipment complexity, and providing an efficient biological carbon sequestration treatment device based on tail gas driven power generation regulation of ion transmembrane transport.

[0008] The technical scheme adopted to achieve the purpose of the utility model is:

[0009] An efficient biological carbon sequestration treatment device driven by tail gas power generation regulation of ion transmembrane transport, comprising a shell and a total control;

[0010] The shell is internally provided with a cathode and an anode, and the inside of the shell is divided into a cathode chamber, an algae liquid chamber and an anode chamber by a cathode film and a bipolar membrane, the cathode chamber is formed between the cathode and the cathode film, the anode chamber is formed between the anode and the bipolar membrane, and the algae liquid chamber is formed between the cathode film and the bipolar membrane, the top of each of the cathode chamber, the algae liquid chamber and the anode chamber is provided with a feeding port for feeding, the top of the cathode chamber is provided with a cathode exhaust port, and the top of the anode chamber is provided with an anode exhaust port; the bottom of the algae liquid chamber is provided with a stirring paddle driven by a driven motor; the bottom of the cathode chamber is provided with a gas inlet communicated with the cathode chamber, and the gas inlet is connected with a gas inlet pipe; the outside of the gas inlet pipe is provided with a N-pole and a S-pole of a magnet, and the gas inlet pipe is internally provided with a coil corresponding to the N-pole and the S-pole, and one end of the coil is provided with a propeller for driving the coil to rotate; the other end of the coil is electrically connected with a commutator, and the commutator is connected with a general control device through a first wire and a second wire.

[0011] In the above technical scheme, the gas inlets are arranged in a matrix on a gas distribution plate, and the input end of the gas distribution plate is connected with the output end of the gas inlet pipe.

[0012] In the above technical scheme, the top of the algae liquid chamber is provided with an illuminating lamp, and the illuminating lamp promotes the microalgae in the algae liquid chamber to carry out photosynthesis.

[0013] In the above technical scheme, the commutator is a Z4 type or a Z2 type commutator.

[0014] In the above technical scheme, the input end of the gas inlet pipe is provided with a filter film.

[0015] In the above technical scheme, the filter film is located on the side close to the tail gas inlet, and the coil and the magnet are located on the side away from the tail gas inlet.

[0016] In the above technical scheme, one end of the gas inlet pipe close to the tail gas inlet is a large-diameter end, and the other end of the gas inlet pipe away from the tail gas inlet is a small-diameter end.

[0017] In the above technical scheme, the illuminating lamp, the driven motor, the cathode and the anode are electrically connected with the general control device respectively.

[0018] In the above technical scheme, the high-efficiency biological carbon fixation treatment device further comprises a support.

[0019] In the above technical scheme, the support is fixedly installed on the bottom of the shell.

[0020] Compared with the prior art, the high-efficiency biological carbon fixation treatment device has the following beneficial effects:

[0021] The high-efficiency biological carbon fixation treatment device of the embodiment is driven by tail gas wind power generation, and converts the tail gas into a carbon source to culture microalgae through ion exchange transmembrane transport. - According to the principle that similar objects repel each other, HCO3 BRIEF DESCRIPTION OF DRAWINGS

[0022] Figure 1 The structure diagram of the high-efficiency biological carbon fixation treatment device is shown.

[0023] In the figure: 1-cathode membrane, 2-total control, 3-first electric wire, 4-coil, 5-N pole, 6-propeller, 7-filter membrane, 8-S pole, 9-commutator, 10-second electric wire, 11-gas conveying pipe, 12-bracket, 13-cathode, 14-cathode chamber, 15-illumination lamp, 16-feeding port, 17-bipolar membrane, 18-anode, 19-anode chamber, 20-algal liquid chamber, 21-liquid collecting valve, 22-stirring paddle, 23-outer shell, 24-gas conveying disc, 25-cathode exhaust port, 26-anode exhaust port. DETAILED DESCRIPTION

[0024] The utility model will be made further detailed description in combination with specific embodiment. It should be understood that the specific embodiment described here is only used to explain the utility model, and is not used to limit the utility model.

[0025] Embodiment 1

[0026] A kind of tail gas driven power generation regulation and control ion transmembrane transport high-efficiency biological carbon fixation treatment device, referring to Figure 1 , including outer shell 23 and total control 2, the total control 2 is fixedly installed on the outside of outer shell 23.

[0027] The opposite sides in the inside of the outer shell 23 are provided with cathode 13 and anode 18;The inside of the outer shell 23 is separated into cathode chamber 14, algal liquid chamber 20 for accommodating microalgae culture and anode chamber 19 for carrying anode ionization chemical process by cathode membrane 1 and bipolar membrane 17;Wherein, the cathode chamber 14 is formed between cathode 13 and cathode membrane 1;The anode chamber 19 is formed between anode 18 and bipolar membrane 17;The algal liquid chamber 20 is formed between cathode membrane 1 and bipolar membrane 17, utilizes cathode 13 to generate negative charge in cathode chamber 14, and HCO3 - Transmembrane transport to algal liquid chamber 20 by cathode membrane 1 provides carbon source for microalgae in algal liquid chamber 20;Anode 18 ionizes water in anode chamber 19 to generate positive charge (H +), transported to the algal liquid chamber 20 through the bipolar membrane 17, so as to balance the ions.

[0028] The top of the cathode chamber 14, the algal liquid chamber 20 and the anode chamber 19 is respectively provided with a feeding port 16 for feeding into the cathode chamber 14, the algal liquid chamber 20 and the anode chamber 19; the bottom of the cathode chamber 14, the algal liquid chamber 20 and the anode chamber 19 is respectively provided with a liquid collecting valve 21 for collecting the liquid in the cathode chamber 14, the algal liquid chamber 20 and the anode chamber 19; the top of the cathode chamber 14 is provided with a cathode exhaust port 25 for discharging H2 in the cathode chamber 14; the top of the anode chamber 19 is provided with an anode exhaust port 26 for discharging O2 in the anode chamber 19; the top of the algal liquid chamber 20 is provided with an illumination lamp 15 for providing light energy to the algal liquid chamber 20 to promote the photosynthesis of microalgae; the bottom of the algal liquid chamber 20 is equipped with a stirring paddle 22 driven by a driven motor to stir the algal liquid in the algal liquid chamber 20.

[0029] The bottom of the cathode chamber 14 is provided with a gas inlet connected with the cathode chamber 14, the gas inlet is connected with a gas inlet pipe 11, preferably, the gas inlet is arranged in a matrix on a gas distribution plate 24, the input end of the gas distribution plate 24 is connected with the output end of the gas inlet pipe 11, the input end of the gas inlet pipe 11 is provided with a filter membrane 7, preferably, the filter membrane 7 is located on the side close to the tail gas inlet, the tail gas is filtered through the filter membrane 7 and then input into the cathode chamber 14 through the gas distribution plate 24, and small and dense foam is generated. In this embodiment, NaOH solution is injected into the cathode chamber 14, Na2SO4 solution is injected into the anode chamber 19, and microalgae culture solution is injected into the algal liquid chamber 20.

[0030] The outside of the gas inlet pipe 11 is provided with N pole 5 and S pole 8 of a magnet, the gas inlet pipe 11 is provided with a coil 4, the coil and the N pole 5 and S pole 8 are corresponding inside and outside, one end of the coil 4 is provided with a propeller 6, the coil 4 is driven by the propeller 6, when the tail gas is input, the wind power of the tail gas drives the propeller 6 to rotate, the propeller 6 drives the coil 4 to rotate; the magnet is coaxial with the coil 4, the coil 4 driven by the propeller 6 cuts the magnetic field of the N pole 5 and S pole 8 of the magnet, and generates induced electromotive force; the other end of the coil 4 is electrically connected with a commutator 9, the electrons formed form direct current through the commutator 9, the commutator 9 is connected with the total control 2 through the first wire 3 and the second wire 10, so as to deliver the direct current to the total control 2, thereby providing power for the work of the high-efficiency biological carbon fixation treatment device. The coil 4 and the magnet are located away from the side of the tail gas inlet. The commutator 9 is a Z4 type or Z2 type commutator.

[0031] The high-efficiency biological carbon fixation treatment method for tail gas driving power generation to regulate ion transmembrane transport includes the following steps:

[0032] Step 1, the exhaust gas (CO2) is introduced into the gas pipe 11 and filtered by the filter membrane 7, and the filtered exhaust gas is introduced into the cathode chamber 14 from the gas distribution plate 24 and generates dense small bubbles in the process of entering.

[0033] Step 2, the exhaust gas drives the propeller 6 to rotate by wind power, and the propeller 6 drives the coil 4 to rotate, so as to cut the magnetic field of the N pole 5 and the S pole 8 by the coil 4, and provide power for the operation of the high-efficiency biological carbon fixation treatment device.

[0034] Step 3, the exhaust gas entering the cathode chamber 14 reacts with NaOH solution to generate NaHCO3, and the total control 2 controls the cathode 13 to generate negative charge in the cathode chamber 14, and the negative charge repels HCO3 - Through the cathode membrane 1 to the algal liquid chamber 20, the microalgae in the algal liquid chamber 20 are provided with carbon source, and the H2 in the cathode chamber 14 is discharged from the cathode exhaust port 25. Among them, 4 units of H2O in the cathode chamber 14 combine with 4 units of negative charge to generate 4 units of OH - And 2 units of H2.

[0035] Step 4, the total control 2 controls the anode 18 to ionize water in the anode chamber 19 to generate positive charge (H + ), OH - And oxygen, H + Through the bipolar membrane 17 into the algal liquid chamber 20, form ion balance, OH - Stay in the anode chamber 19, and the O2 in the anode chamber 19 is discharged from the anode exhaust port. Among them, the microalgae culture solution in the algal liquid chamber 20 carries out photosynthesis.

[0036] Example 2

[0037] In order to make the propeller 6 rotate stably, the structure of the gas pipe 11 is further improved in this embodiment, one end of the gas pipe 11 close to the exhaust gas inlet is a large diameter end, and the other end away from the exhaust gas inlet is a small diameter end, which can form a gas pressure difference to drive the propeller 6 to rotate, and the coil 4 is driven by the propeller 6 to cut the magnetic field of the N pole 5 and the S pole 8.

[0038] Further, the lighting lamp 15, the propeller 6, the cathode 13 and the anode 18 are respectively electrically connected with the total control 2, which is used for controlling the electron generation of the cathode 13 and the anode 18 by the total control 2, and controlling the lighting lamp 15 to emit light and the stirring paddle 22 to stir the algal liquid in the algal liquid chamber 20.

[0039] Example 3

[0040] On the basis of example 1, the high-efficiency biological carbon fixation treatment device further comprises a support 12, which is fixedly installed at the bottom of the shell 23, and is used for supporting the whole high-efficiency biological carbon fixation treatment device, which can play a role in preventing moisture and corrosion.

[0041] For ease of description, spatially relative terms, such as "upper", "lower", "left", "right", and the like, can be used herein for the purpose of illustrating one element or feature's relationship to another element or feature, as illustrated in the figures. It will be understood that the spatially relative terms are intended to encompass different orientations of the device in use or operation, in addition to the orientation depicted in the figures. For example, if a device in the figures is inverted, elements described as being on the "lower" side of other elements or features would then be oriented on "upper" sides thereof, and vice versa. Thus, the exemplary term "lower" can encompass both an orientation of "lower" and "upper", depending on the particular orientation of the device. The devices can be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein interpreted accordingly.

[0042] Also, the terms "first" and "second" are used herein only to distinguish one element from another element having a same name, and do not necessarily imply or require any such actual relationship or order between the elements.

[0043] The above description is only preferred embodiments of the present application, and it should be pointed out that for those skilled in the art, some improvements and refinements can be made without departing from the principles of the present application, and these improvements and refinements should also be considered as the protection scope of the present application.

Claims

1. An efficient biological carbon fixation treatment device for regulating ion transmembrane transport driven by exhaust gas generated electricity, comprising a shell and a general control, characterized in that: opposite sides of the interior of the shell are provided with a cathode and an anode, the interior of the shell is divided into a cathode chamber, an algal liquid chamber and an anode chamber by a cathode membrane and a bipolar membrane, the cathode chamber is formed between the cathode and the cathode membrane, the anode chamber is formed between the anode and the bipolar membrane, the algal liquid chamber is formed between the cathode membrane and the bipolar membrane, the top of the cathode chamber, the algal liquid chamber and the anode chamber are respectively provided with a feeding port for feeding, the top of the cathode chamber is provided with a cathode exhaust port, and the top of the anode chamber is provided with an anode exhaust port; the bottom of the algal liquid chamber is equipped with a stirring paddle driven by a driven motor; the bottom of the cathode chamber is provided with a gas inlet connected with the cathode chamber, and the gas inlet is connected with a gas inlet pipe; The outside of the gas inlet pipe is provided with N-pole and S-pole of magnet, the gas inlet pipe is provided with a coil inside, the coil and N-pole and S-pole are corresponding inside and outside, one end of the coil is provided with a propeller for driving the coil to rotate; the other end of the coil is electrically connected with a commutator, and the commutator is connected with the general control through a first wire and a second wire. The gas inlets are arranged in a matrix on a gas distribution plate, and the input end of the gas distribution plate is connected with the output end of the gas inlet pipe.

2. The high-efficiency biological carbon sequestration treatment device according to claim 1, characterized in that: The top of the algal liquid chamber is provided with an illuminating lamp, which promotes the photosynthesis of microalgae in the algal liquid chamber.

3. The high-efficiency biological carbon sequestration treatment device according to claim 1, characterized in that: The commutator is a Z4 type or Z2 type commutator.

4. The high-efficiency biological carbon sequestration treatment device according to claim 1, characterized in that: The input end of the gas inlet pipe is provided with a filter membrane.

5. The high-efficiency biological carbon sequestration treatment device according to claim 1, characterized in that: The filter membrane is located on the side close to the exhaust gas inlet, and the coil and the magnet are located on the side away from the exhaust gas inlet.

6. The high-efficiency biological carbon sequestration treatment device according to claim 5, characterized in that: The end of the gas inlet pipe close to the exhaust gas inlet is a large diameter end, and the end away from the exhaust gas inlet is a small diameter end.

7. The high-efficiency biological carbon sequestration treatment device according to claim 1, characterized in that: The illuminating lamp, the driven motor, the cathode and the anode are electrically connected with the general control respectively.

8. The high-efficiency biological carbon sequestration treatment device according to claim 3, characterized in that: The efficient biological carbon fixation treatment device further comprises a support.

9. The high-efficiency biological carbon sequestration treatment device according to claim 1, characterized in that: The support is fixedly installed at the bottom of the shell.

10. The high-efficiency biological carbon sequestration treatment device according to claim 9, characterized in that: ​

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