Auxiliary equipment for detection method for analyzing components of corroded grid in battery
By designing a grid composition detection device for lead-acid batteries, which utilizes heated cleaning with a sugar-alkali solution combined with direct-reading spectrometer detection, the problem of difficult composition detection caused by grid corrosion has been solved, thus improving accuracy and safety.
Patent Information
- Application Number
- CN202423095460.5
- Authority / Receiving Office
- CN · China
- Patent Type
- Utility models(China)
- Current Assignee / Owner
- Filing Date
- 2024-12-16
- Publication Date
- 2026-01-16
- Estimated Expiration
- 2034-12-16
AI Technical Summary
In the prior art, the positive grid of lead-acid batteries is corroded by the electrolyte during charging and discharging, making it impossible to accurately detect the grid composition in the initial state. Furthermore, the color change of the cleaning solution makes it impossible to confirm the degree of cleaning.
Design an auxiliary device for a method to analyze the composition of corroded grids in a battery, including a housing, a lifting basket, and a drive mechanism. The grids are cleaned by heating a sugar-alkali solution, and the grid composition is detected by a direct-reading spectrometer. A stirring device and a transparent lifting basket are set up to observe the cleaning status.
It enables accurate detection of grid composition, avoids interference from corrosion layer and impurity elements, ensures observable cleaning status, and improves detection efficiency and safety.
Smart Images

Figure CN223808340U_ABST
Abstract
Description
TECHNICAL FIELD
[0001] The utility model relates to battery technical field especially relates to a kind of detection methods for the auxiliary equipment of the component of corroded grid in battery. BACKGROUND
[0002] Lead-acid battery is widely used in power grid energy storage, telecommunications, transportation and other fields with the advantages of mature technology, low cost, safe and reliable and high material recovery rate.
[0003] There can be multiple reasons for the failure of lead-acid batteries, such as sulfuration, water loss, thermal runaway, active material shedding, and plate softening. For non-normal failure batteries or long cycle life batteries, the battery is usually disassembled to find the cause of failure and long cycle life.
[0004] Grid is the main component of lead-acid battery, which is the current-carrying framework of the electrode, plays a role in conducting and collecting current and making current distribution uniform, and supports the active material, which is the carrier of the active material. The corrosion problem of the positive grid of lead-acid battery seriously restricts its service life. The composition of the grid alloy has a great influence on the battery. Suitable composition can ensure that the grid has good mechanical strength, such as adding some calcium in the alloy, which can prevent it from deforming and damaging during the assembly and use of the battery, thereby maintaining the integrity of the battery structure. Different compositions will also cause differences in the corrosion resistance of the grid. Good corrosion resistance of the grid can prolong the service life of the battery and reduce the performance degradation of the battery caused by grid corrosion. Suitable composition can also reduce the oxygen evolution of the positive electrode and the hydrogen evolution of the negative electrode, reduce the water loss of the battery, and improve the service life of the battery. Lead-calcium alloy has been widely used in maintenance-free lead-acid batteries due to its high hydrogen evolution overpotential and low water loss. When looking for the cause of battery failure, the grid of the battery is also collected for composition analysis.
[0005] During the charging and discharging process of lead-acid battery, the positive grid will be significantly corroded due to high battery temperature, acid or organic salt in the electrolyte with corrosion effect, and the composition of the grid in the initial state cannot be obtained. UTILITY MODEL CONTENT
[0006] Therefore, it is necessary to provide an auxiliary device for analyzing the composition of the corroded grid in the battery to solve the problem that the grid cannot be cleaned completely due to the color change of the cleaning liquid in the prior art.
[0007] To solve the above technical problems, the technical scheme adopted by the utility model is:
[0008] The application discloses a detection method auxiliary device for analyzing corroded grid components in a battery, which is used for analyzing corroded grid components in a battery and comprises a box body, a lifting basket and a driving mechanism.
[0009] The auxiliary device is used for cleaning the grid, facilitates real-time observation of the cleaning state of the grid, and solves the problem that the cleaning state of the grid cannot be determined due to color change of the cleaning liquid in the prior art.
[0010] In a feasible implementation, a heating device is arranged in the box body to heat the cleaning liquid.
[0011] In a feasible implementation, a stirring device is arranged in the box body to stir the cleaning liquid.
[0012] Preferably, the stirring device is arranged at the bottom center of the box body.
[0013] Preferably, the partial structure of the grid is a tab of the grid.
[0014] The auxiliary device can ensure uniform liquid temperature in the box body and prevent sugar alkali solution from suddenly boiling over and hurting people.
[0015] In a feasible implementation, the bottom of the lifting basket is provided with through holes, and the number of the through holes is multiple.
[0016] Preferably, the area of the multiple through holes is greater than or equal to 1 / 3 of the area of the bottom of the lifting basket and less than or equal to 2 / 3 of the area of the bottom of the lifting basket.
[0017] The auxiliary device is provided with the through holes, which can ensure that the lifting basket is lifted to more clearly observe the state of the grid, and the limitation of the area of the through holes can ensure the strength of the lifting basket and the descending speed of the sugar alkali solution, thereby facilitating observation and saving time.
[0018] Preferably, the lifting basket is provided with a partition plate, and the partition plate divides the lifting basket into at least two storage spaces.
[0019] Preferably, the partition plate is provided with connecting holes, the number of the connecting holes is multiple, and adjacent storage spaces are communicated through the connecting holes.
[0020] Preferably, the side wall of the lifting basket is a transparent plate.
[0021] Preferably, the area of the multiple connecting holes arranged on the partition plate accounts for 1 / 3-2 / 3 of the area of the partition plate.
[0022] The utility model discloses set up multiple article space, can wash multiple plate grid pole simultaneously, improve efficiency, the limitation of connecting hole, on the one hand guarantee the strength of the lifting basket, on the other hand when lifting basket rises, benefit sugar alkali solution drops, the cleaning degree of pole ear is convenient for observation.
[0023] In a feasible implementation, the bottom of the box is provided with a drainage device.
[0024] Compared with the prior art, the utility model has the following advantages due to the adoption of the above technical scheme:
[0025] 1. The auxiliary equipment for cleaning plate grid of the utility model is convenient for observing the cleaning state of plate grid at any time, and solves the problem that whether plate grid is cleaned completely cannot be confirmed due to the color change of cleaning liquid in the prior art.
[0026] 2. The auxiliary equipment of the utility model is provided with a stirring device, which can ensure that the temperature of liquid in the equipment is uniform and prevent the cleaning liquid from suddenly boiling over and causing injury. BRIEF DESCRIPTION OF DRAWINGS
[0027] Figure 1 It is the physical map of plate grid after removing surface active substance in example 1.
[0028] Figure 2 It is the physical map of plate grid after treating with sugar alkali solution in example 1.
[0029] Figure 3 It is the structure schematic view of the auxiliary equipment of the utility model.
[0030] Figure 4 It is the structure schematic view of the box of the auxiliary equipment of the utility model.
[0031] Figure 5 It is the structure schematic view of the lifting basket of the auxiliary equipment of the utility model.
[0032] Among them, 1, the box;11, support column;2, lifting basket;21, through -hole;22, article space;23, connecting hole;24, partition;3, heating device;4, stirring device;5, drainage device. DETAILED DESCRIPTION
[0033] In order to make the above objects, features and advantages of the present application more obvious and easy to understand, the specific embodiments of the present application will be described in detail below with reference to the drawings. In the following description, many specific details are set forth in order to provide a thorough understanding of the present application. However, the present application can be practiced in a variety of ways different from those described herein, and those skilled in the art can make similar improvements without departing from the spirit of the present application, so the present application is not limited to the specific embodiments disclosed below.
[0034] It should be noted that when an element is referred to as being "fixed" to another element, it can be directly on the other element or there can be intervening elements. When an element is referred to as being "connected" to another element, it can be directly connected to the other element or intervening elements can be present. The terms "vertical", "horizontal", "left", "right", "upper" and "lower" and similar terms as used herein are for the purpose of description only.
[0035] In addition, the terms "first", "second", "third", etc. are used herein only to describe various circumstances, but can not be understood as indicating or implying relative importance or an indicated number of technical features. Therefore, the features defined as "first", "second" can explicitly or implicitly include one or more of the features. In the description of the present application, the meaning of "multiple" is two or more, unless otherwise specifically limited. In the present application, " / " means "or".
[0036] Unless otherwise defined, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which the present application belongs. The terms used in the specification of the present application are only for the purpose of describing specific embodiments and are not intended to limit the present application. The term "and / or" used herein includes any and all combinations of one or more of the related listed items.
[0037] At present, during the charging and discharging process of the lead-acid storage battery, the positive grid will be obviously corroded due to high battery temperature, and acid or organic salt contained in the electrolyte, and the grid composition in the initial state cannot be obtained.
[0038] On this basis, the present application provides a detection method and auxiliary equipment for analyzing the corroded grid composition in the battery, for analyzing the corroded grid composition of the lead-acid storage battery. The detection method of the present application can avoid the interference of the corrosion layer and impurity elements in the battery, and the detection result is accurate.
[0039] The present application will be described in detail below in combination with specific embodiments. The present embodiment detects the grid of the lead-acid storage battery produced by the same process, the same production line and the same batch.
[0040] Examples 1-5
[0041] This embodiment analyzes the detection method of the corroded grid component in the battery, including the following steps:
[0042] I. Preparation of the sample, specifically, the preparation of the sample includes the following steps:
[0043] (1) After dissecting the battery, the electrode plate is taken out, the active material on the surface of the electrode plate is removed, and the grid in the battery is taken out, as shown in Figure 1 At this time, the grid surface contains some adhered lead powder and corrosion layer.
[0044] (2) Put the grid into a container and treat it with a cleaning solution, then wash it with pure water and dry it, wherein the cleaning solution has reducing property and can dissolve the residual on the surface of the grid, so that the grid exposes its metal color, as shown in Figure 2
[0045] In this embodiment, the cleaning solution is a sugar base solution, the mass percentage of sugar base in the sugar base solution is 20%, the mass ratio of sugar to base in the sugar base solution is 2:1, the sugar in the sugar base solution is glucose, and the base is sodium hydroxide.
[0046] In this embodiment, the grid is subjected to micro-boiling treatment in the sugar base solution under heating conditions, and the heating temperature is 85°C.
[0047] The sugar base solution is selected in this embodiment because under alkaline conditions, glucose will undergo ring-opening reaction to generate aldehyde and carboxylic acid with open-chain structure, which has stronger reducing property and can dissolve the surface material of the grid under heating conditions to expose its metal color. This component is similar to the component of the grid itself. At the same time, glucose and sodium hydroxide are easy to obtain and have low cost.
[0048] (3) Take the dried grid or part of its structure and inlay it in pure lead as a sample.
[0049] In this embodiment, the part of the grid structure is the tab of the grid, that is, the tab is inlaid in pure lead as a sample in this embodiment, and attention should be paid to the flatness of the sample during treatment of the sample to avoid interference with the detection data.
[0050] II. Test the sample with a direct-reading spectrometer and record the data
[0051] Since the positive plate grid is generally made of lead calcium tin aluminum alloy, the lead-based general analysis program Pb-01 should be selected for testing when testing the grid alloy, and the sample should be selected to calibrate the equipment first. If the Sn content of the alloy to be tested is about 1.2%, a lead alloy standard sample with Sn content of about 1.2% can be selected for calibration, and the same is true for other elements. Sometimes a standard sample can calibrate multiple elements at the same time. In order to ensure the accuracy of the results, argon with a purity of more than 99.999% should be selected as the protective gas. After calibrating the equipment, the sample is excited, and the same sample is excited at least twice, and the data is recorded.
[0052] In this embodiment, the direct-reading spectrometer has the detection capability of Ca, Sn, Al, Ag, Cu, Bi, S, Te, Mg, Pb elements,
[0053] The analysis spectrum and detection limit of each element are as follows:
[0054] Ca: 315.887 nm, 0.00020%-1.3%
[0055] Sn: 317.505 nm, 0.00010%-1.3%
[0056] Al: 309.271 nm, 0.000010%-0.0750%
[0057] Ag: 338.289 nm, 0.000050%-0.0250%
[0058] Cu: 324.753 nm, 0.00001%-0.0150%
[0059] Bi: 306.772 nm, 0.000050%-1.2%
[0060] S: 180.731 nm, 0.00010%-0.0110%
[0061] Te: 214.28 nm, 0.00010%-0.100%
[0062] Mg: 279.077 nm, 0.000050%-0.180%.
[0063] In the lead-based direct-reading spectrometer, the Pb content is 100% minus the sum of other impurity elements. Ca, Sn, Al, Ag, Cu, Bi, S, Te, Mg basically contain the impurity elements present in lead.
[0064] The weight change of the grid treatment in Examples 1-5 is shown in Table 1.
[0065] Table 1 Weight change of grid treatment in Examples 1-5
[0066]
[0067] In the above examples, the surface oxide layer of the grid is not completely reduced due to the low glucose content in the sugar base solution.
[0068] In this embodiment, if the active substance needs to be analyzed, the following steps can also be included: washing the surface of the plate with water to pH 6-7, drying the plate, and removing the plate after complete drying and knocking off the active substance to be tested. The active substance here mainly refers to the substance in the battery that participates in the electrochemical reaction. The positive active substance is closely related to the charge and discharge state of the battery. When the battery is dissected, the discharge state can be judged according to the lead dioxide content in the active substance. Currently, the active substance is generally titrated with EDTA solution.
[0069] Embodiments 6-10
[0070] When the grid is treated with a sugar base solution, the surface area of the grid is large, the corrosion area is large, and the sugar base solution is consumed too quickly, which is easy to cause waste. Moreover, only the tabs are treated in subsequent operations. Therefore, in order to avoid waste and save costs, the applicant usually cuts off the grid tabs first, and then puts the tabs into the sugar base solution for micro-boiling treatment. Specifically, the detection method for analyzing the components of the corroded grid in the battery in this embodiment includes the following steps:
[0071] I. Preparing a test sample, specifically, preparing a test sample includes the following steps:
[0072] (1) After dissecting the battery, the plate is removed, the active substance on the surface of the plate is removed, and the grid in the battery is taken out, at this time the surface of the grid contains part of the adhered lead powder and the corrosion layer.
[0073] (2) Part of the structure of the grid is taken into a container, treated with a cleaning solution, then washed with pure water, and dried, wherein the cleaning solution has reducing property and can dissolve the residual on the surface of the grid, so that the grid exposes its metal color.
[0074] In this embodiment, the cleaning solution is a sugar base solution, the mass percentage of sugar base in the sugar base solution is 20%, the mass ratio of sugar to base in the sugar base solution is 3:1, the sugar in the sugar base solution is glucose, and the base is sodium hydroxide.
[0075] In this embodiment, the grid is micro-boiled in the sugar base solution under heating conditions, and the heating temperature is 90°C.
[0076] In this embodiment, part of the structure of the grid is the tab of the grid, that is, the tab is put into a container, treated with a cleaning solution, then washed with pure water, and dried.
[0077] (3) The lug after drying is inlaid in pure lead as a sample. When processing the sample, attention should be paid to the flatness of the sample and no gap should exist to avoid interfering with the test data.
[0078] II. Test the sample with a direct-reading spectrometer and record the data
[0079] Since the positive plate grid is generally made of lead-calcium-tin-aluminum alloy, when testing the grid alloy, the lead-based general analysis program Pb-01 should be selected for testing, and the standard sample should be selected to calibrate the equipment first. If the Sn content of the alloy to be tested is about 1.2%, a lead alloy standard sample with Sn content of about 1.2% can be selected for calibration, and the same applies to other elements. Sometimes one standard sample can calibrate multiple elements at the same time. In order to ensure the accuracy of the results, argon with a purity of more than 99.999% should be selected as the protective gas. After calibrating the equipment, the sample is excited, and the same sample is excited at least twice, and the data is recorded.
[0080] In this embodiment, the direct-reading spectrometer has the detection capability of Ca, Sn, Al, Ag, Cu, Bi, S, Te, Mg, and Pb elements,
[0081] The analysis spectrum lines and detection limits of each element are as follows:
[0082] Ca: 315.887 nm, 0.00020%-1.3%
[0083] Sn: 317.505 nm, 0.00010%-1.3%
[0084] Al: 309.271 nm, 0.000010%-0.0750%
[0085] Ag: 338.289 nm, 0.000050%-0.0250%
[0086] Cu: 324.753 nm, 0.00001%-0.0150%
[0087] Bi: 306.772 nm, 0.000050%-1.2%
[0088] S: 180.731 nm, 0.00010%-0.0110%
[0089] Te: 214.28 nm, 0.00010%-0.100%
[0090] Mg: 279.077 nm, 0.000050%-0.180%.
[0091] In the lead-based direct-reading spectrometer, the content of Pb is 100% minus the sum of other impurity elements. Ca, Sn, Al, Ag, Cu, Bi, S, Te, and Mg basically include the impurity elements present in lead.
[0092] The weight changes of the grids in Examples 6-10 are shown in Table 2.
[0093] Table 2 Weight changes of the grids in Examples 6-10
[0094]
[0095] In this embodiment, if the active substance needs to be analyzed, the following steps can also be included: washing the surface of the electrode plate with water to pH 6-7, drying the electrode plate, and knocking off the active substance to be tested after complete drying. The active substance here mainly refers to the substance in the battery that participates in the electrochemical reaction. The positive active substance is closely related to the charge and discharge state of the battery. When the battery is dissected, the discharge state can be judged according to the content of lead dioxide in the active substance. Currently, the active substance is generally titrated with EDTA solution.
[0096] Examples 11-15
[0097] The detection method in Examples 11-15 is different from the detection method in Examples 6-10 in that the cleaning solution is a sugar base solution, the mass percentage of sugar base in the sugar base solution is 20%, the mass ratio of sugar to base in the sugar base solution is 4:1, the sugar in the sugar base solution is glucose, and the base is sodium hydroxide.
[0098] In this embodiment, the grid is subjected to micro-boiling treatment in the sugar base solution under heating conditions, the heating temperature is 95°C, and the rest of the details are the same.
[0099] The weight changes of the grids in Examples 11-15 are shown in Table 3.
[0100] Table 3 Weight changes of the grids in Examples 11-15
[0101]
[0102] Examples 16-20
[0103] The detection method in Examples 16-20 is different from the detection method in Examples 6-10 in that the cleaning solution is a sugar base solution, the mass percentage of sugar base in the sugar base solution is 20%, the mass ratio of sugar to base in the sugar base solution is 5:1, the sugar in the sugar base solution is glucose, and the base is sodium hydroxide.
[0104] In this embodiment, the grid is subjected to micro-boiling treatment in the sugar base solution under heating conditions, the heating temperature is 100°C, and the rest of the details are the same.
[0105] The weight change of the grid treatment in Examples 16-20 is shown in Table 4.
[0106] Table 4 Weight change of grid treatment in Examples 16-20
[0107]
[0108] Examples 21-25
[0109] The difference between the detection method in Examples 21-25 and the detection method in Examples 6-10 is that the cleaning solution is a sugar base solution, the mass percentage of sugar base in the sugar base solution is 20%, the mass ratio of sugar to base in the sugar base solution is 3:1, the sugar in the sugar base solution is glucose, and the base is sodium hydroxide.
[0110] In this example, the grid is treated in a sugar base solution under heating conditions, the heating temperature is 70±5℃, and the rest of the details are the same.
[0111] The weight change of the grid treatment in Examples 21-25 is shown in Table 5.
[0112] Table 5 Weight change of grid treatment in Examples 21-25
[0113]
[0114] Comparative Examples 1-5
[0115] The difference between the detection method in Comparative Examples 1-5 and the detection method in Examples 6-10 is that the cleaning solution is a sodium bicarbonate solution, and the mass percentage of sodium bicarbonate is 20%.
[0116] In this comparative example, the grid is treated in a sodium bicarbonate solution under heating conditions, the heating temperature is 90℃, and the rest of the details are the same.
[0117] The weight change of the grid treatment in Comparative Examples 1-5 is shown in Table 6.
[0118] Table 6 Weight change of grid treatment in Comparative Examples 1-5
[0119]
[0120] The reaction is slow in this comparative example because the sodium bicarbonate is decomposed by heat during heating and is ineffective.
[0121] Comparative Examples 6-10
[0122] The detection method in Comparative Examples 6-10 is different from the detection method in Examples 6-10 in that the electrolyte environment is simulated, and in lead-acid batteries, the electrolyte is sulfuric acid. Here, the cleaning is performed with sulfuric acid having a concentration of 1.255 g / cm 3 .
[0123] In this comparative example, the grid is subjected to micro-boiling treatment under heating conditions, and the heating temperature is 90 DEG C, and the remaining details are the same.
[0124] The grid treatment weight changes in Comparative Examples 6-10 are shown in Table 7.
[0125] Table 7 Grid treatment weight changes in Comparative Examples 6-10
[0126]
[0127] In this comparative example, lead sulfate generated during discharging adheres to the surface of the plate and does not react with sulfuric acid.
[0128] The direct-reading spectrometer data of Examples 1, 6, 11, 16, 21 and Comparative Examples 1 and 6 are shown in Table 8.
[0129] Table 8 Direct-reading spectrometer data of Examples 1, 6, 11, 16, 21 and Comparative Examples 1 and 6
[0130]
[0131] As shown in Table 8, the detection method of the present application can avoid the interference of the corrosion layer and impurity elements in the battery, and the detection result is accurate.
[0132] Since the tab is small, it is not easy to take out from the container, and the glucose undergoes caramelization reaction, and the solution gradually changes from transparent to brown and black, so that it is impossible to determine whether the tab is cleaned or not through the beaker. To solve the above technical problems, the present application provides the following specific embodiments.
[0133] As shown in Figures 3-5 , the detection method for analyzing the composition of the corroded grid in the battery uses an auxiliary device for analyzing the composition of the corroded grid in the battery, which comprises a box body 1, a lifting basket 2 and a driving mechanism.
[0134] In this embodiment, the box body 1 is made of a ceramic material resistant to high temperature and alkali, and is used to place the cleaning solution. The box body 1 comprises a bottom and a side wall extending upward from the bottom, and the bottom and the side wall together enclose a space for containing the cleaning solution.
[0135] In this embodiment, the lifting basket 2 is arranged in the box body 1 and can move up and down relative to the box body 1, the grid or part of the structure of the grid is placed in the lifting basket 2, and the driving mechanism is used to drive the lifting basket 2 to move up and down. In this embodiment, the part of the structure of the grid is the tab of the grid.
[0136] Specifically, four support columns 11 are arranged on the inner side of the side wall of the box body 1, and the lifting basket 2 is slidingly arranged on the support columns 11. A driving mechanism drives the lifting basket 2 to slide up and down, so as to adjust the height of the lifting basket 2, facilitating observation of the cleaning state of the current grid or tab. The driving mechanism here can be electric or manual. The electric driving mechanism can be motor-driven, and the manual driving mechanism can be hand-held rocker-driven.
[0137] In this embodiment, the side wall of the lifting basket 2 is provided as a transparent plate, which can be made of a light-transmitting material, preferably polyhexamethylene terephthalamide. This material has high light transmittance, which facilitates observation of the state of the tabs in the lifting basket 2, and has the characteristics of high temperature resistance, stable chemical properties, etc., meeting the requirements.
[0138] In this embodiment, the bottom of the lifting basket 2 is provided with a plurality of through holes 21. At the same time, the area of the plurality of through holes 21 is greater than or equal to 1 / 3 of the area of the bottom of the lifting basket 2 and less than or equal to 2 / 3 of the area of the bottom of the lifting basket 2.
[0139] The arrangement of the through holes 21 can ensure that the state of the grid can be more clearly observed when the lifting basket 2 is lifted. At the same time, the limitation of the area of the through holes 21 ensures the strength of the lifting basket 2 and the descending speed of the sugar alkali solution, facilitating observation and saving time.
[0140] In this embodiment, a partition plate 24 is arranged in the lifting basket 2, which divides the interior of the lifting basket 2 into at least two storage spaces 22. Specifically, in this embodiment, the storage spaces 22 are six. The partition plate 24 is provided with a plurality of connecting holes 23, and adjacent storage spaces 22 are communicated through the connecting holes 23. The area of the plurality of connecting holes 23 arranged on the partition plate 24 accounts for 1 / 3-2 / 3 of the area of the partition plate 24.
[0141] The arrangement of the plurality of storage spaces 22 can simultaneously clean the tabs of a plurality of grids, improving efficiency. The limitation of the connecting holes 23 ensures the strength of the lifting basket 2 and facilitates the descent of the sugar alkali solution when the lifting basket 2 is lifted, exposing the tabs and facilitating observation of the cleaning degree of the tabs.
[0142] In this embodiment, a heating device 3 is arranged at the bottom of the box body 1, which is used to heat the cleaning liquid. The heating device 3 here is a conventional means.
[0143] In this embodiment, a stirring device 4 is arranged at the center of the bottom of the box body 1, which is used to stir the cleaning liquid, so as to ensure the uniformity of the liquid temperature in the box body 1 and prevent the sugar alkali solution from suddenly boiling over and causing injury.
[0144] In the embodiment, the bottom of the box 1 is provided with a drainage device 5, which comprises a water outlet at the bottom of the box 1. The drainage device 5 is used to flow out the sugar alkali solution inside the box 1 and the waste liquid of the cleaning instrument through the water outlet and collect them for reprocessing, so as to prevent the test liquid and residual liquid from polluting the environment.
[0145] In the embodiment, the box 1 is also provided with a control panel, and the lifting height of the lifting basket 2, the heating of the heating device 3 and the stirring of the stirring device 4 can be operated through the control panel. The operation circuit of the control panel is a conventional means.
[0146] The technical features of the above-mentioned embodiments can be combined arbitrarily. In order to make the description simple, all possible combinations of the technical features in the above-mentioned embodiments are not described, however, as long as the combination of the technical features does not exist contradictory, it should be considered as the scope of the present application.
[0147] The above-mentioned embodiments only express several implementation manners of the present application, the description is more specific and detailed, but it should not be understood as the limitation of the scope of the present application. It should be pointed out that for ordinary skilled in the art, without departing from the concept of the present application, a number of modifications and improvements can be made, which belong to the protection scope of the present application. Therefore, the protection scope of the present application should be subject to the appended claims.
Claims
1. An auxiliary device for a detection method of analyzing a corroded grid component in a battery, for analyzing a corroded grid component in a battery, characterized by, The box is used for placing cleaning liquid, the lifting basket is arranged in the box and can move up and down relative to the box, the grid or part of the structure is placed in the lifting basket, and the driving mechanism is used for driving the lifting basket to move.
2. The auxiliary device for detecting a method of analyzing a component of a grid corroded in a battery according to claim 1, characterized by, The box is provided with a heating device, and the cleaning liquid is heated.
3. The detecting method for assisting equipment for analyzing a component of a grid corroded in a battery according to claim 1, characterized by, The box is provided with a stirring device, and the cleaning liquid is stirred. The part of the structure of the grid is the tab of the grid.
4. The detecting method for assisting equipment for analyzing a component of a grid corroded in a battery according to claim 1, characterized by, The bottom of the lifting basket is provided with a plurality of through holes.
5. The auxiliary device for detecting a method of analyzing a component of a grid corroded in a battery according to claim 4, characterized by, The area of the plurality of through holes is greater than or equal to 1 / 3 of the area of the bottom of the lifting basket and less than or equal to 2 / 3 of the area of the bottom of the lifting basket.
6. The detecting method for assisting equipment for analyzing a component of a grid corroded in a battery according to claim 1, characterized by, The lifting basket is provided with a partition plate, and the partition plate divides the lifting basket into at least two storage spaces.
7. The auxiliary device for detecting a method of analyzing a component of a grid corroded in a battery according to claim 6, characterized by, The partition plate is provided with a plurality of connecting holes, and adjacent storage spaces are communicated through the connecting holes.
8. The detecting method for assisting equipment for analyzing a component of a grid corroded in a battery according to claim 1, characterized by, The side wall of the lifting basket is a transparent plate.
9. The detecting method for assisting equipment for analyzing a corroded component of a grid in a battery according to claim 7, characterized by, The area of the plurality of connecting holes on the partition plate accounts for 1 / 3-2 / 3 of the area of the partition plate.
10. The auxiliary device for detecting a method of analyzing a component of a grid corroded in a battery according to claim 1, characterized by, The bottom of the box is provided with a drainage device.