Chlorination reaction kettle with chlorine introduced from bottom
By combining a bottom-flow chlorination design with a stirring device, the problems of vibration corrosion of chlorine pipes and catalyst deposition in traditional chlorination reactors are solved, achieving uniformity and efficiency in the chlorination reaction, and improving production safety and product quality.
Patent Information
- Application Number
- CN202520477248.0
- Authority / Receiving Office
- CN · China
- Patent Type
- Utility models(China)
- Current Assignee / Owner
- Filing Date
- 2025-03-18
- Publication Date
- 2026-02-27
- Estimated Expiration
- 2035-03-18
AI Technical Summary
In traditional chlorination reactors, chlorine gas is introduced from the top, which leads to problems such as vibration, corrosion and breakage of the chlorine gas pipe, uneven deposition of catalyst at the bottom, and incomplete reaction, affecting production safety and product quality.
The bottom-inlet chlorine design allows for uniform distribution of chlorine and uniform mixing of the catalyst by introducing chlorine gas through the bottom of the vessel and combining it with a stirring device. Variable-angle stirring paddles and bottom chlorine bubbling promote uniform heating of the materials.
It improved the reaction rate, shortened the reaction time, avoided corrosion from chlorine pipe vibration, prevented catalyst from settling to the bottom, and improved product quality and production efficiency.
Smart Images
Figure CN223945672U_ABST
Abstract
Description
TECHNICAL FIELD
[0001] The utility model belongs to the technical field of chlorination kettle, concretely relates to bottom pass chlorine formula chlorination reaction kettle. BACKGROUND
[0002] In the production process of traditional sulfur monochloride, chlorine gas is usually introduced from the top of the reaction kettle. This method has several problems: first, the high-speed introduction of chlorine gas can cause the chlorine gas pipe to vibrate violently, and the chlorine gas pipe is prone to breakage due to fatigue and corrosion after a long time of operation, which not only affects the continuity of production, but also poses a safety hazard; second, since chlorine gas is introduced from the top, the material (such as sulfur) at the bottom of the reaction kettle can solidify due to temperature reduction during the reaction process, causing the discharge port to be blocked during discharge; finally, the catalyst (such as ferric trichloride) is prone to deposit at the bottom of the reaction kettle due to its high density under the action of gravity, and it cannot be fully stirred by the stirring device alone, resulting in uneven reaction, prolonged reaction time, and reduced production efficiency. At the same time, the catalyst sinking to the bottom can also cause local overheating or incomplete reaction, affecting the quality of the final product. Therefore, there is an urgent need for a chlorination reaction kettle design that can solve the above problems to improve production efficiency, ensure production safety, and improve product quality. SUMMARY
[0003] In view of the above deficiencies in the prior art, the purpose of the present utility model is to provide a bottom pass chlorine formula chlorination reaction kettle, which introduces chlorine gas from the bottom of the kettle. This not only achieves uniform distribution of chlorine gas in the reaction material, but also prevents catalyst from sinking to the bottom through chlorine gas bubbling and efficient stirring, promoting uniform heating and mixing of the material, thereby significantly accelerating the reaction rate, shortening the reaction time, and improving product quality.
[0004] The utility model is implemented by adopting the following technical solutions:
[0005] The bottom pass chlorine formula chlorination reaction kettle comprises a kettle body, a feed inlet is provided at the top of the kettle body, a bottom valve port and an electromagnetic vibrator are provided at the bottom of the kettle body, a tetrafluoro distributor extends into the interior of the kettle body through the bottom valve port, the top of the tetrafluoro distributor is of a sealing structure, the side wall is provided with uniformly distributed through holes, and the bottom edge is provided with a flange; a three-way valve is connected below the bottom valve port, the flange of the tetrafluoro distributor at the bottom is fixedly connected with the flange of the bottom valve port through a loose flange, and the specific connection mode is as follows: the tetrafluoro distributor extends into the interior of the kettle body through the bottom valve port, the flange at the bottom of the tetrafluoro distributor is fixed below the flange of the bottom valve port, and the three-way valve is connected below the flange of the tetrafluoro distributor; the horizontal port of the three-way valve is connected with a chlorine gas buffer tank through a pipeline, the vertical port of the three-way valve is connected with a discharge pipeline, a tetrafluoro bag filter is arranged on the discharge pipeline, and a pressure gauge and a flow control valve are arranged on the pipeline between the horizontal port of the three-way valve and the chlorine gas buffer tank.
[0006] The flange of the bottom valve port and the flange of the bottom of the Teflon distributor, and the flange of the bottom of the Teflon distributor and the three-way valve are all provided with sealing gaskets.
[0007] The kettle body is internally provided with a stirring device, which comprises a stirring shaft, a stirring paddle and a driving motor, the stirring shaft extends into the kettle body from the center of the top of the kettle body, the stirring paddle is arranged on the stirring shaft, and the driving motor is connected with the stirring shaft through a speed reducer.
[0008] The kettle body is internally further provided with a temperature monitoring device and a pressure monitoring device.
[0009] The kettle body is internally further provided with a temperature monitoring device and a pressure monitoring device.
[0010] The kettle body is internally further provided with a temperature monitoring device and a pressure monitoring device.
[0011] Compared with the prior art, the beneficial effects of the bottom chlorine feeding type chlorination reaction kettle are as follows:
[0012] (1) The bottom chlorine feeding type chlorination reaction kettle has the advantages that: the chlorine gas can be more uniformly distributed in the reaction materials by the mode of blowing chlorine gas from the kettle bottom, the problem of easy breakage of the chlorine gas pipe due to vibration and corrosion in the traditional top chlorine feeding mode is effectively avoided, meanwhile, the bottom chlorine feeding mode also stirs the reaction materials through the bubbling action of the chlorine gas, the phenomenon of catalyst sinking to the bottom is effectively prevented, the uniform distribution of the catalyst in the reaction process is ensured, the contact area of the chlorine gas with the sulfur and the catalyst is increased, thereby the reaction rate is accelerated, and the reaction time is shortened.
[0013] (2) The bottom chlorine feeding type chlorination reaction kettle has the advantages that: the stirring paddle with a variable angle design can adjust the stirring angle according to the requirements of the reaction process, thereby realizing a more efficient stirring effect; meanwhile, the bubbling action of the chlorine gas at the kettle bottom promotes the further uniform heating and mixing of the materials at the kettle bottom, the uniformity and consistency of the reaction materials in the reaction process are ensured, the quality of the product is improved, and the problems of solidification of the sulfur material and blockage of the discharge are avoided. BRIEF DESCRIPTION OF DRAWINGS
[0014] Fig. 1 It is a structural schematic view of the bottom chlorine feeding type chlorination reaction kettle;
[0015] Fig. 2 It is an enlarged schematic view of A;
[0016] In the figure: 1, kettle body; 2, flange flange of bottom valve port; 3, electromagnetic vibrator; 4, four fluorine distributor; 5, through hole; 6, three-way valve; 7, chlorine buffer tank; 8, discharge pipeline; 9, four fluorine bag filter; 10, pressure gauge; 11, flow control valve; 12, sealing washer; 13, stirring shaft; 14, stirring paddle; 15, driving motor; 16, speed reducer; 17, temperature monitoring device; 18, pressure monitoring device; 19, jacket; 20, feed inlet; 21, exhaust port. DETAILED DESCRIPTION
[0017] In order to make the utility model purposes, technical scheme more clearly, below, combining with the drawing, to the utility model make further detailed description.
[0018] Example 1
[0019] As Figs. 1-2 The bottom chlorine type chlorination reactor shown in the figure, including kettle body 1, kettle body 1 top is equipped with feed inlet 20, kettle body 1 bottom is equipped with bottom valve port and electromagnetic vibrator 3, four fluorine distributor 4 is extended into kettle body 1 inside through bottom valve port, the top of four fluorine distributor 4 is sealed structure, is equipped with evenly distributed through hole 5 on side wall, is equipped with flange on bottom edge;Bottom valve port is connected with three-way valve 6 below, the flange of four fluorine distributor 4 bottom and three-way valve 6 are all fixedly connected with the flange flange 2 of bottom valve port through loose flange;Three-way valve 6 horizontal port is connected with chlorine buffer tank 7 through pipeline, three-way valve 6 vertical port is connected with discharge pipeline 8, is equipped with four fluorine bag filter 9 on discharge pipeline 8, is equipped with pressure gauge 10 and flow control valve 11 on the pipeline between three-way valve 6 horizontal port and chlorine buffer tank 7.
[0020] The flange flange 2 of bottom valve port and the flange between four fluorine distributor 4 bottom and three-way valve 6 are all equipped with sealing washer 12.
[0021] The kettle body 1 is equipped with stirring device, and the stirring device comprises a stirring shaft 13, a stirring paddle 14 and a driving motor 15.
[0022] The kettle body 1 is further provided with temperature monitoring device 17 and pressure monitoring device 18.
[0023] The outer wall of the kettle body 1 is provided with a jacket 19.
[0024] The kettle body 1 top is further provided with exhaust port 21.
[0025] When working, the specific steps are as follows:
[0026] First, sulfur and catalyst ferric chloride are added into the kettle body 1 through the feed inlet 20 on the top of the kettle body 1. Then, the stirring device in the kettle body 1 is started, which is driven by the driving motor 15 to rotate the stirring shaft 13 through the speed reducer 16, and then drives the stirring paddle 14 to mix and stir the materials in the kettle body 1;
[0027] Then, steam is introduced into the jacket 19 to heat the kettle body 1. After the sulfur is melted, the horizontal port of the three-way valve 6 is opened, so that the chlorine gas in the chlorine gas buffer tank 7 enters the three-way valve 6 through the pipeline, and then enters the kettle body 1 through the uniformly distributed through holes 5 on the side wall of the four-fluorine distributor 4, and reacts with the sulfur under the action of the catalyst ferric chloride. In this process, the pressure and flow of chlorine gas are monitored and controlled by the pressure gauge 10 and the flow control valve 11 to ensure the smooth progress of the reaction;
[0028] After the reaction is completed, the horizontal port of the three-way valve 6 is closed, and the supply of chlorine gas is cut off. Then, the valve on the discharge pipeline 8 is opened, and the reaction product and catalyst are discharged together from the kettle body 1. During the discharge process, the catalyst passes through the four-fluorine bag filter 9 on the discharge pipeline 8 for recycling, so as to realize the recycling of the catalyst. If the material is blocked during the discharge process, the electromagnetic vibrator 3 at the bottom of the kettle body 1 can be started to vibrate the material to be discharged smoothly;
[0029] During the whole working process, the temperature monitoring device 17 and the pressure monitoring device 18 continuously monitor the temperature and pressure in the kettle body 1 to ensure that the reaction is carried out in a safe and stable condition.
Claims
1. A bottom-chlorine feed type chlorination reactor, characterized by comprising: The utility model relates to a kind of four fluorine distribution devices for chlorination reaction, including cauldron body (1), cauldron body (1) top is equipped with feed inlet (20), the bottom of cauldron body (1) is equipped with bottom valve mouth and electromagnetic vibrator (3), four fluorine distributor (4) is inserted into cauldron body (1) inside by bottom valve mouth, the top of four fluorine distributor (4) is sealed structure, side wall is equipped with evenly distributed through-hole (5), bottom edge is equipped with flanging;Bottom valve mouth is connected with three-way valve (6) below, the flanging of four fluorine distributor (4) bottom and three-way valve (6) are all fixedly connected with the flange flanging (2) of bottom valve mouth by loose flange;The horizontal port of three-way valve (6) is connected with chlorine buffer tank (7) by pipeline, the vertical port of three-way valve (6) is connected with discharge pipeline (8), four fluorine bag filter (9) is equipped on discharge pipeline (8), pressure gauge (10) and flow control valve (11) are equipped on the pipeline between the horizontal port of three-way valve (6) and chlorine buffer tank (7).
2. The bottom pass chlorine chlorination reactor according to claim 1, characterized in that, The flange flanging (2) of bottom valve mouth and the flanging between the bottom of four fluorine distributor (4) and three-way valve (6) are all equipped with sealing washer (12).
3. The bottom pass chlorine fed chlorination reactor of claim 1 wherein, The cauldron body (1) is equipped with stirring device, and the stirring device includes stirring shaft (13), stirring paddle (14) and driving motor (15), the stirring shaft (13) is inserted from the top center of cauldron body (1), the stirring paddle (14) is arranged on the stirring shaft (13), and the driving motor (15) is connected with the stirring shaft (13) through the speed reducer (16).
4. The bottom pass chlorine fed chlorination reactor of claim 1 wherein, The cauldron body (1) is further equipped with temperature monitoring device (17) and pressure monitoring device (18).
5. The bottom pass chlorination reactor of claim 1, wherein The cauldron body (1) is further equipped with jacket (19) on the outer wall.
6. The bottom pass chlorination reactor of claim 1, wherein The cauldron body (1) is further equipped with exhaust port (21) on the top.