Neodymium iron boron powder surface passivation device

Abstract

The utility model relates to the technical field of neodymium iron boron permanent magnet materials, in particular to a neodymium iron boron powder surface passivation device. The device comprises a gas inlet mechanism, a main body mechanism and an exhaust mechanism which are sequentially communicated, the gas inlet mechanism comprises a nitrogen storage tank, a compressed air storage tank, a mixer, a pressure meter, an oxygen meter, a gas flowmeter and a thermometer, the pressure meter, the oxygen meter, the gas flowmeter and the thermometer are sequentially communicated, and the main body mechanism comprises a sample reaction bottle and a transmission mechanism used for driving the sample reaction bottle to turn over. Nitrogen and dry air are mixed to serve as a passivation gas source, the oxidation reaction rate of neodymium iron boron powder is controlled by flexibly controlling the conditions of oxygen content, temperature, pressure, gas flow and the like in the passivation process, a compact oxidation film is formed on the surface of the neodymium iron boron powder through slow oxidation reaction, the surface activity of powder particles is reduced, and the passivation effect is improved. And the powder is prevented from spontaneous combustion / explosion in the powder testing process under the open condition.

Description

Technical Field

[0001] This utility model relates to the field of neodymium iron boron permanent magnet materials technology, and in particular to a neodymium iron boron powder surface passivation device. Background Technology

[0002] Neodymium iron boron permanent magnets are widely used in many fields such as rail transportation, 3C electronics, medical devices, and new energy due to their small size, light weight, and strong magnetism.

[0003] Currently, grain refinement technology is a key method to significantly improve the coercivity of sintered NdFeB magnets without using heavy rare earth elements. It has become the mainstream production method for high-coercivity, low-heavy-rare-earth sintered NdFeB permanent magnet materials. To achieve grain refinement in sintered NdFeB magnets, the industry is continuously refining NdFeB powder in its powder-making process, gradually approaching the theoretical value. Due to the presence of rare earth elements, NdFeB magnetic powder has extremely high chemical activity and is very prone to oxidation and spontaneous combustion when exposed to water and oxygen for extended periods. The smaller the particle size, the greater the surface activity, making it easier to oxidize and, once exposed to air, highly susceptible to spontaneous combustion, posing a greater fire risk.

[0004] In the production of NdFeB (neodymium iron boron) powder, the powder preparation process is crucial, directly affecting product performance. Therefore, the particle size, loose density, tap density, and flowability of NdFeB powder are key indicators we focus on, often requiring extensive and frequent testing and characterization. To prevent spontaneous combustion of NdFeB fine powder during testing, powder passivation or testing in a glove box is generally employed. However, placing equipment in a glove box is inconvenient, space-constrained, inefficient, and difficult to disassemble and maintain. Therefore, powder surface passivation is a simple, convenient, versatile, and highly flexible method. Currently, there is no specific equipment for NdFeB powder passivation in the industry; most companies use liquid passivating agents or manual air passivation with sample bags. The use of liquid passivating agents... This can cause powder adhesion and agglomeration, affecting the accuracy of powder particle size and flowability tests and increasing test deviation. The artificial air passivation method has a significant risk of spontaneous combustion during sampling and passivation, and there are also cases of uneven and incomplete passivation, resulting in a high powder spontaneous combustion rate. If the amount of powder to be passivated is too large, the risk of spontaneous combustion of artificial air passivation is even higher. If there are too many powder test items, or multiple tests are required, or the demand for a single test is large (such as powder flowability test), then the artificial air passivation method is very inconvenient and affects the test efficiency. Summary of the Invention

[0005] To overcome the above shortcomings, the purpose of this invention is to provide a passivation device for NdFeB powder surface. This device uses a mixture of nitrogen and dry air as the passivation gas source. By flexibly controlling the oxygen content, temperature, pressure, and gas flow rate during the passivation process, the oxidation reaction rate of the NdFeB powder is controlled. A dense oxide film is formed on the surface of the NdFeB powder through a slow oxidation reaction, reducing the surface activity of the powder particles. This ensures that the powder does not spontaneously combust or explode during powder testing under open conditions. This solves the problems in existing technologies where passivating agents affect the accuracy of powder testing, artificial air passivation is incomplete, and powder spontaneous combustion easily damages instruments and equipment.

[0006] The technical solution of this utility model to solve its technical problem is:

[0007] A passivation device for neodymium iron boron powder includes an inlet mechanism, a main body mechanism, and an exhaust mechanism connected in sequence. The inlet mechanism includes a nitrogen storage tank, a compressed air storage tank, a mixer, and a pressure gauge, an oxygen analyzer, a gas flow meter, and a thermometer connected in sequence. The nitrogen storage tank and the compressed air storage tank are both connected to the inlet of the mixer, and the outlet of the mixer is connected to the pressure gauge. The main body mechanism includes a sample reaction bottle and a transmission mechanism for rotating the sample reaction bottle. The thermometer is connected to the left side of the sample reaction bottle through an inlet pipe, and the exhaust mechanism is connected to the right side of the sample reaction bottle through an exhaust pipe.

[0008] The transmission mechanism includes a platform, a drive motor, and a support frame. The two ends of the sample reaction bottle are respectively connected to one of the support frames, and the two support frames are respectively connected to the two sides of the platform. The left support frame has a gear set embedded in it, and the right support frame has a ball bearing embedded in its groove. The drive motor is located below the platform and is connected to the gear set through a transmission belt. The gear set is connected to the sample reaction bottle.

[0009] As an improvement of this utility model, the weighing sensor is disposed below the platform, and the weighing sensor has a slot inside, and the weighing sensor is electrically connected to the touch screen.

[0010] As a further improvement of this utility model, the air inlet pipe and the air outlet pipe are respectively connected to a rotary quick connector located at both ends of the sample reaction bottle.

[0011] As a further improvement of this utility model, the gas inlet of the nitrogen storage tank is connected to a pressure regulating valve, which is connected to an electromagnetic regulating valve, and the gas outlet of the electromagnetic regulating valve is connected to the nitrogen interface of the mixer.

[0012] As a further improvement of this utility model, the air inlet of the compressed air storage tank is connected to a pressure regulating valve, which is connected to a solenoid regulating valve, and the air outlet of the solenoid regulating valve is connected to the air interface of the mixer.

[0013] As a further improvement of this utility model, the exhaust mechanism includes a filter, a three-way purge valve, an oxygen analyzer for exhaust, and an automatic pressure relief valve connected in sequence. The air inlet of the filter is connected to the exhaust pipe, and the automatic pressure relief valve is equipped with a pressure sensor.

[0014] As a further improvement of this utility model, the air inlet of the three-way purge valve is connected to the pressure regulating valve connected to the nitrogen storage tank, the air outlet on one side of the three-way purge valve is connected to the air outlet of the filter, and the air outlet on the other side of the three-way purge valve is connected to the air inlet of the oxygen analyzer of the exhaust mechanism.

[0015] As a further improvement of this utility model, the sample reaction bottle is provided with a safety pressure relief valve, which includes an adjustment knob, a fine powder filter element, a valve body and a pressure gauge. The fine powder filter element is disposed in the air inlet of the valve body and the pressure gauge is embedded in the center of the adjustment knob.

[0016] As a further improvement of this utility model, the rotary quick connector at either end of the sample reaction bottle can be connected to the sampling tube of the powder equipment.

[0017] This invention comprises an air intake mechanism, a main body mechanism, and an exhaust mechanism connected in sequence. The air intake mechanism includes a nitrogen storage tank, a compressed air storage tank, a mixer, and a pressure gauge, an oxygen analyzer, a gas flow meter, and a thermometer connected in sequence. The main body mechanism includes a sample reaction bottle and a transmission mechanism for rotating the sample reaction bottle. This invention uses a mixture of nitrogen and dry air as the passivation gas source. By flexibly controlling the oxygen content, temperature, pressure, and gas flow rate during the passivation process, the oxidation reaction rate of NdFeB powder is controlled. A dense oxide film is formed on the surface of the NdFeB powder through a slow oxidation reaction, reducing the surface activity of the powder particles and ensuring that the powder does not spontaneously combust / explode during powder testing under open conditions. This solves the problems in the prior art where passivating agents affect the accuracy of powder testing, artificial air passivation is incomplete, and powder spontaneous combustion easily damages the instrument. Attached Figure Description

[0018] For ease of explanation, the present invention will be described in detail below with reference to the preferred embodiments and accompanying drawings.

[0019] Figure 1 This is a schematic diagram of the structure of this utility model;

[0020] Figure 2This is a schematic diagram of the main structure of this utility model;

[0021] Figure 3 This is a schematic diagram of the transmission mechanism of this utility model;

[0022] Figure reference numerals: 1-Nitrogen storage tank, 2-Normally closed electromagnetic regulating valve, 3-Pressure gauge, 4-Oxygen analyzer, 5-PPS inlet pipe, 6-Gas pipe fixing bracket, 7-Rotary quick connector, 8-Cap, 9-Support frame, 10-Safety pressure relief valve, 11-PPS exhaust pipe, 12-PID automatic pressure relief valve, 13-Three-way purge valve, 14-Filter, 15-Touch screen, 16-Thermocouple, 17-Handle, 18-Sample reaction bottle, 19-Weighing sensor, 20-Drive motor, 21-Transmission belt, 22-Platform, 23-Gear set, 24-Thermometer, 25-Gas flow meter, 26-Mixer, 27-Pressure regulating valve, 28-Compressed air storage tank, 29-Ball bearing. Detailed Implementation

[0023] To make the objectives, technical solutions, and advantages of this utility model clearer, the present utility model will be further described in detail below with reference to the accompanying drawings and embodiments. It should be understood that the specific embodiments described herein are merely illustrative of the present utility model and are not intended to limit the present utility model.

[0024] like Figures 1 to 3 As shown, the NdFeB powder surface passivation device of this utility model includes an air inlet mechanism, an air outlet mechanism, and a main body mechanism. Specifically, the end air pipe of the air inlet mechanism is connected to the air inlet end of the main body mechanism, and the air outlet end of the main body mechanism is connected to the beginning air pipe of the air outlet mechanism.

[0025] In this invention, the air intake mechanism includes a nitrogen storage tank 1, a compressed air storage tank 28, a pressure regulating valve 27, a pressure gauge 3, a normally closed electromagnetic regulating valve 2, a mixer 26, a thermometer 24, an oxygen analyzer 4, and a gas flow meter 25. The air inlet of the nitrogen storage tank 1 is connected to the pressure regulating valve 27, which is then connected to the normally closed electromagnetic regulating valve 2. The outlet of the normally closed electromagnetic regulating valve 2 is connected to the nitrogen interface of the mixer 26. The air inlet of the compressed air storage tank 28 is connected to the pressure regulating valve 27, which is then connected to the normally closed electromagnetic regulating valve 2. The outlet of the normally closed electromagnetic regulating valve 2 is connected to the air interface of the mixer 26. The outlet of the mixer 26 is sequentially connected to the pressure gauge 3, the oxygen analyzer 4, the normally closed electromagnetic regulating valve 2, the gas flow meter 25, and the thermometer 24, and finally connected to the PPS air intake pipe 5 of the main mechanism.

[0026] In this utility model, the main structure includes a sample reaction bottle 18, a support frame 9, a platform 22, a thermocouple 16, a gear set 23, a drive motor 20, a transmission belt 21, a weighing sensor 19, a touch screen 15, a PPS inlet pipe 5, a PPS exhaust pipe 11, and a pipe fixing bracket 6. The sample reaction bottle 18 is placed on the support frame 9, which is installed on the left and right sides of the platform 22. The gear set 23 is embedded in the left support frame 9, and the ball bearings 29 are embedded in the groove of the right support frame 9. The drive motor 20 is placed below the platform 22, and the transmission belt 21 transmits power to the gear set 23. The gear set 23 consists of two meshing gears. The upper gear of the gear set 23 drives the sample reaction bottle 18 to rotate, causing the powder in the sample reaction bottle to tumble, effectively promoting the reaction between the powder and oxygen, ensuring that the powder is fully passivated, and improving the passivation reaction efficiency.

[0027] In this invention, the sample reaction bottle 18 includes a rotary quick connector 7, a cap 8, a limiting ear, a bottle body, a safety relief valve 10, and a handle 17. The sample reaction bottle 18 has symmetrical ends, with a thicker cylinder in the middle and thinner cylinders at both ends. The thicker and thinner cylinders are connected by a 45° conical transition. Both ends of the bottle body are equipped with internally threaded caps 8. Unscrewing the caps 8 allows the passivated powder sample to be poured out. The rotary quick connector 7 for the gas tube is installed at the center of the cap 8. After the gas tube is connected, the rotary quick connector 7 allows the gas tube to rotate 360°. The rotary quick connector 7 is equipped with a rotary sealing device to ensure no air leakage during rotation. The safety relief valve 10 is installed on the thicker cylinder in the middle of the bottle body, and the handle 17 is installed on the side of the thicker cylinder in the middle of the bottle body. The thinner cylinder at the air inlet end of the bottle body has a limiting ear, which is connected to the groove of the central hole of the gear on the gear set 23. The cap 8 at the left end of the bottle body can pass through the central hole of the gear on the gear set 23.

[0028] In this invention, the safety relief valve 10 includes an adjustment knob, a fine powder filter element, a valve body, and a pressure gauge. The fine powder filter element is installed at the air inlet of the valve body to prevent fine powder from being carried away during exhaust. The pressure gauge is embedded in the center of the adjustment knob and can measure and display the internal air pressure of the sample reaction bottle 18 and the automatic exhaust pressure set by the safety relief valve 10. The adjustment function of the knob is switched by pulling it up. When the adjustment knob is not pulled up, it is in position 0, and pressure adjustment cannot be set to prevent accidental operation. Pulling the knob up one position is position 1, and the exhaust pressure can be set by rotating the knob. The pressure adjustment range is 0.02~0.6MPa. The sample reaction bottle 18 will automatically exhaust pressure when the set pressure is exceeded. Pulling the knob up two positions is position 2, which allows manual exhaust to avoid the sample reaction bottle 18 and the powder equipment having too small a pressure difference during secondary sampling, which would prevent secondary sampling.

[0029] In this invention, the sampling method for the sample reaction bottle 18 is as follows: The rotary quick-connect fitting 7 at either end of the sample reaction bottle 18 can be connected to the sampling tube of the powder equipment. The sampling valve of the powder equipment is opened, and the high-pressure airflow within the powder equipment carries the powder to the sample reaction bottle 18. After the sampling process is complete, the sampling tube is disconnected. If secondary sampling is required, the gas in the sample reaction bottle 18 must first be manually released to depressurize it before connecting the sampling tube for secondary sampling.

[0030] In this invention, the PPS inlet pipe 5 and the PPS exhaust pipe 11 pass through the pipe fixing bracket 6 and are inserted into the rotary quick connectors 7 at both ends of the sample reaction bottle 18. Thermocouple 16 is embedded in the PPS exhaust pipe 11 and is used to measure the temperature during the powder passivation process. The pipe fixing bracket 6 and the touch screen 15 are both mounted on the platform 22. The weighing sensor 19 is placed below the platform 22 and passes through the square hole in the platform 22. When the sample reaction bottle 18 is placed in the slot of the weighing sensor 19, the weighing sensor 19 can measure the weight and feed it back to the touch screen 15 for easy calculation of the sample volume.

[0031] In this invention, the exhaust mechanism includes a filter 14, a three-way purge valve 13, an oxygen analyzer 4, and a PID automatic pressure relief valve 12. The inlet of the filter 14 is connected to the PPS exhaust pipe 11 of the main body. The inlet of the three-way purge valve 13 is connected to the pressure regulating valve 27 of the nitrogen storage tank 1. One outlet of the three-way purge valve 13 is connected to the outlet of the filter 14, and the other outlet is connected to the inlet of the oxygen analyzer 4. The outlet of the oxygen analyzer 4 is connected to the PID automatic pressure relief valve 12. The PID automatic pressure relief valve 12 is equipped with a pressure sensor, which can measure the pipeline pressure and set the automatic exhaust pressure. When the measured pressure is greater than the set pressure, it will automatically exhaust and record the pressure measurement curve on the touch screen 15.

[0032] In this utility model, the touch screen 15 can display the pipeline system diagram, the values ​​of the weighing sensor 19, the oxygen analyzer 4, the pressure gauge 3, the thermometer 24, the temperature measurement value of the thermocouple 16, and the flow meter 25, and record the temperature, pressure, and oxygen content curves on the exhaust pipe. The normally closed electromagnetic regulating valve 2 can be opened or closed on the touch screen 15.

[0033] The method for passivating the surface of NdFeB powder in this invention is as follows:

[0034] 1. Nitrogen purging: Adjust the safety relief valve 10 of the sample reaction bottle 18 to 0.2MPa, then insert the nitrogen tube into the rotary quick connector 7 at any end of the sample reaction bottle 18, and introduce nitrogen at 0.6MPa. After the safety relief valve 10 vents for half a minute, disconnect the nitrogen tube, and then adjust the safety relief valve 10 to 0.6MPa.

[0035] II. Powder Sampling: The air pressure of the air jet mill fine powder sampling tube is 0.6 MPa. Insert the air jet mill fine powder sampling tube into the rotary quick connector 7 at the left end of the sample reaction bottle 18, open the air jet mill fine powder sampling valve, and close the air jet mill fine powder sampling valve after the pressure gauge of the safety relief valve 10 shows 0.6 MPa.

[0036] 3. Sample Weighing: Place the sample reaction bottle 18 that has been sampled on the weighing sensor 19 and calculate the sample weight as 0.8 kg. At this point, the sample weight does not meet the required amount, and a second sampling is required. Pull the adjustment knob of the safety relief valve 10 upward to the 2 position to manually release the pressure. When the pressure gauge of the safety relief valve 10 shows 0.2 MPa, press the adjustment knob downward to the 0 position, and then repeat the second step. Place the sample reaction bottle 18 that has been sampled on the weighing sensor 19 again and calculate the sample weight as 1.2 kg. At this point, the sample weight meets the required amount.

[0037] IV. Setup and Installation: Place the sample reaction bottle 18 (after sampling) into the support frame 9. Insert the limiting ear on the left end of the sample reaction bottle 18 into the center slot of the gear on the gear set 23. Place the right end of the sample reaction bottle 18 on the right support frame 9. Pass the PPS inlet pipe 5 and PPS exhaust pipe 11 through the left and right side air pipe fixing frames 6 and insert them into the rotary quick connector 7 at the measuring end of the sample reaction bottle 18. Start the drive motor 20 to rotate the sample reaction bottle 18 at a speed of 50 r / min. Set the pressure regulating valves 27 of the nitrogen and air lines to 0.4 MPa. Set the normally closed electromagnetic regulating valve 2 of the air line to 0. Set the speed of the mixer 26 to 100 r / min. Set the automatic exhaust pressure of the PID automatic pressure relief valve 12 to 0.3 MPa.

[0038] V. Passivation Treatment: The normally closed solenoid valve 2 of the nitrogen pipeline is opened to 50%, and the normally closed solenoid valve 2 of the mixed gas pipeline is opened to 100%. By adjusting the opening of the normally closed solenoid valve 2 of the air pipeline, the oxygen content in the mixed gas pipeline is controlled to be 1000~1100ppm. After the PID automatic pressure relief valve 12 continuously vents for 2 minutes, the normally closed solenoid valve 2 of the mixed gas pipeline is closed. If the change in the thermocouple 16 value within 5 minutes is less than 1℃, or the change in the oxygen content value in the exhaust pipeline within 5 minutes is less than 10ppm, the passivation treatment process is stopped. If the oxygen content in the exhaust pipeline is below 100ppm, the normally closed solenoid valve 100% of the mixed gas pipeline is reopened, and the normally closed solenoid valve 2 of the mixed gas pipeline is closed after the PID automatic pressure relief valve 12 continuously vents for 2 minutes. If the temperature of the thermocouple 16 exceeds 50℃, the normally closed solenoid valve 2 of the air pipeline is closed. The normally closed electromagnetic regulating valve 2 of the nitrogen pipeline and the mixed gas pipeline is adjusted to 100% for air cooling. When the temperature of thermocouple 16 drops below 25℃, the normally closed electromagnetic regulating valve 2 of the nitrogen pipeline is adjusted to 50%. By adjusting the opening of the normally closed electromagnetic regulating valve 2 of the air pipeline, the oxygen content of the mixed gas pipeline is controlled to be 1000~1100ppm. After the PID automatic pressure relief valve 12 continuously exhausts for 2 minutes, the normally closed electromagnetic regulating valve 2 of the mixed gas pipeline is closed.

[0039] VI. Passivation Test: Close the normally closed solenoid valve 2 of the nitrogen pipeline, open the normally closed solenoid valve 100% of the mixed gas pipeline, adjust the opening of the normally closed solenoid valve 2 of the air pipeline to 50%, and after the PID automatic pressure relief valve 12 continuously exhausts gas for 2 minutes, close the normally closed solenoid valve 2 of the mixed gas pipeline; observe that the change in the thermocouple 16 value within 5 minutes is less than 1℃, or the change in the oxygen content value of the exhaust pipeline within 5 minutes is less than 10ppm, then the passivation is considered complete.

[0040] 7. Sample discharge: Close all normally closed electromagnetic regulating valves 2, start the three-way purge valve 13 to purge three times, disconnect the PPS inlet pipe 5 and PPS exhaust pipe 11 at both ends of the sample reaction bottle 18, remove the sample reaction bottle 18, unscrew the cap 8, and pour out the NdFeB sample powder.

[0041] The above description is only a preferred embodiment of the present utility model and is not intended to limit the present utility model. Any modifications, equivalent substitutions and improvements made within the spirit and principles of the present utility model should be included within the protection scope of the present utility model.

Claims

1. A passivation device for neodymium iron boron powder surface, characterized in that, The device includes an air intake mechanism, a main body mechanism, and an exhaust mechanism connected in sequence. The air intake mechanism includes a nitrogen storage tank, a compressed air storage tank, a mixer, and a pressure gauge, an oxygen analyzer, a gas flow meter, and a thermometer connected in sequence. The nitrogen storage tank and the compressed air storage tank are both connected to the air intake of the mixer, and the air outlet of the mixer is connected to the pressure gauge. The main body mechanism includes a sample reaction bottle and a transmission mechanism for rotating the sample reaction bottle. The thermometer is connected to the left side of the sample reaction bottle through an air intake pipe, and the exhaust mechanism is connected to the right side of the sample reaction bottle through an exhaust pipe. The transmission mechanism includes a platform, a drive motor, and a support frame. The two ends of the sample reaction bottle are respectively connected to one of the support frames, and the two support frames are respectively connected to the two sides of the platform. The left support frame has a gear set embedded in it, and the right support frame has a ball bearing embedded in its groove. The drive motor is located below the platform and is connected to the gear set through a transmission belt. The gear set is connected to the sample reaction bottle.

2. The NdFeB powder surface passivation device according to claim 1, characterized in that, The weighing sensor is located below the platform, and the weighing sensor has a slot inside. The weighing sensor is electrically connected to the touch screen.

3. The NdFeB powder surface passivation device according to claim 1 or 2, characterized in that, The air inlet pipe and the air outlet pipe are respectively connected to a rotary quick connector located at both ends of the sample reaction bottle.

4. The NdFeB powder surface passivation device according to claim 1, characterized in that, The nitrogen storage tank's gas inlet is connected to a pressure regulating valve, which is connected to a solenoid regulating valve. The outlet of the solenoid regulating valve is connected to the nitrogen port of the mixer.

5. The NdFeB powder surface passivation device according to claim 1, characterized in that, The compressed air tank's air inlet is connected to a pressure regulating valve, which is connected to a solenoid regulating valve. The solenoid regulating valve's outlet is connected to the air interface of the mixer.

6. The NdFeB powder surface passivation device according to claim 1, characterized in that, The exhaust mechanism includes a filter, a three-way purge valve, an oxygen analyzer for exhaust, and an automatic pressure relief valve connected in sequence. The air inlet of the filter is connected to the exhaust pipe, and the automatic pressure relief valve is equipped with a pressure sensor.

7. The NdFeB powder surface passivation device according to claim 6, characterized in that, The inlet of the three-way purge valve is connected to the pressure regulating valve connected to the nitrogen storage tank. The outlet on one side of the three-way purge valve is connected to the outlet of the filter, and the outlet on the other side of the three-way purge valve is connected to the inlet of the oxygen analyzer of the exhaust mechanism.

8. The NdFeB powder surface passivation device according to claim 1, characterized in that, The sample reaction flask is equipped with a safety pressure relief valve, which includes an adjustment knob, a fine powder filter element, a valve body, and a pressure gauge. The fine powder filter element is located inside the air inlet of the valve body, and the pressure gauge is embedded in the center of the adjustment knob.

9. The NdFeB powder surface passivation device according to claim 1, characterized in that, The rotary quick-connector at either end of the sample reaction bottle can be connected to the sampling tube of the powder equipment.

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