Graphdiyne-modified flexible supercapacitor electrode plate assembly

By using a graphdiyne-modified electrode structure, combined with support and capacitor components, the problems of increased resistance and structural instability of flexible supercapacitor electrode sheets during long-term use are solved, achieving rapid charging and discharging and mechanical stability, making it suitable for wearable devices and flexible electronic devices.

CN224190813UActive Publication Date: 2026-05-01SHANDONG LINGKE NEW MATERIAL TECH CO LTD
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Utility models(China)
Current Assignee / Owner
SHANDONG LINGKE NEW MATERIAL TECH CO LTD
Filing Date
2025-06-03
Publication Date
2026-05-01

AI Technical Summary

Technical Problem

Existing flexible supercapacitor electrode assemblies suffer from increased resistance and decreased capacitance performance during long-term use. Furthermore, the structure is prone to displacement and deformation after repeated bending and stretching, making it difficult to maintain stability and flexibility.

Method used

The electrode sheet structure is modified with graphyne and combined with a support component and a capacitor component. The support component consists of a support layer and a support outer layer. The support layer is composed of a support plate and a honeycomb plate. The capacitor component includes a functional layer, a graphyne layer and a conductive layer. The support component provides mechanical stability, and the graphyne layer provides conductivity and flexibility to enhance the bending and compressive strength of the electrode sheet.

Benefits of technology

It improves the mechanical stability and electrochemical performance of the electrode sheet, enables rapid charging and discharging, extends the cycle life of the supercapacitor, and is suitable for wearable devices and flexible electronic devices.

✦ Generated by Eureka AI based on patent content.

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Abstract

The utility model provides a graphdiyne modified flexible supercapacitor electrode slice assembly, which comprises a support assembly and a capacitor assembly, the outer side surface of the support assembly is provided with an electrode assembly used for being connected with a discharge device, the support assembly comprises a support layer used for supporting the capacitor assembly and a support outer layer, and the support outer layer is provided with an electrode. Compared with the prior art, the utility model has the following beneficial effects: through the arrangement of the supporting layer comprising the supporting plate and the honeycomb plate and the supporting assembly of the supporting outer layer, when in use, the supporting plate provides basic bearing, and the honeycomb plate disperses stress with high mechanical efficiency by virtue of a unique porous structure, so that the strength of the honeycomb plate is improved, and the service life of the honeycomb plate is prolonged. And meanwhile, the supporting outer layer further buffers external impact and protects an internal capacitor assembly, the three parts are combined, so that the electrode plate has excellent mechanical stability, electrochemical performance and environmental adaptability, and the requirements of wearable equipment, flexible electronics and other scenes can be met.
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Description

A graphdiyne-modified flexible supercapacitor electrode assembly Technical Field

[0001] This utility model belongs to the field of electrical equipment, and specifically relates to a graphdiyne-modified flexible supercapacitor electrode assembly. Background Technology

[0002] Flexible supercapacitor electrode assemblies are key energy storage components used in flexible electronic devices. Currently, there are several areas for improvement in flexible supercapacitor electrode assemblies. From an energy storage perspective, commonly used electrode materials such as carbon-based materials are insufficient to meet the demands of long-term continuous power supply. To address this, a conventional approach is to introduce pseudocapacitive materials such as metal oxides, but this increases manufacturing complexity and cost. Regarding structural stability, the bonding forces between materials within the electrode sheet are not very strong. After repeated bending and stretching, the internal structure is prone to displacement and deformation, such as poor contact between electrode material particles, leading to increased resistance and decreased capacitance. Stability is generally enhanced by optimizing material ratios and binders, but this may affect the flexibility of the electrode sheet and fails to fundamentally solve the problem of cumulative damage caused by repeated deformation. Therefore, a new structure is needed to address these technical issues. Summary of the Invention

[0003] To address the shortcomings of existing technologies, the purpose of this invention is to provide a graphdiyne-modified flexible supercapacitor electrode assembly, thereby resolving the problems mentioned in the background section.

[0004] This utility model is achieved through the following technical solution: a graphdiyne-modified flexible supercapacitor electrode assembly, comprising: a support assembly and a capacitor assembly, wherein an electrode assembly for connection to a discharge device is mounted on the outer surface of the support assembly, the support assembly includes a support layer and a support outer layer for supporting the capacitor assembly, the support outer layer is mounted on the upper surface of the support layer, and the capacitor assembly is mounted inside the support outer layer, wherein the capacitor assembly includes a functional layer for energy storage and discharge, and a graphdiyne layer and a conductive layer are mounted on the lower surface of the functional layer.

[0005] In a preferred embodiment, the outer edge of the upper surface of the support layer is rectangular and a support outer layer is installed thereon. The length and width of the support layer match the length and width of the support outer layer. The support layer includes a support plate and a honeycomb plate.

[0006] In a preferred embodiment, two support plates are provided, both of which have the same structure. A honeycomb panel is installed between the two support plates. Both the support plates and the honeycomb panel are made of polyethylene terephthalate. In use, the support plates, the support layers of the honeycomb panel, and the support components of the outer support layer provide basic load-bearing capacity. The honeycomb panel, with its unique porous structure, disperses stress with high mechanical efficiency, enhancing the bending and compressive strength of the electrode sheet.

[0007] In a preferred embodiment, the electrode assembly includes a first connecting plate and a second connecting plate. The first connecting plate is connected to an external power supply device through electrode points, and the first connecting plate is electrically connected to a support assembly through the second connecting plate.

[0008] In a preferred embodiment, a protective coating is provided on the upper surface of the functional layer, the functional layer is composed of a capacitor, a graphyne layer is installed on the lower surface of the functional layer, and a fiber layer is installed on the lower surface of the graphyne layer. The graphyne layer has good flexibility, and when combined with a support layer, it can maintain structural stability when the electrode sheet is bent, significantly enhancing the cycle life and overall performance of the supercapacitor.

[0009] In a preferred embodiment, a conductive layer is mounted on the lower surface of the fiber layer, and the lower surface of the conductive layer is connected to the upper surface of the support layer.

[0010] After adopting the above technical solution, the beneficial effects of this utility model are as follows: 1. By setting a support component, the support component includes a support layer for supporting the capacitor component and a support outer layer. The support outer layer is installed on the upper surface of the support layer. The support layer includes a support plate and a honeycomb plate. In use, the support plate, the support layer of the honeycomb plate, and the support outer layer of the support component provide basic load-bearing capacity. The honeycomb plate, with its unique porous structure, disperses stress with high mechanical efficiency, enhancing the bending and compressive strength of the electrode sheet. At the same time, the support outer layer further buffers external impacts and protects the internal capacitor component. The combination of the three allows the electrode sheet to have excellent mechanical stability, electrochemical performance, and environmental adaptability, which can meet the needs of wearable devices, flexible electronics, and other scenarios.

[0011] 2. By setting up a capacitor assembly, the capacitor assembly is installed inside the outer support layer. The capacitor assembly includes a functional layer for energy storage and discharge. A graphdiyne layer and a conductive layer are installed on the lower surface of the functional layer. In use, the graphdiyne layer in the capacitor assembly can reduce the internal resistance of the electrode due to its excellent conductivity, so as to achieve rapid charging and discharging, thereby increasing the specific capacitance. At the same time, the graphdiyne layer has good flexibility. When combined with the support layer, it can maintain structural stability when the electrode sheet is bent, which significantly enhances the cycle life and overall performance of the supercapacitor. Attached Figure Description

[0012] To more clearly illustrate the technical solutions in the embodiments of this utility model or the prior art, the drawings used in the description of the embodiments or the prior art will be briefly introduced below. Obviously, the drawings described below are only some embodiments of this utility model. For those skilled in the art, other drawings can be obtained based on these drawings without creative effort.

[0013] Figure 1 is a schematic diagram of the overall structure of a graphdiyne-modified flexible supercapacitor electrode assembly according to this utility model.

[0014] Figure 2 is a schematic diagram of the support layer of a graphdiyne-modified flexible supercapacitor electrode assembly according to this utility model.

[0015] Figure 3 is a schematic diagram of the functional layer of a graphdiyne-modified flexible supercapacitor electrode assembly according to this invention.

[0016] Figure 4 is a schematic diagram of the graphdiyne layer in a graphdiyne-modified flexible supercapacitor electrode assembly according to this invention.

[0017] In the diagram, 100 - connecting plate one, 110 - electrode point, 120 - connecting plate two;

[0018] 200 - Outer supporting layer, 210 - Supporting layer, 211 - Supporting plate, 212 - Honeycomb panel;

[0019] 300 - Functional layer, 301 - Protective coating, 320 - Conductive layer, 330 - Graphdiyne layer, 340 - Fiber layer. Detailed Implementation

[0020] The technical solutions of the present utility model will be clearly and completely described below with reference to the accompanying drawings of the embodiments. Obviously, the described embodiments are only some embodiments of the present utility model, and not all embodiments. Based on the embodiments of the present utility model, all other embodiments obtained by those of ordinary skill in the art without creative effort are within the protection scope of the present utility model.

[0021] Please refer to Figures 1 to 4, as the first embodiment of this utility model: a graphdiyne-modified flexible supercapacitor electrode assembly, including: a support assembly and a capacitor assembly. The outer surface of the support assembly is equipped with an electrode assembly for connection with a discharge device. The support assembly includes a support layer 210 and a support outer layer 200 for supporting the capacitor assembly. The support outer layer 200 is installed on the upper surface of the support layer 210. The capacitor assembly is installed inside the support outer layer 200. The capacitor assembly includes a functional layer 300 for energy storage and discharge. The lower surface of the functional layer 300 is equipped with a graphdiyne layer 330 and a conductive layer 320.

[0022] The outer edge of the upper surface of the support layer 210 is rectangular and a support outer layer 200 is installed thereon. The length and width of the support layer 210 match the length and width of the support outer layer 200. The support layer 210 includes a support plate 211 and a honeycomb plate 212.

[0023] There are two support plates 211, and the two support plates 211 have the same structure. A honeycomb panel 212 is installed between the two support plates 211. The support plates 211 and the honeycomb panel 212 are both made of polyethylene terephthalate.

[0024] In use, the functional layer 300, graphdiyne layer 330, fiber layer 340, and conductive layer 320 are all mounted on the upper surface of the support layer 210, and are disposed inside the outer support layer 200. When the functional layer 300 is in use, the user can discharge it through an external device to charge and discharge the functional layer 300 (the specific working principle is existing technology, and the specific circuit connection method and structure are not described here). (To be elaborated further), the support plate 211 and the support layer 210 of the honeycomb plate 212, as well as the support components of the outer support layer 200, provide basic load-bearing capacity during use. The honeycomb plate 212, with its unique porous structure, disperses stress with high mechanical efficiency, enhancing the electrode sheet's resistance to bending and compression. Meanwhile, the outer support layer 200 further buffers external impacts and protects the internal capacitor components. The combination of these three components gives the electrode sheet excellent mechanical stability, electrochemical performance, and environmental adaptability, meeting the needs of wearable devices, flexible electronics, and other scenarios.

[0025] Please refer to Figures 1 to 4 as the second embodiment of this utility model: Based on the description in the above embodiments, the electrode assembly further includes a first connecting plate 100 and a second connecting plate 120. The first connecting plate 100 is connected to an external power supply device through electrode point 110, and the first connecting plate 100 is electrically connected to the support assembly through the second connecting plate 120.

[0026] The upper surface of the functional layer 300 is provided with a protective coating 301. The functional layer 300 is composed of a capacitor. The lower surface of the functional layer 300 is provided with a graphdiyne layer 330. The lower surface of the graphdiyne layer 330 is provided with a fiber layer 340.

[0027] A conductive layer 320 is mounted on the lower surface of the fiber layer 340, and the lower surface of the conductive layer 320 is connected to the upper surface of the support layer 210.

[0028] During use, when storing electricity, the energy is first transferred to the conductive layer 320, and then to the graphyne layer 330 (the graphyne layer 330 is existing technology, and its specific structure and working principle will not be described in detail here). Then, the graphyne layer 330 transfers the energy to the functional layer 300 for energy storage and discharge operations. Since the graphyne layer 330 is set in the capacitor assembly, its excellent conductivity can reduce the internal resistance of the electrode and achieve rapid charging and discharging, thereby increasing the specific capacitance. At the same time, the graphyne layer 330 has good flexibility. When combined with the support layer 210, it can maintain structural stability when the electrode sheet is bent, which significantly enhances the cycle life and overall performance of the supercapacitor.

[0029] The above description is only a preferred embodiment of the present utility model and is not intended to limit the present utility model. Any modifications, equivalent substitutions, improvements, etc., made within the spirit and principles of the present utility model should be included within the protection scope of the present utility model.

Claims

1. A graphdiyne-modified flexible supercapacitor electrode sheet assembly comprising: A support assembly and a capacitor assembly, characterized in that an electrode assembly for connection to a discharge device is mounted on the outer surface of the support assembly, the support assembly includes a support layer (210) for supporting the capacitor assembly and a support outer layer (200), the support outer layer (200) is mounted on the upper surface of the support layer (210), the capacitor assembly is mounted inside the support outer layer (200), the capacitor assembly includes a functional layer (300) for storing and discharging electricity, and a graphyne layer (330) and a conductive layer (320) are mounted on the lower surface of the functional layer (300).

2. The graphyne-modified flexible supercapacitor electrode sheet assembly of claim 1, wherein: The outer edge of the upper surface of the support layer (210) is rectangular and a support outer layer (200) is installed thereon. The length and width of the support layer (210) match the length and width of the support outer layer (200). The support layer (210) includes a support plate (211) and a honeycomb plate (212).

3. The graphdiyne-modified flexible supercapacitor electrode assembly as described in claim 2, characterized in that: There are two support plates (211), and the two support plates (211) have the same structure. A honeycomb plate (212) is installed between the two support plates (211). The support plates (211) and the honeycomb plate (212) are both made of polyethylene terephthalate.

4. The graphdiyne-modified flexible supercapacitor electrode assembly as described in claim 3, characterized in that: The electrode assembly includes a first connecting plate (100) and a second connecting plate (120). The first connecting plate (100) is connected to an external power supply device through an electrode point (110), and the first connecting plate (100) is electrically connected to a support assembly through the second connecting plate (120).

5. The graphdiyne-modified flexible supercapacitor electrode assembly as described in claim 4, characterized in that: The upper surface of the functional layer (300) is provided with a protective coating (301), the functional layer (300) is composed of a capacitor, the lower surface of the functional layer (300) is provided with a graphyne layer (330), and the lower surface of the graphyne layer (330) is provided with a fiber layer (340).

6. The graphdiyne-modified flexible supercapacitor electrode assembly as described in claim 5, characterized in that: A conductive layer (320) is mounted on the lower surface of the fiber layer (340), and the lower surface of the conductive layer (320) is connected to the upper surface of the support layer (210).