Nonwoven fabric and method for producing the same

Abstract

Nonwoven fabric (1), in particular for a filter medium, with a first layer (12), wherein at least one integral fiber strand (2) of the first layer (12) has a first fiber section (3) and a second fiber section (4) in the longitudinal direction, characterized by that the fiber strand (2) has a thickening (5) in the second fiber section (4), which additionally has a second layer (13) whose pore size is on average smaller than that of the first layer, which additionally has a third layer (14) whose pore size is on average smaller than that of the second layer and which is preferably arranged on the side of the first layer facing away from the second layer, the three layers (12, 13, 14) together have a mass coverage of 105 g / m 2 up to 180 g / m 2 and / or have a thickness of 1.2 mm to 2.5 mm.

Description

[0001] The invention relates to a nonwoven fabric, in particular for a filter medium, comprising at least one fiber strand which has at least a first section and a second section in the longitudinal direction.

[0002] Nonwoven fabrics of this type are used in filter media, e.g. for room air filters or filters for air conditioning systems, but especially for air filters for vehicle interiors or for engine filters.

[0003] The nonwoven fabrics are usually produced in a primary forming process, in particular with a melt spinning process such as a spun bond process or a meltblown process, as described, for example, in DE 41 23 122 A1.

[0004] The intake air of internal combustion engines, for example in motor vehicles or off-highway applications, is typically filtered to protect the engine's combustion chamber from mechanical damage caused by particles drawn in from the ambient air. An important criterion in the design of the elements is to ensure a long service life of the filter while maintaining high separation efficiency for the intake particles.

[0005] On the other hand, motor vehicles have a precisely calculated energy distribution system. Only a limited amount of energy is available for heating / ventilation / air conditioning, especially in electrically powered vehicles. Due to increasingly strict emissions regulations, these energy quantities must be reduced ever further, especially in electric vehicles, where the stored energy should be used only for propulsion if possible. The costs of vehicle components must also remain within a narrow range. On the other hand, vehicle buyers have ever greater demands for comfort and safety. From this perspective, particulate filters with the lowest possible pressure drop or differential pressure are particularly important, as the fan motor only needs to generate a low pressure, thus reducing energy consumption.Furthermore, due to the lower power required, it also operates more quietly, which reduces noise and thus significantly increases driving comfort.

[0006] The demand for filter systems with low differential pressure competes with the required separation efficiency and the required service life, i.e. the time in km mileage that a filter can remain in the vehicle before it needs to be replaced. For example, pollen filters that only filter pollen from the air flowing into the vehicle are not sufficient for the vehicle interior. The allergens to which the immune system reacts are proteins whose diameter is only a fraction of the pollen diameter. They are in the size range around 0.1 µm, i.e. in the range that poses the greatest problems for particle filters, the so-called MPPS (most penetrating particle size) range. Accordingly, the separation efficiency in this size range should be at least 50%, whereby this is measured using an aerosol whose particles are approximately the same size as the particles to be filtered, e.g. sodium chloride.At the same time, such filters should achieve a service life of at least 30,000 km when installed in motor vehicles.

[0007] In common filters, such as ring filters or frame filters, the nonwoven filter medium is pleated in a zigzag pattern to increase the surface area of the filter medium per unit area of the filter. To make the filter medium pleatable, it must have a certain degree of rigidity. Even in the pleated state, a certain degree of rigidity is desirable in the filter medium to prevent the individual pleats from collapsing upon one another when exposed to the air to be filtered.

[0008] Various methods are known in the art to increase the stiffness of a filter medium. For example, it is known to provide a filter medium with an embossed pattern, which stiffens the material through its three-dimensional structure.

[0009] Furthermore, it is known to use bicomponent fibers that combine the properties of two different polymers in a nonwoven fabric. A nonwoven fabric with high-strength, tear-resistant component fibers is disclosed, for example, in EP 1 866 472 B1.

[0010] DE 38 86 199 T2 deals with a filter element with adjustable draw and effectiveness for tobacco smoking articles. In particular, D1 discloses a filter plug for smoking articles made of thermoplastic fibers and featuring a controlled pressure drop and filter effectiveness. Crossover points between the fibers are induced via welding points (34).

[0011] WO 2011 / 133394 A1 discloses thickenings in a fiber fleece which are induced by additives in the form of particles.

[0012] JP 2010 254 685 A relates to an α-(unsaturated alkoxyalkyl) acrylate composition and a method for producing the same. More specifically, α-(unsaturated alkoxyalkyl) acrylates can be suitably used as raw materials for the production of curable resin compositions, dye dispersion compositions, and the like in various fields such as engineering plastics, optical materials, and resist materials.

[0013] US 2012 171408 A1 relates to nonwovens, such as woven and nonwoven webs. In particular, nonwovens treated by mechanical deformation to improve their softness or bulk properties. Further prior art is JP 2010-84284 A.

[0014] Known nonwovens with increased stiffness have the disadvantage that, on the one hand, they can only be produced with increased effort and / or the stiffness is only increased by subsequent processing of the nonwoven.

[0015] The invention therefore has for its object to provide a fiber fleece with increased stiffness which can be produced simply and inexpensively, in particular on existing devices.

[0016] This object is achieved according to the invention by a nonwoven fabric according to claim 1 and a method for producing a nonwoven fabric according to claim 18.

[0017] The thickened portions according to the invention act as structural reinforcements of the nonwoven fabric. This contributes to increasing its rigidity. This makes the nonwoven fabric more easily pleatable and also retains its shape better across its entire surface. As a result, individual pleats of a filter do not fall or collapse upon one another when exposed to air flow to be filtered, thus maintaining a large filter surface.

[0018] A nonwoven fabric, as defined by the invention, is a nonwoven fabric in which fiber strands are laid on top of one another during the primary forming process and bonded together to form a nonwoven fabric. If necessary, consolidation occurs in a further step through calendering, thermobonding, hot air welding, and / or ultrasonic welding.

[0019] A fiber strand within the meaning of the invention is formed by one or more fibers, wherein the fiber(s) have no interruption in the longitudinal direction and are therefore one-piece.

[0020] A thickening within the meaning of the invention is an enlargement of the diameter and / or circumference of the fiber strand.

[0021] Crimp, as defined by the invention, is a twist of the fiber strand with itself and is preferably described by the so-called in-crimping. To determine this, the length of the fiber in the crimped and stretched state and the required tensile stress are required. Such a determination can be made, in particular, according to DIN 53840.

[0022] A fiber bundle within the meaning of the invention consists of several fiber strands.

[0023] A polymer within the meaning of the invention is a pure polymer or a polymer mixture. In particular, it has a characteristic distribution of molecular chain length and / or a characteristic molecular structure.

[0024] Air permeability in the sense of the invention is the volume per square meter through which a fiber fleece flows at 200 Pa flow pressure per second.

[0025] The separation efficiency within the meaning of the invention is determined with NaCl particles, in particular with a size of 0.3 µm to 0.5 µm and according to DIN 71460-1, at an inflow velocity of 0.14 m / s.

[0026] The mass occupancy within the meaning of the invention is the mass per unit area and is determined according to DIN EN 29073-1.

[0027] The average pore size within the meaning of the patent is determined in accordance with the bubble point test according to the standards ASTM D6767, ASTM F316-0 and / or ISO 2942, ISO 4003, in particular using the Topas PSM 165 measuring device.

[0028] Preferred embodiments are claimed in the subclaims.

[0029] According to the invention, the thickening comprises a crimp of the fiber strand. In this case, the crimp, in particular, forms the thickening. The crimp strengthens the affected fiber strand in the second section. This occurs, in particular, through the interaction of individual swirls of the fiber strand with each other.

[0030] In a further preferred embodiment, the thickening comprises crimps and / or fiber bundles. The crimps and / or fiber bundles not only reinforce individual fiber strands, but also mutually support adjacent fiber strands.

[0031] In a further preferred embodiment, the thickened portion comprises intertwined loops of the fiber strand. The interaction of individual loops of a fiber strand also leads to a reinforcement of the nonwoven fabric. Alternatively, the loops of several fiber strands can also be intertwined.

[0032] In a further preferred embodiment, the thickened portion has a region in which the fiber strand lies against itself and is preferably at least partially fused in this region. The fusion of adjacent regions also increases the stiffness of the nonwoven fabric.

[0033] In a further preferred embodiment, the first fiber section essentially comprises a first polymer and the second fiber section essentially comprises a second polymer, wherein the second polymer has a higher viscosity than the first polymer.

[0034] By selecting different polymers for the sections of the fiber strand, different material properties can be achieved in each section. An increase in stiffness due to the thickened portions can be enhanced by appropriate material selection. Furthermore, the formation of thickened portions in the second section can be triggered in the first place by appropriate material selection.

[0035] In a further preferred embodiment, the proportion of the second polymer (10) in the nonwoven fabric (1) is 2 wt.% to 20 wt.%, preferably 5 wt.% to 15 wt.%, and most preferably 10 wt.%. These proportions have proven particularly advantageous for the formation of thickened portions.

[0036] In a further preferred embodiment, the second fiber section adjoins the first fiber section and the one-piece fiber strand has a third fiber section which adjoins the second fiber section and whose structure is substantially identical to the first fiber section.

[0037] By changing the polymer again in the third fiber section, the macrostructure of this fiber section is essentially identical to that of the first fiber section and therefore does not exhibit any tangling.

[0038] In a further preferred embodiment, the first layer has a mass coverage of approximately 25 g / m 2 up to 45 g / m 2 , preferably about 30 g / m 2 up to 40 g / m 2 and most preferably of about 35 g / m 2 and / or a thickness of about 0.4 mm to about 0.7 mm, preferably about 0.5 mm to about 0.6 mm, and most preferably about 0.55 mm.

[0039] With these parameter values, it was determined that a particularly good dust storage capacity and a particularly good separation performance of the first layer is achieved.

[0040] In a further preferred embodiment, the first layer has on average about 2 to 10, preferably about 4 to 8 thickenings / cm 2 , particularly preferably about 5 to 7 thickenings / cm 2 and most preferably about 6 thickenings / cm 2 on.

[0041] With these concentrations of thickenings, it was found that a good stabilization of the first layer or a filter medium is achieved with only a slightly reduced separation efficiency.

[0042] In a further preferred embodiment, the first layer has an air permeability of approximately 5000 l / m 2 up to 7000 l / m 2 s, preferably about 5500 l / m 2 s up to 6500 l / m 2 and most preferably from about 6000 l / m 2s and / or a separation efficiency of about 10% to 20% and preferably of about 15%.

[0043] These parameter values are particularly suitable for the use of the filter medium as an air filter, especially in a vehicle.

[0044] According to the invention, the filter medium additionally comprises a second layer whose pore size is on average substantially smaller than that of the first layer.

[0045] This second layer further stabilizes the filter medium. Furthermore, coarse dust particles can be pre-filtered in this second layer.

[0046] In a further preferred embodiment, the second layer has a mass coverage of approximately 45 to 75 g / m 2 , preferably from about 50 to 70 g / m 2 , particularly preferably from about 55 to 65 g / m 2 and most preferably from about 60g / m 2and / or a thickness of about 0.5 mm to 0.9 mm, preferably about 0.6 mm to 0.8 mm, and most preferably about 0.7 mm.

[0047] With these parameter values, it was determined that a particularly good dust storage capacity and a particularly good separation performance of the second layer is achieved.

[0048] In a further preferred embodiment, the second layer has an air permeability of approximately 3000 l / m 2 s up to 4000 l / m 2 s, preferably about 3250 l / m 2 s to 3750 I / m 2 s and most preferably of about 3500 l / m 2 s and / or a separation efficiency of about 10% to 25%, preferably about 15% to 20% and most preferably about 17.5%.

[0049] These parameter values are particularly suitable for the use of the filter medium as an air filter, especially in a vehicle.

[0050] According to the invention, the filter medium additionally comprises a third layer whose pore size is on average substantially smaller than that of the second layer and which is preferably arranged on the side of the first layer facing away from the second layer.

[0051] This layer can be used particularly well as an electret filter layer in the filter medium, since this material has a high static charge capacity.

[0052] In a further preferred embodiment, the third layer has a mass coverage of approximately 35 to 60 g / m 2 , preferably from about 40 to 55 g / m 2 , particularly preferably from about 45 to 50 g / m 2 and most preferably about 47.5 g / m 2 and / or a thickness of about 0.4 mm to 0.7 mm, preferably about 0.5 mm to 0.6 mm, and most preferably about 0.55 mm.

[0053] With these parameter values, it was determined that a particularly good dust storage capacity and a particularly good separation performance of the third layer is achieved.

[0054] In a further preferred embodiment, the third layer has an air permeability of approximately 800 l / m 2 s up to 1300 l / m 2 s, preferably about 900 l / m 2 s up to 1200 l / m 2 s and most preferably about 1000 l / m 2 s and / or a separation efficiency of about 40% to 80%, preferably about 50% to 70% and most preferably about 60%.

[0055] These parameter values are particularly suitable for the use of the filter medium as an air filter, especially in a vehicle.

[0056] According to the invention, the three layers together have a mass coverage of 105 g / m 2 up to 180 g / m 2 and / or a thickness of 1.2 mm to 2.5 mm.

[0057] In a further preferred embodiment, the three layers together have a mass coverage of approximately 120 g / m 2 up to 160 g / m 2 and most preferably of about 140 g / m 2 and / or a thickness of about 1.3 mm to 2.3 mm, more preferably about 1.5 mm to 2.1 mm, more preferably about 1.7 mm to 1.9 mm, and most preferably about 1.8 mm.

[0058] With these parameter values, it was determined that a particularly good dust storage capacity and a particularly good separation performance of the second layer is achieved.

[0059] In a further preferred embodiment, the three layers together have an air permeability of approximately 500 l / m 2 s up to 1300 l / m 2 s, preferably about 600 l / m 2 s up to 1200 l / m 2 s, particularly preferably about 800 l / m 2 s up to 1000 l / m 2 s and most preferably about 900 l / m 2 s up.

[0060] These parameter values are also particularly suitable for the use of the filter medium as an air filter, especially in a vehicle.

[0061] The method according to the invention has the advantage that sections of a fiber strand, so-called fiber sections, with different structures can be produced in the primary forming process without requiring further post-treatment of the fiber strands or the fiber mat. Furthermore, different layers of a fiber mat with varying structures can be produced simultaneously in a single primary forming process. This is not possible if structural changes in one layer can only be created in a subsequent processing step, since each additional layer can then only be applied in a further primary forming process.

[0062] Furthermore, by varying the parameters, it is possible to form fiber strands with multiple structures in one piece. If the same effect were to be achieved by partially inserting fiber strands of a different structure, these would form droplets, so-called shots, at their beginnings and ends, which would lead to a reduction in the quality of the nonwoven fabric.

[0063] In a preferred embodiment, at least two polymers are mixed to produce the first polymer melt in such a way that the polymers are preferably inhomogeneously distributed in the first polymer melt.

[0064] By providing areas in the polymer melt in which different polymers dominate, fiber strands with fiber sections of different material structures are produced when the polymer melt is discharged from a spinning beam in the primary forming process.

[0065] In a further preferred embodiment, at least one of the polymers, in particular the first polymer, is in a molten state during mixing.

[0066] By mixing the second polymer into the molten first polymer, or vice versa, individual regions can be created in the molten first "main polymer" in which the second polymer is predominantly present. Thus, inhomogeneous mixing with regions of polymer can be achieved, but in which the regions are homogeneously arranged.

[0067] According to the invention, several of the above-described embodiments of the invention can also be combined with one another as desired - as far as technically reasonable.

[0068] The above and other advantages, features, and possible applications of the present invention will become apparent from the following descriptions of the preferred embodiments with reference to the drawings. These are shown as follows: Fig. 1 is a partially schematic representation of two fiber strands with a thickening of a fiber web according to the present invention; Fig. Figure 2a is an electron micrograph of a nonwoven fabric according to the present invention; Fig. Figure 2b is a partially schematic representation of the electron micrograph according to Fig. 2a; Fig. 3a is another electron micrograph of a nonwoven fabric according to the present invention; Fig. Figure 3b is a partially schematic representation of the electron micrograph according to Fig. 3a; Fig. 4a is another electron micrograph of a nonwoven fabric according to the present invention; Fig. Figure 4b is a partially schematic representation of the electron micrograph according to Fig. 4a; Fig. 5a is another electron micrograph of a nonwoven fabric according to the present invention; Fig. Figure 5b is a partially schematic representation of the electron micrograph according to Fig. 5a; Fig. 6 is a partially schematic illustration of a nonwoven fabric having multiple swells according to the present invention; Fig. 7 is a partially schematic diagram of the manufacturing process according to a first embodiment of the present invention; Fig. 8 is a partially schematic diagram of a manufacturing process according to a second embodiment of the present invention; Fig. 9 is a partially schematic representation of a polymer melt for the manufacturing process according to the second embodiment of the invention according to Fig. 5; Fig. 10 is a partially schematic representation of a three-layer nonwoven fabric according to the invention; Fig. 11 is a partially schematic illustration of a manufacturing process of a three-layer nonwoven fabric according to the present invention; Fig. 12 is a block diagram partially schematically illustrating a manufacturing process of a three-layer nonwoven fabric according to the present invention.

[0069] Fig. 1 shows two fiber strands 2 of a fiber fleece 1 according to the invention, each having a thickening 5. The fiber strands 2 can each be divided into three fiber sections 3, 4 and 6. A first fiber section 3 extends from one end of the fiber strand into the area of the thickening 5. A second fiber section 4 has the thickening 5 and preferably the areas just before and just after the thickening 5. The second fiber section 4 is followed by the third fiber section 6, which contains a similar or even identical material structure to the first fiber section 3. The third fiber section 6 can also be followed by a second fiber section 4 with a further thickening 5, wherein the length of the fiber strand 2 is theoretically not limited.

[0070] As in the Fig. 1, the thickening 5 can have intertwined loops of the fiber strand 2 or can also represent only a thickening of the fiber strand 2. Preferably, the thickening 5 is formed by a crimp of the fiber strand 2; more preferably, sections of a fiber strand lie against one another in the region of the thickening, wherein these regions are at least partially fused together. More preferably, the thickenings 5 have fiber bundles 7 made up of several fiber strands 2, which lie against one another. However, such a fiber bundle 7 can preferably also consist of only one fiber strand 2, wherein the fiber strand 2 forms essentially parallel loops. More preferably, the first fiber section 3 and the second fiber section 4 consist of different polymers. The second polymer preferably has a higher viscosity than the first polymer.Different polymers are also preferably two polymers with the same structural formula but different characteristic distributions of molecular chain length. This promotes the formation of a thickening in the second section, as described in detail with reference to the . Fig. 5 is described.

[0071] Fig. 2a and Fig. Figure 2b shows an electron microscope image of a thickening 5 arranged in a fiber fleece 1. It is clearly visible that the fiber strand 2 is connected in the area of the thickening 5 and partially forms fiber bundles 7 and partially intertwined in loops. Adjacent regions of the fiber strand 2 in the area of the thickening 5 are partially fused together.

[0072] Fig. 3a and Fig. 3b shows another electron microscope image of a thickening 5 arranged in a fiber fleece 1. The increased fiber thickness or fiber diameter of the fiber strand 2 marked with "2" is clearly visible compared to the lower and right edge of the image, where this fiber strand 2 continues.

[0073] Fig. 4a and Fig. 4b shows another electron microscope image of a thickening 5 arranged in a fiber fleece 1. It is clearly visible that the individual fibers of the fiber strand 2 are fused together with the thickening 5 in the area of the thickening.

[0074] Fig. 5a and Fig. 5b shows a further electron microscope image of a thickening 5 which is arranged in a fiber fleece 1 and which is formed in particular by fiber bundles 7.

[0075] Fig. Figure 6 schematically illustrates a nonwoven fabric 1 according to the present invention. The nonwoven fabric 1 consists of a plurality of fiber strands 2. Some of the fiber strands 2 have thickenings formed by fiber bundles 7, by an increased fiber thickness, by crimping, and / or by loops. Preferably, the thickenings comprise a combination of thickenings, fiber bundles, crimping, and / or loops.

[0076] As a rule, the fiber strands 2 do not end with thickenings 5, but rather the fiber strand 2 is continued on both sides of the second fiber section 4 with the thickening 5 in a first fiber section 3 and a third fiber section 6. This distinguishes the thickenings from so-called shots, which arise in a fiber fleece when the fiber strand 2 is torn off during the manufacturing process. Since the thickenings 5 are part of the fiber strands 2, a good separation performance of the fiber fleece 1 is maintained despite the accumulation of the polymer forming the fiber strand at the location of a thickening 5. This is due to the fact that the thickenings 5 can also absorb particles to be filtered on their surface.

[0077] With a nonwoven fabric 1 according to the invention, better separation performance is achieved than with a material reinforced by a second fiber or a bicomponent fiber, which have similar stiffness values to the nonwoven fabric 1 according to the invention.

[0078] Fig. Figure 7 schematically shows a manufacturing process for a nonwoven fabric 1 according to the invention using the meltblown or spunbond process. The spinneret 12 is shown at a nozzle for dispensing a polymer at different times, which occur consecutively from left to right.

[0079] First, a polymer is discharged under pressure from the spinning beam 12. This discharged polymer is then heated by a process air stream which flows around the spinning beam 12 from above and into the Fig. 7 is indicated by an arrow, is stretched and transported to the substrate 11, on which the resulting fiber strand 2 is deposited. In a next step, the intensity of the process air flow is reduced. At the nozzle of the spinning beam 12, the fiber strand 2 thickens because the polymer is transported away or stretched more slowly (lower process air flow indicated by the small arrow). This creates a first section 3 with an essentially homogeneous structure and a second section 4 on the fiber strand 2, which gradually forms a thickening 5. At a given point in time, the intensity of the air flow is increased again, whereby the removal of the polymer sprayed through the spinning beam 12 or its stretching increases again. This creates a third section 6 in the fiber strand 2, the material structure of which is similar to or even identical to the first section 3.

[0080] Finally, as shown on the far right in the Fig. 7, the thickening 5 is deposited on the substrate 11. During the entire process, the substrate 11 is preferably in motion, so that the fiber strand 2 is deposited one after the other on the substrate 11. Preferably, the fiber strand 2 does not tear off at the spinning beam 12 or the respective spray nozzle during the entire process for forming a thickening 5, so that a continuous fiber strand 2 is created.

[0081] Fig. Figure 8 illustrates the manufacturing process of a nonwoven fabric 1 according to the invention in accordance with a second embodiment. The chronological sequence of the processes at a nozzle of a spinning beam 12 is again shown from left to right. Essentially, the manufacturing process according to Fig. 8 of the manufacturing process according to Fig. 7 in that the process air flow remains constant, but the viscosity of the polymer is changed. Preferably, different polymers are introduced one after the other into the spinning beam 12, which polymers form regions of a first polymer 9 and regions of a second polymer 10 in the spinning beam. The first polymer 9 forms a first fiber section 3 or a third fiber section 6 of a fiber strand 2 when sprayed out of the spinning beam 12. The second polymer 10 forms a second fiber section 4 of a fiber strand 2 when sprayed out of the nozzle, in which thickenings 5 form in a first layer (12) of the fiber fleece 1 when deposited on the substrate.

[0082] The thickened portions 5 arise because the second polymer 10 has a higher viscosity than the first polymer 9, which is why it cannot be stretched as easily by the process air flow. Consequently, it remains longer in the area of a spinneret of the spin beam 12 and accumulates there to form a structure according to a third section 4, which ultimately forms a thickened portion 5.

[0083] Alternatively or in addition to different polymers 9, 10, the process temperature and / or the process air speed at the spinning beam 12 or at the spray nozzles of the spinning beam 12 can preferably also be changed, so that the viscosity of a single polymer is influenced in order to form first sections 3, second sections 4 and third sections 6 respectively.

[0084] Fig. 9 shows a container with a polymer melt which is used to produce a nonwoven fabric 2 according to the invention according to the embodiment of Fig. 5 is used. In this case, regions containing the second polymer 10 are introduced into the melt of a first polymer 9. This can be achieved by introducing individual granules of the second polymer 10 into the polymer granules of the first polymer 9, i.e. by mixing the polymers in the solid state. Furthermore, such mixing can preferably be achieved by introducing polymer granules of the second polymer 10 into a melt of the first polymer 9. Further preferably, different polymers 9, 10 can also be introduced into the respective nozzle 9 of a spinning beam 12 through different feeds.

[0085] The proportion of the higher viscosity polymer in the melt is typically 2 wt% to 20 wt%, preferably 5 wt% to 15 wt%, and most preferably 10 wt%.

[0086] Suitable polymers for producing a nonwoven fabric 1 according to the invention are preferably synthetic polymers, in particular polyesters, selected from the group consisting of polyethylene (PE), polyethylene terephthalate (PET), polycarbonate (PC), polyamide (PA), polypropylene (PP), polyvinyl chloride (PVC), polybutylene terephthalate (PBT), and mixtures thereof for the first polymer 9. Suitable polymers for the second polymer 10 are preferably synthetic polymers selected from the group consisting of polyethylene (PE), polyethylene terephthalate (PET), polycarbonate (PC), polyamide (PA), polypropylene terephthalate (PBT), polypropylene (PP), polyester, polyvinyl chloride (PVC), polybutylene terephthalate (PBT), and mixtures thereof. The first polymer 9 and the second polymer 10 can be used in any desired combination. Furthermore, mixtures of various of these or other polymers can preferably be used for both the first polymer 9 and the second polymer 10.

[0087] The following combinations of first polymer 9 and second polymer 10 are preferably suitable: PET and PC, PET and PA, PET and PP, PET and PE, PET and PVC, PET and PBT, PC and PA, PC and PP, PC and PE, PC and PVC, PC and PBT, PA and PP, PA and PE, PA and PVC, PA and PBT, PP and PE, PP and PVC, PP and PBT, PE and PVC, PE and PBT or PVC and PBT.

[0088] Furthermore, the following combinations are preferably suitable: PBT and PVC, PBT and PE, PBT and PP, PBT and PA, PBT and PC, PBT and PET, PVC and PE, PVC and PP, PVC and PA, PVC and PC, PVC and PET, PE and PP, PE and PA, PE and PC, PE and PET, PP and PA, PP and PC, PP and PET, PA and PC, PA and PET or PC and PET.

[0089] Two polymers with the same structural formula but different characteristic distribution of the molecular chain length are also particularly suitable as first polymer 9 and second polymer 10.

[0090] Finally, as explained with reference to the previous figures, the nonwoven fabric 1 can also be produced with only a single polymer and / or only a single characteristic molecular chain length from this group.

[0091] It is also possible to use the Fig. 7 and Fig. 8. Furthermore, the various sections 3, 4, and 6 of a fiber strand 2 can preferably be formed by changing the polymer throughput through the nozzles of the spinning beam 12, for example, by changing the spray pressure in the spinning beam 12. This technique can also be combined with the previous techniques.

[0092] A first layer 12 of a nonwoven fabric 5 produced in this way preferably has a mass coverage of about 25 g / m 2 up to 45 g / m 2 , preferably about 30 g / m 2 up to 40 g / m 2and most preferably of about 35 g / m 2 and more preferably a thickness of about 0.4 mm to about 0.7 mm, preferably about 0.5 mm to about 0.6 mm, and most preferably about 0.55 mm. Furthermore, this first layer 12 preferably has an average of about 2 to 10 thickenings / cm 2 , preferably about 4 to 8 thickenings / cm 2 , particularly preferably about 5 to 7 thickenings / cm 2 and most preferably about 6 thickenings / cm 2 The air permeability of this first layer 12 is preferably about 5000 l / m 2 s up to 7000 l / m 2 s, preferably about 5500 l / m 2 s up to 6500 l / m 2 s and most preferably about 6000 l / m 2The separation efficiency is preferably approximately 10% to 20%, and more preferably approximately 15%. The effect according to the invention can also be achieved at the edges of the respective specified ranges. Furthermore, all parameter values mentioned are average values, which may deviate significantly at individual points on the first layer 12.

[0093] The first layer 12 preferably has an average pore size according to the bubble point test of more than 80 µm to 100 µm. The first fiber section 3 and / or the third fiber section 6 further preferably have an average thickness of 10 µm to 40 µm, preferably of 20 µm to 30 µm, and most preferably of 25 µm. The second fiber section 4, in the region of a thickening 5, further preferably has an average thickness of 100 µm to 1000 µm, preferably of 200 µm to 900 µm, preferably of 300 µm to 800 µm, even more preferably of 400 µm to 700 µm, and most preferably of 500 µm.

[0094] It was surprisingly found that a nonwoven fabric 1 with thickened portions 5 arranged in a nonwoven fabric 1 increases the stiffness of the nonwoven fabric 1. This is due in particular to the fact that the thickened portions 5 cool more slowly in the second fiber sections during the production of the nonwoven fabric 1 than the fiber strand 2 in the first fiber section 3 and the third fiber section 6. In particular, the accumulation of polymer in the second fiber sections 4 of the fiber strand 1 leads to the slower cooling.

[0095] On the one hand, the cooled thickening 5 forms a reinforcement in the nonwoven fabric 1. On the other hand, other parts of the fiber strand 2 or other fiber strands 2 are at least partially fused with the thickening 5, so that the thickening 5 leads to a stiffening of the material in its entire surroundings. At the same time, the thickening 5 remains part of the fiber strand 2 with a similar surface structure and can therefore absorb particles to be filtered.

[0096] Fig. Figure 10 shows a nonwoven fabric 1 according to a further embodiment of the invention. In this embodiment, the nonwoven fabric 1 has three layers 12, 13, 14. These three layers 12, 13, 14 are preferably formed in a common primary forming process according to Fig. 11. Preferably, three spinning beams 15a, 15b, 15c are arranged one behind the other above a substrate 11, which simultaneously deposit fiber strands 2 on the substrate 11, preferably by means of a meltblown or spun-bond process, which is Fig.11 is moved to the right. A second layer 13 is produced by the left spinning beam 15a, a first layer 12 as described above by the middle spinning beam 15b, and a third layer 14 by the right spinning beam 15c. The order in which the three layers 12, 13, 14 are laid down is not limited to the embodiment described, but can be done in any desired order. Preferably, the nonwoven fabric according to the invention can also have just two layers, the first layer 12 and the second layer 13, or the first layer 13 and the third layer 14, wherein each of the two layers can be laid down first during the manufacturing process. Further preferably, production can also be done with a single spinning beam, the nozzles of which can each extrude different polymers.

[0097] The second layer 13 and the third layer 14 can be produced using the same process as the first layer 12, but preferably, other processes are used to produce layers with different properties. Preferably, the second layer 13 is a relatively coarse nonwoven fabric 1 for further stabilization of the nonwoven fabric 1 and / or to prefilter coarse particles. The third layer 14 is preferably an electret filter, which increases the dust storage capacity and separation efficiency through electrostatic bonding of particles.

[0098] The second layer 13 preferably has a mass coverage of about 45 to 75 g / m 2 , preferably from about 50 to 70 g / m 2 , particularly preferably from about 55 to 65 g / m 2 and most preferably from about 60g / m 2and more preferably a thickness of about 0.5 mm to 0.9 mm, preferably about 0.6 mm to 0.8 mm, and most preferably about 0.7 mm. Furthermore, the second layer 13 has an air permeability of about 3000 l / m 2 s up to 4000 l / m 2 s, preferably about 3250 l / m 2 s up to 3750 l / m 2 s and most preferably of about 3500 l / m 2 s and more preferably a separation efficiency of about 10% to 25%, preferably about 15% to 20%, and most preferably about 17.5%. The second layer 13 more preferably has an average pore size according to the bubble point test of more than 65 µm to 120 µm, preferably from 70 µm to 90 µm, and most preferably 80 µm.

[0099] The third layer 14 preferably has a mass coverage of about 35 to 60 g / m 2 , preferably from about 40 to 55 g / m 2 , particularly preferably from about 45 to 50 g / m 2 and most preferably of about 47.5 g / m2 and preferably a thickness of about 0.4 mm to 0.7 mm, preferably about 0.5 mm to 0.6 mm, and most preferably about 0.55 mm. Furthermore, the third layer 14 preferably has an air permeability of about 800 l / m 2 s up to 1300 l / m 2 s, preferably about 900 l / m 2 s up to 1200 l / m 2 s and most preferably from about 1000 I / m 2 s and / or a separation efficiency of approximately 40% to 80%, preferably approximately 50% to 70%, and most preferably approximately 60%. The third layer 14 further preferably has an average pore size according to the bubble point test of more than 10 µm to 60 µm, preferably 20 µm to 50 µm, more preferably 30 to 40 µm, and most preferably 35 µm.

[0100] Together, the three layers 12, 13, 14 preferably have a mass coverage of approximately 105 g / m 2 up to 180 g / m 2 , preferably about 120 g / m 2 up to 160 g / m 2and most preferably of about 140 g / m 2 and further preferably a thickness of about 1.2 mm to 2.5 mm, preferably about 1.3 mm to 2.3 mm, particularly preferably about 1.5 mm to 2.1 mm, more preferably about 1.7 mm to 1.9 mm, and most preferably about 1.8 mm. The combined air permeability is about 500 l / m 2 s up to 1300 l / m 2 s, preferably about 600 l / m 2 s up to 1200 l / m 2 s, particularly preferably about 800 l / m 2 s up to 1000 l / m 2 s and most preferably about 900 l / m 2 see

[0101] The average pore diameter of the three layers is preferably 15 µm to 25 µm.

[0102] The effect according to the invention can also be achieved at the edges of the respective ranges. Furthermore, all parameter values mentioned are average values, which may vary significantly at individual points within the respective layers.

Claims

[1] Nonwoven fabric (1), in particular for a filter medium, with a first layer (12), wherein at least one integral fiber strand (2) of the first layer (12) has a first fiber section (3) and a second fiber section (4) in the longitudinal direction, characterized by , that the fiber strand (2) has a thickening (5) in the second fiber section (4), which additionally has a second layer (13) whose pore size is on average smaller than that of the first layer, which additionally has a third layer (14) whose pore size is on average smaller than that of the second layer and which is preferably arranged on the side of the first layer facing away from the second layer, the three layers (12, 13, 14) together have a mass coverage of 105 g / m 2 up to 180 g / m 2 and / or have a thickness of 1.2 mm to 2.5 mm. [2] Nonwoven fabric (1) according to claim 1, wherein the thickening (5) has a crimp and / or a fiber bundle (7). [3] Nonwoven fabric (1) according to claim 1 or 2, wherein the thickening (5) comprises intertwined loops of the fiber strand. [4] Nonwoven fabric (1) according to one of the preceding claims, wherein the thickening (5) has a region (8) in which the fiber strand (2) lies against itself and is preferably at least partially fused in this region (8). [5] Nonwoven fabric (1) according to one of the preceding claims, wherein the first fiber section (3) consists of a first polymer (9) and / or the second fiber section (4) consists of a second polymer (10), wherein the second polymer (10) preferably has a different, in particular higher, viscosity than the first polymer (9). [6] Nonwoven fabric (1) according to one of the preceding claims, wherein the proportion of the second polymer (10) in the nonwoven fabric (1) is 2 wt.% to 20 wt.%, preferably 5 wt.% to 15 wt.% and most preferably 10 wt.%. [7] Nonwoven fabric (1) according to one of the preceding claims, wherein the second fiber section (4) adjoins the first fiber section (3) and the one-piece fiber strand (2) has a third fiber section (6) which adjoins the second fiber section (4) and whose structure is identical to the first fiber section (3). [8] Nonwoven fabric (1) according to one of the preceding claims, wherein the first layer (12) has a mass coverage of 25 g / m 2 up to 45 g / m 2 , preferably 30 g / m 2 up to 40 g / m 2 and most preferably 35 g / m 2 and / or a thickness of 0.4 mm to 0.7 mm, preferably 0.5 mm to 0.6 mm and most preferably 0.55 mm. [9] Nonwoven fabric (1) according to one of the preceding claims, wherein the first layer (12) has on average 2 to 10 thickenings / cm 2 , preferably 4 to 8 thickenings / cm 2 , particularly preferably 5 to 7 thickenings / cm 2 and most preferably 6 thickenings / cm 2 has. [10] Nonwoven fabric (1) according to one of the preceding claims, wherein the first layer (12) has an air permeability of 5000 l / m 2 s up to 7000 l / m 2 s, preferably 5500 l / m 2 s to 6500 I / m 2 s and most preferably 6000 l / m 2 s and / or a separation efficiency of 10% to 20% and preferably 15%. [11] Nonwoven fabric (1) according to one of the preceding claims, wherein the second layer (13) has a mass coverage of 45 to 75 g / m 2 , preferably from 50 to 70 g / m 2 , particularly preferably from 55 to 65 g / m 2 and most preferably 60g / m 2and / or a thickness of 0.5 mm to 0.9 mm, preferably 0.6 mm to 0.8 mm and most preferably 0.7 mm. [12] Nonwoven fabric (1) according to one of the preceding claims, wherein the second layer (13) has an air permeability of 3000 l / m 2 s up to 4000 l / m 2 s prefers 3250 I / m 2 s up to 3750 l / m 2 s and most preferably 3500 I / m 2 s and / or a separation efficiency of 10% to 25%, preferably 15% to 20% and most preferably 17.5%. [13] Nonwoven fabric (1) according to one of the preceding claims, wherein the third layer (14) has a mass coverage of 35 to 60 g / m 2 , preferably from 40 to 55 g / m 2 , particularly preferably from 45 to 50 g / m 2 and most preferably 47.5 g / m 2 and / or a thickness of 0.4 mm to 0.7 mm, preferably 0.5 mm to 0.6 mm and most preferably 0.55 mm. [14] Nonwoven fabric (1) according to one of the preceding claims, wherein the third layer (14) has an air permeability of 800 l / m 2 s up to 1300 l / m 2 s, preferably 900 l / m 2 s to 1200 I / m 2 s and most preferably 1000 I / m 2 s and / or a separation efficiency of 40% to 80%, preferably 50% to 70% and most preferably 60%. [15] Nonwoven fabric (1) according to one of the preceding claims, wherein the three layers (12, 13, 14) together have a mass coverage of 120 g / m 2 up to 160 g / m 2 , preferably 140 g / m 2 and / or have a thickness of 1.3 mm to 2.3 mm, preferably 1.5 mm to 2.1 mm, more preferably 1.7 mm to 1.9 mm and most preferably 1.8 mm. [16] Nonwoven fabric (1) according to one of the preceding claims, wherein the three layers (12, 13, 14) together have an air permeability of 500 l / m 2 s up to 1300 l / m 2 s, preferably 600 l / m 2s up to 1200 l / m 2 s, particularly preferably 800 l / m 2 s to 1000 I / m 2 s and most preferably 900 l / m 2 s have. [17] Filter with a nonwoven fabric (1) according to one of claims 1 to 16 as filter medium, wherein the nonwoven fabric (1) is preferably pleated. [18] Method for producing a nonwoven fabric (1), comprising the following steps: Providing (17) a first polymer melt (9, 10); Producing (18) a first layer (11) from the first polymer melt (9, 10), in particular by meltblown or spunbond processes; Changing (19), in particular intermittently or oscillatingly, at least one process parameter in the meltblown or spunbond process, in particular the process temperature, the composition of the polymer melt (9, 10), the polymer throughput and / or the process air speed, to produce two fiber sections (3, 4) with different structures of a one-piece fiber strand (2); and Depositing (20) the fiber strand (2) on a substrate (11), characterized by , that the fiber strand (2) has a thickening (5) in the second fiber section (4), further comprising the following work steps: Providing (21) a second polymer melt and a third polymer melt; Producing (22) a second layer (13) from the second polymer melt and a third layer (14) from the third polymer melt, wherein the first layer (12) and the second layer (13) and / or the third layer (14) are produced simultaneously in a single primary forming process, in particular in the meltblown or spunbond process, wherein the second layer (13) has a pore size which is on average smaller than that of the first layer, wherein the third layer (14) has a pore size which is on average smaller than that of the second layer and which is preferably arranged on the side of the first layer facing away from the second layer, the three layers (12, 13, 14) together have a mass coverage of 105 g / m 2 up to 180 g / m 2 and / or have a thickness of 1.2 mm to 2.5 mm. [19] Method according to claim 18, which comprises the following further step: Mixing (16) at least two polymers (9, 10) to produce the first polymer melt (9, 10) in such a way that the polymers (9, 10) are preferably inhomogeneously distributed in the first polymer melt (9, 10).

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