Generator for providing cleaning agents

Abstract

A generator (110) for cleaning agents comprises a first container (150) for receiving a first liquid; a second container (150) for receiving a second liquid; a reaction vessel (120) with electrodes (130) for the electrolytic production of cleaning agents based on the first and the second liquid; and a control device (170) for guiding the first and second liquid into the reaction vessel (120).

Description

[0001] The present invention relates to the provision of cleaning agents at the point of need. In particular, the invention relates to a generator and a method for providing cleaning agents, as well as a cleaning device.

[0002] In a household, water and a cleaning agent are used to clean a floor. The cleaning agent is designed to loosen the soil on the floor, bond with it, and be removed from the surface together with the water. The floor can be cleaned manually or using an automatic floor cleaner.

[0003] To remove contaminants, cleaning agents contain so-called active ingredients. These can include surfactants, acids, or bases, for example. When used and dosed correctly, cleaning agents can lead to good and hygienic cleaning results. A user can overdose, resulting in more cleaning agent being used than necessary. Unused cleaning agent can enter the wastewater and must be removed through a complex treatment process.

[0004] It has been suggested that cleaning agents should only be provided directly at the location where they are to be used. For example, an ozone generator or a cold plasma source can produce an ionizing gas from air that contains, in addition to ozone, various nitrate and nitrite compounds. This gas can be introduced into water, forming small amounts of hydrogen peroxide and nitric acid, among other substances. The resulting cleaning solution can effectively combat dirt and inactivate microorganisms.

[0005] The documents WO 2022 / 083 317 A1, CN 1 17 414 087 A and EP 4 082 974 A1 each describe generators for cleaning agents with electrodes for the electrolytic production of cleaning agents.

[0006] Existing technologies may require the handling of aggressive chemicals. It can be difficult for a user to dose the chemicals correctly. Some chemicals are in a form that makes automated processing, particularly controlling the cleaning agent production process, difficult.

[0007] The present invention is based on the object of providing an improved technology for providing cleaning agents on demand. The invention achieves this object by means of the subject matter of the independent claims. Subclaims specify preferred embodiments.

[0008] A generator for cleaning agents comprises a first container for holding a first liquid; a second container for holding a second liquid; a reaction vessel with electrodes for the electrolytic generation of cleaning agents based on the first and second liquids; a control device for guiding the first and second liquids into the reaction vessel; and a dispensing device connected to the reaction vessel for providing a predetermined volume flow of liquid with cleaning agent from the reaction vessel, wherein the dispensing device comprises a positive displacement pump, a flow pump and / or a jet pump.

[0009] The electrolytic supply of cleaning agent based on two liquids can allow for significantly simplified or improved control. A predetermined amount or volume flow of cleaning agent can be provided more effectively. The mixing ratio of reactants from the first and second containers can be controlled more easily or more precisely. Problems with the conveyance or dosing of solids or gases can be avoided. Overall, the supply of cleaning agent can be controlled more effectively.

[0010] The generator can comprise a first addition device for metering first liquid from the first container into the reaction vessel. The first addition device can be configured, when activated, to deliver a predetermined volume or a predetermined volume flow of the first liquid into the reaction vessel. In a simple embodiment, the first addition device comprises a valve, and a flow of liquid through the valve can be caused by gravity, or the first container can be pressurized to a predetermined level to drive the first liquid toward the reaction vessel. The valve can be provided in any desired design. For reasons of simplicity, it is preferred that the valve be designed as a switching valve, although a proportional valve is also possible. In another embodiment, the first addition device can also be implemented by another actuator, for example a pump.

[0011] The generator may further comprise a second addition device for metering a second liquid from the second container into the reaction vessel. The options outlined for the first addition device essentially apply to the second addition device.

[0012] A feed device can also comprise a pump, preferably a positive displacement pump, a flow pump, and / or a jet pump. The positive displacement pump can also be called a metering pump and comprise a chamber that can be filled with liquid from the first container before the chamber is emptied into the reaction vessel. Exemplary embodiments include a piston pump, a gear pump, a diaphragm pump, or a peristaltic pump. The use of a positive displacement pump can facilitate metering of the liquid into the reaction vessel.

[0013] Particularly preferably, a feed device comprises a peristaltic pump. The peristaltic pump can comprise a hose leading from one of the containers to the reaction vessel. The peristaltic pump can deform the hose such that the liquid to be pumped is forced through it by external mechanical deformation of the hose. A peristaltic pump can be of simple construction, is insensitive to the medium to be pumped, and allows the implementation of a completely closed hydraulic system. The peristaltic pump can be suitable for metering pumped liquid, be dry-run safe, or self-locking. Pumping a mixture of liquid and gas or solid can be unproblematic. The hose can be designed as a wearing part and be easy to replace.

[0014] According to the invention, a dispensing device connected to the reaction vessel is provided for providing a predetermined volume flow of liquid containing cleaning agent from the reaction vessel. The dispensing device also comprises a positive displacement pump, a flow pump, and / or a jet pump, preferably a diaphragm pump or a peristaltic pump.

[0015] The second container can be configured to hold a liquid and a solid salt. The salt and liquid can be poured into the second container by a user. The salt can be dissolved in the liquid in the second container. The container can be designed such that any undissolved salt is not transferred into the reaction vessel along with the liquid. For example, an outlet for the liquid can be located lower than a receptacle for the salt in the second container.

[0016] According to a further aspect of the invention, a cleaning device comprises a generator as described herein. The cleaning device is configured for treating a surface in a household. For example, the cleaning device may comprise a handheld device or a floor cleaning robot. In particular, the generator may be arranged in a floor nozzle of the cleaning device, particularly in handheld devices, or on a lower housing part of the floor cleaning robot, thereby advantageously enabling very short travel distances.

[0017] In a preferred embodiment, the cleaning device is configured to clean a floor surface with the cleaning agent. The cleaning device can, in particular, comprise a multifunctional, hand-held floor device with a handle (multi-use handstick, MUH).

[0018] A further aspect of the invention comprises a method for providing a cleaning agent, the method comprising the steps of supplying a first liquid from a first container to a reaction vessel; supplying a second liquid from a second container to the reaction vessel; applying a predetermined direct electrical voltage to electrodes in the reaction vessel such that an electrical current flows through the solution to form a cleaning agent by means of a redox reaction; and supplying liquid in which the cleaning agent is present from the reaction vessel. A ratio of supplied first liquid to supplied second liquid is determined as a function of an electrical current flowing through the electrodes.

[0019] The method can be carried out using a generator described herein, and in particular a cleaning device described herein. A control device of the generator can comprise an electronic processing device, and the method can be in the form of a computer program product with program code means. The computer program product can also be stored on a computer-readable data carrier. Features or advantages of the method can be transferred to the device, or vice versa.

[0020] The invention will now be described in more detail with reference to the accompanying figures, in which: Fig. 1 a cleaning appliance for use in a household; Fig. 2 an illustration of electrolysis; Fig. 3 a generator for cleaning agents; Fig. 4 a schematic representation of a peristaltic pump; and Fig. 5 shows a flow diagram of a method;

[0021] Fig. 1 shows a cleaning device 100 for use in a household. The cleaning device 100 is configured to treat a substrate 105, in particular a floor surface, for example, parquet, laminate, screed, or linoleum. In addition to a wiping function described in more detail below, the cleaning device 100 can also be used for dry cleaning, for example, by vacuuming or sweeping. In the present case, the cleaning device 100 is embodied, by way of example, as a handheld floor cleaning nozzle with a handle. The cleaning device 100 can also be referred to as a multifunctional handheld floor device (multi-use handstick, MUH).

[0022] Instead of a hand-held guide, the cleaning device 100 can also comprise a drive device and be configured for autonomous cleaning of a floor surface. In yet another embodiment, the cleaning device 100 can comprise a handheld device without a handle, which can also be used, for example, to clean the surface of a table, a stove, a window or mirror, or a tile.

[0023] The cleaning device 100 comprises a generator 110 for providing a cleaning agent as directly as possible at the location where cleaning is to be performed. A textile 115 for mechanically processing the substrate 105 is provided in a front area of ​​the cleaning device 100, for example. The provided cleaning agent can be dispensed in this area. A support or drive wheel 118 is provided in a rear area of ​​the cleaning device 100, for example. Above the wheel 118, a receptacle for a handle can be seen, with which the cleaning device 100 can be guided over the substrate 105.

[0024] The generator 110 comprises a reaction vessel 120 for holding an aqueous solution 125. Two electrodes 130 are arranged spaced apart in the reaction vessel 120. An electric current can be induced through the aqueous solution 125 by means of a direct current source 135. The provided direct current can be a low voltage, so that there is no danger to a person. The direct current is preferably below approximately 12 V, more preferably in the range of approximately 5 V or even lower. The direct current source 135 can comprise a power supply that can be connected to a power grid by means of a connecting cable. Alternatively, a local energy storage device can be used, for example in the form of a battery or an accumulator. The direct current source 135 is preferably configured to provide a direct current at a constant level.

[0025] A current sensor 140 can be provided in a supply line between one of the electrodes 130 and the DC voltage source 135. The current sensor 140 is configured to provide a sensor signal indicative of the strength of an electric current flowing through the aqueous solution 125. The current sensor 140 can be implemented in any desired manner, for example, as a shunt resistor or as a thermal measuring device. In another embodiment, a magnetic field can be determined that develops in the region of the supply line due to the flowing current. The current sensor 140 can, for example, comprise a Hall sensor.

[0026] The solution 125 can be provided by means of a dispensing device 145 in the region of the textile 115. The dispensing device 145 can, for example, comprise a throttle or an orifice to direct a predetermined volume flow of liquid to the textile 115. Preferably, the dispensing device 145 is controllable and, in particular, is designed as a pump. In some embodiments, a volume flow of liquid flowing through the pump can be controlled continuously or in multiple stages.

[0027] To provide the aqueous solution 125 in the reaction vessel 120, a first container 150 with a first addition device 155 and a second container 160 with a second addition device 165 are provided. The first container 150 contains water, and the second container 160 contains a predetermined salt, in particular table salt (NaCl). The table salt is preferably dissolved in water, i.e., in the form of a saline solution. The containers 150, 160 can be configured for refilling by a user of the cleaning device 100. The user can fill the first container 150 with clear water.

[0028] The second container 160 can be filled with either a saline solution or water plus solid table salt. A saline solution can have a predetermined salinity, which can be specified, for example, as a volume or weight percentage of table salt in water. For example, an isotonic saline solution contains 0.9% table salt in water, which can correspond to 9 g of table salt per 1000 ml of water. The supply of cleaning agent can be more easily controlled if the salinity of the saline solution in the second container 160 is known.

[0029] The salinity of the saline solution in the second container 160 can be controlled by the user by filling the saline solution and water in a predetermined weight or volume ratio. A dosing aid, such as a measuring cup for salt or a volume marking on the second container 160, can be provided for this purpose, allowing a predetermined amount of water to be added. A known salinity also exists in a saturated solution of saline in water. To create a saturated solution of saline, the user can fill the second container 160 with water and add more saline than can be dissolved in the water.

[0030] The addition devices 155, 165 are each configured to deliver a predetermined amount or a predetermined volume flow of water or saline solution into the reaction vessel 120. The addition devices 155, 165 are preferably designed as pumps, but can also be valves if the dispensing device 145 is designed as a pump.

[0031] A control device 170 is connected to the feed devices 155, 165, to the output device 145, and to the current sensor 140. Furthermore, a connection to the DC voltage source 135 may be provided. Not shown in Fig. 1 shows an optional control element with which a user can express a request regarding a quantity of cleaning fluid to be provided or a concentration of cleaning agent in the fluid.

[0032] The control device 170 can be configured to control a supply of water and saline solution into the reaction vessel 120 and preferably an outflow of aqueous solution 125 from the reaction vessel 120. In the reaction vessel 120, a direct current is passed through the aqueous solution 125, so that a redox reaction is forced by electrolysis, in which a predetermined cleaning agent can be formed.

[0033] Fig. Figure 2 shows an illustration of electrolysis. The reaction vessel 120 contains the aqueous solution 125, which initially only contains table salt dissolved in water. When the table salt dissolves in water, negatively charged anions 205 and positively charged cations 210 are formed. If a direct current is then applied to the electrodes 130, the anions 205 are moved to one electrode 130 and the cations 210 to the other. This creates a potential difference between the electrodes 130, which is balanced by electrons 215 flowing from one electrode 130 through the direct current source 135 to the other electrode 130.

[0034] Ions 205, 210 that accumulate in the area of ​​one of the electrodes 130 are energized by the flowing electric current, enabling one or more redox reactions. In the process, the ions 205, 210 are converted into other reaction products, one of which comprises the desired cleaning agent.

[0035] The water (H2O) from the first container 150 and the table salt (NaCl) from the second container 160 can be converted in the reaction vessel 120, for example, by means of the following reactions in the reaction vessel 120: 2NaCl + 2H2O → 2NaOH + H2 + Cl2 2NaOH + Cl2 → NaOCl + NaCl + H2O

[0036] The NaOCl formed by the second reaction equation is also known as sodium hypochlorite or sodium hypochlorite. It is the sodium salt of hypochlorous acid (HClO). NaOCl has good cleaning and dirt-binding properties and can inactivate microorganisms.

[0037] Fig. 3 shows a generator 110 for cleaning agents, preferably for use in a cleaning device 100. In the illustrated embodiment, the generator 110 comprises the reaction vessel 120 with the electrodes 130, the first container 150, the first addition device 155, the second container 160 and the second addition device 165. A dispensing device 145 is provided to convey liquid from the reaction vessel 120 to a dispensing opening 305.

[0038] The first container 150 is intended for holding water. Preferably, clear water is used, which can be drawn, for example, from a water pipe. Purified water, boiled water, or distilled water can also be added. A filling opening of the first container 150 is preferably designed such that filling a liquid is easy, but filling a solid is difficult. For this purpose, the filling opening can comprise, for example, a sieve, a grid, or a labyrinth seal.

[0039] The second container 160 is configured to hold a liquid solution of table salt in water. In one embodiment, the finished solution can be poured into the second container 160, wherein a filling opening of the second container 160 can be designed analogously to that of the first container. In another embodiment, the second container 160 is configured to hold water and solid table salt 310, for example in the form of a tablet, a lump, or spreadable salt. The filling opening can be designed accordingly large to facilitate clean filling of the salt. The table salt 310 can then dissolve in the added water.

[0040] In a further embodiment, the second container 160 can be configured to be filled only with salt by a user. Water can be supplied from the first container 150, for example, by means of a valve or a pump. Optionally, the second addition device 165 can be arranged between the first container 150 and the second container 160. In a further embodiment, water can flow from the first container 150 into the second container 160 due to gravity. A check valve is preferably provided between the first container 150 and the second container 160 so that as little salt 310 as possible enters the first container 150. Alternatively, a controllable valve can also be used.

[0041] The addition devices 155 and 165 are each preferably designed as positive displacement pumps and more preferably as peristaltic pumps. The control device 170 can control the addition devices to move a predetermined amount or a predetermined volume flow of liquid from the respective container 150, 160 into the reaction vessel 120. The dispensing device 145 can also comprise a positive displacement pump and more preferably a peristaltic pump.

[0042] The reaction vessel 120 preferably has no openings other than the connections to the containers 150, 160 and the dispensing device 145. A volume flow of supplied liquid therefore corresponds to a volume flow of discharged liquid. In one embodiment, one of the addition devices 155, 165 or the dispensing device 145 can be omitted, and the respective volume flow can be controlled automatically based on this relationship.

[0043] The supplied and discharged volume flows can correspond particularly well to one another when the reaction vessel 120 is completely filled with liquid. For flooding and displacing gas from the reaction vessel 120, it is preferred that a backflow of liquid into one of the containers 150, 160 is prevented by means of a check valve if no addition device 155, 165 is provided at this point to prevent backflow. If necessary, a check valve can prevent backflow into a container 150, 160. In a particularly preferred embodiment, both addition devices 155, 165 are present and the discharge opening 305 can be omitted. A check valve can also be provided between the reaction vessel 120 and the discharge opening 305.

[0044] Fig. 4 shows a schematic representation of an exemplary peristaltic pump 400, which can form one of the addition devices 155, 165 or the output device 145. The pump 400 comprises a hose 405 that is laid in a loop around an axis 410. On a radial outer side of the hose 405, a boundary 415 is provided, which extends circumferentially around the axis 410. In a direction along the axis 410, the boundary 415 can, for example, run straight. On a radial inner side of the hose 405, two rollers 420 are attached, which are held circumferentially around the axis 410. The rollers 420 are opposite one another; with a larger number of rollers 420, these are preferably evenly distributed over the circumference. Instead of rollers 420, sliding shoes can also be used.The hose 405 is compressed between a roller 420 and the limiter 415, so that a constriction is formed through which liquid in the hose 405 cannot pass.

[0045] The roller 420 can be moved circumferentially around the axis 410 by means of an electric motor 425, so that the constriction is displaced and liquid is moved along the tube 405. In the illustration of Fig. 4, fluid can be pumped from a suction side 430 (shown on the left) to a pressure side 435 (shown on the right) by rotating the roller 420 clockwise. If the direction of rotation is reversed, the pumping direction also changes.

[0046] The peristaltic pump 400 is self-locking and resistant to aggressive media. The hose 405 can run directly between the reaction vessel 120 and a container 150, 160, or the discharge opening 305. The hose 405 can be made of a durable and flexible material such as silicone.

[0047] Fig.5 shows a flowchart of a method 500 for controlling a generator 110, particularly within a cleaning device 100. In a step 505, electrolysis takes place, in which an aqueous solution of common salt is forced into a redox reaction to provide cleaning agent in the form of sodium hypochlorite. The strength of an actual electrical current flowing through the aqueous solution 125 during the electrolysis can be determined in a step 510. The magnitude of the actual current is preferably determined by means of the current sensor 140, which can be arranged between an electrode 130 and the DC voltage source 135.

[0048] In a step 515, a desired concentration of cleaning agent in the liquid can be determined. For this purpose, a user request can be recorded, which can be expressed, for example, using an input device. Different concentrations can be predetermined, from which the user can select one. A maximum selectable concentration can be determined depending on the prevailing conditions in the area of ​​the reaction vessel 120.

[0049] In step 520, a target current intensity can be determined that is associated with the desired concentration. This association can be determined, for example, in a table, using a formula, using a characteristic map, or in another way.

[0050] In a step 525, the actual current determined in step 510 and the target current determined in step 520 can be compared. If the current intensities correspond sufficiently closely to one another, the concentration of cleaning agent in the aqueous solution 125 is at the desired level. If the actual current exceeds the target current by a predetermined amount, the concentration of cleaning agent in the aqueous solution 125 is too high. In this case, in a step 530, water can be added from the first container 150 to the reaction vessel 120. The added water can influence the electrolytic reaction in step 505, causing the actual current to drop again.

[0051] Correspondingly, in step 525, it can be determined that the target current strength is greater than the actual current strength by a predetermined amount. In this case, in a step 535, salt can be supplied from the second container 160 into the reaction vessel 120. This can increase the concentration of salt in the solution 125, so that the electrolytic reaction taking place in step 505 can be influenced. Due to the increased salinity of the aqueous solution 125, more free ions can be available to participate in the redox reaction. As a result, the actual current strength can increase. The salt can be supplied as a liquid, in particular as salt dissolved in water, or as a solid.

[0052] The method 500 can be carried out to provide a predetermined amount of aqueous solution 125 with a predetermined concentration of cleaning agent. The DC voltage source 135 can then be turned off, and the provided solution 125 can be used to clean the substrate 105 by removal in a step 540. If a provided supply of solution 125 is exhausted, the reaction vessel 120 can be refilled with water and salt, and the DC voltage source 135 can be turned on again to provide another predetermined amount of dissolved cleaning agent.

[0053] In another embodiment, the method 500 can also be carried out continuously, whereby a variable or continuous outflow of liquid 540 from the reaction vessel 120 through the dispensing device 145 can always be compensated by a corresponding inflow of water and salt. A volume flow of liquid leaving the reaction vessel 120 can be adjustable by a user. In a step 545, a requirement for a predetermined volume flow can be determined. The addition of water in step 530 and / or salt in step 535 to the reaction vessel 120 can be controlled depending on the determined volume flow. It should be noted that only a combined amount of water and salt supplied to the reaction vessel 120 is determined here, while a ratio of supplied substances can be controlled depending on the comparison of current intensities in step 525. Reference symbol 100 cleaning devices 105 Substrat 110 Generator 115 Textiles, Pillows 118 wheels 120 reaction vessels 125 aqueous solution 130 Electrode 135 DC voltage source 140 current sensor 145 Dispensing device 150 first containers 155 first addition device 160 second container 165 second addition device 170 Control device 205 Anion 210 cation 215 electron 305 Dispensing opening 310 Salt 400 pump 405 hose 410 Axle 415 Limitation 420 roll 425 electric motor 430 suction side 435 printed page 500 procedures 505 Electrolysis 510 Determine actual current 515 Determine desired concentration 520 Determine target current Compare 525 currents 530 Add water 535 Add salt 540 Drain fluid 545 Determine desired quantity

Claims

[1] Generator (110) for cleaning agents, the generator (110) comprising the following elements: - a first container (150) for holding a first liquid; - a second container (160) for holding a second liquid; - a reaction vessel (120) with electrodes (130) for the electrolytic production of cleaning agent based on the first and second liquids; - a control device (170) for guiding first and second liquid into the reaction vessel (120); - a dispensing device (145) connected to the reaction vessel (120) for providing a predetermined volume flow of liquid with cleaning agent from the reaction vessel (120), wherein the dispensing device (145) comprises a positive displacement pump, a flow pump and / or a jet pump. [2] Generator (110) according to claim 1, further comprising a first addition device (155) for dosing first liquid from the first container (150) into the reaction vessel (120). [3] Generator (110) according to claim 1 or 2, further comprising a second addition device (165) for dosing second liquid from the second container (160) into the reaction vessel (120). [4] Generator (110) according to claim 2 or 3, wherein an addition device (155, 165) comprises a positive displacement pump, a flow pump and / or a jet pump. [5] Generator (110) according to claim 4, wherein an addition device (155, 165) comprises a diaphragm pump or a peristaltic pump. [6] Generator (110) according to one of the preceding claims, wherein the second container (160) is adapted to hold a liquid and a solid salt (310). [7] Cleaning device (100) comprising a generator (110) according to one of claims 1 to 6, . [8] Cleaning device (100) according to claim 7, wherein the cleaning device (100) is configured to clean a floor surface with the cleaning agent. [9] A method (500) for providing a cleaning agent, the method comprising the following steps: - feeding (530) a first liquid from a first container (150) into a reaction vessel (120); - feeding (535) a second liquid from a second container (160) into the reaction vessel (120); - applying (505) a predetermined electrical DC voltage to electrodes (130) in the reaction vessel (120) so that an electrical current flows through the solution to form a cleaning agent by means of a redox reaction; and - Providing (540) liquid in which the cleaning agent is formed from the reaction vessel (120); - wherein a ratio of supplied first liquid to supplied second liquid is determined as a function of an electrical current flowing through the electrodes (130).

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