Stone-plastic composite flooring with decorative surface

Description

TECHNICAL FIELD

[0001] The present invention relates to the field of synthetic floors, and specifically relates to a stone plastic composite (SPC) floor comprising a decorative surface.BACKGROUND ART

[0002] Production of ground decoration materials, including bamboo floors, solid wood floors or composite wood floors, requires the use of large amounts of natural bamboo and wood resources, so with increases in public requirements for environmental protection and in awareness about nature conservation, such use is restricted and has become more and more expensive, and, since large amounts of formaldehyde adhesives are used in the preparation process, a smell of formaldehyde may still be detected in the room even after use for a long time. On the other hand, after use for a long time, problems, such as deformation of the bottom board, will occur if there is damp, especially in the ground floors of one-storey houses and storied buildings, or seaside or lakeside houses, which become more serious in wet seasons.

[0003] To overcome the shortcomings of existing decorative materials, it is necessary to replace the above-described materials with novel ones. A novel alternative product has been introduced on the market: PVC stone plastic floor, which, comprising a substrate being a board made by mixing calcium powder and PVC, and a surface coated with a film and grooved, is a ground paving material and a high-quality, high-tech novel ground decoration material with superhigh wear resistance and a bright and nonslippery surface, and thus may be called a model high-tech new material for the twenty-first century. Such stone plastic floor has been disclosed for example in CN 107698192 A. The surface of a PVC stone plastic substrate may be coated with a wooden veneer to give an appearance of solid wood, but the wooden veneer is prone to warping on the surface of the PVC stone plastic substrate, which results in a high defective rate during processing. PVC flooring with a solid wood board veneer are disclosed in CN 108019028 A and EP 1 982 832 A2.

[0004] CN 105804369 discloses a decorative bamboo and plastic floor with a bamboo plastic composite substrate and a bamboo veneer. The bamboo veneer is cold pressed with a two component polyurethane rubber to the substrate with a glass fiber cloth intermediate thereto. The water content of the bamboo veneer is controlled to be within 7-9%.SUMMARY OF THE INVENTIONTECHNICAL PROBLEM TO BE SOLVED

[0005] In the existing stone plastic floor structure, a wooden veneer is prone to warping on the surface of the PVC stone plastic substrate, which results in a high defective rate during processing.SOLUTION TO THE PROBLEMTECHNICAL SOLUTION

[0006] An objective of the present invention is to overcome the above-mentioned shortcomings of the existing stone plastic floor by providing a stone plastic composite (SPC) floor comprising a decorative surface, which can effectively solve the problem of deformation due to warpage.

[0007] The present invention adopts the following technical solution: a stone plastic composite (SPC) floor comprising a decorative surface, the SPC floor comprising an SPC substrate and a decorative surface formed on the SPC substrate, the decorative surface being a wooden board and an adhesive layer is arranged between the decorative surface and the SPC substrate, the moisture content of the decorative surface being controlled within 5-7% and said adhesive layer being formed using a cold glue polyurethane adhesive.

[0008] In the above-described technical solution, the problem that the decorative surface is prone to warping on the surface of the stone plastic floor is solved by controlling the moisture content of the decorative surface and the use of a cold glue polyurethane adhesive.

[0009] Preferably, the main components of the SPC substrate comprise polyvinyl chloride resin powder, calcium carbonate, a calcium-zinc stabilizer, an inner lubricant, PE wax, chlorinated polyethylene (CPE), acrylic ester (ACR), a composite lubricant, and a coloring agent.

[0010] Preferably, the SPC substrate is divided into an upper layer, a middle layer, and a lower layer, wherein the components of the upper layer comprise 100 parts of polyvinyl chloride resin powder, 270-300 parts of calcium carbonate, 4-6 parts of calcium-zinc stabilizer, 0.5-1 part of inner lubricant, 0.6-1.0 part of PE wax, 2-5 parts of chlorinated polyethylene (CPE), 1-3 parts of acrylic ester (ACR), 0.5-1 part of composite lubricant, and 0.5-0.7 parts of coloring agent.

[0011] The components of the middle layer comprise 100 parts of polyvinyl chloride resin powder, 350-380 parts of calcium carbonate, 4-6 parts of calcium-zinc stabilizer, 0.5-0.8 parts of inner lubricant, 0.6-0.9 parts of PE wax, 2-4 parts of chlorinated polyethylene (CPE), 1-3 parts of acrylic ester (ACR), 0.5-0.8 parts of composite lubricant, and 0.5-0.7 parts of coloring agent.

[0012] The components of the lower layer comprise 100 parts of polyvinyl chloride resin powder, 270-300 parts of calcium carbonate, 4-6 parts of calcium-zinc stabilizer, 0.5-1 part of inner lubricant, 0.6-1.0 part of PE wax, 2-5 parts of chlorinated polyethylene (CPE), 1-3 parts of acrylic ester (ACR), 0.5-1 part of composite lubricant, and 0.5-0.7 parts of coloring agent.

[0013] Since the upper layer and the lower layer have the same compositions, having completely identical physical and chemical properties, when the substrate is subjected to extrusion or immersed in water or laminated with the decorative surface, warpage of the decorative surface may be better limited. In addition, use of the same compositions makes it more convenient to control the processing and production cost of the floor.

[0014] Preferably, the middle layer has a thickness of 1.5 mm - 4 mm. The thickness of the middle layer is crucial to ensuring the support strength of the SPC substrate and the strength of the floor, but if the thickness exceeds 4 mm, the anti-warping effect will be affected.

[0015] Preferably, the upper layer has a thickness of 1.0 mm - 2.0 mm, and the lower layer has a thickness of 1.0 mm - 2.0 mm.

[0016] Preferably, the substrate has a total thickness of 4-7 mm.

[0017] Preferably, the decorative surface has a thickness of 0.5-1.5 mm.

[0018] According to the invention, an adhesive layer is arranged between the decorative surface and the SPC substrate.

[0019] According to the invention, the adhesive layer is formed using a cold glue polyurethane adhesive.

[0020] Preferably, the adhesive layer is formed by a roller coating and cold pressing process.

[0021] Preferably, the decorative surface is covered with a UV coating.

[0022] Further preferably, the UV coating is obtainable with an aqueous two-component polyurethane coating.

[0023] Preferably, to improve the sound-deadening performance of the floor, a sound-deadening layer may be glued to the back of the floor, the sound-deadening layer being made of organic polymer foam materials such as PE, EVA, and PU.

[0024] The present invention further provides a process for preparing a stone plastic composite (SPC) floor comprising a decorative surface as described above, the process comprising steps: S-1. Preparing a SPC substrate board, and sanding the board to fix its thickness, thus obtaining a SPC substrate; S-2. Laminating the decorative surface and the SPC substrate with cold glue, and performing cold pressing; S-3. Performing surface sanding and wire drawing after the cold pressing; and S-4. Subjecting the surface to UV treatment to obtain a finished product.

[0025] The SPC substrate board is formed by co-extrusion.

[0026] During co-extrusion of the SPC substrate board, the barrel temperature of the main engine is 170-210°C, the confluence core temperature is 140-180°C, the die temperature is 170-210°C, the speed of the main engine is 18-20 r / min, the feeding speed is 7-16 r / min, the extrusion speed is 1400-1500 mm / min, and the roller temperature is 175-200°C.BENEFICIAL EFFECTS OF THE INVENTIONBeneficial Effects

[0027] By the above-described technical solution, the present invention has the following advantages: the floor obtained by means of the present invention ensures that the decorative surface does not warp or deform while other performances of the floor remain unaffected, and thus is low in costs.BRIEF DESCRIPTION OF THE DRAWINGSDESCRIPTION OF THE DRAWINGS

[0028] Fig. 1 is a schematic structural diagram of a floor obtained in one embodiment of the present invention; Fig. 2 is a simplified schematic flow chart of preparing an SPC substrate board in one embodiment of the present invention. PREFERRED EMBODIMENTS OF THE INVENTIONPREFERRED MODES OF IMPLEMENTING THE INVENTIONEmbodiment 1:

[0029] A stone plastic composite (SPC) floor comprising a decorative surface, the floor comprises an SPC substrate 10, a decorative surface 20, and an adhesive layer 30 bonding the SPC substrate and the decorative surface, the decorative surface 20 being a wood board, the moisture content of the decorative surface being controlled within 5-7%. The adhesive layer 30 was formed with a cold glue polyurethane adhesive by roller coating and cold pressing.

[0030] The SPC substrate was divided into an upper layer, a middle layer, and a lower layer, the main components of the upper layer and the lower layer comprising PVC resin powder and calcium carbonate, and the preferred compositions are listed in Table 1: Table 1. Compositions of the upper and lower layers.MaterialInput amount in embodiment 1Input amount in embodiment 2Input amount in embodiment 3Comparative example 4PVC resin powder100 kg100 kg100 kg100 kgCalcium carbonate303 kg285 kg270 kg150 kgCalcium-zinc stabilizer5 kg5 kg5 kg5 kgComposite lubricant0.8 kg0.8 kg0.7 kg0.8 kg(LUBDE A380)PE wax1 kg0.6 kg0.7 kg1 kgStearic acid SP600.8 kg0.5 kg0.8 kg0.8 kgCPE5 kg4 kg3 kg15 kgACR2 kg2.5 kg1.5 kg2 kgCarbon black (coloring agent)0.5 kg0.5 kg0.5 kg0.5 kg

[0031] The main components of the middle layer comprised PVC resin powder and calcium carbonate, with the preferred compositions listed in Table 2: Table 2. Compositions of the middle layer.MaterialInput amount in embodiment 1Input amount in embodiment 2Input amount in embodiment 3Comparative example 4PVC resin powder100 kg100 kg100 kg100 kgCalcium carbonate380 kg365 kg350 kg270 kgCalcium-zinc stabilizer5 kg4 kg5 kg15 kgComposite lubricant (LUBDE A380)0.8 kg0.7 kg0.6 kg0.8 kgPE wax0.9 kg0.8 kg0.7 kg0.9 kgStearic acid SP600.6 kg0.7 kg0.7 kg0.6 kgCPE4 kg3 kg3.5 kg4 kgACR2 kg2 kg15 kg2 kg

[0032] The SPC substrate had the components listed in Tables 1-2.

[0033] In the present embodiment, as shown in Fig. 2, the method for manufacturing the floor comprised first feeding raw materials into extruder A according to the materials and input amounts listed in Table 1; and then feeding raw materials into extruder B according to Table 2. Extruder A extruded the upper and lower layers of equal mass and equal thickness at the same time, and extruder B extruded the middle layer. Then, the extrudate entered the runner distributor of the die, so that the middle layer was located between the upper layer and the lower layer, and then it entered the die orifice for extrusion into an SPC substrate. The middle layer had a thickness of 4 mm. The upper and lower layers had the same thickness of 1.0 mm.

[0034] Each extruder had a main engine barrel temperature of 200-210°C, a confluence core temperature of 160-180°C, a die temperature of 200-210°C, a main engine speed of 18-20 r / min, a feeding speed of 7-16 r / min, an extrusion speed of 1400-1450 mm / min, and a roller temperature of 175-180°C.

[0035] Thus, there was no adhesive between the upper, middle and lower layers. The board ejected from the die was pressed between a shading roller 1 and a mirror roller 2 to form shade, and the substrate was conveyed to extrusion between a mirror roller 3 and an embossing roller 4 to eject a board, which was shaped, cooled, cut, and shaped to obtain a stone plastic composite (SPC) substrate. Thus, there was no adhesive between the three layers, which is more environmentally friendly and reduces the cost of floor production.

[0036] The method for manufacturing the wooden veneer was as follows: the bottom surface of the wooden veneer was sanded with a 120-150 mesh sand belt until the surface became smooth and was moved into a kiln, the kiln entrance was closed for stepped heating, the heating continued after the temperature had been kept at 35°C for 10 hours, the temperature needed to reach 50°C within 24 hours, when the temperature had reached 50°C, spraying was performed for 3 hours, so that the humidity had a difference of 3 percent with the temperature, then, an equilibrium was maintained for 24 hours at 50°C, so that the humidity fell to have a difference of 10 percent with the temperature, then, spraying was performed for 3 hours at 50°C, so that the humidity had a difference of 5 percent with the temperature, an equilibrium was maintained for 60 hours at 50°C, so that the humidity fell to have a difference of 10 percent with the temperature, until a spot check showed that the oven-dry moisture content had reached the moisture content required for a slab, with the moisture content controlled within 5-7%. The decorative surface had a thickness of 0.5 mm - 1.5 mm.

[0037] The SPC substrate and the decorative layer needed to be compounded by glue. According to the invention, the glue is cold glue polyurethane. The cold glue compounding process parameters of the process for laminating the SPC substrate and the decorative layer are listed in Table 3. Table 3. Cold glue compounding process parameters of the process for laminating the SPC substrate and decorative layers.Key point in processRatio of curing agent to glueGlue temperature / °CGlue amount / (g / m 2< )Roller coating temperature / °CProcess requirement1:520 - 30138 - 17020 - 30

[0038] A polyisocyanate curing agent was used as the curing agent.

[0039] The process parameters for cold pressing the SPC substrate and the decorative layer are listed in Table 4. Table 4. Process parameters for cold pressing the SPC substrate and the decorative layer.Key point in processUnit pressureTemperature / °CCold pressing timeProcess requirement1.5 MPa / cm 2< 25 - 306 h SPECIFIC EMBODIMENTSEMBODIMENTS OF THE INVENTIONEmbodiment 2:

[0040] This embodiment differed from embodiment 1 in the compositions of the upper layer, the middle layer, and the lower layer, details of which are listed in Tables 1-2. Each extruder had a main engine barrel temperature of 170-180°C, a confluence core temperature of 140-150°C, a die temperature of 170-210°C, a main engine speed of 18-20 r / min, a feeding speed of 7-16 r / min, an extrusion speed of 1400-1500 mm / min, and a roller temperature of 175-200°C. The middle layer had a thickness of 3 mm. The upper and lower layers had the same thickness of 1.5 mm.Embodiment 3:

[0041] This embodiment differed from embodiment 1 in the compositions of the upper layer, the middle layer, and the lower layer, details of which are listed in Tables 1-2. Each extruder had a main engine barrel temperature of 180-190°C, a confluence core temperature of 140-180°C, a die temperature of 180-190°C, a main engine speed of 18-20 r / min, a feeding speed of 7-16 r / min, an extrusion speed of 1500 mm / min, and a roller temperature of 180-185°C.

Claims

1. Stone plastic composite (SPC) floor comprising a decorative surface (20), wherein the SPC floor comprises an SPC substrate (10) and a decorative surface (20) formed on the SPC substrate (10), the decorative surface (20) is a wooden board and an adhesive layer (30) is arranged between the decorative surface (20) and the SPC substrate (10), characterized in that the moisture content of the decorative surface (20) is controlled within 5-7%, and said adhesive layer (30) is formed using a cold glue polyurethane adhesive.

2. Stone plastic composite (SPC) floor comprising a decorative surface according to claim 1, characterized in that the main components of the SPC substrate (10) comprise polyvinyl chloride resin powder, calcium carbonate, a calcium-zinc stabilizer, an inner lubricant, PE wax, chlorinated polyethylene (CPE), acrylic ester (ACR), a composite lubricant, and a coloring agent.

3. Stone plastic composite (SPC) floor comprising a decorative surface according to claim 2, characterized in that the SPC substrate (10) is divided into an upper layer, a middle layer, and a lower layer, wherein the components of the upper layer comprise 100 parts of polyvinyl chloride resin powder, 270-300 parts of calcium carbonate, 4-6 parts of calcium-zinc stabilizer, 0.5-1 part of inner lubricant, 0.6-1.0 part of PE wax, 2-5 parts of chlorinated polyethylene (CPE), 1-3 parts of acrylic ester (ACR), 0.5-1 part of composite lubricant, and 0.5-0.7 parts of coloring agent; wherein the components of the middle layer comprise 100 parts of polyvinyl chloride resin powder, 350-380 parts of calcium carbonate, 4-6 parts of calcium-zinc stabilizer, 0.5-0.8 parts of inner lubricant, 0.6-0.9 parts of PE wax, 2-4 parts of chlorinated polyethylene (CPE), 1-3 parts of acrylic ester (ACR), 0.5-0.8 parts of composite lubricant, and 0.5-0.7 parts of coloring agent; wherein the components of the lower layer comprise 100 parts of polyvinyl chloride resin powder, 270-300 parts of calcium carbonate, 4-6 parts of calcium-zinc stabilizer, 0.5-1 part of inner lubricant, 0.6-1.0 part of PE wax, 2-5 parts of chlorinated polyethylene (CPE), 1-3 parts of acrylic ester (ACR), 0.5-1 part of composite lubricant, and 0.5-0.7 parts of coloring agent.

4. Stone plastic composite (SPC) floor comprising a decorative surface according to claim 2 or 3, characterized in that the middle layer has a thickness of 1.5 mm - 4 mm.

5. Stone plastic composite (SPC) floor comprising a decorative surface according to claim 4, characterized in that the substrate (10) has a total thickness of 4-7 mm.

6. Stone plastic composite (SPC) floor comprising a decorative surface according to claim 1 or 4, characterized in that the decorative surface (30) has a thickness of 0.5-1.5 mm.

7. Stone plastic composite (SPC) floor comprising a decorative surface according to claim 3, characterized in that the SPC substrate board is formed by co-extrusion.

8. Stone plastic composite (SPC) floor comprising a decorative surface according to claim 1, characterized in that a sound-deadening layer is glued to the back of the floor, wherein the sound-deadening layer is made of organic polymer foam materials.

9. Stone plastic composite (SPC) floor comprising a decorative surface according to claim 8, characterized in that the adhesive layer (30) is formed by a roller coating and cold pressing process.

10. Process for preparing the stone plastic composite (SPC) floor comprising a decorative surface according to claim 1, comprising the steps: S-1. Preparing a SPC substrate board, and sanding the board to fix its thickness, thus obtaining a SPC substrate (10); S-2. Laminating the decorative surface (30) and the SPC substrate (10) with cold glue, and performing cold pressing; S-3. Performing surface sanding and wire drawing after the cold pressing; and S-4. Subjecting the surface to UV treatment to obtain a finished product.