Method and system for digital printing with control of matt
The method of partial and complete solidification with microfolding of inkjet-printed ink achieves controlled matt or gloss without altering color tones, enhancing wear resistance and automation in decorative print production.
Patent Information
- Application Number
- EP2024382710
- Authority / Receiving Office
- EP · EP
- Patent Type
- Applications
- Current Assignee / Owner
- Filing Date
- 2024-07-01
- Publication Date
- 2026-01-07
AI Technical Summary
Existing methods for achieving controlled matt or gloss in inkjet printing either require a varnish layer that alters color tones or lack automation in achieving desired finishes.
A method involving partial and complete solidification of colored ink, combined with microfolding through varying curing radiation intensity, directly on the inkjet-printed image, allowing controlled matt or gloss without altering color tones.
Enables automatic and easy production of decorative printouts with varying degrees of matt or gloss, enhancing resistance to wear through microfolding, while preserving color appearance and preventing varnish layer necessity.
Smart Images

Figure IMGAF001_ABST
Abstract
Description
SUBJECT MATTER OF THE INVENTION
[0001] The present invention relates to a method and a system for obtaining decorative printouts with a controlled degree of matt or gloss, by means of inkjet printing.
[0002] The invention is applicable, for example, to the production of cardboard packaging, regarding which there is commercial demand for matt designs that are easy to achieve.PRIOR ART
[0003] Two sets of different solutions are known in the prior art for obtaining decorative printouts by means of inkjet printing with a controlled degree of matt or gloss.
[0004] A first set of known solutions is based on the application of a curable varnish which is spread, covering the decoration which has been printed by inkjet. The varnish is subjected to a process of microfolding, by means of which microfolds are created at the surface of the varnish which, through the optical effect of dispersion of light through their microstructure, give rise to the desired matt appearance.
[0005] To obtain the microfolding, the partially cured varnish is subjected to special curing radiation, referred to as excimer radiation. A greater degree of matt is achieved by partially curing the varnish to a low degree before applying the excimer radiation. For example, patent document DE 102006042063 A1 describes a solution of this type.
[0006] As an alternative to curing by means of excimer radiation to produce microfolding, it is also known practice for the varnish used to incorporate agents for promoting curing or photoinitiators located mainly in a surface area of the varnish. For example, patent document DE 102016120878 A1 describes a solution of this type.
[0007] A second set of known solutions is based on adjusting the size of the droplets of ink deposited for the decoration which is printed by inkjet, by adjusting the intensity of curing of the printout. By playing with the level of intensity of curing, greater or lesser contraction or expansion of the droplets is obtained.
[0008] The matt finish is achieved in this case by the optical effect of the different reflection of the light striking the printout, depending on the size or expansion of the droplets deposited. Greater expansion of the droplets or greater coverage of the surface printed results in a higher gloss, owing to the coalescence between the droplets and the elimination of hollows between droplets. For example, patent document WO 2013078297 A1 describes a solution of this type.
[0009] Compared to the first set of known solutions, this second set of known solutions has the drawback of affecting the range of colours and tones of the printout, since this is determined by the separation and distribution of the droplets in the various pixels of the printout.
[0010] It is also well known practice to use coloured inks with matting agents which make it possible to obtain decorative printouts with a required degree of matt. However, these solutions do not make it possible to control the degree of matt automatically and easily, since it is necessary to select the matting agents for each individual printout.
[0011] Normally, inkjet inks, once cured, have a gloss appearance, such that it is necessary to implement a method for control of matt which makes it possible to increase the degree of matt, or reduce the degree of gloss. This is the case, for example, with cardboard packaging.
[0012] The present invention aims to provide a method and a system for digital printing with control of matt offering an alternative to the methods and systems existing in the prior art.
[0013] In particular, the present invention aims to overcome the limitations of the known solutions by providing a method and system for digital printing with control of matt which makes it possible to obtain printouts with matt finishes automatically and easily.EXPLANATION OF THE INVENTION
[0014] To achieve the above aim, as well as other technical advantages that may become clear from the present description, the invention provides a method for digital printing with control of matt, which comprises the following steps: a) printing by inkjet of a digitalized image, depositing curable coloured ink on a substrate; b) partial solidification of the coloured ink deposited; c) microfolding of the surface of the coloured ink deposited; and d) complete solidification of the coloured ink deposited after microfolding of its surface.
[0015] Steps b), c) and d), in other words the partial solidification, the microfolding of the surface and the complete solidification, are carried out by means of curing radiation.
[0016] According to the invention, to obtain printouts or printout areas with different degrees of matt, the curing radiation for partial solidification and / or the curing radiation for microfolding are applied with a level of radiation intensity that is different for each printout or printout area of the digitalized image.
[0017] The application, in the partial solidification of the printout, of curing radiation with different levels of radiation intensity makes it possible to obtain different degrees of matt in a controlled manner. This is because the application of curing radiation for microfolding produces microfolding at the surface which is more accentuated the lower the degree of curing or solidification of the coloured ink deposited during printing is upon application of said curing radiation for microfolding.
[0018] Similarly, the curing radiation for microfolding itself may be applied with a level of radiation intensity that is different for each printout or printout area of the digitalized image, as an alternative or in addition to the different levels of intensity of curing radiation for partial solidification. It is thus possible to achieve the same effect of different degrees of matt in a controlled manner in different printout areas or different printouts.
[0019] In the context of the present invention, "level of intensity of curing radiation" means, in particular, the curing radiation energy irradiated per unit area for solidification, partial or complete, or for microfolding.
[0020] The different level of radiation intensity may be applied to different printout areas of the same printed digitalized image, or to different printouts corresponding to different digitalized images.
[0021] Thus, the invention makes it possible to obtain printouts with different degrees of matt or gloss automatically and easily, since each of the steps of the method may be carried out automatically and easily, and may be controlled individually or in a coordinated manner.
[0022] Unlike the methods of the prior art, with the invention it is possible to obtain decorative printouts with controlled degrees of matt or gloss without the need for a layer of varnish which covers the decoration printed and without altering the appearance of colours and tones of the printout. This is possible because the curing radiation for microfolding is applied directly to the printout, microfolding its surface.
[0023] Advantageously, moreover, it must be noted that, thanks to the microfolding transferred to the surface of the printout, the invention makes it possible to obtain printouts with improved resistance to wear, owing to the increase in local bending inertia of the microfolding of the coating of the printout itself.
[0024] In the context of the present invention, microfolding of the surface of a coating means the phenomenon whereby a liquid surface layer of the coating is hardened with respect to the core of the coating, such that said surface layer deforms, contracting, resulting in structuring or folding of the surface layer with a magnitude measured in microns, or even tenths of a micron (distance between peak and trough). As stated, this phenomenon of microfolding is generally known per se in the prior art.
[0025] According to the invention, therefore, it has been found that, surprisingly, it is possible to generate microfolding by making use of the actual coloured ink deposited by inkjet printing. The coloured ink deposited, which forms the printout corresponding to the digitalized image as it is perceived visually on the substrate, may be microfolded directly, making it possible to control the degree of matt or gloss of the printout directly.
[0026] To be specific, it was found, in particular, that for the resolutions and speeds usual in inkjet printing of digital images, the coloured ink of the printout may be spread across a coating having a thickness of the order of tens of microns, or even microns. This facilitates the microfolding of a layer of coloured ink duly spread, bearing in mind that, as stated, the structuring resulting from microfolding may be of the order of microns or tenths of a micron.
[0027] Preferably, according to the invention, the method for digital printing with control of matt described may further comprise the following steps: supplying an agglutinant liquid for agglutinating the coloured ink deposited, the agglutinant liquid being curable; and, by means of curing radiation, partial solidification of the agglutinant liquid supplied, together with the coloured ink deposited, in step b); microfolding of the surface of the agglutinant liquid supplied, together with the surface of the coloured ink deposited, in step c); and complete solidification of the agglutinant liquid supplied after microfolding of its surface, together with the coloured ink deposited, in step d).
[0028] According to the invention, to obtain printouts or printout areas with different degrees of matt, the curing radiation for partial solidification and / or the curing radiation for microfolding are applied - to the printout and to the agglutinant liquid in each corresponding step - with a level of radiation intensity that is different for each printout or printout area of the digitalized image.
[0029] In the context of this variant of the invention in which agglutinant liquid is supplied, "agglutinating" (the coloured ink deposited) means, in particular, joining up (the coloured ink) by connecting the droplets of coloured ink deposited, through the contact which occurs between the agglutinant liquid and the liquid of the droplets of coloured ink.
[0030] The selection of an agglutinant liquid capable of agglutinating a given coloured ink and having other properties that may be envisaged by the invention, is known per se to those skilled in the art. For example, an agglutinant liquid with a chemical composition identical or similar to the coloured ink facilitates the agglutination or coalescence between the agglutinant liquid and the coloured ink. The use of specific chemical agents makes it possible, in particular, to ensure any viscosity and surface tension properties required.
[0031] Thus, in the case where an agglutinant liquid is supplied, the curing radiation for solidification, partial or complete, or the curing radiation for microfolding may be applied both to the coloured ink deposited and to the agglutinant liquid supplied.
[0032] In this regard, the curing radiation for partial solidification of the coloured ink and the agglutinant liquid, and / or the curing radiation for microfolding the surface of the coloured ink and of the agglutinant liquid, are applied with a level of radiation intensity that is different for each printout or printout area of the digitalized image. Each printout or each printout area may comprise, at least locally, coloured ink and / or agglutinant liquid.
[0033] Generally and in the context of the present invention, curing refers to the chemical process of reticulation which causes hardening of polymer materials by crosslinking of their polymer molecules, which occurs upon the application of curing radiation.
[0034] Likewise, curing radiation is any electromagnetic or subatomic particle radiation which initiates or accelerates a curing process. As curing radiation, use is usually made of ultraviolet (UV) radiation, although use may also be made, for example, of electron beam (EB) radiation. The curable materials are mixtures of polymers which include chemical agents such as photoinitiators or surfactants.
[0035] The coloured ink and the agglutinant liquid must be curable by means of curing radiation, for solidification, partial or complete, and for microfolding, in particular, and the curing radiation may be the same both for solidification, partial or complete, and for microfolding.
[0036] Acrylates or acrylate polymers are used extensively in inkjet printing and, in particular, may be used as curable material for the coloured ink and the agglutinant liquid in accordance with the invention. The selection of a curable material with specific properties for each application, for example in relation to its hardening and solidification, through the selection of an appropriate type of polymer and chemical agents, is known per se to those skilled in the art.
[0037] In the context of the present invention, "solidification" means, in particular, the hardening which occurs substantially throughout the thickness of the material deposited. Partial solidification means hardening substantially throughout the thickness of the material deposited, albeit incomplete.
[0038] Likewise, "complete solidification", or "final solidification", means the final step of solidification by curing radiation, in addition to partial solidification, in accordance with the invention. By means of complete solidification, in particular, a degree of solidification that is effective and permanent for normal use of the printout to be obtained is achieved.
[0039] To this end, the exposure time and the intensity of the curing radiation for solidification may be especially critical. Insufficient curing may result in the material not reaching its effective properties, whereas overexposure can damage the material.
[0040] As curing radiation for solidification, partial or complete, use may preferably be made of UV radiation, in the UV-A, UV-B and / or UV-C range of wavelengths. As regards the curing radiation for microfolding, in accordance with a preferred embodiment of the invention, this radiation may be excimer radiation.
[0041] Excimer radiation is substantially monochromatic radiation, of short wavelength and with high radiation energy. This radiation does not penetrate deeply into the layer of liquid deposited, the radiated energy being concentrated in a surface area of the layer, such that, as the liquid is partially solidified, microfolding is generated.
[0042] The use of excimer radiation to produce microfolding is known per se, for example, from patent document DE 102006042063 A1, the disclosure of which in this regard is incorporated into the present description by reference.
[0043] For the invention, use may be made, for example, of excimer radiation, substantially concentrated, in particular in the UV-C range of wavelengths, for example at 172 nm. Since at 172 nm photons have a high rate of absorption by oxygen in the air, irradiation is performed in an inert atmosphere, preferably in an inerted chamber under a supply of nitrogen.
[0044] In the case of the use of excimer radiation for microfolding in accordance with the invention, the application of curing radiation for partial solidification may begin, in particular may take place, prior to the application of the excimer radiation. This makes it possible to ensure solidification of the core of the coating, of coloured ink and / or agglutinant liquid deposited, which is sufficient to produce microfolding.
[0045] For the implementation of the invention, it must be noted that the level of intensity of the curing radiation for partial solidification, applied to the coloured ink and / or to the agglutinant liquid, in particular prior to the application of the excimer radiation, must preferably lie in a range, between a minimum and a maximum. In general, this range depends on the thickness of the material which receives the excimer radiation and on the final degree of matt finish which it is desired to obtain.
[0046] The minimum level of intensity is necessary because, if the layer of material deposited which receives the excimer radiation is very fluid, hardening of the surface layer does not result in proper microfolding, but cracks occur as a consequence of the hardening gradients occurring at the surface.
[0047] The maximum level of intensity is necessary because, if the layer of material deposited is highly solidified, this also prevents proper microfolding since the surface is not able to deform further to give rise to the microfolds.
[0048] According to the invention, microfolding may also be carried out by means other than the application of excimer radiation. For example, the coloured ink and / or the agglutinant liquid, on the surfaces of which the microfolding takes place, may be configured to promote surface curing when a specific curing radiation, in particular other than excimer radiation, is applied.
[0049] This process of promotion of the surface curing of coatings so as to generate microfolding therein is known per se, for example, from patent document DE 102016120878 A1, the disclosure of which in this regard is incorporated into the present description by reference.
[0050] Also according to the invention, the same curing radiation may be used for partial solidification and for microfolding, especially in the case of microfolding by promotion of surface curing. Likewise, the application of curing radiation for partial solidification may be carried out before and / or simultaneously with the application of curing radiation for microfolding, in particular by means of the same irradiation means. Furthermore, partial solidification may occur before and / or during microfolding.
[0051] In any case, preferably, the application of curing radiation for partial solidification begins, in particular takes place, prior to the application of the radiation for microfolding, especially in the case of application with excimer radiation, regardless of whether they may be carried out with the same or different irradiation means. This allows greater control, as it is possible to disassociate the process of solidification from that of microfolding.
[0052] As regards the use of agglutinant liquid in accordance with a general embodiment of the invention, the agglutinant liquid may be in the form of a liquid layer which is spread over the substrate, in particular in contact with the substrate. Coloured ink is printed directly on the layer of agglutinant liquid, the coloured ink being deposited directly on said layer. In this way, the agglutinant liquid supplied agglutinates the droplets of ink deposited, like a bed on which the droplets of ink of the printout are laid.
[0053] The layer of agglutinant liquid may be transparent or pigmented with any colour. Layers of white agglutinant liquid have the advantage of acting as a background for printing to enhance the visual appearance of decorative printouts, especially if the surface of the substrate printed is not white.
[0054] It is also conceivable for the layer of agglutinant liquid itself to act as a primer layer to facilitate the adhesion of the printout to the substrate. The layer of agglutinant liquid may be configured to have this adhesion function by selecting a suitable composition of chemical agents, such as surfactants.
[0055] These chemical agents make it possible, in particular, to ensure any viscosity and surface tension properties required, as known per se to those skilled in the art.
[0056] The layer of agglutinant liquid may be spread over the substrate, for example, by means of a roller or spraying. In particular, spraying may be carried out using nozzles. The liquid layer may also be spread by means of inkjet printing or any other known method.
[0057] According to another general embodiment of the invention, the agglutinant liquid may be supplied by being intermingled with droplets of coloured ink deposited, corresponding to the printout of the digitalized image. The agglutinant liquid may be spread, for example, by spraying through nozzles or, preferably, by means of inkjet printing, using agglutinant liquid ink.
[0058] In the case where the agglutinant liquid is spread by being intermingled with droplets of coloured ink, the agglutinant liquid or ink is, preferably, transparent. It is thus possible to preserve the colours and tones of the printed image formed by the droplets of coloured ink.
[0059] The agglutinant liquid makes it possible to make the degree of matt finish uniform in the irradiated area, regardless of the amount of coloured ink deposited per area, which in principle depends on the corresponding colour and tone of the digitalized image printed. It is thus possible to neutralize the matt effect produced by the expansion and contraction of the droplets of coloured ink themselves.
[0060] Everything set out above in relation to the characteristics of the coloured ink applies to the agglutinant liquid, in that it must be curable by means of curing radiation, for the purposes of partial and complete solidification, as well as curable by means of curing radiation for microfolding, in particular by means of excimer radiation and / or by means of radiation for the promotion of surface curing.
[0061] In particular, the partial solidification of transparent agglutinant liquid and / or the complete solidification, of agglutinant liquid and / or of the printout of the digitalized image, may be carried out by means of mercury UV lamps. Likewise, the partial solidification of non-transparent agglutinant liquid and / or of the printout of the digitalized image may be carried out by means of gallium UV lamps. Efficient curing is thus achieved, taking advantage of the property of gallium UV lamps to penetrate into the thickness of the printout and / or of the agglutinant liquid deposited.
[0062] The implementation of the method of the invention makes it possible to obtain matt finishes over a wide range, in particular in the range from 10 to 100 GU (gloss units), measured at 85º in accordance with the standard ISO 2813:2014 (or the equivalent standard UNE-EN ISO 2813:2015).
[0063] Preferably, the coloured ink and / or the agglutinant liquid are configured such that, if they undergo complete solidification separately, applying only the curing radiation and without microfolding the surface (without applying curing radiation for microfolding), they have a degree of gloss, measured at 85º in accordance with the standard ISO 2813:2014, of greater than or equal to 60 GU, preferably 75 GU, more preferably 90 GU.
[0064] In particular, the coloured ink and the agglutinant liquid are configured such that, if they undergo complete solidification separately, applying only the curing radiation and without microfolding the surface, the difference in their degree of gloss, measured at 85º in accordance with the standard ISO 2813:2014, is less than or equal to 10 GU, preferably 5 GU, more preferably 1 GU. This minimizes any differences in gloss between different printout areas for the different formulations of coloured ink and / or agglutinant liquid that may be selected.
[0065] Moreover, as regards the quantity of coloured ink and / or agglutinant liquid that may be used, the droplet size for printing, the thicknesses of the layers, etc. the invention may be applied, in particular, with droplet sizes corresponding to the usual printing resolutions, such as for example 360 dpi.
[0066] For example, the printout may have thicknesses of the order of microns or tens of microns. Likewise, the layer of agglutinant liquid or agglutinant liquid also may have thicknesses of microns or tens of microns. In particular, the primer layers for the printout may be adapted as a function of the type of substrate to be printed. For example, for cardboard they may be approximately 5-10 microns, for wood or plastic, approximately 10-40 microns.
[0067] According to another aspect of the present invention, the invention also relates to a system for digital printing with control of matt, for carrying out a method for digital printing as described above.
[0068] According to the invention, the system for printing with control of matt comprises: an inkjet printer for injecting coloured ink so as to print a digitalized image, in particular a single pass inkjet printer; a curing radiation station for microfolding the surface of the coloured ink deposited; a curing radiation station for partial solidification of the coloured ink deposited and / or the curing radiation station for microfolding the surface being configured also for partial solidification; a curing radiation station for complete solidification of the coloured ink deposited after microfolding; and a controller configured to process and send control signals to the curing radiation station for partial solidification and / or to the curing radiation station for microfolding, so as to apply different levels of radiation intensity to each printout or printout area and thus obtain printouts or printout areas with different degrees of matt.
[0069] The printing system may comprise substrate conveyor means, for conveying the substrate through the printer and the radiation stations, so as to carry out the method of the invention. In this case, the conveyor means may also be controlled by the controller.
[0070] For the application of UV curing radiation, use may be made of the usual lamps which emit in the UV-A, UV-B and / or UV-C spectrum, for example, arc discharge lamps or LED lamps.
[0071] Arc discharge lamps include mercury vapour lamps, usually referred to as "mercury lamps", which emit UV radiation substantially distributed around the wavelengths of 254 nm and 365 nm, with a greater concentration of energy in the short wavelengths.
[0072] Mercury vapour lamps doped with heavy metal compounds, such as gallium iodide or iron iodide are also used. Lamps doped with gallium iodide, usually referred to as "gallium lamps", make it possible to change the emission spectrum of mercury lamps, emitting UV radiation substantially distributed around wavelengths of 400 to 450 nm.
[0073] When used for the invention, gallium lamps are suitable for curing coloured ink or non-transparent agglutinant liquid since, owing to the pigmentation of these materials, they to some degree block UV radiation of shorter wavelength. With gallium lamps, as the wavelengths are longer, the radiation penetrates further into the material and the qualitative result is gradual curing at depth rather than at the surface, and therefore more effective solidification, right through the thickness to the surface.
[0074] According to the invention, use may also be made of LED lamps for the emission of UV curing radiation, in particular for solidification, partial or complete, and / or for microfolding. For example, LED lamps configured to emit UV radiation, in particular at 260 nm, 360 nm, 385 nm and / or 395 nm, may be suitable for the invention.
[0075] To obtain different matt or gloss effects in different printout areas of a printout corresponding to one and the same digitalized image, in accordance with the invention, the curing radiation for partial solidification of the printout may be applied with different levels of radiation intensity for the different areas of the printout by means of an array of LED lamps, of the same or different wavelength.
[0076] Preferably, the system for digital printing with control of matt in accordance with the invention further comprises a station for supplying the agglutinant liquid, wherein the system may be provided with a curing radiation station for microfolding, a curing radiation station for partial solidification and / or a curing radiation station for complete solidification of the agglutinant liquid. In particular, the same curing radiation station may be used (for microfolding, partial solidification and / or complete solidification) both for the coloured ink and for the agglutinant liquid.
[0077] In particular, the station for supplying agglutinant liquid may be of various types, depending on the variant of the method for printing with control of matt of the invention for which the system may be configured.
[0078] Thus, if the agglutinant is spread as a layer of liquid, means for coating by roller, spray nozzles or an agglutinant liquid inkjet printer may be used, for example, for supplying agglutinant liquid. Conversely, if the agglutinant is spread intermingled with the droplets of the coloured ink corresponding to the digital image, an agglutinant liquid inkjet printer may be used, for example.
[0079] For its part, the coloured ink inkjet printer corresponding to the digital image may be the same as the agglutinant ink inkjet printer, in which case different heads or rows of heads of nozzles may be used for the different inks.
[0080] In this regard, it is also conceivable for the same curing radiation station to be used to carry out different steps of the method of the invention, in particular for microfolding, partial solidification and / or complete solidification. For example, especially when microfolding is carried out by promotion of surface curing, the curing radiation station for microfolding may be configured also for partial and / or complete solidification.
[0081] In other cases, a curing radiation station may be used to carry out only one step of the method of the invention. For example, according to the invention there may be a curing radiation station for partial solidification of the agglutinant liquid prior to printing the digitalized image, especially in the case in which the agglutinant liquid is spread in the form of a layer on the substrate.
[0082] Naturally, when the system includes the station for supplying agglutinant, the controller of the system is additionally configured to process and send control signals to the curing radiation station for partial solidification and / or to the curing radiation station for microfolding the agglutinant liquid (together with the coloured ink), so as to apply different levels of radiation intensity to each printout or printout area and thus obtain printouts or printout areas with different degrees of matt.
[0083] Likewise, also according to the invention, the controller may additionally be configured to process and send control signals to other stations or units of the system for correct operation thereof, for example to the coloured ink inkjet printer, agglutinant liquid inkjet printer, curing radiation station for complete solidification and / or to the substrate conveyor means, etc.
[0084] According to another aspect, the present invention also relates to a substrate printed digitally with control of matt, which may be obtained by means of a method or with a system for digital printing as described above.
[0085] Preferably, the substrate may be a laminar material, especially for packaging or containers. The substrate may be cardboard, in particular comprising cardboard or being a cardboard box. In this regard, the invention may be advantageously applicable to packaging or containers for food since, by virtue of the improvement of the method in terms of curing efficiency, migration of the printout and / or agglutinant liquid to the interior of the packaging is prevented.BRIEF DESCRIPTION OF THE DRAWINGS
[0086] The invention is described in greater detail below, by way of non-limiting illustration, and with regard to a preferred embodiment by way of example, making reference to the attached drawings. In the drawings: Figure 1 schematically depicts a system for carrying out a method for digital printing with control of matt according to a first embodiment in accordance with the invention. Figure 2 schematically depicts a system for carrying out a method for digital printing with control of matt according to a second embodiment in accordance with the invention. Figures 3A and 3B show two photographs of respective substrates printed with the same digitalized image, but with different degrees of gloss, obtained according to an example of a method for digital printing with control of matt according to the first embodiment of the invention. Figure 4 shows a table which presents the gloss values measured, in accordance with standard ISO 2813:2014, for respective printed substrates shown in the photographs in Figures 3A and 3B. DETAILED DESCRIPTION OF THE INVENTION
[0087] With reference to Figure 1, the system for digital printing with control of matt (1) shown corresponds to a first embodiment of the invention. The system (1) comprises an inkjet printer (10) for injecting coloured ink, a curing radiation station (20) for partial solidification of the printout, an excimer radiation station (30) for microfolding the surface of the printout and a curing radiation station (40) for complete solidification of the printout.
[0088] The inkjet printer (10) is a single pass printer, the substrate (2) being printed as it moves, passing under the print heads (11, 12, 13, 14) of the printer (10). Each head (11, 12, 13, 14) is formed by rows of injection nozzles, through which the coloured ink is injected.
[0089] The substrate (2) may be, for example, a laminar material for packaging, in particular a laminar material which comprises cardboard or a cardboard box.
[0090] The printer (10) includes pinning lamps (15, 16, 17, 18), which are positioned after each print head (11, 12, 13, 14), and which serve to freeze the droplets of ink to a given degree when the substrate (2) is being printed.
[0091] According to this first embodiment, the system (1) includes a station for applying a layer of transparent agglutinant liquid (50), by means of a roller, and a partial curing radiation station (60), prior to inkjet printing, the printout being deposited directly on the layer of agglutinant liquid generated, like a bed.
[0092] For example, in this embodiment the excimer radiation station (30) is configured to emit substantially monochromatic radiation at 172 nm and comprises an excimer radiation lamp (31) arranged in a chamber inerted with nitrogen (32).
[0093] Likewise, the curing radiation stations (20, 40) which come after printing are formed by gallium UV lamps and the curing radiation station (60) prior to printing is formed by mercury UV lamps, since the layer of agglutinant liquid generated is transparent.
[0094] The system (1) includes a conveyor means (80) for conveying the substrates (2), with a conveyor belt (81) for conveying the substrates (2) through the system (1), from the point where they are supplied (on the left in the figure) to the point where they are collected (on the right in the figure), as the various corresponding steps of the method of the invention are carried out.
[0095] The printer (10), the curing radiation stations (20, 40, 60), the excimer radiation station (30), the station for applying the layer of agglutinant liquid (50) and the conveyor means (80) are controlled by means of a controller (90).
[0096] The controller (90) processes and sends control signals to the various subsystems so as to apply different levels of radiation intensity to each printout or printout area and thus obtain printouts or printout areas with different degrees of matt.
[0097] With reference to Figure 2, the system for digital printing with control of matt (1) shown corresponds to a second embodiment of the invention. As in the first embodiment described, the system (1) comprises an inkjet printer (10) for injecting coloured ink, a curing radiation station (20) for partial solidification of the printout, an excimer radiation station (30) for microfolding the surface of the printout and a curing radiation station (40) for complete solidification of the printout.
[0098] The system (1) of this second embodiment differs from the system (1) of the first embodiment in that, instead of including a station for applying a layer of agglutinant liquid (50) and a corresponding partial curing radiation station (60), the system (1) includes a station for applying the agglutinant liquid by inkjet (70). For example, the partial curing radiation station (60) is located before the inkjet printer (10). Likewise, in particular, the station for applying the agglutinant liquid by inkjet (70) is located after the inkjet printer (10).
[0099] In all other aspects, the general operation of the system (1) is as in the first embodiment. The printer (10), the curing radiation stations (20, 40), the excimer radiation station (30), the station for applying the layer of agglutinant liquid (70) and the conveyor means (80) are controlled by means of the controller (90).
[0100] The controller (90) processes and sends control signals to the various subsystems so as to apply different levels of radiation intensity to each printout or printout area and thus obtain printouts or printout areas with different degrees of matt.
[0101] According to this embodiment, the agglutinant liquid is supplied by means of inkjet printing (70) using transparent ink, which is intermingled with deposited droplets of the printout of the digitalized image. The agglutinant liquid ink is injected through the nozzles arranged in the heads (71, 72) and, as in the printer (10), the station (70) is provided with pinning lamps (73, 74) for freezing the ink injected.
[0102] The heads (71, 72) of the station for applying (70) the transparent liquid, in general, may be arranged as in the printer (10) that prints the digitalized image, in other words in one or two rows (offset from one another) or aligned if redundancy is sought. It is thus possible to adjust the droplets of agglutinant ink to the resolution of printing of the digitalized images.
[0103] The application of agglutinant liquid by inkjet makes it possible to deposit the agglutinant liquid selectively in different printout areas, with, for example, a greater amount of liquid per unit area being deposited in some areas than in others. Moreover, in general, this may be carried out in correspondence with printout areas having a lesser amount of coloured ink deposited per area, obtaining a layer of more uniform thickness over the entire digital printout and, therefore, a resulting matt finish which is also more uniform.
[0104] As a general variant of the embodiments described, the partial curing radiation station (20) may be formed by an array of LED lamps, which makes it possible to apply a different level of curing intensity in different printout areas. A higher level of partial curing makes it possible to inhibit to a greater degree the effect of microfolding, such that by varying the intensity of the LED lamps by area it is possible to obtain a different matt finish in the different areas. The array of LED lamps may consist of a row or a matrix of LED lamps.
[0105] Another general variant which is conceivable as regards the embodiments described is the provision of an additional coating layer on the printout obtained. These layers may be, for example, functional layers, structuring or texturing layers, protective layers, etc.
[0106] In particular, as a protective layer for giving the matt printout obtained greater resistance to wear, a layer of varnish may be spread over the printout. However, microfolding per se provides greater resistance to wear than the resistance obtained by coating the printout without microfolding.
[0107] According to the invention, additional layers may be applied on the microfolded printed layer before, during or after complete solidification. A given degree of partial curing of the printed layer, with or without agglutinant liquid, may promote the adhesion of a surface layer to its surface. However, the inherent characteristics of the microfolded printed layer, as regards its small thickness and surface distribution of the ink or agglutinant liquid, may themselves facilitate adhesion.
[0108] A practical example of substrates printed with control of matt, obtained in accordance with the first embodiment of the invention is set out below, with reference to Figures 3 and 4. The printouts were produced on respective wooden substrates, using the same digitalized image.
[0109] Figures 3A and 3B show two photographs corresponding to the respective substrates printed. The printed substrate in Figure 3A (referred to in the table in Figure 4 as "S.Fig.3A") was obtained with a low degree of matt (high gloss). The printed substrate in Figure 3B (referred to in the table in Figure 4 as "S.Fig.3B") was obtained with a high degree of matt (low gloss).
[0110] For the coloured ink and the agglutinant liquid, use was made of a mixture of acrylates curable with UV radiation, by means of mercury lamps and gallium lamps, and curable with excimer radiation at 172 nm in an inerted chamber under a supply of nitrogen.
[0111] Digital printing by inkjet was carried out in the usual manner, with a single pass printer (10) with a resolution of 360 dpi and print heads (11, 12, 13, 14) with coloured inks C ("cyan"), M ("magenta"), Y ("yellow"), K ("black"). The substrates (2) were conveyed through the system (1) at a conveyor speed of 20 m / min.
[0112] Following the application of a first layer of transparent agglutinant liquid with a thickness of approximately 20 microns, by means of a roller (50), partial solidification was carried out prior to printing, using mercury lamps (60) at 120 W / cm, supplying radiation energy of approximately 130 mJ / cm 2< to each substrate.
[0113] This was followed by digital printing (10) with the coloured ink, pinning by means of LED lamps (15, 16, 17, 18) at 395 nm.
[0114] After printing of the digitalized image, partial solidification of the printout together with the lower layer of agglutinant liquid was carried out. Gallium lamps (20) at 80 W / cm were used for this purpose.
[0115] Partial solidification was carried out with a different level of radiation intensity for each one of the substrates (2). The printed substrate (2) in Figure 3A was irradiated with radiation energy of approximately 50 mJ / cm 2< . The printed substrate (2) in Figure 3B was irradiated with radiation energy of approximately 10 mJ / cm 2< .
[0116] Partial solidification was followed by microfolding, applying excimer radiation (30) by means of an excimer radiation lamp (31) at 172 nm, placed in a chamber inerted with nitrogen (32). The radiation energy supplied by the excimer radiation to each substrate (2) was approximately 130 mJ / cm 2< .
[0117] Lastly, the substrates (2) were subjected to curing radiation for the complete solidification of the printout and the agglutinant liquid, by means of gallium lamps (40) at 80 W / cm. The radiation energy supplied by this curing radiation to each substrate was approximately 1060 mJ / cm 2< .
[0118] The table in Figure 4 presents the gloss measurements, performed in accordance with standard ISO 2813:2014, for each of the printed substrates obtained. To be specific, the gloss measurements were performed in a black area of the printout.
[0119] As can be seen in the table, gloss values GU measured at 85º were obtained, namely 44.3 GU for the printed substrate in Figure 3A ("S.Fig.3A") and 9.2 GU for that in Figure 3B ("S.Fig.3B"). The gloss values GU measured at 60º were similar for the two printed substrates (2), namely 3.1-3.4 GU.
[0120] Gloss measurements were also taken on a sample of printed substrate to which only the curing radiation was applied, without microfolding the surface, having been printed with the same ink as the substrates in Figures 3A and 3B and without agglutinant liquid. The gloss value GU measured at 85º, in accordance with standard ISO 2813:2014, for the black area of the printout and following complete solidification, was 91.2 GU.
[0121] To sum up, as shown in this patent specification, the invention provides a method and system for digital printing with control of matt which makes it possible to obtain printed substrates with matt finishes automatically and easily, overcoming the limitations of the prior art and providing additional technical advantages.
[0122] To this end, the invention is not limited to the embodiments described, but includes all variants, modifications and combinations that fall within the scope of the attached claims.List of reference signs
[0123] 1Printing system 2Substrate for printing 10Digitalized image inkjet printer 11, 12, 13, 14Nozzle heads for printing 15, 16, 17, 18Pinning lamps for printing 20Partial curing radiation station 30Excimer radiation station 31Excimer radiation lamp 32Chamber inerted with nitrogen 40Complete curing radiation station 50Station for applying a layer of agglutinant liquid 60Partial curing radiation station 70Station for applying agglutinant liquid by inkjet 71, 72Nozzle heads for printing 73, 74Pinning lamps for printing 80Substrate conveyor means 81Conveyor belt 90Controller for the printing system
Examples
Embodiment Construction
[0087]With reference to Figure 1, the system for digital printing with control of matt (1) shown corresponds to a first embodiment of the invention. The system (1) comprises an inkjet printer (10) for injecting coloured ink, a curing radiation station (20) for partial solidification of the printout, an excimer radiation station (30) for microfolding the surface of the printout and a curing radiation station (40) for complete solidification of the printout.
[0088]The inkjet printer (10) is a single pass printer, the substrate (2) being printed as it moves, passing under the print heads (11, 12, 13, 14) of the printer (10). Each head (11, 12, 13, 14) is formed by rows of injection nozzles, through which the coloured ink is injected.
[0089]The substrate (2) may be, for example, a laminar material for packaging, in particular a laminar material which comprises cardboard or a cardboard box.
[0090]The printer (10) includes pinning lamps (15, 16, 17, 18), which are positioned after each print...
Claims
1. Method for digital printing with control of matt, which comprises: a) printing by inkjet of a digitalized image, depositing curable coloured ink on a substrate (2); and, by means of curing radiation, b) partial solidification of the coloured ink deposited; c) microfolding of the surface of the coloured ink deposited; and d) complete solidification of the coloured ink deposited after microfolding of its surface; such that, to obtain printouts or printout areas with different degrees of matt, the curing radiation for partial solidification and / or the curing radiation for microfolding are applied with a level of radiation intensity that is different for each printout or printout area of the digitalized image.
2. Method for digital printing with control of matt according to Claim 1, characterized in that it comprises: - supplying an agglutinant liquid for agglutinating the coloured ink deposited, the agglutinant liquid being curable; and, by means of curing radiation, - partial solidification of the agglutinant liquid supplied, together with the coloured ink deposited, in step b); - microfolding of the surface of the agglutinant liquid supplied, together with the surface of the coloured ink deposited, in step c); and - complete solidification of the agglutinant liquid supplied after microfolding of its surface, together with the coloured ink deposited, in step d).
3. Method for digital printing with control of matt according to Claim 2, characterized in that the agglutinant liquid is supplied by spreading on the substrate (2) a liquid layer, in particular transparent, on which the coloured ink is deposited directly.
4. Method for digital printing according to Claim 3, characterized in that the liquid layer is spread by means of a roller (5), spraying or inkjet printing.
5. Method for digital printing according to either of Claims 3 and 4, characterized in that the liquid layer is partially solidified, by means of curing radiation, prior to depositing the coloured ink.
6. Method for digital printing according to Claim 2, characterized in that the agglutinant liquid is supplied by being intermingled with droplets of coloured ink deposited, in particular, by means of inkjet printing (70) with transparent ink.
7. Method for digital printing with control of matt according to one of Claims 2 to 6, characterized in that the coloured ink and the agglutinant liquid are configured such that, if they undergo complete solidification separately, applying only the curing radiation without microfolding the surface, the difference in their degree of gloss, measured at 85º in accordance with the standard ISO 2813:2014, is less than or equal to 10 GU, preferably 5 GU, more preferably 1 GU.
8. Method for digital printing according to one of the preceding claims, characterized in that the coloured ink and / or the agglutinant liquid are configured such that, if they undergo complete solidification separately, applying only the curing radiation and without microfolding the surface, they have a degree of gloss, measured at 85º in accordance with the standard ISO 2813:2014, of greater than or equal to 60 GU, preferably 75 GU, more preferably 90 GU.
9. Method for digital printing with control of matt according to one of the preceding claims, characterized in that the curing radiation for microfolding is excimer radiation.
10. Method for digital printing with control of matt according to one of the preceding claims, characterized in that the coloured ink and / or the agglutinant liquid, on the surface of which the microfolding takes place, are configured to promote surface curing when curing radiation for microfolding is applied thereto.
11. Method for digital printing according to one of the preceding claims, characterized in that the curing radiation for partial solidification and / or the curing radiation for microfolding are applied with different levels of radiation intensity for different printout areas by means of an array of LED lamps.
12. System for digital printing with control of matt (1), for carrying out a method for digital printing according to one of the preceding claims, which comprises: - an inkjet printer (10) for injecting coloured ink so as to print a digitalized image, in particular a single pass inkjet printer (10); - a curing radiation station for microfolding the surface (30) of the coloured ink deposited; - a curing radiation station for partial solidification (20) of the coloured ink deposited and / or the curing radiation station for microfolding the surface (30) being configured also for partial solidification; - a curing radiation station for complete solidification (40) of the coloured ink deposited; and - a controller (90) configured to process and send control signals to the curing radiation station for partial solidification (20) and / or to the curing radiation station for microfolding (30), so as to apply different levels of radiation intensity to each printout or printout area and thus obtain printouts or printout areas with different degrees of matt.
13. System for digital printing with control of matt according to Claim 12, characterized in that it comprises a station for supplying the agglutinant liquid (50, 70), the curing radiation station for microfolding the surface (30), the curing radiation station for partial solidification (20) and / or the curing radiation station for complete solidification (40) being in particular both for the coloured ink and for the agglutinant liquid.
14. System for digital printing with control of matt according to either of Claims 12 and 13, characterized in that the curing radiation station for microfolding the surface is an excimer radiation station (30).
15. Substrate (2) printed digitally with control of matt, characterized in that it may be obtained by means of a method for digital printing according to one of Claims 1 to 11, in particular, the substrate (2) being cardboard, more particularly being packaging or a container.
Citation Information
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