Powdered composition for cosmetic cleansing of skin or hair
A powdered cosmetic cleansing composition with surfactants and thickeners, dissolving in water to form a fluid agent, addresses inefficiencies in liquid products by offering sustainable, flexible, and effective cleansing with reduced resource use.
Patent Information
- Application Number
- FR2023002454
- Authority / Receiving Office
- FR · FR
- Patent Type
- Patents
- Current Assignee / Owner
- Priority Date
- 2022-03-23
- Filing Date
- 2023-03-16
- Publication Date
- 2026-02-06
- Estimated Expiration
- 2043-03-16
AI Technical Summary
Existing cosmetic cleansing products in liquid or paste form face issues such as high water content, bulky packaging, environmental impact due to non-recyclable plastics, and inconsistent application due to variable foam production based on user technique, leading to inefficiencies and resource wastage.
A powdered composition containing surfactants and thickeners, which dissolves rapidly in water to form a ready-to-use fluid cleansing agent, allowing flexible use in recyclable packaging and ensuring consistent cleaning efficacy.
The powdered composition provides a sustainable, easy-to-use, and efficient cleansing solution with optimal viscosity, reducing resource consumption and environmental footprint while ensuring thorough cleaning and care for skin or hair.
Abstract
Description
Title of the invention: Powdered composition for cosmetic cleansing of skin or hair
[0001] The application describes a powdered composition for cosmetic cleansing of the skin or hair, based on surfactants and a specific mixture of thickeners, which dissolves rapidly upon contact with water and is easily transformed into a ready-to-use fluid cleansing agent. The application also describes a process for producing the powdered composition and its use in the production of a ready-to-use, cosmetic, fluid cleansing agent.
[0002] Products containing surfactants for cleansing the human body and / or hair have been known for a long time and are marketed primarily as bubble baths, shower preparations, shampoos, and / or oral care compositions in liquid or paste form in suitable packaging. When using, end consumers dispense the required amount of product from the packaging and dispose of it after emptying. Compared to conventional soaps marketed in solid form, such products offer the user the advantage of quick and easy handling, which is why they currently dominate the market. However, this advantage comes at the cost of certain drawbacks, which are discussed below.Most of the time, the packaging for the described liquid or paste products is made of plastic that is not or only slightly recyclable, which is a serious environmental problem given the ever-increasing amount of plastic waste.
[0003] Another problem is that current products generally contain higher quantities of water or water / solvent mixtures, which means that the products have a larger volume and, from a transport perspective, potentially more importantly, a relatively high weight. This is disadvantageous for several reasons. In times of increasing water scarcity, resources should be conserved. An undesirable high transport volume associated with heavy and bulky products is also important from an environmental perspective, as well as from a cost perspective.
[0004] The provision of alternative product forms with very low water content and contained in a compact manner in more environmentally friendly packaging, for example recyclable, is therefore an important objective when formulating improved, modern and sustainable cosmetic products.
[0005] Shampoos in powder form containing substantially surfactants sulfate-free (and other surfactants), as well as thickeners and conditioning agents, are disclosed in WO 2019 / 023332.
[0006] According to the extract from the Mintel database (Registration ID: 7460103), a facial skin cleansing powder is known which also contains sulfate-free surfactants as well as thickeners and conditioning agents.
[0007] The two powders are rubbed with a little water between the hands and form a foam which is spread on the skin of the face or on the hair.
[0008] For the consumer, this form of use is unusual and, possibly, also undesirable.
[0009] In addition, such a form of use also has disadvantages, because, depending on the force with which the consumer rubs the powder and / or the amount of water used during rubbing to produce foam, the amount of resulting foam and thus the effective amount of cleaning composition applied to the surface of use can vary considerably.
[0010] In addition, this type of use always presents the risk that some of the powder will not produce foam, that it will clump in the consumer's wet hands and fall to the ground without being used or that it will be rinsed off without being used after massaging the foam.
[0011] The practical use of said powders is therefore not always satisfactory.
[0012] There is therefore also a need for powdered compositions for the cleansing of the human body which, in addition to the requirements mentioned above, are easy and convenient to use.
[0013] In view of the problems and requirements described above, the inventors have set themselves the objective of developing cosmetic powder compositions for the cleansing of the human body and / or hair, with which alternative and sustainable product forms can be used flexibly and with which, in addition to cleansing, excellent care of the human body and / or hair is also ensured.
[0014] The objective of the invention is achieved by means of the formulations, processes and uses described in detail below:
[0015] 1. Powdered composition for the cosmetic cleansing of the skin or hair, containing, in relation to the total weight of the powder,
[0016] a) 10 to 65% by weight of at least one surfactant,
[0017] b) a mixture of thickeners, comprising
[0018] i) 10 to 40% by weight of at least one starch or a starch fraction, possibly hydrophobically modified,
[0019] ii) 5 to 30% by weight of at least one starch hydrolysis product and
[0020] iii) 1 to 20% by weight of at least one natural polymer different from i) and ii).
[0021] 2. Powdered composition as per declaration 1, containing at least one surfactant anionic a) in a weight proportion of 10 to 65% by weight relative to the total weight of the powder.
[0022] 3. Powdered composition as previously stated, containing at least one anionic surfactant a) in a weight proportion of 20 to 60% by weight relative to the total weight of the powder.
[0023] 4. Powdered composition according to a previous declaration, containing at least one anionic surfactant a) in a weight proportion of 30 to 55% by weight relative to the total weight of the powder.
[0024] 5. Powdered composition according to a previous declaration, containing at least one amino acid-based surfactant, isethionate-containing surfactant, sulfosuccinate-containing surfactant, olefin sulfonate or mixtures thereof.
[0025] 6. Powdered composition as previously stated, containing at least one surfactant containing isethionate of formula (I) following
[0026] [Chem.l]
[0027] in which
[0028] - R1 represents a linear or branched hydrocarbon radical, saturated or unsaturated, containing 6 to 30 carbon atoms,
[0029] - R2 to R5 independently represent a hydrogen atom, a alkyl radical in C1-C4 or a hydroxyalkyl radical in C1-C4, and
[0030] - M+ represents an ammonium cation, an alkanolammonium cation or a me cation tallique.
[0031] 7. Powdered composition according to a previous declaration, containing at least one alkaline or ammonium salt of Cocoyl Isethionate, Cocoyl Methyl Isethionate, Lauroyl Isethionate, Lauroyl Methyl Isethionate or mixtures thereof.
[0032] 8. Powdered composition according to a previous declaration, further containing less an amphoteric surfactant, a non-ionic surfactant or mixtures thereof in a weight proportion of 0 to 10% by weight relative to the total weight of the powder.
[0033] 9. Powdered composition as previously stated, containing as that thickener b)i) starch or a starch fraction of maize, potato, rice, wheat, tapioca, hydroxypropyl starch phosphate, dihydroxypropyl starch phosphate, distarch phosphate or mixtures of these.
[0034] 10. Powdered composition as per declaration 9, containing modified starch known under the INCI name Hydroxypropyl Starch Phosphate in a weight proportion of 10 to 40% by weight relative to the total weight of the powder.
[0035] 11. Powdered composition as per declaration 9, containing known starch under the INCI name Oryza Sativa Starch in a weight proportion of 10 to 40% by weight relative to the total weight of the powder.
[0036] 12. Powdered composition as previously stated, containing as thickening b)ii) of maltodextrin in a weight proportion of 10 to 30% by weight relative to the total weight of the powder.
[0037] 13. Powdered composition as previously stated, containing as that thickening b)iii) natural polymers of the gum group, polysaccharides, galactomannans or mixtures thereof.
[0038] 14. Powdered composition according to declaration 13, containing as that thickening b)iii) of xanthan gum in a weight proportion of 1 to 20% by weight relative to the total weight of the powder.
[0039] 15. Powdered composition according to declaration 13, containing as that thickening b)iii) of guar gum in a weight proportion of 1 to 20% by weight relative to the total weight of the powder.
[0040] 16. Powdered composition according to declaration 13, containing as that thickening b)iii) of Caesalpinia Spinosa gum in a weight proportion of 1 to 20% by weight relative to the total weight of the powder.
[0041] 17. Powdered composition according to a previous declaration, containing a cationic polysaccharide polymer c) in a weight proportion of 0 to 7.5% by weight relative to the total weight of the powder.
[0042] 18. Powdered composition according to a previous declaration, containing at least a cationic polymer c) obtained from cellulose, guar, cassia and / or inulin.
[0043] 19. Powdered composition according to a previous declaration, containing a cationic polysaccharide polymer c) known by the INCI name Guar Hydroxypropyltrimonium Chloride in a weight proportion of 0.1 to 5% by weight relative to the total weight of the powder.
[0044] 20. Powdered composition according to a previous declaration, which is exempt of surfactants containing sulfate.
[0045] 21. A process for producing a powdered composition according to one of the following methods: declarations 1 to 20, in which all the ingredients are mixed in a powder cosmetic mixing apparatus and optionally sieved.
[0046] 22. Use of a powdered composition according to one of the declarations 1 to 20 for the production of a fluid, cosmetic and ready-to-use cleaning agent by dissolving the powdered composition in water.
[0047] 23. Process for producing a ready-to-use, cosmetic, fluid cleaning agent employment, including the following steps:
[0048] - making available a powdered composition according to one of the declarations 1 to 20,
[0049] - mixing the powdered composition with water in a weight ratio of 1 10 to 1:15 in a suitable container,
[0050] - possibly, shaking or stirring the resulting mixture.
[0051] 24. A process according to declaration 23, wherein the fluid cleaning agent, cosmetic and ready-to-use resulting exhibits a viscosity in the range of 2,000 to 11,000 mPas (measured at 20 °C with a Haake VT 550 rotary viscometer, MV measuring system).
[0052] 25. Cosmetic process for cleaning the human body and / or hair, in in which a ready-to-use, cosmetic, fluid cleansing agent obtained according to one of statements 23 or 24 is distributed over the part of the body to be cleaned and rinsed off with water after an exposure period of 5 seconds to 15 minutes.
[0053] The powdered compositions according to the invention offer the advantage
[0054] - to be able to be produced in an energy-efficient manner and to be able to contained compactly in more environmentally friendly packaging, for example recyclable,
[0055] - to consume fewer resources during their transport due to the strong concentrations of active substances and to allow easy transport without too much effort or restrictions (compared to liquid dosage forms),
[0056] - to be able to be mixed by any user with tap water in order to produce the ready-to-use cleaning agent,
[0057] - to dissolve very well in water,
[0058] - to thoroughly clean and take care of the skin or hair.
[0059] The powdered compositions according to the invention may
[0060] a) either be packaged as individual portions and used directly by mixing the powder with water,
[0061] b) or, before use, be transformed with water in a suitable container into a fluid cleaning agent that can be used in a traditional manner.
[0062] According to the present invention, the possibility of use b) is particularly preferred because
[0063] it offers the following additional advantages compared to option a):
[0064] - the mixing of the powdered composition with water can be carried out in any (recyclable) container, such as for example a glass bottle or resealable plastic,
[0065] - the user can freely determine the volume of the cleaning preparation usable produced (and, depending on the quantities of powder and water chosen, produce any quantity, from a single quantity to a stock of several liters),
[0066] - the rapid dissolution of the powder system in water ensures the availability quick and easy positioning of a ready-to-use liquid cleaning agent without the need for high shear, but possibly only by shaking or gently agitating.
[0067] - the specific mixture of thickeners i), ii) and iii) in the powder system after mixing with water, it yields liquid products with an optimal viscosity for use.
[0068] - the powder system can be formulated without non-biodegradable ingredients and sulfate-free.
[0069] The powder composition according to the invention comprises, in relation to its total weight, 10.0 to 65.0% by weight of at least one surfactant a) as the first essential ingredient.
[0070] The appropriate surfactants a) may be chosen from anionic, amphoteric, zwitterionic, nonionic and / or cationic surfactants. Preferably, anionic surfactants are used in the powder compositions according to the invention because they exhibit excellent foaming and / or cleaning power, are mainly soluble in water, and are available in solid form.
[0071] In a preferred embodiment, the powdered systems according to the invention contain at least one anionic surfactant as a surfactant a) in a weight proportion of 10 to 65% relative to the total weight of the powder. Amounts of anionic surfactants of 20 to 60% by weight, and in particular 30 to 55% by weight, in the powdered system are particularly preferred.
[0072] The types of anionic surfactants suitable for use in the powdered compositions according to the invention are, for example:
[0073] a) ethercarboxylic acids of formula RO-(CH2-CH2O)X-CH2-COOH, in which R represents a linear or branched, saturated or unsaturated alkyl group comprising 8 to 30 carbon atoms and x = 0 or 1 to 16,
[0074] b) surfactants obtained from natural sources such as
[0075] - acyl glycinate,
[0076] - acyl sarcosinate,
[0077] - acyl lactylate,
[0078] - acyl glutamate,
[0079] - acyl aspartate,
[0080] - acyl taurate,
[0081] - acyl isethionate,
[0082] - sulfosuccinate and
[0083] the corresponding salified forms of the aforementioned surfactants, the acyl groups comprising 10 to 30 carbon atoms.
[0084] c) alpha-olefin sulfonates comprising 8 to 24 carbon atoms (surfactants containing alpha-olefin sulfonates),
[0085] d) alkyl sulfates of formula RO-SO3X, in which R preferably represents a linear or branched alkyl group, saturated or unsaturated, comprising 8 to 30 carbon atoms and X represents an alkali ion, an alkaline earth ion, an ammonium ion or an alkanolamine ion,
[0086] e) unsaturated fatty acid sulfonates comprising 8 to 24 carbon atoms and 1 to 6 double bonds,
[0087] f) esters of tartaric acid and citric acid comprising alcohols which are addition products of about 2 to 15 molecules of ethylene oxide and / or propylene oxide with fatty alcohols comprising 8 to 22 carbon atoms, and / or
[0088] g) alkyl and / or alkenyl ether phosphates of formula
[0089] [Chem.2] OX
[0090] wherein R1 preferably represents an aliphatic hydrocarbon radical comprising 8 to 30 carbon atoms, R2 represents hydrogen, a (CH2CH2 O)nR* radical or X, n represents numbers from 0 to 10 and X represents hydrogen, an alkali or alkaline earth metal or the group -NR3R4R5R6, with R3 to R6 independently representing a C1 to C4 hydrocarbon radical.
[0091] Anionic surfactants from groups b) and c) above are preferred.
[0092] Surfactants of group b) above and their corresponding salified forms, in which the acyl groups comprise 10 to 24 carbon atoms and in particular 10 to 18 carbon atoms, are particularly preferred.
[0093] Examples of particularly suitable surfactants from group b) are the alkali, alkaline earth, ammonium and / or alkanolamine salts of amino acid-based surfactants such as Cocoyl Glycinate, Cocoyl Sarcosinate, Lauroyl Sarcosinate, Myristoyl Sarcosinate, Oleoyl Sarcosinate, Cocoyl Glutamate, Lauroyl Glutamate, Stearoyl Glutamate, Lauroyl Aspartate, Palmitoyl Aspartate, Cocoyl Taurate (CrC4 alkyl), Lauroyl Taurate (CrC4 alkyl), Oleoyl Taurate (CrC4 alkyl) as well as Lauroyl Lactylate, Stearoyl Lactylate, Cocoyl Isethionate (CrC4 alkyl), Lauroyl Isethionate (CrC4 alkyl), Lauryl Sulfosuccinate and / or any mixtures thereof.
[0094] The following acyl isethionates of formula (I) are particularly preferred
[0095] [Chem.3] Q R4 R ■ ---3.:......... 0 ...................... j.......... R-
[0096] in which
[0097] - R1 represents a linear or branched, saturated or unsaturated hydrocarbon radical containing 6 to 30 carbon atoms,
[0098] - R2 to R5 independently represent a hydrogen atom, a a C1-C4 alkyl radical or a C1-C4 hydroxyalkyl radical, and
[0099] - M+ represents an ammonium cation, an alkanolammonium cation or a me cation tallique.
[0100] Alkaline or ammonium salts of Cocoyl Isethionate, Cocoyl Methyl Isethionate, Lauroyl Isethionate, Lauroyl Methyl Isethionate or mixtures thereof are even more particularly preferred.
[0101] According to a preferred embodiment, it may also be advantageous to use as a surfactant a) a mixture of said surfactants, such as for example isethionate-containing and glutamate-containing surfactants or isethionate-containing and taurate-containing surfactants.
[0102] According to another preferred embodiment, it may further be advantageous to use as a surfactant a) a mixture of said anionic surfactants with amphoteric surfactants, non-ionic surfactants or mixtures thereof, the amphoteric surfactants, non-ionic surfactants or mixtures thereof being present in a weight proportion of 0 to 10% by weight relative to the total weight of the powder composition.
[0103] Amphoteric and / or zwitterionic surfactants suitable for use in the powder compositions according to the invention include, for example: alkyl betaines, alkyl amidoalkyl betaines, alkyl amphoacetates, alkyl amphodiacetates, alkyl amphopropionates, alkyl amphodipropionates, alkyl sultaines, alkyl hydroxysultaines, alkyl amino-oxides, alkyl amphoglycinates, alkyl iminodiacetates, alkyl iminodipropionates, alkyl amphopropylsulfonates, alkyl amphocarboxyglycinates and alkyl amphocarboxypropionates.
[0104] Suitable alkyl betaines and / or alkyl amidopropyl betaines preferably comprise alkyl chains in the C4-C24, more preferably in the C6-C18, manner particularly preferred in C8-Ci4, which can be linear or branched, with linear chains being preferred.
[0105] Cocamidopropyl Betaine is particularly preferred.
[0106] Alkyl amphoathetas, alkyl amphodiacetates, alkyl amphoapropionates or alkyl amphodipropionates are preferably sodium cocoamphoacetate and disodium cocoamphoacetate.
[0107] Non-ionic surfactants suitable for use in powder compositions according to the invention include, for example:
[0108] - amino-oxides, for example surfactants known by the names INCI Cocamine Oxide, Lauramine Oxide and / or Cocamidopropylamine Oxide, commercially available from various suppliers,
[0109] - fatty acid alkanolamides, in particular the compounds known under the denomination INCI Cocamide MEA
[0110] - alkoxylates of fatty alcohols (in particular ethoxylates) comprising a C chain length of 8 to 24, especially 10 to 20, and a degree of alkoxylation (degree of ethoxylation) of 2 to 30, such as laureth-4,
[0111] - mixtures of alkyl (oligo)glucosides and fatty alcohols, for example the product Montanov®68 is commercially available.
[0112] - alkyl (oligo)glycosides. Suitable alkyl (oligo)glycosides may be chosen from compounds of general formula RO-[G]X, in which [G] is preferably derived from aldoses and / or ketoses comprising 5 to 6 carbon atoms, preferably from glucose.
[0113] The index x represents the degree of oligomerization (DP), that is, the distribution of monoglycosides and oligoglycosides. The index x preferably has a value in the range of 1 to 10, particularly preferably in the range of 1 to 3, and cannot be an integer, but a fractional number that can be determined analytically.
[0114] Particularly preferred alkyl (oligo)glycosides have a degree of oligomerization between 1.2 and 1.5. The R radical preferably represents at least one alkyl and / or alkenyl radical comprising 4 to 24 carbon atoms.
[0115] The alkyl (oligo)glycosides that are even more particularly preferred are the compounds known under the INCI names Caprylyl / Capryl Glucoside, Decyl Glucoside, Lauryl Glucoside and Coco Glucoside.
[0116] The powder composition according to the invention comprises as a second essential ingredient b) a mixture of thickeners comprising (relative to the total weight of the powder composition)
[0117] i) 10 to 40% by weight of at least one starch or a starch fraction, possibly hydrophobically modified,
[0118] ii) 5 to 30% by weight of at least one starch hydrolysis product and
[0119] iii) 1 to 20% by weight of at least one natural polymer different from i) and ii).
[0120] According to the present invention, suitable starches or starch fractions are preferably starches from potatoes, maize, rice, peas, acorns, chestnuts, barley, wheat, bananas, sago, millet, sorghum, oats, rye, beans, sweet potatoes, arrowroot, or cassava. Starch fractions from maize, potatoes, rice, wheat, tapioca, or mixtures thereof are particularly preferred.
[0121] According to the present invention, hydrophobically modified starches or starch fractions are preferably hydrophobically modified corn, wheat, rice, tapioca, potato and / or sago starch compounds.
[0122] According to the present invention, "hydrophobic modification" means chemical crosslinking, for example by ionic crosslinking, with calcium, aluminum and / or polyphosphates, preferably with polyphosphates, and / or chemical modification by the introduction of hydrophobic groups.
[0123] By "hydrophobic groups" we preferably mean non-ionic radicals such as, for example, hydroxyalkyl groups, "hydroxyalkyl groups" preferably representing hydroxyethyl, hydroxypropyl and / or hydroxybutyl groups.
[0124] According to the present invention, particularly preferred hydrophobically modified starch compounds are crosslinked and carry non-ionic hydrophobic substituents, particularly preferably hydroxyethyl or propyl groups.
[0125] Hydrophobically modified starch compounds known by the INCI names Distarch Phosphate, Hydroxyethyl Starch Phosphate, Dihydroxyethyl Starch Phosphate, Hydroxypropyl Starch Phosphate and Dihydroxypropyl Starch Phosphate and mixtures thereof are particularly preferred.
[0126] Hydroxypropyl Starch Phosphate is even more particularly preferred.
[0127] These products are known and available, for example, under the names Structure® XL, Structure® ZEA or Stardesign® Care.
[0128] Hydrophobically modified starches and / or starch compounds (i) can be used in the powder compositions according to the invention (with respect to their total weight), preferably in amounts of 15 to 37.5% by weight, more preferably 17.5 to 35% by weight, particularly preferably 19 to 32.5% by weight and in particular 20 to 30% by weight.
[0129] In a preferred embodiment, the powder compositions according to the invention contain as a thickener b)i) starch or a starch fraction of maize, potato, rice, wheat, tapioca, hydroxypropyl starch phosphate, dihydroxypropyl starch phosphate, distarch phosphate or mixtures thereof.
[0130] In said embodiment, powder compositions according to the invention which contain modified starch known by the INCI name Hydroxypropyl Starch Phosphate in a weight proportion of 10 to 40% (more preferably 15 to 35% and in particular 20 to 30%) relative to the total weight of the powder are particularly preferred.
[0131] In said embodiment, powder compositions according to the invention which contain starch known by the INCI name Oryza Sativa Starch in a weight proportion of 10 to 40% (more preferably 15 to 35% and in particular 20 to 30%) relative to the total weight of the powder are further particularly preferred.
[0132] According to the present invention, suitable starch hydrolysis products are understood to mean:
[0133] a) starches treated by reaction with acids, such as, for example, hydrochloric acid or sulfuric acid, and / or
[0134] b) starches modified enzymatically, for example, by treatment with amylases, for example amylases α and β or glucoamylase.
[0135] In the reactions described in a) and b), there is a decomposition by hydrolysis of the starch into starch degradation products of different compositions, for example into dextrins (such as maltodextrin) or, in the case of b), a decomposition of the amylopectin contained in the starch only down to the branches (limit dextrins) and of the amylose down to the monosaccharides.
[0136] According to the present invention, a particularly preferred hydrolysis product of starch ii) is maltodextrin.
[0137] In a preferred embodiment, the powder compositions according to the invention contain, as a thickener b)ii), maltodextrin in a weight proportion of 10 to 30% (more preferably 12.5 to 25% and in particular 15 to 20%) relative to the total weight of the powder.
[0138] According to the present invention, suitable natural polymers (iii) other than (i) and (ii) are understood to mean, preferably, natural polymers other than (i) and (ii) from the group of gums, polysaccharides, galactomannans, or mixtures thereof. They can be incorporated into the powder compositions according to the invention (by weight) preferably in amounts of 1.5 to 17.5% by weight, more preferably from 2 to 15% by weight, particularly preferably from 2.5 to 12.5% by weight, and in particular from 3 to 10% by weight.
[0139] Examples of suitable natural polymers from the gum group are xanthan gum, gellan gum, locust bean gum or mixtures thereof.
[0140] Examples of suitable natural polymers from the polysaccharide group are preferably non-ionic modified cellulosic polymers such as Hydroxyethylcellulose, hydroxypropylcellulose, ethylcellulose, carboxymethylcellulose or mixtures thereof.
[0141] Suitable galactomannans are understood to be starch-like substances derived from branched carbohydrate chains. The main chain consists of mannose, with short side chains of individual galactose molecules appearing at various intervals. The main chain of the polysaccharide is composed of D-mannose units that form a helical structure. The monomers are linked only by 3-1,4 glycosidic bonds. Side chains of individual galactose molecules appear at irregular intervals; these are linked to the mannose by α-6,1 glycosidic bonds.
[0142] Common sources of galactomannan are guar flour, carob flour, fenugreek (Trigonelia foenum graecum) and alfalfa (Medicago sativa).
[0143] Preferred galactomannans include guar gum, locust bean gum, cassia gum, Caesalpinia spinosa gum (tara gum) or mixtures thereof.
[0144] In a preferred embodiment, the powder compositions according to the invention contain, as a thickener b)iii), xanthan gum in a weight proportion of 1 to 20% (more preferably 2 to 15% and in particular 3 to 10%) relative to the total weight of the powder.
[0145] In another preferred embodiment, the powder compositions according to the invention contain, as a thickener b)iii), guar gum in a weight proportion of 1 to 20% (more preferably 2 to 15% and in particular 3 to 10%) relative to the total weight of the powder.
[0146] In another preferred embodiment, the powder compositions according to the invention contain, as a thickener b)iii), Caesalpinia Spinosa gum (tara gum) in a weight proportion of 1 to 20% (more preferably 2 to 15% and in particular 3 to 10%) relative to the total weight of the powder.
[0147] To improve the skin or hair conditioning properties, it may be advantageous for the powder compositions according to the invention to further contain at least one active skin or hair care substance.
[0148] By active substances suitable for conditioning the skin or hair, we preferably mean
[0149] - cationic polymers, in particular polymers of ca polysaccharides tionics,
[0150] - lipids,
[0151] - vegetable oils, butters and / or waxes,
[0152] - protein hydrolysates,
[0153] - plant extracts
[0154] - or mixtures thereof.
[0155] According to the present invention, suitable cationic polymers are preferably cationic polymers of natural origin, in particular cationic polysaccharide polymers. Particularly suitable examples are:
[0156] - quaternized cellulose derivatives, as commercially available under the names Celquat® and Polymer JR®,
[0157] - cationic starch derivatives, such as are available for example in the traded under the name Mirustyle®,
[0158] - hydrophobically modified cellulose derivatives, for example cationic polymers distributed under the trade name SoftCat®,
[0159] - cationic alkyl polyglycosides,
[0160] - cationized honey, for example the commercial product Honeyquat® 50,
[0161] - cationic guar derivatives, such as in particular products distributed under the trade names Cosmedia®Guar, N-Hance® and Jaguar®,
[0162] - cationic cassia and / or inulin derivatives such as cationic polymers known under the INCI names Cassia Hydroxypropyltrimonium Chloride and Hy-droxypropyltrimonium Inulin.
[0163] Cationic polymers obtained from cellulose, guar, cassia and / or inulin are particularly preferred.
[0164] In a preferred embodiment, the powder compositions according to the invention contain at least one cationic polysaccharide polymer c) in a weight proportion of 0 to 7.5% (more preferably from 0.01 to 7% by weight, particularly preferably from 0.05 to 6% by weight and in particular from 0.1 to 5% by weight) relative to the total weight of the powder.
[0165] In another preferred embodiment, the powder compositions according to the invention contain a cationic polysaccharide polymer c) known by the INCI name Guar Hydroxypropyltrimonium Chloride in a weight proportion of 0.1 to 5% by weight relative to the total weight of the powder.
[0166] Preferably, the powder compositions according to the invention contain substantially active substances and additives obtained from natural sources.
[0167] By "substantially", it is understood that the powder compositions according to the invention, in relation to their total weight, contain at least 90% by weight, preferably at least 92% by weight and in particular at least 95% by weight, of active substances and additives obtained from natural sources.
[0168] Powdered compositions according to the invention that are substantially free of sulfated acids are further preferred, which makes it possible to obtain a maximum content of sulfated surfactants of 0.05% by weight, more preferably of 0.01% by weight and by- specific of 0% by weight (relative to the total weight of the powder compositions).
[0169] According to the present invention, suitable lipids are understood to mean all fats and fat-like substances that preferably melt in a range of 30 to 150 °C. These include, among others, triglycerides, monoglycerides and / or diglycerides, waxes, fatty and waxy alcohols, fatty acids, esters and / or ethers of fatty alcohols and fatty acids, as well as fatty acid amides, hydrocarbons, lipoproteins, glycolipids, phospholipids or any mixtures of these substances.
[0170] Triglycerides are understood to mean “natural” oils, preferably vegetable oils.
[0171] Preferably, these are triglycerides and mixtures of triglycerides such as amaranth seed oil, apricot kernel oil, argan oil, avocado oil, babassu oil, bamboo oil, baobab oil, canola oil, safflower oil, pomegranate kernel oil, rosehip kernel oil, hemp oil, hazelnut oil, gooseberry oil, blackcurrant oil, jojoba oil, coconut oil, pumpkin seed oil, macadamia nut oil, mallow oil, almond (sweet) oil, mango kernel oil, evening primrose oil, olive oil, Brazil nut oil, passion fruit oil, palm kernel oil, peach kernel oil, rambutan oil, rice bran oil, castor oil, safflower oil, sasanqua oil, sesame oil, soybean oil, sunflower oil, tea tree oil, grapeseed oil, tsubaki oil,Walnut oil, wheat germ oil and / or meadowfoam oil.
[0172] Suitable vegetable butters are preferably understood to mean shea butter, mango butter, murumuru butter, cocoa butter, apricot kernel butter, mafura butter, bacuri butter, tucuma butter, ucuuba butter and / or cupuaçu butter.
[0173] Waxes are defined as natural or artificial substances having the following properties: they are solid in consistency with high resistance to breakage, have coarse to fine crystallinity, are translucent to cloudy, and melt above 30 °C without disintegration. They are already slightly above their melting point, have low viscosity and are not stringy, and exhibit a consistency and solubility that are strongly dependent on temperature. According to the invention, natural vegetable waxes with a melting point of 30 to 150 °C can be used, such as candelilla wax, carnauba wax, Japanese wax, esparto grass wax, cork wax, guaruma wax, rice bran oil wax, sugar cane wax, urucury wax, lignite wax, sunflower wax, and fruit waxes such as orange wax, lemon wax, grapefruit wax, and bay wax. bay berry) and animal waxes, such as beeswax, shellac, spermaceti, wool wax, and rump fat. According to the invention, it may be advantageous to use hydrogenated or hardened waxes. Natural waxes that can be used according to the invention also include mineral waxes such as ceresin and ozocerite, or petrochemical waxes such as petrolatum, paraffin waxes, and microcrystalline waxes. Chemically modified waxes can also be used as wax components, in particular hard waxes such as lignite ester waxes, Sasol waxes, and hydrogenated jojoba waxes. Synthetic waxes that can be used according to the invention include, for example, polyalkylene waxes and waxy polyethylene glycol waxes.
[0174] Glyceride mixtures such as Cutina® HR (hardened castor oil) and Novata® AB (C12-C18 monoglyceride, diglyceride and triglyceride mixture) may preferably be used as a monoglyceride and / or diglyceride.
[0175] Fatty alcohols that can be used according to the invention include, for example, unbranched C12-C50 fatty alcohols, in particular C14-C30 fatty alcohols obtained from natural fats, oils, and waxes such as, for example, lauryl alcohol, myristyl alcohol, 1-pentadecanol, cetyl alcohol, 1-heptadecanol, stearyl alcohol, 1-nonadenol, arachidyl alcohol, 1-heneicosanol, behenyl alcohol, brassidyl alcohol, lignoceryl alcohol, ceryl alcohol, or myricyl alcohol. According to the invention, unbranched, saturated, and unsubstituted fatty alcohols are preferred.
[0176] However, branched fatty alcohols, saturated or unsaturated, can also be used according to the invention. According to the invention, fatty alcohol fractions, such as those resulting from the reduction of naturally occurring fats and oils, can also be used.
[0177] Preferably, C12-C40 fatty acids or mixtures thereof are considered as fatty acids. Examples include lauric, tridecanoic, myristic, pentadecanoic, palmitic, margaric, stearic, nonadecanoic, arachinic, behenic, lignoceric, cerotic, melissic, erucic, and eleostearic acids, as well as substituted fatty acids such as, for example, 12-hydroxystearic acid and fatty acid amides or monoethanolamides, this list being illustrative and not restrictive. Suitable hydrocarbons are understood to mean liquid or solid hydrocarbons such as petrolatum, ceresin, ozokerite, paraffins, isoparaffins, and / or squalene.
[0178] According to the present invention, suitable glycolipids are sugar-based surfactants, alkyl polyglycosides and / or ceramides.
[0179] According to the present invention, a suitable phospholipid is lecithin.
[0180] Lipids may be used in the powder compositions according to the invention, preferably in a weight proportion of 0 to 10% relative to the total weight of the powder composition. Amounts of 0.01 to 8.5% by weight, and particularly preferably 0.05 to 7% by weight, are preferred.
[0181] By suitable protein hydrolysates is meant mixtures of products which can be obtained by acid-, basic-, or enzymatic-catalyzed degradation of proteins (albumens).
[0182] Hydrolysates of plant, animal and / or marine proteins may be used.
[0183] Hydrolysates of animal proteins are, for example, hydrolysates of elastin, collagen, keratin, silk, and milk proteins, which may also be present in the form of salts. Such products are distributed, for example, under the brand names Dehylan® (Cognis), Promois® (Interorgana), Collapuron® (Cognis), Nutrilan® (Cognis), Gelita-Sol® (Deutsche Gélatine Fabriken Stoess & Co), Lexein® (Inolex), and Kerasol® (Croda).
[0184] Hydrolyzed proteins of plant origin, for example hydrolyzed soybean, almond, rice, pea, potato and wheat proteins, are preferred. Such products are available, for example, under the brand names Gluadin® (Cognis), DiaMin® (Diamalt), Lexein® (Inolex) and Crotein® (Croda).
[0185] Cationized protein hydrolysates can also be used, the underlying protein hydrolysate being derived from animal sources, for example collagen, milk, or keratin; from plants, for example wheat, maize, rice, potatoes, soybeans, or almonds; from marine life forms, for example fish or algal collagen; or from protein hydrolysates produced by biotechnology. The protein hydrolysates on which the cationic derivatives are based can be obtained from the corresponding proteins by chemical hydrolysis, in particular alkaline or acidic hydrolysis, by enzymatic hydrolysis, and / or by a combination of both types of hydrolysis. Protein hydrolysis generally yields a protein hydrolysate with a molecular weight distribution ranging from about 100 daltons to several thousand daltons.Such cationic protein hydrolysates, with an underlying protein content having a molecular weight of 100 to 25,000 daltons, preferably 250 to 5,000 daltons, are preferred. Quaternized amino acids and mixtures thereof are also understood to be cationic protein hydrolysates. The quaternization of protein hydrolysates or amino acids is often carried out using quaternary ammonium salts such as, for example, N,N-dimethyl-N-(n-alkyl)-N-(2-hydroxy-3-chloro-n-propyl)ammonium halides. Cationic protein hydrolysates can be further derived. Typical examples of cationic protein hydrolysates and their derivatives are... produits connus sous les dénominations INCI et disponibles dans le commerce : Coco-dimonium Hydroxypropyl Hydrolyzed Collagen, Cocodimonium Hydroxypropyl Hy-drolyzed Casein, Cocodimonium Hydroxypropyl Hydrolyzed Collagen, Cocodimonium Hydroxypropyl Hydrolyzed Hair Keratin, Cocodimonium Hydroxypropyl Hydrolyzed Keratin, Cocodimonium Hydroxypropyl Hydrolyzed Rice Protein, Cocodimonium Hydroxypropyl Hydrolyzed Silk, Cocodimonium Hydroxypropyl Hydrolyzed Soy Protein, Cocodimonium Hydroxypropyl Hydrolyzed Wheat Protein, Cocodimonium Hydroxypropyl Silk Amino Acids, Hydroxypropyl Arginine Lauryl / Myristyl Ether HCl, Hydroxypropyltrimonium Gelatin, Hydroxypropyltrimonium Hydrolyzed Casein, Hydroxypropyltrimonium Hydrolyzed Collagen, Hydroxypropyltrimonium Hydrolyzed Conchiolin Protein, Hydroxypropyltrimonium Hydrolyzed Keratin, Hydroxypropyltrimonium Hydrolyzed Rice Bran Protein, Hydroxypropyltrimonium Hydrolyzed Silk, Hydroxypropyltrimonium Hydrolyzed Soy Protein,Hydroxypropyl Hydrolyzed Vegetable Protein, Hydroxypropyltrimonium Hydrolyzed Wheat Protein, Hydroxypropyltrimonium Hydrolyzed Wheat Protein / Siloxysilicate, Laurdimonium Hydroxypropyl Hydrolyzed Soy Protein, Laurdimonium Hydroxypropyl Hydrolyzed Wheat Protein, Laurdimonium Hydroxypropyl Hydrolyzed Wheat Protein / Siloxysilicate, Lauryldimonium Hydroxypropyl Hydrolyzed Casein, Lauryldimonium Hydroxypropyl Hydrolyzed Collagen, Lauryldimonium Hydroxypropyl Hydrolyzed Keratin, Lauryldimonium Hydroxypropyl Hydrolyzed Silk, Lauryldimonium Hydroxypropyl Hydrolyzed Soy Protein, Steardimonium Hydroxypropyl Hydrolyzed Casein, Steardimonium Hydroxypropyl Hydrolyzed Collagen, Steardimonium Hydroxypropyl Hydrolyzed Keratin, Steardimonium Hydroxypropyl Hydrolyzed Rice Protein, Steardimonium Hydroxypropyl Hydrolyzed Silk, Steardimonium Hydroxypropyl Hydrolyzed Soy Protein, Steardimonium Hydroxypropyl Hydrolyzed Vegetable Protein, Steardimonium Hydroxypropyl Hydrolyzed Wheat Protein,Steartrimonium Hydroxyethyl Hydrolyzed Collagen, Quatemium-76 Hydrolyzed Collagen, Quatemium-79 Hydrolyzed Collagen, Quatemium-79 Hydrolyzed Keratin, Quaternium-79 Hydrolyzed Milk Protein, Quatemium-79 Hydrolyzed Silk, Quaternium-79 Hydrolyzed Soy Protein, Quatemium-79 Hydrolyzed Wheat Protein. ,
[0186] The weight proportion of the protein hydrolysate(s) in relation to the total weight of the powder compositions according to the invention is preferably 0 to 5% by weight, more preferably 0.01 to 3% by weight and in particular 0.05 to 2% by weight.
[0187] Suitable plant extracts are primarily extracts of green tea, oak bark, nettle, witch hazel, hops, henna, chamomile, burdock root, horsetail, hawthorn, linden flowers, almond, aloe vera, spruce needles, horse chestnut, date palm, cinnamon, sandalwood, juniper, coconut, mango, apricot, lime, wheat, kiwi, melon, orange, grapefruit, sage, rosemary, birch, mallow, valerian, meadowfoam, wild thyme, yarrow, thyme, lemon balm, bugrane, coltsfoot, marshmallow, meristem, ginseng, coffee, cocoa, moringa, ginger root and Ayurvedic plant extracts such as for example Aegle Marmelos (bilva), Cyperus Rotundus (nagarmotha), Emblica Of-ficinalis (Amalki), Morida Citrifolia (Ashyuka), Tinospora Cordifolia (guduchi), Santalum album, (chandana), Crocus Sativus (kumkuma), Cinnamonum Zeylanicum and Nelumbo Nucifera (kamala), sweet grasses such as wheat, barley, rye, oats, spelt, maize, various varieties of millet (seed millet, finger millet, branch millet as examples), sugarcane, ryegrass, meadow foxtail, tall oatgrass, bentgrass, meadow fescue, purple moor grass,bamboo, cottongrass, pennisetum, Andropogonodeae (Imperata cylindrica also called flammable grass or Cogon grass), buffalo grass, sparta, cynodon, eragrostides, Cymbopogon (lemongrass), Oryzeae (rice), Zizania (wild rice), oat, perennial oats, huulques, breezes, bluegrass, quackgrass and echinacea, in particular Echinacea angustifolia DC, Echinacea paradoxa (Norton), Echinacea simulata, E. atrorubens, E. tennesiensis, Echinacea strigosa (Mc Gregor), Echinacea laevigata, Echinacea purpurea (L.) Moench and Echinacea pallida (Nutt), all kinds of algae, coralline and kelp (such as for example the extract of Macrocystis Pyrifera), all kinds of wine and the pericarp of Litchi sinensis. ,
[0188] Suitable extracts may be obtained from the fruits, seeds, flowers, roots, leaves and / or bark of the aforementioned plants or from the whole of the plants (algae, kelp).
[0189] According to the invention, plant extracts can be used both in pure and diluted form. When used in diluted form, they generally contain about 2 to 80% by weight of the active substance and, as a solvent, the extraction agent or mixture of extraction agents used in their preparation. Suitable extraction agents are generally water and / or alcohols.
[0190] The plant extract(s) may be used in the powder compositions according to the invention preferably in total quantities of 0 to 1% by weight, preferably from 0.001 to 0.75% by weight and in particular from 0.01 to 0.5% by weight, the indication of quantity referring to the weight of the powder compositions.
[0191] Other active substances, adjuvants and additives, which may preferably be contained in the powder compositions according to the invention, are for example:
[0192] - vitamins, provitamins and vitamin precursors,
[0193] - abrasive substances,
[0194] - perfumes, possibly also in capsule form,
[0195] - UV filters,
[0196] - (natural) colorants intended to color the agent,
[0197] - active substances such as bisabolol and / or allantoin,
[0198] - complexing agents such as EDTA, NTA, [3-alanine-diacetic acid and phosphonic acids,
[0199] - antioxidants,
[0200] - pH adjusting agents such as citric acid and / or lactic acid,
[0201] - conservation agents,
[0202] - salts (NaCl).
[0203] An important advantage of the powder compositions according to the invention compared to commercially available concentrates is that it is not necessary to add free water to them, which results in an even smaller volume.
[0204] A small proportion of water may nevertheless be contained in the powder compositions according to the invention as a constituent of commercial products, but they are preferably substantially free of water.
[0205] According to the present invention, "substantially free" of water is understood to mean preferably a maximum water content of 5% by weight, more preferably 3% by weight and particularly preferably 1.5% by weight (relative to the total weight of the powder compositions according to the invention).
[0206] The invention also relates to a method for producing a powdered composition as described above, in which all the ingredients are mixed in a mixing apparatus for powdered cosmetic products and optionally sieved.
[0207] Optionally, the liquid raw materials contained in the powder composition can be simply dosed and mixed with the powder constituents or be sprayed to form the powder constituents.
[0208] This is advantageous because a solid cosmetic composition is thus available in powder form, and sieving ensures a uniform and pleasant grain. The further advantage of such a process is that it is possible to work at high temperatures without melting, which saves energy and is very gentle on the ingredients. This is particularly important when using minimally processed and largely natural ingredients that can offer benefits not obtainable with highly processed products.
[0209] An exciting new use of the powdered compositions according to the invention, combined with a particular experience, is packaging, for example, in a (paper) bag or a glass container. Besides the new sensory experience, this primarily offers the advantage of relatively rapid dissolution thanks to to a high surface area. Glass and paper packaging materials are highly recyclable and popular with environmentally conscious buyers, and their properties therefore correspond well to the properties of the powder-based cosmetic compositions described and claimed herein.
[0210] It is also possible to fill a crucible, for example made of glass, with the powdered compositions according to the invention. Because the resistance of said compositions is within a range that allows a portion to be manually taken, without tools, from a crucible intended for multiple uses. If the composition has been transformed into a foam in a crucible during its production, this provides a particularly interesting sensation.
[0211] The invention also relates to the use of a powdered composition as described above for the production of a ready-to-use, cosmetic, fluid cleaning agent by dissolving the powdered composition in water.
[0212] Such use of the powdered compositions according to the invention is particularly advantageous, because
[0213] - the mixing of the powdered composition with water can be carried out in any (recyclable) container, such as for example a glass or resealable plastic bottle,
[0214] - the user can freely determine the volume of the cleaning preparation usable produced (and, depending on the quantities of powder and water chosen, produce any quantity, from a single quantity to a stock of several liters),
[0215] - the rapid dissolution of the powder system in water ensures the availability simple and quick positioning of a ready-to-use liquid cleaning agent without the need for high shear, but possibly only by shaking or agitating lightly.
[0216] The invention also relates to a method for producing a ready-to-use, cosmetic, fluid cleaning agent, comprising the following steps:
[0217] - making available a powdered composition described above,
[0218] - mixing the powdered composition described above with water in a weight ratio of 1 to 12 in a suitable container,
[0219] - optionally, shaking or stirring the resulting mixture until homogeneous.
[0220] Fluid, cosmetic and ready-to-use cleaning agents obtained using said process have an optimal viscosity for common use in the shower.
[0221] Optimal viscosity is preferably understood to be a viscosity in the range of 2,000 to 11,000 mPas, more preferably from 2,500 to 10,000 mPas and in particular from 3,000 to 9,000 mPas (measured at 20 °C with a Haake VT 550 rotary viscometer, MV measuring system).
[0222] The invention also relates to a cosmetic method for cleansing the human body and / or hair, in which a ready-to-use, cosmetic, fluid cleansing agent obtained according to the method described above is distributed over the part of the body to be cleansed and rinsed off with water after an exposure period of 5 seconds to 15 minutes. This method makes the benefits described above perceptible to a user and thus constitutes an enhancement not only for hygiene and personal care, but also a sensory enrichment.
[0223] Examples:
[0224] The basic exemplary powder compositions are shown in Tables 1 to 8 below (compositions Z1 to Z33). Quantity indications refer (unless otherwise stated) to [% by weight]:
[0225] [Tables 1] Ingredient Z1 Z2 Z3 Z4 one or more surfactants 10-65 15-62.5 20-60 25-55 mixture of thickeners possibly starch or hydrophobically modified starch fraction starch hydrolysis product natural polymer other than i) and ii) 10-40 5-30 1-20 15-37.5 10-30 2-15 17.5-35 12.5-25 2.5-12 20-30 15-20 3-10 possibly other adjuvants and additives up to 100 up to 100 up to 100 up to 100
[0226] [Tables2] Ingredient Z5 Z6 Z7 Z8 one or more anionic surfactants 10-65 15-62.5 20-60 30-55 mixture of thickeners possibly starch or hydrophobically modified starch fraction starch hydrolysis product natural polymer other than i) and ii) 10-40 5-30 1-20 15-37.5 10-30 2-15 17.5-35 12.5-25 2.5-12 20-30 15-20 3-10 possibly other adjuvants and additives up to 100 up to 100 up to 100 up to 100
[0227] [Tables3] Ingredient Z9 Z10 Z11 Z12 one or more anionic surfactants 10-65 15-62.5 20-60 30-55 amphoteric and / or non-ionic surfactant 0-10 0-10 0-10 0-10 thickener mixture Hydroxypropyl Starch Phosphate starch hydrolysis product natural polymer other than i) and ii) 10-40 5-30 1-20 15-35 10-30 2-15 17.5-35 12.5-25 2.5-12 20-30 15-20 3-10 possibly other adjuvants and additives up to 100 up to 100 up to 100 up to 100
[0228] [Tables4] Ingredient Z13 Z14 Z15 Z16 one or more anionic surfactants 10-65 15-62.5 20-60 30-55 amphoteric and / or non-ionic surfactant 0-10 0-10 0-10 0-10 thickener mixture Oryza Sativa Starch starch hydrolysis product natural polymer other than i) and ii) 10-40 5-30 1-20 15-35 10-30 2-15 17.5-35 12.5-25 2.5-12 20-30 15-20 3-10 possibly other adjuvants and additives up to 100 up to 100 up to 100 up to 100
[0229] [Tables5] Ingredient Z17 Z18 Z19 Z20 one or more anionic surfactants 10-65 15-62.5 20-60 30-55 amphoteric and / or non-ionic surfactant 0-10 0-10 0-10 0-10 mixture of thickeners possibly starch or hydrophobically modified starch fraction maltodextrin natural polymer other than i) and ii) 10-40 5-30 1-20 15-35 10-30 2-15 17.5-35 12.5-25 2.5-12 20-30 15-20 3-10 possibly other adjuvants and additives up to 100 up to 100 up to 100 up to 100
[0230] [Tableauxô] Ingredient Z21 Z22 Z23 Z24 one or more anionic surfactants 10-65 15-62.5 20-60 30-55 amphoteric and / or non-ionic surfactant 0-10 0-10 0-10 0-10 mixture of thickeners possibly starch or hydrophobically modified starch fraction starch hydrolysis product xanthan gum and / or guar gum and / or Caesalpinia Spinosa gum 10-40 5-30 1-20 15-35 10-30 2-15 17.5-35 12.5-25 2.5-12 20-30 15-20 3-10 possibly other adjuvants and additives up to 100 up to 100 up to 1.00 up to 1.00
[0231] [Tables?] Ingredient Z25 Z26 Z27 Z28 one or more anionic surfactants 10-65 15-62.5 20-60 30-55 amphoteric and / or non-ionic surfactant 0-10 0-10 0-10 0-10 mixture of thickeners possibly starch or hydrophobically modified starch fraction starch hydrolysis product natural polymer other than i) and ii) 10-40 5-30 1-20 15-35 10-30 2-15 17.5-35 12.5-25 2.5-12 20-30 15-20 3-10 cationic polymer 0-7.5 0.01-7 0.05-6 0.1-5 possibly other adjuvants and additives up to 100 up to 100 up to 100 up to 100
[0232] [Tables8] Ingredients Z29 Z30 Z31 Z32 Z33 Sodium Lauroyl Methyl Isethionate 50 48 Sodium Cocoyl Isethionate 48 48 48 Hydroxypropyl Starch Phosphate 23 25 25 Oryza Sativa (Rice) Starch 25 25 Maltodextrin 15 17 17 17 17 Xanthan Gum 5 5 5 5 Caesalpinia Spinosa (Tara) Gum 5 Guar Hydroxypropyltrimonium Chloride 3 3 3 3 Perfume, preservative, pH adjuster and possibly water up to 1.00 up to 1.00 up to 1.00 up to 1.00 up to 1.00
[0233] The constituents of composition Z29 have been mixed to form a powder. 10 g of the powdered composition Z29 were mixed with water in a weight ratio of 1:10 to 1:15 in a suitable container. A cleaning agent The fluid, cosmetic and ready-to-use product was produced in just 30 seconds by gentle stirring and has a viscosity in the range of 2,000 to 11,000 mPas (measured at 20°C with a Haake VT 550 rotary viscometer, MV measuring system) and can generally be used in the shower.
[0234] The fluid cleansing agent thus obtained from the powder composition Z29 has excellent foaming properties (high quantities of a stable and creamy foam), the foam spreads very well on the skin and is rinsed from the skin and leaves a pleasant feeling of freshness, softness and comfort.
Claims
Demands
1. Powdered composition for cosmetic cleansing of skin or hair, containing, in relation to the total weight of the powder, a) 10 to 65% by weight of at least one surfactant, b) a mixture of thickeners, comprising i) 10 to 40% by weight of at least one starch or a starch fraction, possibly hydrophobically modified, ii) 5 to 30% by weight of at least one starch hydrolysis product and iii) 1 to 20% by weight of at least one natural polymer other than i) and ii).
2. Powdered composition according to any one of the preceding claims, containing at least one amino acid-based surfactant, an isethionate-containing surfactant, a sulfosuccinate-containing surfactant, an olefin sulfonate or mixtures thereof.
3. Powdered composition according to any one of the preceding claims, containing as a thickener b)i) starch or a starch fraction of maize, potato, rice, wheat, tapioca, hydroxypropyl starch phosphate, dihydroxypropyl starch phosphate, distarch phosphate or mixtures thereof.
4. Powdered composition according to claim 3, containing modified starch known by the INCI name Hydroxypropyl Starch Phosphate in a weight proportion of 10 to 40% by weight relative to the total weight of the powder.
5. Powdered composition according to claim 3, containing starch known by the INCI name Oryza Sativa Starch in a weight proportion of 10 to 40% by weight relative to the total weight of the powder.
6. Powdered composition according to any one of the preceding claims, containing as a thickener b)ii) maltodextrin in a weight proportion of 10 to 30% by weight relative to the total weight of the powder.
7. Powdered composition according to any one of the preceding claims, containing as a thickener b)iii) natural polymers of the gum group, polysaccharides, galactomannans or mixtures thereof.
8. Powdered composition according to claim 7, containing as a thickener b)iii) xanthan gum, Cae- gum salpinia spinosa or their mixtures in a weight proportion of 1 to 20% by weight relative to the total weight of the powder.
9. Powdered composition according to any one of the preceding claims, containing a cationic polysaccharide polymer c) in a weight proportion of 0 to 7.5% by weight relative to the total weight of the powder.
10. A process for producing a ready-to-use, cosmetic, fluid cleaning agent, comprising the following steps: - making available a powder composition according to any one of claims 1 to 9, - mixing the powder composition with water in a weight ratio of 1:10 to 1:15 in a suitable container, - optionally, shaking or stirring the resulting mixture until homogeneous.