Process for the production of trifluoroethylene

Abstract

The present invention relates to a process for producing trifluoroethylene in a reactor provided with a fixed catalytic bed comprising a catalyst, said process comprising a step a) of reacting a composition A comprising chlorotrifluoroethylene with hydrogen in the presence of a catalyst and in the gas phase to produce a stream B comprising trifluoroethylene, characterized in that said composition A also comprises at least one of the additional compounds C1 chosen from the group consisting of 1,1,1-trifluoroethane, 1,1,1,2-tetrafluoroethane, hexafluorocyclobutene, fluoroethane, 2-chloro-1,1,1-trifluoroethane, 1,2-dichlorohexafluorocyclobutane. The present invention also relates to a chlorotrifluoroethylene composition.

Description

Title of the invention: Process for the production of trifluoroethylene Technical field of the invention

[0001] The present invention relates to a process for producing hydrofluoroolefins. In particular, the present invention relates to a process for producing trifluoroethylene (HFO-1123 or VF3) by hydrogenolysis of chlorotrifluoroethylene. The present invention also relates to a composition comprising chlorotrifluoroethylene. Technological background of the invention

[0002] Fluorinated olefins, such as VF3, are known and are used as monomers or co-monomers for the manufacture of fluorocarbon polymers having remarkable characteristics, in particular excellent chemical resistance and good thermal resistance.

[0003] Trifluoroethylene is a gas under normal conditions of pressure and temperature. The main risks associated with the use of this product concern its flammability, its propensity for self-polymerization when not stabilized, its explosiveness due to its chemical instability and its supposed sensitivity to peroxidation, by analogy with other halogenated olefins. Trifluoroethylene has the particularity of being extremely flammable, with a lower explosive limit (LEL) of approximately 10% and an upper explosive limit (UEL) of approximately 30%. The major danger, however, is associated with the propensity of VF3 to decompose violently and explosively under certain pressure conditions in the presence of an energy source, even in the absence of oxygen.

[0004] Given the above main risks, the synthesis and storage of VF3 pose particular problems and impose strict safety rules throughout these processes. A known route for the preparation of trifluoroethylene uses chlorotrifluoroethylene (CTFE) and hydrogen as starting products in the presence of a catalyst and in the gas phase.

[0005] WO 2013 / 128102 discloses a process for producing trifluoroethylene by hydrogenolysis of CTFE in the gas phase and in the presence of a catalyst based on a group VIII metal at atmospheric pressure and at low temperatures.

[0006] EP 2 993 213 discloses a process for producing trifluoroethylene. This can be obtained by hydrogenolysis of chlorotrifluoroethylene or by thermal decomposition of chlorodifluoromethane and chlorofluoromethane. The production process involves the implementation of a distillation step at a pressure of 10 barg and by which the trifluoroethylene is recovered by side withdrawal. The implementation of high-pressure distillation requires the establishment of operating conditions special laboratories given the explosive nature of trifluoroethylene above 3 bara.

[0007] There is therefore a need to provide a simpler and safer process for producing trifluoroethylene while maintaining high yields and selectivities. Summary of the invention

[0008] According to a first aspect, the present invention provides a process for producing trifluoroethylene in a reactor provided with a fixed catalytic bed comprising a catalyst, said process comprising a step a) of reacting a composition A comprising chlorotrifluoroethylene with hydrogen in the presence of a catalyst and in the gas phase to produce a stream B comprising trifluoroethylene, characterized in that said composition A also comprises at least one of the additional compounds Cl chosen from the group consisting of 1,1,1-trifluoroethane, 1,1,1,2-tetrafluoroethane, hexafluorocyclobutene, fluoroethane, 2-chloro-1,1,1-trifluoroethane, 1,2-dichloro-hexafluorocyclobutane.

[0009] Surprisingly, it has been observed that the productivity of trifluoroethylene was increased in the presence of the additional Cl compounds. The presence of these compounds in small quantities in addition to chlorotrifluoroethylene makes it possible to improve the trifluoroethylene production process. The present invention demonstrates that it is not necessary to have high purity chlorotrifluoroethylene to achieve significant productivities. This makes it possible to simplify the production process and limit its overall cost.

[0010] According to a preferred embodiment, the total mass content of said at least one of the additional compounds Cl is less than 15% based on the total weight of said composition A, preferably less than 10% based on the total weight of said composition A, in particular less than 5% based on the total weight of said composition A.

[0011] According to a preferred embodiment, said composition A comprises at least 80% by weight of chlorotrifluoroethylene based on the total weight of said composition A, preferably at least 95% by weight of chlorotrifluoroethylene based on the total weight of said composition A, in particular at least 90% by weight of chlorotrifluoroethylene based on the total weight of said composition A.

[0012] According to a preferred embodiment, said composition A also comprises trifluoroethylene, preferably in a mass content of less than 5% based on the total weight of said composition A.

[0013] According to a preferred embodiment, said composition A also comprises at least one of the additional compounds C2 selected from the group consisting of 1,1,2-trifluoroethane, 1-chloro-1,1,2-trifluoroethane, 1-chloro-2,2-difluoroethylene, E / Z-1 -chloro-1,2-difluoroethylene, 1 -chloro-1,2,2-trifluoroethane.

[0014] According to a preferred embodiment, the mass content of said at least one of the additional compounds C2 is less than 5% based on the total weight of said composition A.

[0015] According to a preferred embodiment, the catalyst comprises palladium supported on alpha alumina.

[0016] According to a preferred embodiment, the chlorotrifluoroethylene and the hydrogen are in anhydrous form.

[0017] According to a preferred embodiment, said method comprises a step i') of activating the catalyst, carried out prior to step a), by bringing it into contact with a gaseous flow comprising a reducing agent, an inert gas or a mixture thereof.

[0018] According to a preferred embodiment, during said step i'):

[0019] - the temperature of the catalytic bed is increased from a temperature T1 to a temperature T2 higher than T1 with a temperature gradient of less than 0.5°C / min; or - the temperature of the catalytic bed is increased from a temperature Tl to a temperature T2 higher than Tl in stages.

[0020] According to a second aspect, the present invention provides a composition comprising at least 80% by weight of chlorotrifluoroethylene and at least one of the additional compounds selected from the group consisting of 1,1,1-trifluoroethane, 1,1,1,2-tetrafluoroethane, hexafluorocyclobutene, fluoroethane, 2-chloro-1,1,1-trifluoroethane, 1,2-dichloro-hexafluorocyclobutane; the total mass content of said at least one of the additional compounds is less than 15% based on the total weight of said composition. Detailed description of the invention

[0021] The present invention relates to a process for producing trifluoroethylene comprising a step of hydrogenolysis reaction of chlorotrifluoroethylene (CTFE) with hydrogen in the gas phase and preferably in the presence of a catalyst.

[0022] According to a preferred embodiment, the method according to the invention described in the present application is implemented continuously.

[0023] According to a preferred embodiment, in the process described in the present application, the hydrogen is in anhydrous form.

[0024] According to a preferred embodiment, in the process described in the present application, the chlorotrifluoroethylene is in anhydrous form.

[0025] The implementation of the methods according to the invention in the presence of hydrogen and / or anhydrous chlorotrifluoroethylene makes it possible to effectively increase the lifetime of the catalyst and thus the overall productivity of the process. The term anhydrous refers to a water mass content of less than 1000 ppm, advantageously 500 ppm, preferably less than 200 ppm, in particular less than 100 ppm based on the total weight of the compound considered. Catalyst

[0026] Preferably, the catalyst is based on a metal from columns 8 to 10 of the periodic table of elements. In particular, the catalyst is based on a metal selected from the group consisting of Pd, Pt, Rh, and Ru; preferably palladium.

[0027] Preferably, the catalyst is supported. The support is preferably selected from the group consisting of activated carbon, an aluminum-based support, calcium carbonate, and graphite. Preferably, the support is aluminum-based. In particular, the support is alumina. The alumina may be alpha alumina. Preferably, the alumina comprises at least 90% alpha alumina. It has been observed that the conversion of the hydrogenolysis reaction is improved when the alumina is an alpha alumina. Thus, the catalyst is more particularly palladium supported on alumina, advantageously palladium supported on an alumina comprising at least 90% alpha alumina, preferably palladium supported on an alpha alumina.

[0028] Preferably, the palladium represents from 0.01% to 5% by weight based on the total weight of the catalyst, preferably from 0.1% to 2% by weight based on the total weight of the catalyst.

[0029] In particular, said catalyst comprises from 0.01% to 5% by weight of palladium supported on alumina, preferably the alumina comprises at least 90% alpha alumina, more preferably the alumina is an alpha alumina. Catalyst activation

[0030] Said catalyst is preferably activated before its use in step a). Preferably, the activation of the catalyst is carried out at high temperature and in the presence of a reducing agent, an inert gas or a mixture thereof.

[0031] According to a particular embodiment, the reducing agent is chosen from the group consisting of hydrogen, carbon monoxide, nitrogen monoxide, formaldehyde, C1-C6 alkanes and C1-C10 hydrohalocarbons, or a mixture thereof; preferably hydrogen or a C1-C10 hydrohalocarbon, or a mixture thereof; in particular hydrogen, chlorotrifluoroethylene, trifluoroethylene, chlorotrifluoroethane, trifluoroethane or difluoroethane or a mixture thereof.

[0032] The inert gas may be nitrogen or argon; preferably nitrogen.

[0033] Preferably, the activation of the catalyst is carried out at a temperature between 100°C and 400°C, in particular at a temperature between 150°C and 350°C. In particular, the activation of the catalyst is carried out at a temperature between 100°C and 400°C, in particular at a temperature between 150°C and 350°C, in the presence of hydrogen as a reducing agent.

[0034] Preferably, during step i'), the temperature of the catalytic bed is increased from a temperature T1 to a temperature T2. In particular, during said step i'), the temperature of the catalytic bed is increased from a temperature T1 to a temperature T2 higher than T1 with a temperature gradient of less than 0.5°C / min. The temperature gradient used makes it possible to avoid early degradation of the catalyst and thus to allow a better yield or better productivity of the hydrogenolysis reaction. In particular, the temperature is increased with a temperature gradient of less than 0.45°C / min or less than 0.40°C / min, or less than 0.35°C / min, or less than 0.30°C / min, or less than 0.25°C / min, or less than 0.20°C / min, or less than 0.15°C / min, or less than 0.10°C / min, or less than 0.05°C / min. The temperature Tl represents the initial temperature of the activation step. This temperature Tl may be room temperature.Alternatively, the temperature T1 may be between 0°C and 150°C, advantageously between 0°C and 120°C, preferably between 0°C and 100°C, more preferably between 10°C and 100°C, in particular between 20°C and 100°C, more particularly between 20°C and 75°C, preferably between 20°C and 50°C. The temperature T2 represents the temperature to be reached during the activation phase. The temperature T2 is advantageously between 150°C and 400°C, preferably between 155°C and 375°C, more preferably between 160°C and 350°C, in particular between 165°C and 325°C, more particularly between 170°C and 320°C, preferably between 175°C and 310°C, more preferably between 180°C and 300°C. According to a preferred embodiment, the temperature T2 is advantageously between 185°C and 290°C, preferably between 190°C and 280°C, more preferably between 195°C and 270°C, in particular between 200°C and 260°C.The temperature T2 can be maintained from 5 min to 200 h, preferably from 10 min to 100 h, in particular from 15 min to 75 h, more particularly from 30 min to 50 h, preferably from 1 h to 25 h. The temperature T2 can be maintained from 5 min to 24 h, preferably from 10 min to 20 h, in particular from 15 min to 15 h, more particularly from 30 min to 10 h, preferably from 1 h to 10 h.

[0035] Preferably, the gas stream used during step i') does not comprise oxygen. Preferably, step i') may be carried out with an amount of reducing agent greater than 0.01 mol per gram of catalyst, preferably greater than 0.05 per gram of catalyst. In particular, step i') may be carried out with an amount of reducing agent of between 0.01 and 10 mol per gram of catalyst, preferably between 0.05 and 5 mol per gram of catalyst.

[0036] According to another embodiment, during step i'), the temperature of the bed catalytic temperature is increased from a temperature T1 to a temperature T2 in steps. Activating the catalyst in steps makes it possible to improve the performance of the catalyst. The implementation of steps makes it possible to avoid degradation of the catalyst. It has also been observed that the properties of the catalyst are further improved if the temperature rise between the steps is gradual and relatively slow compared to the usual conditions for activating a catalyst. Thus, preferably, in step i'), between two steps, the temperature is increased with a temperature gradient of less than 0.5°C / min. The temperature gradient implemented between two steps makes it possible to avoid premature degradation of the catalyst and thus to allow a better yield or better productivity of the hydrogenolysis reaction.In particular, the temperature is increased with a temperature gradient less than 0.45°C / min or less than 0.40°C / min, or less than 0.35°C / min, or less than 0.30°C / min, or less than 0.25°C / min, or less than 0.20°C / min, or less than 0.15°C / min, or less than 0.10°C / min, or less than 0.05°C / min. The temperature Tl represents the initial temperature of the activation step. This temperature Tl may be room temperature. Alternatively, the temperature T1 may be between 0°C and 150°C, advantageously between 0°C and 120°C, preferably between 0°C and 100°C, more preferably between 10°C and 100°C, in particular between 20°C and 100°C, more particularly between 20°C and 75°C, preferably between 20°C and 50°C. The temperature T2 represents the temperature to be reached during the activation phase.The temperature T2 is advantageously between 150°C and 400°C, preferably between 155°C and 375°C, more preferably between 160°C and 350°C, in particular between 165°C and 325°C, more particularly between 170°C and 320°C, preferably between 175°C and 310°C, more preferably between 180°C and 300°C. According to a preferred embodiment, the temperature T2 is advantageously between 185°C and 290°C, preferably between 190°C and 280°C, more preferably between 195°C and 270°C, in particular between 200°C and 260°C. The temperature T2 can be maintained from 5 min to 200 h, preferably from 10 min to 100 h, in particular from 15 min to 75 h, more particularly from 30 min to 50 h, preferably from 1 h to 25 h. The temperature T2 can be maintained from 5 min to 24 h, preferably from 10 min to 20 h, in particular from 15 min to 15 h, more particularly from 30 min to 10 h, preferably from 1 h to 10 h.Step i') of activating the catalyst contains at least one step between the temperature T1 and the temperature T2. Step i') of activating the catalyst may comprise several steps between the temperature T1 and the temperature T2. Preferably, step i') comprises at least one step at a temperature T1a of between 90 and 120°C. The presence of a step between 90°C and 120°C is preferred to increase the lifetime of the catalyst. Step i') may also comprise one or more steps between the temperature T1 and T1a and / or between the temperature T1a and T1a. temperature T1a and T2. Preferably, each stage between temperature T1 and temperature T2 may last between 5 min and 200 h, preferably between 10 min and 100 h, in particular between 15 min and 75 h, more particularly between 30 min and 50 h. In particular, each stage between temperature T1 and temperature T2 may last between 5 min and 24 h, preferably between 10 min and 20 h, in particular between 15 min and 15 h, more particularly between 30 min and 10 h. In particular, the stage at temperature T1a may last between 5 min and 200 h, preferably between 10 min and 100 h, in particular between 15 min and 75 h, more particularly between 30 min and 50 h. Preferably, the temperature plateau Tla can last between 5 min and 24 h, preferably between 10 min and 20 h, in particular between 15 min and 15 h, more particularly between 30 min and 10 h.

[0037] The gas stream used during step i') may be different over time. For example, the gas stream may comprise an inert gas between two stages and for example comprise a reducing agent between two other stages. In particular, the gas stream comprises an inert gas when step i') is carried out between temperature T1 and T1a and the gas stream comprises a reducing agent, preferably hydrogen or C1-C10 hydrohalocarbons as defined above, when step i') is carried out between temperature T1a and T2. Thus, the gas stream used during step i') is modified during the stage carried out at temperature T1a. Alternatively, the gas stream may comprise a reducing agent such as hydrogen or C1-C10 hydrohalocarbons as defined above throughout step i'), optionally mixed with an inert gas such as nitrogen.It has been observed that the use of a reducing agent such as hydrogen or C 1 -C 10 hydrohalocarbons as defined above, optionally in a mixture with an inert gas such as nitrogen, during the temperature rise between the temperature T1a of said stage and the temperature T2 represents an additional advantage in terms of productivity. As mentioned above, the temperature T2 is maintained for a certain period. During this stage at the temperature T2, the gas flow can be modified. Thus, the gas flow during the stage at the temperature T2 may comprise hydrogen or a C 1 -C 10 hydrohalocarbon as defined above; in particular the gas flow during the stage at the temperature T2 may comprise hydrogen, chlorotrifluoroethylene, trifluoroethane, trifluoroethylene, chlorotrifluoroethane or difluoroethane.Preferably, step i') can be carried out with an amount of reducing agent greater than 0.01 per gram of catalyst, preferably greater than 0.05 per gram of catalyst. In particular, step i') can be carried out with an amount of reducing agent of between 0.01 and 10 mol per gram of catalyst, preferably between 0.05 and 5 mol per gram of catalyst.

[0038] According to another embodiment, the catalyst activation step i') comprises bringing said catalyst into contact with a gaseous stream which comprises chlorotrifluo- ethylene, and optionally hydrogen. It has been noted that chlorotrifluoroethylene (CTFE) can activate the catalyst, particularly when hydrogen is also present. This allows for an improvement in the trifluoroethylene production process. Activation in the presence of CTFE allows the catalyst to be activated at a lower temperature and therefore provides a less energy-intensive process. The process is further simplified since the reducing agent during activation is also one of the reactants for the subsequent reaction. Preferably, in this embodiment, step i') is carried out at a temperature T2' below 100°C. This temperature T2' can be reached from a temperature T1' using a low temperature gradient.Thus, during said step i'), the temperature of the catalytic bed is increased from a temperature T1' to a temperature T2' higher than T1', preferably the temperature of the catalytic bed is increased from a temperature T1' to a temperature T2' higher than T1' with a temperature gradient of less than 0.5°C / min. The temperature gradient implemented makes it possible to avoid early degradation of the catalyst and thus to allow a better yield or better productivity of the hydrogenolysis reaction. In particular, the temperature is increased with a temperature gradient less than 0.45°C / min or less than 0.40°C / min, or less than 0.35°C / min, or less than 0.30°C / min, or less than 0.25°C / min, or less than 0.20°C / min, or less than 0.15°C / min, or less than 0.10°C / min, or less than 0.05°C / min.

[0039] Preferably, the temperature of the catalytic bed is increased by increasing the contact time calculated as the ratio between the volume, in liters, of catalyst and the total flow rate of said gas flow, in normal liters per second, at the inlet of the reactor. The contact time is between 1 and 60 seconds, preferably between 5 and 45 seconds, in particular between 10 and 30 seconds, more particularly between 15 and 25 seconds. The temperature T1' may be between 0°C and 50°C, advantageously between 10°C and 50°C, preferably between 20°C and 50°C. Preferably, the temperature T2' is lower than the temperature T3 at which step a) is carried out. The temperature T3 is preferably between 100°C and 180°C, more preferably between 100°C and 160°C, in particular between 120°C and 160°C. Catalyst regeneration

[0040] Said catalyst used in the present process can be regenerated. This regeneration step can be carried out in a temperature range of the catalytic bed between 90°C and 450°C. Preferably, the regeneration step is carried out in the presence of hydrogen. The implementation of the regeneration step makes it possible to improve the yield of the reaction compared to the initial yield before regeneration.

[0041] According to a preferred embodiment, the regeneration step can be implemented at a catalyst bed temperature of 90°C to 300°C, preferably at a catalyst bed temperature of 90°C to 250°C, more preferably from 90°C to 200°C, in particular from 90°C to 175°C, more particularly at a catalyst bed temperature of 90°C to 150°C. In particular, carrying out the regeneration step at a low temperature, for example from 90°C to 200°C or from 90°C to 175°C or from 90°C to 150°C, allows the desorption of compounds harmful to the activity of the catalyst and / or to limit phase transitions modifying the structure of the catalyst.

[0042] According to another preferred embodiment, the regeneration step can be carried out at a temperature of the catalytic bed greater than 200°C, advantageously greater than 230°C, preferably greater than 250°C, in particular greater than 300°C. The regeneration step can be carried out periodically depending on the productivity or the conversion obtained in step a). The regeneration step may advantageously be carried out at a temperature of the catalytic bed of between 200°C and 300°C, preferably between 205°C and 295°C, more preferably between 210°C and 290°C, in particular between 215°C and 290°C, more particularly between 220°C and 285°C, preferably between 225°C and 280°C, more preferably between 230°C and 280°C. Alternatively, the regeneration step may be carried out at a temperature of between 300°C and 450°C, preferably between 300°C and 400°C.The regenerated catalyst can be reused in step a) of the present process. Hydrogenolysis reaction.

[0043] The present invention comprises, as mentioned above, a hydrogenolysis reaction step of a composition A comprising chlorotrifluoroethylene with hydrogen to produce a stream comprising trifluoroethylene. The hydrogenolysis step is carried out in the presence of a catalyst and in the gas phase. Preferably, the hydrogenolysis step is carried out in the presence of a previously activated catalyst and in the gas phase. The hydrogenolysis step consists of simultaneously introducing hydrogen, CTFE and optionally an inert gas, such as nitrogen, into the gas phase and in the presence of said catalyst, preferably activated.

[0044] Preferably, said step a) is carried out at a fixed catalytic bed temperature of between 50°C and 250°C. Said step a) may be carried out at a fixed catalytic bed temperature of between 50°C and 240°C, advantageously between 50°C and 230°C, preferably between 50°C and 220°C, more preferably between 50°C and 210°C, in particular between 50°C and 200°C. Said step a) may also be carried out at a fixed catalytic bed temperature of between 60°C and 250°C, advantageously between 70°C and 250°C, preferably between 80°C and 250°C, more preferably between 90°C and 250°C, in particular between 100°C and 250°C, more particularly between 120°C and 250°C. Said step a) may also be carried out at a fixed catalytic bed temperature of between 60°C and 240°C, advantageously between 70°C and 230°C, preferably between 80°C and 220°C, more preferably between 90°C and 210°C, in particular between 100°C and 200°C, more particularly between 100°C and 180°C, preferably between 100°C and 160°C, particularly preferably between 120°C and 160°C.

[0045] The H2 / CTFE molar ratio is between 0.5 / 1 to 2 / 1 and preferably between 1 / 1 to 1.2 / 1. If an inert gas such as nitrogen is present in step a), the nitrogen / H2 molar ratio is between 0 / 1 to 2 / 1 and preferably between 0 / 1 to 1 / 1.

[0046] Step a) is preferably carried out at a pressure of 0.05 MPa to 1.1 MPa, more preferably of 0.05 MPa to 0.5 MPa, in particular at atmospheric pressure.

[0047] The contact time calculated as the ratio between the volume, in liters, of catalyst and the total flow rate of the gas mixture, in normal liters per second, at the inlet of the reactor, is between 1 and 60 seconds, preferably between 5 and 45 seconds, in particular between 10 and 30 seconds, more particularly between 15 and 25 seconds.

[0048] According to the present invention, said composition A also comprises at least one of the additional compounds Cl chosen from the group consisting of 1,1,1-trifluoroethane, 1,1,1,2-tetrafluoroethane, hexafluorocyclobutene, fluoroethane, 2-chloro-1,1,1-trifluoroethane, 1,2-dichlorohexafluorocyclobutane.

[0049] Said composition A may comprise one or more of the additional compounds Cl. Said composition A may comprise one, two, three, four, five or all of the additional compounds Cl.

[0050] Advantageously, the total mass content of said at least one of the additional compounds Cl is less than 15% based on the total weight of said composition A. Preferably, the total mass content of said at least one of the additional compounds Cl is less than 10%, more preferably less than 5%, in particular less than 2%, more particularly less than 1%.

[0051] Advantageously, the total mass content of said at least one of the additional compounds Cl is greater than 1 ppm based on the total weight of said composition A. Preferably, the total mass content of said at least one of the additional compounds Cl is greater than 5 ppm, more preferably greater than 10 ppm, in particular greater than 20 ppm, more particularly greater than 50 ppm, preferably greater than 100 ppm based on the total weight of said composition A.

[0052] According to a preferred embodiment, composition A comprises 1,1,1-trifluoroethane and the total mass content of 1,1,1-trifluoroethane is less than 5000 ppm, advantageously less than 2500 ppm, preferably less than 1000 ppm, more preferably less than 750 ppm based on the total weight of said composition A. When it is contained in the composition, the total mass content of 1,1,1-trifluoroethane is greater than 1 ppm, advantageously greater than 5 ppm, preferably greater than 10 ppm, more preferably greater than 20 ppm, in particular greater than 50 ppm, more particularly greater than 100 ppm based on the total weight of said composition A.

[0053] According to a preferred embodiment, composition A comprises 1,1,1,2-tetrafluoroethane and the total mass content of 1,1,1,2-tetrafluoroethane is less than 1000 ppm, advantageously less than 750 ppm, preferably less than 500 ppm, more preferably less than 250 ppm, in particular less than 100 ppm based on the total weight of said composition A. When it is contained in the composition, the total mass content of 1,1,1,2-tetrafluoroethane is greater than 1 ppm, advantageously greater than 5 ppm, preferably greater than 10 ppm, more preferably greater than 20 ppm based on the total weight of said composition A.

[0054] According to a preferred embodiment, composition A comprises hexafluorocyclobutene and the total mass content of hexafluorocyclobutene is less than 1%, advantageously less than 7500 ppm, preferably less than 5000 ppm, more preferably less than 2500 ppm, in particular less than 1000 ppm based on the total weight of said composition A. When it is contained in the composition, the total mass content of hexafluorocyclobutene is greater than 1 ppm, advantageously greater than 5 ppm, preferably greater than 10 ppm, more preferably greater than 20 ppm, in particular greater than 50 ppm, more particularly greater than 100 ppm based on the total weight of said composition A.

[0055] According to a preferred embodiment, composition A comprises fluoroethane and the total mass content of fluoroethane is less than 100 ppm, advantageously less than 75 ppm, preferably less than 50 ppm, more preferably less than 25 ppm, in particular less than 10 ppm based on the total weight of said composition A. When it is contained in the composition, the total mass content of fluoroethane is greater than 0.1 ppm, advantageously greater than 0.5 ppm, preferably greater than 1 ppm based on the total weight of said composition A.

[0056] According to a preferred embodiment, composition A comprises 2-chloro-1,1,1-trifluoroethane and the total mass content of 2-chloro-1,1,1-trifluoroethane is less than 1%, advantageously less than 7500 ppm, preferably less than 5000 ppm, more preferably less than 2500 ppm, in particular less than 1000 ppm based on the total weight of said composition A. When it is contained in the composition, the total mass content of 2-chloro-1,1,1-trifluoroethane is greater than 1 ppm, advantageously greater than 5 ppm, preferably greater than 10 ppm, more preferably greater than 20 ppm, in particular greater than 50 ppm, more particularly greater than 100 ppm based on the total weight of said composition A.

[0057] According to a preferred embodiment, composition A comprises the 1,2-Dichlorohexafluorocyclobutane. 1,2-Dichlorohexafluorocyclobutane can exist as two diastereomers. The term "1,2-Dichlorohexafluorocyclobutane" refers to both diastereomers. Preferably, the total mass content of 1,2-dichlorohexafluorocyclobutane is less than 15%, advantageously less than 10%, preferably less than 5%, in particular less than 1% based on the total weight of said composition A. According to a preferred embodiment, the total mass content of 1,2-dichlorohexafluorocyclobutane is less than 5000 ppm, advantageously less than 1000 ppm, preferably less than 500 ppm, more preferably less than 250 ppm, in particular less than 100 ppm based on the total weight of said composition A. When it is contained in the composition, the total mass content of 1,2-dichlorohexafluorocyclobutane is greater than 1 ppm, advantageously greater than 5 ppm, preferably greater than 10 ppm, more preferably greater than 20 ppm based on the total weight of said composition A.

[0058] According to a preferred embodiment, said composition A comprises at least 80% by weight of chlorotrifluoroethylene based on the total weight of said composition A, advantageously at least 82% by weight, preferably at least 84% by weight, more preferably at least 86% by weight, in particular at least 88% by weight, more particularly at least 90%, preferably at least 92% by weight of chlorotrifluoroethylene based on the total weight of said composition A.

[0059] Said composition A may also comprise trifluoroethylene, preferably in a mass content of less than 5%, preferably less than 4.5%, in particular less than 4% based on the total weight of said composition A.

[0060] Said composition A may optionally comprise at least one of the additional compounds C2 selected from the group consisting of 1,1,2-trifluoroethane, 1-chloro-1,1,2-trifluoroethane, 1-chloro-2,2-difluoroethylene, 1-chloro-1,2-difluoroethylene, 1-chloro-1,2,2-trifluoroethane. The mass content of said at least one of the additional compounds C2 may be less than 5% based on the total weight of said composition A, advantageously less than 4%, preferably less than 3%, more preferably less than 2%, in particular less than 1% based on the total weight of said composition A. Reaction flow treatment

[0061] Stream B from step a) may be treated to recover a purified trifluoroethylene (HFO-1123) stream. Said stream B may comprise, in addition to trifluoroethylene, HF, HCl, unreacted hydrogen, unreacted chlorotrifluoroethylene, optionally one or more of the additional compounds Cl or C2

[0062] Said current B can be treated according to the following steps:

[0063] i. Removal of HF and / or HCl from said product stream obtained in step a) to form a gas mixture; ii. Drying of the gas mixture from step i); iii. Treatment of the dried gas mixture in step ii) to remove hydrogen and optionally inert gases; iv. Distillation of the mixture from step iii).

[0064] Stream B from step a) is recovered at the reactor outlet in gaseous form. Preferably, at the outlet of the hydrogenolysis reactor, the product stream is first treated to remove HCl and HF. The product stream is passed through water in a washing column and then washed with a dilute base such as NaOH or KOH. The remainder of the gas mixture, consisting of the unconverted reactants (H2 and CTFE), diluting nitrogen (if present), trifluoroethylene and the additional compounds mentioned above, is directed to a dryer in order to remove traces of washing water. Drying can be carried out using products such as sodium or magnesium calcium sulfate, calcium chloride, potassium carbonate, silica gel (silica gel) or zeolites. In one embodiment, a molecular sieve (zeolite) such as siliporite is used for drying.The gas mixture thus dried is subjected to a step of separating the hydrogen and the inerts from the rest of the other products present in the gas mixture by absorption / desorption in the presence of an alcohol comprising 1 to 4 carbon atoms and preferably ethanol, at atmospheric pressure and at a temperature below room temperature, preferably below 10°C and even more preferably at a temperature of -25°C, for absorption. In one embodiment, the absorption of the organics is carried out in a countercurrent column with ethanol cooled to -25°C. The flow rate of ethanol is adjusted according to the flow rate of organics to be absorbed. The hydrogen and the inert gases, insoluble in ethanol at this temperature, are eliminated at the top of the absorption column. The organics are then recovered by heating the ethanol to its boiling point (desorption), to be subsequently distilled.Alternatively, step iii) may be carried out by a membrane separation process.

[0065] According to step iv), the organics thus obtained are distilled to form and recover a stream DI comprising trifluoroethylene and a stream D2 comprising chloro-trifluoroethylene and optionally one or more of the additional compounds Cl or C2. The stream D2 can be recycled to step a).

[0066] According to a preferred embodiment, the distillation step iv) is carried out at a pressure of less than 3 bara, preferably at a pressure of between 0.5 and 3 bara, in particular at a pressure of between 0.9 and 2 bara. Carrying out distillation at a pressure of less than 3 bara makes it possible to make the process safe given the explosive nature of trifluoroethylene above 3 bara. preferably, distillation step iv) is carried out in a distillation column comprising structured packing. It has been observed that structured packing allows for a more efficient distillation step. Said structured packing may be made of a metallic material. Said DI stream is preferably recovered at the top of the distillation column. Before being recovered, the DI stream may optionally be partially condensed at the top of the distillation column. When partial condensation is carried out, the DI stream is brought to a temperature of -50°C to -70°C. The temperature is adjusted according to the applied pressure. Partial condensation makes it possible to improve the efficiency of the distillation by limiting the content of additional compounds in the DI stream.Said DI stream may comprise at least 95% trifluoroethylene, advantageously at least 96%, preferably at least 97%, in particular at least 98%, more particularly at least 99% by weight based on the total weight of said stream B. Composition

[0067] According to a second aspect, the present invention provides compositions comprising chlorotrifluoroethylene.

[0068] Said composition comprises at least 80% by weight of chlorotrifluoroethylene and at least one of the additional compounds selected from the group consisting of 1,1,1-trifluoroethane, 1,1,1,2-tetrafluoroethane, hexafluorocyclobutene, fluoroethane, 2-chloro-1,1,1-trifluoroethane, 1,2-dichlorohexafluorocyclobutane; the total mass content of said at least one of the additional compounds is less than 15% based on the total weight of said composition.

[0069] According to a preferred embodiment, the composition comprises 1,1,1-trifluoroethane and the total mass content of 1,1,1-trifluoroethane is less than 5000 ppm, advantageously less than 2500 ppm, preferably less than 1000 ppm, more preferably less than 750 ppm based on the total weight of said composition. When it is contained in the composition, the total mass content of 1,1,1-trifluoroethane is greater than 1 ppm, advantageously greater than 5 ppm, preferably greater than 10 ppm, more preferably greater than 20 ppm, in particular greater than 50 ppm, more particularly greater than 100 ppm based on the total weight of said composition.

[0070] According to a preferred embodiment, the composition comprises the 1,1,1,2-tetrafluoroethane and the total mass content of 1,1,1,2-tetrafluoroethane is less than 1000 ppm, advantageously less than 750 ppm, preferably less than 500 ppm, more preferably less than 250 ppm, in particular less than 100 ppm based on the total weight of said composition. When contained in the composition, the total mass content of 1,1,1,2-tetrafluoroethane is greater than 1 ppm, advantageously greater than 5 ppm, preferably greater than 10 ppm, more preferably potentially greater than 20 ppm based on the total weight of said composition.

[0071] According to a preferred embodiment, the composition comprises hexafluorocyclobutene and the total mass content of hexafluorocyclobutene is less than 1%, advantageously less than 7500 ppm, preferably less than 5000 ppm, more preferably less than 2500 ppm, in particular less than 1000 ppm based on the total weight of said composition. When it is contained in the composition, the total mass content of hexafluorocyclobutene is greater than 1 ppm, advantageously greater than 5 ppm, preferably greater than 10 ppm, more preferably greater than 20 ppm, in particular greater than 50 ppm, more particularly greater than 100 ppm based on the total weight of said composition.

[0072] According to a preferred embodiment, the composition comprises fluoroethane and the total mass content of fluoroethane is less than 100 ppm, advantageously less than 75 ppm, preferably less than 50 ppm, more preferably less than 25 ppm, in particular less than 10 ppm based on the total weight of said composition. When it is contained in the composition, the total mass content of fluoroethane is greater than 0.1 ppm, advantageously greater than 0.5 ppm, preferably greater than 1 ppm based on the total weight of said composition.

[0073] According to a preferred embodiment, the composition comprises 2-chloro-1,1,1-trifluoroethane and the total mass content of 2-chloro-1,1,1-trifluoroethane is less than 1%, advantageously less than 7500 ppm, preferably less than 5000 ppm, more preferably less than 2500 ppm, in particular less than 1000 ppm based on the total weight of said composition. When it is contained in the composition, the total mass content of 2-chloro-1,1,1-trifluoroethane is greater than 1 ppm, advantageously greater than 5 ppm, preferably greater than 10 ppm, more preferably greater than 20 ppm, in particular greater than 50 ppm, more particularly greater than 100 ppm based on the total weight of said composition.

[0074] According to a preferred embodiment, the composition comprises 1,2-dichlorohexafluorocyclobutane and the total mass content of 1,2-dichlorohexafluorocyclobutane is less than 15%, advantageously less than 10%, preferably less than 5%, in particular less than 1% based on the total weight of said composition. According to a preferred embodiment, the total mass content of 1,2-dichlorohexafluorocyclobutane is less than 5000 ppm, advantageously less than 1000 ppm, preferably less than 500 ppm, more preferably less than 250 ppm, in particular less than 100 ppm based on the total weight of said composition. When it is contained in the composition, the total mass content of 1,2-dichlorohexafluorocyclobutane is greater than 1 ppm, advantageously greater than 5 ppm, preferably greater than 10 ppm, more preferably partially greater than 20 ppm based on the total weight of said composition. Examples

[0075] In a tubular reactor consisting of a stainless steel tube with a length of 1200 mm and a diameter of 25 mm, and equipped with a double jacket, 25 cm3 of catalyst (0.2% palladium supported on alpha alumina) were introduced. The catalyst thus loaded was then activated in the following manner: the reaction tube was placed in a tubular furnace and was supplied with a flow of hydrogen (from 0.05 to 0.1 moles per gram of catalyst). The catalytic bed was heated to a temperature of 200°C to 250°C with a temperature gradient of 0.2°C / min. After this activation period, the tube was cooled to room temperature and then isolated for subsequent installation on a hydrogenolysis test bench.

[0076] Four test benches are used in parallel, each comprising a reactor prepared as described above. The four benches were supplied with 1 mol / h of starting composition and 1 mol / h of hydrogen in anhydrous form. The temperature of the reactor jacket is 25°C. The contact time, calculated as the ratio between the volume in liters of catalyst and the sum of the flow rates of the reactants in normal liters per second, was of the order of 22 seconds. Tests are carried out using different starting compositions. Comparative Example 1 was carried out using chlorotrifluoroethylene.Example 2 according to the invention was carried out using the chlorotrifluoroethylene used in the comparative example to which the following compounds were added to obtain a composition A with the proportions mentioned for each of the constituents: 1,1,1-trifluoroethane (519 ppm), 1,1,1,2-tetrafluoroethane (39 ppm), hexafluorocyclobutene (880 ppm), fluoroethane (5 ppm), 2-chloro-1,1,1-trifluoroethane (600 ppm), 1,2-dichlorohexafluorocyclobutane (68 ppm) and trifluoroethylene (2.9%) and the balance in chlorotrifluoroethylene.

[0077] The results are shown in Table 1 below:

[0078] [Tableauxl] Examples Flow rate H2 g / h Flow rate CTFEg / h Product. VF3 g / h Ex. 1 (Comp.) 2 115.87 113.04 Ex. 2 (Invention) 2 115.87 173.33

[0079] The productivity mentioned corresponds to the sum of the productivities obtained for all four hydrogenolysis benches. As can be seen, the trifluoroethylene productivity is significantly improved starting from the composition according to the invention compared to a chlorotrifluoroethylene composition without the additional compounds.

Claims

Claims

1. Process for producing trifluoroethylene in a reactor equipped with a fixed catalytic bed comprising a catalyst, said process comprising a step a) of reacting a composition A comprising chlorotrifluoroethylene with hydrogen in the presence of a catalyst and in the gas phase to produce a stream B comprising trifluoroethylene, characterized in that said composition A also comprises at least one of the additional compounds Cl chosen from the group consisting of 1,1,1-trifluoroethane, 1,1,1,2-tetrafluoroethane, hexafluorocyclobutene, fluoroethane, 2-chloro-1,1,1-trifluoroethane, 1,2-dichlorohexafluorocyclobutane.

2. Method according to the preceding claim, characterized in that the total mass content of said at least one of the additional compounds Cl is less than 15% based on the total weight of said composition A, preferably less than 10% based on the total weight of said composition A, in particular less than 5% based on the total weight of said composition A.

3. A method according to any one of the preceding claims characterized in that said composition A comprises at least 80% by weight of chlorotrifluoroethylene based on the total weight of said composition A, preferably at least 85% by weight of chlorotrifluoroethylene based on the total weight of said composition A, in particular at least 90% by weight of chlorotrifluoroethylene based on the total weight of said composition A.

4. Method according to any one of the preceding claims, characterized in that said composition A also comprises trifluoroethylene, preferably in a mass content of less than 5% based on the total weight of said composition A.

5. Process according to any one of the preceding claims, characterized in that said composition A also comprises at least one of the additional compounds C2 selected from the group consisting of 1,1,2-trifluoroethane, 1-chloro-1,1,2-trifluoroethane, 1-chloro-2,2-difluoroethylene, E / Z-1-chloro-1,2-difluoroethylene, 1-chloro-1,2,2-trifluoroethane.

6. Method according to the preceding claim, characterized in that the mass content of said at least one of the additional compounds C2 is in- less than 5% based on the total weight of said composition A.

7. Process according to any one of the preceding claims characterized in that the catalyst comprises palladium supported on alpha alumina.

8. Process according to any one of the preceding claims, characterized in that the chlorotrifluoroethylene and the hydrogen are in anhydrous form.

9. Method according to any one of the preceding claims, characterized in that said method comprises a step i') of activation of the catalyst, carried out prior to step a), by bringing it into contact with a gaseous flow comprising a reducing agent, an inert gas or a mixture thereof.

10. Method according to the preceding claim characterized in that during said step i'): - the temperature of the catalytic bed is increased from a temperature T1 to a temperature T2 higher than T1 with a temperature gradient of less than 0.5°C / min; or - the temperature of the catalytic bed is increased from a temperature T1 to a temperature T2 higher than T1 in stages.

11. Composition comprising at least 80% by weight of chlorotrifluoroethylene and at least one of the additional compounds selected from the group consisting of 1,1,1-trifluoroethane, 1,1,1,2-tetrafluoroethane, hexafluorocyclobutene, fluoroethane, 2-chloro-1,1,1-trifluoroethane, 1,2-dichloro-hexafluorocyclobutane; the total mass content of said at least one of the additional compounds is less than 15% based on the total weight of said composition.