Installation and process for the storage and distribution of cryogenic fluid

The vaporization gas recovery line with pressure and flow control devices addresses the challenge of underground storage by efficiently recycling gases, maintaining pump operation and reducing losses in cryogenic fluid distribution systems.

FR3159001B1Active Publication Date: 2025-12-26LAIR LIQUIDE SA POUR LETUDE & LEXPLOITATION DES PROCEDES GEORGES CLAUDE
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Patent Information

Application Number
FR2024000982
Authority / Receiving Office
FR · FR
Patent Type
Patents
Current Assignee / Owner
Filing Date
2024-02-01
Publication Date
2025-12-26
Estimated Expiration
2044-02-01

AI Technical Summary

Technical Problem

The challenge of supplying cryogenic pumps with liquid during their lifecycle phases is exacerbated when the storage tank is buried underground, as gravity-fed liquid supply is hindered, and vaporization gases are difficult to return to the tank when the tank's highest point is lower than the pump inlet, leading to inefficiencies and evaporative losses.

Method used

A vaporization gas recovery line with a pressure and/or flow control device regulates the tank pressure above the pump inlet pressure, utilizing components like heaters, heat exchangers, and compressors to manage vaporization gases, ensuring efficient recovery and reinjection into the tank.

Benefits of technology

This solution maintains a positive pressure differential, ensuring continuous pump operation by recovering and recycling vaporization gases, reducing overall station losses and maintaining efficient fluid supply.

✦ Generated by Eureka AI based on patent content.

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Abstract

The invention relates to a cryogenic fluid storage and distribution installation, for example of liquid hydrogen, comprising a cryogenic tank (11) buried underground, a liquid withdrawal circuit (20) connected to the tank (11) with a downstream end located above ground and intended to be connected to a user, the withdrawal circuit (20) comprising, disposed above ground, a cryogenic pump (2), the installation (1) comprising a vaporization gas recovery line (3) generated within the pump (2) having a downstream end connected to the tank (11), the vaporization gas recovery line (3) comprising at least one device (8, 9) for regulating the pressure and / or flow of the vaporization gas returned to the tank (11), the pressure and / or flow regulation device (8, 9) being configured to regulate the pressure within the tank (11) to a pressure level higher than the pressure at the inlet of the pump (2).Abbreviated figure: Fig. 1.
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Description

Title of the invention: Installation and method for storing and distributing cryogenic fluid

[0001] The invention relates to an installation and a method for storing and distributing cryogenic fluid.

[0002] The invention relates more particularly to a cryogenic fluid storage and distribution installation, for example of liquid hydrogen, comprising a cryogenic tank buried underground, a liquid withdrawal circuit comprising an upstream end connected to the tank and a downstream end located above ground and intended to be connected to a user, the withdrawal circuit comprising, disposed above ground, a cryogenic pump, the installation comprising a vaporization gas recovery line generated within the pump having an upstream end connected to the pump and a downstream end connected to the tank.

[0003] The space required for hydrogen storage is a major challenge. One solution is underground storage. However, combining underground cryogenic storage with above-ground filling pumps raises the issue of supplying these pumps with liquid during their various lifecycle phases. Liquid is traditionally supplied to the pump by gravity, provided there is sufficient liquid level in the storage tank to ensure the liquid reaches the pump inlet. Furthermore, in cryogenic fueling stations, the pump requires a cooling phase during startup, which causes some of its supply to evaporate (boiling gas, or "BOG"). This vaporization gas is usually returned to the storage tank via lines that carry the gas to the top of the tank. When the storage tank is located above the pump, this return occurs naturally.This function becomes more difficult to ensure in a configuration where the highest point of the storage tank is lower than the pump inlet.

[0004] One object of the present invention is to overcome all or part of the disadvantages of the prior art noted above.

[0005] To this end, the installation according to the invention, which also conforms to the generic definition given in the preamble above, is essentially characterized in that the vaporization gas recovery line includes at least one pressure and / or flow control device for the vaporization gas returned to the tank, the pressure and / or flow control device being configured to regulate the pressure within the tank at a pressure level higher than the pressure at the pump inlet.

[0006] This arrangement ensures a good supply of power to the pump for to ensure its operation by allowing the recovery of vaporization gases from the pump in storage to reduce overall station losses.

[0007] Furthermore, embodiments of the invention may include one or more of the following features: - The pressure and / or flow control device is configured to regulate the pressure within the tank to a level between 5mbar and 500mbar above the pressure at the pump inlet. - the pressure and / or flow control device includes at least one of the following: a heater, a heat exchanger, a compressor, for example a cryogenic compressor, - The pressure and / or flow control device comprises, arranged in series, a preheating heat exchanger, a compressor, - the vaporization gas recovery line comprises two separate passages in the preheating heat exchanger, respectively before and after compression in the compressor, to ensure respectively preheating of the vaporization gas before compression and cooling before injection into the tank, - The vaporization gas recovery line includes a bypass line for the heat exchanger and a set of valve(s) configured to allow at least part of the vaporization gas flow to bypass the heat exchanger, - the vaporization gas recovery line includes a branch equipped with a valve leading to an evacuation zone. - the installation includes a self-contained tank pressurization device separate from the vaporization gas recovery line and the control device, - The invention also relates to a method of drawing fluid using an installation according to any one of the characteristics above or below, characterized in that it comprises the following steps: pumping cryogenic liquid from the reservoir via the pump, recovery of vaporization gases generated at the pump, compression of the recovered vaporization gases and injection of the compressed gases into the reservoir at a determined pressure.

[0008] According to other possible features: - The compression of the recovered vaporization gases is carried out with a cryogenic compressor or with a non-cryogenic compressor, the vaporization gases being heated before compression in the case of the non-cryogenic compressor, - the compression of the recovered vaporization gases is carried out with a non-cryogenic compressor and also includes a step of cooling the compressed vaporization gases via a heat exchange with the vaporization gas stream upstream of the compressor.

[0009] The invention may also relate to any alternative device or method comprising any combination of the above or below features within the scope of the claims.

[0010] Other features and advantages will become apparent from the following description, given with reference to the figures in which: Brief description of the figures

[0011] The invention will be better understood upon reading the following description, given solely by way of example and made with reference to the accompanying drawings in which:

[0012] [Fig-1] is a schematic vertical cross-sectional view describing an example of a structure and the operation of an installation according to the invention. Detailed description

[0013] In all figures, the same references refer to the same elements.

[0014] In this detailed description, the following embodiments are examples. Although the description refers to one or more embodiments, this does not mean that the features apply only to a single embodiment. Simple features from different embodiments can also be combined and / or interchanged to provide other embodiments.

[0015] The cryogenic fluid storage and distribution installation 1 illustrated can be used, for example, for liquid hydrogen. The installation comprises a cryogenic tank 11 buried underground and a liquid withdrawal circuit 20 comprising an upstream end connected to the tank 11 and a downstream end located above ground and intended to be connected to a user.

[0016] The withdrawal circuit 20 includes, arranged above the ground, a cryogenic pump 2.

[0017] The installation 1 includes a vaporization gas recovery line 3 generated within the pump 2, having an upstream end connected to the pump 2 and a downstream end connected to the tank 11. This vaporization gas recovery line 3 includes at least one pressure and / or flow control device for the vaporization gas returned to the tank 11. This at least one pressure and / or flow control device 8, 9 being configured to regulate the pressure within the tank 11 to a pressure level higher than the pressure at the inlet of the pump 2.

[0018] This pressure and / or flow control device is preferably configured to regulate the pressure within the tank 11 above the pressure at the inlet of the pump in such a way as to overcome the hydrostatic head between the tank and the inlet of pump 2. For example, the pressure and / or flow control device is configured to regulate the pressure within the tank to a level between 5mbar and 500mbar above the pressure at the inlet of the pump, for example between 5mbar and 100mbar above the pressure at the inlet of the pump.

[0019] The pressure and / or flow control device comprises at least one of the following: a heater 8, a heat exchanger 7, a compressor 9, for example a cryogenic compressor. For the sake of simplicity, [Fig. 1] shows the three aforementioned components in series. Of course, only one or two may be required.

[0020] The pressure and / or flow control device may include or consist, for example, of a reheating heat exchanger 7 in series with a compressor 9.

[0021] The vaporization gas produced by the pump 2 is heated in the heat exchanger 7 and can then be returned to the tank 11.

[0022] The reservoir 11 can thus be kept under pressure to ensure an efficient supply to the pump 2. The pump 2, which is relatively high, is therefore at a lower pressure than that of the reservoir 11. This pressure difference represents, for example, between 10 and 100 mbar, as this is the pressure required to overcome the head difference between the reservoir 11 and the inlet of the pump 2 and the pressure losses in the inlet line. Recirculating the vaporization gas from the pump 2 into the reservoir 11 compensates for this relative pressure difference.

[0023] This architecture allows for the recovery of vaporization gases generated by pump 2 during its various operating phases. During startup, pump 2 produces a relatively large quantity of vaporization gases. After cooling, during its operation, pump 2 generates a smaller quantity of vaporization gases, for example, due to leaks, thermal ingress, etc.

[0024] These vaporization gases can be collected and returned to the tank 11 via the recovery line 3.

[0025] This allows all or part of these vaporization gases to be recovered during these different operating phases.

[0026] The vaporization gases are collected in the recovery line 3, heated in the heating exchanger 7, and compressed before being returned to the tank. The compressor 9 circulates the vaporization gas flow by compressing it to the tank pressure, for example, to a level of a few tens of millibars.

[0027] The compressed vaporization gas can pass back into the reheating heat exchanger 7 to be cooled before being reinjected into the tank 11.

[0028] If this heating exchanger 7 is not sufficient to heat the gas before compression (excessive vaporization gas flow rate, inlet temperature too cold, ...), an additional heat exchanger 8 (heater) may be provided to complete the heating up to a determined temperature (ambient temperature or compressor inlet temperature).

[0029] This optional heater 8 is shown in dotted lines between the heating exchanger 7 and the compressor 9.

[0030] As illustrated, a valve 5, for example an isolation valve, can be arranged in series between the pump 5 and the preheating heat exchanger 7. Similarly, a valve 5 is preferably provided upstream of the pump 2. A valve 5 can also be provided between the preheating heat exchanger 7 and the compressor 9.

[0031] Similarly, a non-return valve 4 can be provided upstream of the pump 2.

[0032] As illustrated, the vaporization gas recovery line can make two separate passes (preferably counter-current) in the reheating heat exchanger 7 respectively before and after compression in the compressor 9 to ensure respectively a reheating of the vaporization gas before compression and a cooling before injection of the compressed gas into the tank 11.

[0033] As schematically shown, the vaporization gas recovery line 3 may further include a heat exchanger bypass line 13 and a set of valve(s) 23 configured to allow at least part of the vaporization gas flow to bypass a passage through the heat exchanger 7. For example, the bypass line 13 allows all or part of the compressed vaporization gas flow to bypass the second pass through the reheating exchanger 7. This makes it possible to increase the temperature of the compressed vaporization gases before returning them to the tank 11 in order to stabilize the pressure in the tank 11 if it rises too rapidly.

[0034] As also illustrated, the vaporization gas recovery line 3 may include a branch 33 equipped with a valve leading to a discharge area. This branch may be located between the heating exchanger 7 and the compressor inlet 9.

[0035] The tank 11 may include a self-contained pressurization device 10 configured to increase its pressure as needed (by drawing off, heating and reinjecting fluid).

[0036] This recovery and utilization of vaporization gases makes it possible to maintain the reservoir 11 under positive pressure relative to the pump 2. This ensures good continuous intake into the pump 2. If the recovered vaporization gases are insufficient to maintain the sufficiently high pressure during the operation of the pump, the pressurization device 10 can be used to pressurize the reservoir 11.

[0037] Of course, the invention is not limited to this embodiment described above.

[0038] Thus, for example, the reheating heat exchanger 7 and the compressor 9 could be replaced by a cryogenic compressor (which can compress gas to cryogenic temperature without the need for prior heating).

Claims

Demands

1. Installation for the storage and distribution of cryogenic fluid, for example liquid hydrogen, comprising a cryogenic tank (11) buried underground, a liquid withdrawal circuit (20) comprising an upstream end connected to the tank (11) and a downstream end located above ground and intended to be connected to a user, the withdrawal circuit (20) comprising, disposed above ground, a cryogenic pump (2), the installation (1) comprising a vaporization gas recovery line (3) generated within the pump (2) having an upstream end connected to the pump (2) and a downstream end connected to the tank (11), characterized in that the vaporization gas recovery line (3) comprises at least one device (8, 9) for regulating the pressure and / or flow rate of the vaporization gas returned to the tank (11), the device (8,9) pressure and / or flow control being configured to regulate the pressure within the reservoir (11) to a pressure level higher than the pressure at the pump inlet (2).

2. Installation according to claim 1, characterized in that the pressure and / or flow control device is configured to regulate the pressure within the tank to a level between 5mbar and 500mbar above the pressure at the inlet of the pump (2).

3. Installation according to claim 1 or 2, characterized in that the pressure and / or flow control device (8, 9) comprises at least one of: a heater (8), a heat exchanger (7), a compressor (9), for example a cryogenic compressor.

4. Installation according to claim 3, characterized in that the pressure and / or flow control device (8, 9) comprises, arranged in series, a reheating heat exchanger (7), a compressor (9).

5. Installation according to claim 4, characterized in that the vaporization gas recovery line (3) comprises two separate passages in the reheating heat exchanger (7) respectively before and after compression in the compressor (9) to respectively ensure reheating of the vaporization gas before compression and cooling before injection into the tank (11).

6. An installation according to claim 4 or 5, characterized in that the vaporization gas recovery line (3) comprises a heat exchanger bypass line (13) and a set of valve(s) (23) configured to allow at least a portion of the gas flow to vaporization to avoid passing through the heat exchanger (7).

7. Installation according to any one of claims 1 to 6, characterized in that the vaporization gas recovery line (3) includes a branch (33) equipped with a valve to an evacuation zone.

8. Installation according to any one of claims 1 to 7, characterized in that it comprises a self-contained tank pressurization device (10) separate from the vaporization gas recovery line (3) and the control device (8, 9).

9. A method for withdrawing fluid using an installation according to any one of claims 1 to 8, characterized in that it comprises the following steps: pumping cryogenic liquid from the reservoir via the pump (2), recovering vaporization gases generated at the pump (2), compressing the recovered vaporization gases and injecting the compressed gases into the reservoir (2) at a determined pressure.

10. A method according to claim 9, characterized in that the compression of the recovered vaporization gases is carried out with a cryogenic compressor or with a non-cryogenic compressor, the vaporization gases being heated before compression in the case of the non-cryogenic compressor.

11. A method according to claim 10, characterized in that the compression of the recovered vaporization gases is carried out with a non-cryogenic compressor and further comprises a step of cooling the compressed vaporization gases via a heat exchange with the vaporization gas stream upstream of the compressor (9).