SPRAY COMPOSITIONS CONTAINING BIS-ETHYLHEXYLOXYPHENOL METHOXYPHENYL TRIAZINE

Abstract

SPRAY COMPOSITIONS CONTAINING BIS-ETHYLHEXYLOXYPHENOL METHOXYPHENYL TRIAZINE This disclosure relates to spray compositions including 2,4-bis-{[4-(2-ethylhexyloxy)-2-hydroxy]-phenyl}-6-(4-methoxyphenyl)-1,3,5-triazine, as well as processes for manufacturing and using such compositions. Figure for abstract: none

Description

Title of the invention: SPRAY COMPOSITIONS CONTAINING BIS-ETHYLHEXYLOXYPHENOL ME-THOXYPHENYL TRIAZINE FIELD OF INVENTION

[0001] This disclosure relates to spray compositions comprising 2,4-bis-{[4-(2-ethylhexyloxy)-2-hydroxy]-phenyl]-6-(4-methoxyphenyl)-1,3,5-triazine (INCI name: bis-ethylhexyloxyphenol methoxyphenyl triazine), as well as processes for manufacturing and using such compositions. DISCUSSION OF THE CONTEXT

[0002] Radiation with wavelengths between 290 nm and 400 nm allows the human epidermis to tan, while radiation with wavelengths between 290 and 320 nm, known as UVB rays, hinders the development of a natural tan. Exposure is also likely to cause a detrimental change in the biomechanical properties of the epidermis, resulting in the appearance of wrinkles and leading to premature skin aging (i.e., photoaging).

[0003] UVA rays with wavelengths between 320 and 400 nm penetrate the skin more deeply than UVB rays. UVA rays cause immediate and persistent tanning of the skin. Daily exposure to UVA rays, even for a short period under normal conditions, can damage collagen and elastin fibers, resulting in changes in the skin's microrelief, the appearance of wrinkles, and uneven pigmentation (spots, uneven skin tone).

[0004] Numerous studies show the need for effective protection against UVA and UVB to prevent sunburn, photoaging, and the like.

[0005] In order to obtain a high protection product, it is generally necessary to combine a large number of sunscreens and / or a large quantity of UV filters to achieve high levels of filtration efficiency.

[0006] However, high levels of UV filters do not lend themselves to the easy preparation of compositions with a stable and pleasant texture that can be sprayed. This is particularly true for compositions containing solid UV filters such as bis-ethylhexyloxyphenol methoxyphenyl triazine.

[0007] Consumers like sprayable sunscreen compositions because they are generally easy to apply and spread during application.

[0008] There remains a need in the art of improved spray compositions containing bis-ethylhexyloxyphenol methoxyphenyl triazine which have good UV protection capabilities in addition to good application and spraying properties.

[0009] Accordingly, one aspect of the present disclosure is a spray composition containing bis-ethylhexyloxyphenol methoxyphenyl triazine which has good UV protection properties in addition to good application and use properties. Summary of the invention

[0010] This disclosure relates to spray compositions comprising bis-ethylhexyloxyphenol methoxyphenyl triazine (BEMT). Preferably, bis-ethylhexyloxyphenol methoxyphenyl triazine (BEMT or bemotrizinol) is added to the compositions in an amount effective in protecting keratinous material against UV radiation.

[0011] This disclosure also relates to methods for manufacturing spray compositions that include the addition of bis-ethylhexyloxyphenol methoxyphenyl triazine during the formation of the compositions. Preferably, bis-ethylhexyloxyphenol methoxyphenyl triazine (BEMT) is added to the compositions in an amount effective in protecting the keratinous material from UV radiation.

[0012] It is understood that both the preceding general description and the following detailed description are provided only by way of example and explanation and not as a limitation of disclosure. DETAILED DESCRIPTION OF THE INVENTION

[0013] In the following description and the claims annexed thereto, it shall be understood that the terms used have their ordinary and usual meanings in the art, unless otherwise specified.

[0014] “Approximately” as used here means to within 10% of the number indicated (for example, "approximately 10%" means from 9% to 11% and "approximately 2%" means from 1.8% to 2.2%.

[0015] “Un” or “une” as used here means “at least one”.

[0016] “At least one” means one or more and thus includes components in individual products as well as mixtures / combinations.

[0017] As used herein, all proposed ranges are intended to include each specific point and range within the given ranges, and combinations of intermediate sub-ranges. Thus, a range from 1 to 5 specifically includes the integers in the range 1, 2, 3, 4, and 5, as well as sub-ranges such as 2 to 5, 3 to 5, 2 to 3, 2 to 4, 1 to 4, etc., and all fractional numbers in the range such as 1,2, 2,3, 3,4, etc., and sub-ranges including these fractional numbers such as 1.5 to 3.8, 2 to 4.3, 4.2 to 4.9, etc.

[0018] “Film-forming”, “film-forming polymer” or “film-forming agent” as used herein means a polymer or resin that is capable of leaving a film on the substrate to which it is applied, for example, after a solvent accompanying the film-forming agent has evaporated, been absorbed into the substrate and / or dissipated on it.

[0019] “Substitute” as used herein means comprising at least one substitute. Non-limiting examples of substituents include atoms, such as hydrogen or chlorine atoms, as well as functional groups, such as hydroxyl groups, ether groups, alkoxy groups, acyloxyalkyl groups, oxyalkylene groups, polyoxyalkylene groups, carboxylic acid groups, amine groups, acylamino groups, amide groups, halogen-containing groups, ester groups, thiol groups, sulfonate groups, thiosulfate groups, siloxane groups, and polysiloxane groups. The substituent(s) may also be substituted.

[0020] “Volatile”, as used herein, means having a flash point less than about 115 °C.

[0021] “Non-volatile”, as used here, means having a flash point greater than approximately 115 °C.

[0022] “Polymer” as used herein means a compound that is made up of at least two monomers.

[0023] “Exempt” or “substantially exempt” or “devoid of” as used herein This means that although it is preferable for no quantity of the specific component to be present in the composition, it is possible for very small quantities of it to be present in the compositions of the disclosure, provided that these quantities do not materially affect at least one, preferably most, of the advantageous properties of the compositions of the disclosure. Thus, for example, "oil-free" means that an effective quantity (i.e., greater than trace amounts) of oil(s) is omitted from the composition (i.e., about 0% by weight), "substantially oil-free" means that oil(s) are present in quantities not exceeding 0.1% by weight, and "oil-free" means that oil(s) are present in quantities not exceeding 0.25% by weight, relative to the total weight of the composition.The same nomenclature applies to all other ingredients identified throughout the application and in this paragraph, such as, for example, specific UV filters and / or surfactants (the compositions in the disclosure that are "free of oxybenzone and / or octinoxate," "substantially free of oxybenzone and / or octinoxate," and "devoid of oxybenzone and / or octinoxate," as well as "free of surfactants," "substantially free of surfactants," and "devoid of surfactants" have meanings consistent with the discussion in this paragraph), even if they are not specifically mentioned for each identified ingredient. The examples mentioned of the use of such language as those in this paragraph are intended to be provided as examples. as an example, not a limitation.

[0024] “UV Filters” as used herein means approved sunscreen active agents by a government regulatory agency such as the Food and Drug Administration (FDA) in the United States or the European Commission in Europe and includes organic UV filters such as avobenzone, octocrylene, benzophenones, benzotriazoles and merocyanines, as well as mineral UV filters such as zinc oxide (ZnO) and titanium dioxide (TiO2).

[0025] “Anhydrous” as used here means that the compositions of the disclosure contain less than 3% water, which means that compositions can also contain less than 2% water, and less than 1% water, as well as be "water-free", "substantially water-free" and "water-free".

[0026] "Keratinous materials" means nails (fingernails and / or toenails), skin such as the body, face and eye area, scalp, keratinous fibers such as eyelashes, eyebrows and hair, and mucous membranes such as lips.

[0027] “Physiologically acceptable” means compatible with spraying and having a pleasant colour, smell and feel, and which does not cause unacceptable discomfort (tingling or pulling) likely to discourage a consumer from using the composition.

[0028] “UV protection efficiency” or “filtration efficiency” in the context of the this disclosure is evaluated from one or more elements among FPS, FPUVA, critical wavelength and UVA-I / UV ratio.

[0029] The "SPF" (Sun Protection Factor) measures the level of protection against erythema provided by a composition. The SPF value corresponds to the ratio between the minimum erythematous dose (MED) measured on skin covered with the composition and the MED measured on bare skin. "SPF" is a term known in the art of sunscreens and is defined, for example, in "A new substrate to measure sunscreen protection factors throughout the ultraviolet spectrum," J. Soc. Cosmet. Chem., 40, 127-133 (May / June 1989).

[0030] The evaluation of the SPF (Sun Protection Factor) can be carried out, for example, in vitro with a spectrophotometer from Labsphere (North Sutton, NH, USA). In such an evaluation, the plate is the material onto which the composition under test is applied. For such an evaluation, polymethyl methacrylate (PMMA) plates can be used. An example of an acceptable protocol is currently undergoing ISO accreditation under the name ISO Committee Draft 23675.

[0031] The evaluation of the sun protection factor (SPF) can also be carried out in vivo in accordance with the ISO 24444:2019 protocol "Cosmetics-Sun protection test methods-In-vivo determination of the sun protection factor (SPF)." It can also be determined according to FDA protocols, as described in the document "Labeling and Effectiveness Testing; Sunscreen Drug Products for Over-the-Counter Human Use" published in the US Federal Register on 07 / 05 / 2011 (https: / / www.federalregister.gov / d / 2011-14766); 21 CFR Part 352 Subpart D § 352.72, updated and revised by the 2011 publication in the Federal Register.

[0032] “UVA protection factor” refers to a characteristic index assessing the UVA protection provided by a composition. For example, the UVA protection factor (UPPF) can be measured in vivo according to the "PPD" (Persistent Pigment Darkening) method of the ISO-24442:2022 protocol, measuring the skin color observed 2 to 4 hours after UVA exposure. It can also be determined according to FDA protocols, as described again in 21 CFR Part 352 Subpart D § 352.72 as mentioned above in relation to SPF.

[0033] UVA protection can also be assessed in vitro with the Labsphere® spectrophotometer under conditions such as those mentioned above in connection with the FPS. ISO 24443:2021 describes such an in vitro procedure. Broad-spectrum test procedures, in particular "critical wavelength" test procedures, are also available in 21 CFR Part 352 Subpart D § 352.72. Furthermore,

[0034] The FDA's broad-spectrum testing procedures include the determination of the UVA1 / UV ratio as described in "Sunscreen Drug Products for Over-the-Counter Human Use" published in the Federal Register https: / / www.federalregister.gov / documents / 26 / 02 / 2019 / 2019-03Q19 / sunscreen-drug-products-for-over-the-counter-human-use. In the assay described in the monograph, known as the Boots adaptation of the Diffey / Robson test method, a ratio is generated between the protection offered by the sunscreen product against UVA1 (340-400 nm) and the protection against total UV radiation (UVB and UVA at 290-400 nm) calculated from the absorbance curve. This UVA1 / UV ratio would represent the product's score in the in vitro test.

[0035] According to this disclosure, the compositions in this disclosure preferably have one or more of the following properties:

[0036] The compositions have a critical wavelength, as determined by FDA critical wavelength procedures, of at least 370 nm;

[0037] The compositions have an FPS value of at least 15, preferably at least 30, preferably at least 50 and preferably at least 70;

[0038] The compositions have an FPUVA / FPS ratio of at least 1 / 3, and preferably of at least 2 / 5; and / or

[0039] The compositions have a UVA1 / UV ratio of 0.7 or more, preferably 0.75 or plus, and preferably 0.8 or more.

[0040] The "makeup result," as used herein, refers to the visual impact of a composition when applied to a keratinous material such as the skin. The makeup result may refer to the apparent color of the product after application to a keratinous material or to an optical effect such as shine, the blurring of fine lines and imperfections, or a concealing effect on pores or blemishes after application of the product to the keratinous material.

[0041] “Longevity,” as used here, refers to compositions where the color or other apparent properties remain the same or substantially the same as at the time of application, as seen with the naked eye, after a prolonged period or after a particular stress event such as immersion in water or rubbing. “Longevity” can be evaluated by assessing the longevity properties by any method known in the art for evaluating such properties. For example, longevity can be assessed by a test involving the application of a composition to a keratinous material such as skin and evaluating the color of the composition after a prolonged period of time. For example, the color of a composition can be evaluated immediately following application to a keratinous material such as skin, and these characteristics can then be re-evaluated and compared after a certain time.Furthermore, these characteristics can be evaluated against other compositions, such as commercially available ones. "Longevity" can also be assessed using in vitro processes on non-keratinous substrates such as polymethyl methacrylate (PMMA), in which properties such as color, transparency, or in vitro FPS can be evaluated before and after a period or stress factor such as immersion in water, incubation at high temperatures, or the application of an abrasive technique.

[0042] “Natural” as in the expression “natural compound” means any compound derived directly from a natural substance such as a plant without having undergone chemical modification.

[0043] “Compound of natural origin” means any compound derived from a natural compound which has undergone one or more chemical modifications, for example by organic synthesis reaction, without the properties of the natural compound having been modified.

[0044] “Synthetic compound” means any compound that is neither a natural compound nor a composed of natural origin.

[0045] “Room temperature” means approximately 20 to 25 °C.

[0046] “Atmospheric pressure” means approximately 760 mmHg, i.e. approximately 105 pascals.

[0047] “UV filter” and “sunscreen agent” are used interchangeably in the present request.

[0048] “UV efficiency” and “UV protection” are used in a manner interchangeable in this application.

[0049] The compositions and processes of this disclosure may include, consist of, or consist essentially of the essential elements and limitations of the disclosure described herein, together with any additional or optional ingredients, components, or limitations described herein or otherwise useful. For example, the UV (ultraviolet) absorbing system of the compositions of the disclosure may "consist essentially of" bis-ethylhexyloxyphenol methoxyphenyl triazine alone, or bis-ethylhexyloxyphenol methoxyphenyl triazine in combination with zinc, titanium, and / or cerium oxides, and / or one or more organic UV filter(s).

[0050] For the purposes of this disclosure, the "fundamental novel property" associated with compositions, components and processes that "consist essentially of" identified ingredients or actions is "the spray angle, droplet distribution and / or product spray volume".

[0051] “Good application and use properties”, as used herein, refers to to the expected properties of a spray composition when dispensed from a suitable spray container. The desired characteristics in a spray composition, which can be referred to here as "performance properties," include an appropriate spray angle, droplet distribution, and product spray volume.

[0052] “Spray angle” or “spray cone angle” as used herein This represents the spray angle created when an actuator on the spray packaging is engaged to dispense the product from the packaging component. The spray angle can be measured visually by photographing the droplets as they exit the packaging component. Alternatively, the spray angle can be determined by measuring the diameter of the spray pattern created on a vertical surface when the packaging is sprayed at a known distance from the vertical surface. The spray angle can be calculated as twice the inverse cosine of half the diameter of the spray pattern divided by the distance of the packaging component from the vertical surface.

[0053] “Droplet distribution” as used herein refers to a property of a spray composition when sprayed from a conditioning component. The distribution can be visually assessed in terms of homogeneity or droplet size and distribution by spraying a spray composition at a controlled distance from a vertical surface and examining the droplet pattern created when the actuator is engaged for a predetermined time. Alternatively, the droplet distribution can be measured at with the aid of laser detection equipment such as a Malvern Spraytec spray particle size analyzer, in which the droplet distribution can be reported as a volume or size distribution.

[0054] “Product spray volume” as used herein for descriptive purposes The good usability properties of a spray composition refer to the quantity of product per unit of time dispensed from a spray container and is used interchangeably with "product spray quantity." The product spray volume can be determined volumetrically or gravimetrically and is recorded as the quantity of product dispensed over a controlled period of time.

[0055] The compositions of this disclosure may be in any form suitable for use as a personal care composition, such as a stick, paste, cream, anhydrous composition, aqueous / alcohol-based composition, emulsion (oil-in-water, water-in-oil, multiple emulsion such as oil-in-water-in-oil), nanoemulsion, thixotropic gel, liquid, etc. These compositions may be used for any personal care purpose in cosmetic and / or dermatological products such as, for example, sunscreen, foundation, lip balms, lipsticks, concealers, mascaras, leave-in hair products, eyeshadows, powders, etc.

[0056] Reference is made herein to trade names of materials, including, but not limited to, materials such as polymers and optional components. The materials are not intended to be limited to those described and referenced herein by a particular trade name. Equivalent materials (for example, those obtained from a different source under a different name or catalogue (reference) number) to those referenced by a trade name may be substituted and used in the processes described and claimed herein.

[0057] Unless otherwise stated, all percentages and ratios are calculated by weight. Unless otherwise stated, all percentages are calculated on the basis of the total weight of a composition. All component or composition levels refer to the active level of that component or composition and are understood to exclude impurities, for example, residual solvents or by-products, which may be present in commercially available sources.

[0058] All US patents or patent applications disclosed herein are expressly incorporated by reference in their entirety. Spray composition

[0059] According to this disclosure, spray compositions comprising a UV (ultraviolet) absorbing system comprising 4-bis-{[4-(2-ethylhexyloxy)-2-hydroxy]-phenyl]-6-(4-methoxyphenyl)-1,3,5-triazine (INCI name: Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine) is proposed. Such spray compositions may be in any suitable form and be capable of being sprayed by any means of spraying, such as a pump spray device or an aerosol spray device. For aerosol spraying, the spray compositions of this disclosure preferably include at least one propellant to facilitate atomization of the composition.

[0060] Suitable examples of acceptable compositional forms include, but are not limited to, anhydrous compositions, aqueous / alcohol-based compositions, and emulsions having either an outer aqueous phase (e.g., oil-in-water (o / w) emulsion) or an outer oily phase (e.g., water-in-oil (w / h) emulsion). Such exemplary compositional forms will be discussed in more detail below in relation to ingredients useful in such compositional forms.

[0061] The preferred spray compositions of this disclosure are fluid. "Fluid" specifically means a composition that is not solid at room temperature (25 °C) and whose viscosity can be measured. The term "fluid" means a liquid composition that flows under its own weight at room temperature (25 °C) and atmospheric pressure. Advantageously, a fluid composition according to this disclosure has a complex stiffness modulus G* of less than 1000 Pa, preferably less than 400 Pa, and preferably less than 200 Pa.

[0062] Preferably, the composition has, at 25 °C, a viscosity between 0.1 and 25 Pa.s and preferably between 0.5 and 22 Pa.s. A suitable method for measuring viscosity is generally carried out at 25 °C, using a Rheomat RM 180 viscometer equipped with a No. 3 or No. 4 rod, depending on the work recommendations, the measurement being carried out after 10 minutes of rotation of the rod in the composition (after which a stabilization of the viscosity and the speed of rotation of the rod is observed), at a speed of 200 rpm.

[0063] The spray compositions of this disclosure may also not be fluid at room temperature and atmospheric pressure, but become fluid when a high shear rate is applied. Spray compositions that are fluid under high shear rate conditions are preferably sprayed using spray packaging designed to exclude mixing of the spray composition and the propellant. Examples of suitable spray packaging include bag-on-valve packaging and may comprise an outer canister and an inner bag, in which the inner bag contains the spray composition and the space between the inner bag and the outer canister is pressurized using of any gas at a predetermined pressure. In such a "bag valve" packaging, an actuator is connected so that when the actuator is engaged, the gas pressure between the outer can and the inner bag is able to compress the inner bag and distribute the spray composition.

[0064] Preferably, spray compositions suitable for distribution via bag valve packaging should be fluid (less than 0.1 Pa.s) at high shear rates (about 1000 / s). B is-ethylhexyloxyphenol methoxyphenyl triazine

[0065] According to this disclosure, spray compositions comprising a UV (ultraviolet) absorbing system comprising 4-bis-{[4-(2-ethylhexyloxy)-2-hydroxy]-phenyl]-6-(4-methoxyphenyl)-1,3,5-triazine (INCI name: Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine) are proposed.

[0066] According to preferred embodiments, the UV-absorbing system comprises at least 5% by weight of bis-ethylhexyloxyphenol methoxyphenyl triazine, preferably at least 15% by weight of bis-ethylhexyloxyphenol methoxyphenyl triazine, preferably at least 20% by weight of bis-ethylhexyloxyphenol methoxyphenyl triazine, preferably at least 30% by weight of bis-ethylhexyloxyphenol methoxyphenyl triazine, preferably at least 40% by weight of bis-ethylhexyloxyphenol methoxyphenyl triazine, preferably at least 50% by weight of bis-ethylhexyloxyphenol methoxyphenyl triazine, preferably at least 70% by weight of bis-ethylhexyloxyphenol methoxyphenyl triazine, preferably at least 80% by weight of bis-ethylhexyloxyphenol methoxyphenyl triazine, and preferably at least 90% by weight of the bis-ethylhexyloxyphenol methoxyphenyl triazine, all weights being based on the total weight of the UV-absorbing system.The "UV absorbing system" contains all organic UV filters and / or all mineral UV filters present in the composition.

[0067] According to preferred embodiments, bis-ethylhexyloxyphenol methoxyphenyl triazine is present in the compositions of this disclosure in an effective UV absorption amount such as, for example, about 0.1% to about 10% by weight relative to the total weight of the composition, about 1% to about 10% by weight, about 2.5% to about 8% by weight, and about 4% to about 6% by weight, including all intermediate ranges and sub-ranges such as, for example, about 4.5% to about 10% by weight, and about 1% to about 8% by weight, about 1% to about 6% by weight, about 5.5% to about 8% by weight, about 5.7% to about 9% by weight, etc., all weights being based on the total weight of the composition. Additional sunscreen agents

[0068] According to preferred embodiments of this disclosure, spray compositions optionally further comprising at least one additional UV filter (in addition to bis-ethylhexyloxyphenol methoxyphenyl triazine) selected from the group consisting of organic UV filters and mineral UV filters such as zinc oxides, cerium oxides, titanium oxides and mixtures thereof are proposed.

[0069] The additional organic UV filter(s) may be hydrophilic or lipophilic. “Hydrophilic organic UV filter” means a water-soluble organic UV filter or a water-dispersible organic UV filter (in colloidal form). “Lipophilic organic UV filter” means a UV filter that is dissolved or dispersed in colloidal form in a liquid oil phase.

[0070] Suitable organic UV filters may be selected from the following non-exhaustive list of compounds: cinnamic compounds; anthranilate compounds; para-aminobenzoic acid compounds; salicylic compounds; dibenzoylmethane compounds; camphor compounds; benzophenone compounds; [3,[3-diphenylacrylate] compounds; triazine compounds other than bis-ethylhexyloxyphenol methoxyphenyl triazine; benzotriazole compounds; benzalmalonate compounds, including those cited in US patent 5,624,663; benzimidazole derivatives; imidazoline compounds; bis-benzoazolyl compounds as described in patents EP669323 and US 2,463,264; the compounds methylene bis(hydroxyphenylbenzotriazole) as described in applications US 5 237 071, US 5 166 355, GB2303549, DE197 26 184 and EP893119; the compounds benzoxazole as described in patent applications EP0832642, EP1027883, EP1300137 and DE10162844;Polymer filters and silicone filters such as those described in particular in application WO 93 / 04665; alkylstyrene-derived dimers such as those described in patent application DE19855649; 4,4-diarylbutadiene compounds such as those described in applications EP0967200, DE19746654, DE19755649, EP-A-1008586, EPI 133980 and EP133981, and mixtures thereof. Preferably, lipophilic organic UV filters are selected from salicylic compounds, dibenzoylmethane compounds, benzylidene camphor compounds; benzophenone compounds; triazine compounds other than bis-ethylhexyloxyphenol methoxyphenyl triazine; benzotriazole compounds; as well as other categories of compounds identified herein; and mixtures thereof.

[0071] Specific reference may be made to suitable salicylic compounds including Homosalate (homomentyl salicylate), marketed, for example, under the trade name "Eusolex HMS" by Rona / EM Industries; and ethylhexyl salicylate, marketed, for example, under the trade name "Neo Heliopan OS" by Symrise; and glycol salicylate. Other examples of compounds salicylates include phenyl salicylate; dipropylene glycol salicylate, for example marketed under the brand name "Dipsal" by Scher; and TEA salicylate, for example marketed under the brand name "Neo Heliopan TS" by Symrise.

[0072] Examples of suitable [3,[3-diphenylacrylate compounds include Octocrylene, for example marketed under the brand name "Uvinul N539" by BASF; and Etocrylene, for example marketed under the brand name "Uvinul N35" by BASF.

[0073] Suitable anthranilic compounds may include menthyl anthranilates, marketed for example under the brand name "Neo Heliopan MA" by Symrise.

[0074] Examples of dibenzoylmethane compounds include butyl methoxydiben-zoylmethane, for example marketed under the brand name "Parsol 1789" by DSM; and isopropyl dibenzoylmethane.

[0075] Suitable cinnamyl compounds include ethylhexyl methoxycinnamate, marketed for example under the brand name "Parsol MCX" by DSM; isopropyl methoxycinnamate; isopropoxyl methoxycinnamate; isoamyl methoxycinnamate, marketed for example under the brand name "Neo Heliopan E 1000" by Symrise; cinoxate (2-ethoxyethyl-4-methoxycinnamate); DEA methoxycinnamate; diisopropyl methylcinnamate; and glyceryl dimethoxycinnamate ethylhexanoate.

[0076] Examples of camphor compounds include benzylidenecamphor derivatives: 3-benzylidenecamphor, for example marketed under the brand name "Mexoryl SD" by Chimex; 4-methylbenzylidenecamphor, for example marketed under the brand name "Eusolex 6300" by Merck; benzylidenecamphor sulfonic acid, for example marketed under the brand name "Mexoryl SL" by Noveal; benzalconium camphor methosulfate, for example marketed under the brand name "Mexoryl SO" by Noveal; dicamphor sulfonic acid terephthalylidene, for example marketed under the brand name "Mexoryl SX" by Noveal; and polyacrylamidomethylbenzylidenecamphor, for example marketed under the brand name "Mexoryl SW" by Noveal.

[0077] Suitable benzophenone compounds include benzophenone-1 (2,4-dihydroxybenzophenone), such as that marketed under the brand name "Uvinul 400" by BASF; benzophenone-2 (tetrahydroxybenzophenone), such as that marketed under the brand name "Uvinul D50" by BASF; benzophenone-3 (2-hydroxy-4-methoxybenzophenone) or oxybenzone, such as that marketed under the brand name "Uvinul M40" by BASF; benzophenone-4 (hydroxymethoxybenzophenone sulfonic acid), such as that marketed under the brand name "Uvinul MS40" by BASF; benzophenone-5 (sodium hydroxymethoxybenzophenone sulfonate); benzophenone-6 (dihydroxy dimethoxybenzophenone), such such as that marketed under the brand name "Helisorb 11" by Norquay; benzophenone-8, such as that marketed under the brand name "Spectra-Sorb UV-24" by American Cyanamid; benzophenone-9 (Disodium dihydroxy dimethoxy benzo-phenonedisulfonate), such as that marketed under the brand name "Uvinul DS-49" by BASF; and benzophenone-12, and n-hexyl 2-(4-diethylamino-2-hydroxybenzoyl)benzoate (such as that marketed under the trade name UVINULA+ by BASF).

[0078] Examples of triazine compounds include diethylhexyl butamido triazone, such as that marketed under the brand name "Uvasorb HEB" by Sigma 3V; 2,4,6-tris(dineopentyl 4'-aminobenzalmalonate)-s-triazine; and bis-ethylhexyloxyphenol methoxyphenyl triazine, such as that marketed under the brand name “TINOSORB S” by BASF and ethylhexyl triazone, such as that marketed under the brand name “UVTNUL T150” by BASF.

[0079] Suitable benzotriazole compounds include phenylbenzotriazole derivatives: 2-(2H-benzotriazole-2-yl)-6-dodecyl-4-methylpheno, branched and linear, and those described in USP 5240975.

[0080] Suitable benzalmalonate compounds include dineopentyl 4'-methoxybenzalmalonate, and polyorganosiloxane comprising benzalmalonate functional groups, such as polysilicone-15, as marketed under the brand name "Parsol SLX" by Hoffmann-LaRoche.

[0081] Examples of benzimidazole compounds include, in particular, phenylbenzimidazole derivatives such as phenylbenzimidazole sulfonic acid, such as that marketed in particular under the brand name "Eusolex 232" by Merck, and phenyl dibenzimidazole tetrasulfonate disodium, such as that marketed under the brand name "Neo Heliopan AP" by Symrise.

[0082] Suitable imidazoline compounds include ethylhexyl dimethoxybenzylidene propionate dioxoimidazoline.

[0083] Examples of bis-benzoazolyl compounds include the compounds described in EP-669 323 and US patent no. 2 463 264.

[0084] Suitable para-aminobenzoic acid compounds include PABA (p-aminobenzoic acid), ethyl PABA, ethyl dihydroxypropyl PABA, pentyl dimethyl PABA, ethylhexyl dimethyl PABA, such as that marketed under the brand name "Escalol 507" by ISP, glyceryl PABA and PEG-25 PABA, such as that marketed under the brand name "Uvinul P25" by BASF.

[0085] Suitable bis-(hydroxyphenylbenzotriazole) methylene compounds include 2,2'-methylenebis[6-(2H-benzotriazol-2-yl)-4-methylphenol], such as that marketed under the brand name "Mixxim BB / 200" by Fairmount Chemical, 2,2'-methylenebis[6-(2H-benzotriazol-2-yl)-4-(l,l,3,3-tetramethylbutyl)phenol], such as that marketed in micronized form in aqueous dispersion under the brand name "Tinosorb M" by BASF or under the brand name "Mixxim BB / 100" by Fairmount Chemical, and derivatives as described in US patents No. 5,237,071 and 5,166,355, GB-2,303,549, DE-197,261,84 and EP-893,119, and drometrizole trisiloxane, such as that marketed under the brand name "Silatrizole" by Rhodia Chimie or "Mexoryl XL" by L'Oréal.

[0086] Examples of benzoxazole compounds include the 2,4-bis[5-l(dimethylpropyl)benzoxazol-2-yl-(4-phenyl)imino]-6-(2-ethylhexyl)imino-1,3,5-triazine, such as that marketed under the brand name Uvasorb K2A by Sigma 3V.

[0087] Suitable examples of shielding polymers and shielding silicones include the silicones described in WO 93 / 04665.

[0088] Suitable α-alkylstyrene derived dimers include the dimers described in DE-19855649.

[0089] Examples of 4,4-diarylbutadiene compounds include l,l-dicarboxy(2,2'-dimethylpropyl)-4,4-diphenylbutadiene.

[0090] According to preferred embodiments, the compositions of this disclosure further comprise at least one additional organic UV filter selected from the group consisting of Avobenzone (butyl methoxydibenzoylmethane), Octisalate (ethylhexyl salicylate), Ensulizole (phenylbenzimidazole sulfonic acid), Homosalate, Octocrylene, and mixtures thereof. In such embodiments, the UV-absorbing system may "consist of" or "consist essentially of" (1) bis-ethylhexyloxyphenol methoxyphenyl triazine and (2) at least one organic UV filter selected from the group consisting of Avobenzone (butyl methoxydibenzoylmethane), Octisalate (ethylhexyl salicylate), Ensulizole (phenylbenzimidazole sulfonic acid), Homosalate, Octocrylene, and mixtures thereof.

[0091] According to other preferred embodiments, however, the compositions of this disclosure are "free", "substantially free" or "devoid", as defined above, of one or more additional organic UV filters selected from the group consisting of Avobenzone (butyl methoxydibenzoylmethane), Octisalate (ethylhexyl salicylate), Ensulizole (phenylbenzimidazole sulfonic acid), Homosalate and Octocrylene, preferably two or more, preferably three or more, preferably four or more, or preferably all five of these five sunscreens.

[0092] According to preferred embodiments, the compositions of this disclosure are "free," "substantially free," or "devoid," as defined above, of one or more additional organic UV filters selected from the group consisting of OXYBENZONE (benzophenone-3), OCTINOXATE (methoxycinnamate). ethylhexyl), ETHYLHEXYL TRIAZONE, DROMETRIZOLE TRISILOXANE, METHYLENE BIS-BENZOTRIAZOLYL TETRAMETHYLBUTYL PHENOL, DIE-THYLAMINO HYDROXYBENZOYL HEXYL BENZOATE, DIETHYLHEXYL BUTAMIDO TRIAZONE, ISOAMYL P-METHOXYCINNAMATE, POLY-SILICONE-15, 4-METHYLBENZYLIDENE CAMPHOR, PHENYL DIBENZL MIDAZOLE DISODIUM TETRASULFONATE, METHOXYETHYLCYA-NOACETATE OF METHOXYPROPYLAMINO CYCLOHEXENYLIDENE, preferably two or more, preferably three or more, preferably four or more, etc., and preferably "free", "substantially free" or "devoid" of all these sunscreen agents.

[0093] According to preferred embodiments, the compositions of this disclosure are "free", "substantially free" or "devoid", as defined above, of OXYBENZONE (benzophenone-3) and / or OCTINOXATE (ethylhexyl methoxycinnamate).

[0094] If present in the compositions of this disclosure, at least one additional UV filter is preferably present in the compositions of this disclosure in an amount of at least about 5% by weight, preferably at least about 10% by weight, preferably at least about 12% by weight, preferably at least about 14% by weight, and preferably at least about 15% by weight, the upper end of the range of additional UV filter present preferably being about 40% by weight (e.g., about 5 to 40%, about 10 to 40%, about 12 to 40%, etc.), preferably about 30% by weight (e.g., about 5 to 30%, about 10 to 30%, about 12 to 30%, etc.), preferably about 25% by weight (e.g., about 5 to 25%, about 10 to 25%, about 12 at 25%, etc.), and preferably about 20% by weight (for example, about 5 to 20%, about 10 to 20%, about 12 to 20%, etc.), all weights being based on the total weight of the composition.

[0095] According to preferred embodiments, the compositions of this disclosure comprise 10% or less by weight relative to the total weight of the composition of additional UV filters, preferably less than 5% by weight relative to the total weight of the composition, preferably less than 3% by weight relative to the total weight of the composition, and preferably less than 1% by weight relative to the total weight of the composition.

[0096] According to preferred embodiments, the compositions of this disclosure comprise 10% or less by weight relative to the total weight of the composition of additional organic UV filters, preferably less than 5% by weight relative to the total weight of the composition, preferably less than 3% by weight relative to the total weight of the composition, and preferably less than 1% by weight per relative to the total weight of the composition.

[0097] According to preferred embodiments, the UV-absorbing system of the compositions of this disclosure may "consist of" or "consist essentially of" bis-ethylhexyloxyphenol methoxyphenyl triazine.

[0098] According to preferred embodiments, the UV-absorbing system of the compositions of this disclosure may "consist of" or "consist essentially of" (1) bis-ethylhexyloxyphenol methoxyphenyl triazine, and (2) zinc oxides, titanium oxides and / or cerium oxides.

[0099] According to preferred embodiments, the UV-absorbing system of the compositions of this disclosure may "consist of" or "consist essentially of" (1) bis-ethylhexyloxyphenol methoxyphenyl triazine, and (2) additional organic UV filter(s).

[0100] According to preferred embodiments, this disclosure envisages omitting one or more of the specific UV filters mentioned above from the UV-absorbing system of the compositions of this disclosure. By way of example, octocrylene and / or octinoxate may be omitted from the compositions. A similar omission of one or more of the specific UV filters mentioned is therefore envisaged.

[0101] The addition of particular UV filters to a spray composition of this disclosure may affect the addition of other ingredients to the spray composition to obtain a suitable product. For example, the addition of solid mineral UV filters may necessitate the addition of dispersing agents such as, for example, polyhydroxystearic acid. Furthermore, since bis-ethylhexyloxyphenol methoxyphenyl triazine is typically in powder (solid) form, it is generally solubilized in a suitable solvent during the formation of the composition. Such solvent selection, alone or in combination with the selection of additional UV filters for addition to the composition, may result in the selection of particular surfactants or emulsifiers based on the final composition of the aqueous and / or oily phase of the composition. Oil

[0102] According to preferred embodiments of this disclosure, compositions further comprising at least one oil are proposed. “Oil” means a substance that is hydrophobic and lipophilic, and is a liquid at approximately room temperature (20 to 25 °C) and approximately atmospheric pressure (760 mm Hg).

[0103] Suitable oils include volatile and / or non-volatile oils. These oils may be any acceptable oil, including, but not limited to, silicone oils and / or hydrocarbon oils.

[0104] According to certain embodiments, the compositions of this disclosure com Preferably, one or more volatile silicone oils are used. Examples of such volatile silicone oils include linear or cyclic silicone oils with 2 to 7 silicon atoms, these silicones optionally being substituted with alkyl or alkoxy groups of 1 to 10 carbon atoms. Specific oils that may be used in disclosure include octamethyltetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, heptamethyloctyltrisiloxane, hexamethyldisiloxane, decamethyltetrasiloxane, dodecamethylpentasiloxane, and mixtures thereof. Other volatile oils that may be used include KF 96A with a viscosity of 6 cSt, a commercial product from Shin Etsu with a flash point of 94 °C. Preferably, volatile silicone oils have a flash point of at least 40 °C.

[0105] Non-limiting examples of volatile silicone oils are listed in Table 1 below.

[0106] [Table 1]

[0107] [Tables] Compound Flash Point (°C) Viscosity (cSt) Octyltrimethicone Hexylrimethicone Decamethylcydopentasiloxane (cyclopentasiloxane or D5) Octamethylcyclotetrasiloxane (cydotetramethyisiloxane or D4) Dodecamethylcyclohexasilaxane (D6) DecamethylUetrasiloxane (14) KF-96 A from Shin Etsu PDMS (polydimethyisiloxane) DC 200 (1.5 cSt) from Dow Corning PDMS DC 200 (2 cSt) from Dow Corning 93 79 72 55 93 63 94 56 87 1.2 1.2 4.2 2.5 7 1.7 6 1.5 2

[0108] In addition, a linear volatile silicone oil may be used in this disclosure. Suitable linear volatile silicone oils include those described in US Patent No. 6,338,839 and WO03 / 042221, the contents of which are incorporated herein by reference. In one embodiment, the linear volatile silicone oil is decamethyltetrasiloxane. In another embodiment, decamethyltetrasiloxane is further combined with another solvent that is more volatile than decamethyltetrasiloxane.

[0109] According to certain embodiments of this disclosure, the composition preferably comprises one or more non-silicone volatile oils which may be selected from volatile hydrocarbon oils, volatile esters and ethers volatiles. Examples of these volatile non-silicone oils include, but are not limited to, volatile hydrocarbon oils having 8 to 16 carbon atoms and mixtures thereof, and in particular, branched C8-Cl6 alkanes such as C8-Cl6 isoalkanes (also known as isoparaffins), isohexadecane, isododecane, isodecane, and, for example, oils sold under the trade names Isopar or Permethyl. Preferably, volatile non-silicone oils have a flash point of at least 40 °C.

[0110] Non-limiting examples of volatile non-silicone oils are given in Table 2 below. [YES] [Table 2]

[0112] [Tableaux2] COMPOUND FLASH POINT (°C) Isododecane 43 n-Propylene glycol n-Butyl ether 60 Ethyl 3-Ethoxypropionate 58 Propylene glycol methyl ether acetate 46 Isopar L (Cn-Ci3 isoparaffin) 62 Isopar H (Cn-Ci2 isoparaffin) 56

[0113] According to certain embodiments of this disclosure, the composition comprises at least one non-volatile oil. Examples of non-volatile oils that may be used in this disclosure include, but are not limited to, polar oils such as, for example:

[0114] - esters and ethers, in particular fatty acids, such as oils of formula R1COOR2, in which RI represents the remainder of a fatty acid having from 8 to 29 carbon atoms, and R2 represents a hydrocarbon chain, branched or unbranched, containing from 3 to 30 carbon atoms, such as, for example, Purcellin oil, isononyl isononanoate, isopropyl myristate, ethyl-2-hexyl palmitate, octyl-2-dodecyl stearate, octyl-2-dodecyl erucate, isostearyl isostearate; hydroxylated esters such as isostearyl lactate, toctylhydroxystearate, octyldodecyl hydroxystearate, diisostearylmalate, triisocetyl citrate, heptanoates, octanoates, fatty alcohol decanoates; polyol esters, such as propylene glycol dioctanoate, neopentyl glycol diheptanoate and diethylene glycol diiso-nonanoate;triglycerides such as caprylic / capric acid triglycerides, for example those sold by Stearineries Dubois or those sold under the names Miglyol 810, 812 and 818 by Dynamit Nobel; and pentaerythritol esters such as pentaerythrityl tetraisostearate or dipentaerythrityl pentaisononanoate;

[0115] - ethers containing 10 to 40 carbon atony;

[0116] - liquid C8 to C26 fatty alcohols, for example oleyl alcohol, alcohol cetyl alcohol, stearyl alcohol, octyldodecanol and cetearyl alcohol;

[0117] - hydrocarbon oils of animal origin, such as perhydrosqualene;

[0118] - vegetable hydrocarbon oils, such as liquid triglycerides of fatty acids having 4 to 10 carbon atoms such as triglycerides of heptanoic or octanoic acid, for example, sunflower, corn, soybean, cucurbit, grapeseed, sesame, hazelnut, apricot, macadamia, ara, sunflower, castor oil, avocado oil, triglycerides of caprylic / capric acid, such as those sold by the Stéarineries Dubois company or those sold under the names Miglyol 810, 812, and 818, by the Dynamit Nobel Company, coco-caprylate / caprate (esterified coconut oil), jojoba oil, shea butter oil; and

[0119] - their mixtures.

[0120] In addition, examples of non-volatile oils that may be used in this disclosure include, but are not limited to, non-polar oils such as branched and unbranched hydrocarbons, in particular Vaseline (petrolatum), paraffin oil, squalane, squalene, hydrogenated polyisobutene, hydrogenated poly-lydecene, polybutene, a mineral oil, pentahydrosqualene, and mixtures thereof.

[0121] According to certain embodiments of this disclosure, the compositions of this disclosure may include at least one non-volatile silicone oil. Appropriate examples of such silicone oils include, but are not limited to, non-volatile silicone fluids such as, for example, polyalkyl (aryl) siloxanes. Appropriate polyalkyl siloxanes include, but are not limited to, polydimethyl siloxanes, which are designated CTFA dimethicone, polydiethyl siloxane, phenyl trimethicone, trimethyl pentaphenyl trisiloxane, phenyldimethicone, phenyltrimethylsi-loxydiphenylsiloxane, diphenyldimethicone, and diphenylmethyldiphenyltrisiloxane, and the siloxanes disclosed in the U.S. patent application publication No. 2004 / 0126350, the full disclosure of which is incorporated herein by reference. Specific examples of suitable high-viscosity silicone oils include, but are not limited to, PCR 15 M 30 (500 cSt) or Wacker Belsil PDM 1000 (1000 cSt) and Dow Corning 200 (350 cSt) (values ​​in parentheses represent viscosities at 25 °C).

[0122] Particularly preferred oils include, but are not limited to, one or more of the following: diisopropyl sebacate, C12-15 alkyl benzoate, phenethyl benzoate, isopropyl lauroyl sarcosinate, diisopropyl adipate, dibutyl adipate, dicaprylyl carbonate, dicaprylate / dicaprate, coco glycerides, caprylic / capric triglyceride, isopropyl myristate, isopropyl palmitate, coco caprylate / caprate, ethylhexyl palmitate, isononyl isononanoate, octyldodecanol, isohexadecane, isododecane, dicaprylyl ether, C15-19 alkane, dii-sopropyl adipate, dicaprylyl ether, and mixtures thereof.

[0123] Preferred oils for solubilizing bis-ethylhexyloxyphenol methoxyphenyl triazine include, but are not limited to, diisopropyl sebacate, C12-15 alkyl benzoate, phenethyl benzoate, isopropyl lauroyl sarcosinate, dibutyl adipate, butyl salicylate, dicaprylyl carbonate, dicaprylate / dicaprate, cocoglycerides, caprylic / capric triglyceride, isopropyl myristate, isopropyl palmitate, coco caprylate / caprate, ethylhexyl palmitate and mixtures thereof. Particularly preferred oils are C12-15 alkyl benzoate, phenethyl benzoate, isopropyl lauroyl sarcosinate, dibutyl adipate and butyl salicylate, with C12-15 alkyl benzoate being the most preferred.

[0124] According to preferred embodiments, the spray compositions of this disclosure comprise a system for solubilizing bis-ethylhexyloxyphenol methoxyphenyl triazine, including at least one solvent that is present in the system in an amount effective for solubilizing bis-ethylhexyloxyphenol methoxyphenyl triazine such that the composition is suitable for use as a spray composition and can be used as such. Preferably, the at least one solvent is selected from among the oils mentioned in the preceding paragraph.

[0125] According to preferred embodiments, at least one oil is present in the compositions of this disclosure in an amount ranging from about 1% to about 50% by weight, more preferably from about 5% to about 40% by weight, and preferably from about 10% to about 35% by weight, relative to the total weight of the composition, including all intermediate ranges and sub-ranges such as, for example, 15% to 40%, 20% to 45%, etc.

[0126] According to preferred embodiments, the compositions of this disclosure are anhydrous.

[0127] According to preferred embodiments, the compositions of this disclosure are in the form of an emulsion and contain at least one oily phase. Aqueous Phase

[0128] The compositions of this disclosure may also optionally contain water. When the compositions of this disclosure contain water, they are preferably in the form of an emulsion. Preferably, when the compositions of this disclosure contain water, they are in the form of an emulsion containing an external aqueous phase such as an oil-in-water emulsion. Water (O / W) or a water-in-oil-in-water (W / O / W) emulsion, or an emulsion containing an external oil phase such as a water-in-oil (W / O) or oil-in-water-in-oil (O / W / O) emulsion. Preferably, when in emulsion form, the oil phase may contain silicone oils (e.g., Si / O or W / Si emulsion) or hydrocarbon oils. Where applicable, water is preferably present in an amount of approximately 10% to approximately 80% by weight, preferably approximately 20% to approximately 70% by weight, preferably approximately 35% to approximately 65% ​​by weight, including all intermediate ranges and sub-ranges, all weights being based on the total weight of the composition.

[0129] According to preferred embodiments, however, the compositions of this disclosure are water-free, substantially water-free, or water-free as defined herein. Preferably, the compositions of this disclosure are anhydrous.

[0130] If present in compositions of this disclosure, the aqueous phase may include at least one water-soluble organic solvent that is liquid at room temperature and atmospheric pressure. For example, such at least one water-soluble organic solvent may include:

[0131] - triethyl citrate;

[0132] - C1-C5 monoalcohols having a C1-C5 alkane chain and a single functional group hydroxyl (OH). Suitable C1-C5 monoalcohols include methanol, ethanol, propanol, isopropanol, butanol and mixtures thereof;

[0133] - polyols (compounds having 2 or more hydroxyl groups) having, for example, 2 with 20 carbon atoms, preferably with 2 to 6 carbon atoms, such as for example glycerol, diglycerol, propylene glycol, isoprene glycol, dipropylene glycol, butylene glycol, hexylene glycol, 1,3-propanediol, pentylene glycol, simple sugars and water-soluble polyalkylene glycols;

[0134] - and their mixtures.

[0135] According to preferred embodiments, at least one water-soluble organic solvent is chosen from the group consisting of ethanol, dipropylene glycol, butylene glycol, propanediol and propylene glycol, and mixtures thereof.

[0136] Where appropriate, the water-soluble organic solvent(s) is / are preferably present in the compositions of this disclosure in a total amount ranging from 0.5% to about 40% by weight, preferably from about 3% to about 30% by weight, and preferably from about 5% to about 20% by weight, relative to the total weight of the composition, including all intermediate ranges and sub-ranges, such as 2% to 15%, 2% to 25%, 7.5% to 30%, etc.

[0137] According to preferred embodiments in which the composition of this disclosure is an alcohol-based composition, such compositions contain Preferably at least one C1-C5 monoalcohol in an amount of approximately 10% to approximately 80% by weight, preferably approximately 25% to approximately 75% by weight, and preferably approximately 40% to approximately 70% by weight, all weights being based on the total weight of the composition, including all intermediate ranges and sub-ranges. Additional optional ingredients

[0138] The compositions of this disclosure may also optionally further include at least one additive or auxiliary commonly used in spray compositions and known to a person skilled in the art as being capable of being incorporated into such compositions.Such additives or auxiliaries may be selected from coloring agents, film-forming agents, waxes, color-protecting agents such as piperidinol compounds, SPF enhancers such as diethylhexyl syringyl nemalonate, ethylhexyl methoxycrylene, and butyl octyl salicylate, thixotropic agents (e.g., clays), fillers, preservatives, perfumes, surfactants, antioxidants, free radical scavengers, spreading agents, dispersing agents, antifoaming agents, neutralizing agents, stabilizing agents, active ingredients selected from essential oils, moisturizing agents, vitamins, actives, proteins, ceramides, plant extracts, fibers and the like, wetting agents, and mixtures thereof. However, preferably, the compositions in this disclosure are "free," "substantially free," or "devoid" of such additives. Coloring agent.

[0139] According to preferred embodiments, spray compositions optionally including at least one coloring agent are proposed. Preferably, the at least one coloring agent is selected from the group consisting of soluble dyes, pigments, pearlescent pigments, and glitter.

[0140] The expression "soluble dyes" should be understood as referring to organic, inorganic or organometallic compounds, soluble in the composition as disclosed and intended to color said composition.

[0141] Suitable dyes are, for example, Sudan Red, DC Red 17, DC Green 6, [3-carotene, soybean oil, Sudan Brown, DC Yellow 11, DC Violet 2, DC Orange 5 and quinoline yellow.

[0142] The term “mother-of-pearl” should be understood as referring to iridescent particles of any form, in particular produced by certain molluscs in their shells or by synthetic means.

[0143] The term “pigments” should be understood as referring to inorganic or organic particles, white or colored of any shape, insoluble in the composition as disclosed and intended to color said composition.

[0144] Pigments can be white or colored, inorganic and / or organic. Among Inorganic pigments include titanium dioxide, optionally surface-treated, zirconium or cerium oxides, as well as zinc, iron (black, yellow or red) or chromium oxides, manganese violet, ultramarine blue, chromium hydrate and iron blue, and metallic powders such as aluminum powder and copper powder.

[0145] Among the organic pigments, we can mention carbon black, type D and C pigments and lakes based on carmine, cochineal, barium, strontium, calcium, aluminum.

[0146] Also citeable are effect pigments such as particles comprising a natural or synthetic organic or inorganic substrate, for example glass, acrylic resins, polyester, polyurethane, polyethylene terephthalate, ceramics, aluminas and optionally coated with metallic substances such as aluminium, gold, copper, bronze, or with metallic oxides such as titanium dioxide, iron oxide, chromium oxide, inorganic or organic pigments, and mixtures thereof.

[0147] Pearlescent pigments can be selected, for example, from pigments based on silica, titanium dioxide and mica, including, for example, mica-based pigments sold under the trade name Spectrval by Merck KGaA, white pearlescent pigments such as titanium-coated mica, or bismuth oxychloride-coated mica, colored pearlescent pigments such as titanium mica coated with iron oxides, titanium mica coated with ferric blue and chromium oxide in particular, titanium mica coated with an organic pigment of the aforementioned type and bismuth oxychloride-based pearlescent pigments.

[0148] Pigments with goniochromatic properties may be used, in particular liquid crystals or multilayer pigments.

[0149] It is also possible to use optical brighteners or fibers possibly coated with optical brighteners.

[0150] Preferably, at least one coloring agent is present in the compositions of this disclosure in an amount effective in providing a visible color upon spraying after application of the composition to the spray, preferably ranging from about 0.1% to about 50% by weight, preferably from about 0.2% to about 40% by weight, preferably from about 0.5% to about 25%, preferably from about 5% to about 25%, and preferably from about 5% to about 20% by weight relative to the weight of the composition, including all intermediate ranges and sub-ranges such as, for example, 2% to 15%, 25% to 50%, 3% to 8%, etc. Wax

[0151] According to preferred embodiments of this disclosure, compositions optionally comprising at least one wax are proposed. Preferably, the at least one wax has a melting point of at least 40 °C, preferably of at least 50°C, and preferably at least 60°C.

[0152] Appropriate examples of waxes that may be included in the compositions of this disclosure include those commonly used in the cosmetic field, such as, for example, synthetic waxes, silicone waxes, fatty alcohol waxes, waxes of natural origin, etc.

[0153] Specific waxes of natural origin include, in particular, beeswax and vegetable waxes, and include waxes such as carnauba wax, candelilla wax, ouricoury wax, Japanese wax, sunflower wax, cork fiber wax or sugar cane wax, bran (rice) wax, montan wax, paraffin wax, lignite wax or microcrystalline wax, ceresin or ozokerite, with beeswax, carnauba wax and bran (rice) wax being preferred.

[0154] Examples of silicone waxes, where appropriate, include, but are not limited to, silicone waxes such as alkyl- or alkoxydimethicones having an alkyl or alkoxy chain of 10 to 45 carbon atoms, poly(di)methylsiloxane esters which are solid at 30 °C and whose ester chain comprises at least 10 carbon atoms, di(l,l,l-trimethylolpropane tetrastearate), which is sold or manufactured by Heterene under the name HEST 2T-4S; Alkylated silicone acrylate copolymer waxes comprising at least 40 mol% of siloxy units conforming to the formula (R2R'SiO1 / 2)x(R"SiO3 / 2)y, where x and y have values ​​from 0.05 to 0.95, R is an alkyl group having 1 to 8 carbon atoms, an aryl group, a carbinol group, or an amino group, R is a monovalent hydrocarbon having 9 to 40 carbon atoms, R" is a monovalent hydrocarbon group having 1 to 8 carbon atoms, an aryl group such as those disclosed in the US patent application2007 / 0149703, the whole of which is incorporated by reference, a particular example being C30-C45 alkyldimethylsilyl polypropylsilsesquioxane; and mixtures thereof.

[0155] Fatty alcohol waxes preferably contain from about 8 to about 30 carbon atoms, preferably from about 12 to about 28 carbon atoms, and preferably from about 14 to about 24 carbon atoms, including, but not limited to, 8 to 24 carbon atoms, 12 to 16 carbon atoms, 16 to 22 carbon atoms, etc. The fatty alcohol wax may be saturated or unsaturated, linear or branched. Examples include cetyl alcohol, stearyl alcohol, behenyl alcohol, and mixtures thereof.Other examples of suitable fatty alcohol waxes include waxes comprising natural components (such as one or more natural oils) and fatty alcohol components such as, for example, hydrogenated stearyl olive ester, commercially available from the supplier Sophim under the trade name Phytowax Olive 18 L 57, and hydrogenated myristyl olive ester, commercially available from the supplier Sophim under the trade name Phytowax Olive 14 L48.

[0156] Where appropriate, at least one wax is preferably present in an amount of about 0.5% to about 30% by weight, preferably about 1% to about 25% by weight, preferably about 2.5% to about 25% by weight, and preferably about 5% to about 20% by weight, including all intermediate ranges and sub-ranges such as, for example, about 1% to about 12% by weight, about 2% to about 10% by weight, about 15% to about 25% by weight, and about 2% to about 8% by weight, all weights being based on the total weight of the composition.

[0157] According to some embodiments, the composition contains less than 10% by weight of beeswax, preferably less than 5% by weight of beeswax, preferably less than 2.5% by weight of beeswax, or is preferably "substantially free", "devoid" or "free" of beeswax as defined above.

[0158] According to some embodiments, the composition contains less than 10% by weight of synthetic wax, preferably less than 5% by weight of synthetic wax, preferably less than 2.5% by weight of synthetic wax, or is preferably "substantially free", "devoid" or "free" of synthetic wax as defined above.

[0159] According to some embodiments, the composition contains less than 10% by weight of silicone wax, preferably less than 5% by weight of silicone wax, preferably less than 2.5% by weight of silicone wax, or is preferably "substantially free of", "devoid of", or "free of" silicone wax as defined above. Thixotropic agent

[0160] According to certain embodiments, the compositions of this disclosure may also optionally include at least one additional thixotropic agent. The at least one thixotropic agent may be selected, for example, from hydrophilic or organophilic clays, hydrophilic or hydrophobic sublimed silicas, elastomeric organopolysiloxanes, and mixtures thereof.

[0161] Clays are silicates containing a cation that can be selected from among the cations calcium, magnesium, aluminum, sodium, potassium and lithium, and mixtures thereof. As used here, the expression "hydrophilic clay" refers to a clay capable of swelling in water; this clay swells in water and, after hydration, forms a colloidal dispersion.

[0162] Examples of such products include, but are not limited to, smectite family clays such as montmorillonites, hectorites, bentonites, beidellites and saponites, vermiculite family clays, stevensite and chlorites.

[0163] These clays can be of natural or synthetic origin.

[0164] Non-limiting examples of hydrophilic clays include smectites such as saponites, hectorites, montmorillonites, bentonites and beidellites and, in at least one embodiment, synthetic hectorites (also known as laponites), for example the products sold by the Laporte company under the names Laponite XLG, Laponite RD and Laponite RDS (these products include, for example, sodium magnesium silicates and sodium lithium magnesium silicates); bentonites, for example the product sold under the name Bentone HC by the Rheox company; magnesium aluminium silicates, which can be hydrated, for example the products sold by the Vanderbilt Company under the names Veegum Ultra, Veegum HS and Veegum DGT, and calcium silicates, such as the synthetic product sold by the company under the name Micro-cel C.

[0165] Organophilic clays are clays modified with chemical compounds that make the clay capable of swelling in solvent-based media.

[0166] The clay may be selected, for example, from montmorillonite, bentonite, hectorite, atapulgite, sepiolite and mixtures thereof. In one embodiment, the clay is selected from bentonite and hectorite.

[0167] The chemical compound used to modify the organophilic clay can be chosen, for example, from quaternary amines, tertiary amines, amine acetates, imidazolines, amine soaps, fatty sulfates, alkyl aryl sulfonates, amine oxides, and mixtures thereof.

[0168] Suitable organophilic clays include, but are not limited to, stearalconium clays such as stearalconium hectorite and stearalconium bentonites such as those sold under the names Bentone 27V by Elementis, Tixogel LG by United Catalyst, and Claytone AF and Claytone APA by Southern Clay; quaternium-18 bentonites such as those sold under the names Bentone 3, Bentone 38, Bentone 27 V CG, and Bentone 38V by Elementis, Tixogel VP by United Catalyst, and Claytone 34, Claytone 40, and Claytone XL by Southern Clay; and quaternium-18 / benzalconium bentonites such as those sold under the names Claytone HT and Claytone PS by Southern Clay.

[0169] Hydrophilic sublimated silicas can be obtained by high-temperature hydrolysis of a volatile silicon compound in an oxyhydrogen flame, producing finely divided silica. Hydrophilic silicas have a large number of silanol groups on their surface. Such hydrophilic silicas are sold, for example, under the names Aerosil 130®, Aerosil 200®, Aerosil 255®, Aerosil 300® and Aerosil 380® by the Degussa company, and Cab-O-Sil HS-5®, Cab-O-Sil EH-5®, Cab-O-Sil LM-130®, Cab-O-Sil MS-55® and Cab-O-Sil M-5® by the Cabot company.

[0170] Hydrophobic sublimed silicas can be obtained by modifying the surface of the silica via a chemical reaction that generates a reduction in the number of silanol groups, these groups possibly being substituted, for example, by hydrophobic groups.

[0171] Hydrophobic groups can be chosen, for example, from:

[0172] - trimethylsiloxyl groups, which can be obtained by processing silica sublimated in the presence of hexamethyldisilazane. Silicas treated in this way are known as "silica silylate" according to the CTFA (6th edition, 1995). They are sold, for example, under the references Aerosil R812® by Degussa, and Cab-O-Sil TS-530® by Cabot.

[0173] - the dimethylsilyloxyl or polydimethylsiloxane groups, which can be obtained in particular by treating sublimed silica in the presence of polydimethylsiloxane or dimethyldichlorosilane. Silicas treated in this way are known as "Silica dimethyl silylate" according to the CTFA (6th edition, 1995). They are sold, for example, under the references Aerosil R972® and Aerosil R974® by Degussa, and CAB-O-SIL TS-610® and CAB-O-SIL TS-720® by Cabot.

[0174] The at least one thixotropic agent, if any, may preferably be present in the composition in an amount ranging from 0.05 percent by weight, for example, preferably from about 0.05 percent to about 15 percent by weight, preferably from about 0.5 percent to about 10 percent by weight, and preferably from about 0.75 percent to about 5 percent by weight, all weights being relative to the total weight of the composition, including all intermediate ranges and sub-ranges such as, for example, 1% to 3%, 0.5% to 7%, 5% to 15%, etc. Charges

[0175] According to certain embodiments, the compositions of this disclosure may also optionally include in addition at least one charge.

[0176] Suitable examples of fillers include mineral or organic particles of any shape, in the form of a sheet, spherical or oblong, regardless of the crystallographic form (e.g. sheet, cubic, hexagonal, orthorhombic, etc.).Examples include talc, mica, kaolin, polyamide (Nylon®) (Orgasol® from Atochem), poly-[3-alanine and polyethylene] powders, tetrafluoroethylene polymer powders (Teflon®), lauroyl lysine, starch, boron nitride, acrylic acid copolymers (Polytrap® from Dow Corning) and silicone resin microbeads (Tospearls® from Toshiba, for example), polyorganosiloxane elastomer particles, precipitated calcium carbonate, magnesium carbonate and hydroxyapatite, glass or ceramic microcapsules, metallic soaps derived from carboxylic organic acids having 8 to 22 carbon atoms, preferably 12 to 18 carbon atoms, for example zinc, magnesium or lithium stearate, zinc laurate, Magnesium myristate.

[0177] At least one charge, if any, is preferably present in a quantity ranging from about 0.01% to about 15% by weight, preferably from about 0.1% to about 5% by weight, preferably from about 0.5% to about 2.5%, all weights being relative to the total weight of the nail compositions, including all intermediate ranges and sub-ranges.

[0178] A person skilled in the art shall ensure that the optional additional additives are chosen and / or their quantity so that the advantageous properties of the composition as disclosed are not, or are not substantially, compromised by the envisaged addition.

[0179] It goes without saying that the composition of the disclosure must be cosmetically or dermatologically acceptable, that is, it must contain a physiologically acceptable, non-toxic carrier. The composition may be in any pharmaceutical form normally used in the cosmetic and dermatological fields that is suitable for topical administration as mentioned above.

[0180] These auxiliary additives may be present in the composition in a proportion of 0% to 99% (such as 0.01% to 90%) relative to the total weight of the composition and furthermore such as 0.1% to 50% by weight (where appropriate), including all intermediate ranges and sub-ranges.

[0181] According to preferred embodiments of this disclosure, methods for protecting, enhancing the appearance of, and / or concealing keratinous material by applying spray compositions of this disclosure to the keratinous material in sufficient quantity to protect, enhance the appearance of, and / or conceal the keratinous material are proposed. Preferably, "concealing" the keratinous material includes applying a composition comprising at least one coloring agent to the keratinous material in sufficient quantity to conceal the keratinous material.

[0182] Preferably, the "protection" of the keratinous material includes the application of a composition of this disclosure to the keratinous material in sufficient quantity to protect the keratinous material from damage resulting from exposure to UV rays.

[0183] According to the preceding embodiments, the compositions of this disclosure are applied topically to the keratinous material in a sufficient quantity to protect, improve the appearance of, care for, and / or conceal the keratinous material. The compositions can be applied to the desired area as needed, preferably once or twice daily, more preferably once daily, and then preferably allowed to dry before being subjected to contact such as with clothing or other objects (e.g., clothing or a top coat). Preferably, the composition is allowed to dry for approximately 1 minute or less, more preferably for approximately 45 seconds or less.

[0184] According to preferred embodiments of this disclosure, processes of Protection of keratinous material against UV rays, including the application of spray compositions of this disclosure to the keratinous material in sufficient quantity to protect the keratinous material against UV rays, is proposed.

[0185] According to preferred embodiments of this disclosure, methods for manufacturing spray compositions comprising the addition of bis-ethylhexyloxyphenol methoxyphenyl triazine during the formation of the compositions are proposed. Preferably, bis-ethylhexyloxyphenol methoxyphenyl triazine (BEMT) is added to the compositions in an amount effective in protecting the keratinous material against UV radiation.

[0186] This disclosure also considers pre-packaged kits and / or materials suitable for consumer use containing one or more compositions as described herein, alone or in combination with other consumer care products such as makeup products like primers, top coats, makeup removers, etc. The packaging and application device for any subject of this disclosure may be selected and manufactured by persons skilled in the art based on their general knowledge and adapted according to the nature of the composition to be packaged. Indeed, the type of device to be used may be particularly related to the consistency of the composition, especially its viscosity; it may also depend on the nature of the constituents present in the composition, such as the presence of volatile compounds.

[0187] Unless otherwise stated, all numbers expressing quantities of ingredients, reaction conditions, etc., used in the patent specification and claims are to be understood as modified in all cases by the term "approximately". Accordingly, unless otherwise stated, the numerical parameters presented in the following patent specification and the attached claims are approximations that may vary depending on the desired properties that are sought to be obtained through this disclosure.

[0188] Although the numerical ranges and parameters defining the general scope of disclosure are approximations, the numerical values ​​shown in the specific examples are reported as accurately as possible. However, every numerical value inherently contains some errors necessarily resulting from the standard deviation found in its respective measurements. The following examples are intended to illustrate disclosure without, however, limiting its scope. Percentages are given on a weighted basis. Example 1

[0189] [Tables3] INGREDIENT(S) SUNSCREEN SPRAY (% by weight) Octisalate (UV FILTER) 2.88 Homosalate (UV FILTER) 9.6 Avobenzone (UV FILTER) 2.68 Bemotrizinol (UV FILTER) 3.46 EMULSIFIERS 2.33 EMOLLIENTS <2 VITAMINS AND PRESERVATIVES <2 Polyurethane-35 and Stearyl Alcohol (POLYMERS AND THICKENERS) 2.62 HUMECTANT 3 WATER QS Example 2

[0190] [Tables4] INGREDIENT(S) SPRAY SPF50 (% by weight) Avobenzone (UV FILTER) 3 Octisalate (UV FILTER) 4.5 Bemotrizinol (UV FILTER) 6 Ensulizole (UV FILTER) 0.5 C12-22 Alkyl Acrylate / Hydroxyethyl Acrylate Copolymer (THICKENER) 2 ADDITIONAL THICKENERS 0.25 OILS / EMOLLIENTS 22 WATER QS VITAMINS AND PRESERVATIVES <2 GLYCOLS / HUMECTANTS 7 C1-C5 MONO ALCOHOL 5 Example 3

[0191] [Tables5] INGREDIENT(S) ANHYDROUS SPRAY SPF30 (% by weight) Avobenzone (UV FILTER) 3 Octisalate (UV FILTER) 5 Bemotrizinol (UV FILTER) 5 OIL / EMOLLIENT QS VITAMINS AND ACTIVE INGREDIENTS <2 Ethylenediamine / dilinoleate copolymer stearyl dimer (POLYMER) 3 C1-C5 monoalcohol 8

Claims

Demands

1. Spray composition comprising bemotrizinol, wherein bemotrizinol is present in the composition in an amount effective to protect the skin against UV rays.

2. Composition according to claim 1, wherein the composition comprises 10% or less by weight relative to the total weight of the composition of additional UV filters, preferably 10% or less by weight relative to the total weight of the composition of additional organic UV filters.

3. Composition according to any one of the preceding claims, wherein the composition is devoid of mineral UV filters.

4. Composition according to any one of the preceding claims, further comprising a propellant.

5. Composition according to any one of the preceding claims, wherein the composition is fluid.

6. Composition according to any one of the preceding claims, wherein the composition is in the form of an emulsion.

7. Composition according to any one of the preceding claims, wherein the composition is anhydrous.

8. Composition according to any one of the preceding claims, further comprising at least one C1-C5 monoalcohol.

9. Composition according to any one of the preceding claims, further comprising at least one active agent.

10. Composition according to any one of the preceding claims, wherein the composition is non-greasy when applied to the skin.