Method for preparing lithium iron phosphate by recycling waste batteries

Abstract

Provided is a method for preparing lithium iron phosphate by recycling waste batteries. First, waste lithium iron phosphate power batteries are pretreated to obtain pure lithium iron phosphate waste; next, each element is supplemented according to a ratio; and a lithium iron phosphate product is prepared by means of spray pyrolysis. The droplets of lithium iron phosphate sprayed by spray pyrolysis have high sphericity and uniform particle size distribution. After high temperature reaction, spherical lithium iron phosphate is obtained. The spheroidization of lithium iron phosphate is beneficial to increase the specific surface area of the material and increase the volume specific energy of the material. When removing impurities, waste heat of high-temperature lithium iron phosphate produced by spraying is used to atomize pure water to remove impurities by spraying, so that the atomized pure water is instantly evaporated, taking away impurities such as hydrogen chloride in the lithium iron phosphate particles. The prepared lithium iron phosphate cathode material has almost the same capacity and charge-discharge performance as the first synthesized lithium iron phosphate cathode material.

Description

TECHNICAL FIELD The present invention relates to the technical field of the new energy material of lithium- ion batteries, and more particularly, to a method of preparing lithium iron phosphate by recycling and utilizing waste batteries. BACKGROUND The lithium iron phosphate power battery has high safety, can be quickly charged and the number of cycles can reach 2000 times, has good safety performance, and has gradually become a new choice for the power battery of electric vehicles. With the increasing market share and scrap volume of lithium iron phosphate power batteries, the recycling utilization of lithium iron phosphate in the waste lithium iron phosphate power batteries also becomes one of the key contents of power battery recycling. Among a variety of lithium power batteries, only the positive electrode material of the lithium iron phosphate power battery does not contain precious metals but is mainly composed of aluminum, lithium, iron, phosphorus, and carbon. As such, enterprises are not enthusiastic about the recycling utilization of lithium iron phosphate, and there are relatively few studies on the recycling of lithium iron phosphate power batteries. Currently, the methods for recycling the positive electrode material of lithium iron phosphate are mainly high-temperature regeneration and wet recycling. The high-temperature regeneration process has high energy consumption and has strict requirements for the pre-treatment of waste materials. Strict impurity removal is required to avoid residual impurities. Compared with the first synthesized positive electrode material of lithium iron phosphate battery, the re-generated lithium iron phosphate shows a significant decrease in the capacitance and charge-discharge performance. The wet recycling technology is relatively mature, has relatively low requirements on the pretreatment of waste batteries, can achieve a high metal recovery rate, thereby obtaining a high-purity precursor material. The current wet recycling method mainly uses crude iron phosphate and lithium-containing leaching liquid as products to be recycled, comprising an acid solution to prepare soluble salt solution and adding alkali to prepare iron phosphate salt and a lithium solution. In the preparation of iron phosphate salt, the pH is usually adjusted by adding sodium hydroxide. On the one hand, a large amount of cationic impurities of Na ions are introduced, causing a decrease of the purity of the subsequent lithium carbonate; on the other hand, since the phosphate salt is difficult to wash due to the high viscosity, both the acid dissolution process and the alkali-addition process will introduce a large amount of impurities of metal cations, which further increases the difficulty of phosphate washing. In order to lower the impurity content, the preparation of higher-purity iron phosphate salt will inevitably consume a large amount of water, thus forming a large amount of chemical wastewater difficult to be treated. Therefore, a new method of preparing lithium iron phosphate by recycling and utilizating waste batteries is needed to solve the above problems. SUMMARY The present invention intends to at least solve one of the technical problems existing in the current technology. For this purpose, the present invention proposes a method of preparing lithium iron phosphate by recycling and utilizing waste batteries. The method re-synthesizes the prepared positive electrode material of lithium iron phosphate by spray pyrolysis after processing the positive electrode material of the waste lithium iron phosphate power batteries. The capacitance and charge-discharge performance of the positive electrode material of lithium iron phosphate prepared by the method is almost the same as those of the first synthesized positive electrode material of lithium iron phosphate. According to one aspect of the present invention, a method of preparing lithium iron phosphate by recycling and utilizing waste batteries is disclosed, comprising the steps of: pre-processing a waste lithium iron phosphate battery to obtain lithium iron phosphate powder, adding alkaline liquid to the lithium iron phosphate powder, and filtering to obtain a filter residue; adding an iron source, a lithium source, or a phosphorus source to the filter residue, and performing ball milling to obtain a ball-milled product; preparing a carbon source solution, and adding a surfactant to the carbon source solution to obtain a mixed solution; mixing the ball-milled product and the mixed solution, performing spray pyrolysis to obtain a high-temperature powder, spraying atomized water to the high-temperature powder to remove impurities, and then calcined to obtain a finished product of lithium iron phosphate. In some embodiments of the present invention, The pre-processing process is as follows: successively discharging, disassembling, and screening the waste lithium iron phosphate battery to obtain a positive electrode sheet, crushing positive electrode sheet, and vibration screening the crushed the positive electrode sheet, undersized compost being the lithium iron phosphate powder. In some embodiments of the present invention, the iron source is one or more of the iron(II) oxalate, ferrous oxalate, ferric oxide, ferric phosphate, ferric chloride, ferrous chloride, or ferric nitrate. In some embodiments of the present invention, the lithium source is one or more of lithium carbonate, lithium hydroxide, or lithium dihydrogen phosphate. In some embodiments of the present invention, the phosphorus source is one or more ofammonium hydrogen phosphate, phosphoric acid, ammonium dihydrogen phosphate, or the iron phosphate. In some embodiments of the present invention, a molar ratio of lithium, iron, phosphorus in the ball-milled product is (1-1.05):(0.95-1):1. In some embodiments of the present invention, the carbon source is one or more of sucrose, starch, or glucose. In some embodiments of the present invention, a mass ratio of the carbon source solution to the ball-milled product is (1-8): 1. In some embodiments of the present invention, the surfactant is one or more of stearate, alkyl glucoside, fatty acid glyceride, or polysorbate. In some embodiments of the present invention, the surfactant is 0.1-3.0% of the total mass of the mixed solution. In some embodiments of the present invention, the pressure of the spray pyrolysis is 0.3-0.8MPa and the temperature is 500-750°C. In some embodiments of the present invention, the temperature of the calcining is 500-700°C with a heating rate of l-5°C / min and the duration of the calcining is 2-10 h. According to one preferred embodiment of the present invention, it at least has the following beneficial effects: 1. The present invention firstly pre-treats the waste lithium iron phosphate power battery to obtain a pure lithium iron phosphate waste and then supplements the ratio of various elements to prepare a lithium iron phosphate product by means of spray pyrolysis. Lithium iron phosphate droplets sprayed by spray pyrolysis have high sphericity and even particle size distribution. After the high-temperature reaction, spherical-like lithium iron phosphate will be obtained. The spheroidization of lithium iron phosphate is conducive to increase the specific surface area of the material and increase the volume specific energy of the material. 2. During the spraying reaction in the present invention, the spherical spraying droplet contains lithium iron phosphate solids, thereby avoiding the presence of hollow particles; through the addition of surfactants, the viscosity and surface tension of the spraying liquid can be further adjusted, which is conducive to the spray pyrolysis reaction and avoids the particles sticking together. 3. When removing impurities, the present invention uses the waste heat of the high-temperature lithium iron phosphate produced by spraying to remove impurities by atomizing and pure water spraying, so that the atomized pure water evaporates instantaneously, thereby taking away impurities such as hydrogen chloride in the lithium iron phosphate particles. 4. The whole process of the present invention reuses the waste lithium iron phosphate power battery, turns wastes into treasures, protects the environment, reduces the cost, has easy operations, and can be widely applied in the production of lithium iron phosphate. BRIEF DESCRIPTION OF DRAWINGS The present invention is further explained in combination with the drawings and embodiments. In which: Fig. 1 is a comparison diagram of the specific capacity and recycling performance between the first synthesized lithium iron phosphate product and the finished product of lithium iron phosphate prepared by Embodiment 1. DETAILED DESCRIPTION The concept of the present invention and the technical effects produced thereof will be described below clearly and completely in combination with the embodiments, so as to fully understand the purpose, features, and effects of the present invention. Obviously, the described embodiments are only a part of the embodiments of the present invention and not all the embodiments. Based on the embodiments of the present invention, other embodiments obtained by those skilled in the art without involving any inventive effort all belong to the protection scope of the present invention. Embodiment 1 A method of preparing lithium iron phosphate by recycling and utilizing waste batteries, comprising the steps of: SI: successively discharging, disassembling, and screening the waste lithium iron phosphate battery to obtain a positive electrode sheet, crushing the positive electrode sheet and vibration screening the crushed positive electrode sheet, removing aluminum foil on the upper layer to obtain lithium iron phosphate powder, adding alkaline liquid to the lithium iron phosphate powder, removing residual aluminum, filtering to obtain a filter residue; S2: adding an iron source, a lithium source, or a phosphorus source to the filter residue in SI, adjusting a molar ratio of lithium, iron, phosphorus to be 1.05:1:1, then performing high-energy ball milling to obtain a ball-milled product; S3: preparing a sucrose solution, and adding alkyl glucoside to the sucrose solution to obtain a mixed solution, the alkyl glucoside being 2.0% of a total mass of the mixed solution; S4: adding the mixed solution and the ball-milled product to a spray pyrolysis device at a mass ratio of 4:1 for spray pyrolysis, setting a spray pressure of the spray pyrolysis device to be 0.8MPa and temperature to be 750°C to obtain the high-temperature powder, eluting gas produced by spray pyrolysis to obtain an acid solution, spraying atomized water to the high-temperature powder by a water mist spray device to remove impurities, mixing the high-temperature lithium iron phosphate with atomized pure water, rapid vaporization of pure water removes impurities in the lithium iron phosphate particle, finally rising the temperature to 500°C at a speed of l°C / min, and remaining the temperature for 2 h to obtain a finished product of lithium iron phosphate. Embodiment 2 A method of preparing lithium iron phosphate by recycling and utilizing waste batteries, comprising: SI: successively discharging, disassembling and screening the waste lithium iron phosphate battery to obtain a positive electrode sheet, crushing the positive electrode sheet and vibration screening the crushed positive electrode sheet, removing aluminum foil on the upper layer to obtain lithium iron phosphate powder, adding alkaline liquid to the lithium iron phosphate powder, removing residual aluminum, filtering to obtain a filter residue; S2: adding an iron source, a lithium source or a phosphorus source to the filter residue in SI, adjusting a molar ratio of lithium, iron, phosphorus to be 1.05:0.95:1, then performing high-energy ball milling to obtain a ball-milled product; S3: preparing a starch solution, and adding fatty acid glyceride to the starch solution to obtain a mixed solution, the fatty acid glyceride being 3.0% of a total mass of the mixed solution; S4: adding the mixed solution and the ball-milled product to a spray pyrolysis device at a mass ratio of 6:1 for spray pyrolysis, setting a spray pressure of the spray pyrolysis device to be 0.8MPa and temperature to be 500°C to obtain high-temperature powder, eluting gas produced by spray pyrolysis to obtain an acid solution, spraying atomized water to the high-temperature powder by a water mist spray device to remove impurities, mixing the high-temperature lithium iron phosphate with atomized pure water, rapid vaporization of pure water removes impurities in the lithium iron phosphate particle, finally rising the temperature to 700°C at a speed of 5°C / min, and remaining the temperature for 10 h to obtain a finished product of lithium iron phosphate. Embodiment 3 A method of preparing lithium iron phosphate by recycling and utilizing waste batteries, comprising the steps of: SI: successively discharging, disassembling and screening the waste lithium iron phosphate battery to obtain a positive electrode sheet, crushing the positive electrode sheet and vibration screening the crushed positive electrode sheet, removing aluminum foil on the upper layer to obtain lithium iron phosphate powder, adding alkaline liquid to the lithium iron phosphate powder, removing residual aluminum, filtering to obtain a filter residue; S2: adding an iron source, a lithium source or a phosphorus source to the filter residue in SI, adjusting a molar ratio of lithium, iron, phosphorus to be 1:0.95:1, then performing high-energy ball milling to obtain a ball-milled product; S3: preparing a glucose solution, and adding polysorbate to the glucose solution to obtain a mixed solution, the polysorbate being 0.5% of a total mass of the mixed solution; S4: adding the mixed solution and the ball-milled product to a spray pyrolysis device at a mass ratio of 2:1 for spray pyrolysis, setting a spray pressure of the spray pyrolysis device to be 0.8MPa and temperature to be 600°C to obtain high-temperature powder, eluting gas produced by spray pyrolysis to obtain an acid solution, spraying atomized water to the high-temperature powder by a water mist spray device to remove impurities, mixing the high-temperature lithium iron phosphate with atomized pure water, rapid vaporization of pure water removes impurities in the lithium iron phosphate particle, finally rising the temperature to 600°C at a speed of 3°C / min, and remaining the temperature for 6 h to obtain a finished product of lithium iron phosphate. Fig. 1 is a comparison diagram of the specific capacity and recycling performance between the first synthesized (not used) conventional lithium iron phosphate product and the finished product of 5 lithium iron phosphate prepared by Embodiment 1. As can be seen from the Figure, their specific capacity and recycling performance are almost the same. The present invention is described in detail above in combination the Drawings. However, the present invention is not limited to the above embodiments. Within the knowledge scope of those skilled in the ail, various modifications can be made without departing from the scope of the present 10 invention. In addition, in the case of no conflict, the embodiments of the present invention and features in the embodiments can be combined with each other.

Claims

1. A method of preparing lithium iron phosphate by recycling and utilizing waste batteries, comprising:pre-processing a waste lithium iron phosphate battery to obtain lithium iron phosphate powder, adding alkaline liquid to the lithium iron phosphate powder, and filtering to obtain a filter residue;adding an iron source, a lithium source or a phosphorus source to the filter residue, and performing ball milling to obtain a ball-milled product;preparing a carbon source solution, and adding a surfactant to the carbon source solution to obtain a mixed solution;mixing the ball-milled product and the mixed solution, performing spray pyrolysis to obtain a high-temperature powder, spraying atomized water to the high-temperature powder to remove impurities, and then calcining to obtain a finished product of lithium iron phosphate.1 C. JL JL JL2. The method of claim 1, wherein pre-processing comprising: successively discharging, disassembling and screening the waste lithium iron phosphate battery to obtain a positive electrode sheet, crushing the positive electrode sheet and vibration screening the crushed positive electrode sheet, undersized compost being the lithium iron phosphate powder.

3. The method of claim 1, wherein the iron source is one or more of iron(II) oxalate, ferrous oxalate, ferric oxide, ferric phosphate, ferric chloride, ferrous chloride or ferric nitrate.

4. The method of claim 1, wherein a molar ratio of lithium, iron, phosphorus in the ball-milled product is (1-1.05):(0.95-1):1.

5. The method of claim 1, wherein the carbon source is one or more of sucrose, starch, or glucose.

6. The method of claim 1, wherein a mass ratio of the carbon source solution to the ball-milled product is (1-8):1.

7. The method of claim 1, wherein the surfactant is one or more of stearate, alkyl glucoside, fatty acid glyceride, or polysorbate.

8. The method of claim 1, wherein the surfactant is 0.1-3.0% of a total mass of the mixedsolution.

9. The method of claim 1, wherein a pressure of the spray pyrolysis is 0.3-0.8 MPa and a temperature is 500-750°C.

10. The method of claim 1, wherein a temperature of the calcining is 500-700°C with a heating 5 rate of l-5°C / min and a duration of the calcining is 2-10 h.A. CLASSIFICATION OF SUBJECT MATTERC01B 25 / 45(2006.01)i; H01M 10 / 54(2006.01)1; H01M 10 / 0525(2010.01)nAccording to International Patent Classification (IPC) or to both national classification and IPCB. FIELDS SEARCHEDMinimum documentation searched (classification system followed by classification symbols) C01B25; H01M10Documentation searched other than minimum documentation to the extent that such documents are included in the fields searchedElectronic data base consulted during the international search (name of data base and, where practicable, search terms used)CNABS, CNTXT, CNKI, VEN, WEB OF SCIENCE: W. 5IM0B, LJjScSh, LiFePO4, lithium iron phosphate, spray pyrolysis, bearing, carbon, ferrous, ball milling, stearic acid,APG, alkyl polyglycoside, fatty glyceride, polysorbateDOCUMENTS CONSIDERED TO BE RELEVANTCategory* Citation of document, with indication, where appropriate, of the relevant passages Relevant to claim No. PX CN 113526482 A (GUANGDONG BRUNP RECYCLING TECHNOLOGY CO., LTD. et al.) 22 October 2021 (2021-10-22) claims 1-10 X CN 112054261 A (KUNMING UNIVERSITY OF SCIENCE AND TECHNOLOGY) 08 December 2020 (2020-12-08) description, page 2, line 3-page 3, line 3 1-10 X CN 112408353 A (AIMU NEW ENERGY (JIANGSU) CO., LTD.) 26 February 2021 (2021-02-26) description, page 1, 17th-to-last line-page 2, line 19 1-10 X CN 110620278 A (RESEARCH INSTITUTE OF TSINGHUA UNIVERSITY IN SHENZHEN) 27 December 2019 (2019-12-27) description, page 1, 8th-to-last line-page 2, line 15 1-10A1™ 10CN 102148374 A (JIANGXI KINGLI TECHNOLOGY CO., LTD.) 10 August 2011 (2011-08-10)entire document| | Further documents are listed in the continuation of Box C. | J | See patent family annex.* Special categories of cited documents:“A” document defining the general state of the art which is not considered“O”“P”to be of particular relevanceearlier application or patent but published on or after the international filing datedocument which may throw doubts on priority claim(s) or which is cited to establish the publication date of another citation or other special reason (as specified)document referring to an oral disclosure, use, exhibition or other meansdocument published prior to the international filing date but later than the priority date claimed“T” later document published after the international filing date or priority date and not in conflict with the application but cited to understand the principle or theory underlying the invention“X” document of particular relevance; the claimed invention cannot be considered novel or cannot be considered to involve an inventive step when the document is taken alone‘Y’document of particular- relevance; the claimed invention cannot be considered to involve an inventive step when the document is combined with one or more other such documents, such combination being obvious to a person skilled in the aitdocument member of the same patent familyDate of the actual completion of the international searchDate of mailing of the international search report09 March 202228 March 2022Name and mailing address of the ISA / CNChina National Intellectual Property Administration (ISA / CN)No. 6, Xitucheng Road, Jimenqiao, Haidian District, Beijing 100088, ChinaFacsimile No. (86-10)62019451Authorized officerTelephone No.C. DOCUMENTS CONSIDERED TO BE RELEVANTCategory* Citation of document, with indication, where appropriate, of the relevant passages Relevant to claim No. A CN 102751548 A (ZHEJIANG UNIVERSITY) 24 October 2012 (2012-10-24) entire document 1-10 A KR 101435657 Bl (HANBAT NATIONAL UNIVERSITY INDUSTRY-ACADEMIC COOPERATION) 29 August 2014 (2014-08-29) entire document 1-10 A CN 112794300 A (HUNAN ZHONGDE NEW MATERIAL TECHNOLOGY CO., LTD.) 14 May 2021 (2021-05-14) entire document 1-10 A CN 109768344 A (JIANGXI GANFENG CYCLING TECHNOLOGY CO., LTD.) 17 May 2019 (2019-05-17) entire document 1-10 A JP 2009062256 A (TOKYO INSTITUTE OF TECHNOLOGY) 26 March 2009 (2009-03-26) entire document 1-10PCT / CN2021 / 142952Patent document cited in search report Publication date (day / month / year) Patent family member)s) Publication date (day / month / year) CN 113526482 A 22 October 2021 None CN 112054261 A 08 December 2020 CN 112054261 B 08 October 2021 CN 112408353 A 26 February 2021 None CN 110620278 A 27 December 2019 CN 110620278 B 02 July 2021 CN 102148374 A 10 August 2011 None CN 102751548 A 24 October 2012 CN 102751548 B 27 August 2014 KR 101435657 Bl 29 August 2014 None CN 112794300 A 14 May 2021 None CN 109768344 A 17 May 2019 None JP 2009062256 A 26 March 2009 None

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